CN106398425A - Fireproof paint and preparation method thereof - Google Patents

Fireproof paint and preparation method thereof Download PDF

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Publication number
CN106398425A
CN106398425A CN201610818792.2A CN201610818792A CN106398425A CN 106398425 A CN106398425 A CN 106398425A CN 201610818792 A CN201610818792 A CN 201610818792A CN 106398425 A CN106398425 A CN 106398425A
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CN
China
Prior art keywords
parts
melamine
resistant coating
fire resistant
fireproof paint
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Pending
Application number
CN201610818792.2A
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Chinese (zh)
Inventor
黄钰雯
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Guangxi University
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Guangxi University
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Priority to CN201610818792.2A priority Critical patent/CN106398425A/en
Publication of CN106398425A publication Critical patent/CN106398425A/en
Pending legal-status Critical Current

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    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D133/00Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Coating compositions based on derivatives of such polymers
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D5/00Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
    • C09D5/18Fireproof paints including high temperature resistant paints
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40Additives
    • C09D7/60Additives non-macromolecular
    • C09D7/61Additives non-macromolecular inorganic
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40Additives
    • C09D7/60Additives non-macromolecular
    • C09D7/63Additives non-macromolecular organic
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40Additives
    • C09D7/70Additives characterised by shape, e.g. fibres, flakes or microspheres
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K2201/00Specific properties of additives
    • C08K2201/014Additives containing two or more different additives of the same subgroup in C08K
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2201/00Properties
    • C08L2201/02Flame or fire retardant/resistant
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2201/00Properties
    • C08L2201/10Transparent films; Clear coatings; Transparent materials
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00Polymer mixtures characterised by other features
    • C08L2205/02Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
    • C08L2205/025Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group containing two or more polymers of the same hierarchy C08L, and differing only in parameters such as density, comonomer content, molecular weight, structure
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00Polymer mixtures characterised by other features
    • C08L2205/03Polymer mixtures characterised by other features containing three or more polymers in a blend

Abstract

The invention provides fireproof paint. Raw materials comprise the following components in parts: 26 to 47 parts of acrylic emulsion, 11 to 23 parts of dipentaerythritol, 6 to 18 parts of expanded graphite, 5 to 17 parts of melamine, 2 to 11 parts of ammonium polyphosphate, 3 to 12 parts of aluminum hydroxide, 3 to 6 parts of zinc oxide, 2 to 5 parts of silicon dioxide, 4 to 11 parts of carbon fiber, 5 to 11 parts of silicon nitride fiber, 21 to 33 parts of water, 11 to 16 parts of hydroxy acrylic resin, 12 to 16 parts of polyurethane resin, 5 to 9 parts of urea, 6 to 9 parts of pentaerythritol, 6 to 11 parts of melamine phosphate, 11 to 13 parts of white carbon black, 6 to 9 parts of sodium silicate, 3 to 5 parts of titanium pigment, 2 to 3 parts of dioctyl phthalate and 2 to 4 parts of dithiocarbamate. The fireproof paint is prepared from the raw materials which are nontoxic or are lower in toxicity, and cannot cause harm to a human body, particularly to a constructor in a normal construction process; further, the made fireproof paint is transparent. The fireproof paint is of an aqueous ultrathin type; when a fire hazard happens, no toxic gas is released; the fireproof paint can be widely applied to various steel structural buildings.

Description

A kind of fire resistant coating and preparation method thereof
Technical field
The present invention relates to building material field, more particularly, to a kind of fire resistant coating and preparation method thereof.
Background technology
Fire resistant coating is a kind of anti-flaming dope being fabricated by by multiple materials such as film forming agent, fire retardant, foaming agents;Due to mesh The combustible material such as timber, cloth is used in a large number in front household, so, fire prevention has been a subject under discussion being worth lifting.Existing Fire resistant coating can be divided into facing fire resistant coating, fire retarding wood protection paint, three kinds of steel structure fireproofing paint.Facing type fireproofing paint is a kind of collection decoration The new paint kind being integrated with fire prevention, when it is coated on flammable base material, can play certain decoration function at ordinary times;Once When fire occurs, then there is prevention fire spreading, thus reaching the purpose protecting flammable base material.Apply more in facing fire resistant coating , effect is preferably expansion fire-proof paint.
Steel construction as a kind of form of high building structure, so that its intensity is high, light weight, and have good extensibility, The features such as shock resistance and short construction period, show powerful vitality at the aspect such as Super High and long span building, in building Increasingly it is widely applied in industry.But the more traditional masonry structure of the fire resistance of steel building and armored concrete knot Structure is poor, and the mechanical strength of steel declines rapidly with the rising of temperature, loses enabling capabilities quickly, leads to building to collapse, therefore, It is imperative steel construction to be carried out protect.Brush in steel structure surface or sprayed fire proofing paint (or fireproof coating) is commonly used at present One of preventive means.
Steel structure fireproofing paint is broadly divided into thick coated type and scumbling type, and thick coated type steel structure fire resistant coating is typically using suitably viscous Knot agent, then be equipped with inorganic lightweight material, reinforcing material is made, because it is all inorganic matter from base-material to most of additives, because This is with low cost, but this kind of coating high temperature easily ftractures, and bonding strength is low.Scumbling formed steel construction fire resistant coating is mainly by polymer Base-material, then it is equipped with the composition such as fire retardant, additive, foamed by expansion during fire, with expanded foamed formed refractory insulating layer Delay the intensification of steel, protect steel beam column.Scumbling formed steel construction fire resistant coating can be divided into solvent-borne type and aqueous two classes, and solvent-borne type is prevented fires Because using a large amount of organic solvents during production and construction, there is certain harm, water-based fireproof to environment and workmen in paint Paint has environmental protection feature, meets the developing direction of low stain, Environmentally friendly coatings, but the research in China is started late, Also has certain gap with solvent-borne type fire resistant coating on physicochemical property and weatherability.
Content of the invention
For above-mentioned problems of the prior art, it is an object of the invention to provide a kind of fire resistant coating and its preparation side Method.
A kind of fire resistant coating, raw material form according to following portion rate:
Acrylic emulsion 26-47 part, bipentaerythrite 11-23 part, expanded graphite 6-18 part, melamine 5-17 part, polyphosphoric acid Ammonium 2-11 part, aluminium hydroxide 3-12 part, zinc oxide 3-6 part, silica 2-5 part, carbon fiber 4-11 part, silicon nitride fiber 5-11 Part, water 21-33 part, Hydroxylated acrylic resin 11-16 part, polyurethane resin 12-16 part, urea 5-9 part, pentaerythrite 6-9 part, Melamine phosphate 6-11 part, white carbon 11-13 part, sodium metasilicate 6-9 part, titanium dioxide 3-5 part, dioctyl phthalate 2- 3 parts, dithiocarbamate 2-4 part.
Further illustrate, described kind fire resistant coating, raw material form according to following portion rate:
27 parts of acrylic emulsion, 13 parts of bipentaerythrite, 12 parts of expanded graphite, 15 parts of melamine, 9 parts of APP, hydrogen-oxygen Change 8 parts of aluminium, 4 parts of zinc oxide, 3 parts of silica, 8 parts of carbon fiber, 7 parts of silicon nitride fiber, 23 parts of water, Hydroxylated acrylic resin 13 Part, 14 parts of polyurethane resin, 8 parts of urea, 7 parts of pentaerythrite, 10 parts of melamine phosphate, 12 parts of white carbon, sodium metasilicate 8 Part, 4 parts of titanium dioxide, 2 parts of dioctyl phthalate, 3 parts of dithiocarbamate.
Further illustrate, the preparation method of described kind fire resistant coating, comprise the steps:
(1) bipentaerythrite, expanded graphite, melamine, APP, aluminium hydroxide, zinc oxide, silica and water are existed Put into after mixing in stirred tank and in ball mill, grind 1-2 hour, drum's speed of rotation is 1500-2000r/min;
(2) and then it is slowly added to acrylic emulsion into ball mill, continues to grind 0.5-1 hour, filter, obtaining fineness is 90- The slurry of 110 mesh, slurry is inserted stirring at low speed in stirred tank and is simultaneously introduced carbon fiber, silicon nitride fiber, hydroxy acrylic acid tree Fat, polyurethane resin, urea, pentaerythrite, melamine phosphate, white carbon, sodium metasilicate, titanium dioxide, phthalic acid two Monooctyl ester, dithiocarbamate, stir, and obtain final product fire resistant coating.
Beneficial effects of the present invention are as follows:
The present invention adopts raw material composition nontoxic or that toxicity is relatively low, will not be to human body, and especially workmen constructs normal During do not result in harm, and the fire resistant coating made is transparent.This fire resistant coating is water super-thin, occurs no there is poison gas during fire Body discharges, and can be widely applied to various steel buildings.
Specific embodiment
Below in conjunction with the embodiment of the present invention, the technical scheme in the embodiment of the present invention is clearly and completely described, Obviously, described embodiment is only a part of embodiment of the present invention, rather than whole embodiments.Based on the reality in the present invention Apply example, the every other embodiment that field those of ordinary skill is obtained under the premise of not making creative work, broadly fall into The scope of protection of the invention.
Embodiment 1
A kind of fire resistant coating, raw material form according to following portion rate:
26 parts of acrylic emulsion, 11 parts of bipentaerythrite, 6 parts of expanded graphite, 5 parts of melamine, 2 parts of APP, hydroxide 3 parts of aluminium, 3 parts of zinc oxide, 2 parts of silica, 4 parts of carbon fiber, 5 parts of silicon nitride fiber, 21 parts of water, Hydroxylated acrylic resin 11 Part, 12 parts of polyurethane resin, 5 parts of urea, 6 parts of pentaerythrite, 6 parts of melamine phosphate, 11 parts of white carbon, 6 parts of sodium metasilicate, 3 parts of titanium dioxide, 2 parts of dioctyl phthalate, 2 parts of dithiocarbamate.
The preparation method of described kind fire resistant coating, comprises the steps:
(1) bipentaerythrite, expanded graphite, melamine, APP, aluminium hydroxide, zinc oxide, silica and water are existed Put into after mixing in stirred tank in ball mill and grind 1 hour, drum's speed of rotation is 1500r/min;
(2) and then it is slowly added to acrylic emulsion into ball mill, continues to grind 0.5 hour, filter, obtaining fineness is 90 purposes Slurry, slurry is inserted stirring at low speed in stirred tank and is simultaneously introduced carbon fiber, silicon nitride fiber, Hydroxylated acrylic resin, poly- ammonia Ester resin, urea, pentaerythrite, melamine phosphate, white carbon, sodium metasilicate, titanium dioxide, dioctyl phthalate, two Thiocarbamate, stirs, and obtains final product fire resistant coating.
Embodiment 2
A kind of fire resistant coating, raw material form according to following portion rate:
47 parts of acrylic emulsion, 23 parts of bipentaerythrite, 18 parts of expanded graphite, 17 parts of melamine, 11 parts of APP, hydrogen-oxygen Change 12 parts of aluminium, 6 parts of zinc oxide, 5 parts of silica, 11 parts of carbon fiber, 11 parts of silicon nitride fiber, 33 parts of water, hydroxy acrylic acid tree 16 parts of fat, 16 parts of polyurethane resin, 9 parts of urea, 9 parts of pentaerythrite, 11 parts of melamine phosphate, 13 parts of white carbon, silicic acid 9 parts of sodium, 5 parts of titanium dioxide, 3 parts of dioctyl phthalate, 4 parts of dithiocarbamate.
The preparation method of described kind fire resistant coating, comprises the steps:
(1) bipentaerythrite, expanded graphite, melamine, APP, aluminium hydroxide, zinc oxide, silica and water are existed Put into after mixing in stirred tank in ball mill and grind 2 hours, drum's speed of rotation is 2000r/min;
(2) and then it is slowly added to acrylic emulsion into ball mill, continues to grind 1 hour, filter, obtaining fineness is 110 purposes Slurry, slurry is inserted stirring at low speed in stirred tank and is simultaneously introduced carbon fiber, silicon nitride fiber, Hydroxylated acrylic resin, poly- ammonia Ester resin, urea, pentaerythrite, melamine phosphate, white carbon, sodium metasilicate, titanium dioxide, dioctyl phthalate, two Thiocarbamate, stirs, and obtains final product fire resistant coating.
Above-described embodiment is the present invention preferably embodiment, but embodiments of the present invention are not subject to above-described embodiment Limit, other any Spirit Essences without departing from the present invention and the change made under principle, modification, replacement, combine, simplify, All should be equivalent substitute mode, be included within protection scope of the present invention.

Claims (3)

1. a kind of fire resistant coating is it is characterised in that raw material form according to following portion rate:
Acrylic emulsion 26-47 part, bipentaerythrite 11-23 part, expanded graphite 6-18 part, melamine 5-17 part, polyphosphoric acid Ammonium 2-11 part, aluminium hydroxide 3-12 part, zinc oxide 3-6 part, silica 2-5 part, carbon fiber 4-11 part, silicon nitride fiber 5-11 Part, water 21-33 part, Hydroxylated acrylic resin 11-16 part, polyurethane resin 12-16 part, urea 5-9 part, pentaerythrite 6-9 part, Melamine phosphate 6-11 part, white carbon 11-13 part, sodium metasilicate 6-9 part, titanium dioxide 3-5 part, dioctyl phthalate 2- 3 parts, dithiocarbamate 2-4 part.
2. the kind fire resistant coating described in 1 is wanted it is characterised in that raw material form according to following portion rate according to right:
27 parts of acrylic emulsion, 13 parts of bipentaerythrite, 12 parts of expanded graphite, 15 parts of melamine, 9 parts of APP, hydrogen-oxygen Change 8 parts of aluminium, 4 parts of zinc oxide, 3 parts of silica, 8 parts of carbon fiber, 7 parts of silicon nitride fiber, 23 parts of water, Hydroxylated acrylic resin 13 Part, 14 parts of polyurethane resin, 8 parts of urea, 7 parts of pentaerythrite, 10 parts of melamine phosphate, 12 parts of white carbon, sodium metasilicate 8 Part, 4 parts of titanium dioxide, 2 parts of dioctyl phthalate, 3 parts of dithiocarbamate.
3. according to right want described in a kind fire resistant coating preparation method it is characterised in that comprising the steps:
(1) bipentaerythrite, expanded graphite, melamine, APP, aluminium hydroxide, zinc oxide, silica and water are existed Put into after mixing in stirred tank and in ball mill, grind 1-2 hour, drum's speed of rotation is 1500-2000r/min;
(2) and then it is slowly added to acrylic emulsion into ball mill, continues to grind 0.5-1 hour, filter, obtaining fineness is 90- The slurry of 110 mesh, slurry is inserted stirring at low speed in stirred tank and is simultaneously introduced carbon fiber, silicon nitride fiber, hydroxy acrylic acid tree Fat, polyurethane resin, urea, pentaerythrite, melamine phosphate, white carbon, sodium metasilicate, titanium dioxide, phthalic acid two Monooctyl ester, dithiocarbamate, stir, and obtain final product fire resistant coating.
CN201610818792.2A 2016-09-13 2016-09-13 Fireproof paint and preparation method thereof Pending CN106398425A (en)

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Application Number Priority Date Filing Date Title
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Cited By (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107216113A (en) * 2017-06-21 2017-09-29 合肥市旺友门窗有限公司 A kind of anti-fire door core board and preparation method thereof
CN107724555A (en) * 2017-11-18 2018-02-23 桂林全州燎原科技有限责任公司 A kind of preparation method of fire-proof plate
CN108624207A (en) * 2018-05-18 2018-10-09 侯伟旗 A kind of fire resistant doorsets special-purpose fire-resistant paint
CN108641513A (en) * 2018-05-24 2018-10-12 合肥市闵葵电力工程有限公司 A kind of power equipment special environment friendly fire resistant coating and preparation method thereof
CN108676399A (en) * 2018-06-15 2018-10-19 广东摩天零和壹涂料科技有限公司 It is a kind of easily to clean acrylic coating
CN108841229A (en) * 2018-07-12 2018-11-20 山东佳星环保科技有限公司 A kind of graphene expansion type low-smoke fireproof coating and preparation method thereof
CN109337571A (en) * 2018-09-30 2019-02-15 江苏耀兴安全玻璃有限公司 A kind of glass fireproof coating and preparation method thereof
CN109868022A (en) * 2019-01-22 2019-06-11 安徽唯楚新材料有限公司 A kind of novel fireproof flame-retardant wood-grain aluminum board and preparation method thereof
CN113388301A (en) * 2021-04-30 2021-09-14 西藏藏建科技股份有限公司 Fireproof paint spraying device for steel structure surface

Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102827519A (en) * 2012-09-12 2012-12-19 山东长星集团有限公司 Fireproof paint
CN102850881A (en) * 2012-09-12 2013-01-02 山东长星集团有限公司 Environment-friendly fire-retardant paint

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102827519A (en) * 2012-09-12 2012-12-19 山东长星集团有限公司 Fireproof paint
CN102850881A (en) * 2012-09-12 2013-01-02 山东长星集团有限公司 Environment-friendly fire-retardant paint

Cited By (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107216113A (en) * 2017-06-21 2017-09-29 合肥市旺友门窗有限公司 A kind of anti-fire door core board and preparation method thereof
CN107724555A (en) * 2017-11-18 2018-02-23 桂林全州燎原科技有限责任公司 A kind of preparation method of fire-proof plate
CN108624207A (en) * 2018-05-18 2018-10-09 侯伟旗 A kind of fire resistant doorsets special-purpose fire-resistant paint
CN108641513A (en) * 2018-05-24 2018-10-12 合肥市闵葵电力工程有限公司 A kind of power equipment special environment friendly fire resistant coating and preparation method thereof
CN108676399A (en) * 2018-06-15 2018-10-19 广东摩天零和壹涂料科技有限公司 It is a kind of easily to clean acrylic coating
CN108841229A (en) * 2018-07-12 2018-11-20 山东佳星环保科技有限公司 A kind of graphene expansion type low-smoke fireproof coating and preparation method thereof
CN109337571A (en) * 2018-09-30 2019-02-15 江苏耀兴安全玻璃有限公司 A kind of glass fireproof coating and preparation method thereof
CN109868022A (en) * 2019-01-22 2019-06-11 安徽唯楚新材料有限公司 A kind of novel fireproof flame-retardant wood-grain aluminum board and preparation method thereof
CN113388301A (en) * 2021-04-30 2021-09-14 西藏藏建科技股份有限公司 Fireproof paint spraying device for steel structure surface

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