CN106398137B - 一种无卤阻燃长玻纤增强pet复合材料及其制备方法 - Google Patents
一种无卤阻燃长玻纤增强pet复合材料及其制备方法 Download PDFInfo
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- CN106398137B CN106398137B CN201610800845.8A CN201610800845A CN106398137B CN 106398137 B CN106398137 B CN 106398137B CN 201610800845 A CN201610800845 A CN 201610800845A CN 106398137 B CN106398137 B CN 106398137B
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- fiber reinforced
- glass fiber
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- 239000003365 glass fiber Substances 0.000 title claims abstract description 70
- 239000002131 composite material Substances 0.000 title claims abstract description 52
- 238000002360 preparation method Methods 0.000 title abstract description 14
- 239000005020 polyethylene terephthalate Substances 0.000 claims abstract description 68
- 229920000139 polyethylene terephthalate Polymers 0.000 claims abstract description 68
- 239000003063 flame retardant Substances 0.000 claims abstract description 54
- DXZMANYCMVCPIM-UHFFFAOYSA-L zinc;diethylphosphinate Chemical compound [Zn+2].CCP([O-])(=O)CC.CCP([O-])(=O)CC DXZMANYCMVCPIM-UHFFFAOYSA-L 0.000 claims abstract description 30
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 24
- 239000003963 antioxidant agent Substances 0.000 claims abstract description 23
- 230000003078 antioxidant effect Effects 0.000 claims abstract description 23
- -1 polyethylene terephthalate Polymers 0.000 claims abstract description 21
- 239000012745 toughening agent Substances 0.000 claims abstract description 19
- MYOXMAQGEINAEF-UHFFFAOYSA-N [C].N1=NN=CC=C1 Chemical compound [C].N1=NN=CC=C1 MYOXMAQGEINAEF-UHFFFAOYSA-N 0.000 claims abstract description 15
- 238000012545 processing Methods 0.000 claims abstract description 8
- 238000007598 dipping method Methods 0.000 claims description 10
- 238000001816 cooling Methods 0.000 claims description 6
- 238000001035 drying Methods 0.000 claims description 6
- 238000001125 extrusion Methods 0.000 claims description 6
- 238000005453 pelletization Methods 0.000 claims description 6
- 238000002844 melting Methods 0.000 claims description 5
- 230000008018 melting Effects 0.000 claims description 5
- 238000002156 mixing Methods 0.000 claims description 5
- 238000000354 decomposition reaction Methods 0.000 claims description 4
- 230000002687 intercalation Effects 0.000 claims description 3
- 238000009830 intercalation Methods 0.000 claims description 3
- 229910052760 oxygen Inorganic materials 0.000 claims description 3
- 239000001301 oxygen Substances 0.000 claims description 3
- 150000003839 salts Chemical class 0.000 claims description 3
- BSYJHYLAMMJNRC-UHFFFAOYSA-N 2,4,4-trimethylpentan-2-ol Chemical compound CC(C)(C)CC(C)(C)O BSYJHYLAMMJNRC-UHFFFAOYSA-N 0.000 claims description 2
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims description 2
- GUJOJGAPFQRJSV-UHFFFAOYSA-N dialuminum;dioxosilane;oxygen(2-);hydrate Chemical compound O.[O-2].[O-2].[O-2].[Al+3].[Al+3].O=[Si]=O.O=[Si]=O.O=[Si]=O.O=[Si]=O GUJOJGAPFQRJSV-UHFFFAOYSA-N 0.000 claims description 2
- 229910052901 montmorillonite Inorganic materials 0.000 claims description 2
- 229910052736 halogen Inorganic materials 0.000 claims 1
- 150000002367 halogens Chemical class 0.000 claims 1
- 238000000034 method Methods 0.000 abstract description 26
- 238000001802 infusion Methods 0.000 abstract description 12
- RNFJDJUURJAICM-UHFFFAOYSA-N 2,2,4,4,6,6-hexaphenoxy-1,3,5-triaza-2$l^{5},4$l^{5},6$l^{5}-triphosphacyclohexa-1,3,5-triene Chemical compound N=1P(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP=1(OC=1C=CC=CC=1)OC1=CC=CC=C1 RNFJDJUURJAICM-UHFFFAOYSA-N 0.000 abstract description 11
- 229920005989 resin Polymers 0.000 abstract description 10
- 239000011347 resin Substances 0.000 abstract description 10
- 239000011159 matrix material Substances 0.000 abstract description 9
- 239000000835 fiber Substances 0.000 abstract description 6
- 230000002195 synergetic effect Effects 0.000 abstract description 6
- 230000000694 effects Effects 0.000 abstract description 3
- 238000005265 energy consumption Methods 0.000 abstract description 3
- 239000002270 dispersing agent Substances 0.000 abstract description 2
- 230000000052 comparative effect Effects 0.000 description 12
- 239000000203 mixture Substances 0.000 description 7
- 239000000463 material Substances 0.000 description 6
- 238000005253 cladding Methods 0.000 description 5
- KKEYFWRCBNTPAC-UHFFFAOYSA-N Terephthalic acid Chemical compound OC(=O)C1=CC=C(C(O)=O)C=C1 KKEYFWRCBNTPAC-UHFFFAOYSA-N 0.000 description 4
- YNPNZTXNASCQKK-UHFFFAOYSA-N phenanthrene Chemical compound C1=CC=C2C3=CC=CC=C3C=CC2=C1 YNPNZTXNASCQKK-UHFFFAOYSA-N 0.000 description 4
- 238000005452 bending Methods 0.000 description 3
- LYCAIKOWRPUZTN-UHFFFAOYSA-N ethylene glycol Natural products OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 3
- WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 description 3
- 238000005470 impregnation Methods 0.000 description 3
- 238000000465 moulding Methods 0.000 description 3
- 239000002245 particle Substances 0.000 description 3
- KUCOHFSKRZZVRO-UHFFFAOYSA-N terephthalaldehyde Chemical compound O=CC1=CC=C(C=O)C=C1 KUCOHFSKRZZVRO-UHFFFAOYSA-N 0.000 description 3
- 238000012360 testing method Methods 0.000 description 3
- 238000010835 comparative analysis Methods 0.000 description 2
- 150000001875 compounds Chemical class 0.000 description 2
- 238000002425 crystallisation Methods 0.000 description 2
- 230000008025 crystallization Effects 0.000 description 2
- 125000005842 heteroatom Chemical group 0.000 description 2
- 230000003647 oxidation Effects 0.000 description 2
- 238000007254 oxidation reaction Methods 0.000 description 2
- 238000011056 performance test Methods 0.000 description 2
- 230000002787 reinforcement Effects 0.000 description 2
- 239000003381 stabilizer Substances 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- 229920001169 thermoplastic Polymers 0.000 description 2
- 229920005992 thermoplastic resin Polymers 0.000 description 2
- 239000004416 thermosoftening plastic Substances 0.000 description 2
- JYEUMXHLPRZUAT-UHFFFAOYSA-N 1,2,3-triazine Chemical compound C1=CN=NN=C1 JYEUMXHLPRZUAT-UHFFFAOYSA-N 0.000 description 1
- 239000004594 Masterbatch (MB) Substances 0.000 description 1
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N Phenol Chemical compound OC1=CC=CC=C1 ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 description 1
- 238000005299 abrasion Methods 0.000 description 1
- 230000003466 anti-cipated effect Effects 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 239000003610 charcoal Substances 0.000 description 1
- 238000013329 compounding Methods 0.000 description 1
- 238000009826 distribution Methods 0.000 description 1
- 238000010292 electrical insulation Methods 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 238000004079 fireproofing Methods 0.000 description 1
- 239000011521 glass Substances 0.000 description 1
- 230000009477 glass transition Effects 0.000 description 1
- 239000008187 granular material Substances 0.000 description 1
- 239000000155 melt Substances 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 150000008301 phosphite esters Chemical class 0.000 description 1
- 229920006111 poly(hexamethylene terephthalamide) Polymers 0.000 description 1
- 229920000642 polymer Polymers 0.000 description 1
- 239000002689 soil Substances 0.000 description 1
- 238000006467 substitution reaction Methods 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L67/00—Compositions of polyesters obtained by reactions forming a carboxylic ester link in the main chain; Compositions of derivatives of such polymers
- C08L67/02—Polyesters derived from dicarboxylic acids and dihydroxy compounds
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/02—Flame or fire retardant/resistant
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/22—Halogen free composition
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Reinforced Plastic Materials (AREA)
Abstract
Description
测试项目 | 实施例1 | 实施例2 | 实施例3 | 对比例1 | 对比例2 |
拉伸强度(MPa) | 138 | 145 | 118 | 102 | 130 |
悬臂梁缺口冲击强度(KJ/M<sup>2</sup>) | 22.5 | 23.9 | 19.2 | 16 | 20 |
弯曲强度(MPa) | 189 | 200 | 157 | 139 | 181 |
阻燃性能(UL94) | V0 | V0 | V0 | V1 | V1 |
成型难易程度 | 易 | 易 | 易 | 易 | 易 |
表面质量 | 无花纹 | 无花纹 | 无花纹 | 无花纹 | 无花纹 |
Claims (7)
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN201610800845.8A CN106398137B (zh) | 2016-09-04 | 2016-09-04 | 一种无卤阻燃长玻纤增强pet复合材料及其制备方法 |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
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CN201610800845.8A CN106398137B (zh) | 2016-09-04 | 2016-09-04 | 一种无卤阻燃长玻纤增强pet复合材料及其制备方法 |
Publications (2)
Publication Number | Publication Date |
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CN106398137A CN106398137A (zh) | 2017-02-15 |
CN106398137B true CN106398137B (zh) | 2019-01-29 |
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CN201610800845.8A Active CN106398137B (zh) | 2016-09-04 | 2016-09-04 | 一种无卤阻燃长玻纤增强pet复合材料及其制备方法 |
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CN (1) | CN106398137B (zh) |
Families Citing this family (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN109867919A (zh) * | 2017-12-04 | 2019-06-11 | 广州汽车集团股份有限公司 | 聚对苯二甲酸乙二醇酯复合材料、制品和制备方法 |
JP7114895B2 (ja) | 2017-12-19 | 2022-08-09 | 三菱ケミカル株式会社 | ポリエチレンテレフタレートフィルム |
CN108485208A (zh) * | 2018-03-29 | 2018-09-04 | 贵州省材料产业技术研究院 | 一种dopo衍生物阻燃pet透明复合材料及制备方法 |
CN108929524A (zh) * | 2018-09-05 | 2018-12-04 | 贵州省材料产业技术研究院 | 一种反应增容阻燃聚酯材料及其制备方法 |
Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN102875982A (zh) * | 2012-10-15 | 2013-01-16 | 宁波优科泰科技发展有限公司 | 原位改性无卤阻燃热塑性树脂组合物及其制备方法 |
CN104086593A (zh) * | 2014-07-14 | 2014-10-08 | 中国科学院宁波材料技术与工程研究所 | 一类dopo衍生物、其制备方法及应用 |
CN104371291A (zh) * | 2014-12-01 | 2015-02-25 | 贵州凯科特材料有限公司 | 高性能无卤阻燃长纤维增强聚乳酸复合材料及其制备方法 |
Family Cites Families (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP1709120B1 (en) * | 2004-01-30 | 2008-09-17 | DSMIP Assets B.V. | Halogen-free flame-retarded polyester composition |
KR100653601B1 (ko) * | 2004-07-08 | 2006-12-04 | 삼박엘에프티 (주) | 폴리올레핀계 장섬유 강화 조성물 및 이를 이용하여 제조된 착색 장섬유 강화 성형품의 제조방법 |
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2016
- 2016-09-04 CN CN201610800845.8A patent/CN106398137B/zh active Active
Patent Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN102875982A (zh) * | 2012-10-15 | 2013-01-16 | 宁波优科泰科技发展有限公司 | 原位改性无卤阻燃热塑性树脂组合物及其制备方法 |
CN104086593A (zh) * | 2014-07-14 | 2014-10-08 | 中国科学院宁波材料技术与工程研究所 | 一类dopo衍生物、其制备方法及应用 |
CN104371291A (zh) * | 2014-12-01 | 2015-02-25 | 贵州凯科特材料有限公司 | 高性能无卤阻燃长纤维增强聚乳酸复合材料及其制备方法 |
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Address after: 236500 Anhui Jieshou City in Fuyang Province Jieshou jingyilu Development Zone Industrial Park Pansum Guangwu West No. 4 Patentee after: Anhui shengchenyuan Material Technology Industrial Development Co.,Ltd. Address before: 236500 Anhui Jieshou City in Fuyang Province Jieshou jingyilu Development Zone Industrial Park Pansum Guangwu West No. 4 Patentee before: KANGMINGYUAN (ANHUI) PLASTIC TECHNOLOGY DEVELOPMENT Co.,Ltd. |
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Denomination of invention: Halogen free flame retardant Long Glass Fiber Reinforced PET composite and its preparation method Effective date of registration: 20220531 Granted publication date: 20190129 Pledgee: The development of small and medium-sized enterprises financing Company Limited by Guarantee Jieshou City Pledgor: Anhui shengchenyuan Material Technology Industrial Development Co.,Ltd. Registration number: Y2022980006721 |
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Date of cancellation: 20230712 Granted publication date: 20190129 Pledgee: The development of small and medium-sized enterprises financing Company Limited by Guarantee Jieshou City Pledgor: Anhui shengchenyuan Material Technology Industrial Development Co.,Ltd. Registration number: Y2022980006721 |
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Denomination of invention: A halogen-free flame retardant long glass fiber reinforced PET composite material and its preparation method Effective date of registration: 20231116 Granted publication date: 20190129 Pledgee: Huaxia Bank Co.,Ltd. Fuyang Branch Pledgor: Anhui shengchenyuan Material Technology Industrial Development Co.,Ltd. Registration number: Y2023980066193 |
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