CN106342836A - Herbicide composition with pyraclonil, oxadiargyl and triafamone - Google Patents
Herbicide composition with pyraclonil, oxadiargyl and triafamone Download PDFInfo
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- CN106342836A CN106342836A CN201610633442.9A CN201610633442A CN106342836A CN 106342836 A CN106342836 A CN 106342836A CN 201610633442 A CN201610633442 A CN 201610633442A CN 106342836 A CN106342836 A CN 106342836A
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- oxadiargyl
- pyraclonil
- herbicidal combinations
- ketone sulphur
- fluorine ketone
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- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/64—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with three nitrogen atoms as the only ring hetero atoms
- A01N43/66—1,3,5-Triazines, not hydrogenated and not substituted at the ring nitrogen atoms
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/72—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with nitrogen atoms and oxygen or sulfur atoms as ring hetero atoms
- A01N43/82—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with nitrogen atoms and oxygen or sulfur atoms as ring hetero atoms five-membered rings with three ring hetero atoms
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/90—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having two or more relevant hetero rings, condensed among themselves or with a common carbocyclic ring system
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- Life Sciences & Earth Sciences (AREA)
- Agronomy & Crop Science (AREA)
- Pest Control & Pesticides (AREA)
- Plant Pathology (AREA)
- Health & Medical Sciences (AREA)
- Engineering & Computer Science (AREA)
- Dentistry (AREA)
- General Health & Medical Sciences (AREA)
- Wood Science & Technology (AREA)
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- Environmental Sciences (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
Abstract
The invention discloses a herbicide composition with pyraclonil, oxadiargyl and triafamone. Active components in the herbicide composition comprise the pyraclonil, the oxadiargyl and the triafamone. A weight ratio of the pyraclonil to the oxadiargyl to the triafamone is 10-90:5-45:1-15. The herbicide composition has the advantages that obvious synergistic effects can be realized by the herbicide composition, the herbicide composition is mainly applied to preventing and treating weed in rice fields, herbicide effects can be obviously improved by the herbicide composition as compared with various single pesticides used independently, and herbicide controlling spectra can be expanded; the application amounts of pesticides can be reduced, accordingly, environmental pollution can be abated, the herbicide resistance of the weed can be delayed, and the service lives of the pesticides can be prolonged.
Description
Technical field
The present invention relates to pesticide Herbicidal combinations and its application, specifically one kind is with pyraclonil, propine
Oxadiazon and fluorine ketone sulphur grass amine are the Herbicidal combinations of active component ternary built, are mainly used in the preventing and treating of paddy field weed.
Background technology
Pyraclonil (pyraclonil): it is a kind of compound with Pyrazolopyridine ring novel structure, the mechanism of action
Inhibitor for proporphyrinogen oxidase.Can be used for rice terrace, to prevent and kill off annual gramineous weed, sedge weed and broad-leaved miscellaneous
Grass and some perennial weeds.
Oxadiargyl (oxadiargyl): belong to diazole type herbicides, be that contact killing type selectivity wide spectrum removes before bud
Careless agent.Can be used for rice terrace prevent and kill off firefly Lin, barnyard grass, wild Corm Eleocharitiss, cyperus iria, Herba Cyperi Difformiss, Herba Eleocharitis aciculariies, mexicana, little najas marina,
The annual grass of rice terrace such as Semen Euphorbiae, Herba Caricis Phacotae, Herba monochoriae vaginaliss, Monochoria korsakowii, Rhizoma Alismatis, short Rhizoma sagittariae sagittifoliae, Rhizoma sagittariae sagittifoliae, Herba Bidentis Tripartitae, Herba potamogetonis distincti
Section weeds, broad leaved weed, sedge weed and water are continuous.
Fluorine ketone sulphur grass amine (triafamone): belong to sulfonamides herbicide, can lead to via plant root and Foliage Absorption
Cross suppression acetolactate synthase to work (als inhibitor), to rice terrace grassy weed barnyard grass, broad leaved weed Eclipta prostrata, Flos Caryophylli
Knotweed, and sedge weed Herba Cyperi Difformiss etc. all have good preventive effect.
Chemical method weeding is agriculturally to control one of Main Means of weeds in field.In recent years, due to some herbicides
The large area of kind is used alone, and already leads to many weeds and creates Drug resistance；Simultaneously as careless phase when weeds in field occurs
Complicated, species is various, and the such as mixing such as grassy weed, sedge weed and broad leaved weed occurs, and the herbicide of single variety makes
With cannot effectively solving the problems referred to above, all can show defect in a certain respect.
By the screening of different mixture of herbicides formula, filter out rational formula, the reality to weeds can be effectively improved
Prevention effect, expands weed control spectrum, reduces dosage, reduces cost, mitigates the pollution to environment, delay the product of herbicide resistance
Raw, extend the Pesticide use life-span, be the important means of agriculturally weeds comprehensive control.
Content of the invention
The purpose of the present invention is for above-mentioned problem, provides one kind with pyraclonil, Oxadiargyl and fluorine ketone
Sulphur grass amine is the Herbicidal combinations with synergistic function being applied to rice terrace management of weeds of active component ternary built.
Technical scheme: for achieving the above object, the present invention provides a kind of careless containing pyraclonil and propine
Ketone and the Herbicidal combinations of fluorine ketone sulphur grass amine, active component is made up of pyraclonil, Oxadiargyl and fluorine ketone sulphur grass amine, double
The weight ratio of azoles oxalic acid dinitrile, Oxadiargyl and fluorine ketone sulphur grass amine is for 10～90:5～45:1～15, pyraclonil, Oxadiargyl
It is 0.5～80% with fluorine ketone sulphur grass amine gross weight percentage composition in the composition, remaining is to allow in pesticide to use and permissible
The auxiliary element accepting.
Described auxiliary element includes solvent, emulsifying agent, wetting agent, dispersant, diffusant, antifreezing agent, thickening agent, disintegrate
Agent, binding agent, slow releasing agent, defoamer, preservative, stabilizer, penetrating agent, synergist, solid acid, carbonate, flowing regulator,
Ph regulator, liquid-carrier and solid carrier etc. are all conventional in pesticidal preparations or allow the composition using, and have no special limit
Determine, concrete composition and consumption are determined by test according to recipe requirements.
Herbicidal combinations of the present invention can be prepared into the multiple application forms being suitable for agriculturally using, and reasonable dosage form has
Granule, suspending agent, microemulsion, wettable powder, water dispersible granules, effervescent tablet and aqueous emulsion.
The production technology of the various application forms of described Herbicidal combinations all belongs to existing known technology, will not be described here.
Compared with prior art, it is an advantage of the current invention that:
1st, pyraclonil, Oxadiargyl and fluorine ketone sulphur grass amine ternary built, have significant synergistic function, than
Each single dose is used alone and significantly improves the prevention effect to weeds, and expands weed control spectrum.
2nd, pyraclonil, Oxadiargyl and fluorine ketone sulphur grass amine ternary built, the mechanism of action is different, and action site increases
Plus, the generation of herbicide resistance can be delayed, extend the Pesticide use life-span.
3rd, pyraclonil, Oxadiargyl and fluorine ketone sulphur grass amine ternary built, decrease Pesticide use amount, reduce use
Cost, alleviate the pollution to environment.
Specific embodiment
Essence for a better understanding of the present invention, is described further to present disclosure with reference to embodiment,
But limitation of the present invention can not be considered as, described below is only used for explaining the present invention, for without departing from present invention spirit and principle
Modification, replacement or the improvement made, belongs to the scope of protection of present invention.
(1) Formulation Example
In following examples, active component adopts 95% pyraclonil active compound, 98% Oxadiargyl active compound and 93.6%
Fluorine ketone sulphur grass amine active compound, each component percentages are weight percentage.
Embodiment 1:55% pyraclonil Oxadiargyl fluorine ketone sulphur grass aqueous amine dispersible granule
Pyraclonil 30%, Oxadiargyl 15%, fluorine ketone sulphur grass amine 10%, sodium lauryl sulphate (wetting agent) 5%,
Sodium acrylate and propionic acid amide. copolymer (dispersant) 5%, poly- naphthalene formaldehyde sulfonate salt 5% (diffusant), bentonite (disintegrating agent)
3%th, white sugar (binding agent) 0.2%, anhydrous calcium chloride (stabilizer) 0.2%, c8-10Aliphatic alcohols compound (defoamer)
0.1%th, citric acid (ph regulator) 0.2%, Kaolin (solid carrier) supplies 100%.Above-mentioned material is mixed in proportion all
Even, pulverized with micro jet, through mediating, be subsequently adding in fluidized-bed granulation dryer and carry out pelletize, drying, screening
Afterwards, you can 55% pyraclonil Oxadiargyl fluorine ketone sulphur grass aqueous amine dispersible granule is obtained.
Embodiment 2:70% pyraclonil Oxadiargyl fluorine ketone sulphur grass amine wettable powder
Pyraclonil 20%, Oxadiargyl 30%, fluorine ketone sulphur grass amine 20%, pull open powder (wetting agent) 5%, sodium acrylate
With propionic acid amide. copolymer (dispersant) 5%, poly- naphthalene formaldehyde sulfonate salt 5% (diffusant), Kaolin (solid carrier) supplies
100%.Above-mentioned material is mixed in proportion, after mechanical activation comminution again after comminution by gas stream mix homogeneously, you can 70% polybenzobisoxazole is obtained
Oxalic acid dinitrile Oxadiargyl fluorine ketone sulphur grass amine wettable powder.
Embodiment 3:40% pyraclonil Oxadiargyl fluorine ketone sulphur grass amine microemulsion
Pyraclonil 10%, Oxadiargyl 15%, fluorine ketone sulphur grass amine 15%, trimethylbenzene (solvent) 10%, loose base oil are (molten
Agent) 10%, ethylene oxide-propylene oxide block copolymer (emulsifying agent) 10%, triphenyl phosphite (stabilizer) 3%, organic
Silicon (penetrating agent) 1%, azone (synergist) 2%, sodium benzoate (preservative) 0.1%, glycerol (antifreezing agent) 1.5%, go from
Sub- water (liquid-carrier) supplies 100%.After above-mentioned material is uniformly mixed in proportion, you can 40% pyraclonil is obtained
Oxadiargyl fluorine ketone sulphur grass amine microemulsion.
Embodiment 4:30% pyraclonil Oxadiargyl fluorine ketone sulphur grass amine effervescent tablet
Pyraclonil 5%, Oxadiargyl 5%, fluorine ketone sulphur grass amine 20%, alkyl sulfate (wetting agent) 5%, alkyl phenol
Polyoxyethylene ether methyl ether condensation substance sulphuric acid (dispersant) 5%, carboxymethyl starch sodium (disintegrating agent) 2%, succinic acid (solid acid)
15%th, sodium carbonate (carbonate) 15%, titanium dioxide (flowing regulator) 3%, arabic gum (binding agent) 1.5%, kieselguhr
(solid carrier) complements to 100%.Above-mentioned material is mixed in proportion, after comminution by gas stream mix homogeneously, uses tablet machine film-making,
Last drying, granulate, detect, pack after, you can 30% pyraclonil Oxadiargyl fluorine ketone sulphur grass amine is obtained
Effervescent tablet.
Embodiment 5:45% pyraclonil Oxadiargyl fluorine ketone sulphur grass aqueous amine Emulsion
Pyraclonil 30%, Oxadiargyl 5%, fluorine ketone sulphur grass amine 10%, dimethylbenzene (solvent) 15%, phenethyl phenol
Polyoxyethylene poly-oxygen propylene aether (emulsifying agent) 10%, glycerine fatty acid ester APEO (dispersant) 5%, triphenyl phosphite
(stabilizer) 3%, ethylene glycol (antifreezing agent) 2%, organosiloxane (defoamer) 0.2%, sodium benzoate (preservative) 0.2%,
Hydroxymethyl cellulose (thickening agent) 0.5%, deionized water (liquid-carrier) supplies 100%.Above-mentioned material is mixed in proportion all
Even, after high-speed stirred, you can 45% pyraclonil Oxadiargyl fluorine ketone sulphur grass aqueous amine Emulsion is obtained.
Embodiment 6:24% pyraclonil Oxadiargyl fluorine ketone sulphur grass amine suspending agent
Pyraclonil 14%, Oxadiargyl 2%, fluorine ketone sulphur grass amine 8%, alkyl sulfate (wetting agent) 3%, phenethyl
Phenol polyethenoxy base ether phosphate (dispersant) 5%, ethylene glycol (antifreezing agent) 3%, carboxymethyl cellulose (thickening agent) 1%, different
Thiazolinone (preservative) 0.3%, epoxy soybean oil (defoamer) 0.2%, triethanolamine (ph regulator) 0.2%, vegetable oil
(synergist) 2%, deionized water (liquid-carrier) supplies 100%.Above-mentioned material is mixed in proportion, disperse through high speed shear,
Sand milling in sand mill, after the high dispersive being formed in water-medium, stable suspension system, you can 24% pyraclonil is obtained
Oxadiargyl fluorine ketone sulphur grass amine suspending agent.
Embodiment 7:5% pyraclonil Oxadiargyl fluorine ketone sulphur grass amine granule
Pyraclonil 2.5%, Oxadiargyl 1%, fluorine ketone sulphur grass amine 1.5%, sodium butylnaphthalenesulfonate (wetting agent) 20%,
Naphthalene sulfonic acid-formaldehyde condensation product sodium salt (dispersant) 20%, polyvinyl methyl ethermaleic anhydride (slow releasing agent) 10%, starch (binding agent) 10%, white
White carbon black (solid carrier) 10%, Kaolin (solid carrier) complements to 100%.By above-mentioned material, blended adding water is carried out in proportion
Mediate, pinched out using pinch-out granulator and shape, afterwards by after granule fluid bed drying, screening, you can 5% polybenzobisoxazole grass is obtained
Nitrile Oxadiargyl fluorine ketone sulphur grass amine granule.
(2) indoor biological determination of activity embodiment
Reagent agent: 95% pyraclonil active compound, 98% Oxadiargyl active compound and 93.6% fluorine ketone sulphur grass amine active compound.
For trying target: Herba monochoriae vaginaliss (monochoria vaginalis), barnyard grass (echinochloa crusgalli), different
Type dried tuber (cyperus difformis l.).
Medicament configuration designs: pyraclonil single dose is configured to 10,50,90g a.i./ha solution for standby；Oxadiargyl list
Agent is configured to 5,25,45g a.i./ha solution for standby；Fluorine ketone sulphur grass amine single dose is configured to 1,8,15g a.i./ha solution for standby；
Pyraclonil, Oxadiargyl and fluorine ketone sulphur grass amine mixture are configured to 10+5+1,10+5+8,10+5+15,10+25+1,10+25+
8、10+25+15、10+45+1、10+45+8、10+45+15、50+5+1、50+5+8、50+5+15、50+25+1、50+25+8、50+
25+15、50+45+1、50+45+8、50+45+15、90+5+1、90+5+8、90+5+15、90+25+1、90+25+8、90+25+
15th, 90+45+1,90+45+8,90+45+15g a.i./ha solution for standby.
Test method: using soil pouring method (ny/t 1155.5-2006): be 0.01m in area2Basin alms bowl in set
Amount soil, to the 3/4 of basin alms bowl, then waters from the top of basin alms bowl, so that soil is moistened completely to saturation.Will be miscellaneous for examination target
Uniformly sowing, in basin alms bowl soil surface, is placed in greenhouse after the fine earth according to seed size lid 0.5～2cm grass seed 15～20
Culture.After 24h, every basin alms bowl quantitatively waters medicinal liquid 10ml, often processes 4 repetitions, and the process setting without medicament is comparison, process
Examination material is placed in warm indoor cultivation, the growing state of routine observation target weeds afterwards, manage everywhere during test basin alms bowl remain 1～
2cm water layer.Range estimation target damage symptoms and growth inhibited situation after 20d, and claim aerial partss fresh weight, with target fresh weight inhibition
Evaluate the toxicity action to target weeds for the medicament.
Investigation method: range estimation target damage symptoms and growth inhibited situation after test process 20d, and claim aerial partss fresh
Weight, calculates fresh weight inhibition (%).
Synergy evaluation methodology: herbicide mode of application (ny/t1155.7-2006) is evaluated according to colby method,
Its formula is: e0=x × y × z/1002, in formula, x is pyraclonil with certain dosage fresh weight inhibition to target weeds when alone
Percent for comparison；Y be Oxadiargyl with certain dosage when alone to the fresh weight inhibition of target weeds for comparison percentage
Number；Z be fluorine ketone sulphur grass amine with certain dosage when alone to the fresh weight inhibition of target weeds for comparison percent；e0For polybenzobisoxazole grass
It is the reason of the percent of comparison to target weeds fresh weight inhibition when nitrile, Oxadiargyl and fluorine ketone sulphur grass three kinds of pharmacy mix of amine
By value；E is pyraclonil, Oxadiargyl and be right to target weeds fresh weight inhibition during fluorine ketone sulphur grass three kinds of pharmacy mix of amine
According to percent measured value.
Evaluation criterion: work as e0It is expressed as potentiation, as -10% e during-e > 10%0It is expressed as during-e 10% being added and make
With working as e0It is expressed as antagonism during-e < -10%.
Table 1, each chemicals treatment Toxicity Determination result to Herba monochoriae vaginaliss
Table 2, each chemicals treatment Toxicity Determination result to barnyard grass
Table 3, each chemicals treatment Toxicity Determination result to Herba Cyperi Difformiss
Pyraclonil, Oxadiargyl and fluorine ketone sulphur be can be seen that by the Toxicity Determination result of table 1, table 2 and table 3
Careless amine ternary built respectively processes the e to Herba monochoriae vaginaliss, barnyard grass and Herba Cyperi Difformiss0- e (%) value is all higher than 10%, and more than 20%,
Illustrate that three's compounding use is respectively provided with significant synergistic function to Herba monochoriae vaginaliss, barnyard grass and Herba Cyperi Difformiss.As can be seen here, polybenzobisoxazole
Oxalic acid dinitrile, Oxadiargyl and fluorine ketone sulphur grass amine Ternary have reasonability and feasibility.
(3) field efficacy checking embodiment
Experimental field select rice terrace to carry out, often process and set 3 repetitions, count each process number of weeds amounts and calculate within 30 days after medicine
Preventive effect.
Table 4, each chemicals treatment prevent and kill off the field control effectiveness test result of paddy field weed
Can be seen that after medicine 30 days each example composition by the field test results of table 4 to the Herba monochoriae vaginaliss of rice terrace, short
The preventive effect of the weeds such as Rhizoma sagittariae sagittifoliae, barnyard grass, Semen Euphorbiae, Herba Cyperi Difformiss and firefly Lin is outstanding, all reaches more than 80% hence it is evident that being better than each single dose
It is used alone, do not find that each example composition produces poisoning to Oryza sativa L. simultaneously during test survey.
In sum, a kind of weeding containing pyraclonil and Oxadiargyl and fluorine ketone sulphur grass amine of the present invention
Compositionss obvious synergy, compares each single dose and is used alone and expand weed control spectrum, improves preventive effect, can effectively anti-eliminating water
The various weeds in rice field, the lasting period is long, to rice safety, is worth popularization and application in agricultural production.
Claims (10)
1. a kind of pyraclonil and Oxadiargyl and fluorine ketone sulphur grass amine Herbicidal combinations it is characterised in that: active component
It is made up of pyraclonil, Oxadiargyl and fluorine ketone sulphur grass amine, the weight ratio of pyraclonil, Oxadiargyl and fluorine ketone sulphur grass amine
For 10～90:5～45:1～15.
2. the Herbicidal combinations of a kind of pyraclonil according to claim 1 and Oxadiargyl and fluorine ketone sulphur grass amine,
It is characterized in that: pyraclonil, Oxadiargyl and fluorine ketone sulphur grass amine gross weight percentage composition in the composition be 0.5%～
80%, remaining is to allow in pesticide to use and acceptable auxiliary element.
3. the Herbicidal combinations of a kind of pyraclonil according to claim 1 and Oxadiargyl and fluorine ketone sulphur grass amine,
It is characterized in that: the dosage form of described Herbicidal combinations is granule.
4. the Herbicidal combinations of a kind of pyraclonil according to claim 1 and Oxadiargyl and fluorine ketone sulphur grass amine,
It is characterized in that: the dosage form of described Herbicidal combinations is suspending agent.
5. the Herbicidal combinations of a kind of pyraclonil according to claim 1 and Oxadiargyl and fluorine ketone sulphur grass amine,
It is characterized in that: the dosage form of described Herbicidal combinations is microemulsion.
6. the Herbicidal combinations of a kind of pyraclonil according to claim 1 and Oxadiargyl and fluorine ketone sulphur grass amine,
It is characterized in that: the dosage form of described Herbicidal combinations is wettable powder.
7. the Herbicidal combinations of a kind of pyraclonil according to claim 1 and Oxadiargyl and fluorine ketone sulphur grass amine,
It is characterized in that: the dosage form of described Herbicidal combinations is water dispersible granules.
8. the Herbicidal combinations of a kind of pyraclonil according to claim 1 and Oxadiargyl and fluorine ketone sulphur grass amine,
It is characterized in that: the dosage form of described Herbicidal combinations is effervescent tablet or aqueous emulsion.
9. the Herbicidal combinations of a kind of pyraclonil according to claim 1 and Oxadiargyl and fluorine ketone sulphur grass amine,
It is characterized in that: the dosage form of described Herbicidal combinations be granule, suspending agent, microemulsion, wettable powder, water dispersible granules,
Effervescent tablet or aqueous emulsion.
10. the Herbicidal combinations of a kind of pyraclonil described in claim 1 and Oxadiargyl and fluorine ketone sulphur grass amine are anti-
Control the purposes in paddy field weed.
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Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106889094A (en) * | 2017-02-27 | 2017-06-27 | 南京华洲药业有限公司 | A kind of Herbicidal combinations and its application containing pyraclonil and pyrazosulfuron |
| CN107047578A (en) * | 2017-02-27 | 2017-08-18 | 南京华洲药业有限公司 | A kind of Herbicidal combinations and its application containing pyraclonil and oxadiargyl |
| CN107047592A (en) * | 2017-02-27 | 2017-08-18 | 南京华洲药业有限公司 | A kind of Herbicidal combinations and its application containing pyraclonil and bensulfuron-methyl |
| CN107047594A (en) * | 2017-02-27 | 2017-08-18 | 南京华洲药业有限公司 | A kind of Herbicidal combinations and its application containing pyraclonil and halosulfuronmethyl |
| CN107114384A (en) * | 2017-05-27 | 2017-09-01 | 北京科发伟业农药技术中心 | A kind of Herbicidal combinations containing pyraclonil |
| CN107743965A (en) * | 2017-10-17 | 2018-03-02 | 四川国光农化股份有限公司 | A kind of Chinese prickly ash moss scavenger composition |
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2016
- 2016-08-03 CN CN201610633442.9A patent/CN106342836A/en not_active Withdrawn
Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106889094A (en) * | 2017-02-27 | 2017-06-27 | 南京华洲药业有限公司 | A kind of Herbicidal combinations and its application containing pyraclonil and pyrazosulfuron |
| CN107047578A (en) * | 2017-02-27 | 2017-08-18 | 南京华洲药业有限公司 | A kind of Herbicidal combinations and its application containing pyraclonil and oxadiargyl |
| CN107047592A (en) * | 2017-02-27 | 2017-08-18 | 南京华洲药业有限公司 | A kind of Herbicidal combinations and its application containing pyraclonil and bensulfuron-methyl |
| CN107047594A (en) * | 2017-02-27 | 2017-08-18 | 南京华洲药业有限公司 | A kind of Herbicidal combinations and its application containing pyraclonil and halosulfuronmethyl |
| CN107114384A (en) * | 2017-05-27 | 2017-09-01 | 北京科发伟业农药技术中心 | A kind of Herbicidal combinations containing pyraclonil |
| CN107743965A (en) * | 2017-10-17 | 2018-03-02 | 四川国光农化股份有限公司 | A kind of Chinese prickly ash moss scavenger composition |
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