CN106350326A - Surface tension increasing agent for hydrocarbon cleaning agent as well as preparation method and use method of surface tension increasing agent - Google Patents
Surface tension increasing agent for hydrocarbon cleaning agent as well as preparation method and use method of surface tension increasing agent Download PDFInfo
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- CN106350326A CN106350326A CN201610717297.2A CN201610717297A CN106350326A CN 106350326 A CN106350326 A CN 106350326A CN 201610717297 A CN201610717297 A CN 201610717297A CN 106350326 A CN106350326 A CN 106350326A
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/72—Ethers of polyoxyalkylene glycols
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/02—Anionic compounds
- C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
- C11D1/14—Sulfonic acids or sulfuric acid esters; Salts thereof derived from aliphatic hydrocarbons or mono-alcohols
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/162—Organic compounds containing Si
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/18—Hydrocarbons
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/36—Organic compounds containing phosphorus
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/36—Organic compounds containing phosphorus
- C11D3/364—Organic compounds containing phosphorus containing nitrogen
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/37—Polymers
- C11D3/3703—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- C11D3/3707—Polyethers, e.g. polyalkyleneoxides
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/37—Polymers
- C11D3/3746—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
- C11D3/3757—(Co)polymerised carboxylic acids, -anhydrides, -esters in solid and liquid compositions
- C11D3/3765—(Co)polymerised carboxylic acids, -anhydrides, -esters in solid and liquid compositions in liquid compositions
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D7/00—Compositions of detergents based essentially on non-surface-active compounds
- C11D7/22—Organic compounds
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D7/00—Compositions of detergents based essentially on non-surface-active compounds
- C11D7/22—Organic compounds
- C11D7/24—Hydrocarbons
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- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Detergent Compositions (AREA)
Abstract
The invention provides a surface tension increasing agent for a hydrocarbon cleaning agent. The surface tension increasing agent is characterized by consisting of or being prepared from the following ingredients in percentage by mass: 80-95% of an organic silicon compound, 0-10% of a stabilizer, 0-10 parts of a dispersant and 0-10% of a penetrant, wherein the ingredients certainty include at least one of the stabilizer, the dispersant and the penetrant. The product provided by the invention is wide in application range, has favorable cleanability, and is capable of effectively preventing secondary pollution of washed-off oil stain. The surface tension increasing agent is also capable of reducing the cleaning agent brought away by workpieces, and reducing losses in a cleaning process.
Description
Technical field
The invention belongs to cleaning additive field, in particular it relates to a kind of surface tension for agent for carbon hydrogen detergent increases
Agent and its preparation and application.
Background technology
Agent for carbon hydrogen detergent system pass through to distill the crude oil obtain stay a point solvent, have petroleum, petroleum Hydrocarbon, hydrocarbon
Series of compounds, hydrocarbon (hydrocarbon), industrial gasoline etc., agent for carbon hydrogen detergent has good environmental protection characteristic and cleansing power, hydrocarbon cleaning
Agent has good environmental protection characteristic and cleansing power, progressively becomes one of important industrial cleaning agent of a class.
Agent for carbon hydrogen detergent is good to processing oil cleaning performance, and the Cleaning principle using agent for carbon hydrogen detergent really adopts oiliness thing
The principle of matter similar compatibility, inner in a certain amount of solvent (agent for carbon hydrogen detergent), dissolve in the solute (work containing greasy dirt to be cleaned
Part).In the conventional method, this cleaning way be infinite dilution ablution, when the greasy dirt in abluent molten to a certain extent after, meeting
Exceed the greasy dirt amount of workpiece itself, lead to abluent to have been out the effect cleaned.
Now, often to be carried out from the mode more renewing liquid, and in order to reduce abluent consumption, existing mode is,
Substitute by groove, pit moves forward, for example: if abluent has 3 grooves, 2 grooves are replaced with former 1 groove, by 3 by the whole emptying of 1 groove the dirtiest
Groove replaces with former 2 grooves, adds new liquid in 3 new grooves.As circulation, it is substantially still simple consumption agent for carbon hydrogen detergent
Mode carrying out.
One side the method leads to substantial amounts of waste, is on the other hand also possible to cause environmental problem.
Content of the invention
It is contemplated that overcoming drawbacks described above, providing one kind can improve agent for carbon hydrogen detergent task performance, realizing hydrocarbon cleaning
The surface tension for agent for carbon hydrogen detergent that agent is efficiently utilized increases agent.
Specifically, a kind of surface tension for agent for carbon hydrogen detergent that the present invention provides increases agent it is characterised in that by such as
The group of lower mass percent is grouped into or is prepared from:
That is, stabilizer, dispersant wherein, stabilizer, dispersant, at least one in penetrating agent are necessarily comprised in component,
Can not be all 0 situation with penetrating agent.
Further, a kind of surface tension for agent for carbon hydrogen detergent according to the present invention increases agent, also has such
Feature: i.e., above-mentioned organo-silicon compound for silicon atom number be less than 10 short chain organo-silicon compound.
Further, a kind of surface tension for agent for carbon hydrogen detergent according to the present invention increases agent, also has such
Feature: i.e., above-mentioned organo-silicon compound be preferably silicon atom number be 2-4 short chain organo-silicon compound.
Further, a kind of surface tension for agent for carbon hydrogen detergent according to the present invention increases agent, also has such
Feature: i.e., the molecular weight of aforementioned stable agent and/or dispersant and/or penetrating agent be 0.2-10 times of organo-silicon compound.
Further, a kind of surface tension for agent for carbon hydrogen detergent according to the present invention increases agent, also has such
Feature: i.e., 1-20 times of a length of organo-silicon compound of chain of aforementioned stable agent and/or dispersant and/or penetrating agent.
I.e., aforementioned stable agent and/or dispersant and/or penetrating agent are most preferably and silanes structure or property phase
Imitative compound.
Further, a kind of surface tension for agent for carbon hydrogen detergent according to the present invention increases agent, also has such
Feature: i.e., above-mentioned organo-silicon compound be selected from silane, siloxanes；
Aforementioned stable agent is selected from organic phosphine compound, organic phospho acid salt compound, polycarboxylic acid compound, alkene or poly-
One or more of olefin(e) compound；
Above-mentioned dispersant be selected from fatty acid, aliphatic amide type, esters, paraffin class, metal soap, low molecule wax class,
One or more of alkene or polyolefin compound；
Above-mentioned penetrating agent is selected from one or more of nonionic surfactant, anion surfactant.
Further, a kind of surface tension for agent for carbon hydrogen detergent according to the present invention increases agent, also has such
Feature: i.e., aforementioned stable agent preferably be selected from ATMP, 1-hydroxy ethylidene-1,1-diphosphonic acid, ethylene diamine tetra methylene phosphonic acid sodium, second two
Amine four methylenephosphonic acid, diethylene triamine pentamethylene phosphonic, 2- phosphonobutane -1,2,4- tricarboxylic acids, PAPE, 2- hydroxyl
Phosphine acyl acetic acid, hexapotassium, polyamino many ethers methylenephosphonic acid, double 1,6 hexamethylene triamine five methylenephosphonic acid, height
Imitate molten zinc agent, or acrylic acid, maleic acid, acrylamide, methyl propane sulfonic acid Hydroxypropyl acrylate, acrylate, phosphonic acids, sulfonic acid
The polymer of one or more of salt, phosphono-carboxylic acids, Epoxysuccinic acid or copolymer, or ATMP four sodium,
ATMP five sodium, ATMP potassium, 1-hydroxy ethylidene-1,1-diphosphonic acid sodium, 1-hydroxy ethylidene-1,1-diphosphonic acid disodium, hydroxyl
Ethylene-diphosphonic acid four sodium, 1-hydroxy ethylidene-1,1-diphosphonic acid potassium, ethylene diamine tetra methylene phosphonic acid five sodium, diethylene triamine pentamethylene phosphonic five
Sodium, diethylenetriamine penta seven sodium, diethylene triamine pentamethylene phosphonic sodium, 2- phosphonobutane -1,2,4- tricarboxylic acids
Four sodium, hexapotassium potassium salt, double 1,6 hexamethylene triamine five methylenephosphonic acid sodium, carbon number be less than 10 alkene or
In polyolefin one or more；
Above-mentioned dispersant preferably is selected from the fatty acid that carbon number is less than 10, aliphatic amide, ester, paraffin, metallic soap, alkene
Or polyolefin compound, one or more of peg200-400；
Above-mentioned penetrating agent preferably is selected from sulfated castor oil, sodium alkyl sulfonate, sodium alkyl benzene sulfonate, alkyl sulfate sodium, secondary
Sodium alkyl sulfonate, secondary alkyl sulphate sodium, a mono- sodium olefin sulfonate, Negel, succinic acid alkyl ester sulfonate sodium, pancreas add
One of drift t, sulfamic acid sodium, fatty alcohol-polyoxyethylene ether, alkylphenol polyoxyethylene, polyethers, phosphate compounds
Or it is several.
Further, a kind of surface tension for agent for carbon hydrogen detergent according to the present invention increases agent, also has such
Feature: i.e., by the group of following mass percent be grouped into or be prepared from:
Additionally, present invention also offers a kind of above-mentioned surface tension for agent for carbon hydrogen detergent increases the manufacture method of agent,
It is characterized in that, comprise following three kinds of preparation methods: i.e.,
Method one, at a temperature of 20-80 DEG C, the material of each component is stirred 0.5-3 hour, wraps to mix homogeneously
Dress；
Or
Method two, each component materials are packed respectively after stand-by；
Or
Method three, each component materials are grouped, the material mixing of each group are uniformly distinguished afterwards packed for standby use.
Additionally, present invention also offers the above-mentioned surface tension for agent for carbon hydrogen detergent increases the using method of agent, it is special
Levy and be:
Using method one, the surface tension that method one is obtained increase use after agent is mixed homogeneously with agent for carbon hydrogen detergent；
Wherein, above-mentioned surface tension increases agent with the mass ratio of agent for carbon hydrogen detergent is 1:0.5-15；This surface tension increases
The addition of agent is relevant with the pollution level of agent for carbon hydrogen detergent and workpiece, when agent for carbon hydrogen detergent after multiple workpiece washing or
It should increase the addition of surface tension dose when the pollution level of the workpiece that need to clean is serious.
Or
Using method two, the organo-silicon compound that will be increased in agent according to prepared surface tension in method two are clear with hydrocarbon
Carry out the cleaning of workpiece after lotion mix homogeneously, add stabilizer and/or dispersant on demand during cleaning and/or ooze
Agent thoroughly；I.e., the joining day of stabilizer, dispersant, penetrating agent is determined the opportunity using by the cleaning situation of workpiece.
Wherein, above-mentioned organo-silicon compound and the mass ratio of agent for carbon hydrogen detergent are 1:0.5-15；
The addition of aforementioned stable agent is the 1-15% of agent for carbon hydrogen detergent gross mass；
The addition of above-mentioned dispersant is the 1-15% of agent for carbon hydrogen detergent gross mass；
The addition of above-mentioned penetrating agent agent is the 1-15% of agent for carbon hydrogen detergent gross mass；
In the present invention, the addition of above-mentioned organo-silicon compound is relevant with the pollution level of agent for carbon hydrogen detergent and workpiece,
And the order of addition of stabilizer, dispersant, penetrating agent and amount determine according to the workpiece situation after preliminary cleaning, when dirts such as greasy dirts
Dye thing is still not properly cleaned when taking off with surface of the work, and the suitable dispersant that adds adheres to come the greasy dirt to understand its surface.
Using method three, by according in method three be obtained surface tension increase agent in little containing organo-silicon compound
Group subpackage bag carries out the clear of workpiece after mixing homogeneously with agent for carbon hydrogen detergent, adds other small components on demand during cleaning
Dress bag；
Wherein, above-mentioned group's subpackage bag containing organo-silicon compound and the mass ratio of agent for carbon hydrogen detergent are 1:0.5-15.
The addition of other group's subpackage bags above-mentioned is respectively the 1-15% of agent for carbon hydrogen detergent gross mass.
The effect of the present invention and effect:
The invention provides the functional complex of multiple additives composition.Select short chain organosilicon compound in the present invention
Thing, as main material, can utilize its characteristic with hydrocarbon lotion similar compatibility, realize amplification to the cleansing power of carbon abluent
Effect.Meanwhile, it is equipped with other components, the further effect optimizing cleaning.
The application range of products of the present invention extensively, and has good spatter property, can be effective to the greasy dirt washing down
Avoid secondary pollution.And can effectively reduce the abluent that workpiece is taken away, reduce the loss in cleaning process.
Specific embodiment
Embodiment one, surface tension increase agent 1#
Material composition by following mass percent:
After above-mentioned each component mix homogeneously, it is stirred at room temperature to transparent shape, packed for standby use.
Embodiment two, surface tension increase agent 2#
Material composition by following mass percent:
Monosilane 15%
Disilicoethane 80%
P-105 5%
After above-mentioned each component mix homogeneously, stir 1 hour in 30 DEG C, after being cooled to room temperature, packed for standby use.
Embodiment three, surface tension increase agent 3#
Material composition by following mass percent:
After above-mentioned each component mix homogeneously, stir 0.5 hour in 45 DEG C, after being cooled to room temperature, packed for standby use.
Example IV, surface tension increase agent 4#
Material composition by following mass percent:
After above-mentioned each component mix homogeneously, it is stirred at room temperature 0.5 hour, after being cooled to room temperature, packed for standby use.
Embodiment five, surface tension increase agent 5#
Material composition by following mass percent:
Hexamethyl two (first) silicon ether 56%
Disilicoethane 39%
Dodecyl sodium sulfate 5%
After above-mentioned each component mix homogeneously, it is stirred at room temperature 0.5 hour, after being cooled to room temperature, packed for standby use.
Embodiment six, surface tension increase agent 6#
Material composition by following mass percent:
Disilicoethane 90%
Peg200 10%
After above-mentioned each component mix homogeneously, it is stirred at room temperature 0.5 hour, after being cooled to room temperature, packed for standby use.
Embodiment seven, surface tension increase agent 7#
Material composition by following mass percent:
After above-mentioned each component mix homogeneously, it is stirred at room temperature 1 hour, after being cooled to room temperature, packed for standby use.
Note: also above-mentioned each component can be packed respectively and be used.
Workpiece cleaning experiment: (, other product effects are similar taking 1# product as a example)
Add the 15% (difference according to workpiece and the access times of lotion being equivalent to lotion weight in agent for carbon hydrogen detergent
Different, this ratio can be adjusted) 1# product；The workpiece machining is soaked in this lotion and is carried out, clean result
As follows: (comparative test result)
Wash time more directly shortens 25% using agent for carbon hydrogen detergent；
Spot residual < 0.1%；
Lotion access times are more directly increased by 25 times using agent for carbon hydrogen detergent.
Claims (10)
1. a kind of surface tension for agent for carbon hydrogen detergent increases agent it is characterised in that being grouped by the group of following mass percent
Become or be prepared from:
Wherein, stabilizer, dispersant, at least one in penetrating agent are necessarily comprised in component.
2. as claimed in claim 1 a kind of surface tension for agent for carbon hydrogen detergent increase agent it is characterised in that: described organic
Silicon compound is less than 10 short chain organo-silicon compound for silicon atom number.
3. as claimed in claim 1 a kind of surface tension for agent for carbon hydrogen detergent increase agent it is characterised in that: described organic
Silicon compound is the short chain organo-silicon compound of 2-4 for silicon atom number.
4. as claimed in claim 1 a kind of surface tension for agent for carbon hydrogen detergent increase agent it is characterised in that: described stable
The molecular weight of agent and/or dispersant and/or penetrating agent is 0.2-10 times of organo-silicon compound.
5. as claimed in claim 1 a kind of surface tension for agent for carbon hydrogen detergent increase agent it is characterised in that: described stable
1-20 times of a length of organo-silicon compound of chain of agent and/or dispersant and/or penetrating agent.
6. as claimed in claim 4 a kind of surface tension for agent for carbon hydrogen detergent increase agent it is characterised in that: described organic
Silicon compound is selected from silane, siloxanes；
Described stabilizer is selected from organic phosphine compound, organic phospho acid salt compound, polycarboxylic acid compound, alkene, polyolefin
One or more of；
Described dispersant is selected from fatty acid, aliphatic amide type, esters, paraffin class, metal soap, low molecule wax class, alkene
One or more of or polyolefin compound；
Described penetrating agent is selected from one or more of nonionic surfactant, anion surfactant.
7. as claimed in claim 1 a kind of surface tension for agent for carbon hydrogen detergent increase agent it is characterised in that: described stable
Agent is selected from ATMP, 1-hydroxy ethylidene-1,1-diphosphonic acid, ethylene diamine tetra methylene phosphonic acid sodium, ethylene diamine tetra methylene phosphonic acid, diethyl
Alkene triamine five methylenephosphonic acid, 2- phosphonobutane -1,2,4- tricarboxylic acids, PAPE, 2- HPAA, hexamethylene diamine
Four methylenephosphonic acids, polyamino many ethers methylenephosphonic acid, double 1,6 hexamethylene triamine five methylenephosphonic acid, efficiently molten zinc agent, or propylene
Acid, maleic acid, acrylamide, methyl propane sulfonic acid Hydroxypropyl acrylate, acrylate, phosphonic acids, sulfonate, phosphono-carboxylic acids, ring
The polymer of one or more of oxydisuccinic acid or copolymer, or ATMP four sodium, ATMP five
Sodium, ATMP potassium, 1-hydroxy ethylidene-1,1-diphosphonic acid sodium, 1-hydroxy ethylidene-1,1-diphosphonic acid disodium, 1-hydroxy ethylidene-1,1-diphosphonic acid four sodium, hydroxyl
Base ethylene-diphosphonic acid potassium, ethylene diamine tetra methylene phosphonic acid five sodium, diethylene triamine pentamethylene phosphonic five sodium, diethylenetriamine five methylene
Base phosphonic acids seven sodium, diethylene triamine pentamethylene phosphonic sodium, 2- phosphonobutane -1,2,4- tricarboxylic acids four sodium, hexamethylene diamine four methene phosphine
Acid potassium salt, double 1,6 hexamethylene triamine five methylenephosphonic acid sodium, carbon number be less than 10 alkene or polyolefin in one or more；
Described dispersant is selected from fatty acid, aliphatic amide, ester, paraffin, metallic soap, alkene or the polyene that carbon number is less than 10
Hydrocarbon, one or more of peg200-400；
Described penetrating agent is selected from sulfated castor oil, sodium alkyl sulfonate, sodium alkyl benzene sulfonate, alkyl sulfate sodium, secondary alkyl sulphur
Sour sodium, secondary alkyl sulphate sodium, a mono- sodium olefin sulfonate, Negel, succinic acid alkyl ester sulfonate sodium, pancreas add drift t, ammonia
One or more of base sodium sulfonate, fatty alcohol-polyoxyethylene ether, alkylphenol polyoxyethylene, polyethers, phosphate compounds.
8. as claimed in claim 1 a kind of surface tension for agent for carbon hydrogen detergent increase agent it is characterised in that: by following matter
The group of amount percentage ratio is grouped into or is prepared from:
9. described a kind of surface tension for agent for carbon hydrogen detergent as arbitrary in claim 1-8 increases the manufacture method of agent, its
It is characterised by:
Method one, at a temperature of 20-80 DEG C, the material of each component is stirred 0.5-3 hour, packs to mix homogeneously；
Or
Method two, each component materials are packed respectively after stand-by；
Or
Method three, each component materials are grouped, the material mixing of each group are uniformly distinguished afterwards packed for standby use.
10. a kind of surface tension for agent for carbon hydrogen detergent increases the using method of agent as claimed in claim 9, and its feature exists
In:
Using method one, the surface tension that method one is obtained increase use after agent is mixed homogeneously with agent for carbon hydrogen detergent；
Wherein, described surface tension increases agent with the mass ratio of agent for carbon hydrogen detergent is 1:0.5-15；
Or
Using method two, organo-silicon compound and the agent for carbon hydrogen detergent that will be increased according to the surface tension being obtained in method two in agent
Carry out the cleaning of workpiece after mix homogeneously, during cleaning, add stabilizer and/or dispersant and/or infiltration on demand
Agent；
Wherein, described organo-silicon compound and the mass ratio of agent for carbon hydrogen detergent are 1:0.5-15；
The addition of described stabilizer is the 1-15% of agent for carbon hydrogen detergent gross mass；
The addition of described dispersant is the 1-15% of agent for carbon hydrogen detergent gross mass；
The addition of described penetrating agent agent is the 1-15% of agent for carbon hydrogen detergent gross mass；
Using method three, the small component containing organo-silicon compound that will be increased according to the surface tension being obtained in method three in agent
Dress bag carries out the clear of workpiece after mixing homogeneously with agent for carbon hydrogen detergent, adds other group's subpackages on demand during cleaning
Bag；
Wherein, described group's subpackage bag containing organo-silicon compound and the mass ratio of agent for carbon hydrogen detergent are 1:0.5-15.Described
The addition of other group's subpackage bags is respectively the 1-15% of agent for carbon hydrogen detergent gross mass.
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610717297.2A CN106350326A (en) | 2016-08-24 | 2016-08-24 | Surface tension increasing agent for hydrocarbon cleaning agent as well as preparation method and use method of surface tension increasing agent |
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|---|---|---|---|
| CN201610717297.2A CN106350326A (en) | 2016-08-24 | 2016-08-24 | Surface tension increasing agent for hydrocarbon cleaning agent as well as preparation method and use method of surface tension increasing agent |
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Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN111234957A (en) * | 2020-03-18 | 2020-06-05 | 诺而曼环保科技（江苏）有限公司 | Efficient environment-friendly metal powder removing hydrocarbon cleaning agent and preparation method thereof |
| CN113621446A (en) * | 2021-09-13 | 2021-11-09 | 常州智高化学科技有限公司 | Environment-friendly quick-modification alcohol detergent |
Citations (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1122146A (en) * | 1993-04-01 | 1996-05-08 | 美国3M公司 | Azeotropic compositions |
| JPH08176598A (en) * | 1994-12-27 | 1996-07-09 | Central Glass Co Ltd | Cleaner for glass plate |
| US20020060368A1 (en) * | 2000-04-06 | 2002-05-23 | Tongbi Jiang | Underfile process |
| JP2003221596A (en) * | 2002-01-31 | 2003-08-08 | Asahi Glass Co Ltd | Detergent for cycle cleaning of cooling or heat pump system |
| CN1600748A (en) * | 2004-10-25 | 2005-03-30 | 孟凡钧 | Method of preparing surface protection agent for marble and ceramic |
| CN101007987A (en) * | 2007-01-15 | 2007-08-01 | 深圳市可林卓特电子有限公司 | Water-based precise cleaning agent |
| CN101688002A (en) * | 2007-02-20 | 2010-03-31 | 塞尔瑞星技术有限公司 | Combination of substituted cyclodextrin compound and activated carbon |
| CN102197065A (en) * | 2008-11-20 | 2011-09-21 | 瓦克化学股份公司 | Antifoaming compositions |
| CN102766547A (en) * | 2012-06-29 | 2012-11-07 | 占协琼 | Industrial cleaning agent |
| CN104830181A (en) * | 2015-05-14 | 2015-08-12 | 广东朗法博涂装新材料科技有限公司 | Acrylic acid water-based paint and preparation method thereof |
-
2016
- 2016-08-24 CN CN201610717297.2A patent/CN106350326A/en active Pending
Patent Citations (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1122146A (en) * | 1993-04-01 | 1996-05-08 | 美国3M公司 | Azeotropic compositions |
| JPH08176598A (en) * | 1994-12-27 | 1996-07-09 | Central Glass Co Ltd | Cleaner for glass plate |
| US20020060368A1 (en) * | 2000-04-06 | 2002-05-23 | Tongbi Jiang | Underfile process |
| JP2003221596A (en) * | 2002-01-31 | 2003-08-08 | Asahi Glass Co Ltd | Detergent for cycle cleaning of cooling or heat pump system |
| CN1600748A (en) * | 2004-10-25 | 2005-03-30 | 孟凡钧 | Method of preparing surface protection agent for marble and ceramic |
| CN101007987A (en) * | 2007-01-15 | 2007-08-01 | 深圳市可林卓特电子有限公司 | Water-based precise cleaning agent |
| CN101688002A (en) * | 2007-02-20 | 2010-03-31 | 塞尔瑞星技术有限公司 | Combination of substituted cyclodextrin compound and activated carbon |
| CN102197065A (en) * | 2008-11-20 | 2011-09-21 | 瓦克化学股份公司 | Antifoaming compositions |
| CN102766547A (en) * | 2012-06-29 | 2012-11-07 | 占协琼 | Industrial cleaning agent |
| CN104830181A (en) * | 2015-05-14 | 2015-08-12 | 广东朗法博涂装新材料科技有限公司 | Acrylic acid water-based paint and preparation method thereof |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN111234957A (en) * | 2020-03-18 | 2020-06-05 | 诺而曼环保科技（江苏）有限公司 | Efficient environment-friendly metal powder removing hydrocarbon cleaning agent and preparation method thereof |
| CN113621446A (en) * | 2021-09-13 | 2021-11-09 | 常州智高化学科技有限公司 | Environment-friendly quick-modification alcohol detergent |
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