CN106402898A - Dioxin treatment system of hazardous waste incineration furnace - Google Patents

Dioxin treatment system of hazardous waste incineration furnace Download PDF

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Publication number
CN106402898A
CN106402898A CN201610954778.5A CN201610954778A CN106402898A CN 106402898 A CN106402898 A CN 106402898A CN 201610954778 A CN201610954778 A CN 201610954778A CN 106402898 A CN106402898 A CN 106402898A
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China
Prior art keywords
dioxin
tower
treatment system
treatment
carbon powder
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Application number
CN201610954778.5A
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Chinese (zh)
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CN106402898B (en
Inventor
陆胜
邵文林
谢能
郝继军
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JIANGSU JINGNAN ENVIRONMENTAL PROTECTION TECHNOLOGY Co Ltd
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JIANGSU JINGNAN ENVIRONMENTAL PROTECTION TECHNOLOGY Co Ltd
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Priority to CN201610954778.5A priority Critical patent/CN106402898B/en
Publication of CN106402898A publication Critical patent/CN106402898A/en
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Classifications

    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F23COMBUSTION APPARATUS; COMBUSTION PROCESSES
    • F23GCREMATION FURNACES; CONSUMING WASTE PRODUCTS BY COMBUSTION
    • F23G5/00Incineration of waste; Incinerator constructions; Details, accessories or control therefor
    • F23G5/44Details; Accessories
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F23COMBUSTION APPARATUS; COMBUSTION PROCESSES
    • F23JREMOVAL OR TREATMENT OF COMBUSTION PRODUCTS OR COMBUSTION RESIDUES; FLUES 
    • F23J15/00Arrangements of devices for treating smoke or fumes
    • F23J15/02Arrangements of devices for treating smoke or fumes of purifiers, e.g. for removing noxious material
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F23COMBUSTION APPARATUS; COMBUSTION PROCESSES
    • F23JREMOVAL OR TREATMENT OF COMBUSTION PRODUCTS OR COMBUSTION RESIDUES; FLUES 
    • F23J15/00Arrangements of devices for treating smoke or fumes
    • F23J15/02Arrangements of devices for treating smoke or fumes of purifiers, e.g. for removing noxious material
    • F23J15/022Arrangements of devices for treating smoke or fumes of purifiers, e.g. for removing noxious material for removing solid particulate material from the gasflow
    • F23J15/025Arrangements of devices for treating smoke or fumes of purifiers, e.g. for removing noxious material for removing solid particulate material from the gasflow using filters
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F23COMBUSTION APPARATUS; COMBUSTION PROCESSES
    • F23JREMOVAL OR TREATMENT OF COMBUSTION PRODUCTS OR COMBUSTION RESIDUES; FLUES 
    • F23J15/00Arrangements of devices for treating smoke or fumes
    • F23J15/02Arrangements of devices for treating smoke or fumes of purifiers, e.g. for removing noxious material
    • F23J15/04Arrangements of devices for treating smoke or fumes of purifiers, e.g. for removing noxious material using washing fluids
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F23COMBUSTION APPARATUS; COMBUSTION PROCESSES
    • F23JREMOVAL OR TREATMENT OF COMBUSTION PRODUCTS OR COMBUSTION RESIDUES; FLUES 
    • F23J2215/00Preventing emissions
    • F23J2215/30Halogen; Compounds thereof
    • F23J2215/301Dioxins; Furans
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F23COMBUSTION APPARATUS; COMBUSTION PROCESSES
    • F23JREMOVAL OR TREATMENT OF COMBUSTION PRODUCTS OR COMBUSTION RESIDUES; FLUES 
    • F23J2217/00Intercepting solids
    • F23J2217/10Intercepting solids by filters
    • F23J2217/101Baghouse type
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F23COMBUSTION APPARATUS; COMBUSTION PROCESSES
    • F23JREMOVAL OR TREATMENT OF COMBUSTION PRODUCTS OR COMBUSTION RESIDUES; FLUES 
    • F23J2217/00Intercepting solids
    • F23J2217/50Intercepting solids by cleaning fluids (washers or scrubbers)
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F23COMBUSTION APPARATUS; COMBUSTION PROCESSES
    • F23JREMOVAL OR TREATMENT OF COMBUSTION PRODUCTS OR COMBUSTION RESIDUES; FLUES 
    • F23J2219/00Treatment devices
    • F23J2219/10Catalytic reduction devices
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F23COMBUSTION APPARATUS; COMBUSTION PROCESSES
    • F23JREMOVAL OR TREATMENT OF COMBUSTION PRODUCTS OR COMBUSTION RESIDUES; FLUES 
    • F23J2219/00Treatment devices
    • F23J2219/20Non-catalytic reduction devices
    • F23J2219/201Reducing species generators, e.g. plasma, corona

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  • Engineering & Computer Science (AREA)
  • Mechanical Engineering (AREA)
  • General Engineering & Computer Science (AREA)
  • Treating Waste Gases (AREA)

Abstract

The invention discloses a dioxin treatment system of a hazardous waste incineration furnace. The dioxin treatment system comprises a pretreatment system, an incineration system and a smoke purification system. The incineration system comprises a rotary kiln and a secondary combustion chamber. A dry reactor is arranged between a smoke outlet of a quench tower and a bag type dust collector of the smoke purification system, and lime activated carbon is jet in the dry reactor. A plasma dioxin removing tower is arranged behind the bag type dust collector. An activated carbon powder adding device is arranged in a circulating pond, and water mixed with activated carbon powder enters a wet deacidification tower to be sprayed. Multiple equipment and process controlling points are set in the whole hazardous waste incineration furnace, dioxin type substances are effectively adsorbed and controlled, and it is ensured that tail gas emission meets the standard. The dioxin treatment system is good in treatment effect, wide in treatment range, good in universality, high in treatment depth and high in operation stability and impact resistance, and the treatment effect is good in winter and summer.

Description

The dioxin treatment system of danger waste burning stove
Technical field
The present invention relates to field of environment protection equipment, especially a kind of dioxin treatment system of danger waste burning stove.
Background technology
Dioxin is the serious liposoluble substance of a kind of colorless and odorless, toxicity, is a class extremely toxic substance.In atmospheric environment Dioxin source is complicated, and smelting iron and steel, non-ferrous metal metallurgy, vehicle exhaust, burning produce(Including pharmaceutical wastewater burning, chemical industry The incineration of waste of factory, consumer waste incineration, coal-burning power plant etc.)Dioxin all can be produced, wherein danger waste waste incineration produces two The mechanism disliking English is more complicated, thus concerned degree highest.Existing danger waste burning stove is less to the process of dioxin or adopts Process dioxin with single equipment, thus environmental requirement can not be met.
Content of the invention
The applicant be directed to above-mentioned existing danger waste burning stove weaker to the process of dioxin the shortcomings of, provide a kind of structure to close The dioxin treatment system of the danger waste burning stove of reason, such that it is able to reach preferable dioxin treatment effect it is ensured that exhaust emissions Up to standard.
The technical solution adopted in the present invention is as follows:
A kind of dioxin treatment system of danger waste burning stove, including pretreatment system, CIU and system for cleaning fume, Described CIU includes rotary kiln and dual firing chamber;The exhanst gas outlet of the chilling tower in described system for cleaning fume is to cloth bag It is provided with dry type reactor between cleaner unit, carry out the injection of Activity of Lime charcoal wherein;It is provided with after sack cleaner Plasma removes dioxin tower;Circulating water pool is provided with active carbon powder adding apparatus, and the water of mixing and doping active carbon powder is again Enter in wet method extracting tower and sprayed.
Improvement further as technique scheme:
In described dual firing chamber, spray into air and combustion gas or fuel oil so as to abundant burn, and ensure flue gas 1100 DEG C in dual firing chamber The temperatures above area time of staying is more than 2 seconds.
It is secondary device that described plasma removes dioxin tower, and the first order is high energy electron ionized region, and the second level is that catalysis is inhaled Attached area.
Beneficial effects of the present invention are as follows:
The present invention passes through setting many places equipment and technology in whole danger waste burning furnace system and controls, and reaches the effect processing dioxin Really.In dual firing chamber, fully burn and dioxin is destroyed by fire with high temperature by spraying into air and combustion gas or fuel oil.Flue gas in chilling tower It is exported on the pipeline between sack cleaner and spray into active carbon powder, the dioxin to the heavy metal in flue gas and possible regeneration Class material is adsorbed.Removing in dioxin tower in plasma makes electronics, ion, free radical and neutral grain using high energy electron ray Son bombards dioxin macromole at a high speed repeatedly, and realizes reacting further using catalysis and absorption.The present invention is by active carbon powder Add circulating water pool and mix, the water being doped with active carbon powder is sprayed in wet method extracting tower, thus more effectively Absorption and control dioxin-like chemical are it is ensured that exhaust emissions is up to standard.High treating effect of the present invention, process range is wide, and versatility is good, Process depth height, operation stability and strong shock resistance, all there is good treatment effect summer in winter.
Brief description
Fig. 1 is the schematic diagram of the present invention.
In figure:1st, hydraulic pressure material-pulling device;2nd, rotary kiln;3rd, dual firing chamber;4th, waste heat boiler;5th, chilling tower;6th, dry type reaction Device;7th, sack cleaner;8th, plasma removes dioxin tower;9th, first order wet method extracting tower;10th, second level wet method extracting tower;11、 Smoke re-heater;12nd, chimney;13rd, circulating water pool;14th, active carbon powder.
Specific embodiment
Below in conjunction with the accompanying drawings, the specific embodiment of the present invention is described.
As shown in figure 1, danger waste burning furnace system generally includes waste pretreatment system, feeding system, CIU, flue gas Several part such as cleaning treatment system.Waste pretreatment system includes pretreatment and the feed process of waste, and industrial hazard is discarded Thing is transported to the center of disposal storehouse by special-purpose vehicle, and the broken material of needs is grabbed to hang by driving after crusher in crushing, compatibility and sent Enter kiln hood charging aperture on operating platform, sent into back by hydraulic pressure material-pulling device 1 after two-stage hydraulic pressure insertion plate door in kiln hood charging aperture Rotary kiln 2.
CIU by rotary kiln 2 and dual firing chamber 3, slag tap and control system forms;Rotary kiln 2 burns the flue gas producing and enters Enter dual firing chamber 3, in dual firing chamber 3, spray into air and combustion gas or fuel oil so as to abundant burn, and ensure flue gas in dual firing chamber 3 1100 DEG C of temperatures above area time of staying are more than 2 seconds, destroy dioxin by fire with high temperature.
System for cleaning fume is absorbed by waste heat recovery, chilling, dry type reactor 6 and cleaner, sour gas, cigarette Gas reheating, except dioxin equipment composition.The high-temperature flue gas that dual firing chamber 3 produces enter waste heat boiler 4, and recovery section energy production is steamed Vapour, steam is available for factory steam and other vapour by gas-distributing cylinder.The sedimentation interior entering waste heat boiler 4 in flue gas is provided with de- Nitre system is it is ensured that the index of exhaust emissions NOX.Flue gas temperature after waste heat boiler 4 drops to 500 DEG C~550 DEG C, and flue gas directly enters In chilling tower 5, spray cooling water, completes to be down to 200 DEG C of chilling in 1 second from 500 DEG C, ensure that flue gas purification system fortune The stability of row and reliability.It is provided with dry type reactor 6 between the exhanst gas outlet of chilling tower 5 is to sack cleaner 7, at it In carry out the injection of Activity of Lime charcoal, the heavy metal in activated carbon powder foot couple flue gas and may the dioxin-like chemical of regeneration carrying out Absorption, Calx carries out the sour gas in moisture absorption and absorption flue gas, and the dust after absorption and absorption enters sack cleaner 7, Deliver to plasma after being purified by sack cleaner 7 and remove dioxin tower 8 under being drawn of air-introduced machine, then the flue gas entrance first order is wet Carry out deacidification once again, after flue gas reheat, gas up to standard passes through smoke re-heater 11 in method extracting tower 9, second level wet method extracting tower 10 Enter air with chimney 12.Active carbon powder 14 is added circulating water pool 13 and mixes by the present invention, will be doped with active carbon powder 14 water is passed through in wet method extracting tower and is sprayed, thus more effectively adsorbing and controlling dioxin-like chemical it is ensured that tail gas is arranged Unconventional and unrestrained mark.
It is secondary device that the plasma that the present invention is arranged after sack cleaner 7 removes dioxin tower 8, and the first order is high energy Electron ionization area, the second level is catalytic adsorption area.High energy electron ionized region makes electronics, ion, freedom using high energy electron ray Base and neutral particle bombard at a high speed dioxin macromole, activation, ionization, each component cracking in waste gas repeatedly, are allowed to oxygen The chemical reaction of the series of complexes such as change.High treating effect, process range is wide, and versatility is good, processes depth high.Pass through rear one again The catalysis of level and absorption, can react the plasma oxygen not reacted further, improve the utilization rate of plasma oxygen, etc. Ion coefficient of oxygen utilization substantially achieves 100%, reduces generator power, and the consumption of electric energy is few, reduces operating cost.At two grades Reason design improves the operation stability of system, strong shock resistance, and all there is good treatment effect summer in winter.On market Other reactor ratios, reactor volume is moderate, has the rational time of staying, and reaction is completely.
Above description is explanation of the invention, is not the restriction to invention, without departing from the spirit of the invention, The present invention can make any type of modification.

Claims (3)

1. a kind of dioxin treatment system of danger waste burning stove, including pretreatment system, CIU and gas cleaning processing system System it is characterised in that:Described CIU includes rotary kiln(2)With dual firing chamber(3);Urgency in described system for cleaning fume Cold tower(5)Exhanst gas outlet to sack cleaner(7)Between be provided with dry type reactor(6), carry out Activity of Lime charcoal wherein Injection;In sack cleaner(7)It is provided with plasma afterwards and remove dioxin tower(8);Circulating water pool(13)It is provided with activated carbon Powder(14)Adding apparatus, mixing and doping active carbon powder(14)Water enter back in wet method extracting tower and sprayed.
2. according to described in claim 1 danger waste burning stove dioxin treatment system it is characterised in that:Described dual firing chamber(3) In, spray into air and combustion gas or fuel oil so as to abundant burn, and ensure flue gas in dual firing chamber(3)Interior 1100 DEG C of temperatures above areas The time of staying is more than 2 seconds.
3. according to described in claim 1 danger waste burning stove dioxin treatment system it is characterised in that:Described plasma removes two Dislike Integrata(8)For secondary device, the first order is high energy electron ionized region, and the second level is catalytic adsorption area.
CN201610954778.5A 2016-11-03 2016-11-03 The dioxin treatment system of dangerous waste incinerator Active CN106402898B (en)

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Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107983126A (en) * 2018-01-22 2018-05-04 天津市美好生活科技有限公司 Incineration flue gas minimum discharge purifying treatment method and its processing system
CN110006050A (en) * 2019-03-20 2019-07-12 浙江大维高新技术股份有限公司 Dangerous waste incineration flue gas purification system and technique
CN110180356A (en) * 2019-03-20 2019-08-30 浙江大维高新技术股份有限公司 The processing unit and method of Cremation Machine incineration flue gas
CN110793338A (en) * 2019-11-29 2020-02-14 中国科学院过程工程研究所 Flue gas purification and waste heat utilization system and method
CN112594728A (en) * 2020-12-07 2021-04-02 安徽欣创节能环保科技股份有限公司 Domestic waste incineration fly ash classification treatment system

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CN104637561A (en) * 2015-02-02 2015-05-20 中科华核电技术研究院有限公司 Plasma volume reducing system and method for processing nuclear facility solid waste
CN105202548A (en) * 2015-10-13 2015-12-30 武汉高特维电气有限公司 Flue gas treatment device for domestic refuse incineration
CN205505013U (en) * 2016-04-06 2016-08-24 山东格润内泽姆环保科技有限公司 Waste liquid, useless burning furnace flue gas processing system that burns admittedly
CN105972605A (en) * 2016-03-29 2016-09-28 东南大学 Small household garbage incineration treatment system and incineration treatment method
CN206131008U (en) * 2016-11-03 2017-04-26 江苏景南环保科技有限公司 Useless dioxin processing system who burns burning furnace of danger

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CN104637561A (en) * 2015-02-02 2015-05-20 中科华核电技术研究院有限公司 Plasma volume reducing system and method for processing nuclear facility solid waste
CN105202548A (en) * 2015-10-13 2015-12-30 武汉高特维电气有限公司 Flue gas treatment device for domestic refuse incineration
CN105972605A (en) * 2016-03-29 2016-09-28 东南大学 Small household garbage incineration treatment system and incineration treatment method
CN205505013U (en) * 2016-04-06 2016-08-24 山东格润内泽姆环保科技有限公司 Waste liquid, useless burning furnace flue gas processing system that burns admittedly
CN206131008U (en) * 2016-11-03 2017-04-26 江苏景南环保科技有限公司 Useless dioxin processing system who burns burning furnace of danger

Cited By (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107983126A (en) * 2018-01-22 2018-05-04 天津市美好生活科技有限公司 Incineration flue gas minimum discharge purifying treatment method and its processing system
CN110006050A (en) * 2019-03-20 2019-07-12 浙江大维高新技术股份有限公司 Dangerous waste incineration flue gas purification system and technique
CN110180356A (en) * 2019-03-20 2019-08-30 浙江大维高新技术股份有限公司 The processing unit and method of Cremation Machine incineration flue gas
CN110793338A (en) * 2019-11-29 2020-02-14 中国科学院过程工程研究所 Flue gas purification and waste heat utilization system and method
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CN112594728A (en) * 2020-12-07 2021-04-02 安徽欣创节能环保科技股份有限公司 Domestic waste incineration fly ash classification treatment system

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