CN106336956A - 一种马桶清洁剂及其制备方法 - Google Patents

一种马桶清洁剂及其制备方法 Download PDF

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CN106336956A
CN106336956A CN201610708158.3A CN201610708158A CN106336956A CN 106336956 A CN106336956 A CN 106336956A CN 201610708158 A CN201610708158 A CN 201610708158A CN 106336956 A CN106336956 A CN 106336956A
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马赛波
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YUYAO DELPACK DAILY PRODUCT Co Ltd
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    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
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    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
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    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
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    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
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Abstract

本发明涉及清洁剂领域。一种马桶清洁剂，该清洁剂由水溶膜及其内的清洁片构成，清洁片按质量百分比计由以下的组分制备得到：纯碱、酒石酸、柠檬酸、二氯异氰尿酸钠、元明粉、低泡非离子表面活性剂和香精。该马桶清洁剂的优点是存放占用空间小，取用方便，不会对手造成污染或腐蚀，对尿渍有很强的去除能力，保护、光亮陶瓷，尤其是杀菌性能好。

Description

一种马桶清洁剂及其制备方法
技术领域
本发明涉及清洁剂领域，特别是涉及一种马桶清洁剂及其制备方法。
背景技术
传统的马桶清洁剂多为液状，如中国发明专利申请(申请号CN201310479781.2CN201510437124.0申请日2013.10.15)公开了一种马桶清洁剂，包括如下重量含量的成分：醋酸20-30份，次氯酸1-2份，表面活性剂2-3份，漂粉精5-15份，香味素1-3份，加入100-150份水，即得成品。该类液状马桶清洁剂存在的不足是体积大，运输成本高。市场上也有固体片状的马桶清洁剂出售，其不足是使用时需要手持片状清洁剂，容易造成手部皮肤污染或腐蚀。
发明内容
本发明的第一个目的是提供一种存放占用空间小，取用方便，不会对手造成污染或腐蚀，且杀菌效果好的马桶清洁剂。本发明的第二个目的是提供上述的桶清洁剂的制备方法。
为了实现上述的第一个目的，本发明采用了以下的技术方案：
一种马桶清洁剂，该清洁剂由水溶膜及其内的清洁片构成，清洁片按质量百分比计由以下的组分制备得到：
纯碱 10-20％
酒石酸 3-10％
柠檬酸 6-15％
二氯异氰尿酸钠 45-60％
元明粉 10-25％
低泡非离子表面活性剂 2-15％
香精 0.1-0.8％。
作为优选，低泡非离子表面活性剂包括烷基酚的聚氧乙烯醚、脂肪醇聚氧乙烯醚、脂肪酸甲酯聚氧乙烯醚和净洗剂6501中的一种或多种；优选，脂肪醇聚氧乙烯醚选用月桂醇聚氧乙烯醚、12-14碳伯醇聚氧乙烯醚、12-14碳仲醇聚氧乙烯醚、支链化13碳格尔伯特醇聚氧乙烯醚、支链化10碳格尔伯特醇聚氧乙烯醚、直链的10碳醇聚氧乙烯醚、直链的8碳辛醇聚氧乙烯醚、直链的8碳异辛醇聚氧乙烯醚中的一种或多种。
作为优选，低泡非离子表面活性剂中AEO-7:AEO-9＝1.7：1-2.3：1或AEO-9:AEO-3＝1：1.2–1：2；上述的配方活性物带来的去污能力最强。
为了实现上述的第二个目的，本发明采用了以下的技术方案：
一种制备上述任意一个技术方案所述的马桶清洁剂的方法，该方法包括以下的步骤：
1)按纯碱、酒石酸、柠檬酸、二氯异氰尿酸钠、元明粉、低泡非离子表面活性剂和香精顺序依次投料，搅拌均匀，压制成片；2)进行水溶膜包装。
作为优选，所述的水溶膜可选材料聚乙烯醇、聚乙烯醇缩乙醛、聚乙烯吡咯烷酮、聚丙烯酸、马来酸/丙烯酸共聚物、淀粉、明胶、黄原胶、瓜尔胶、羟丙基甲基纤维素，以及以上成分的均聚、共聚物和改性成分中的一种或多种混合。低泡非离子表面活性剂中AEO-7:AEO-9＝1.8：1。
本发明由于采用了上述的技术方案，与液状马桶清洁剂比较，该马桶清洁剂的优点是存放占用空间小，取用方便，清洁片通过水溶膜包覆，不会对手造成污染或腐蚀。清洁片配方合理，总活性物含量高，对尿渍有很强的去除能力，保护、光亮陶瓷，尤其是对金黄色葡萄球菌、大肠杆菌和白色念珠菌的杀灭效果可超过99.9％。
具体实施方式
实施例1
一种马桶清洁剂，由水溶膜及其内的清洁片构成，清洁片按质量百分比计由以下的组分制备得到：纯碱15％、酒石酸5％、柠檬酸8％、二氯异氰尿酸钠50％、元明粉15％、低泡非离子表面活性剂6.5％和香精0.5％。
上述纯碱和酒石酸的作用是清洁、崩解，柠檬酸的的作用是清洁、崩解、软水，二氯异氰尿酸钠的作用是消毒杀菌，元明粉的作用是赋形，低泡非离子表面活性剂的作用是去污，香精的作用是去除异味。低泡非离子表面活性剂中AEO-7:AEO-9＝1.8：1。
上述马桶清洁剂的制备方法，该方法包括以下的步骤：
1)按纯碱、酒石酸、柠檬酸、二氯异氰尿酸钠、元明粉、低泡非离子表面活性剂和除异味香精顺序依次投料，搅拌均匀，压制成片；2)进行水溶膜包装。水溶膜可选材料聚乙烯醇、聚乙烯醇缩乙醛、聚乙烯吡咯烷酮、聚丙烯酸、马来酸/丙烯酸共聚物、淀粉、明胶、黄原胶、瓜尔胶、羟丙基甲基纤维素，以及以上成分的均聚、共聚物和改性成分。膜的组成可以是以上的单一成分，也可以是多种成分的混合。
本发明定量包装，使用方便，不会使清洁片沾到手上。使用时，取产品一片，放入马桶中，半小时后，可用刷子沾水清洗马桶内部。
实施例1的马桶清洁剂测评报告如下。
样品:A.实施例1的马桶清洁剂；
B.市售洁厕液。
实施例2
一种马桶清洁剂，由水溶膜及其内的清洁片构成，清洁片按质量百分比计由以下的组分制备得到：纯碱12％、酒石酸4％、柠檬酸8％、二氯异氰尿酸钠53％、元明粉13％、低泡非离子表面活性剂9.5％和香精0.5％。低泡非离子表面活性剂中AEO-9:AEO-3＝1：1.3。
上述纯碱和酒石酸的作用是清洁、崩解，柠檬酸的的作用是清洁、崩解、软水，二氯异氰尿酸钠的作用是消毒杀菌，元明粉的作用是赋形，低泡非离子表面活性剂的作用是去污，香精的作用是去除异味。
上述马桶清洁剂的制备方法与实施例1相同。
实施例3
一种马桶清洁剂，由水溶膜及其内的清洁片构成，清洁片按质量百分比计由以下的组分制备得到：纯碱10％、酒石酸6％、柠檬酸10％、二氯异氰尿酸钠48％、元明粉11％、低泡非离子表面活性剂14.5％和香精0.5％。低泡非离子表面活性剂中AEO-9:AEO-3＝1：1.4。
上述纯碱和酒石酸的作用是清洁、崩解，柠檬酸的的作用是清洁、崩解、软水，二氯异氰尿酸钠的作用是消毒杀菌，元明粉的作用是赋形，低泡非离子表面活性剂的作用是去污，香精的作用是去除异味。
上述马桶清洁剂的制备方法与实施例1相同。

Claims (5)

1.一种马桶清洁剂，其特征在于该清洁剂由水溶膜及其内的清洁片构成，清洁片按质量百分比计由以下的组分制备得到：
纯碱 10-20％
酒石酸 3-10％
柠檬酸 6-15％
二氯异氰尿酸钠 45-60％
元明粉 10-25％
低泡非离子表面活性剂 2-15％
香精 0.1-0.8％。
2.根据权利要求1所述的一种马桶清洁剂，低泡非离子表面活性剂包括烷基酚的聚氧乙烯醚、脂肪醇聚氧乙烯醚、脂肪酸甲酯聚氧乙烯醚和净洗剂6501中的一种或多种；优选，脂肪醇聚氧乙烯醚选用月桂醇聚氧乙烯醚、12-14碳伯醇聚氧乙烯醚、12-14碳仲醇聚氧乙烯醚、支链化13碳格尔伯特醇聚氧乙烯醚、支链化10碳格尔伯特醇聚氧乙烯醚、直链的10碳醇聚氧乙烯醚、直链的8碳辛醇聚氧乙烯醚、直链的8碳异辛醇聚氧乙烯醚中的一种或多种。
3.根据权利要求1所述的一种马桶清洁剂，其特征在于低泡非离子表面活性剂中AEO-7:AEO-9＝1.7：1-2.3：1或AEO-9:AEO-3＝1：1.2–1：2；所述的非离子表面活性剂：十二烷基苯磺酸＝2：8-3：7。
4.一种制备权利要求1-3任意一项权利要求所述的马桶清洁剂的方法，其特征在于该方法包括以下的步骤：1)按纯碱、酒石酸、柠檬酸、二氯异氰尿酸钠、元明粉、低泡非离子表面活性剂和香精顺序依次投料，搅拌均匀，压制成片；2)进行水溶膜包装。
5.根据权利要求4所述的马桶清洁剂的制备方法，其特征在于水溶膜可选材料聚乙烯醇、聚乙烯醇缩乙醛、聚乙烯吡咯烷酮、聚丙烯酸、马来酸/丙烯酸共聚物、淀粉、明胶、黄原胶、瓜尔胶、羟丙基甲基纤维素，以及以上成分的均聚、共聚物和改性成分中的一种或多种混合。
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Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1096812A (zh) * 1993-06-19 1994-12-28 靳松 厕所清洁剂
CN1608123A (zh) * 2001-12-20 2005-04-20 雷克特本克斯尔有限公司 装有干燥活性物的水溶性容器
CN103068959A (zh) * 2010-08-06 2013-04-24 雷利维股份公司 覆有薄膜的清洁剂
CN104450342A (zh) * 2014-11-10 2015-03-25 王海林 一种用于洁具的缓释型发泡剂
CN104903434A (zh) * 2013-01-07 2015-09-09 宝洁公司 用于再循环多隔室单位剂量制品的方法

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1096812A (zh) * 1993-06-19 1994-12-28 靳松 厕所清洁剂
CN1608123A (zh) * 2001-12-20 2005-04-20 雷克特本克斯尔有限公司 装有干燥活性物的水溶性容器
CN103068959A (zh) * 2010-08-06 2013-04-24 雷利维股份公司 覆有薄膜的清洁剂
CN104903434A (zh) * 2013-01-07 2015-09-09 宝洁公司 用于再循环多隔室单位剂量制品的方法
CN104450342A (zh) * 2014-11-10 2015-03-25 王海林 一种用于洁具的缓释型发泡剂

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