CN106359391A - Cyclaniliprole-containing pesticide composition - Google Patents

Cyclaniliprole-containing pesticide composition Download PDF

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Publication number
CN106359391A
CN106359391A CN201610741396.4A CN201610741396A CN106359391A CN 106359391 A CN106359391 A CN 106359391A CN 201610741396 A CN201610741396 A CN 201610741396A CN 106359391 A CN106359391 A CN 106359391A
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China
Prior art keywords
cyclaniliprole
pesticidal combination
ethyl pleocidin
test
combination containing
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CN201610741396.4A
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Chinese (zh)
Inventor
刘永
曹欢
黄柯程
朱卫锋
李鹏飞
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Shenzhen Noposion Agrochemicals Co Ltd
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Shenzhen Noposion Agrochemicals Co Ltd
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Priority to CN201610741396.4A priority Critical patent/CN106359391A/en
Publication of CN106359391A publication Critical patent/CN106359391A/en
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    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/48—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with two nitrogen atoms as the only ring hetero atoms
    • A01N43/56—1,2-Diazoles; Hydrogenated 1,2-diazoles
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/02—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms
    • A01N43/04—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms with one hetero atom
    • A01N43/22—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms with one hetero atom rings with more than six members

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  • Life Sciences & Earth Sciences (AREA)
  • Agronomy & Crop Science (AREA)
  • Pest Control & Pesticides (AREA)
  • Plant Pathology (AREA)
  • Health & Medical Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Dentistry (AREA)
  • General Health & Medical Sciences (AREA)
  • Wood Science & Technology (AREA)
  • Zoology (AREA)
  • Environmental Sciences (AREA)
  • Agricultural Chemicals And Associated Chemicals (AREA)

Abstract

The invention discloses a cyclaniliprole-containing pesticide composition. The effective components of the composition are cyclaniliprole and spinetoram in a mass ratio of 80:1-1:80. The composition has obvious synergistic actions, has wider control spectrum, overcomes and postpones the drug resistance of pests, reduces the pesticide consumption, lowers the residue level of the pesticides on crops, reduces the environmental pollution, is safe for people and livestock, and has favorable environmental compatibility. The composition is suitable for controlling rice stem borers, rice leaf rollers, thrips, plant hoppers, aphids, cabbage moths and asparagus caterpillars on rice and vegetable crops.

Description

A kind of Pesticidal combination containing cyclaniliprole
Technical field
The present invention relates to a kind of Pesticidal combination, more particularly, to a kind of Pesticidal combination containing cyclaniliprole and The application of its preventing and treating crop pests, belongs to technical field of pesticide.
Background technology
Cyclaniliprole (test code number iki 3106) is the bisamide class that Japanese Ishihara Sangyo Kaisha, Ltd. develops Insecticide.There is the insecticidal activity of wide spectrum, to diamondback moth, Prodenia litura, aleyrodid, aphid, thrips, housefly, liriomyza bryoniae, Coptotermes formosanus Shtrari. etc. There is good prevention effect, and there is good systemic activity, although possessing the double of ryanodine receptor inhibitor in structure Amide structure, but there are different mechanism of action.
Ethyl pleocidin, english common name: spinetoram, is a kind of novel many of Dow AgroSciences's exploitation Bacteriocidin insecticides, are the second filial generation product of pleocidin, are by spinosyn a and two kinds of pleocidin of spinosyn d The novel pesticide that class compound finally gives in the presence of catalyst, reactant and solvent after chemical modification.Ethyl is many Bacteriocidin is the upgrading products of pleocidin, and its insecticidal activity is the several times of pleocidin, and field using dosage compares minimizing number Times.Currently, in the case that resistance in pleocidin, ethyl pleocidin there is also higher resistance risk.In addition, second Bacteriocidin single use cost in Quito is higher.
In the real process of agricultural production, pest control is easiest to generate the problem that the generation of pest resistance to insecticide.No Compounded with kind composition, be the very common method of preventing and treating resistant insect.Heterogeneity is compounded, and is imitated according to practical application Really, to judge that certain compounds is potentiation, addition or antagonism.In most cases, the compounding effect of pesticide is all phase Plus effect, really have potentiation compounding seldom, especially potentiation clearly, co-toxicity coefficient very high compounding just more Few.
There is no relevant report with regard to cyclaniliprole with the compounding of ethyl pleocidin and application at present.
Content of the invention
It is an object of the invention to provide a kind of potentiation is obvious, prevention effect is good, dosage is low, safe, preventing and treating Compose wide Pesticidal combination.
It is a further object of the present invention to provide a kind of Recompounded pesticide containing cyclaniliprole and ethyl pleocidin Compositionss are used for the preventing and treating of crop pests.
The technical scheme is that a kind of Pesticidal combination containing cyclaniliprole, it is characterized in that effectively becoming Be divided into cyclaniliprole and ethyl pleocidin, both mass ratioes be 80:1～1:80, preferred mass than for 10:1～ 1:10.Compositionss can be processed into aqueous emulsion, microemulsion, suspending agent, granule, wettable powder, water using known method Dispersible granule, microcapsule suspending agent or ultra low volume liquids.
Pesticidal combination containing cyclaniliprole proposed by the present invention is used for preventing and treating the purposes of insect on crops, institute The crops stated include cereal crops, legume crop, melon crop；Described insect includes striped rice borer, rice leaf roller, Ji Horse, plant hopper, aphid, diamondback moth and beet armyworm.
Pesticidal combination of the present invention can also have weeding with other, the compound of bactericidal property is used in mixed way, Can also be used in mixed way with nematicide, protective agent, growth regulator, nutrient for plants or soil conditioner.
With respect to prior art, the good effect that the present invention produces is as follows:
1st, compositionss have obvious potentiation, decrease dosage, can effectively prevent and treat existing medicament has been produced anti- The insect of property.
2nd, dispenser of compositionss simultaneous can control various pests, reduces drug cost.
3rd, in compositionss, the mechanism of action of 2 effective ingredient is different, and by mixture, action site increases, is conducive to overcoming With delay insect to develop immunity to drugs, extend medicament service life.
Specific embodiment
With reference to embodiment, the present invention will be further described.
The embodiment of the present invention following Biological Testing Examples and example of formulations further illustrate the application and actively of compositionss Effect, but the present invention is only limitted to absolutely not these examples.Described below is only the preferable embodiment of the present invention, is used only for description originally Invention is it is impossible to be interpreted as limitation of the scope of the invention.It should be pointed out that all done within the spirit and principles in the present invention Any modification, equivalent and improvement etc., should be included within the scope of the present invention.
Inventor passes through substantial amounts of indoor bioassay experiment sieving, has been surprisingly found that cyclaniliprole is killed with ethyl more After rhzomorph is compounded with aforementioned proportion, the various pests such as striped rice borer, rice leaf roller, plant hopper, thrips, aphid and diamondback moth are had Significantly potentiation.On the basis of above-mentioned discovery, through symphyogenetic quantitative analyses are carried out to compositionss, define this Invention, that is, with cyclaniliprole for a kind of effective ingredient, ethyl pleocidin is another effective ingredient, and two kinds become split-phase auxiliary Coordinate, synergism, plays excellent potentiation.
The Pesticidal combination of the embodiment of the present invention can according to the crop of required preventing and treating, local environment condition, prevention and controls, The various factors such as cost accounting, effective ingredient are processed into together with auxiliary agent and carrier (filler) acceptable in pesticides application Any one dosage form, preferred dosage form is aqueous emulsion, microemulsion, granule, suspending agent, wettable powder, microcapsule suspending agent, moisture Shot agent or ultra low volume liquids.Adjuvant used, carrier and process technology adopt known component.In above-mentioned various dosage forms, The gross mass percentage composition of cyclaniliprole and ethyl pleocidin is 0.5%～80%, for example, when When the weight/mass percentage composition of cyclaniliprole and ethyl pleocidin is 20% and 20%, total content is 40%, specifically always Shown in the following example of value of weight/mass percentage composition.
In order that the purpose of the present invention, technical scheme and pluses and minuses become more apparent, the present invention uses following tool further Body test example illustrates.In the examples below, unless otherwise indicated, all percentage ratios are mass percent.
First, example of formulations
Embodiment 1:30%cyclaniliprole ethyl pleocidin suspending agent (cyclaniliprole: ethyl is many Bacteriocidin=1:1)
Make according to common process, wherein cyclaniliprole 15g, ethyl pleocidin 15g, sodium lignin sulfonate (dispersant) 4g, ethylene glycol (antifreeze) 4g, bentonite (thickening agent) 0.15g, organic silicone (defoamer) 0.4g, deionized water Mend to 100g.
Embodiment 2:77%cyclaniliprole ethyl pleocidin water dispersible granules (cyclaniliprole: second Quito bacteriocidin=1:10)
Make according to common process, cyclaniliprole 7g, ethyl pleocidin 70g, Negel (dispersion Agent) 2g, sodium lignin sulfonate (dispersant) 4g, sodium lauryl sulphate (wetting agent) 1g, ammonium sulfate (disintegrating agent) 3g, lightweight carbon Sour calcium (filler) complements to 100g.
Embodiment 3:55%cyclaniliprole ethyl pleocidin wettable powder (cyclaniliprole: second Quito bacteriocidin=10:1)
Cyclaniliprole 50g, ethyl pleocidin 5g, sodium lauryl sulphate (wetting agent) 2g, lignin sulfonic acid Sodium (dispersant) 3g, nno (dispersant) 5g, Kaolin complements to 100g.
Embodiment 4:2.1%cyclaniliprole ethyl pleocidin microemulsion (cyclaniliprole: ethyl is many Bacteriocidin=1:20)
Make according to common process, cyclaniliprole 0.1g, ethyl pleocidin 2g, n- methyl pyrrolidone (helps Solvent) 10g, calcium dodecyl benzene sulfonate (emulsifying agent) 8g, phenethyl phenol polyethenoxy ether (emulsifying agent) 7g, triphenoethyl benzene phenol Polyoxyethylene (emulsifying agent) 5g, deionized water (carrier) complements to 100g.
Embodiment 5:21%cyclaniliprole ethyl pleocidin microcapsule suspending agent (cyclaniliprole: second Quito bacteriocidin=20:1)
Cyclaniliprole 20g, ethyl pleocidin 1g, Ketohexamethylene (solvent) 1g, polyisocyanates (firming agent) 0.4g, ethylene glycol (solvent) 0.4g, arabic gum (thickening agent) 1g, deionized water (carrier) complements to 100g.
Embodiment 6:41%cyclaniliprole ethyl pleocidin aqueous emulsion (cyclaniliprole: ethyl is many Bacteriocidin=1:40)
Cyclaniliprole 1g, ethyl pleocidin 40g, calcium dodecyl benzene sulfonate (emulsifying agent) 2.1g, phenethyl Phenol polyethenoxy ether (emulsifying agent) 1.5g, Ketohexamethylene (solvent) 10.1g, toluene (solvent) 10.2g, xanthan gum (thickening agent) 0.5g, deionized water (carrier) complements to 100g.
Embodiment 7:0.41%cyclaniliprole ethyl pleocidin granule (cyclaniliprole: ethyl Pleocidin=40:1)
Cyclaniliprole 0.4g, ethyl pleocidin 0.01g, dioctyl sodium sulphosuccinate 1g, wood moulding sodium sulfonate 2g, polyvinyl alcohol-co-vinyl base alkyl ether copolymer 2.5g, clay complements to 100g.
Embodiment 8:1.62%cyclaniliprole ethyl pleocidin ultra low volume liquids (cyclaniliprole: ethyl pleocidin=80:1)
Cyclaniliprole 1.60g, ethyl pleocidin 0.02g, n- methyl pyrrolidone 10g, n, n- dimethyl methyl Amide 15g, n-octyl alcohol 2g, dodecyl sodium sulfonate calcium 2g, OPEO 3g, c10 aromatic hydrocarbons complements to 100g.
Embodiment 9:0.81%cyclaniliprole ethyl pleocidin granule (cyclaniliprole: ethyl Pleocidin=1:80)
Cyclaniliprole 0.01g, ethyl pleocidin 0.8g, dioctyl sodium sulphosuccinate 1g, wood moulding sodium sulfonate 2g, polyvinyl alcohol-co-vinyl base alkyl ether copolymer 2.5g, clay complements to 100g.
2nd, indoor bioassay test and field control effectiveness test embodiment
One) indoor bioassay test example
Bioassay test embodiment 1:cyclaniliprole, the ethyl pleocidin and different ratio room to diamondback moth Interior virulence determination test.
Subjects: diamondback moth (plutella xylostella), indoors artificial raises many generations.
Test method: leaf dipping method.Respectively the mother solution of each mixed agent is diluted to five series concentration during test, is respectively placed in Standby in beaker.Using first soaking the method that leaf is followed by worm, the blade of the same size not in contact with any medicament is being configured Take out after soaking 5s in medicinal liquid, naturally dry, put in insect box, then connect for examination 3 instar larvaes, raise under the conditions of 25 DEG C Support, often process 4 repetitions, often repeat test worm number used and be 50, set blank simultaneously, check dead borer population in 48h, calculate dead Rate of dying and corrected mortality, try to achieve virulence regression equation and calculate lc50Value.If comparison mortality rate is more than 10%, it is invalid to be considered as Test.Computing formula is as follows:
Actual measurement toxicity index (ati)=(standard agent lc50/ reagent agent lc50)×100
Percentage composition+b the medicament toxicity index of a in theoretical toxicity index (tti)=a medicament toxicity index × mixture × mixed The percentage composition of b in agent
Co-toxicity coefficient (ctc)=(mixture surveys toxicity index ati/ mixture theoretical toxicity index tti) × 100
Calculate co-toxicity coefficient (ctc) according to the abundant method of Sun Yun, as ctc 80, then compositionss show as antagonism, as 80 ＜ Ctc ＜ 120, then compositionss show as summation action, as ctc 120, then compositionss show as potentiation.
Result of the test is shown in Table 1.
Table 1 cyclaniliprole, the ethyl pleocidin and different ratio Toxicity Determination test knot to diamondback moth Really (48h)
From result of the test in table 1, cyclaniliprole and ethyl pleocidin between 80:1～1:80, to little The co-toxicity coefficient (ctc) of diamond-back moth is all higher than 120, shows as potentiation.Wherein, when cyclaniliprole is sterilized with ethyl more When element is between 10:1～1:10, co-toxicity coefficient (ctc) is all higher than 200, and diamondback moth is shown as with significant potentiation.
Bioassay test embodiment 2:cyclaniliprole, ethyl pleocidin and different ratio are to yellow breast thrips Toxicity Determination is tested.
Subjects: yellow breast thrips (thrips hawaiiensis), indoor feeding many generations.
First cyclaniliprole, ethyl pleocidin are made into mother solution with enough acetone solutions, then are diluted to clear water Some Concentraton gradient are it is ensured that having prepared that medicinal liquid is transparent, being uniformly dispersed.After preparing medicinal liquid, make centrifuge tube medicine film (pipe first Wall is pricked some pores), take 1ml medicinal liquid to add in pipe, waggle until medicinal liquid in pipe medicine uniform, unnecessary medicinal liquid is inclined Go out, Indoor Natural dries.The medicinal liquid using same concentrations again impregnates banana flowers petal, until after medicine film and leaching medicine petal dry, will Band medicine petal is put in medicine film pipe, forms leaf pipe medicine film.Finally, access test worm 30 of participating in the experiment, and cultivate observation, check after 48h The survival condition of test worm, with fine, soft fur pen touch test worm motionless as death.Using the banana flowers petal of moisture film pipe and leaching clear water as right According to group, every concentration processes 4 repetitions.Matched group mortality rate ＜ 10% is efficiency test.Computational methods are real with bioassay test Apply example 1, result of the test is shown in Table 2.
Table 2 cyclaniliprole, ethyl pleocidin and different ratio are tested to the Toxicity Determination of yellow breast thrips Result (48h)
From result of the test in table 2, cyclaniliprole and ethyl pleocidin between 80:1～1:80, to Huang The co-toxicity coefficient (ctc) of breast thrips is all higher than 120, shows as potentiation.Wherein, when cyclaniliprole is killed with ethyl more When rhzomorph is between 10:1～1:10, co-toxicity coefficient (ctc) is all higher than 190, shows as significant potentiation to yellow breast thrips.
Two) field control effectiveness test embodiment
1st, the prevention effect to paddy rice rice leaf roller
Test and carry out in June, 2015, test site is located at Fengcheng rice terrace, test adopts knapsack sprayer Rice plant is carried out with even spraying, the paddy rice growth of selection is basically identical, that a situation arises is basically identical for rice leaf roller. And 3d, 7d and 15d investigate leaf roll rate after medicine, result of the test refers to table 3.From table 3, result of the test can draw, After cyclaniliprole is compounded with ethyl pleocidin, each example of formulations potentiation is obvious；3d, 7d and 15d after dispenser Each compound drug is also significantly better than single dose to the prevention effect of rice leaf roller.
Table 3 cyclaniliprole compounds the prevention effect to paddy rice rice leaf roller with ethyl pleocidin
2nd, the prevention effect to Laphygma exigua Hubner
Test and carry out in Nanchang City, Jiangxi Province one Caulis et Folium Brassicae capitatae in September, 2014, test is using knapsack sprayer to Caulis et Folium Brassicae capitatae Herb carries out even spraying, investigates insect population before medicine, and 3d, 7d and 15d investigation borer population alive after medicine, and result of the test refers to table 4.From table 4, result of the test can draw, after cyclaniliprole is compounded with ethyl pleocidin, various dosage form potentiations Substantially；After dispenser, each compound drug of 3d, 7d and 15d is also significantly better than single dose to the prevention effect of beet armyworm.
Table 4 cyclaniliprole and the prevention effect to Laphygma exigua Hubner for the ethyl pleocidin complex composition
3rd, the prevention effect to Fructus Musae Huang breast thrips
With regard to borer pest in reference " pesticide field efficacy medicine test criterion (two) " (the Institute for the Control of Agrochemicals of the Ministry of Agriculture,PRC, 2004) Pesticide field efficacy medicine test method carry out.Experimental plot adopts random district's groups arrangement, often processes and is repeated 4 times, every cell Fructus Musae 2 Strain；First time spraying time is on April 25th, 2015, selects to be exactly in squaring period plant medication；Whole alabastrum is uniformly sprayed Till wet, every dispenser in 2 days once, until the 8th comb fruit bract open till, concrete spraying time be respectively April 28,5 The moon 1, May 4 and May 7, spray clear water is comparison.In May 10 survey result.Every cell is fixing to investigate 2 plants, every plant Investigation from top to bottom 7 comb fruit, often combs 10 fruits of investigation and refers to.Record each really refer on the black speck number that produces because being caused harm by thrips.
Really refer to aggrieved rate (%)=aggrieved fruit index/total fruit index × 100
Prevention effect (%)=(check plot black speck number-treatment region black speck number)/check plot black speck number × 100
Result of the test refers to table 5.From table 5, result of the test can draw, cyclaniliprole and ethyl pleocidin After compounding, various dosage form potentiations are obvious；After dispenser, each compound drug is also significantly better than list to the prevention effect of beet armyworm Agent.
Table 5 cyclaniliprole prevention effect to Fructus Musae Huang breast thrips with ethyl pleocidin complex composition

Claims (5)

1. a kind of Pesticidal combination containing cyclaniliprole, is characterized in that effective ingredient is cyclaniliprole and second Quito bacteriocidin, both mass ratioes are 80:1～1:80.
2. the Pesticidal combination containing cyclaniliprole according to claim 1, is characterized in that effective ingredient The mass ratio of cyclaniliprole and ethyl pleocidin is 10:1～1:10.
3. the Pesticidal combination containing cyclaniliprole according to claim 1 and 2, is characterized in that having in compositionss Effect composition gross mass percentage composition is 0.5%～80%.
4. the Pesticidal combination containing cyclaniliprole according to claim 3, is characterized in that the dosage form of compositionss For aqueous emulsion, microemulsion, suspending agent, granule, wettable powder, water dispersible granules, microcapsule suspending agent or ultra low volume liquids.
5. the Pesticidal combination containing cyclaniliprole described in claim 1 is used for preventing and treating Oryza sativa L., on vegetable crop The purposes of striped rice borer, rice leaf roller, thrips, plant hopper, aphid, diamondback moth and beet armyworm.
CN201610741396.4A 2016-08-27 2016-08-27 Cyclaniliprole-containing pesticide composition Pending CN106359391A (en)

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Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103518767B (en) * 2006-12-14 2016-06-08 石原产业株式会社 Pesticide composition
CN106212464A (en) * 2016-08-02 2016-12-14 佛山市盈辉作物科学有限公司 A kind of Pesticidal combination containing ethyl pleocidin

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103518767B (en) * 2006-12-14 2016-06-08 石原产业株式会社 Pesticide composition
CN106212464A (en) * 2016-08-02 2016-12-14 佛山市盈辉作物科学有限公司 A kind of Pesticidal combination containing ethyl pleocidin

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Application publication date: 20170201