CN106396396A - Color-increasing colored glaze suitable for complementing colors in silk screen printing and ceramic tiles prepared by color-increasing colored glaze - Google Patents
Color-increasing colored glaze suitable for complementing colors in silk screen printing and ceramic tiles prepared by color-increasing colored glaze Download PDFInfo
- Publication number
- CN106396396A CN106396396A CN201610798127.1A CN201610798127A CN106396396A CN 106396396 A CN106396396 A CN 106396396A CN 201610798127 A CN201610798127 A CN 201610798127A CN 106396396 A CN106396396 A CN 106396396A
- Authority
- CN
- China
- Prior art keywords
- parts
- glaze
- color
- following component
- including following
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C8/00—Enamels; Glazes; Fusion seal compositions being frit compositions having non-frit additions
- C03C8/14—Glass frit mixtures having non-frit additions, e.g. opacifiers, colorants, mill-additions
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C8/00—Enamels; Glazes; Fusion seal compositions being frit compositions having non-frit additions
- C03C8/02—Frit compositions, i.e. in a powdered or comminuted form
- C03C8/04—Frit compositions, i.e. in a powdered or comminuted form containing zinc
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B41/00—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
- C04B41/45—Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements
- C04B41/52—Multiple coating or impregnating multiple coating or impregnating with the same composition or with compositions only differing in the concentration of the constituents, is classified as single coating or impregnation
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B41/00—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
- C04B41/80—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone of only ceramics
- C04B41/81—Coating or impregnation
- C04B41/89—Coating or impregnation for obtaining at least two superposed coatings having different compositions
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Ceramic Engineering (AREA)
- Materials Engineering (AREA)
- Organic Chemistry (AREA)
- Structural Engineering (AREA)
- Life Sciences & Earth Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Geochemistry & Mineralogy (AREA)
- Finishing Walls (AREA)
Abstract
The invention provides color-increasing colored glaze suitable for complementing colors in silk screen printing and ceramic tiles prepared by the color-increasing colored glaze and belongs to the field of production of building ceramic. The color-increasing colored glaze provided by the invention is prepared from the following components in parts by mass: 12 parts of high-boron-calcium transparent frit, 0.1 to 10 parts of color-complementing pigment, 1.3 part of carboxymethyl cellulose, 45 parts of ethylene glycol and 40 parts of water; the high-boron-calcium transparent frit is prepared from the following chemical components according to weight part of oxide: 6 parts of Na2O, 12 parts of CaO, 7 parts of ZnO, 8 parts of B2O3, 3 parts of Al2O3 and 54 parts of SiO2; the color-complementing pigment is one or a combination of more of public known pigments for colored glaze. By adopting the color-increasing colored glaze provided by the invention, inject printing and silk screen printing manners are combined in the aspect of a process, and printed patterns with abundant and bright colors and lusters can be obtained, so that the quality and commercial additional value of a product are improved.
Description
Technical field
The present invention relates to architectural pottery production field, the increasing pink blossom glaze of more particularly, to a kind of suitable silk screen printing complementary color and making
The Ceramic Tiles prepared with it.
Background technology
Stamp is the Main Means of architectural pottery product incrustation.Stamp can be divided mainly into screen printing, roller printing
With ink-jet printed.Printing technology can make product surface have abundant textured pattern decorative effect, and improving product business is additional
Value.Ink-jet printed at present have become as main flow, but limited to by ink-jet technology and equipment and ink, much colors of higher gray scale
Ink-jet printer is ensureing definition and also can not reach on the premise of steady production at present.
Content of the invention
The present invention is directed in prior art and higher greyscale color is being ensured definition and can guarantee that steady in ink-jet printer
Also do not reach on the premise of fixed production, a kind of increasing pink blossom glaze of suitable silk screen printing complementary color is provided, using this increasing pink blossom glaze, same
When in technique, ink-jet printed and silk screen printing mode is combined, it is possible to obtain color and luster enriches gorgeous decalcomania,
The quality of improving product and business added value.
A kind of increasing pink blossom glaze of suitable silk screen printing complementary color, it is calculated with mass fraction, including following component：High boron is calcareous
Clear frit：12 parts, complementary color colorant 0.1-10 part, carboxymethylcellulose calcium：1.3 parts, ethylene glycol：45 parts, water：40 parts；
The chemical constituent of the calcareous clear frit of above-mentioned high boron is calculated with oxide weight number, including following component：Na2O:
6 parts, CaO:12 parts, ZnO:7 parts, B2O3:8 parts, Al2O3:3 parts, SiO2:54 parts；
Above-mentioned complementary color colorant is one or more combination of known pottery glaze stain.
This is the hair color effect that can ensure chromatography glaze stain using the calcareous clear frit of high boron, simultaneously transparent after its burning
Characteristic, the decalcomania colour generation under it will not be impacted, using this increasing pink blossom glaze, be the face to original decalcomania
Color is supplemented so as to the border texture of pattern is clear, and contrast is strong, and the hardness of this glaze is higher than general transparent
Glaze, preferably can be protected to the decalcomania under it.
The present invention also provides a kind of production technology of Ceramic Tiles, and it comprises the steps：
Step 1) make adobe from known ceramic body powder punching press；
Step 2) in cover-coat enamel known to billet surface charity, form cover coat；
Step 3) ink-jet printed, formation printed layer is carried out on cover coat；
Step 4) in printed layer, the increasing pink blossom glaze for complementary color is printed by screen printing mode, described increasing pink blossom glaze with
Mass fraction calculates, including following component：The calcareous clear frit of high boron：12 parts, complementary color colorant 0.1-10 part, carboxymethyl cellulose
Element：1.3 parts, ethylene glycol：45 parts, water：40 parts；The chemical constituent of the calcareous clear frit of described high boron is in terms of oxide weight number
Calculate, including following component：Na2O:6 parts, CaO:12 parts, ZnO:7 parts, B2O3:8 parts, Al2O3:3 parts, SiO2:54 parts；Described complementary color
Colorant is one or more combination of known pottery glaze stain；
Step 5) enter kiln and fire；
Step 6) base substrate after burning till is polished and edging process, obtain ceramic brick product.
When carrying out printing ornament, for the color of high saturation, it is extremely difficult to corresponding color saturation, therefore in print
It can be carried out after spending with hyperchromic process, complementary color colorant used herein above is the inorganic pigment well known to Production of Ceramics, its choosing
Select and organic assembling can be carried out according to different complementary color effects.Frit used herein is the calcareous clear frit of high boron, frit
In also have higher calcium boron matter raw material, simultaneously also using the zinc oxide of larger consumption, also adjust while promoting pigment color development
Hardness after glaze burning.Here the printing mode increasing pink blossom glaze is preferably after stamp, using consistent with decalcomania texture
Set floral pattern (depending on meshcount is according to the required depth heightening the color and clear patterns degree, mesh number scope is in 80-250
Mesh, bigger using meshcount, pattern definition is higher, but the amplitude that can heighten the color is less；And use the mesh number of silk screen
Less, then the definition of pattern and fine and smooth degree are lower, but the effect that heightens the color can be higher).
Preferably, in above ceramic tile production technique, step 2) and step 3) between also include increasing by silk screen printing
The step of white glaze material, the described glaze that brightens is calculated with mass fraction, including following component：Clear frit：50 parts, zirconium silicate：50
Part, print cream：65 parts, sodium tripolyphosphate：0.3 part, water：35 parts；
The chemical constituent of described clear frit is calculated with oxide weight number, including following component：
Na2O:5 parts, CaO:9 parts, ZnO:8 parts, Al2O3:8 parts, B2O3:2 parts, SiO2:60 parts.
Here zirconium silicate is to brighten Main Ingredients and Appearance, and it is coordinated with the clear frit of speciality, adjusts it using print cream
Printing effect, to reach the effect that base substrate is preferably brightened.Here print cream is the print of commercially available traditional regulation glaze charity effect
Cream, its exemplary group is divided into, and calculates according to the mass fraction：Methyl：1.3 parts, ethylene glycol：35 parts, water：35 parts, preservative：0.001
Part.This brightens glaze, and using clear frit and zirconium silicate as Main Ingredients and Appearance, wherein clear frit is to firing temperature and sintering effect
It is adjusted, zirconium silicate is brightened, combined by both, on the premise of production cost is relatively low, so that the base substrate after burning is had
Higher whiteness, and can be with effective control blank deformation by way of screen printing.
In order to ensure whitening effect, the Ceramic Tiles that produced using it, brightening glaze is by silk screen printing side at least twice
In billet surface, the number of times of silk screen printing is more for formula charity, the glaze layer being correspondingly formed thicker it is however generally that, need to carry out two
Secondary printing, can reach cost whiteness 60-68 degree after burning twice afterwards, can reach 72-78 degree for three times, can reach 80- four times
83 degree.By the way of drenching glaze, whiteness is substantially stationary, and selects the mode of silk screen printing, can print number of times pair by different
After base substrate burns, whiteness is adjusted, and so that process matching width is greatly promoted, in the situation of corresponding difference whiteness demand
Under, it is possible to use lower cost realizes technological requirement.
Preferably, in above-mentioned ceramic tile production technique, step 4) and step 5) between also include cloth and support color fancy glaze
Step, helps color fancy glaze to be formed using serigraphy and helps color fancy glaze layer,
Described help color fancy glaze with mass fraction calculate, including following component：100 parts of high zinc matter frit, prints 130 parts of cream, and three
0.3 part of polyphosphate sodium, 40 parts of water；
The chemical constituent of described high zinc matter frit is calculated with oxide weight number, including following component：
SiO2:53 parts, ZnO:21 parts, K2O:4 parts, Al2O3:7 parts, MgO:3 parts, CaO:3.5 part.
High zinc matter frit has preferable effect to colorant color development, but big amount zinc oxide is used as the marzacotto of raw material
Intensity is poor, the higher potassium matter raw material of high temperature viscosity therefore used in high zinc matter frit, simultaneously its also contain a certain amount of
Calcium magnesia raw material.Cloth supports the step of color fancy glaze after charity increases pink blossom glaze.So help the color fancy glaze not only can be to stamp
Layer carries out helping color color can also be made to have more preferable saturation degree to improving the hyperchromic effect increasing pink blossom glaze.In addition, supporting in cloth
During color fancy glaze, in order to avoid the two tone colour causing because glazed thickness is uneven, carry out mutual reprinting using two sets of full impregnated silk screens
System.
Preferably, in above-mentioned ceramic tile production technique, after color fancy glaze supported by cloth, also include transparent guarantor known to charity
Shield glaze forms protection glaze layer and covers in described printed layer.
Preferably, in above-mentioned ceramic tile production technique, after transparency protected glaze described in charity, brilliant using serigraphy mineral
Body fancy glaze forms mineral crystal fancy glaze layer,
Described mineral crystal fancy glaze is calculated with mass fraction, including following component：
100 parts of mineral crystal dry granular, clear frit 0-50 part, print cream 60-80 part, 0.2 part of carboxymethylcellulose calcium, water 25-40
Part,
The chemical constituent of described mineral crystal dry granular is calculated with oxide weight number, including following component：
SiO2:8,Al2O3:3,B2O3:20,Fe2O3：9, MnO:46,TiO2:8.
Preferably, in above-mentioned ceramic tile production technique, mineral crystal fancy glaze thickeies effect net by 60 mesh and is printed.
Preferably, in above-mentioned ceramic tile production technique, step 5) firing temperature be 1175～1185 DEG C, firing period
For 60～70min.
Compared to the prior art, the complementary color that the present invention provides increases pink blossom glaze, and existing ink-jetting process cannot can be obtained
High gray scale and gorgeous color carry out complementary color, lift product property.
Specific embodiment
Come to the solution of the present invention below by some specific embodiments.
Embodiment 1
The present embodiment provides a kind of increasing pink blossom glaze of suitable silk screen printing complementary color, is calculated with mass fraction, including such as the following group
Point：The calcareous clear frit of high boron：12 parts, complementary color colorant 0.1-10 part, carboxymethylcellulose calcium：1.3 parts, ethylene glycol：45 parts, water：
40 parts；
The chemical constituent of the calcareous clear frit of above-mentioned high boron is calculated with oxide weight number, including following component：Na2O:
6 parts, CaO:12 parts, ZnO:7 parts, B2O3:8 parts, Al2O3:3 parts, SiO2:54 parts；
Above-mentioned complementary color colorant is one or more combination of known pottery glaze stain.
This is the hair color effect that can ensure chromatography glaze stain using the calcareous clear frit of high boron, simultaneously transparent after its burning
Characteristic, the decalcomania colour generation under it will not be impacted, using this increasing pink blossom glaze, be the face to original decalcomania
Color is supplemented so as to the border texture of pattern is clear, and contrast is strong, and the hardness of this glaze is higher than general transparent
Glaze, preferably can be protected to the decalcomania under it.
Embodiment 2
The present embodiment provides a kind of pottery increasing the production of pink blossom glaze of the suitable silk screen printing complementary color of use embodiment 1 offer
Brick, it is included by lower：Green body layer, cover coat, decalcomania layer, increasing pink blossom glaze layer.
Step 1) make adobe from known ceramic body powder punching press；
Step 2) billet surface by drench glaze by way of cover-coat enamel known to charity, formed cover coat；
Step 3) ink-jet printed, formation printed layer is carried out on cover coat；
Step 4) in printed layer, the increasing pink blossom glaze for complementary color is printed by screen printing mode, described increasing pink blossom glaze with
Mass fraction calculates, including following component：The calcareous clear frit of high boron：12 parts, complementary color colorant 0.1-10 part, carboxymethyl cellulose
Element：1.3 part, ethylene glycol：45 parts, water：40 parts；The chemical constituent of the calcareous clear frit of described high boron is in terms of oxide weight number
Calculate, including following component：Na2O:6 parts, CaO:12 parts, ZnO:7 parts, B2O3:8 parts, Al2O3:3 parts, SiO2:54 parts；Described complementary color
Colorant is one or more combination of known pottery glaze stain；
Step 5) enter kiln and fire；
Step 6) base substrate after burning till is polished and edging process, obtain ceramic brick product.
Wherein, described step 1) in blank formulation be common glazed ceramic brick body recipe, here provide one show
The formula of example property.For ensureing the flatness of product and ripple glaze deformation, 21% about, whiteness is on 35 degree left sides for base substrate aluminum content
The right side, it is as follows that its formula presses mass fraction：Yichuan sand：20 parts, Ganzhou low temperature potassium sodium sand：15 parts, mud is washed in Qianshan：16～20 parts,
Guangxi White mud：8 parts, 3 parts of the white mud in Ji'an, Guangchang potassium sand：31 parts, Fuzhou City's bentonite：1 part, black talc：2～3 parts.Using wet method
Ball milling method, Ball-milling Time 11～12 hours；After slurry fineness was 250 mesh sieves, tail over as 1.6～2.0 grams；Blank moisture content
For 6～6.5%, its grain composition：More than 20 mesh 0～1.5%, -20～+40 mesh 30～60%, -20～+60 mesh 72～88%,
0～6% below 100 mesh, remaining is -60～+100 mesh.
Step 2) cover-coat enamel that uses is to ensure product sintering temperature, brick, the common ceramic glaze of effect fancy glaze stereoeffect
The conventional cover-coat enamel of surface ceramic tile, as follows by mass fraction：Potassium feldspar：25 parts, quartz：15～30 parts, nepheline：15～25 parts, forge
Burn kaolin：7 parts, aluminum oxide：10 parts, wollastonite：4 parts, zinc oxide：1 part, zirconium silicate：20 parts, CNH00058：10～15 parts,
Sodium humate：0.2, carboxymethylcellulose calcium:0.2 part, sodium tripolyphosphate：0.15 part, by the way of wet ball grinding, ball milling 4～5
Hour；Cover-coat enamel proportion 1.75～1.85g/cm3, the flow velocity 30-35 second, after crossing 325 mesh sieves, tail over as 3～4 grams.Cover-coat enamel is to base substrate
Covered, reduced the impact to glaze paint for the impurity in base substrate.
It is, of course, also possible to increase pink blossom glaze surface charity layer of transparent protection glaze, form protection glaze layer, so can avoid
The damage to decalcomania for the abrasion in follow-up rubbing down and use.
Here step 5) firing temperature be 1175～1185 DEG C, firing period be 60～70min.
Embodiment 3
The present embodiment provide a kind of suitable silk screen printing brighten glaze, its with mass fraction calculate, including following component：
Clear frit：50 parts, zirconium silicate：50 parts, print cream：65 parts, sodium tripolyphosphate：0.3 part, water：35 parts；
The chemical constituent of described clear frit is calculated with oxide weight number, including following component：
Na2O:5 parts, CaO:9 parts, ZnO:8 parts, Al2O3:8 parts, B2O3:2 parts, SiO2:60 parts.
Here zirconium silicate is to brighten Main Ingredients and Appearance, and it is coordinated with the clear frit of speciality, adjusts it using print cream
Printing effect, to reach the effect that base substrate is preferably brightened.Here print cream is the print of commercially available traditional regulation glaze charity effect
Cream, its exemplary group is divided into, and calculates according to the mass fraction：Methyl：1.3 parts, ethylene glycol：35 parts, water：35 parts, preservative：0.001
Part.This brightens glaze, and with clear frit and zirconium silicate as Main Ingredients and Appearance, wherein clear frit is to firing temperature and sintering effect
It is adjusted, zirconium silicate is brightened, combined by both, on the premise of production cost is relatively low, so that the base substrate after burning is had
Higher whiteness, and can be with effective control blank deformation by way of screen printing.Brighten for illustrating that the present embodiment provides
The advantage of glaze, special offer embodiment 4.Present embodiments provide a kind of Ceramic Tiles producing using this glaze and its preparation work
Skill.
Embodiment 4
A kind of Ceramic Tiles, it by the structure on lower is：Including green body layer, cover coat, brighten glaze layer, decalcomania
Layer, increase pink blossom glaze layer, help color fancy glaze layer, protection glaze layer and mineral crystal fancy glaze layer.
Its preparation technology comprises the steps：
The present invention also provides a kind of production technology of Ceramic Tiles, and it comprises the steps：
Step 1) base raw material through dispensing, ball milling be obtained slurry, then remove iron, sieve, old, powder by spraying after sieve,
Prepared blank；
Step 2) by press, blank is pressed, prepare base substrate；
Step 3) base substrate is put into dry kiln it is dried；
Step 4) carry out charity cover-coat enamel by the way of drenching glaze；
Step 5) glaze is brightened using serigraphy brightened；
Step 6) carry out decorating stamp by ink-jet printing apparatus；
Step 7) color that pink blossom glaze compensates needs reinforcement is increased by serigraphy；
Step 8) help color fancy glaze to help color development by serigraphy；
Step 9) protect glaze layer that ink-jetting pattern is protected by serigraphy；
Step 10) pass through serigraphy mineral crystal fancy glaze；
Step 11) enter kiln and be fired；
Step 12) polishing；
Step 13) edging, quality restriction, packaging obtain final product.
Wherein, the blank formulation in described step 1 is the body recipe of common glazed ceramic brick, provides an example here
The formula of property.For ensureing the flatness of product and ripple glaze deformation, base substrate aluminum content 21% about, whiteness at 35 degree about,
It is as follows that its formula presses mass fraction：Yichuan sand：20 parts, Ganzhou low temperature potassium sodium sand：15 parts, mud is washed in Qianshan：16～20 parts, Guangxi
White mud：8 parts, 3 parts of the white mud in Ji'an, Guangchang potassium sand：31 parts, Fuzhou City's bentonite：1 part, black talc：2～3 parts.Using wet ball grinding
Mode, Ball-milling Time 11～12 hours；After slurry fineness was 250 mesh sieves, tail over as 1.6～2.0 grams；Blank moisture content is 6
～6.5%, its grain composition：More than 20 mesh 0～1.5%, -20～+40 mesh 30～60%, -20～+60 mesh 72～88%, 100
0～6% below mesh, remaining is -60～+100 mesh.
Baking temperature in step 3 is 100～160 DEG C, and arid cycle is 50～70min.Drying is to remove base substrate
In unnecessary moisture content, this guarantee product quality, be typically dried process.
Cover-coat enamel formula in step 4, for ensureing the common porcelain of product sintering temperature, brick, effect fancy glaze stereoeffect
The conventional cover-coat enamel of glazed ceramic brick, as follows by mass fraction：Potassium feldspar：25 parts, quartz：15～30 parts, nepheline：15～25 parts,
Calcined kaolin：7 parts, aluminum oxide：10 parts, wollastonite：4 parts, zinc oxide：1 part, zirconium silicate：20 parts, CNH00058：10～15
Part, sodium humate：0.2, carboxymethylcellulose calcium:0.2 part, sodium tripolyphosphate：0.15 part, by the way of wet ball grinding, ball milling 4
～5 hours；Cover-coat enamel proportion 1.75～1.85g/cm3, the flow velocity 30-35 second, after crossing 325 mesh sieves, tail over as 3～4 grams.Cover-coat enamel is to base
Body is covered, and reduces the impact to glaze paint for the impurity in base substrate.
Brighten fancy glaze in described step 5,80 mesh full impregnated nets are printed using silk-screen printing technique, print twice brighten fancy glaze, burn
After one-tenth, in 60-68 degree, Yin Sandao brightens fancy glaze to finished product whiteness, and in 72-78 degree, Yin Sidao brightens fancy glaze to finished product whiteness, and finished product is white
Degree is in 80-83 degree.Brighten fancy glaze as follows by mass fraction：Clear frit:50 parts, zirconium silicate：50 parts, print cream:65 parts, trimerization phosphorus
Sour sodium：0.3 part, water：35 parts.The glaze slip using after ball milling needs to reach following requirement：325 mesh sieves tail over 0.05-0.1%, than
1.55-1.58 gram/cc of weight.The composition of clear frit is following (calculating of oxide mass number):Na2O:5 parts, CaO:9
Part, ZnO:8,Al2O3:8 parts, B2O3:2 parts, SiO2:60 parts.Print cream is that common fancy glaze print cream (is chosen as Dow in the present embodiment
The DS4003 of science and technology), it is counted as point as follows according to the mass fraction：Carboxymethylcellulose calcium：1.3 parts, ethylene glycol：35 parts, water：35 parts,
Preservative：0.001 part.
Brighten mode in view of glaze for glazed tile, can by improve base substrate whiteness and raising cover-coat enamel whiteness reach similar
Effect, brightens mode around these three in experimentation and does a lot of work.
The serial example 1 of contrast：Under the experiment condition of fixing step 2,3,4,5,6,7,8,9,10,11,12,13, only to step
Base substrate whiteness in rapid 1 is adjusted, and draws following table：
Base substrate is the basis of product, and its deformation has a direct impact to follow-up finished product glacing flatness and ripple glaze, by adopting
Selected raw material can improve finished product whiteness to a certain extent, but raw material is required too high.Also indivedual enterprises are had to be to reach in industry
To preferable base substrate whiteness, to be realized by slow burning (reducing more than half yield), thus can relax to base substrate composition
Require, the problems such as without excessively considering the deformation producing due to due to base substrate composition, a large amount of blank raw materials using high whiteness,
But because yield is too low, cost input is too big, also do not reach preferable whiteness simultaneously.Adjust the mode of whiteness using body recipe
Sexual valence is poor.
The serial example 2 of contrast：Under the experiment condition of fixing step 1,2,3,5,6,7,8,9,10,11,12,13, only to step
Cover-coat enamel formula in rapid 4 is adjusted, simultaneously remaining component in fixing step 4, only the zirconium silicate to impact whiteness most critical
Number be adjusted, draw following table：
| Zirconium silicate number in cover-coat enamel | Finished product whiteness | Cost | Finished product deforms (mm) |
| 10 | 42 | 0.6 yuan/square metre | Positive and negative 0.1 |
| 20 | 51 | 1.2 yuan/square metre | Positive 0.2 |
| 30 | 56 | 1.8 yuan/square metre | Positive 0.4 |
| 40 | 60 | 2.4 yuan/square metre | Positive 0.55 |
| 60 | 65 | 3.6 yuan/square metre | Positive more than 0.8 |
Because the coefficient of expansion of zirconium silicate is less, if excessive add the deformation that can have a strong impact on product in cover-coat enamel so that producing
Product increasingly encircle with the increase adding zirconium silicate amount, product.Simultaneously in cover-coat enamel after addition is a certain amount of, the impact to whiteness is got over
Come weaker, and the glaze volume of cover-coat enamel is relatively thick, so this scheme is also with high costs in the case of not reaching preferable whiteness,
But comparatively brightened using cover-coat enamel plus zirconium silicate and either will be better than for the lifting of whiteness still becomes present aspect
Increase the input of base substrate whiteness and the effect of generation.
The serial example 3 of contrast：Under the experiment condition of fixing step 1,2,3,4,6,7,8,9,10,11,12,13, only to step
Rapid 5 brighten glaze is adjusted, and draws following table：
By the research of three of the above mode, we can draw, brightens fancy glaze layer come improving product by serigraphy
The technical scheme of whiteness, to consider from the whitening effect that can reach, production stability, product quality and integrated cost hence it is evident that
Better than the technical scheme lifting whiteness in terms of base substrate and cover-coat enamel.Preferable whiteness can be reached moreover it is possible to ensure the deformation of product
Deng in product in, external quality, and Optimum cost.This also exactly the present invention program advantage be located, by change tradition
Improve base substrate whiteness using drenching glaze mode, glaze layer is thicker and is difficult to adjust, the scheme that the present invention provides, there is provided a kind of suitable
Silk screen printing brighten glaze, it is used for ceramic tile production, can be reached different white by way of printing the different numbers of plies
Degree effect, makes process window more wide in range, is issued to best effect in the minimum situation of cost.
Increasing pink blossom glaze in step 7, using silk-screen printing technique, prints the set floral pattern consistent with ink-jetting pattern texture
(depending on meshcount is according to the required depth heightening the color and clear patterns degree, mesh number scope in 80-250 mesh, in this product
Use 160 mesh effect nets.Bigger using meshcount, pattern definition is higher, but the amplitude that can heighten the color is less；
And use silk screen mesh number less, then the definition of pattern and fine and smooth degree are lower, but the effect that heightens the color can be higher) so that
The color that InkJet printing processes do not reach can be compensated by increasing powder craft, thus reaching more abundant, face true to nature
Color effect.In product development and production process, can according to product need adjust silk-screen patterns and colorant proportioning, thus reaching
To the various patterns wanted and color.It is as follows that increasing pink blossom glaze presses mass fraction：The calcareous clear frit of high boron：12 parts, Jin Zong：3.3
Part, reddish brown：0.6 part, parcel is red：3 parts, parcel is yellow：0.6 part, carboxymethylcellulose calcium：1.3 parts, ethylene glycol：45 parts, water：40 parts.
Here the calcareous frit of high boron is calculated with oxide mass number：Na2O:6 parts, CaO:12 parts, ZnO:7 parts, B2O3:8 parts, Al2O3:3
Part, SiO2:54 parts.Need exist for illustrating, Jin Zong, reddish brown, parcel is red and parcel Huang is the inorganic pigment of glaze, its select and
Proportioning, to need the color increasing powder as reference, is mated according to actual toning experience.Ink-jet can be realized using increasing pink blossom glaze
The unapproachable gray scale of stamp.
Help color fancy glaze in step 8,140 mesh full impregnated nets are printed using silk-screen printing technique, for ensureing fancy glaze uniform fold, no
Can cause because of the thickness difference helping color fancy glaze helps aberration different thus producing two tone colour, and the full impregnated net using print twice 140 mesh to enter
Row is complementary.Help color fancy glaze as follows by mass fraction：High zinc matter frit:100 parts, DS4003 (the print cream of Dow):130 parts, trimerization：
0.3 part, water：40 parts.325 mesh sieves tail over as 0.1-0.2%, and proportion is 1.32-1.35 gram/cc.High zinc matter frit with
Chemical oxide mass fraction calculates：SiO2:53 parts, ZnO:21 parts, K2O:4 parts, Al2O3:7 parts, MgO:3 parts, CaO:3.5 part.
Under the experiment condition of fixing step 1,2,3,4,5,6,7,9,10,11,12,13, only step 8 is adjusted,
Show that print helps color fancy glaze and not printing to help color fancy glaze to contrast：Coloring intensity lifting more than 10%, so can save the ink of costliness
And colorant, advantageously reduce production cost.
Protection glaze layer in described step 9, prints 80 mesh full impregnated nets using silk-screen printing technique or carries veined effect net,
Textured effect net would generally be nested flower with the inkjet printing pattern of the step 6 of as described before, and according to protection glaze thickness
Thin needs select print 1-3 road silk screen fancy glaze, for ensureing the needs of later stage cold working polishing, generally select using print 3 road silk screens
Fancy glaze, by print clear frit or complete throw glaze and other effects glaze so that ink-jetting pattern be difficult to be worn during routine use or
Be conducive to this series of products is carried out with the cold work in later stage.It is as follows that protection glaze fancy glaze presses mass fraction：DJY801-G2 is (big
The low-temperature transparent protection glaze of border science and technology):70 parts, DJY801-121 (the temperature resistant transparent protection glaze of big border science and technology):30 parts, DS4003
(the print cream of Dow):47 parts, sodium tripolyphosphate：0.3 part, water：25 parts.250 mesh sieves tail over 0.7-1.0%, proportion 1.60-1.63
Gram/cc.This protection glaze layer can also be other clear frits or entirely throw glaze.DJY801-G2 composition presses the matter of oxide
Amount number is calculated as follows：SiO2:67 parts, Al2O3:14 parts, CaO:12 parts, B2O3:5 parts.DJY801-121 composition presses oxidation material
Amount number is calculated as follows：SiO2:51 parts, Al2O3:15,K2O part:2,Na2O:5 parts, MgO:3.2 parts, CaO:10 parts, B2O3:8 parts.
Mineral crystal fancy glaze in step 10, prints 60 mesh effect nets, this effect net pattern texture using silk-screen printing technique
It is mutually matched (set flower) with the inkjet printing pattern of as described before step 6, in the place printing to mineral crystal fancy glaze, mineral crystal
Fancy glaze can be merged with following fancy glaze, and (high temperature viscosity of mineral crystal fancy glaze is relatively low, and metal oxide content is higher and molten
Also ratio is relatively low to melt temperature, can melt and arrange following glaze layer during burning till) so that this local pattern sink (under
Sunken effect can ensure that the pattern of mineral crystal, effect will not be disposed when product is carried out with cold working polishing), produce simultaneously
Raw mineral crystal effect.It is as follows that mineral crystal fancy glaze formula presses mass fraction：100 parts of mineral crystal dry granular, clear frit 0-50 part
(needing to change according to calcining system), print cream (the print cream of Dow) 60-80 (reach need according to formula change adjustment usage amount
The fancy glaze proportion wanted) part, 0.2 part of carboxymethylcellulose calcium, water 25-40 part, the particle diameter of mineral crystal dry granular：80～120 mesh account for 70
～80%, remainder is by 120 mesh, fancy glaze proportion 1.6～1.7g/cm3, after crossing 320 mesh sieves, tail over as 0.1 gram.Mineral crystal
Fancy glaze thickeies effect net by 60 mesh together and is printed.Mineral crystal dry granular is as follows with chemical oxide composition：SiO2:8 parts,
Al2O3:3 parts, B2O3:20 parts, Fe2O3：9 parts, MnO:46 parts, TiO2:8 parts.
Clear frit is calculated with oxide component, and its chemical constituent is as follows：SiO2:55 parts, Al2O3:14 parts, K2O:2 parts,
Na2O:6 parts, MgO:2 parts, CaO:10 parts, B2O3:8 parts.
Firing temperature in step 11 is 1175～1185 DEG C, and firing period is 60～70min.
Polishing edging is the common process of Production of Ceramics, and correspondence carries out selecting here.
Embodiment 5
In the present embodiment, give this product with negative ion health function.
Anion is a kind of negatively charged gas ion of in the air.Various gas componants in air are not exclusively to divide
Submode exists, and a portion is existed with the free state of ion.Wherein electronegative molecule or particulate (be commonly called as bearing from
Son) human body synthesis and vitamin storage can not only be facilitated, the physiological activity of strengthening and human activin, to human body and other biological
Vital movement has highly important impact, and therefore it is otherwise known as " air vitamin ".
In the prior art, be typically employed in composition of raw materials and add a certain proportion of tourmaline powder, using when temperature and
When pressure changes, electric heating difference and voltage difference can be caused between tourmaline crystal, this electrostatic potential difference can be up to 1.0 ×
106EV, this energy be enough to make air ionize, and is converted into negative aeroion.But the main component because of tourmaline powder is
The aluminium that is characterized with boracic, sodium, iron, the silicate material of lithium circulus, a large amount of introducings in base substrate can cause blank deformation,
And introduce in glaze, also the characteristic of glaze can be produced with certain impact, especially for marzacotto, thus while there being correlation
Functional product occurs, but overall performance not up to optimum.
Pin in this regard, the present embodiment provide corresponding solution, because tourmaline powder need and air contact could produce right
The effect answered.Therefore, in the present embodiment, the component of mineral crystal fancy glaze is improved, introduce tourmaline powder wherein
With improvement component, it is allowed to both there is abundant brilliant flower decorative effect, with more negative ion health function.
Concrete scheme is as follows：
It is as follows that the present embodiment provides mineral crystal fancy glaze formula to press mass fraction：100 parts of mineral crystal dry granular, tourmaline powder
1-3 part, light rare earth oxide 0.01-0.05 part, 20 parts of clear frit (corresponding firing temperature is suitably selected), print cream
(the print cream of Dow) 60-80 (reaching the fancy glaze proportion of needs according to formula change adjustment usage amount) part, carboxymethylcellulose calcium
0.2 part, water 25-40 part, the particle diameter of mineral crystal dry granular：80～120 mesh account for 70～80%, and remainder is by 120 mesh, fancy glaze ratio
Weigh 1.6～1.7g/cm3, after crossing 320 mesh sieves, tail over as 0.1 gram.Mineral crystal fancy glaze thickeies effect net by 60 mesh together and enters
Row printing.
This programme adds a small amount of tourmaline powder and micro light rare earth oxide in mineral crystal fancy glaze, so that
Its electrostatic potential difference lifting, can be issued to higher anion releasing effect in less consumption.
The process being provided using such as embodiment 4, prepared Ceramic Tiles, under 25 degrees Celsius, relative humidity 60%
Under the conditions of test, anion-generating capacity be 1800-2000/cm3.Because producing anion needs in the larger ring of relative humidity
Border, therefore such brick is suitable for using in the larger space of the humidity such as bathroom.
Certainly, tourmaline can also be replaced using Strange ice stone, opal or rare talent's stone here.Because generation provided above
The material of anion has considerable influence to the firing temperature of base substrate and blank deformation, and in the present invention, the mineral being used are brilliant
Body fancy glaze contains substantial amounts of metallic element, and the glaze that it can arrange below in sintering forms depression, so both can report barrier
The anion effect layer being formed will not be skimmed when follow-up rubbing down is processed, and meanwhile, this being applied in combination also makes Ceramic Tiles produce
The anti-pollution characteristic of product and finished product deformation all control in less scope, essentially identical with un-added effect.
And adopt traditional the tradition anion powder such as tourmaline is used as added material, add in conventional glaze,
The addition reaching the negative ion concentration of the present invention is needed to need to increase 1.5-2 times.So anion powder burns till to glaze
Effect has considerable influence, and then affects anti-pollution characteristic and the deformation of finished product.
Embodiment 6
In the present embodiment, give this product antibacterial functions, in traditional handicraft, product surface material introduces antibacterial
Agent is conventional selection.The antiseptics such as example common silver, copper, zinc.But because product needed passes through high temperature sintering, this can be to product
Antibacterial effect produce deleterious effect, in this regard, people select using above antiseptic phosphate.But be given with prior art
Scheme from the point of view of, all cannot solve the problems, such as the deformation of products after there is good antibacterial effect very well.
Pin, in this regard, the present invention introduces a certain amount of antibacterial components in above mineral crystal fancy glaze, is spent using mineral crystal
The a large amount of metallic elements containing in glaze, glaze can melt at a lower temperature, concave downward, it is to avoid follow-up rubbing down is to antibacterial
The destruction of layer, the metallic element simultaneously containing in mineral crystal fancy glaze is also so that the antibacterial effect of its antiseptic is enhanced.
It is as follows that the present embodiment provides mineral crystal fancy glaze formula to press mass fraction：100 parts of mineral crystal dry granular, antiseptic
1.5 parts, 10 parts of clear frit (corresponding firing temperature suitably selected), print cream (the print cream of Dow) 60-80 (according to formula
Change adjustment usage amount is reaching the fancy glaze proportion of needs) part, 0.2 part of carboxymethylcellulose calcium, water 25-40 part, mineral crystal does
The particle diameter of grain：80～120 mesh account for 70～80%, and remainder is by 120 mesh, fancy glaze proportion 1.6～1.7g/cm3, cross 320 mesh sieves
Afterwards, tail over as 0.1 gram.
Here antiseptic is chosen as the mixture of silver orthophosphate and basic zirconium phosphate, the wherein 5- accounting for antiseptic quality of basic zirconium phosphate
15%.The combination selecting silver orthophosphate and basic zirconium phosphate is as antiseptic, it is possible to reduce the silver in antiseptic to mineral crystal fancy glaze is in
The impact of color.Here the used in amounts of basic zirconium phosphate will control below 15%, otherwise because the covering of brightening of zirconium acts on, can make whole
The decorative effect of brick is affected.
The above-mentioned description to embodiment is to be understood that and use invention for ease of those skilled in the art.
Person skilled in the art obviously easily can make various modifications to these embodiments, and described herein general
Principle is applied in other embodiment without through performing creative labour.Therefore, the invention is not restricted to above-described embodiment, ability
, according to the announcement of the present invention, the improvement made without departing from scope and modification all should be the present invention's for field technique personnel
Within protection domain.
Claims (9)
1. a kind of increasing pink blossom glaze of suitable silk screen printing complementary color, it is calculated with mass fraction, including following component：High boron is calcareous
Bright frit：12 parts, complementary color colorant 0.1-10 part, carboxymethylcellulose calcium：1.3 parts, ethylene glycol：45 parts, water：40 parts；
The chemical constituent of the calcareous clear frit of described high boron is calculated with oxide weight number, including following component：Na2O:6 parts,
CaO:12 parts, ZnO:7 parts, B2O3:8 parts, Al2O3:3 parts, SiO2:54 parts；
Described complementary color colorant is one or more combination of known pottery glaze stain.
2. a kind of Ceramic Tiles using increasing pink blossom glaze preparation as claimed in claim 1 are it is characterised in that described Ceramic Tiles have
Printed layer, described increasing pink blossom glaze is located in described printed layer.
3. a kind of production technology of Ceramic Tiles is it is characterised in that comprise the steps：
Step 1) make adobe from known ceramic body powder punching press；
Step 2) in cover-coat enamel known to billet surface charity, form cover coat；
Step 3) ink-jet printed, formation printed layer is carried out on cover coat；
Step 4) in printed layer, the increasing pink blossom glaze for complementary color is printed by screen printing mode, described increasing pink blossom glaze is with quality
Number calculates, including following component：The calcareous clear frit of high boron：12 parts, complementary color colorant 0.1-10 part, carboxymethylcellulose calcium：1.3
Part, ethylene glycol：45 parts, water：40 parts；The chemical constituent of the calcareous clear frit of described high boron is calculated with oxide weight number, bag
Include following component：Na2O:6 parts, CaO:12 parts, ZnO:7 parts, B2O3:8 parts, Al2O3:3 parts, SiO2:54 parts；Described complementary color colorant
One or more combination for known pottery glaze stain；
Step 5) enter kiln and fire；
Step 6) base substrate after burning till is polished and edging process, obtain ceramic brick product.
4. as claimed in claim 3 a kind of ceramic tile production technique it is characterised in that described step 2) and step 3) between also
Step including brightening glaze by silk screen printing, the described glaze that brightens is calculated with mass fraction, including following component：Transparent molten
Block：50 parts, zirconium silicate：50 parts, print cream：65 parts, sodium tripolyphosphate：0.3 part, water：35 parts；
The chemical constituent of described clear frit is calculated with oxide weight number, including following component：
Na2O:5 parts, CaO:9 parts, ZnO:8 parts, Al2O3:8 parts, B2O3:2 parts, SiO2:60 parts.
5. as claimed in claim 3 a kind of ceramic tile production technique it is characterised in that described step 4) and step 5) between also
The step supporting color fancy glaze including cloth, helps color fancy glaze to be formed using serigraphy and helps color fancy glaze layer；
Described help color fancy glaze with mass fraction calculate, including following component：100 parts of high zinc matter frit, prints 130 parts of cream, trimerization phosphorus
0.3 part of sour sodium, 40 parts of water；
The chemical constituent of described high zinc matter frit is calculated with oxide weight number, including following component：
SiO2:53 parts, ZnO:21 parts, K2O:4 parts, Al2O3:7 parts, MgO:3 parts, CaO:3.5 part.
6. as claimed in claim 5 a kind of ceramic tile production technique it is characterised in that after color fancy glaze supported by described cloth cloth
Apply known transparency protected glaze and form protection glaze layer covering in described printed layer.
7. as claimed in claim 6 a kind of ceramic tile production technique it is characterised in that after transparency protected glaze described in charity, making
Form mineral crystal fancy glaze layer with serigraphy mineral crystal fancy glaze,
Described mineral crystal fancy glaze is calculated with mass fraction, including following component：
100 parts of mineral crystal dry granular, clear frit 0-50 part, print cream 60-80 part, 0.2 part of carboxymethylcellulose calcium, water 25-40 part,
The chemical constituent of described mineral crystal dry granular is calculated with oxide weight number, including following component：
SiO2:8 parts, Al2O3:3 parts, B2O3:20 parts, Fe2O3：9 parts, MnO:46 parts, TiO2:8 parts.
8. a kind of ceramic tile production technique according to claim 7 is it is characterised in that described mineral crystal fancy glaze passes through 60
Mesh thickeies effect net and is printed.
9. a kind of ceramic tile production technique according to claim 7 is it is characterised in that described step 5) firing temperature be
1175～1185 DEG C, firing period is 60～70min.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610798127.1A CN106396396A (en) | 2016-08-31 | 2016-08-31 | Color-increasing colored glaze suitable for complementing colors in silk screen printing and ceramic tiles prepared by color-increasing colored glaze |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610798127.1A CN106396396A (en) | 2016-08-31 | 2016-08-31 | Color-increasing colored glaze suitable for complementing colors in silk screen printing and ceramic tiles prepared by color-increasing colored glaze |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN106396396A true CN106396396A (en) | 2017-02-15 |
Family
ID=58000545
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201610798127.1A Pending CN106396396A (en) | 2016-08-31 | 2016-08-31 | Color-increasing colored glaze suitable for complementing colors in silk screen printing and ceramic tiles prepared by color-increasing colored glaze |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN106396396A (en) |
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107352968A (en) * | 2017-08-24 | 2017-11-17 | 四川汇丰陶瓷有限公司 | A kind of preparation method of ceramic body and bright convex glaze ceramics |
| CN110698216A (en) * | 2019-11-21 | 2020-01-17 | 广东金意陶陶瓷集团有限公司 | Whitening ceramic body and preparation method thereof |
| WO2021012009A1 (en) * | 2019-07-24 | 2021-01-28 | Iluka Resources Limited | Whitening methods and compositions |
| CN113845306A (en) * | 2021-10-09 | 2021-12-28 | 广东松发陶瓷股份有限公司 | Ceramic color glaze material for underglaze transfer printing decoration, daily ceramic utensil and preparation method thereof |
| CN116253583A (en) * | 2021-12-10 | 2023-06-13 | 佛山市东鹏陶瓷有限公司 | Full-polished glazed tile with rough and fine concave textures and preparation process thereof |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE3223548A1 (en) * | 1982-06-24 | 1984-02-02 | Ceramano Baukeramik Gmbh & Co Kg, 5412 Ransbach-Baumbach | Method for manufacturing ceramic tiles with a coloured glaze layer |
| CN102515873A (en) * | 2011-12-14 | 2012-06-27 | 潮州市三泰陶瓷有限公司 | Decorative ceramic with golden crystalline glaze surface |
| CN103497007A (en) * | 2013-09-17 | 2014-01-08 | 佛山市五月玫瑰陶瓷有限公司 | Ceramic tile with dispersed shimmering powder and manufacturing method thereof |
| CN104557144A (en) * | 2014-12-29 | 2015-04-29 | 广东家美陶瓷有限公司 | Colorful transparent polished-glazed brick and production method thereof |
-
2016
- 2016-08-31 CN CN201610798127.1A patent/CN106396396A/en active Pending
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE3223548A1 (en) * | 1982-06-24 | 1984-02-02 | Ceramano Baukeramik Gmbh & Co Kg, 5412 Ransbach-Baumbach | Method for manufacturing ceramic tiles with a coloured glaze layer |
| CN102515873A (en) * | 2011-12-14 | 2012-06-27 | 潮州市三泰陶瓷有限公司 | Decorative ceramic with golden crystalline glaze surface |
| CN103497007A (en) * | 2013-09-17 | 2014-01-08 | 佛山市五月玫瑰陶瓷有限公司 | Ceramic tile with dispersed shimmering powder and manufacturing method thereof |
| CN104557144A (en) * | 2014-12-29 | 2015-04-29 | 广东家美陶瓷有限公司 | Colorful transparent polished-glazed brick and production method thereof |
Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107352968A (en) * | 2017-08-24 | 2017-11-17 | 四川汇丰陶瓷有限公司 | A kind of preparation method of ceramic body and bright convex glaze ceramics |
| WO2021012009A1 (en) * | 2019-07-24 | 2021-01-28 | Iluka Resources Limited | Whitening methods and compositions |
| CN110698216A (en) * | 2019-11-21 | 2020-01-17 | 广东金意陶陶瓷集团有限公司 | Whitening ceramic body and preparation method thereof |
| CN110698216B (en) * | 2019-11-21 | 2022-03-15 | 广东金意陶陶瓷集团有限公司 | Whitening ceramic body and preparation method thereof |
| CN113845306A (en) * | 2021-10-09 | 2021-12-28 | 广东松发陶瓷股份有限公司 | Ceramic color glaze material for underglaze transfer printing decoration, daily ceramic utensil and preparation method thereof |
| CN116253583A (en) * | 2021-12-10 | 2023-06-13 | 佛山市东鹏陶瓷有限公司 | Full-polished glazed tile with rough and fine concave textures and preparation process thereof |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN106348594A (en) | Whitening glaze suitable for silk screening and ceramic tile prepared from whitening glaze | |
| CN106396399A (en) | Mineral crystal fancy glaze with antibacterial effect and ceramic tiles prepared from mineral crystal fancy glaze | |
| CN106396407A (en) | Mineral crystal fancy glaze capable of releasing negative ions and ceramic tile produced by using mineral crystal fancy glaze | |
| CN106396396A (en) | Color-increasing colored glaze suitable for complementing colors in silk screen printing and ceramic tiles prepared by color-increasing colored glaze | |
| CN106986540B (en) | Formula for making sunken and peeled marble glaze | |
| CN106430967A (en) | Dyeing-assistant fancy glaze capable of promoting pigment color development and ceramic tile prepared from same | |
| CN106396397A (en) | Ceramic tile with color-assisting flower glaze layer and preparation method thereof | |
| CN106396741B (en) | A kind of Ceramic Tiles and preparation method thereof with mineral crystal fancy glaze layer | |
| CN105565907B (en) | A kind of preparation method of transmutation crystalline substance flower seeding fixation Ceramic Tiles | |
| CN105777089B (en) | A kind of transparent brick and preparation method thereof | |
| CN101407435B (en) | Method for preparing ceramic underglaze color mud base and ceramic underglaze color mud decoration | |
| CN107311457B (en) | Anti-skid wearable Ceramic Tiles | |
| CN107285737B (en) | The easy clean Ceramic Tiles of anti-skid wearable | |
| CN106522499B (en) | Antique Imitation Tiles and preparation method thereof with 3D decorative effect | |
| CN103332968B (en) | Full-polishing glaze production process and prepared product | |
| CN109384476A (en) | A kind of anti-skid wearable negative ion ceramic ceramic tile and preparation method thereof | |
| CN100360462C (en) | Glaze coloured decoration daily use poocelain and its production method | |
| CN105293909B (en) | In-glaze decoration embossment bottom material, in-glaze decoration marble paper and its manufacture craft with its production | |
| CN109553299A (en) | A kind of entire body Imitation Rock Porcelain Tiles of combination ink-jet effect and preparation method thereof | |
| CN105271751B (en) | A kind of Antiskid ceramic tile high temperature glaze and its production method and methods for using them | |
| CN104150965A (en) | Copper red glaze formula and manufacturing process of copper red glaze porcelain | |
| CN109795017B (en) | Preparation method of stable spot brick | |
| CN106116696A (en) | A kind of preparation method of three-dimensional cover-coat enamel | |
| CN106810297B (en) | Production process of ceramic tile with high-brightness matte surface and precious metal luster | |
| CN107382377A (en) | The preparation method of easy clean Ceramic Tiles |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| RJ01 | Rejection of invention patent application after publication | ||
| RJ01 | Rejection of invention patent application after publication |
Application publication date: 20170215 |