CN106398834A - Oil-soluble compound screw-type air compressor oil - Google Patents
Oil-soluble compound screw-type air compressor oil Download PDFInfo
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- CN106398834A CN106398834A CN201610788735.4A CN201610788735A CN106398834A CN 106398834 A CN106398834 A CN 106398834A CN 201610788735 A CN201610788735 A CN 201610788735A CN 106398834 A CN106398834 A CN 106398834A
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- C—CHEMISTRY; METALLURGY
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- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M169/00—Lubricating compositions characterised by containing as components a mixture of at least two types of ingredient selected from base-materials, thickeners or additives, covered by the preceding groups, each of these compounds being essential
- C10M169/04—Mixtures of base-materials and additives
- C10M169/048—Mixtures of base-materials and additives the additives being a mixture of compounds of unknown or incompletely defined constitution, non-macromolecular and macromolecular compounds
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- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
- C10M2207/02—Hydroxy compounds
- C10M2207/023—Hydroxy compounds having hydroxy groups bound to carbon atoms of six-membered aromatic rings
- C10M2207/026—Hydroxy compounds having hydroxy groups bound to carbon atoms of six-membered aromatic rings with tertiary alkyl groups
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- C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
- C10M2207/28—Esters
- C10M2207/283—Esters of polyhydroxy compounds
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- C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
- C10M2207/40—Fatty vegetable or animal oils
- C10M2207/401—Fatty vegetable or animal oils used as base material
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- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2209/00—Organic macromolecular compounds containing oxygen as ingredients in lubricant compositions
- C10M2209/02—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
- C10M2209/08—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds containing monomers having an unsaturated radical bound to a carboxyl radical, e.g. acrylate type
- C10M2209/084—Acrylate; Methacrylate
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- C10M2209/00—Organic macromolecular compounds containing oxygen as ingredients in lubricant compositions
- C10M2209/10—Macromolecular compoundss obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- C10M2209/102—Polyesters
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- C10M2209/00—Organic macromolecular compounds containing oxygen as ingredients in lubricant compositions
- C10M2209/10—Macromolecular compoundss obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- C10M2209/103—Polyethers, i.e. containing di- or higher polyoxyalkylene groups
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- C10M2209/00—Organic macromolecular compounds containing oxygen as ingredients in lubricant compositions
- C10M2209/10—Macromolecular compoundss obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- C10M2209/103—Polyethers, i.e. containing di- or higher polyoxyalkylene groups
- C10M2209/107—Polyethers, i.e. containing di- or higher polyoxyalkylene groups of two or more specified different alkylene oxides covered by groups C10M2209/104 - C10M2209/106
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- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2215/00—Organic non-macromolecular compounds containing nitrogen as ingredients in lubricant compositions
- C10M2215/02—Amines, e.g. polyalkylene polyamines; Quaternary amines
- C10M2215/06—Amines, e.g. polyalkylene polyamines; Quaternary amines having amino groups bound to carbon atoms of six-membered aromatic rings
- C10M2215/064—Di- and triaryl amines
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- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2219/00—Organic non-macromolecular compounds containing sulfur, selenium or tellurium as ingredients in lubricant compositions
- C10M2219/04—Organic non-macromolecular compounds containing sulfur, selenium or tellurium as ingredients in lubricant compositions containing sulfur-to-oxygen bonds, i.e. sulfones, sulfoxides
- C10M2219/044—Sulfonic acids, Derivatives thereof, e.g. neutral salts
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- C10M2219/00—Organic non-macromolecular compounds containing sulfur, selenium or tellurium as ingredients in lubricant compositions
- C10M2219/08—Thiols; Sulfides; Polysulfides; Mercaptals
- C10M2219/082—Thiols; Sulfides; Polysulfides; Mercaptals containing sulfur atoms bound to acyclic or cycloaliphatic carbon atoms
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- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2223/00—Organic non-macromolecular compounds containing phosphorus as ingredients in lubricant compositions
- C10M2223/02—Organic non-macromolecular compounds containing phosphorus as ingredients in lubricant compositions having no phosphorus-to-carbon bonds
- C10M2223/04—Phosphate esters
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- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2223/00—Organic non-macromolecular compounds containing phosphorus as ingredients in lubricant compositions
- C10M2223/02—Organic non-macromolecular compounds containing phosphorus as ingredients in lubricant compositions having no phosphorus-to-carbon bonds
- C10M2223/04—Phosphate esters
- C10M2223/047—Thioderivatives not containing metallic elements
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- C—CHEMISTRY; METALLURGY
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- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2227/00—Organic non-macromolecular compounds containing atoms of elements not provided for in groups C10M2203/00, C10M2207/00, C10M2211/00, C10M2215/00, C10M2219/00 or C10M2223/00 as ingredients in lubricant compositions
- C10M2227/06—Organic compounds derived from inorganic acids or metal salts
- C10M2227/061—Esters derived from boron
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2229/00—Organic macromolecular compounds containing atoms of elements not provided for in groups C10M2205/00, C10M2209/00, C10M2213/00, C10M2217/00, C10M2221/00 or C10M2225/00 as ingredients in lubricant compositions
- C10M2229/04—Siloxanes with specific structure
- C10M2229/041—Siloxanes with specific structure containing aliphatic substituents
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- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2030/00—Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
- C10N2030/02—Pour-point; Viscosity index
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- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2030/00—Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
- C10N2030/10—Inhibition of oxidation, e.g. anti-oxidants
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- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2030/00—Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
- C10N2030/12—Inhibition of corrosion, e.g. anti-rust agents or anti-corrosives
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- C10N2030/00—Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
- C10N2030/18—Anti-foaming property
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- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2030/00—Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
- C10N2030/64—Environmental friendly compositions
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- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Organic Chemistry (AREA)
- Lubricants (AREA)
Abstract
The invention discloses oil-soluble compound screw-type air compressor oil. The oil-soluble compound screw-type air compressor oil comprises, by mass, 16-25 parts of synthetic base oil A, 30-39 parts oil-soluble polyalkylene glycol, 0.1-1.4 parts of alkylated diphenylamine, 0.8-2 parts of 2, 6-di-tert-butyl mixed phenol, 0.8-2 parts of a borate antioxidant, 1.2-2.2 parts of a high temperature ashless antiwear agent, 0.5-1.8 parts of sorbitan fatty acid ester, 0.001-0.05 parts of an acrylate-ether copolymer, 10-12 parts of tributyl phosphate, 1.2-2.2 parts of alkyl phosphorothioate, 0.005-0.05 parts of a methyl siloxane mixture or liquid ester copolymer, 3-7 parts of a metal salt of dialkyl naphthalene sulfonic acid and 20-22 parts of a vulcanized isobutene fatty acid salt. The compatibility of the materials of the compressor oil is excellent. The oil-soluble compound screw-type air compressor oil has excellent anti-oxidation stability, anti-emulsifying properties, corrosion resistance, excellent defoaming properties and excellent viscosity-temperature performances. Performance indicators of the oil-soluble compound screw-type air compressor oil satisfy 46# compressor oil standards. The oil-soluble compound screw-type air compressor oil can be used for equipment in an air compression system.
Description
Technical field
The invention belongs to technical field of lubricating oil is and in particular to one kind can oil-soluble complex screw formula air compressor oil.
Background technology
Air compressor oil is mainly used in the lubrication of compressor cylinder moving component and air bleeding valve, and rises antirust, anti-corrosion, close
Envelope and cooling effect.Because compressor is constantly in high pressure, high temperature and the environment with the presence of condensed water (to air compressor machine), therefore
Compressor oil should have excellent high-temperature oxidation stability, low tendency to soot, suitable viscosity and viscosity temperature characteristic and good
Oil-water separativeness, resistance to rust and corrosion etc..The too low lubricating oil of viscosity is difficult to be formed sufficiently strong oil film, meeting accelerated wear test, contracting
The service life of short parts.Conversely, lubricating oil viscosity is too high, internal friction can be increased, so that the specific power of compressor is increased, so that
Increase power consumption and oil consumption, also easily in piston ring groove, form deposit on air valve, in exhaust passage etc..Compressor oil is in fortune
It is also easy to produce emulsion in row, causes Oil-gas Separation unclear, oil consumption increases, simultaneously oily emulsified and make oil film breakdown, can cause
Abrasion increases.
Base oil is undoubtedly the deciding factor of compressor oil lubricant effect, the especially base oil of Biodegradation Lubricating Oil
Need to meet following standard:There is good dispersing and dissolving performance to additive, good cryogenic property, sufficient biodegradation
Property, good greasy property, high-flash.Base oil for environmental friendly lubricant mainly has vegetable oil, synthetic ester, epoxidation
Thing polymer, polyethers or isohydrocarbon etc..
Polyethers is that the monomers such as oxirane, expoxy propane, epoxy butane and oxolane occur open loop homopolymerization or copolymerization life
The linear compound becoming.The performance of polyethers is closely related with its molecular structure, molecular backbone alkylene oxide type, ratio, end
The type of base is all affected with distribution to some extent with the size of concentration, the hydrocarbon chain structure of initiator and length and pfpe molecule
The performances such as their viscosity, viscosity index (VI), pour point, dissolubility and heat stability.In general, polyethers and mineral oil, synthesis hydrocarbon
Immiscible.
Content of the invention
The technical problem to be solved is:Offer is a kind of to be had excellent anti-oxidative stability, resistance to emulsion, resists
Rotten rust-preventing characteristic, fabulous defoaming and excellent viscosity temperature characteristic, can with mineral oil and mix can oil-soluble complex screw formula empty
Air compressor oil.
For solving above-mentioned technical problem, the technical scheme that the present invention provides is:A kind of oil-soluble complex screw formula air pressure
Contracting machine oil, according to the mass fraction, including raw material:
Described synthetic base oil A:According to the mass fraction, plant Oleum Brassicae campestriss 80-90 part and isopropanol 16-18 part,
NaOH1.2-1.9 part, at 60-68 DEG C, is reacted 3-4 hour, is obtained vegetable oil acid isopropyl alcohol ester;Vegetable oil acid isopropyl alcohol ester again with 2-3
Part Et2Al2Cl3, 35~40 parts of isopropanol chloro-formates 55-60 DEG C, friedel-craft reaction 5-5.5 hour obtain base oil A;
(Polyalkyleneglycols (PAG), its essential building blocks is by oxirane for described poly alkylene glycol
(EO), expoxy propane (PO), epoxy butane (BO) or oxolane (THF) composition.
The dynamic viscosity when 40 DEG C for the described oil-soluble poly alkylene glycol is 100000~150000mm2/s.
A kind of described oil-soluble complex screw formula air compressor oil is it is characterised in that it is preferred according to the mass fraction
Consist of:
A kind of described oil-soluble complex screw formula air compressor oil is according to general preparation method system in industry
Standby obtain.
Beneficial effect:Using amine and phenolic compound as antioxidant, high temperature ash-free antiwear agent is as antiwear additive, Pyrusussuriensiss
, as antirust agent, the copolymer of acrylate and ether is as anti-foaming agent for sugar alcohol fatty acid fat.The oil-soluble complex screw being obtained
Formula air compressor oil environmental friendliness, in this compressor oil, between each component, the compatibility is good, has excellent antioxidation peace
The advantages of qualitative, resistance to emulsion, anti-corruption rust-preventing characteristic, fabulous defoaming and excellent viscosity temperature characteristic, is so as to performance indications reach
No. 46 compressor oil standards, for air compression system plant equipment etc..
Specific embodiment
Embodiment 1
Described synthetic base oil A:According to the mass fraction, plant Oleum Brassicae campestriss 80-90 part and isopropanol 16-18 part,
NaOH1.2-1.9 part, at 60-68 DEG C, is reacted 3-4 hour, is obtained vegetable oil acid isopropyl alcohol ester;Vegetable oil acid isopropyl alcohol ester again with 2-3
Part Et2Al2Cl3, 35~40 parts of isopropanol chloro-formates 55-60 DEG C, friedel-craft reaction 5-5.5 hour obtain base oil A;
The dynamic viscosity when 40 DEG C for the described oil-soluble poly alkylene glycol is 100000~140000mm2/s.
Embodiment 2
Embodiment 3
The air compressor oil that this method is prepared from, after tested result be listed in the table below.
Upper table data is learnt:This compressor oil has excellent viscosity temperature characteristic, Oxidation Stability, high temperature performance.Table
Bright vegetable oil is modified process and can be used as high perofmrnace lubricating oils base oil, is mixed with appropriate oil-soluble poly alkylene glycol
After becoming combination base oil, with environmental friendly additives mixing preparation, it is obtained in that high-quality environmental protection air compressor oil.
Claims (3)
1. a kind of oil-soluble complex screw formula air compressor oil, according to the mass fraction, including raw material:
Described synthetic base oil A:According to the mass fraction, plant Oleum Brassicae campestriss 80-90 part and isopropanol 16-18 part, NaOH1.2-
1.9 parts, at 60-68 DEG C, are reacted 3-4 hour, obtain vegetable oil acid isopropyl alcohol ester;Vegetable oil acid isopropyl alcohol ester again with 2-3 part
Et2Al2Cl3, 35~40 parts of isopropanol chloro-formates 55-60 DEG C, friedel-craft reaction 5-5.5 hour obtain base oil A;
Described poly alkylene glycol, its essential building blocks is by oxirane, expoxy propane, epoxy butane or oxolane group
Become.
2. a kind of oil-soluble complex screw formula air compressor oil according to claim 1 it is characterised in that:Described oil
The dynamic viscosity when 40 DEG C for the soluble polyalkylene glycol is 100000~150000mm2/s.
3. a kind of oil-soluble complex screw formula air compressor oil described in claim 1 is it is characterised in that according to the mass fraction
Consisting of:
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Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN107474895A (en) * | 2017-07-31 | 2017-12-15 | 广东美芝制冷设备有限公司 | Refrigerator oil antioxygen composition and refrigerating machine oil composition and their application |
CN116554945A (en) * | 2023-04-28 | 2023-08-08 | 孚牌(宁波)油品技术有限公司 | Composite additive for screw compressor oil and preparation method thereof |
Citations (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN103773575A (en) * | 2013-12-30 | 2014-05-07 | 张家港市胜宇石油化工制品有限公司 | Biodegradable screw air compressor oil |
CN105296107A (en) * | 2015-10-28 | 2016-02-03 | 张家港市胜宇石油化工制品有限公司 | Composite screw type air compressor oil |
-
2016
- 2016-08-31 CN CN201610788735.4A patent/CN106398834A/en active Pending
Patent Citations (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN103773575A (en) * | 2013-12-30 | 2014-05-07 | 张家港市胜宇石油化工制品有限公司 | Biodegradable screw air compressor oil |
CN105296107A (en) * | 2015-10-28 | 2016-02-03 | 张家港市胜宇石油化工制品有限公司 | Composite screw type air compressor oil |
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN107474895A (en) * | 2017-07-31 | 2017-12-15 | 广东美芝制冷设备有限公司 | Refrigerator oil antioxygen composition and refrigerating machine oil composition and their application |
CN116554945A (en) * | 2023-04-28 | 2023-08-08 | 孚牌(宁波)油品技术有限公司 | Composite additive for screw compressor oil and preparation method thereof |
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