CN106398332A - Anti-wear and anti-corrosion super-hydrophobic self-cleaning window glass film and preparation method thereof - Google Patents
Anti-wear and anti-corrosion super-hydrophobic self-cleaning window glass film and preparation method thereof Download PDFInfo
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- CN106398332A CN106398332A CN201610805133.5A CN201610805133A CN106398332A CN 106398332 A CN106398332 A CN 106398332A CN 201610805133 A CN201610805133 A CN 201610805133A CN 106398332 A CN106398332 A CN 106398332A
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D1/00—Coating compositions, e.g. paints, varnishes or lacquers, based on inorganic substances
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B60—VEHICLES IN GENERAL
- B60J—WINDOWS, WINDSCREENS, NON-FIXED ROOFS, DOORS, OR SIMILAR DEVICES FOR VEHICLES; REMOVABLE EXTERNAL PROTECTIVE COVERINGS SPECIALLY ADAPTED FOR VEHICLES
- B60J1/00—Windows; Windscreens; Accessories therefor
- B60J1/20—Accessories, e.g. wind deflectors, blinds
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J7/00—Chemical treatment or coating of shaped articles made of macromolecular substances
- C08J7/04—Coating
- C08J7/06—Coating with compositions not containing macromolecular substances
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/08—Anti-corrosive paints
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- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Life Sciences & Earth Sciences (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Inorganic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Mechanical Engineering (AREA)
- Laminated Bodies (AREA)
- Surface Treatment Of Glass (AREA)
Abstract
The invention discloses an anti-wear and anti-corrosion super-hydrophobic self-cleaning window glass film and a preparation method thereof. The anti-wear and anti-corrosion super-hydrophobic self-cleaning window glass film comprises a transparent flexible organic base film, a nano particle layer and a transparent nano rough film which are arranged in sequence. By a method of combining cluster deposition and vacuum cold spraying or vacuum spraying mist settling, an anti-wear transparent nano rough film containing the transparent flexible organic base film and microparticle bulges is prepared. The film has the advantages that firstly, high transparency is guaranteed; secondly, based on the cooperation of the nano rough film and the microparticle bulges, the good super-hydrophobic self-cleaning effect is achieved; thirdly, microparticles and the nano rough film or a base are firmly combined, so that the anti-wear characteristic is realized; finally, an anti-corrosion non-metal material is used for preparing a film layer material of the film, so that excellent corrosion resistance is realized. In conclusion, on the premise of meeting the transparency of a coating layer, a super-hydrophobic coating layer is realized; meanwhile, the anti-wear and anti-corrosion super-hydrophobic self-cleaning window glass film has anti-wear and anti-corrosion performance, and the usability of an automobile film is obviously improved.
Description
Technical field
The present invention relates to coating technology field, super-hydrophobic particularly to a kind of wear resistant corrosion resistant that can be used for glass for vehicle window
Automatically cleaning pad pasting and preparation method thereof.
Background technology
Automobile glass for vehicle window in rainy day traveling is easily affected by rainwater, thus affecting driver in the process of moving
Road conditions are made with correct judgement, thus causes traffic accident even to cause casualties.Front truck glass pane can pass through rain brush
Carry out solve problem, but survey glass pane and can only be solved by means of hydrophobic type glass or glass-film with most of vehicle rear window.However, by
In side window glass, often serious surface abrasion is born in lifting at its sealing joint strip, there is no so far excellent abrasive resistance glass or
Glass-film can use.
Content of the invention
It is an object of the invention to provide a kind of super-hydrophobic automatic cleaning glass for vehicle window pad pasting of wear resistant corrosion resistant and its preparation
Method, to solve above-mentioned technical problem.Pad pasting of the present invention comprises the organic basement membrane of transparent flexible, transparent nano rough textured film, micron
Grain is raised.This pad pasting further increases super-hydrophobic, automatically cleaning, wear-resistant and corrosion on the basis of traditional glass for vehicle window pad pasting
Characteristic.
To achieve these goals, the present invention adopts the following technical scheme that：
The super-hydrophobic automatic cleaning glass for vehicle window pad pasting of wear resistant corrosion resistant, including the organic basement membrane of the transparent flexible setting gradually,
Micron particles layer and transparent nano rough textured film.
Further, the organic basement membrane of described transparent flexible is the adhering film to glass of high-molecular organic material.
Further, the organic basement membrane of described transparent flexible, is combined on the basis of the adhesive film material being high-molecular organic material
Heat-insulated, every ultraviolet, unidirectional one or more of hidden characteristic pad pasting.
Further, described transparent nano rough textured film, surface undulation is averagely less than 200nm, thickness is less than 5 μm；
The material of transparent nano rough textured film is one or more of silica, yittrium oxide, titanium oxide or zinc oxide.
Further, micron particles layer is less than the micron particles of 15 μm of surface distributed for average height；Micron particles
In layer, granular materials is silica, zirconium oxide, yittrium oxide, titanium oxide, zinc oxide, silicon nitride, carborundum, titanium nitride or titanium carbide
One or more of.
Further, the light transmittance of the super-hydrophobic automatic cleaning glass for vehicle window pad pasting of described wear resistant corrosion resistant is not less than 85%,
Hydrophobic contact angle is not less than 165 °.
Further, it is provided with one layer of bottom nanometer rough textured film between transparent nano rough textured film and the organic basement membrane of transparent flexible；
Bottom nanometer rough film surface rises and falls and is averagely less than 200nm, thickness is 0.5～3 μm；The material of bottom nanometer rough textured film is oxygen
One or more of SiClx, yittrium oxide, titanium oxide or zinc oxide.
The preparation method of the super-hydrophobic automatic cleaning glass for vehicle window pad pasting of wear resistant corrosion resistant, comprises the following steps：
(1) attachment film surface pretreatment：Remove the spot of transparent flexible organic basement membrane surface attachment or absorption；
(2) micro- in one layer of transparent flexible organic membrane surface preparation by the way of vacuum cold spray or airless injection sedimentation
Rice grain；
(3) pressure be 10-5～104The within the chamber of Pa by way of Cluster deposition, in transparent flexible organic basement membrane table
Face deposition preparation layer of transparent nanometer rough textured film, cluster refers to that atom number is no less than 3 atom aggregates being not more than 200.
Further, going back using plasma method for activating surface in step (1) makes organic membrane surface molecule produce dangling bond.
Further, before preparing micron particles in step (2), first is 10 in pressure-5～104The within the chamber of Pa passes through cluster
The mode of deposition, deposits one layer of bottom nanometer rough textured film of preparation in the organic membrane surface of the pretreated transparent flexible of step (1)；
Micron particles are deposited on bottom nanometer rough textured film；Transparent nano rough textured film is deposited on micron particles and bottom nanometer rough textured film
On.
Further, described airless injection sedimentation, is within the chamber, micron particles injection dispersion to fall after natural subsidence
In bottom nanometer rough film surface；Or, it is to disperse powered micron particles injection after gravity natural subsidence within the chamber
Fall in bottom nanometer rough film surface；Or, it is through settling path at it within the chamber by powered micron particles injection dispersion
Collide in bottom nanometer rough film surface after accelerating under the electric field action of upper setting.
With respect to prior art, the invention has the advantages that：
The present invention discloses super-hydrophobic automatic cleaning glass for vehicle window pad pasting of a kind of wear resistant corrosion resistant and preparation method thereof, by group
Cluster deposition and the method for vacuum cold spray or the sedimentation mixing of airless injection mist, prepare and comprise the organic basement membrane of transparent flexible, transparent
Raised wear-resisting, the corrosion-resistant super-hydrophobic automatic cleaning coating of nanometer rough textured film, micron particles.Pad pasting involved in the present invention, first
Ensure that the good transparency；Secondly, based on the raised cooperation of nanometer rough textured film and micron particles it is achieved that good is super-hydrophobic
Automatic cleaning action；Again, it is firmly combined between micron particles and nanometer rough textured film or between base, there is wear-resistant property；?
Afterwards, from the preparation of corrosion resistant nonmetallic materials as pad pasting film material it is achieved that excellent corrosion resistance.In a word, exist
Meet coating light transmittance and be not less than the super-hydrophobic coat realizing on the premise of 85% that hydrophobic contact angle is not less than 165 °, have simultaneously
Wear-resisting, corrosion resistant performance, significantly improves automobile adhesive film serviceability.
Brief description
Fig. 1 is three step preparation method deposition schematic diagrames；
Fig. 2 is three step preparation method structural representations；
Fig. 3 deposits schematic diagram for four steps preparation method；
Fig. 4 is four steps preparation method structural representation.
Specific embodiment
The following is the specific embodiment that inventor provides, it should be noted that these embodiments are the present invention preferably examples
Son, understands the present invention for those skilled in the art, but the invention is not limited in these embodiments.
Embodiment 1：
A kind of preparation method of the super-hydrophobic automatic cleaning glass for vehicle window pad pasting of wear resistant corrosion resistant, comprises the steps of：
Organic basement membrane 1 surface preparation to transparent flexible, removes the spot of surface attachment or absorption, adopt further etc. from
Daughter method for activating surface makes the organic basement membrane of transparent flexible 1 surface molecular produce dangling bond, is beneficial to subsequent film and combines.Then, adopt
The Zirconium oxide powder being 1～3 μm with particle diameter, prepares one layer by way of vacuum cold spray on the organic basement membrane of transparent flexible 1
Micron particles layer 2.Then, using grain silica pressure be 10-5～104The within the chamber of Pa by way of Cluster deposition,
Attachment film surface deposition one layer of top layer nanometer rough textured film 3 of preparation, this cluster refers to that atom number is no less than 3 atoms being not more than 200
Aggregation, forms strong bonded by means of its huge surface energy with depositing base during Cluster deposition.Top layer nanometer rough textured film 3 is
Surface undulation is averagely less than 200nm, thickness is 0.2～0.5 μm.Whole coating deposition process as shown in figure 1, finally give as
Film structure shown in Fig. 2, under the premise of prepared pad pasting achieves the light transmittance ensureing to be not less than 85%, possesses hydrophobic contact angle
It is not less than 165 ° of ultra-hydrophobicity, there is wear-resisting, corrosion resistant performance simultaneously.
Embodiment 2：
A kind of preparation method of the super-hydrophobic automatic cleaning glass for vehicle window pad pasting of wear resistant corrosion resistant, comprises the steps of：
Organic basement membrane 1 surface preparation to transparent flexible, removes the spot of surface attachment or absorption, is beneficial to subsequent film knot
Close.The yttrium oxide powder being 2～5 μm using particle diameter, by way of airless injection settles, within the chamber by powered micron
Grain sprays the basement membrane organic in transparent flexible that disperse to fall after gravity natural subsidence, and particle contacts the moment of the organic basement membrane of transparent flexible
Occur electric discharge to make micron particles be firmly bonded to surface with surface, form micron particles layer 2.Using titanium oxide pressure be 10-5
～104The within the chamber of Pa, by way of Cluster deposition, deposits one layer of top layer nanometer rough textured film 3 of preparation, this group in attachment film surface
Cluster refers to that atom number is no less than 3 atom aggregates being not more than 200, during Cluster deposition by means of its huge surface energy with heavy
Long-pending matrix forms strong bonded.Top layer nanometer rough textured film 3 is that surface undulation is averagely less than 150nm, thickness is 0.3～1 μm
The film of rough surface.Finally give film structure as shown in Figure 2, prepared pad pasting achieve ensure be not less than 85% saturating
Under the premise of light rate, possess the ultra-hydrophobicity that hydrophobic contact angle is not less than 160 °, there is wear-resisting, corrosion resistant performance simultaneously.
Embodiment 3：
A kind of preparation method of the super-hydrophobic automatic cleaning glass for vehicle window pad pasting of wear resistant corrosion resistant, comprises the steps of：
Organic basement membrane 1 surface preparation to transparent flexible, removes the spot of surface attachment or absorption, adopt further etc. from
Daughter method for activating surface makes organic membrane surface molecule produce dangling bond, is beneficial to follow-up nanometer rough textured film and combines.Using yittrium oxide
It is 10 in pressure-5～104The within the chamber of Pa, by way of Cluster deposition, deposits preparation on the organic basement membrane of transparent flexible 1 surface
One layer of bottom nanometer rough textured film 4, forms strong bonded by means of its huge surface energy with depositing base during Cluster deposition.Bottom
Nanometer rough textured film 4 is the film that surface undulation is averagely less than the rough surface that 100nm, thickness are 0.5～3 μm.Then, adopt
Particle diameter is 1～3 μm of silicon carbide powder, prepares one layer of micron particles layer 2 by way of vacuum cold spray.Then, using oxygen
Change yttrium and continue deposition formation top layer nanometer rough textured film 3 again by way of Cluster deposition, meanwhile, be deposited on micron particles and bottom
The material of nanometer rough textured film 4 near interface is by the interface enhancing between micron particles and bottom nanometer rough textured film 4.Top layer nanometer is thick
Rough film 3 is the film that surface undulation is averagely less than the rough surface that 200nm, thickness are 0.2～1.5 μm.Whole coating deposition
Process as shown in figure 3, finally giving film structure as shown in Figure 4, prepared pad pasting achieve ensure be not less than 85% saturating
Under the premise of light rate, possess the ultra-hydrophobicity that hydrophobic contact angle is not less than 165 °, there is wear-resisting, corrosion resistant performance simultaneously.
Embodiment 4：
A kind of preparation method of the super-hydrophobic automatic cleaning glass for vehicle window pad pasting of wear resistant corrosion resistant, comprises the steps of：
Organic basement membrane 1 surface preparation to transparent flexible, removes the spot of surface attachment or absorption, is beneficial to follow-up nanometer
Rough textured film combines.Using silica pressure be 10-5～104The within the chamber of Pa by way of Cluster deposition, in attachment film surface
Deposition one layer of bottom nanometer rough textured film 4 of preparation, is formed firmly by means of its huge surface energy and depositing base during Cluster deposition
In conjunction with.Bottom nanometer rough textured film 4 is the film that surface undulation is averagely less than the rough surface that 200nm, thickness are 0.5～3 μm.
Then, the alpha-silicon nitride powders being 1～3 μm using particle diameter, by way of airless injection settles, within the chamber by powered micron
Particle injection dispersion is collided on bottom nanometer rough textured film 4 surface after acceleration through settling at it under the electric field action of setting on path,
The moment on particle contact bottom layer nanometer rough textured film 4 surface and surface occur electric discharge to make micron particles be firmly bonded to surface, are formed
One layer of micron particles layer 2.Then, continue deposition by the way of silica is again by Cluster deposition and form top layer nanometer rough textured film
3, meanwhile, the material being deposited on micron particles and bottom nanometer rough textured film 4 near interface will be coarse with bottom nanometer for micron particles
Interface enhancing between film 4.Top layer layer nanometer rough textured film 3 is that surface undulation is averagely less than 200nm, thickness is 0.5～3 μm
The film of rough surface.Finally give film structure as shown in Figure 4, prepared pad pasting achieve ensure be not less than 85% saturating
Under the premise of light rate, possess the ultra-hydrophobicity that hydrophobic contact angle is not less than 165 °, there is wear-resisting, corrosion resistant performance simultaneously.
Embodiment 5：
A kind of preparation method of the super-hydrophobic automatic cleaning glass for vehicle window pad pasting of wear resistant corrosion resistant, comprises the steps of：
Organic basement membrane 1 surface preparation to transparent flexible, removes the spot of surface attachment or absorption, adopt further etc. from
Daughter method for activating surface makes organic membrane surface molecule produce dangling bond, is beneficial to follow-up nanometer rough textured film and combines.Using titanium oxide
It is 10 in pressure-5～104The within the chamber of Pa, by way of Cluster deposition, deposits preparation on the organic basement membrane of transparent flexible 1 surface
One layer of bottom nanometer rough textured film 4, forms strong bonded by means of its huge surface energy with depositing base during Cluster deposition.Bottom
Nanometer rough textured film 4 surface undulation is averagely less than the film of the rough surface that 200nm, thickness are 0.5～3 μm.Then, using grain
Footpath is 1～3 μm of yttrium oxide powder, by way of airless injection settles, divides powered micron particles injection within the chamber
Dissipate fall on bottom nanometer rough textured film 4 surface after gravity natural subsidence, the moment on particle contact bottom layer nanometer rough textured film 4 surface with
Surface occurs electric discharge to make micron particles be firmly bonded to surface, forms one layer of micron particles layer 2.Then, led to again using titanium nitride
The mode crossing Cluster deposition continues deposition formation top layer nanometer rough textured film 3, meanwhile, is deposited on micron particles coarse with bottom nanometer
The material of film 4 near interface is by the interface enhancing between micron particles and bottom nanometer rough textured film 4.Top layer nanometer rough textured film 3 is
Surface undulation is averagely less than the film of the rough surface that 200nm, thickness are 0.3～1 μm.Finally give patch as shown in Figure 4
Membrane structure, under the premise of prepared pad pasting achieves the light transmittance ensureing to be not less than 85%, possesses hydrophobic contact angle and is not less than 165 °
Ultra-hydrophobicity, there is wear-resisting, corrosion resistant performance simultaneously.
Claims (10)
1. the super-hydrophobic automatic cleaning glass for vehicle window pad pasting of wear resistant corrosion resistant is it is characterised in that include the transparent flexible setting gradually
Organic basement membrane, micron particles layer and transparent nano rough textured film.
2. the super-hydrophobic automatic cleaning glass for vehicle window pad pasting of wear resistant corrosion resistant according to claim 1 is it is characterised in that described
The organic basement membrane of transparent flexible be high-molecular organic material adhering film to glass.
3. the super-hydrophobic automatic cleaning glass for vehicle window pad pasting of wear resistant corrosion resistant according to claim 1 is it is characterised in that described
The organic basement membrane of transparent flexible, be compounded with heat-insulated, every ultraviolet, unidirectional hidden on the basis of the adhesive film material being high-molecular organic material
One or more of cover the pad pasting of characteristic.
4. the super-hydrophobic automatic cleaning glass for vehicle window pad pasting of wear resistant corrosion resistant according to claim 1 is it is characterised in that described
Transparent nano rough textured film, surface undulation averagely be less than 200nm, thickness be less than 5 μm；The material of transparent nano rough textured film is
One or more of silica, yittrium oxide, titanium oxide or zinc oxide.
5. the super-hydrophobic automatic cleaning glass for vehicle window pad pasting of the wear resistant corrosion resistant stated according to claim 1 is it is characterised in that micron
Granulosa average height is less than the micron particles of 15 μm of surface distributed；In micron particles layer, granular materials is silica, oxidation
One or more of zirconium, yittrium oxide, titanium oxide, zinc oxide, silicon nitride, carborundum, titanium nitride or titanium carbide.
6. the super-hydrophobic automatic cleaning glass for vehicle window pad pasting of wear resistant corrosion resistant according to claim 1 is it is characterised in that described
The light transmittance of the super-hydrophobic automatic cleaning glass for vehicle window pad pasting of wear resistant corrosion resistant is not less than 85%, and hydrophobic contact angle is not less than 165 °.
7. the super-hydrophobic automatic cleaning glass for vehicle window pad pasting of wear resistant corrosion resistant according to any one of claim 1 to 6, it is special
Levy and be, between transparent nano rough textured film and the organic basement membrane of transparent flexible, be provided with one layer of bottom nanometer rough textured film；Bottom nanometer is thick
Rough film surface undulation is averagely less than 200nm, thickness is 0.5～3 μm；The material of bottom nanometer rough textured film is silica, oxidation
One or more of yttrium, titanium oxide or zinc oxide.
8. the preparation side of the super-hydrophobic automatic cleaning glass for vehicle window pad pasting of the wear resistant corrosion resistant any one of claim 1 to 6
Method is it is characterised in that comprise the following steps：
(1) attachment film surface pretreatment：Remove the spot of transparent flexible organic basement membrane surface attachment or absorption；
(2) in the organic membrane surface of transparent flexible by the way of the sedimentation of vacuum cold spray, airless injection sedimentation or vacuum spraying
One layer of micron particles of preparation；
(3) pressure be 10-5～104The within the chamber of Pa, by way of Cluster deposition, is sunk in the organic membrane surface of transparent flexible
Long-pending preparation layer of transparent nanometer rough textured film, cluster refers to that atom number is no less than 3 atom aggregates being not more than 200.
9. the preparation method described in claim 7 is it is characterised in that go back using plasma method for activating surface in step (1)
Organic membrane surface molecule is made to produce dangling bond.
10., before the preparation method described in claim 7 is it is characterised in that prepare micron particles in step (2), in pressure it is first
10-5～104The within the chamber of Pa by way of Cluster deposition, in the organic membrane surface of the pretreated transparent flexible of step (1)
Deposition one layer of bottom nanometer rough textured film of preparation；Micron particles are deposited on bottom nanometer rough textured film；Transparent nano rough textured film deposits
On micron particles and bottom nanometer rough textured film；Described airless injection sedimentation, is, within the chamber, micron particles are sprayed dispersion warp
Fall after natural subsidence in bottom nanometer rough film surface；Or, it is through weight within the chamber by powered micron particles injection dispersion
Fall after power natural subsidence in bottom nanometer rough film surface；Described vacuum spraying sedimentation, is by powered micron within the chamber
Particle injection dispersion is collided in bottom nanometer rough film surface after acceleration under the electric field action of setting on path through settling at it.
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Cited By (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108276922A (en) * | 2018-01-19 | 2018-07-13 | 全椒光太胶粘制品有限公司 | A kind of manufacturing method of automobile-used isolation film |
| CN108912747A (en) * | 2017-04-18 | 2018-11-30 | 吴瑛 | For glass or the anion coating of rupture pressure disc and preparation method thereof |
| TWI677478B (en) * | 2017-12-26 | 2019-11-21 | 鴻海精密工業股份有限公司 | A hydrophobic window, a house and a vehicle using the same |
| US10877187B2 (en) | 2017-12-26 | 2020-12-29 | Tsinghua University | Hydrophobic mirror and vehicle using the same |
| US10877186B2 (en) | 2017-12-26 | 2020-12-29 | Tsinghua University | Hydrophobic mirror and vehicle using the same |
| US11111175B2 (en) | 2017-12-26 | 2021-09-07 | Tsinghua University | Hydrophobic window, house and vehicle using the same |
| CN113528040A (en) * | 2021-07-28 | 2021-10-22 | 宁波泰意德过滤技术有限公司 | Heat-insulating anti-ultraviolet glass film and preparation method thereof |
| US11247430B2 (en) | 2017-12-26 | 2022-02-15 | Tsinghua University | Hydrophobic film |
| WO2024021971A1 (en) * | 2022-07-28 | 2024-02-01 | 华为技术有限公司 | Light-transmitting plate, structural member, and light sensing apparatus |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN202130083U (en) * | 2011-06-20 | 2012-02-01 | 江阴市通利包装材料有限公司 | Nano protective film of composite structure |
| CN103572299A (en) * | 2013-11-05 | 2014-02-12 | 铁道第三勘察设计院集团有限公司 | Optional voltage type drainage circuit structure |
| CN204977691U (en) * | 2015-09-22 | 2016-01-20 | 郑州艾比利特节能科技有限公司 | Thermal -insulated self -cleaning glass pad pasting keeps warm |
-
2016
- 2016-09-06 CN CN201610805133.5A patent/CN106398332B/en active Active
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN202130083U (en) * | 2011-06-20 | 2012-02-01 | 江阴市通利包装材料有限公司 | Nano protective film of composite structure |
| CN103572299A (en) * | 2013-11-05 | 2014-02-12 | 铁道第三勘察设计院集团有限公司 | Optional voltage type drainage circuit structure |
| CN204977691U (en) * | 2015-09-22 | 2016-01-20 | 郑州艾比利特节能科技有限公司 | Thermal -insulated self -cleaning glass pad pasting keeps warm |
Cited By (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108912747A (en) * | 2017-04-18 | 2018-11-30 | 吴瑛 | For glass or the anion coating of rupture pressure disc and preparation method thereof |
| TWI677478B (en) * | 2017-12-26 | 2019-11-21 | 鴻海精密工業股份有限公司 | A hydrophobic window, a house and a vehicle using the same |
| US10732326B2 (en) | 2017-12-26 | 2020-08-04 | Tsinghua University | Hydrophobic window, house and vehicle using the same |
| US10877187B2 (en) | 2017-12-26 | 2020-12-29 | Tsinghua University | Hydrophobic mirror and vehicle using the same |
| US10877186B2 (en) | 2017-12-26 | 2020-12-29 | Tsinghua University | Hydrophobic mirror and vehicle using the same |
| US11111175B2 (en) | 2017-12-26 | 2021-09-07 | Tsinghua University | Hydrophobic window, house and vehicle using the same |
| US11247430B2 (en) | 2017-12-26 | 2022-02-15 | Tsinghua University | Hydrophobic film |
| CN108276922A (en) * | 2018-01-19 | 2018-07-13 | 全椒光太胶粘制品有限公司 | A kind of manufacturing method of automobile-used isolation film |
| CN113528040A (en) * | 2021-07-28 | 2021-10-22 | 宁波泰意德过滤技术有限公司 | Heat-insulating anti-ultraviolet glass film and preparation method thereof |
| WO2024021971A1 (en) * | 2022-07-28 | 2024-02-01 | 华为技术有限公司 | Light-transmitting plate, structural member, and light sensing apparatus |
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