CN106386831A - Pesticide composition for preventing and treating cucumber downy mildew - Google Patents

Pesticide composition for preventing and treating cucumber downy mildew Download PDF

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Publication number
CN106386831A
CN106386831A CN201610799555.6A CN201610799555A CN106386831A CN 106386831 A CN106386831 A CN 106386831A CN 201610799555 A CN201610799555 A CN 201610799555A CN 106386831 A CN106386831 A CN 106386831A
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CN
China
Prior art keywords
composition
downy mildew
preventing
zhongshengmycin
cucumber downy
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Withdrawn
Application number
CN201610799555.6A
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Chinese (zh)
Inventor
陈佛祥
王礼文
吴泽伟
朱刚
张志伟
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Guangdong Zhongxun Agri Science Corp
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Guangdong Zhongxun Agri Science Corp
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Publication date
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Priority to CN201610799555.6A priority Critical patent/CN106386831A/en
Publication of CN106386831A publication Critical patent/CN106386831A/en
Withdrawn legal-status Critical Current

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    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01NPRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N47/00Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid
    • A01N47/08Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid the carbon atom having one or more single bonds to nitrogen atoms
    • A01N47/10Carbamic acid derivatives, i.e. containing the group —O—CO—N<; Thio analogues thereof
    • A01N47/18Carbamic acid derivatives, i.e. containing the group —O—CO—N<; Thio analogues thereof containing a —O—CO—N< group, or a thio analogue thereof, directly attached to a heterocyclic or cycloaliphatic ring
    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01NPRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N43/00Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/34Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one nitrogen atom as the only ring hetero atom
    • A01N43/40Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one nitrogen atom as the only ring hetero atom six-membered rings

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  • Life Sciences & Earth Sciences (AREA)
  • Agronomy & Crop Science (AREA)
  • Pest Control & Pesticides (AREA)
  • Plant Pathology (AREA)
  • Health & Medical Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Dentistry (AREA)
  • General Health & Medical Sciences (AREA)
  • Wood Science & Technology (AREA)
  • Zoology (AREA)
  • Environmental Sciences (AREA)
  • Agricultural Chemicals And Associated Chemicals (AREA)

Abstract

The invention relates to a pesticide composition for preventing and treating cucumber downy mildew; effective ingredients comprise Zhongshengmycin and LH-2010A, the weight part ratio of Zhongshengmycin to LH-2010A in the composition is 10:1-1:20, and the weight percentage of the total weight of Zhongshengmycin and LH-2010A in the composition is 1%-80%. Compared with the prior art, the pesticide composition has obvious synergistic effect, improves the use effect, reduces the use amount, and delays the resistance of downy mildew to the effective ingredients.

Description

A kind of composition pesticide of preventing and treating cucumber downy mildew
Technical field
The invention belongs to pesticides application technical field is and in particular to a kind of compositionss of preventing and treating cucumber downy mildew, compositionss Combined by bactericidal active ingredient Zhongshengmycin and fluorine ether bacterium amide, for preventing and treating cucumber downy mildew.
Background technology
Cucumber downy mildew, is commonly called as " horse race is dry ", " dry leaves ", seedling stage strain all can be aggrieved, mainly cause harm blade and stem.Disease Originally it was Mastigomycotina Pseudoperonospora Cuba artificial downy mildew [Pseudoperonospora cubensis (Berk.et Curt.) Rostov.], it is that the most universal, disease of the most serious that cause harm occurs in cucumber cultivation.The state of an illness oncoming force is violent, morbidity weight, propagates fast, such as Prevent and treat not in time, destructive loss will be caused to Fructus Cucumidis sativi.
The use of pesticide control cucumber downy mildew is agricultural production common method, but, pesticide single variety uses, pathogenic bacteria pole It easily produces resistance.Different pesticide species are combined using or are used alternatingly, and are to solve the effective means that resistance produces.Example As metalaxyl, a season 3 times can not be used more than.
Known 201410185177.3 bactericidal compositions, open Zhongshengmycin (zhongshengmycin) is used for anti-Yellow River harnessing Melon downy mildew uses technology.
A kind of known 201310341037.6 fluorine-containing ether bacterium amide and the bactericidal composition of iprovalicarb, open fluorine ether bacterium amide Use technology for preventing and treating cucumber downy mildew.
The present invention has made intensive studies to Zhongshengmycin and the combination of fluorine ether bacterium amide, on the basis of lot of experiments, Find that fluorine ether bacterium amide and Zhongshengmycin combine preventing and treating cucumber downy mildew potentiation significantly in the range of certain proportion, reduction makes Consumption is hence it is evident that lifting Zhongshengmycin and fluorine ether bacterium amide use.Delay the resistance to Zhongshengmycin and fluorine ether bacterium amide for the downy mildew Produce, effectively extend Zhongshengmycin and fluorine ether bacterium amide service life.After further study, complete the present invention.
Content of the invention
It is an object of the invention to provide one kind has synergistic function, delay pathogenic bacteria resistance to produce, extend and use the longevity Life, the composition pesticide containing Zhongshengmycin and fluorine ether bacterium amide easy to use, and compositionss are used for preventing and treating Fructus Cucumidis sativi downy mildew Disease.
The technical scheme realizing the object of the invention is:A kind of composition pesticide of preventing and treating cucumber downy mildew, its effective ingredient It is made up of Zhongshengmycin and fluorine ether bacterium amide, Zhongshengmycin and fluorine ether bacterium amide ratio of weight and number in the composition are 10:1~ 1:20, Zhongshengmycin and fluorine ether bacterium amide weight summation percentage by weight 1%~80% in the composition, remaining is agriculturally Allow to use and acceptable insecticides adjuvant.
Further, Zhongshengmycin and fluorine ether bacterium amide preferred weight portion rate in the composition are 1:1~1:20, more excellent Ratio of weight and number is 1:1~1:10.
Composition pesticide of the present invention can be prepared into preparation according to existing process technology, including wettable powder;
The preparation method of composite wettable powder:Zhongshengmycin 0.1%~10%, fluorine ether bacterium amide 1%~50%, helps Agent surplus.Weigh Zhongshengmycin, fluorine ether bacterium amide, auxiliary agent by required percentage, pulverize through mechanical mixture, after comminution by gas stream Machine 2 times, you can obtain the Zhongshengmycin fluorine ether bacterium amide wettable powder of required percentage.
Composition pesticide of the present invention, can be used it is also possible to adopt as needed using the method being watered spraying The other agriculturally applied uses technology.
Insecticides adjuvant of the present invention include wetting agent, disintegrating agent, dispersant, pH adjusting agent, stabilizer, antifreezing agent, One or more mixing of carrier, are the conventional auxiliary elements of formulations of pesticide processing.
Wetting agent of the present invention includes sodium butylnaphthalenesulfonate, sodium lauryl sulphate, aliphatic alcohol polyethenoxy (6-7) One or more of ether, aerosol-OT salt, Morwet EFW, alkylnaphthalene sulfonate etc..
Disintegrating agent of the present invention includes sodium bicarbonate, magnesium chloride, aluminum chloride, sodium chloride, carbamide, ammonium sulfate, swelling One or more of soil etc..
Dispersant of the present invention includes the formaldehyde condensation products of methyl naphthalene sulfonic acid sodium, sodium lignin sulfonate, sulfomethylated lignin Sour calcium, to methoxyl group fatty acyl anilinesulfonic acid, desaccharide the sodium lignin sulfonate being classified, naphthalene sulfonic acid condensate sodium salt, alkyl One or more of LOMAR PWA EINECS 246-676-2 condensation polymer sodium salt, APES formaldehyde condensation product sulphuric acid etc..
PH adjusting agent of the present invention include ammonium hydroxide, potassium hydroxide, sodium hydroxide, hydrochloric acid, acetic acid, citric acid, One or more of phosphoric acid etc..
Stabilizer of the present invention includes epoxy soybean oil, epoxychloropropane, Butylated hydroxyanisole, dibutyl hydroxy One or more of toluene, propylgallate, tert-butylhydroquinone etc..
Antifreezing agent of the present invention includes a kind of or several in glycerol, ethylene glycol, propylene glycol, Sorbitol, Polyethylene Glycol etc. Kind.
Carrier of the present invention include Kaolin, kieselguhr, bentonite, white carbon, precipitated calcium carbonate, attapulgite, One or more of clay, Pulvis Talci, quartz sand, starch, APG etc..
Composition pesticide of the present invention, can be that finished product preparation form provides, that is, in compositionss, each material has mixed Close, the composition of compositionss can also unit dose form provide, and is mixed before use according to each single dose required ratio.
Composition pesticide of the present invention has following beneficial effect:
Zhongshengmycin and fluorine ether bacterium amide combine preventing and treating cucumber downy mildew performance Synergistic in certain ratio range and make With;Reduce usage amount, improve using effect;The mechanism of action is different, delays pathogenic bacteria resistance to produce, and extends compositionss and uses the longevity Life;Reduce single active ingredient production, packaging, cost of transportation, reduce energy resource consumption.
Specific embodiment
In order that the object of the invention, technical scheme and advantage are more short and sweet, present invention specific examples below is entered Row explanation, but the present invention is only limitted to absolutely not these examples.Described below is only the preferable embodiment of the present invention, is used only for describing The present invention is it is impossible to be interpreted as limiting the scope of the present invention.It should be pointed out that all within the spirit and principles in the present invention Any modification, equivalent and improvement of being made etc., should be included within the scope of the present invention.Therefore, the present invention is special The protection domain of profit should be defined by claims.
In these embodiments, unless otherwise indicated, all percentage ratios are percentage by weight after folding hundred.
Chemical prevention information system of crop pest distribution in China is common method, and different types of pesticide active ingredient is combined, and leads to Often show three kinds of type of action, i.e. antagonism, summation action and potentiation.
Embodiment 1:Zhongshengmycin frost mould to Fructus Cucumidis sativi with fluorine ether bacterium amide mixture virus power determination test.
Adopt field Fructus Cucumidis sativi nebulization dispenser (having water membrane to be advisable with blade surface), spray apparatus adopts hand spray Device (liquid capacity about 2.0L), every 10 days sprays once, continuously spray 2 times.Often process and select uniform 20 blades of morbidity As efficacy of medicine observing object, each processes 3 repetitions.
According to blank incidence, classification investigation is carried out to inoculation blade, using following stage division
0 grade:Anosis;
1 grade:Lesion area accounts for less than the 5% of full wafer leaf area;
3 grades:Lesion area accounts for the 6%~10% of full wafer leaf area;
5 grades:Lesion area accounts for the 11%~20% of full wafer leaf area;
7 grades:Lesion area accounts for the 21%~40% of full wafer leaf area;
9 grades:Lesion area accounts for more than the 40% of full wafer leaf area;
According to survey data, calculate disease index and prevention effect.
(1) disease index is calculated by formula, and result of calculation retains 2 significant digits:
In formula:
X represents disease index;
NiRepresent the disease numbers of sheets at different levels;
I represents value of series relatively;
N represents investigation total number of sheets.
(2) prevention effect is calculated by formula:
In formula:
P represents prevention effect, and unit is percentage rate (%);
CK represents blank disease index;
PT represents chemicals treatment disease index.
Survey standard method NY/T1156.4-2006 with reference to raw, according to the co-toxicity coefficient method of Sun&Johnson (1960) (CTC) evaluating the potentiation of pharmacy mix, that is, CTC≤80 are antagonism, 80<CTC<120 is summation action, CTC >= 120 is potentiation.
The percentage composition of A medicament in toxicity index × 100 mixture of mixture theoretical toxicity index (TTI)=medicament A
The percentage composition of the toxicity index × 100 mixture Chinese medicine of+medicament B
Can be seen that Zhongshengmycin and fluorine ether bacterium amide portfolio ratio 1~10 from table 1, table 2:1~20 co-toxicity coefficient (CTC Value) it is all higher than 120, illustrate that Zhongshengmycin and the combination of fluorine ether bacterium amide are notable to cucumber downy mildew potentiation.
Table 1, Zhongshengmycin, fluorine ether bacterium amide and combinations thereof are to cucumber downy mildew toxicity test result
Table 2, Zhongshengmycin, fluorine ether bacterium amide and combinations thereof are to cucumber downy mildew toxicity test result
Embodiment 2:18% Zhongshengmycin fluorine ether bacterium amide wettable powder.
12% Zhongshengmycin 25 parts of medicine of mother (effective ingredient), 98% fluorine 15.3 parts of bacterium amide active compound of ether (effective ingredient), wood 5 parts of quality sodium sulfonate (auxiliary agent), 7 parts of alkyl naphthalene sulfonic acid condensation polymer sodium salt (auxiliary agent), 5 parts of sodium lauryl sulphate (auxiliary agent), carbon Sour 5 parts of hydrogen sodium (auxiliary agent), 10 parts of bentonite (auxiliary agent), 27.7 parts of Kaolin (auxiliary agent).Will be mixed through machinery to effective ingredient and auxiliary agent Close and pulverize, after jet mill 2 times, you can obtain 18% Zhongshengmycin fluorine ether bacterium amide wettable powder.Wherein, middle life Rhzomorph weight/mass percentage composition 3%;Fluorine ether bacterium amide weight/mass percentage composition 15%.
Embodiment 3:Field control effectiveness test
It is used for preventing and treating cucumber downy mildew using 18% Zhongshengmycin fluorine ether bacterium amide wettable powder, in cucumber downy mildew Their early stage is watered spraying, and every dispenser in 5 days once, continuous dispenser is secondary.
From table 3 it can be seen that preventing and treating cucumber downy mildew, 3% Zhongshengmycin 15% fluorine ether bacterium amide wettable powder has 5 days, 10 days prevention effects 70.26~77.59%, 81.09~86.97% after effect 40~60 grams/ha of medicines of Ingredient Amount, preventing and treating Prevent within 5 days, 10 days after effect is substantially better than single dose 15% fluorine ether bacterium amide wettable powder and 3% Zhongshengmycin wettable powder medicinal Control effect 68.02%, 60.42 and 71.64%, 63.57%.
Table 3,3% Zhongshengmycin 21% fluorine ether bacterium amide wettable powder preventing and treating cucumber downy mildew statistical table.

Claims (9)

1. a kind of preventing and treating cucumber downy mildew composition pesticide it is characterised in that:Its effective ingredient is by Zhongshengmycin and fluorine ether bacterium Amide forms, and Zhongshengmycin and fluorine ether bacterium amide ratio of weight and number in the composition are 10:1~1:20.
2. according to claim 1 a kind of preventing and treating cucumber downy mildew composition pesticide it is characterised in that:Zhongshengmycin with Fluorine ether bacterium amide ratio of weight and number in the composition is 1:1~1:20.
3. according to claim 1 a kind of preventing and treating cucumber downy mildew composition pesticide it is characterised in that:Zhongshengmycin with Fluorine ether bacterium amide ratio of weight and number in the composition is 1:1~1:10.
4. according to claim 1 a kind of preventing and treating cucumber downy mildew composition pesticide it is characterised in that:Zhongshengmycin with Fluorine ether bacterium amide ratio of weight and number in the composition is 1:5.
5. a kind of preventing and treating cucumber downy mildew according to any one of claim 1-4 composition pesticide it is characterised in that:In Raw rhzomorph and fluorine ether bacterium amide weight summation percentage by weight 1%~80% in the composition.
6. a kind of preventing and treating cucumber downy mildew according to any one of claim 1-4 composition pesticide it is characterised in that:In Raw rhzomorph percentage by weight in the composition is 0.1%~10%, and fluorine ether bacterium amide percentage by weight in the composition is 1%~50%, remaining is insecticides adjuvant.
7. a kind of preventing and treating cucumber downy mildew according to any one of claim 1-4 composition pesticide it is characterised in that:Institute State composition pesticide and preparation is processed into according to existing process technology, including wettable powder.
8. a kind of composition pesticide of the preventing and treating cucumber downy mildew according to any one of claim 1-4 is it is characterised in that group The preparation method that compound is processed as wettable powder is:Weigh Zhongshengmycin, fluorine ether bacterium amide, auxiliary agent by required percentage, After pulverizing through mechanical mixture, then through twice of comminution by gas stream, you can obtain the Zhongshengmycin fluorine ether bacterium amide of required percentage Wettable powder.
9. according to claim 8 a kind of preventing and treating cucumber downy mildew composition pesticide it is characterised in that:Described auxiliary agent bag Include wetting agent, disintegrating agent, dispersant, pH adjusting agent, stabilizer, antifreezing agent, carrier, be that the conventional auxiliary of formulations of pesticide processing becomes Point.
CN201610799555.6A 2016-08-31 2016-08-31 Pesticide composition for preventing and treating cucumber downy mildew Withdrawn CN106386831A (en)

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107136131A (en) * 2017-06-08 2017-09-08 合肥龙滨化工科技有限公司 A kind of medicine for preventing and treating cucumber downy mildew and preparation method thereof

Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN104412998A (en) * 2013-09-02 2015-03-18 张通 Efficient antibacterial composition containing fluoride ether bacteria amide

Patent Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN104412998A (en) * 2013-09-02 2015-03-18 张通 Efficient antibacterial composition containing fluoride ether bacteria amide

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
刘广文: "《现代农药剂型加工技术》", 31 January 2013 *

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107136131A (en) * 2017-06-08 2017-09-08 合肥龙滨化工科技有限公司 A kind of medicine for preventing and treating cucumber downy mildew and preparation method thereof

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Application publication date: 20170215