CN106380683A - Slip polypropylene film - Google Patents
Slip polypropylene film Download PDFInfo
- Publication number
- CN106380683A CN106380683A CN201610778441.3A CN201610778441A CN106380683A CN 106380683 A CN106380683 A CN 106380683A CN 201610778441 A CN201610778441 A CN 201610778441A CN 106380683 A CN106380683 A CN 106380683A
- Authority
- CN
- China
- Prior art keywords
- parts
- smooth
- polypropylene
- agent
- master batch
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
- C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L23/10—Homopolymers or copolymers of propene
- C08L23/12—Polypropene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J3/00—Processes of treating or compounding macromolecular substances
- C08J3/20—Compounding polymers with additives, e.g. colouring
- C08J3/22—Compounding polymers with additives, e.g. colouring using masterbatch techniques
- C08J3/226—Compounding polymers with additives, e.g. colouring using masterbatch techniques using a polymer as a carrier
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J5/00—Manufacture of articles or shaped materials containing macromolecular substances
- C08J5/18—Manufacture of films or sheets
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2323/00—Characterised by the use of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Derivatives of such polymers
- C08J2323/02—Characterised by the use of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Derivatives of such polymers not modified by chemical after treatment
- C08J2323/10—Homopolymers or copolymers of propene
- C08J2323/12—Polypropene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2423/00—Characterised by the use of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Derivatives of such polymers
- C08J2423/02—Characterised by the use of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Derivatives of such polymers not modified by chemical after treatment
- C08J2423/10—Homopolymers or copolymers of propene
- C08J2423/12—Polypropene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/011—Nanostructured additives
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/04—Antistatic
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/08—Stabilised against heat, light or radiation or oxydation
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2203/00—Applications
- C08L2203/16—Applications used for films
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
- C08L2205/025—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group containing two or more polymers of the same hierarchy C08L, and differing only in parameters such as density, comonomer content, molecular weight, structure
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
Abstract
The invention discloses a slip polypropylene film. The slip polypropylene film comprises the following components in parts by weight: 100 parts of polypropylene mother material, 7-12 parts of slipping master batch, 0.3-1.5 parts of an antifoaming agent, 0.4-1 part of a coupling agent, 2-5 parts of a slipping agent, 1-1.5 parts of a dispersant, 0.6-1.2 parts of an anti-oxidant, 2-5 parts of glass beads, and 1-2 parts of a reinforcing agent; and the slipping master batch comprises the following components in parts by weight: 100 parts of polypropylene mother material, 8-15 parts of nano barium sulfate, 5-8 parts of nano titanium dioxide, 3-7 parts of carbon nanotube, 1-5 parts of calcium carbonate, 2-4 parts of organo montmorillonite, 3-6 part of the slipping agent, 3-5 parts of a polyolefin elastomer, 0.3-1 part of lithium oxide, 1-3 parts of polystyrolsulfon acid, 0.3-1 part of zinc oxide, 0.3-1 part of boron oxide, and 0.3-1 part of tellurium dioxide. The polypropylene film has the advantages of excellent slipping performance, tensile property, breaking elongation, impact performance, and aging-resistant performance.
Description
Technical field
The present invention relates to plastic sheeting production technical field, specifically a kind of smooth polypropylene film.
Background technology
With industrial continuous development, macromolecular material is extensively applied, and the requirement to material property for the every field constantly carries
Rise.In order to meet the needs of application, the material that simple pure resin is made seems unable to do what one wishes, so, polymeric material field must
Must weed out the old and bring forth the new, the research of modifying plastics is also just more and more important, for example, expect that polymeric material is high temperature resistant, be easily processed into
Type, there is good toughness, higher intensity, functional and cheap etc..Single homopolymers material is often difficult
To meet above-mentioned requirements, therefore by nanometer composite technology, existing polymeric material can be modified, synthesis can be made
The novel high polymer material of excellent performance, it has also become the important research direction of new material development field, has wide market and opens
Send out application prospect.
Polypropylene (PP) is a kind of larger polymer of industrial output, and it is good that it has light weight, easy to process, chemical stability
Good the advantages of, the application in fields such as electronic product, auto parts, packaging material is quite varied, but the weatherability of PP and low temperature
Toughness is not high so as to application in some aspects is restricted.And pass through nano modification and can not only make up these aspects
In actual production, the addition of slipping agent can make the surface of BOPP film have smoothness, and so that the frictional decrease on surface is arrived
The degree needing or numerical value, are conducive to the smooth degree that composite soft packaging material passes through during automatic packaging machine to improve.Slipping agent leads to
Often it is added on the top layer in film three-decker and internal layer, top layer uses to play and maintains compared with low-friction coefficient in certain period of time
Effect, internal layer slipping agent is when temperature reduces to the surface migration of film so that the frictional decrease of film surface is with more
Mend the deficiency that skin-friction coefficient increases in time and changes.
However, can be by its other party such as volatilization, precipitations through the slipping agent that BOPP film internal layer migrates out after a period of time
Formula causes damage, if the superficial velocity moving to film is too fast, the performance of film can be made to occur significantly to become in storage period
Change, the problems such as fast in generation glossiness decline, mist degree rising, films tacky, coefficient of friction decay, lead to the use of downstream client
Ageing shortening.
Content of the invention
It is an object of the invention to provide a kind of smooth polypropylene film, with asking of solving to propose in above-mentioned background technology
Topic.
For achieving the above object, the present invention provides following technical scheme：
A kind of smooth polypropylene film, is made up of the component of following weight portion：100 parts of polypropylene masterbatch, smooth master batch 7-
12 parts, defoamer 0.3-1.5 part, coupling agent 0.4-1 part, slipping agent 2-5 part, dispersant 1-1.5 part, antioxidant 0.6-1.2 part,
Glass microballoon 2-5 part, reinforcing agent 1-2 part；
Described smooth master batch includes following component by weight ratio：100 parts of polypropylene masterbatch, nano barium sulfate 8-15
Part, nano titanium oxide 5-8 part, CNT 3-7 part, calcium carbonate 1-5 part, organo montmorillonite 2-4 part, slipping agent 3-6 part, poly-
Olefin elastomer 3-5 part, lithia 0.3-1 part, polystyrolsulfon acid 1-3 part, zinc oxide 0.3-1 part, boron oxide 0.3-1 part,
Tellurium dioxide 0.3-1 part.
A kind of smooth polypropylene film, is made up of the component of following weight portion：100 parts of polypropylene masterbatch, smooth master batch 7
Part, 0.3 part of defoamer, 0.4 part of coupling agent, 2 parts of slipping agent, 1 part of dispersant, 0.6 part of antioxidant, 2 parts of glass microballoon, reinforcing agent
1 part；
Described smooth master batch includes following component by weight ratio：100 parts of polypropylene masterbatch, 8 parts of nano barium sulfate, receive
Rice 5 parts of titanium dioxide, 3 parts of CNT, 1 part of calcium carbonate, 2 parts of organo montmorillonite, 3 parts of slipping agent, 3 parts of polyolefin elastomer,
0.3 part of lithia, 1 part of polystyrolsulfon acid, 0.3 part of zinc oxide, 0.3 part of boron oxide, 0.3 part of tellurium dioxide.
A kind of smooth polypropylene film, is made up of the component of following weight portion：100 parts of polypropylene masterbatch, smooth master batch 12
Part, 1.5 parts of defoamer, 1 part of coupling agent, 5 parts of slipping agent, 1.5 parts of dispersant, 1.2 parts of antioxidant, 5 parts of glass microballoon, reinforcing agent
2 parts；
Described smooth master batch includes following component by weight ratio：100 parts of polypropylene masterbatch, 15 parts of nano barium sulfate,
8 parts of nano titanium oxide, 7 parts of CNT, 5 parts of calcium carbonate, 4 parts of organo montmorillonite, 6 parts of slipping agent, polyolefin elastomer 5
Part, 1 part of lithia, 3 parts of polystyrolsulfon acid, zinc oxide part, 1 part of boron oxide, 1 part of tellurium dioxide.
A kind of smooth polypropylene film, is made up of the component of following weight portion：100 parts of polypropylene masterbatch, smooth master batch 9
Part, 0.8 part of defoamer, 0.7 part of coupling agent, 3.5 parts of slipping agent, 1.3 parts of dispersant, 0.9 part of antioxidant, 4 parts of glass microballoon, increasing
Strong 1.5 parts of agent；
Described smooth master batch includes following component by weight ratio：100 parts of polypropylene masterbatch, 11 parts of nano barium sulfate,
6.5 parts of nano titanium oxide, 5 parts of CNT, 3 parts of calcium carbonate, 3 parts of organo montmorillonite, 4.5 parts of slipping agent, polyolefin elastic
4 parts of body, 0.7 part of lithia, 2 parts of polystyrolsulfon acid, 0.6 part of zinc oxide, 0.6 part of boron oxide, 0.6 part of tellurium dioxide.
Described slipping agent be erucyl amide, oleamide, low-molecular-weight polypropylene, paraffin, stearic acid, high-concentration silicone oil,
High molecular weight silicone is according to 1:1:2:2:1:3:The mixture of 1 mixing.
Preferably, described dispersant is one or more of polypropylene wax, palm wax.
Preferably, described coupling agent is methyl hydroxyethylcellulose.
Nano titanium oxide is the super-fine material that particle size is less than 100nm, and its outward appearance is fluffy white powder, has anti-
Ultraviolet, antibacterial, self-cleaning, anti-aging effect.Applications to nanostructures be polymeric material modification open one new
Approach, also lays a good foundation for design, preparation high-performance, multifunctional plastic, the interfacial energy of nanometer titanium dioxide is very big, place
In energy unstable state.
Compared with prior art, the invention has the beneficial effects as follows：
The present invention passes through to add the smooth master batch of unique formula, from nano barium sulfate, nano titanium oxide, CNT
Nano inorganic material, particle diameter is little, insoluble under the temperature conditionss of processing film.Nano inorganic material have greatly than table
Area has highly active suction-operated to slipping agent, can control release and the migration of slipping agent at normal temperatures, effectively delay
Slipping agent moves to the speed of film surface, increased the action time of smooth system.Be conducive to downstream client use when
Effect property extends it is ensured that product quality stability；The addition of nano barium sulfate can lift the tensile property of polypropylene film, fracture
Percentage elongation, impact property, ageing-resistant performance etc.；The present invention passes through to add polyolefin elastomer, polystyrene in smooth master batch
Sulfonic acid is modified to it, lifts its high tenacity, the performance of high impact-resistant power, creatively with the addition of lithia, zinc oxide, oxygen simultaneously
Change boron, tellurium dioxide so that prepared polypropylene film has good mechanical properties, corrosion-resistant, peel strength is high, electric conductivity
Advantage superior, that ductility is good, have simultaneously good antistatic, antibiotic property, weatherability, stability, heat-insulated, uvioresistant,
Anti- self-cleaning, anti-aging effect.Primary raw material and auxiliary material are lower-cost material, and the inorganic filler nature such as auxiliary material is originated
Extensively, so both economical practicality.
Specific embodiment
Embodiment 1
A kind of smooth polypropylene film, is made up of the component of following weight portion：100 parts of polypropylene masterbatch, smooth master batch 7
Part, 0.3 part of defoamer, 0.4 part of coupling agent, 2 parts of slipping agent, 1 part of dispersant, 0.6 part of antioxidant, 2 parts of glass microballoon, reinforcing agent
1 part；
Described smooth master batch includes following component by weight ratio：100 parts of polypropylene masterbatch, 8 parts of nano barium sulfate, receive
Rice 5 parts of titanium dioxide, 3 parts of CNT, 1 part of calcium carbonate, 2 parts of organo montmorillonite, 3 parts of slipping agent, 3 parts of polyolefin elastomer,
0.3 part of lithia, 1 part of polystyrolsulfon acid, 0.3 part of zinc oxide, 0.3 part of boron oxide, 0.3 part of tellurium dioxide.
Described slipping agent be erucyl amide, oleamide, low-molecular-weight polypropylene, paraffin, stearic acid, high-concentration silicone oil,
High molecular weight silicone is according to 1:1:2:2:1:3:The mixture of 1 mixing.
Preferably, described dispersant is one or more of polypropylene wax, palm wax.
Preferably, described coupling agent is methyl hydroxyethylcellulose.
Nano titanium oxide is the super-fine material that particle size is less than 100nm, and its outward appearance is fluffy white powder, has anti-
Ultraviolet, antibacterial, self-cleaning, anti-aging effect.Applications to nanostructures be polymeric material modification open one new
Approach, also lays a good foundation for design, preparation high-performance, multifunctional plastic, the interfacial energy of nanometer titanium dioxide is very big, place
In energy unstable state.
Embodiment 2
A kind of smooth polypropylene film, is made up of the component of following weight portion：100 parts of polypropylene masterbatch, smooth master batch 12
Part, 1.5 parts of defoamer, 1 part of coupling agent, 5 parts of slipping agent, 1.5 parts of dispersant, 1.2 parts of antioxidant, 5 parts of glass microballoon, reinforcing agent
2 parts；
Described smooth master batch includes following component by weight ratio：100 parts of polypropylene masterbatch, 15 parts of nano barium sulfate,
8 parts of nano titanium oxide, 7 parts of CNT, 5 parts of calcium carbonate, 4 parts of organo montmorillonite, 6 parts of slipping agent, polyolefin elastomer 5
Part, 1 part of lithia, 3 parts of polystyrolsulfon acid, zinc oxide part, 1 part of boron oxide, 1 part of tellurium dioxide.
Described slipping agent be erucyl amide, oleamide, low-molecular-weight polypropylene, paraffin, stearic acid, high-concentration silicone oil,
High molecular weight silicone is according to 1:1:2:2:1:3:The mixture of 1 mixing.
Preferably, described dispersant is one or more of polypropylene wax, palm wax.
Preferably, described coupling agent is methyl hydroxyethylcellulose.
Nano titanium oxide is the super-fine material that particle size is less than 100nm, and its outward appearance is fluffy white powder, has anti-
Ultraviolet, antibacterial, self-cleaning, anti-aging effect.Applications to nanostructures be polymeric material modification open one new
Approach, also lays a good foundation for design, preparation high-performance, multifunctional plastic, the interfacial energy of nanometer titanium dioxide is very big, place
In energy unstable state.
Embodiment 3
A kind of smooth polypropylene film, is made up of the component of following weight portion：100 parts of polypropylene masterbatch, smooth master batch 9
Part, 0.8 part of defoamer, 0.7 part of coupling agent, 3.5 parts of slipping agent, 1.3 parts of dispersant, 0.9 part of antioxidant, 4 parts of glass microballoon, increasing
Strong 1.5 parts of agent；
Described smooth master batch includes following component by weight ratio：100 parts of polypropylene masterbatch, 11 parts of nano barium sulfate,
6.5 parts of nano titanium oxide, 5 parts of CNT, 3 parts of calcium carbonate, 3 parts of organo montmorillonite, 4.5 parts of slipping agent, polyolefin elastic
4 parts of body, 0.7 part of lithia, 2 parts of polystyrolsulfon acid, 0.6 part of zinc oxide, 0.6 part of boron oxide, 0.6 part of tellurium dioxide.
Described slipping agent be erucyl amide, oleamide, low-molecular-weight polypropylene, paraffin, stearic acid, high-concentration silicone oil,
High molecular weight silicone is according to 1:1:2:2:1:3:The mixture of 1 mixing.
Preferably, described dispersant is one or more of polypropylene wax, palm wax.
Preferably, described coupling agent is methyl hydroxyethylcellulose.
Nano titanium oxide is the super-fine material that particle size is less than 100nm, and its outward appearance is fluffy white powder, has anti-
Ultraviolet, antibacterial, self-cleaning, anti-aging effect.Applications to nanostructures be polymeric material modification open one new
Approach, also lays a good foundation for design, preparation high-performance, multifunctional plastic, the interfacial energy of nanometer titanium dioxide is very big, place
In energy unstable state.
Claims (7)
1. a kind of smooth polypropylene film is it is characterised in that be made up of the component of following weight portion：100 parts of polypropylene masterbatch, refreshing
Sliding master batch 7-12 part, defoamer 0.3-1.5 part, coupling agent 0.4-1 part, slipping agent 2-5 part, dispersant 1-1.5 part, antioxidant
0.6-1.2 part, glass microballoon 2-5 part, reinforcing agent 1-2 part；
Described smooth master batch includes following component by weight ratio：100 parts of polypropylene masterbatch, nano barium sulfate 8-15 part, receive
Rice titanium dioxide 5-8 part, CNT 3-7 part, calcium carbonate 1-5 part, organo montmorillonite 2-4 part, slipping agent 3-6 part, polyolefin
Elastomer 3-5 part, lithia 0.3-1 part, polystyrolsulfon acid 1-3 part, zinc oxide 0.3-1 part, boron oxide 0.3-1 part, dioxy
Change tellurium 0.3-1 part.
2. smooth polypropylene film according to claim 1 is it is characterised in that a kind of smooth polypropylene film, by following
The component of weight portion is made：100 parts of polypropylene masterbatch, 7 parts of smooth master batch, 0.3 part of defoamer, 0.4 part of coupling agent, slipping agent 2
Part, 1 part of dispersant, 0.6 part of antioxidant, 2 parts of glass microballoon, 1 part of reinforcing agent；
Described smooth master batch includes following component by weight ratio：100 parts of polypropylene masterbatch, nano barium sulfate 8 part, nanometer two
5 parts of titanium oxide, 3 parts of CNT, 1 part of calcium carbonate, 2 parts of organo montmorillonite, 3 parts of slipping agent, 3 parts of polyolefin elastomer, oxidation
0.3 part of lithium, 1 part of polystyrolsulfon acid, 0.3 part of zinc oxide, 0.3 part of boron oxide, 0.3 part of tellurium dioxide.
3. smooth polypropylene film according to claim 1 is it is characterised in that be made up of the component of following weight portion：Poly-
100 parts of propylene masterbatch, 12 parts of smooth master batch, 1.5 parts of defoamer, 1 part of coupling agent, 5 parts of slipping agent, 1.5 parts of dispersant, antioxidant
1.2 parts, 5 parts of glass microballoon, 2 parts of reinforcing agent；
Described smooth master batch includes following component by weight ratio：100 parts of polypropylene masterbatch, nano barium sulfate 15 part, nanometer
8 parts of titanium dioxide, 7 parts of CNT, 5 parts of calcium carbonate, 4 parts of organo montmorillonite, 6 parts of slipping agent, 5 parts of polyolefin elastomer, oxygen
Change 1 part of lithium, 3 parts of polystyrolsulfon acid, zinc oxide part, 1 part of boron oxide, 1 part of tellurium dioxide.
4. smooth polypropylene film according to claim 1 is it is characterised in that a kind of smooth polypropylene film, by following
The component of weight portion is made：100 parts of polypropylene masterbatch, 9 parts of smooth master batch, 0.8 part of defoamer, 0.7 part of coupling agent, slipping agent
3.5 parts, 1.3 parts of dispersant, 0.9 part of antioxidant, 4 parts of glass microballoon, 1.5 parts of reinforcing agent；
Described smooth master batch includes following component by weight ratio：100 parts of polypropylene masterbatch, nano barium sulfate 11 part, nanometer
6.5 parts of titanium dioxide, 5 parts of CNT, 3 parts of calcium carbonate, 3 parts of organo montmorillonite, 4.5 parts of slipping agent, polyolefin elastomer 4
Part, 0.7 part of lithia, 2 parts of polystyrolsulfon acid, 0.6 part of zinc oxide, 0.6 part of boron oxide, 0.6 part of tellurium dioxide.
5. smooth polypropylene film according to claim 1 is it is characterised in that described slipping agent is erucyl amide, oleic acid
Acid amides, low-molecular-weight polypropylene, paraffin, stearic acid, high-concentration silicone oil, high molecular weight silicone are according to 1:1:2:2:1:3:1 mixing
Mixture.
6. smooth polypropylene film according to claim 1 is it is characterised in that described dispersant is polypropylene wax, palm
One or more of wax.
7. smooth polypropylene film according to claim 1 is it is characterised in that described coupling agent is methyl hydroxyethyl cellulose
Element.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610778441.3A CN106380683A (en) | 2016-08-31 | 2016-08-31 | Slip polypropylene film |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610778441.3A CN106380683A (en) | 2016-08-31 | 2016-08-31 | Slip polypropylene film |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN106380683A true CN106380683A (en) | 2017-02-08 |
Family
ID=57938589
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201610778441.3A Pending CN106380683A (en) | 2016-08-31 | 2016-08-31 | Slip polypropylene film |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN106380683A (en) |
Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107325408A (en) * | 2017-08-23 | 2017-11-07 | 安徽国泰印务有限公司 | A kind of flame retardant plastics packaging material |
| CN107603031A (en) * | 2017-09-29 | 2018-01-19 | 福建和盛塑业有限公司 | TiO2/BaSO4Modified low surface energy, self-lubricating polypropylene planomural enhancing IFB bellowss and preparation method thereof |
| CN109438834A (en) * | 2018-10-09 | 2019-03-08 | 中国石油化工股份有限公司 | A kind of polypropylene casting membrane material and preparation method thereof |
| CN110878157A (en) * | 2019-12-04 | 2020-03-13 | 中山火炬职业技术学院 | Low-solvent-residue master batch applied to BOPP printing film |
| CN112409701A (en) * | 2020-11-23 | 2021-02-26 | 金发科技股份有限公司 | Low-density conductive polypropylene composition and preparation method and application thereof |
| CN115536873A (en) * | 2022-11-02 | 2022-12-30 | 佛山市南海区承欣塑料助剂有限公司 | Preparation method of anti-sticking smooth master batch for environment-friendly composite film |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105172284A (en) * | 2015-07-30 | 2015-12-23 | 中山火炬职业技术学院 | BOPP film with endurable and smoothness characteristics and preparation method therefor |
| CN105315555A (en) * | 2015-11-11 | 2016-02-10 | 宿迁市金田塑业有限公司 | High-transmittance antistatic BOPP thin film and production process thereof |
| CN105694307A (en) * | 2016-03-11 | 2016-06-22 | 汤卓群 | Polyvinylidene fluoride nano-film material and preparation method thereof |
-
2016
- 2016-08-31 CN CN201610778441.3A patent/CN106380683A/en active Pending
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105172284A (en) * | 2015-07-30 | 2015-12-23 | 中山火炬职业技术学院 | BOPP film with endurable and smoothness characteristics and preparation method therefor |
| CN105315555A (en) * | 2015-11-11 | 2016-02-10 | 宿迁市金田塑业有限公司 | High-transmittance antistatic BOPP thin film and production process thereof |
| CN105694307A (en) * | 2016-03-11 | 2016-06-22 | 汤卓群 | Polyvinylidene fluoride nano-film material and preparation method thereof |
Cited By (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107325408A (en) * | 2017-08-23 | 2017-11-07 | 安徽国泰印务有限公司 | A kind of flame retardant plastics packaging material |
| CN107603031A (en) * | 2017-09-29 | 2018-01-19 | 福建和盛塑业有限公司 | TiO2/BaSO4Modified low surface energy, self-lubricating polypropylene planomural enhancing IFB bellowss and preparation method thereof |
| CN107603031B (en) * | 2017-09-29 | 2020-04-07 | 福建和盛塑业有限公司 | TiO2/BaSO4Modified low-surface-energy self-lubricating polypropylene flat-wall reinforced IFB corrugated pipe and preparation method thereof |
| CN109438834A (en) * | 2018-10-09 | 2019-03-08 | 中国石油化工股份有限公司 | A kind of polypropylene casting membrane material and preparation method thereof |
| CN109438834B (en) * | 2018-10-09 | 2022-09-09 | 中国石油化工股份有限公司 | Polypropylene casting film material and preparation method thereof |
| CN110878157A (en) * | 2019-12-04 | 2020-03-13 | 中山火炬职业技术学院 | Low-solvent-residue master batch applied to BOPP printing film |
| CN112409701A (en) * | 2020-11-23 | 2021-02-26 | 金发科技股份有限公司 | Low-density conductive polypropylene composition and preparation method and application thereof |
| CN112409701B (en) * | 2020-11-23 | 2022-04-19 | 金发科技股份有限公司 | Low-density conductive polypropylene composition and preparation method and application thereof |
| CN115536873A (en) * | 2022-11-02 | 2022-12-30 | 佛山市南海区承欣塑料助剂有限公司 | Preparation method of anti-sticking smooth master batch for environment-friendly composite film |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN106380683A (en) | Slip polypropylene film | |
| WO2018086159A1 (en) | High strength nano plastic and preparation method therefor | |
| CN103665821B (en) | Arctic rubber | |
| CN104592632B (en) | High tenacity high modulus polypropylene composite and preparation method thereof | |
| CN104194300B (en) | Ageing-resistant antibacterial PC/ABS blend alloy and preparation method thereof | |
| CN106243499A (en) | A kind of antistatic antibiotic BOPP thin film | |
| CN106380684A (en) | Osmosis-resistant polypropylene film | |
| CN106336574A (en) | BOPP film | |
| CN110564143B (en) | Biaxially oriented polyketone co-extrusion barrier film and preparation method thereof | |
| CN104802482A (en) | Three-layer co-extruded PP (polypropylene)/PE (polyethylene)/PP upward-blown film and preparation method thereof | |
| CN110760169A (en) | Barrier material and preparation method thereof | |
| CN103289342A (en) | High heat conduction reinforced PC/PBT alloy | |
| CN106380687A (en) | Low-temperature-resistant polypropylene film material | |
| CN106317636A (en) | Modified polypropylene film | |
| CN110724333B (en) | Linear low-density polyethylene additive master batch, preparation method and application thereof | |
| CN104744775A (en) | Composite material for polyethylene film and preparation method thereof | |
| CN103144392B (en) | Photostable antimicrobial polypropylene material product and preparation method thereof | |
| KR101427677B1 (en) | Nylon Film for Pouch | |
| CN114290784A (en) | High-barrier bio-based nylon film with antibacterial property and preparation method and application thereof | |
| CN104845121A (en) | Glass-fiber reinforced PET/PTT/TPEE composite material | |
| CN107674278A (en) | A kind of preparation method of NEW TYPE OF COMPOSITE Based Full-degradable Plastics Film | |
| CN113912948A (en) | Polypropylene nano composite material with low-temperature toughness and rigidity and toughness and preparation method thereof | |
| CN106279988A (en) | A kind of corrosion-resistant BOPP thin film | |
| CN110964258B (en) | Low-shrinkage polypropylene composition and preparation method and application thereof | |
| CN106084487A (en) | A kind of weather resistance environmental protection type automobile bumper material |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| RJ01 | Rejection of invention patent application after publication |
Application publication date: 20170208 |
|
| RJ01 | Rejection of invention patent application after publication |