CN106398092A - Packaging winding film - Google Patents
Packaging winding film Download PDFInfo
- Publication number
- CN106398092A CN106398092A CN201610760946.7A CN201610760946A CN106398092A CN 106398092 A CN106398092 A CN 106398092A CN 201610760946 A CN201610760946 A CN 201610760946A CN 106398092 A CN106398092 A CN 106398092A
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- Prior art keywords
- temperature
- packaging
- wound around
- area
- film
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Classifications
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L55/00—Compositions of homopolymers or copolymers, obtained by polymerisation reactions only involving carbon-to-carbon unsaturated bonds, not provided for in groups C08L23/00 - C08L53/00
- C08L55/02—ABS [Acrylonitrile-Butadiene-Styrene] polymers
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C48/00—Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor
- B29C48/25—Component parts, details or accessories; Auxiliary operations
- B29C48/92—Measuring, controlling or regulating
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B65—CONVEYING; PACKING; STORING; HANDLING THIN OR FILAMENTARY MATERIAL
- B65D—CONTAINERS FOR STORAGE OR TRANSPORT OF ARTICLES OR MATERIALS, e.g. BAGS, BARRELS, BOTTLES, BOXES, CANS, CARTONS, CRATES, DRUMS, JARS, TANKS, HOPPERS, FORWARDING CONTAINERS; ACCESSORIES, CLOSURES, OR FITTINGS THEREFOR; PACKAGING ELEMENTS; PACKAGES
- B65D65/00—Wrappers or flexible covers; Packaging materials of special type or form
- B65D65/38—Packaging materials of special type or form
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C2948/00—Indexing scheme relating to extrusion moulding
- B29C2948/92—Measuring, controlling or regulating
- B29C2948/92504—Controlled parameter
- B29C2948/92704—Temperature
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2203/00—Applications
- C08L2203/16—Applications used for films
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/14—Polymer mixtures characterised by other features containing polymeric additives characterised by shape
- C08L2205/16—Fibres; Fibrils
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Mechanical Engineering (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Manufacture Of Macromolecular Shaped Articles (AREA)
- Wrappers (AREA)
Abstract
The invention discloses a packaging winding film, which is prepared from acrylonitrile-butadiene-styrene, aramid fiber, surface modified mineral fiber, polyurethane, a plasticizer and a stabilizer as the raw materials. Specifically, the surface modified mineral fiber is prepared by adding TES into chloroform with suspending mineral fiber, and conducting shocking, standing, washing and drying. The packaging winding film is prepared by mechanical mixing, double-screw high temperature extrusion, and film casting by virtue of a melt casting machine. The packaging winding film provided by the invention has the advantages of simple preparation process, low cost, excellent tensile performance and penetration resistance, and excellent self-adhesion.
Description
Technical field
The invention belongs to field of packaging material, it is related to a kind of membrane material, more particularly, to a kind of packaging is wound around film.
Background technology
With the progress of expanding economy and society, people are wound around to the various stretchings in harness, packaging and cladding operation
The demand of film is increasing.Being wound around film, to have a tensile property good, and tear-resistant, penetration-resistant is strong, and transparency is high, autohension good and
Relaxation shrinkage is high, and packaging closely, the features such as will not be loose, be at home and abroad widely used in packaging market in recent years, be related to chemical industry and produce
Application is tied up in the packing such as product, electronic product case, ceramic product, electromechanical equipment.
At present, more than the conventional winding film of application on market, polrvinyl chloride is had using expressing technique processing, its primary raw material
(PVC), Low Density Polyethylene, vinyl-ester acid ethylene copolymer, linear low density of polyethylene, polybutadiene etc. have viscoelasticity
High polymer.These have a case that the high polymer of autohension is inter-adhesive when using and produce so that being wound around film than more serious
During, film production is unstable, and product quality is uneven.It is wound around tensile strength and the anti-puncture poor-performing of membrane material, and raw
Produce relatively costly.
Therefore, it is necessary to the significantly more efficient method of demand, develop that with low cost, tensile property is good, penetration-resistant is strong, from
The good novel package of viscosity is wound around film.
Content of the invention
In order to overcome defect of the prior art, a kind of open packaging of the present invention is wound around film, and this packaging is wound around film preparation work
Skill is simple, with low cost, has excellent tensile property and penetration performance, and self-adhesion is good.
For reaching object above, the technical solution used in the present invention is:
A kind of packaging is wound around film, is to be divided into raw material to be prepared from the group of following weight portion:
Wherein, the mineral fibres of described surface modification is to be suspended with ore deposit by being added to Pehanorm base ethyl sulfonic acid
In the chloroform of fibres, through shaking, standing, clean, drying is prepared from.
As a kind of preferred implementation, the preparation method of the mineral fibres of described surface modification is:By trihydroxy methyl first
Amido ethyl sulfonic acid is added in the chloroform being suspended with a diameter of 5-20 μm of mineral fibres, after ultrasonic wave concussion 20-40min, standing
20-30min, takes out, and is cleaned with chloroform, is placed in 70-80 DEG C of vacuum drying oven and 12-24h is dried, obtain the ore deposit of surface modification
Fibres.
It is preferred that Pehanorm base ethyl sulfonic acid is 1 with the mass ratio of mineral fibres: (2-4), mineral fibres and chloroform
Mass ratio be 1: (3-5).
Preferably, described plasticizer is in epoxy soybean oil, dioctyl phthalate, diisononyl phthalate
One or more
Preferably, described stabilizer is dibutyl tin laurate, maleic acid tin octylate, dibasic lead stearate, disalt
One or more of base lead phthalate, dibasic lead phosphite.
Wherein, acrylonitrile-butadiene-styrene (ABS) has excellent mechanical performance, pliability, and its puncture-resistant intensity is high,
But its viscoelasticity has much room for improvement, polyurethane is the preferable material of a class viscoelasticity, with the acrylonitrile-butadiene-styrene (ABS) compatibility
Preferably, can substitute polrvinyl chloride (PVC), Low Density Polyethylene, vinyl-ester acid ethylene copolymer, linear low density of polyethylene,
The use of the convenient source such as polybutadiene, can reduces cost to a certain extent, acrylonitrile-butadiene-styrene (ABS) can be given again
Preferably viscoelasticity;Polyurethane is compounded with acrylonitrile-butadiene-styrene (ABS) and fiber, can also reduce polyurethane when using
Inter-adhesive probability;The addition of the mineral fibres of aramid fiber and surface modification, is on the one hand conducive to improving the anti-of winding film
Drawing-die amount, contractility and tear resistance;On the one hand, modify in mineral fiber surfaces and contain amino and sulfonic organic group
Group, the amino group amino similar on polyurethane has the preferable compatibility, and can be with the end group acyl group of poly- aramid fiber
Learn bonded, sulfonic group, in high temperature casting film-forming, can be occurred with the phenyl of poly- aramid fiber and acrylonitrile-butadiene-styrene (ABS)
Chemical bonding, the catalyst that mineral fibres can react as this again, the main component of whole film bonded together so that final
The winding membrane structure being formed is compact, and viscoelasticity is good, and mechanical performance is excellent, and tear resistance is excellent;On the other hand, to mineral fibres
Surface modification, can promote organic and inorganic mutually compatible, be conducive to cryogenic tensile, improve the flexibility being wound around film and tear resistance.
The invention also discloses above-mentioned packaging is wound around the preparation method of film, it is achieved by the steps of:
1) raw material of corresponding weight portion is added in mixer and carry out mechanical type mixing, with the speed of 800-1200r/min
Stirring mixing 50-70min, obtains material A;
2) high temperature extrusion process is carried out to material A using double screw extruder, obtain material B, in pairs screw extruding temperature
It is divided into seven areas, first area's temperature is 175-185 DEG C, second area's temperature is 195-205 DEG C, the 3rd area's temperature is 215-225 DEG C,
4th area's temperature is 237-243 DEG C, and the 5th area's temperature is 246-253 DEG C, and the 6th area's temperature is 253-256 DEG C, SECTOR-SEVEN temperature
For 253-260 DEG C;
3) with melt casting machine, casting film-forming is carried out to material B, casting temperature is 200-220 DEG C, is cooled to temperature after curtain coating
25-30 DEG C of degree, prepares packaging and is wound around film.
The present invention compared with prior art, has advantages below and beneficial effect:
(1) packaging that the present invention provides is wound around film, and manufacturing process is simple, raw material is easy to get, easily operation, the requirement to equipment
Not high, with low cost;
(2) packaging that the present invention provides is wound around film, has excellent tensile property and penetration performance, and self-adhesion
Good.
Specific embodiment
Hereinafter describe for disclosing the present invention so that those skilled in the art are capable of the present invention.Excellent in below describing
Embodiment is selected to be only used as illustrating, it may occur to persons skilled in the art that other obvious modifications.
Raw material used in the following embodiment of the present invention comes from Haiquan sunrise foreign trade company limited.
Embodiment 1
A kind of packaging is wound around film, is to be divided into raw material to be prepared from the group of following weight portion:
Wherein, the preparation method of the mineral fibres of described surface modification, is achieved by the steps of:By 100g tri- hydroxyl
Methyl methylamino ethyl sulfonic acid is added in the 1000g chloroform being suspended with a diameter of 5 μm of mineral fibres of 200g, ultrasonic wave concussion
20min, stands 20min afterwards again, takes out, and after being cleaned with chloroform, 24h is dried, obtains table at placing 70 DEG C in vacuum drying oven
The mineral fibres that face is modified.
A kind of packaging is wound around the preparation method of film, comprises the steps:
1) raw material of corresponding weight portion is added in mixer and carry out mechanical type mixing, mixed with the speed stirring of 800r/min
Close 70min, obtain material A;
2) high temperature extrusion process is carried out to material A using double screw extruder, obtain material B, twin-screw extruder temperature is divided
For seven areas, first area's temperature is 180 DEG C, and second area's temperature is 200 DEG C, and the 3rd area's temperature is 220 DEG C, and the 4th area's temperature is
240 DEG C, the 5th area's temperature is 250 DEG C, and the 6th area's temperature is 255 DEG C, and SECTOR-SEVEN temperature is 255 DEG C;
3) with melt casting machine, casting film-forming is carried out to material B, casting temperature is 200 DEG C, is cooled to temperature 25 after curtain coating
DEG C, prepare packaging and be wound around film.
Embodiment 2
A kind of packaging is wound around film, is to be divided into raw material to be prepared from the group of following weight portion:
Wherein, the preparation method of the mineral fibres of described surface modification, is achieved by the steps of:By 100g tri- hydroxyl
Methyl methylamino ethyl sulfonic acid is added in the 1200g chloroform being suspended with a diameter of 10 μm of mineral fibres of 300g, ultrasonic wave concussion
30min, stands 25min afterwards again, takes out, and after being cleaned with chloroform, 18h is dried, obtains table at placing 75 DEG C in vacuum drying oven
The mineral fibres that face is modified.
A kind of packaging is wound around the preparation method of film, comprises the steps:
1) raw material of corresponding weight portion is added in mixer and carry out mechanical type mixing, with the speed stirring of 1000r/min
Mixing 56min, obtains material A;
2) high temperature extrusion process is carried out to material A using double screw extruder, obtain material B, twin-screw extruder temperature is divided
For seven areas, first area's temperature is 175 DEG C, and second area's temperature is 195 DEG C, and the 3rd area's temperature is 215 DEG C, and the 4th area's temperature is
237 DEG C, the 5th area's temperature is 246 DEG C, and the 6th area's temperature is 253 DEG C, and SECTOR-SEVEN temperature is 253 DEG C;
3) with melt casting machine, casting film-forming is carried out to material B, casting temperature is 210 DEG C, is cooled to temperature 25 after curtain coating
DEG C, prepare packaging and be wound around film.
Embodiment 3
A kind of packaging is wound around film, is to be divided into raw material to be prepared from the group of following weight portion:
Wherein, the preparation method of the mineral fibres of described surface modification, is achieved by the steps of:By 100g tri- hydroxyl
Methyl methylamino ethyl sulfonic acid is added in the 1500g chloroform being suspended with a diameter of 15 μm of mineral fibres of 400g, ultrasonic wave concussion
35min, stands 26min afterwards again, takes out, and after being cleaned with chloroform, 21h is dried, obtains table at placing 77 DEG C in vacuum drying oven
The mineral fibres that face is modified.
A kind of packaging is wound around the preparation method of film, comprises the steps:
1) raw material of corresponding weight portion is added in mixer and carry out mechanical type mixing, with the speed stirring of 1100r/min
Mixing 60min, obtains material A;
2) high temperature extrusion process is carried out to material A using double screw extruder, obtain material B, twin-screw extruder temperature is divided
For seven areas, first area's temperature is 185 DEG C, and second area's temperature is 205 DEG C, and the 3rd area's temperature is 225 DEG C, and the 4th area's temperature is
243 DEG C, the 5th area's temperature is 253 DEG C, and the 6th area's temperature is 256 DEG C, and SECTOR-SEVEN temperature is 260 DEG C;
3) with melt casting machine, casting film-forming is carried out to material B, casting temperature is 215 DEG C, is cooled to temperature 30 after curtain coating
DEG C, prepare packaging and be wound around film.
Embodiment 4
A kind of packaging is wound around film, is to be divided into raw material to be prepared from the group of following weight portion:
Wherein, the preparation method of the mineral fibres of described surface modification, is achieved by the steps of:By 100g tri- hydroxyl
Methyl methylamino ethyl sulfonic acid is added in the 2000g chloroform being suspended with a diameter of 20 μm of mineral fibres of 400g, ultrasonic wave concussion
40min, stands 30min afterwards again, takes out, and after being cleaned with chloroform, 12h is dried, obtains table at placing 80 DEG C in vacuum drying oven
The mineral fibres that face is modified.
A kind of packaging is wound around the preparation method of film, comprises the steps:
1) raw material of corresponding weight portion is added in mixer and carry out mechanical type mixing, with the speed stirring of 1200r/min
Mixing 70min, obtains material A;
2) high temperature extrusion process is carried out to material A using double screw extruder, obtain material B, twin-screw extruder temperature is divided
For seven areas, first area's temperature is 178 DEG C, and second area's temperature is 202 DEG C, and the 3rd area's temperature is 220 DEG C, and the 4th area's temperature is
240 DEG C, the 5th area's temperature is 248 DEG C, and the 6th area's temperature is 254 DEG C, and SECTOR-SEVEN temperature is 257 DEG C;
3) with melt casting machine, casting film-forming is carried out to material B, casting temperature is 220 DEG C, is cooled to temperature 30 after curtain coating
DEG C, prepare packaging and be wound around film.
Comparative example:
A kind of packaging is wound around film, with Low Density Polyethylene as raw material, its preparation method with embodiment 1-4, preparation method
Actual conditions is same as Example 4.
Table 1 various embodiments of the present invention and comparative example's the performance test results
Understand according to table 1, the tensile strength of packaging winding film that various embodiments of the present invention prepare and tearing toughness are equal
It is wound around the performance (tensile strength >=10MPa, tear-resistant power >=18N) of membrane material higher than conventional Low Density Polyethylene, and can
To find, by carrying out preferably to the ratio of composition, the tensile strength of embodiment 4 and tearing toughness highest.
Ultimate principle, principal character and the advantages of the present invention of the present invention have been shown and described above.The technology of the industry
The simply present invention it should be appreciated that the present invention is not restricted to the described embodiments, described in above-described embodiment and description for the personnel
Principle, without departing from the spirit and scope of the present invention the present invention also have various changes and modifications, these change and
Improvement both falls within the range of claimed invention.The protection domain of application claims by appending claims and its
Equivalent defines.
Claims (6)
1. a kind of packaging is wound around film it is characterised in that being to be divided into raw material to be prepared from the group of following weight portion:
Wherein, the mineral fibres of described surface modification is that to be suspended with mineral fine by being added to Pehanorm base ethyl sulfonic acid
In the chloroform of dimension, through shaking, standing, clean, drying is prepared from.
2. packaging as claimed in claim 1 is wound around film it is characterised in that the preparation method of the mineral fibres of described surface modification
For:Pehanorm base ethyl sulfonic acid is added in the chloroform being suspended with a diameter of 5-20 μm of mineral fibres, ultrasonic wave concussion
After 20-40min, stand 20-30min, take out, cleaned with chloroform, be placed in 70-80 DEG C of vacuum drying oven and 12-24h is dried,
Obtain the mineral fibres of surface modification.
3. as claimed in claim 2 packaging be wound around film it is characterised in that:Pehanorm base ethyl sulfonic acid and mineral fibres
Mass ratio is 1: (2-4), mineral fibres is 1 with the mass ratio of chloroform: (3-5).
4. as claimed in claim 1 packaging be wound around film it is characterised in that:Described plasticizer is selected from epoxy soybean oil, adjacent benzene two
One or more of formic acid dioctyl ester, diisononyl phthalate.
5. as claimed in claim 1 packaging be wound around film it is characterised in that:Described stabilizer is dibutyl tin laurate, horse
Come one or more of sour tin octylate, dibasic lead stearate, Dythal, dibasic lead phosphite.
6. as described packaging arbitrary in claim 1-5 is wound around the preparation method of film it is characterised in that being real as follows
Existing:
1) raw material of corresponding weight portion is added in mixer and carry out mechanical type mixing, with the speed stirring of 800-1200r/min
Mixing 50-70min, obtains material A;
2) high temperature extrusion process is carried out to material A using double screw extruder, obtain material B, twin-screw extruder temperature is divided into seven
Individual area, first area's temperature is 175-185 DEG C, and second area's temperature is 195-205 DEG C, and the 3rd area's temperature is 215-225 DEG C, the 4th area
Temperature is 237-243 DEG C, and the 5th area's temperature is 246-253 DEG C, and the 6th area's temperature is 253-256 DEG C, and SECTOR-SEVEN temperature is 253-
260℃;
3) with melt casting machine, casting film-forming is carried out to material B, casting temperature is 200-220 DEG C, is cooled to temperature 25- after curtain coating
30 DEG C, prepare packaging and be wound around film.
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CN201610760946.7A CN106398092B (en) | 2016-08-24 | 2016-08-24 | A kind of packaging winding film |
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CN201610760946.7A CN106398092B (en) | 2016-08-24 | 2016-08-24 | A kind of packaging winding film |
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CN106398092A true CN106398092A (en) | 2017-02-15 |
CN106398092B CN106398092B (en) | 2018-10-26 |
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Cited By (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN107325473A (en) * | 2017-08-08 | 2017-11-07 | 佛山市合宏泰业科技有限公司 | A kind of high-wearing feature composite |
CN107353571A (en) * | 2017-08-08 | 2017-11-17 | 佛山市合宏泰业科技有限公司 | The preparation method of high-wearing feature composite |
CN108892875A (en) * | 2018-05-23 | 2018-11-27 | 湖南辰砾新材料有限公司 | A kind of packaging winding film and preparation method thereof |
CN113801440A (en) * | 2021-07-28 | 2021-12-17 | 泗县绿昂新材料科技有限公司 | Packaging winding film and preparation method thereof |
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Cited By (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN107325473A (en) * | 2017-08-08 | 2017-11-07 | 佛山市合宏泰业科技有限公司 | A kind of high-wearing feature composite |
CN107353571A (en) * | 2017-08-08 | 2017-11-17 | 佛山市合宏泰业科技有限公司 | The preparation method of high-wearing feature composite |
CN107325473B (en) * | 2017-08-08 | 2020-03-31 | 佛山市合宏泰业科技有限公司 | High-wear-resistance composite material |
CN108892875A (en) * | 2018-05-23 | 2018-11-27 | 湖南辰砾新材料有限公司 | A kind of packaging winding film and preparation method thereof |
CN113801440A (en) * | 2021-07-28 | 2021-12-17 | 泗县绿昂新材料科技有限公司 | Packaging winding film and preparation method thereof |
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