CN106398425A - Fireproof paint and preparation method thereof - Google Patents
Fireproof paint and preparation method thereof Download PDFInfo
- Publication number
- CN106398425A CN106398425A CN201610818792.2A CN201610818792A CN106398425A CN 106398425 A CN106398425 A CN 106398425A CN 201610818792 A CN201610818792 A CN 201610818792A CN 106398425 A CN106398425 A CN 106398425A
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- China
- Prior art keywords
- parts
- melamine
- resistant coating
- fire resistant
- fireproof paint
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Classifications
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D133/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Coating compositions based on derivatives of such polymers
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/18—Fireproof paints including high temperature resistant paints
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/61—Additives non-macromolecular inorganic
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/63—Additives non-macromolecular organic
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/70—Additives characterised by shape, e.g. fibres, flakes or microspheres
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/014—Additives containing two or more different additives of the same subgroup in C08K
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/02—Flame or fire retardant/resistant
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/10—Transparent films; Clear coatings; Transparent materials
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
- C08L2205/025—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group containing two or more polymers of the same hierarchy C08L, and differing only in parameters such as density, comonomer content, molecular weight, structure
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
Abstract
The invention provides fireproof paint. Raw materials comprise the following components in parts: 26 to 47 parts of acrylic emulsion, 11 to 23 parts of dipentaerythritol, 6 to 18 parts of expanded graphite, 5 to 17 parts of melamine, 2 to 11 parts of ammonium polyphosphate, 3 to 12 parts of aluminum hydroxide, 3 to 6 parts of zinc oxide, 2 to 5 parts of silicon dioxide, 4 to 11 parts of carbon fiber, 5 to 11 parts of silicon nitride fiber, 21 to 33 parts of water, 11 to 16 parts of hydroxy acrylic resin, 12 to 16 parts of polyurethane resin, 5 to 9 parts of urea, 6 to 9 parts of pentaerythritol, 6 to 11 parts of melamine phosphate, 11 to 13 parts of white carbon black, 6 to 9 parts of sodium silicate, 3 to 5 parts of titanium pigment, 2 to 3 parts of dioctyl phthalate and 2 to 4 parts of dithiocarbamate. The fireproof paint is prepared from the raw materials which are nontoxic or are lower in toxicity, and cannot cause harm to a human body, particularly to a constructor in a normal construction process; further, the made fireproof paint is transparent. The fireproof paint is of an aqueous ultrathin type; when a fire hazard happens, no toxic gas is released; the fireproof paint can be widely applied to various steel structural buildings.
Description
Technical field
The present invention relates to building material field, more particularly, to a kind of fire resistant coating and preparation method thereof.
Background technology
Fire resistant coating is a kind of anti-flaming dope being fabricated by by multiple materials such as film forming agent, fire retardant, foaming agents;Due to mesh
The combustible material such as timber, cloth is used in a large number in front household, so, fire prevention has been a subject under discussion being worth lifting.Existing
Fire resistant coating can be divided into facing fire resistant coating, fire retarding wood protection paint, three kinds of steel structure fireproofing paint.Facing type fireproofing paint is a kind of collection decoration
The new paint kind being integrated with fire prevention, when it is coated on flammable base material, can play certain decoration function at ordinary times;Once
When fire occurs, then there is prevention fire spreading, thus reaching the purpose protecting flammable base material.Apply more in facing fire resistant coating
, effect is preferably expansion fire-proof paint.
Steel construction as a kind of form of high building structure, so that its intensity is high, light weight, and have good extensibility,
The features such as shock resistance and short construction period, show powerful vitality at the aspect such as Super High and long span building, in building
Increasingly it is widely applied in industry.But the more traditional masonry structure of the fire resistance of steel building and armored concrete knot
Structure is poor, and the mechanical strength of steel declines rapidly with the rising of temperature, loses enabling capabilities quickly, leads to building to collapse, therefore,
It is imperative steel construction to be carried out protect.Brush in steel structure surface or sprayed fire proofing paint (or fireproof coating) is commonly used at present
One of preventive means.
Steel structure fireproofing paint is broadly divided into thick coated type and scumbling type, and thick coated type steel structure fire resistant coating is typically using suitably viscous
Knot agent, then be equipped with inorganic lightweight material, reinforcing material is made, because it is all inorganic matter from base-material to most of additives, because
This is with low cost, but this kind of coating high temperature easily ftractures, and bonding strength is low.Scumbling formed steel construction fire resistant coating is mainly by polymer
Base-material, then it is equipped with the composition such as fire retardant, additive, foamed by expansion during fire, with expanded foamed formed refractory insulating layer
Delay the intensification of steel, protect steel beam column.Scumbling formed steel construction fire resistant coating can be divided into solvent-borne type and aqueous two classes, and solvent-borne type is prevented fires
Because using a large amount of organic solvents during production and construction, there is certain harm, water-based fireproof to environment and workmen in paint
Paint has environmental protection feature, meets the developing direction of low stain, Environmentally friendly coatings, but the research in China is started late,
Also has certain gap with solvent-borne type fire resistant coating on physicochemical property and weatherability.
Content of the invention
For above-mentioned problems of the prior art, it is an object of the invention to provide a kind of fire resistant coating and its preparation side
Method.
A kind of fire resistant coating, raw material form according to following portion rate:
Acrylic emulsion 26-47 part, bipentaerythrite 11-23 part, expanded graphite 6-18 part, melamine 5-17 part, polyphosphoric acid
Ammonium 2-11 part, aluminium hydroxide 3-12 part, zinc oxide 3-6 part, silica 2-5 part, carbon fiber 4-11 part, silicon nitride fiber 5-11
Part, water 21-33 part, Hydroxylated acrylic resin 11-16 part, polyurethane resin 12-16 part, urea 5-9 part, pentaerythrite 6-9 part,
Melamine phosphate 6-11 part, white carbon 11-13 part, sodium metasilicate 6-9 part, titanium dioxide 3-5 part, dioctyl phthalate 2-
3 parts, dithiocarbamate 2-4 part.
Further illustrate, described kind fire resistant coating, raw material form according to following portion rate:
27 parts of acrylic emulsion, 13 parts of bipentaerythrite, 12 parts of expanded graphite, 15 parts of melamine, 9 parts of APP, hydrogen-oxygen
Change 8 parts of aluminium, 4 parts of zinc oxide, 3 parts of silica, 8 parts of carbon fiber, 7 parts of silicon nitride fiber, 23 parts of water, Hydroxylated acrylic resin 13
Part, 14 parts of polyurethane resin, 8 parts of urea, 7 parts of pentaerythrite, 10 parts of melamine phosphate, 12 parts of white carbon, sodium metasilicate 8
Part, 4 parts of titanium dioxide, 2 parts of dioctyl phthalate, 3 parts of dithiocarbamate.
Further illustrate, the preparation method of described kind fire resistant coating, comprise the steps:
(1) bipentaerythrite, expanded graphite, melamine, APP, aluminium hydroxide, zinc oxide, silica and water are existed
Put into after mixing in stirred tank and in ball mill, grind 1-2 hour, drum's speed of rotation is 1500-2000r/min;
(2) and then it is slowly added to acrylic emulsion into ball mill, continues to grind 0.5-1 hour, filter, obtaining fineness is 90-
The slurry of 110 mesh, slurry is inserted stirring at low speed in stirred tank and is simultaneously introduced carbon fiber, silicon nitride fiber, hydroxy acrylic acid tree
Fat, polyurethane resin, urea, pentaerythrite, melamine phosphate, white carbon, sodium metasilicate, titanium dioxide, phthalic acid two
Monooctyl ester, dithiocarbamate, stir, and obtain final product fire resistant coating.
Beneficial effects of the present invention are as follows:
The present invention adopts raw material composition nontoxic or that toxicity is relatively low, will not be to human body, and especially workmen constructs normal
During do not result in harm, and the fire resistant coating made is transparent.This fire resistant coating is water super-thin, occurs no there is poison gas during fire
Body discharges, and can be widely applied to various steel buildings.
Specific embodiment
Below in conjunction with the embodiment of the present invention, the technical scheme in the embodiment of the present invention is clearly and completely described,
Obviously, described embodiment is only a part of embodiment of the present invention, rather than whole embodiments.Based on the reality in the present invention
Apply example, the every other embodiment that field those of ordinary skill is obtained under the premise of not making creative work, broadly fall into
The scope of protection of the invention.
Embodiment 1
A kind of fire resistant coating, raw material form according to following portion rate:
26 parts of acrylic emulsion, 11 parts of bipentaerythrite, 6 parts of expanded graphite, 5 parts of melamine, 2 parts of APP, hydroxide
3 parts of aluminium, 3 parts of zinc oxide, 2 parts of silica, 4 parts of carbon fiber, 5 parts of silicon nitride fiber, 21 parts of water, Hydroxylated acrylic resin 11
Part, 12 parts of polyurethane resin, 5 parts of urea, 6 parts of pentaerythrite, 6 parts of melamine phosphate, 11 parts of white carbon, 6 parts of sodium metasilicate,
3 parts of titanium dioxide, 2 parts of dioctyl phthalate, 2 parts of dithiocarbamate.
The preparation method of described kind fire resistant coating, comprises the steps:
(1) bipentaerythrite, expanded graphite, melamine, APP, aluminium hydroxide, zinc oxide, silica and water are existed
Put into after mixing in stirred tank in ball mill and grind 1 hour, drum's speed of rotation is 1500r/min;
(2) and then it is slowly added to acrylic emulsion into ball mill, continues to grind 0.5 hour, filter, obtaining fineness is 90 purposes
Slurry, slurry is inserted stirring at low speed in stirred tank and is simultaneously introduced carbon fiber, silicon nitride fiber, Hydroxylated acrylic resin, poly- ammonia
Ester resin, urea, pentaerythrite, melamine phosphate, white carbon, sodium metasilicate, titanium dioxide, dioctyl phthalate, two
Thiocarbamate, stirs, and obtains final product fire resistant coating.
Embodiment 2
A kind of fire resistant coating, raw material form according to following portion rate:
47 parts of acrylic emulsion, 23 parts of bipentaerythrite, 18 parts of expanded graphite, 17 parts of melamine, 11 parts of APP, hydrogen-oxygen
Change 12 parts of aluminium, 6 parts of zinc oxide, 5 parts of silica, 11 parts of carbon fiber, 11 parts of silicon nitride fiber, 33 parts of water, hydroxy acrylic acid tree
16 parts of fat, 16 parts of polyurethane resin, 9 parts of urea, 9 parts of pentaerythrite, 11 parts of melamine phosphate, 13 parts of white carbon, silicic acid
9 parts of sodium, 5 parts of titanium dioxide, 3 parts of dioctyl phthalate, 4 parts of dithiocarbamate.
The preparation method of described kind fire resistant coating, comprises the steps:
(1) bipentaerythrite, expanded graphite, melamine, APP, aluminium hydroxide, zinc oxide, silica and water are existed
Put into after mixing in stirred tank in ball mill and grind 2 hours, drum's speed of rotation is 2000r/min;
(2) and then it is slowly added to acrylic emulsion into ball mill, continues to grind 1 hour, filter, obtaining fineness is 110 purposes
Slurry, slurry is inserted stirring at low speed in stirred tank and is simultaneously introduced carbon fiber, silicon nitride fiber, Hydroxylated acrylic resin, poly- ammonia
Ester resin, urea, pentaerythrite, melamine phosphate, white carbon, sodium metasilicate, titanium dioxide, dioctyl phthalate, two
Thiocarbamate, stirs, and obtains final product fire resistant coating.
Above-described embodiment is the present invention preferably embodiment, but embodiments of the present invention are not subject to above-described embodiment
Limit, other any Spirit Essences without departing from the present invention and the change made under principle, modification, replacement, combine, simplify,
All should be equivalent substitute mode, be included within protection scope of the present invention.
Claims (3)
1. a kind of fire resistant coating is it is characterised in that raw material form according to following portion rate:
Acrylic emulsion 26-47 part, bipentaerythrite 11-23 part, expanded graphite 6-18 part, melamine 5-17 part, polyphosphoric acid
Ammonium 2-11 part, aluminium hydroxide 3-12 part, zinc oxide 3-6 part, silica 2-5 part, carbon fiber 4-11 part, silicon nitride fiber 5-11
Part, water 21-33 part, Hydroxylated acrylic resin 11-16 part, polyurethane resin 12-16 part, urea 5-9 part, pentaerythrite 6-9 part,
Melamine phosphate 6-11 part, white carbon 11-13 part, sodium metasilicate 6-9 part, titanium dioxide 3-5 part, dioctyl phthalate 2-
3 parts, dithiocarbamate 2-4 part.
2. the kind fire resistant coating described in 1 is wanted it is characterised in that raw material form according to following portion rate according to right:
27 parts of acrylic emulsion, 13 parts of bipentaerythrite, 12 parts of expanded graphite, 15 parts of melamine, 9 parts of APP, hydrogen-oxygen
Change 8 parts of aluminium, 4 parts of zinc oxide, 3 parts of silica, 8 parts of carbon fiber, 7 parts of silicon nitride fiber, 23 parts of water, Hydroxylated acrylic resin 13
Part, 14 parts of polyurethane resin, 8 parts of urea, 7 parts of pentaerythrite, 10 parts of melamine phosphate, 12 parts of white carbon, sodium metasilicate 8
Part, 4 parts of titanium dioxide, 2 parts of dioctyl phthalate, 3 parts of dithiocarbamate.
3. according to right want described in a kind fire resistant coating preparation method it is characterised in that comprising the steps:
(1) bipentaerythrite, expanded graphite, melamine, APP, aluminium hydroxide, zinc oxide, silica and water are existed
Put into after mixing in stirred tank and in ball mill, grind 1-2 hour, drum's speed of rotation is 1500-2000r/min;
(2) and then it is slowly added to acrylic emulsion into ball mill, continues to grind 0.5-1 hour, filter, obtaining fineness is 90-
The slurry of 110 mesh, slurry is inserted stirring at low speed in stirred tank and is simultaneously introduced carbon fiber, silicon nitride fiber, hydroxy acrylic acid tree
Fat, polyurethane resin, urea, pentaerythrite, melamine phosphate, white carbon, sodium metasilicate, titanium dioxide, phthalic acid two
Monooctyl ester, dithiocarbamate, stir, and obtain final product fire resistant coating.
Priority Applications (1)
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CN201610818792.2A CN106398425A (en) | 2016-09-13 | 2016-09-13 | Fireproof paint and preparation method thereof |
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CN201610818792.2A CN106398425A (en) | 2016-09-13 | 2016-09-13 | Fireproof paint and preparation method thereof |
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Cited By (9)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN107216113A (en) * | 2017-06-21 | 2017-09-29 | 合肥市旺友门窗有限公司 | A kind of anti-fire door core board and preparation method thereof |
CN107724555A (en) * | 2017-11-18 | 2018-02-23 | 桂林全州燎原科技有限责任公司 | A kind of preparation method of fire-proof plate |
CN108624207A (en) * | 2018-05-18 | 2018-10-09 | 侯伟旗 | A kind of fire resistant doorsets special-purpose fire-resistant paint |
CN108641513A (en) * | 2018-05-24 | 2018-10-12 | 合肥市闵葵电力工程有限公司 | A kind of power equipment special environment friendly fire resistant coating and preparation method thereof |
CN108676399A (en) * | 2018-06-15 | 2018-10-19 | 广东摩天零和壹涂料科技有限公司 | It is a kind of easily to clean acrylic coating |
CN108841229A (en) * | 2018-07-12 | 2018-11-20 | 山东佳星环保科技有限公司 | A kind of graphene expansion type low-smoke fireproof coating and preparation method thereof |
CN109337571A (en) * | 2018-09-30 | 2019-02-15 | 江苏耀兴安全玻璃有限公司 | A kind of glass fireproof coating and preparation method thereof |
CN109868022A (en) * | 2019-01-22 | 2019-06-11 | 安徽唯楚新材料有限公司 | A kind of novel fireproof flame-retardant wood-grain aluminum board and preparation method thereof |
CN113388301A (en) * | 2021-04-30 | 2021-09-14 | 西藏藏建科技股份有限公司 | Fireproof paint spraying device for steel structure surface |
Citations (2)
Publication number | Priority date | Publication date | Assignee | Title |
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CN102827519A (en) * | 2012-09-12 | 2012-12-19 | 山东长星集团有限公司 | Fireproof paint |
CN102850881A (en) * | 2012-09-12 | 2013-01-02 | 山东长星集团有限公司 | Environment-friendly fire-retardant paint |
-
2016
- 2016-09-13 CN CN201610818792.2A patent/CN106398425A/en active Pending
Patent Citations (2)
Publication number | Priority date | Publication date | Assignee | Title |
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CN102827519A (en) * | 2012-09-12 | 2012-12-19 | 山东长星集团有限公司 | Fireproof paint |
CN102850881A (en) * | 2012-09-12 | 2013-01-02 | 山东长星集团有限公司 | Environment-friendly fire-retardant paint |
Cited By (9)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN107216113A (en) * | 2017-06-21 | 2017-09-29 | 合肥市旺友门窗有限公司 | A kind of anti-fire door core board and preparation method thereof |
CN107724555A (en) * | 2017-11-18 | 2018-02-23 | 桂林全州燎原科技有限责任公司 | A kind of preparation method of fire-proof plate |
CN108624207A (en) * | 2018-05-18 | 2018-10-09 | 侯伟旗 | A kind of fire resistant doorsets special-purpose fire-resistant paint |
CN108641513A (en) * | 2018-05-24 | 2018-10-12 | 合肥市闵葵电力工程有限公司 | A kind of power equipment special environment friendly fire resistant coating and preparation method thereof |
CN108676399A (en) * | 2018-06-15 | 2018-10-19 | 广东摩天零和壹涂料科技有限公司 | It is a kind of easily to clean acrylic coating |
CN108841229A (en) * | 2018-07-12 | 2018-11-20 | 山东佳星环保科技有限公司 | A kind of graphene expansion type low-smoke fireproof coating and preparation method thereof |
CN109337571A (en) * | 2018-09-30 | 2019-02-15 | 江苏耀兴安全玻璃有限公司 | A kind of glass fireproof coating and preparation method thereof |
CN109868022A (en) * | 2019-01-22 | 2019-06-11 | 安徽唯楚新材料有限公司 | A kind of novel fireproof flame-retardant wood-grain aluminum board and preparation method thereof |
CN113388301A (en) * | 2021-04-30 | 2021-09-14 | 西藏藏建科技股份有限公司 | Fireproof paint spraying device for steel structure surface |
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