CN106399756B - A kind of preparation method of high-performance cubic texture nickel-base alloy base band - Google Patents
A kind of preparation method of high-performance cubic texture nickel-base alloy base band Download PDFInfo
- Publication number
- CN106399756B CN106399756B CN201610787450.9A CN201610787450A CN106399756B CN 106399756 B CN106399756 B CN 106399756B CN 201610787450 A CN201610787450 A CN 201610787450A CN 106399756 B CN106399756 B CN 106399756B
- Authority
- CN
- China
- Prior art keywords
- alloy
- base band
- cold rolling
- nickel
- initial
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C19/00—Alloys based on nickel or cobalt
- C22C19/03—Alloys based on nickel or cobalt based on nickel
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C1/00—Making non-ferrous alloys
- C22C1/02—Making non-ferrous alloys by melting
- C22C1/023—Alloys based on nickel
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22F—CHANGING THE PHYSICAL STRUCTURE OF NON-FERROUS METALS AND NON-FERROUS ALLOYS
- C22F1/00—Changing the physical structure of non-ferrous metals or alloys by heat treatment or by hot or cold working
- C22F1/02—Changing the physical structure of non-ferrous metals or alloys by heat treatment or by hot or cold working in inert or controlled atmosphere or vacuum
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22F—CHANGING THE PHYSICAL STRUCTURE OF NON-FERROUS METALS AND NON-FERROUS ALLOYS
- C22F1/00—Changing the physical structure of non-ferrous metals or alloys by heat treatment or by hot or cold working
- C22F1/10—Changing the physical structure of non-ferrous metals or alloys by heat treatment or by hot or cold working of nickel or cobalt or alloys based thereon
Abstract
The invention discloses a kind of preparation method of high-performance cubic texture nickel-base alloy base band, belong to the preparing technical field of high temperature coating conductor industrialization textured metal base band.Technical scheme main points comprise the following steps：The preparation of initial ni-w-p alloy billet；The cold rolling of initial ni-w-p alloy billet；The primary recrystallization annealing of ni-w-p alloy cold rolling base band；The high temperature re-crystallization annealing of ni-w-p alloy base band.Preparation process of the present invention is simple, and obtained nickel-base alloy base band in liquid nitrogen temperature without ferromagnetism, mechanical strength is higher, is adapted to industrialized production.
Description
Technical field
The invention belongs to the preparing technical field of high temperature coating conductor industrialization textured metal base band, and in particular to Yi Zhonggao
The preparation method of performance cubic texture nickel-base alloy base band.
Background technology
Research shows that it is that second generation coating superconducting YBCO materials obtain to prepare high performance high temperature super conductor metal base band
The basis that must be applied.In the research of second generation high temperature coating superconductor, Ni-5at.%W alloy base bands are widely used as high-temperature coating
Layer superconducting tape base material epitaxial growth transition zone and superconducting layer, at present You Duo companies can with industrialized production,
But its mechanical strength is still relatively low and has ferromagnetism in liquid nitrogen temperature（Curie temperature is 335K）.Research shows, when tungsten
Nickel-tungsten alloy base-band is in liquid nitrogen temperature without ferromagnetism when atomic percentage content is more than 9.3at.%, and mechanical strength is higher, still
When the atomic percentage content of tungsten>It is difficult to obtain strong cubic texture by traditional base band syntheti c route when 5%.Publication No. CN
The patent of 101635185A discloses a kind of low or iron-free magnetic cubic texture nickel-tungsten alloy base-band preparation method, and this method is adopted
Initial alloy billet is prepared with powder metallurgy, and billet porosity prepared by powder metallurgy is larger, to follow-up transition zone and surpasses
The preparation of conducting shell has adverse effect on, and the preparation efficiency of powder is relatively low, cost is higher, it is difficult to realizes industrialized production.
The content of the invention
The purpose of the present invention is the nickel of high mechanical properties and strong cubic texture is prepared on the basis of industrialized production is realized
A kind of base alloy baseband, there is provided preparation method of high-performance cubic texture nickel-base alloy base band.
It is of the invention to adopt the following technical scheme that to achieve the above object, a kind of high-performance cubic texture nickel-base alloy base band
Preparation method, it is characterised in that concretely comprise the following steps：
The preparation of step 1, initial ni-w-p alloy billet
According to the atomic percentage content of tungsten and phosphorus it is respectively 9.5% by nickel block, tungsten block and phosphorus block that purity is 99.999%
Matched with 0.05%-0.1%, the mixing material after proportioning is placed in melting in electromagnetic induction vacuum melting furnace obtains nickel tungsten phosphorus
Alloy cast ingot, then ni-w-p alloy ingot casting removed keep the temperature 1h at 1800 DEG C after the oxide skin on surface after forged and hot rolling obtains
Obtain the initial ni-w-p alloy billet before cold rolling；
The cold rolling of step 2, initial ni-w-p alloy billet
Cold rolling is carried out after the oxide skin on initial ni-w-p alloy billet surface is removed and obtains ni-w-p alloy cold rolling base band,
Total deformation is 98.2%, and pass deformation is 2%-10%；
The primary recrystallization annealing of step 3, ni-w-p alloy cold rolling base band
Ni-w-p alloy cold rolling base band is subjected to primary recrystallization annealing and obtains ni-w-p alloy base band, its concrete technology bar
Part is：Heating-up temperature is 650-800 DEG C, and heating rate is 900 DEG C/min, and soaking time 15min, protective atmosphere is pure hydrogen；
The high temperature re-crystallization annealing of step 4, ni-w-p alloy base band
Ni-w-p alloy base band is subjected to high temperature re-crystallization annealing and obtains final products high-performance cubic texture nickel-base alloy
Base band, its concrete technology condition are：Heating-up temperature is 1200-1250 DEG C, and heating rate is 900 DEG C/min, and soaking time is
50min, protective atmosphere are pure hydrogen.
The present invention adds the phosphorus of certain content in the higher nickel tungsten of purity, makes in primary recrystallization annealing process
Phosphorous segregation makes in strip surface（100）The surface energy of crystal face is minimum, and crystal grain occurs when high temperature re-crystallization is annealed and grows up, with table
Face can reduce the driving force grown up as crystal grain and then form the iron-free Magnetic nickel base alloy baseband of strong cubic texture on top layer.
Brief description of the drawings
Fig. 1 is nickel-base alloy base band surface made from the embodiment of the present invention 1（200）Face pole figure；
Fig. 2 is nickel-base alloy base band surface made from the embodiment of the present invention 2（200）Face pole figure.
Embodiment
The above of the present invention is described in further details by the following examples, but this should not be interpreted as to this
The scope for inventing above-mentioned theme is only limitted to following embodiment, and all technologies realized based on the above of the present invention belong to this hair
Bright scope.
Embodiment 1
According to the atomic percentage content of tungsten and phosphorus it is respectively 9.5% by nickel block, tungsten block and phosphorus block that purity is 99.999%
Matched with 0.05%, the mixing material after proportioning is placed in melting in electromagnetic induction vacuum melting furnace obtains ni-w-p alloy
Ingot casting, then ni-w-p alloy ingot casting removed keep the temperature 1h at 1800 DEG C after the oxide skin on surface after forged and hot rolling obtain it is cold
Initial ni-w-p alloy billet before rolling；Cold rolling is carried out after the oxide skin on initial ni-w-p alloy billet surface is removed and obtains nickel
Tungsten phosphorus alloy cold rolling base band, total deformation 98.2%, pass deformation is 2%-10%；By ni-w-p alloy cold rolling base band into
The annealing of row primary recrystallization obtains ni-w-p alloy base band, its concrete technology condition is：Heating-up temperature is 650 DEG C, heating rate
For 900 DEG C/min, soaking time 15min, protective atmosphere is pure hydrogen；Ni-w-p alloy base band is subjected to high temperature re-crystallization annealing
Final products nickel-base alloy base band is obtained, its concrete technology condition is：Heating-up temperature be 1200 DEG C, heating rate for 900 DEG C/
Min, soaking time 50min, protective atmosphere are pure hydrogen.The nickel-base alloy base band surface（200）Face pole figure as shown in Figure 1,
The nickel-base alloy base band surface obtains strong cubic texture as seen from the figure.
Embodiment 2
According to the atomic percentage content of tungsten and phosphorus it is respectively 9.5% by nickel block, tungsten block and phosphorus block that purity is 99.999%
Matched with 0.1%, the mixing material after proportioning is placed in melting in electromagnetic induction vacuum melting furnace obtains ni-w-p alloy casting
Ingot, then ni-w-p alloy ingot casting removed keep the temperature 1h at 1800 DEG C after the oxide skin on surface after forged and hot rolling obtains cold rolling
Preceding initial ni-w-p alloy billet；Cold rolling is carried out after the oxide skin on initial ni-w-p alloy billet surface is removed and obtains nickel tungsten
Phosphorus alloy cold rolling base band, total deformation 98.2%, pass deformation are 2%-10%；Ni-w-p alloy cold rolling base band is carried out
Primary recrystallization annealing obtains ni-w-p alloy base band, its concrete technology condition is：Heating-up temperature is 800 DEG C, and heating rate is
900 DEG C/min, soaking time 15min, protective atmosphere is pure hydrogen；Ni-w-p alloy base band is carried out high temperature re-crystallization annealing to obtain
Final products nickel-base alloy base band is obtained, its concrete technology condition is：Heating-up temperature is 1250 DEG C, and heating rate is 900 DEG C/min,
Soaking time is 50min, and protective atmosphere is pure hydrogen.The nickel-base alloy base band surface（200）Face pole figure is as shown in Fig. 2, by scheming
Understand that the nickel-base alloy base band surface obtains strong cubic texture.
Basic principle, main features and advantages embodiment above describes the present invention, the technical staff of the industry should
Understand, the present invention is not limited to the above embodiments, and the above embodiments and description only describe the original of the present invention
Reason, under the scope for not departing from the principle of the invention, various changes and modifications of the present invention are possible, these changes and improvements are each fallen within
In the scope of protection of the invention.
Claims (1)
1. a kind of preparation method of high-performance cubic texture nickel-base alloy base band, it is characterised in that concretely comprise the following steps：
The preparation of step 1, initial ni-w-p alloy billet
According to the atomic percentage content of tungsten and phosphorus it is respectively 9.5% and by nickel block, tungsten block and phosphorus block that purity is 99.999%
0.05%-0.1% is matched, and the mixing material after proportioning is placed in melting in electromagnetic induction vacuum melting furnace obtains the conjunction of nickel tungsten phosphorus
Golden ingot casting, then ni-w-p alloy ingot casting removed keep the temperature 1h at 1800 DEG C after the oxide skin on surface after forged and hot rolling obtains
Initial ni-w-p alloy billet before cold rolling；
The cold rolling of step 2, initial ni-w-p alloy billet
Cold rolling is carried out after the oxide skin on initial ni-w-p alloy billet surface is removed and obtains ni-w-p alloy cold rolling base band, it is total to become
Shape amount is 98.2%, and pass deformation is 2%-10%；
The primary recrystallization annealing of step 3, ni-w-p alloy cold rolling base band
Ni-w-p alloy cold rolling base band is subjected to primary recrystallization annealing and obtains ni-w-p alloy base band, its concrete technology condition
For：Heating-up temperature is 650-800 DEG C, and heating rate is 900 DEG C/min, and soaking time 15min, protective atmosphere is pure hydrogen；
The high temperature re-crystallization annealing of step 4, ni-w-p alloy base band
Ni-w-p alloy base band is subjected to high temperature re-crystallization annealing and obtains final products high-performance cubic texture nickel-base alloy base band,
Its concrete technology condition is：Heating-up temperature is 1200-1250 DEG C, and heating rate is 900 DEG C/min, soaking time 50min, is protected
Shield atmosphere is pure hydrogen.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610787450.9A CN106399756B (en) | 2016-08-31 | 2016-08-31 | A kind of preparation method of high-performance cubic texture nickel-base alloy base band |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610787450.9A CN106399756B (en) | 2016-08-31 | 2016-08-31 | A kind of preparation method of high-performance cubic texture nickel-base alloy base band |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN106399756A CN106399756A (en) | 2017-02-15 |
| CN106399756B true CN106399756B (en) | 2018-05-08 |
Family
ID=58001170
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201610787450.9A Expired - Fee Related CN106399756B (en) | 2016-08-31 | 2016-08-31 | A kind of preparation method of high-performance cubic texture nickel-base alloy base band |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN106399756B (en) |
Families Citing this family (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106702216B (en) * | 2017-02-28 | 2018-07-17 | 安阳师范学院 | A kind of preparation method of iron-free magnetic cubic texture nickel-tungsten alloy base-band |
| CN109371286A (en) * | 2018-12-17 | 2019-02-22 | 河南师范大学 | A kind of iron-free magnetic cubic texture Ni base alloy baseband and preparation method thereof |
| CN109355519B (en) * | 2018-12-17 | 2020-06-12 | 河南师范大学 | Preparation method for improving strength of non-ferromagnetic cubic texture copper-based alloy baseband |
| CN110938757B (en) * | 2018-12-27 | 2021-05-07 | 河南城建学院 | Preparation method of ultrahigh-strength texture nickel-based alloy baseband |
| CN110951995B (en) * | 2019-12-25 | 2021-03-19 | 河南工学院 | Preparation method of high-strength nickel-based alloy baseband |
| CN111822900A (en) * | 2020-07-24 | 2020-10-27 | 曹怡 | Nickel-based alloy, preparation method thereof and welding strip |
Citations (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1740357A (en) * | 2005-09-23 | 2006-03-01 | 北京工业大学 | Prepn process of high temperature superconductive Ni-W alloy |
| CN1844429A (en) * | 2006-05-19 | 2006-10-11 | 北京工业大学 | Ni-base alloy composite baseband and its smelting preparation method |
| CN101249607A (en) * | 2008-04-07 | 2008-08-27 | 北京工业大学 | Preparation of coating superconductivity high W content Ni-W alloy baseband |
| CN101635186A (en) * | 2009-08-28 | 2010-01-27 | 北京工业大学 | Method for Ni-W alloy base band with non-magnetic cubic texture |
| CN101635185A (en) * | 2009-08-28 | 2010-01-27 | 北京工业大学 | Method for preparing Ni-W alloy base band with non/low magnetic cubic texture |
| US7879161B2 (en) * | 2007-08-08 | 2011-02-01 | Ut-Battelle, Llc | Strong, non-magnetic, cube textured alloy substrates |
| JP4800740B2 (en) * | 2005-10-21 | 2011-10-26 | 財団法人国際超電導産業技術研究センター | Rare earth tape-shaped oxide superconductor and method for producing the same |
| JP5323444B2 (en) * | 2007-10-18 | 2013-10-23 | 古河電気工業株式会社 | Composite substrate for oxide superconducting wire, manufacturing method thereof, and superconducting wire |
| CN103938031A (en) * | 2014-05-05 | 2014-07-23 | 河南师范大学 | Preparation method of non-magnetic high-strength texture Ni-W alloy baseband |
| CN104894415A (en) * | 2015-06-03 | 2015-09-09 | 河南师范大学 | Preparation method of ferromagnetism-free high-strength strong-cube-texture Ni-W-Al ternary alloy base band |
-
2016
- 2016-08-31 CN CN201610787450.9A patent/CN106399756B/en not_active Expired - Fee Related
Patent Citations (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1740357A (en) * | 2005-09-23 | 2006-03-01 | 北京工业大学 | Prepn process of high temperature superconductive Ni-W alloy |
| JP4800740B2 (en) * | 2005-10-21 | 2011-10-26 | 財団法人国際超電導産業技術研究センター | Rare earth tape-shaped oxide superconductor and method for producing the same |
| CN1844429A (en) * | 2006-05-19 | 2006-10-11 | 北京工业大学 | Ni-base alloy composite baseband and its smelting preparation method |
| US7879161B2 (en) * | 2007-08-08 | 2011-02-01 | Ut-Battelle, Llc | Strong, non-magnetic, cube textured alloy substrates |
| JP5323444B2 (en) * | 2007-10-18 | 2013-10-23 | 古河電気工業株式会社 | Composite substrate for oxide superconducting wire, manufacturing method thereof, and superconducting wire |
| CN101249607A (en) * | 2008-04-07 | 2008-08-27 | 北京工业大学 | Preparation of coating superconductivity high W content Ni-W alloy baseband |
| CN101635186A (en) * | 2009-08-28 | 2010-01-27 | 北京工业大学 | Method for Ni-W alloy base band with non-magnetic cubic texture |
| CN101635185A (en) * | 2009-08-28 | 2010-01-27 | 北京工业大学 | Method for preparing Ni-W alloy base band with non/low magnetic cubic texture |
| CN103938031A (en) * | 2014-05-05 | 2014-07-23 | 河南师范大学 | Preparation method of non-magnetic high-strength texture Ni-W alloy baseband |
| CN104894415A (en) * | 2015-06-03 | 2015-09-09 | 河南师范大学 | Preparation method of ferromagnetism-free high-strength strong-cube-texture Ni-W-Al ternary alloy base band |
Non-Patent Citations (3)
| Title |
|---|
| A.Tuissi等.Biaxially textured NiCrX (X ¼W and V) tapes as substrates for HTS coated conductor applications.《physica c》.2002,759-762. * |
| Cube-textured nickel and Ni alloy substrates for YBCO coated conductors;R.Nast;《physica c》;20021231;733-737 * |
| D. P. Rodionov等.Textured Ni–Cr–W Alloy Substrates with Curie Temperatures below 77 K for High Temperature Superconductors of Second Generation.《TECHNICAL PHYSICS LETTERS》.2010,393-396. * |
Also Published As
| Publication number | Publication date |
|---|---|
| CN106399756A (en) | 2017-02-15 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN106399756B (en) | A kind of preparation method of high-performance cubic texture nickel-base alloy base band | |
| CN102500638B (en) | Method for producing high-cube-texture high-tungsten-content NI (nickel)-W (tungsten) alloy substrate bands | |
| CN102756512B (en) | Low-magnetism or magnetism-free and high-strength Ni-W alloy composite base band and preparation method thereof | |
| CN103938031B (en) | A kind of preparation method of nonmagnetic, strength texture Ni-W alloy base band | |
| CN101635185B (en) | Method for preparing Ni-W alloy base band with non/low magnetic cubic texture | |
| CN106381418B (en) | A kind of preparation method of strong cubic texture Ni 10at.%W alloy base bands | |
| CN103952592B (en) | The preparation method of nonmagnetic conductor of high-temperature superconductor coat cubic texture nickel-base alloy base band | |
| CN111996397A (en) | Method for regulating hydrogen embrittlement resistance and corrosion resistance of CoNiV medium-entropy alloy | |
| CN107267901B (en) | A kind of preparation method of the high intensity without ferromagnetism texture Ni-W alloy base bands | |
| CN103236321A (en) | Method for preparing strong-cube-texture low-magnetism compound Ni-W alloy base bands | |
| CN103924108B (en) | A kind of nonmagnetic strong cubic texture copper base alloy composite baseband and preparation method thereof | |
| CN103421985A (en) | Preparing method of nonmagnetic high-strength textured Cu-base ternary alloy base band | |
| CN109371286A (en) | A kind of iron-free magnetic cubic texture Ni base alloy baseband and preparation method thereof | |
| CN110951995B (en) | Preparation method of high-strength nickel-based alloy baseband | |
| CN106077642B (en) | A kind of method of alloy nano-powder prepares coating conductor high-tungsten alloy base band billet | |
| CN106702216B (en) | A kind of preparation method of iron-free magnetic cubic texture nickel-tungsten alloy base-band | |
| CN104711475A (en) | Fe-Ga-Al alloy strip with high magnetostrictive properties and preparation method thereof | |
| CN109338161B (en) | Cubic texture nickel alloy base band and preparation method thereof | |
| CN107267900A (en) | A kind of preparation method of high intensity without ferromagnetism texture acid bronze alloy base band | |
| CN109930099B (en) | Preparation method of high-strength strong-cube-texture Cu-Fe-Zr-P alloy baseband | |
| CN109355519B (en) | Preparation method for improving strength of non-ferromagnetic cubic texture copper-based alloy baseband | |
| CN104894415A (en) | Preparation method of ferromagnetism-free high-strength strong-cube-texture Ni-W-Al ternary alloy base band | |
| CN108300895B (en) | Method for manufacturing nonmagnetic cube texture Cu-Ni-Cr alloy baseband for high-temperature superconducting coated conductor | |
| CN111074094A (en) | Preparation method of high-strength cube-texture copper-based alloy baseband | |
| CN102154578A (en) | Nonmagnetic texture NiV (nickel vanadium) alloy base band and smelting preparation method thereof |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| GR01 | Patent grant | ||
| GR01 | Patent grant | ||
| CF01 | Termination of patent right due to non-payment of annual fee | ||
| CF01 | Termination of patent right due to non-payment of annual fee |
Granted publication date: 20180508 Termination date: 20200831 |