CN106398102A - Zinc-containing anti-static flame-retardant type car plastic-absorbing material and preparation method thereof - Google Patents
Zinc-containing anti-static flame-retardant type car plastic-absorbing material and preparation method thereof Download PDFInfo
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- CN106398102A CN106398102A CN201610932871.6A CN201610932871A CN106398102A CN 106398102 A CN106398102 A CN 106398102A CN 201610932871 A CN201610932871 A CN 201610932871A CN 106398102 A CN106398102 A CN 106398102A
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L55/00—Compositions of homopolymers or copolymers, obtained by polymerisation reactions only involving carbon-to-carbon unsaturated bonds, not provided for in groups C08L23/00 - C08L53/00
- C08L55/02—ABS [Acrylonitrile-Butadiene-Styrene] polymers
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/017—Additives being an antistatic agent
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/02—Flame or fire retardant/resistant
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/04—Antistatic
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/08—Stabilised against heat, light or radiation or oxydation
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/04—Polymer mixtures characterised by other features containing interpenetrating networks
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Abstract
The invention discloses a zinc-containing anti-static flame-retardant type car plastic-absorbing material and a preparation method thereof. The zinc-containing anti-static flame-retardant type plastic-absorbing material is characterized by taking the following materials: acrylonitrile-butadiene-styrene copolymer (ABS), linear phenolic epoxy resin, microencapsulated red phosphorus, basic magnesium sulfate whisker, nitrile rubber, mesoporous molecular sieve SBA-15, ammonium polyphosphate, melamine formaldehyde resin, kaolin, Sb2O3, dimethyl silicon oil, graphene, zinc oxide, sebacic acid, triphenyl phosphate, polyethylene glycol, styrene-maleic anhydride copolymer, palmitic acid, caprolactam, a silane coupling agent KH-560 and the like. The zinc-containing anti-static flame-retardant type plastic-absorbing material disclosed by the invention has the advantages that mesoporous molecular sieves and the linear phenolic epoxy resin generate bonding action, so that the heat stability of matrix resin is improved; the microencapsulated ammonium polyphosphate and antimony oxide/kaolin composite flame-retardant micropowder generate a synergistic effect, so that the flame-retardant effect is better; the graphene is added into the ABS resin matrix, so that the flame retardance and the heat stability of the resin are obviously improved, and the mechanical property is also higher; and the zinc-containing anti-static flame-retardant type car plastic-absorbing material is obtained.
Description
Technical field
The present invention relates to the field of fire-proof technology of composite is and in particular to a kind of anti-electrostatic fire retardant type automobile containing zinc is inhaled
Moulding material, and its preparation technology.
Background technology
The terpolymer that ABS is made up of acrylonitrile, butadiene and styrene, as a kind of thermoplastic engineering plastic,
With its excellent mechanical property, chemical inertness and workability, it is widely used in auto industry, electronics, electrical equipment, weaving, device
The field such as tool and building materials.But the fire resistance of ABS resin is poor, how to find a kind of additive, ABS resin can be made
While fire resistance is improved, and so that the premium properties of itself is reduced, become the focus of research.
Yang Bing is in Master's thesis《Research based on linear phenol-aldehyde resin and microcapsule red phosphorus halogen-free flame retardant ABS》Profit in one literary composition
With the low cigarette of low toxicity, high temperature resistant, high fixing carbon, economical and efficient linear phenol-aldehyde resin as carbon forming agent, with microencapsulated powder oil association
With fire-retardant, with alkali magnesium sulfate crystal whisker as inorganic combustion inhibitor, the preferable nitrile rubber with ABS matrix compatibility has been selected to be increased
Tough modification, sequentially adds antioxidant and mixed uniformly line style after plastifying ABS in 180 DEG C of the two-roll mill during experiment
Phenolic resin, microcapsule red phosphorus, inorganic combustion inhibitor alkali magnesium sulfate crystal whisker, nitrile rubber blends, knead uniformly rear discharging simultaneously
It is positioned in mould, hot pressing 10 minutes on 180 DEG C of vulcanizing press, then colds pressing at room temperature 10 minutes, depanning is obtained
Modified ABS plastic sheet material, but it is not enough to there is flame retardant effect.
The present invention on this basis, produces bonded effect by mesopore molecular sieve with linear phenolic resin, and strand runs through
Inside and outside the duct of mesopore molecular sieve, form organic-inorganic hybrid material, improve matrix resin heat endurance；With in-situ polymerization
Method is prepared for microencapsulation APP, is prepared for Ultrafine Antimony-Oxide/Kaolin Composite Powder with ball-milling method, and Graphene is added to
Hence it is evident that improve anti-flammability and the heat endurance of resin in ABS resin matrix, mechanical property is also higher；Prepared zinc-containing polyether ester
Acid amides anti-static material, obtains a kind of anti-electrostatic fire retardant type automobile plastic uptake material containing zinc.
Content of the invention
The invention mainly solves the technical problem of provide a kind of anti-electrostatic fire retardant type automobile plastic uptake material containing zinc and its
Preparation technology, has light weight, heat-resisting, fire protection flame retarding, anlistatig premium properties according to the automobile plastic uptake material that this technique makes.
The technical problem to be solved to be realized using following technical scheme：
Acrylonitrile-butadiene-styrene copolymer (ABS) 42-50, linear phenol-aldehyde resin 6-10, microcapsule red phosphorus 4-10, alkali
Formula magnesium sulfate crystal whisker 3-4, nitrile rubber 2-4, mesoporous molecular sieve SBA-15 3-10, APP 4-10, melamino-formaldehyde tree
Fat 2-4, kaolin 1-3, Sb2O33-8, dimethicone 1-2, Graphene 4-8, zinc oxide 1-5, decanedioic acid 2-3, phosphoric acid triphen
Ester 0.1-0.5, polyethylene glycol 1-3, styrene-maleic anhydride copolymer 1-2, palmitic acid 0.1-0.4, caprolactam 1-2, silane
Coupling agent KH-560 0.5-1, ethanol, distilled water, acetic acid, acetone in proper.
A kind of preparation method of the anti-electrostatic fire retardant type automobile plastic uptake material containing zinc is it is characterised in that enter according to the following steps
OK：
A. mesoporous molecular sieve SBA-15 is mixed with linear phenol-aldehyde resin, after reaction 1-3h at 180-190 DEG C,
Add microcapsule red phosphorus, continue reaction 1-2h, product is placed in absolute ethyl alcohol, 25-40 DEG C of stirring 10-12h, second
Alcohol dissolves unreacted resin, filters, alcohol is washed, dry hybrid material；
B. in APP 1:2-3 adds ethanol and distilled water, after dispersed with stirring 10-30min, adds melamino-formaldehyde
Resin, adjusting pH with acetic acid is 4-5, is warming up to 80-90 DEG C of stirring reaction 2-3h, suction filtration, washing, dry not exclusively cladding micro-
Encapsulated APP；
C. kaolin is ground washing and calcine 1-2h after 600-900 DEG C, and Sb2O3Mixing, is placed in water ultrasonic disperse and makes
Slurries, put into baking oven after ball milling 4-6h, in 110-130 DEG C of drying 5-8h, obtain composite micro-powder, and it is mixed with resulting material in b
Uniformly, dimethicone, whip modified 15-60min, suction filtration, washing, dry composite flame-retardant agent are added at 60-120 DEG C；
D. ABS resin is added to plasticizing in 180-190 DEG C of two-roll mill, becomes after molten condition after ABS resin, then plus
Enter the hybrid material obtaining in Graphene and a, after mixing 10-40min, material must be kneaded；
E. by zinc oxide, decanedioic acid, triphenyl phosphate mixed dissolution in acetone, in 30-50 DEG C of isothermal reaction 1-2h, then plus
Enter polyethylene glycol, styrene-maleic anhydride copolymer, palmitic acid, in 140-170 DEG C of isothermal reaction 2-4h, product is washed, takes out
After filter, mix with resulting material in caprolactam, d and silane coupler KH-560, in N23- is reacted in 230-260 DEG C under protection
5h, decompression vacuum pumping 1-2h, obtain anti-static material containing zinc；
F. resulting material in c, e and other residual components are blended at 185-195 DEG C, knead uniformly rear discharging and be positioned over
In mould, hot pressing 10-30min on 180-190 DEG C of vulcanizing press, then the 10-30min that colds pressing at room temperature, depanning is obtained
Modified ABS plastic sheet material, that is, obtain a kind of anti-electrostatic fire retardant type automobile plastic uptake material containing zinc.
The reaction mechanism of the present invention and having the beneficial effect that：
（1）Mesopore molecular sieve/linear phenol-aldehyde resin organic-inorganic hybrid material, linear phenol are prepared for by the method for in-situ polymerization
Urea formaldehyde is distributed in inside and outside mesopore molecular sieve duct, and there is bonded effect with SBA-15, forms organic-inorganic interpenetrating networks knot
Structure, improves matrix resin heat endurance.
（2）Microencapsulation APP is prepared with situ aggregation method（MCAPP）, APP after cladding, can be significantly reduced
（APP）Water solubility and hygroscopicity, improve the resistance to leaching and limited oxygen index of material, melamine resin（MF）
There is good synergy with APP, in the case of APP cladding is incomplete, can more effectively play both interactions,
Improve the anti-flammability of composite.
（3）It is prepared for Sb with ball-milling method2O3/ kaolin composite flame-proof micro mist, Sb2O3Belong to additive flame retardant, with stibium trioxide
Based on powder, kaolin is attached to stibium trioxide powder surface, and abundant and stibium trioxide powder occurs physics, chemical action；
It is used in combination with APP, produce cooperative effect, flame retardant effect is more preferably.
（4）Graphene, as the new lover in material with carbon element family, has incomparably excellent performance, can as the additive of ABS,
Graphene is added in ABS resin matrix hence it is evident that improve anti-flammability and the heat endurance of resin, mechanical property is also higher.
（5）Decanedioic acid, polyethylene glycol, caprolactam polymerisation generate polyether ester amides, with phenylethylene-maleic anhydride altogether
Polymers be compatilizer, with triphenyl phosphate as heat stabilizer, with palmitic acid as lubricant, add silane coupler KH-560,
Zinc oxide, obtains zinc-containing polyether ester amides anti-static material；Have that sheet resistance is low, permanent anti-static, of light color and mechanical property
The good advantage of energy, and nontoxic pollution-free, moulding process are simple, have wide practical use.
Specific embodiment
In order that technological means, creation characteristic, reached purpose and effect that the present invention realizes are easy to understand, tie below
Close specific embodiment, the present invention is expanded on further.
Embodiment
A kind of anti-electrostatic fire retardant type automobile plastic uptake material containing zinc, is obtained by the raw material of following weight parts (g)：
Acrylonitrile-butadiene-styrene copolymer (ABS) 46, linear phenol-aldehyde resin 6, microcapsule red phosphorus 4, alkali magnesium sulfate is brilliant
Palpus 3, nitrile rubber 2, mesoporous molecular sieve SBA-15 6, APP 4, melamine resin 2, kaolin 1, Sb2O33, two
Methyl-silicone oil 1, Graphene 4, zinc oxide 5, decanedioic acid 2, triphenyl phosphate 0.1, polyethylene glycol 1, styrene-maleic anhydride copolymer
Thing 2, palmitic acid 0.1, caprolactam 2, silane coupler KH-560 0.5, ethanol, distilled water, acetic acid, acetone in proper.
A kind of preparation method of the anti-electrostatic fire retardant type automobile plastic uptake material containing zinc is it is characterised in that enter according to the following steps
OK：
A. mesoporous molecular sieve SBA-15 is mixed with linear phenol-aldehyde resin, after reaction 1h at 180 DEG C, adds microcapsule red phosphorus,
Continue reaction 2h, product is placed in absolute ethyl alcohol, 40 DEG C of stirring 10h, ethanol dissolves unreacted resin, filtration, alcohol
Wash three times, dry hybrid material；
B. in APP 1:2 add ethanol and distilled water, after dispersed with stirring 10min, add melamine resin,
Adjust pH to 5 with acetic acid, be warming up to 80 DEG C of stirring reactions 3h, suction filtration, washing, the microencapsulation polyphosphoric acid of dry not exclusively cladding
Ammonium；
C. kaolin is ground washing and calcine 1h after 750 DEG C, and Sb2O3Mixing, is placed in water ultrasonic disperse and makes slurries,
Put into baking oven after ball milling 4h, in 130 DEG C of dryings 5h, obtain composite micro-powder, it is mixed with resulting material in b, at 80 DEG C
Add dimethicone, whip modified 30min, suction filtration, washing, dry composite flame-retardant agent；
D. ABS resin is added to plasticizing in 185 DEG C of two-roll mill, becomes after molten condition after ABS resin, add stone
The hybrid material obtaining in black alkene and a, must knead material after mixing 20min；
E. by zinc oxide, decanedioic acid, triphenyl phosphate mixed dissolution in acetone, in 40-50 DEG C of isothermal reaction 1h, add
Polyethylene glycol, styrene-maleic anhydride copolymer, palmitic acid, in 160-170 DEG C of isothermal reaction 2h, product are washed, suction filtration
Afterwards, mix with resulting material in caprolactam, d and silane coupler KH-560, in N25h is reacted in 250-260 DEG C under protection,
Decompression vacuum pumping 1h, obtains anti-static material containing zinc；
F. resulting material in c, e and other residual components are blended at 185-195 DEG C, knead uniformly rear discharging and be positioned over
In mould, hot pressing 30min on 180-190 DEG C of vulcanizing press, then the 30min that colds pressing at room temperature, depanning is obtained modified
ABS plastic sheet material, that is, obtain a kind of anti-electrostatic fire retardant type automobile plastic uptake material containing zinc.
A kind of performance test results of anti-electrostatic fire retardant type automobile plastic uptake material containing zinc of above-described embodiment preparation are as follows
Shown：
The vertical combustion performance of flame-proof ABS reaches UL-94 V-0 level, LOI value 25-35%, carbon yield (600 DEG C) 15-20%, and stretching is strong
Degree reaches 40MPa, and notch impact strength is 25 KJ/m2, elongation at break 40%, sheet resistance 2 × 10-10Ω.
Claims (2)
1. a kind of anti-electrostatic fire retardant type automobile plastic uptake material containing zinc is it is characterised in that be obtained by the raw material of following weight parts：
Acrylonitrile-butadiene-styrene copolymer (ABS) 42-50, linear phenol-aldehyde resin 6-10, microcapsule red phosphorus 4-10, alkali
Formula magnesium sulfate crystal whisker 3-4, nitrile rubber 2-4, mesoporous molecular sieve SBA-15 3-10, APP 4-10, melamino-formaldehyde tree
Fat 2-4, kaolin 1-3, Sb2O33-8, dimethicone 1-2, Graphene 4-8, zinc oxide 1-5, decanedioic acid 2-3, phosphoric acid triphen
Ester 0.1-0.5, polyethylene glycol 1-3, styrene-maleic anhydride copolymer 1-2, palmitic acid 0.1-0.4, caprolactam 1-2, silane
Coupling agent KH-560 0.5-1, ethanol, distilled water, acetic acid, acetone in proper.
2. the preparation method of a kind of anti-electrostatic fire retardant type automobile plastic uptake material containing zinc according to claim 1, its feature
It is, carry out according to the following steps：
Mesoporous molecular sieve SBA-15 is mixed with linear phenol-aldehyde resin, after reaction 1-3h at 180-190 DEG C, adds microcapsules red
Phosphorus, continues reaction 1-2h, product is placed in absolute ethyl alcohol, 25-40 DEG C of stirring 10-12h, and ethanol dissolves unreacted tree
Fat, filters, alcohol is washed, dry hybrid material；
B. in APP 1:2-3 adds ethanol and distilled water, after dispersed with stirring 10-30min, adds melamino-formaldehyde
Resin, adjusting pH with acetic acid is 4-5, is warming up to 80-90 DEG C of stirring reaction 2-3h, suction filtration, washing, dry not exclusively cladding micro-
Encapsulated APP；
C. kaolin is ground washing and calcine 1-2h after 600-900 DEG C, and Sb2O3Mixing, is placed in water ultrasonic disperse and makes
Slurries, put into baking oven after ball milling 4-6h, in 110-130 DEG C of drying 5-8h, obtain composite micro-powder, and it is mixed with resulting material in b
Uniformly, dimethicone, whip modified 15-60min, suction filtration, washing, dry composite flame-retardant agent are added at 60-120 DEG C；
D. ABS resin is added to plasticizing in 180-190 DEG C of two-roll mill, becomes after molten condition after ABS resin, then plus
Enter the hybrid material obtaining in Graphene and a, after mixing 10-40min, material must be kneaded；
E. by zinc oxide, decanedioic acid, triphenyl phosphate mixed dissolution in acetone, in 30-50 DEG C of isothermal reaction 1-2h, then plus
Enter polyethylene glycol, styrene-maleic anhydride copolymer, palmitic acid, in 140-170 DEG C of isothermal reaction 2-4h, product is washed, takes out
After filter, mix with resulting material in caprolactam, d and silane coupler KH-560, in N23- is reacted in 230-260 DEG C under protection
5h, decompression vacuum pumping 1-2h, obtain anti-static material containing zinc；
F. resulting material in c, e and other residual components are blended at 185-195 DEG C, knead uniformly rear discharging and be positioned over
In mould, hot pressing 10-30min on 180-190 DEG C of vulcanizing press, then the 10-30min that colds pressing at room temperature, depanning is obtained
Modified ABS plastic sheet material, that is, obtain a kind of anti-electrostatic fire retardant type automobile plastic uptake material containing zinc.
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Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107141534A (en) * | 2017-07-10 | 2017-09-08 | 合肥雄川机械销售有限公司 | A kind of preparation method of hay mover rubber accessory |
| CN107987541A (en) * | 2017-12-11 | 2018-05-04 | 山西省交通科学研究院 | A kind of bio-based fire-retardant modified asphalt and preparation method thereof |
| CN108148170A (en) * | 2017-12-25 | 2018-06-12 | 桐城市祥泰塑业有限公司 | A kind of flame-proof cross-linking nylon fire proofing material and preparation method thereof |
Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101338201A (en) * | 2007-07-03 | 2009-01-07 | 东丽纤维研究所（中国）有限公司 | Organic-inorganic composite flame retardants with mesoporous molecular sieve and method for preparing same |
| CN101845197A (en) * | 2009-03-25 | 2010-09-29 | 上海锦湖日丽塑料有限公司 | High-performance halogen-free flame retardant ABS modified resin and preparation method thereof |
| CN101864141A (en) * | 2010-06-13 | 2010-10-20 | 华东理工大学 | Modified ABS antistatic material and preparation method thereof |
| CN102504475A (en) * | 2011-11-30 | 2012-06-20 | 华南理工大学 | Halogen-free flame retardant containing linear phenolic aldehyde and polymer material containing halogen-free flame retardant |
| CN103396647A (en) * | 2013-08-15 | 2013-11-20 | 常州汉邦工程塑料有限公司 | Anti-ultraviolet low-smoke fire retardation ABS resin for school buses, and preparation method thereof |
-
2016
- 2016-10-25 CN CN201610932871.6A patent/CN106398102A/en active Pending
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101338201A (en) * | 2007-07-03 | 2009-01-07 | 东丽纤维研究所（中国）有限公司 | Organic-inorganic composite flame retardants with mesoporous molecular sieve and method for preparing same |
| CN101845197A (en) * | 2009-03-25 | 2010-09-29 | 上海锦湖日丽塑料有限公司 | High-performance halogen-free flame retardant ABS modified resin and preparation method thereof |
| CN101864141A (en) * | 2010-06-13 | 2010-10-20 | 华东理工大学 | Modified ABS antistatic material and preparation method thereof |
| CN102504475A (en) * | 2011-11-30 | 2012-06-20 | 华南理工大学 | Halogen-free flame retardant containing linear phenolic aldehyde and polymer material containing halogen-free flame retardant |
| CN103396647A (en) * | 2013-08-15 | 2013-11-20 | 常州汉邦工程塑料有限公司 | Anti-ultraviolet low-smoke fire retardation ABS resin for school buses, and preparation method thereof |
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107141534A (en) * | 2017-07-10 | 2017-09-08 | 合肥雄川机械销售有限公司 | A kind of preparation method of hay mover rubber accessory |
| CN107141534B (en) * | 2017-07-10 | 2019-05-21 | 江苏南翔橡胶制品有限公司 | A kind of preparation method of grass trimmer rubber accessory |
| CN107987541A (en) * | 2017-12-11 | 2018-05-04 | 山西省交通科学研究院 | A kind of bio-based fire-retardant modified asphalt and preparation method thereof |
| CN107987541B (en) * | 2017-12-11 | 2020-04-24 | 山西省交通科学研究院 | Bio-based flame-retardant modified asphalt and preparation method thereof |
| CN108148170A (en) * | 2017-12-25 | 2018-06-12 | 桐城市祥泰塑业有限公司 | A kind of flame-proof cross-linking nylon fire proofing material and preparation method thereof |
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Application publication date: 20170215 |