CN106336189A - Environment-friendly fireproof material and preparation method thereof - Google Patents

Environment-friendly fireproof material and preparation method thereof Download PDF

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Publication number
CN106336189A
CN106336189A CN201610768869.XA CN201610768869A CN106336189A CN 106336189 A CN106336189 A CN 106336189A CN 201610768869 A CN201610768869 A CN 201610768869A CN 106336189 A CN106336189 A CN 106336189A
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Prior art keywords
parts
powder
water
environment
fireproof material
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Pending
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CN201610768869.XA
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Chinese (zh)
Inventor
裴寿益
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Individual
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Individual
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Priority to CN201610768869.XA priority Critical patent/CN106336189A/en
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    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B28/00Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements
    • C04B28/34Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements containing cold phosphate binders
    • C04B28/344Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements containing cold phosphate binders the phosphate binder being present in the starting composition solely as one or more phosphates
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2111/00Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
    • C04B2111/00008Obtaining or using nanotechnology related materials
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2111/00Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
    • C04B2111/00017Aspects relating to the protection of the environment
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2111/00Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
    • C04B2111/00474Uses not provided for elsewhere in C04B2111/00
    • C04B2111/00482Coating or impregnation materials
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2111/00Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
    • C04B2111/20Resistance against chemical, physical or biological attack
    • C04B2111/27Water resistance, i.e. waterproof or water-repellent materials

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Ceramic Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Inorganic Chemistry (AREA)
  • Materials Engineering (AREA)
  • Structural Engineering (AREA)
  • Organic Chemistry (AREA)
  • Fireproofing Substances (AREA)

Abstract

The invention relates to an environment-friendly fireproof material and a preparation method thereof. The environment-friendly fireproof material is prepared from 10 to 30 parts of distilled water, 10 to 20 parts of water-based emulsion, 30 to 50 parts of ammonium polyphosphate, 18 to 24 parts of nano titanium dioxide, 10 to 20 parts of black mud powder, 5 to 10 parts of kyanite powder, 5 to 10 parts of zirconium silicate powder or yttria-stabilized zirconia powder, 3 to 7 parts of a coalescing agent, 1 to 2 parts of expandable graphite and 0.2 to 0.6 part of kaoline. The fireproof material disclosed by the invention has the characteristics of resistance to high temperature and cracking resistance, is non-toxic and odorless, environment-friendly, high in decorating property and convenient to construct, can be sprayed and can keep the original appearance of a base material.

Description

A kind of environment-friendly fireproof material and preparation method thereof
Technical field
The present invention relates to new material technology field is and in particular to a kind of environment-friendly fireproof material and preparation method thereof.
Background technology
Fire proofing material is widely used in the multiple fields such as industry, building industry, and its quality directly affects personal safety and wealth Produce safety, the selection of therefore fire proofing material is most important.How to provide a kind of fire proofing material of environment-friendly type most important.
Content of the invention
The technical problem to be solved is for the deficiencies in the prior art, provide a kind of environment-friendly fireproof material and Its preparation method.
The technical scheme is that a kind of environment-friendly fireproof material, including 10 parts -30 parts Distilled water, 10 parts of -20 parts of water-based emulsions, 30 parts of -50 parts of ammonium polyphosphates, 18 parts of -24 parts of nanometer titanium dioxides, 10 parts -20 parts black Mud powder, 5 parts -10 parts aquamaine stone powders, 5 parts of -10 parts of zirconium silicate powders or yttrium stable zirconium oxide powder, 3 parts of -7 parts of coalescents, 1 part -2 Part expansible graphite, 0.2 part of -0.6 part of Kaolin.
The invention has the beneficial effects as follows: the fire proofing material of the present invention have the characteristics that high temperature resistant, anti-hardening crack, and nontoxic nothing Taste, environmental protection, decoration performance is good, easy construction, and spary can keep the original appearance of base material.
On the basis of technique scheme, the present invention can also do following improvement.
Further, in parts by weight, including 10 parts of distilled water, 10 parts of water-based emulsions, 30 parts of ammonium polyphosphates, 18 parts of nanometers Titanium dioxide, 10 parts of black mud powder, 5 parts of aquamaine stone powders, 5 parts of zirconium silicate powders or yttrium stable zirconium oxide powder, 3 parts of coalescents, 1 part can be swollen Swollen graphite, 0.2 part of Kaolin.
Further, in parts by weight, including 20 parts of distilled water, 15 parts of water-based emulsions, 40 parts of ammonium polyphosphates, 20 parts of nanometers Titanium dioxide, 15 parts of black mud powder, 8 parts of aquamaine stone powders, 7 parts of zirconium silicate powders or yttrium stable zirconium oxide powder, 4 parts of coalescents, 1.5 parts can Expanded graphite, 0.4 part of Kaolin.
Further, in parts by weight, including 30 parts of distilled water, 20 parts of water-based emulsions, 50 parts of ammonium polyphosphates, 24 parts of nanometers Titanium dioxide, 20 parts of black mud powder, 10 parts of aquamaine stone powders, 10 parts of zirconium silicate powders or yttrium stable zirconium oxide powder, 7 parts of coalescents, 2 parts can Expanded graphite, 0.6 part of Kaolin.
A kind of preparation method of environment-friendly fireproof material as described above, comprises the following steps:
Step 1), weigh distilled water, nanometer titanium dioxide, ammonium polyphosphate, zirconium silicate powder or yttrium by weight and stably aoxidize Zirconium powder, black mud powder and aquamaine stone powder, and mix homogeneously obtains mixed liquor;
Step 2), weigh water-based emulsion by weight, and water-based emulsion is added in mixed liquor, stir and make aqueouss Emulsion evenly spreads in mixed liquor, obtains dispersion liquid;
Step 3), will add coalescents, expansible graphite and Kaolin in dispersion liquid, dispersed 50min-80min, Filter fill.
The invention has the beneficial effects as follows: the method for the present invention is simple, can reduce the destruction of effective ingredient.
Specific embodiment
Hereinafter the principle and feature of the present invention is described, example is served only for explaining the present invention, is not intended to limit Determine the scope of the present invention.
Embodiment 1
A kind of environment-friendly fireproof material of the present embodiment, in parts by weight, including 10 parts of distilled water, 10 parts of water-based emulsions, 30 parts of ammonium polyphosphates, 18 parts of nanometer titanium dioxides, 10 parts of black mud powder, 5 parts of aquamaine stone powders, 5 parts of zirconium silicate powders or yttrium stably aoxidize Zirconium powder, 3 parts of coalescents, 1 part of expansible graphite, 0.2 part of Kaolin.
The fire proofing material of the present embodiment have the characteristics that high temperature resistant, anti-hardening crack, and nonpoisonous and tasteless, environmental protection, ornamental Good, the easy construction of energy, spary, the original appearance of base material can be kept.
A kind of preparation method of environment-friendly fireproof material of the present embodiment, comprises the following steps:
Step 1), weigh distilled water, nanometer titanium dioxide, ammonium polyphosphate, zirconium silicate powder or yttrium by weight and stably aoxidize Zirconium powder, black mud powder and aquamaine stone powder, and mix homogeneously obtains mixed liquor;
Step 2), weigh water-based emulsion by weight, and water-based emulsion is added in mixed liquor, stir and make aqueouss Emulsion evenly spreads in mixed liquor, obtains dispersion liquid;
Step 3), coalescents, expansible graphite and Kaolin, dispersed 50min will be added in dispersion liquid, filter and fill Dress.
The method of the present embodiment is simple, can reduce the destruction of effective ingredient.
Embodiment 2
A kind of environment-friendly fireproof material of embodiment, in parts by weight, including 20 parts of distilled water, 15 parts of water-based emulsions, 40 Part ammonium polyphosphate, 20 parts of nanometer titanium dioxides, 15 parts of black mud powder, 8 parts of aquamaine stone powders, 7 parts of zirconium silicate powders or yttrium stable zirconium oxide Powder, 4 parts of coalescents, 1.5 parts of expansible graphites, 0.4 part of Kaolin.
A kind of preparation method of environment-friendly fireproof material of the present embodiment, comprises the following steps:
Step 1), weigh distilled water, nanometer titanium dioxide, ammonium polyphosphate, zirconium silicate powder or yttrium by weight and stably aoxidize Zirconium powder, black mud powder and aquamaine stone powder, and mix homogeneously obtains mixed liquor;
Step 2), weigh water-based emulsion by weight, and water-based emulsion is added in mixed liquor, stir and make aqueouss Emulsion evenly spreads in mixed liquor, obtains dispersion liquid;
Step 3), coalescents, expansible graphite and Kaolin, dispersed 65min will be added in dispersion liquid, filter and fill Dress.
The method of the present embodiment is simple, can reduce the destruction of effective ingredient.
Embodiment 3
A kind of environment-friendly fireproof material of embodiment, in parts by weight, including 30 parts of distilled water, 20 parts of water-based emulsions, 50 Part ammonium polyphosphate, 24 parts of nanometer titanium dioxides, 20 parts of black mud powder, 10 parts of aquamaine stone powders, 10 parts of zirconium silicate powders or yttrium stably aoxidize Zirconium powder, 7 parts of coalescents, 2 parts of expansible graphites, 0.6 part of Kaolin.
A kind of preparation method of environment-friendly fireproof material of the present embodiment, comprises the following steps:
Step 1), weigh distilled water, nanometer titanium dioxide, ammonium polyphosphate, zirconium silicate powder or yttrium by weight and stably aoxidize Zirconium powder, black mud powder and aquamaine stone powder, and mix homogeneously obtains mixed liquor;
Step 2), weigh water-based emulsion by weight, and water-based emulsion is added in mixed liquor, stir and make aqueouss Emulsion evenly spreads in mixed liquor, obtains dispersion liquid;
Step 3), coalescents, expansible graphite and Kaolin, dispersed 80min will be added in dispersion liquid, filter and fill Dress.
The method of the present embodiment is simple, can reduce the destruction of effective ingredient.
The resistance to elevated temperatures of the environment-friendly fireproof material in embodiment 1-3 is tested.Respectively described in Example 1-3 Fire proofing material, respectively fire proofing material a, fire proofing material b, fire proofing material c, then fire proofing material a-c is coated in wall On one side, and using identical temperature, high-temperature heating is carried out to the another side of wall and heat time heating time is identical, heating-up temperature For 150 DEG C, heat time heating time is 2h.Then the temperature of the another side of waterproof material is detected, testing result such as table 1 institute Show.
The fire protecting performance of table 1 fire proofing material
Fire proofing material Heating-up temperature Detection temperature
a 150℃ 42℃
b 150℃ 35℃
c 150℃ 36℃
As shown in Table 1, the fire proofing material of the present embodiment can fire-proof and thermal-insulation effect good.
The foregoing is only presently preferred embodiments of the present invention, not in order to limit the present invention, all spirit in the present invention and Within principle, any modification, equivalent substitution and improvement made etc., should be included within the scope of the present invention.

Claims (6)

1. a kind of environment-friendly fireproof material is it is characterised in that in parts by weight, including 10 parts of -30 parts of distilled water, 10 parts -20 parts Water-based emulsion, 30 parts of -50 parts of ammonium polyphosphates, 18 parts of -24 parts of nanometer titanium dioxides, 10 parts -20 parts black mud powder, 5 parts of -10 parts of aquamaines Stone powder, 5 parts of -10 parts of zirconium silicate powders or yttrium stable zirconium oxide powder, 3 parts of -7 parts of coalescents, 1 part of -2 parts of expansible graphite, 0.2 - 0.6 part of Kaolin of part.
2. a kind of environment-friendly fireproof material it is characterised in that in parts by weight, distills including 10 parts according to claim 1 Water, 10 parts of water-based emulsions, 30 parts of ammonium polyphosphates, 18 parts of nanometer titanium dioxides, 10 parts of black mud powder, 5 parts of aquamaine stone powders, 5 parts of silicic acid Zirconium powder or yttrium stable zirconium oxide powder, 3 parts of coalescents, 1 part of expansible graphite, 0.2 part of Kaolin.
3. a kind of environment-friendly fireproof material it is characterised in that in parts by weight, distills including 20 parts according to claim 1 Water, 15 parts of water-based emulsions, 40 parts of ammonium polyphosphates, 20 parts of nanometer titanium dioxides, 15 parts of black mud powder, 8 parts of aquamaine stone powders, 7 parts of silicic acid Zirconium powder or yttrium stable zirconium oxide powder, 4 parts of coalescents, 1.5 parts of expansible graphites, 0.4 part of Kaolin.
4. a kind of environment-friendly fireproof material it is characterised in that in parts by weight, distills including 30 parts according to claim 1 Water, 20 parts of water-based emulsions, 50 parts of ammonium polyphosphates, 24 parts of nanometer titanium dioxides, 20 parts of black mud powder, 10 parts of aquamaine stone powders, 10 parts of silicon Sour zirconium powder or yttrium stable zirconium oxide powder, 7 parts of coalescents, 2 parts of expansible graphites, 0.6 part of Kaolin.
5. a kind of environment-friendly fireproof material it is characterised in that in parts by weight, also includes 1 part -2 parts according to claim 1 Plastics smog inhibitor.
6. environment-friendly fireproof material as described in a kind of any one as claim 1 to 5 preparation method it is characterised in that include with Lower step:
Step 1), weigh by weight distilled water, nanometer titanium dioxide, ammonium polyphosphate, zirconium silicate powder or yttrium stable zirconium oxide powder, Black mud powder and aquamaine stone powder, and mix homogeneously obtains mixed liquor;
Step 2), weigh water-based emulsion by weight, and water-based emulsion is added in mixed liquor, stir and make water-based emulsion Evenly spread in mixed liquor, obtain dispersion liquid;
Step 3), coalescents, expansible graphite and Kaolin, dispersed 50min-80min will be added in dispersion liquid, filter Fill.
CN201610768869.XA 2016-08-30 2016-08-30 Environment-friendly fireproof material and preparation method thereof Pending CN106336189A (en)

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Application Number Priority Date Filing Date Title
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Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107673671A (en) * 2017-10-20 2018-02-09 广西银英生物质能源科技开发股份有限公司 High-temperature-resistant fireproof material
CN107721261A (en) * 2017-10-20 2018-02-23 广西银英生物质能源科技开发股份有限公司 Heat-insulating fireproof material and preparation method thereof
CN107777986A (en) * 2017-10-20 2018-03-09 广西银英生物质能源科技开发股份有限公司 Environment-friendly fireproof material and preparation method thereof
CN109536029A (en) * 2017-08-02 2019-03-29 天源华威集团有限公司 A kind of environmental-protection fireproof material

Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2006070960A1 (en) * 2004-12-31 2006-07-06 Kyung Dong Ceratech Co., Ltd. Covering composite for fire resistance and sound absorption
CN102584115A (en) * 2011-12-20 2012-07-18 汪洋 Fireproof material, preparation method thereof and fireproof door
CN104743974A (en) * 2013-12-30 2015-07-01 天津赫得建材发展有限公司 Fireproof material
CN105176242A (en) * 2015-10-10 2015-12-23 徐州市三为水性漆科技有限公司 Water-based environment-friendly expansive fireproof new material and preparing method thereof
CN105440411A (en) * 2015-12-19 2016-03-30 青岛大方智慧网络科技有限公司 Fireproof material for strongbox

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2006070960A1 (en) * 2004-12-31 2006-07-06 Kyung Dong Ceratech Co., Ltd. Covering composite for fire resistance and sound absorption
CN102584115A (en) * 2011-12-20 2012-07-18 汪洋 Fireproof material, preparation method thereof and fireproof door
CN104743974A (en) * 2013-12-30 2015-07-01 天津赫得建材发展有限公司 Fireproof material
CN105176242A (en) * 2015-10-10 2015-12-23 徐州市三为水性漆科技有限公司 Water-based environment-friendly expansive fireproof new material and preparing method thereof
CN105440411A (en) * 2015-12-19 2016-03-30 青岛大方智慧网络科技有限公司 Fireproof material for strongbox

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN109536029A (en) * 2017-08-02 2019-03-29 天源华威集团有限公司 A kind of environmental-protection fireproof material
CN107673671A (en) * 2017-10-20 2018-02-09 广西银英生物质能源科技开发股份有限公司 High-temperature-resistant fireproof material
CN107721261A (en) * 2017-10-20 2018-02-23 广西银英生物质能源科技开发股份有限公司 Heat-insulating fireproof material and preparation method thereof
CN107777986A (en) * 2017-10-20 2018-03-09 广西银英生物质能源科技开发股份有限公司 Environment-friendly fireproof material and preparation method thereof

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Application publication date: 20170118