CN106318491A - Nano-composite gasoline and preparation method thereof - Google Patents

Abstract

The invention discloses a nano-composite gasoline and a preparation method thereof. The nano-composite gasoline contains the following raw materials in parts by weight: 5-10 parts of water, 40-50 parts of national standard gasoline, 15-20 parts of oleic acid, 15-20 parts of barbadosnut seed oil, 10-15 parts of ethyl alcohol, 21-28 parts of solvent oil, 10-15 parts of isobutyl alcohol, 10-12 parts of n-butyl alcohol, 7-9 parts of n-caprylic alcohol, 8-10 parts of ethylene glycol monomethyl ether, 10-15 parts of diethyl ether, 12-18 parts of acetone, 0.5-0.7 part of benzotriazole, 5-7 parts of tri-phosphate and 2-4 parts of antioxygen. According to the invention, the reproducible biologic materials including ethyl alcohol, water, oleic acid and the like are taken as the main raw materials; the production is simple and convenient; the raw material resource is wide; the preparation technique is simple; in a use process, the gasoline is fully combusted and is non-toxic and smoke-free; the nano-composite gasoline can replace the national standard gasoline and is used as fuel in a gasoline motor vehicle; the nano-composite gasoline belongs to a clean renewable energy source, is low in cost and is beneficial to environmental protection.

Description

A kind of nano composite gasoline and preparation method thereof

Technical field

The present invention relates to a kind of fuel oil and preparation method thereof, particularly one nano composite gasoline and preparation method thereof, Belong to fuel oil chemical technology field.

Background technology

Along with expanding economy, world energy consumption is continuously increased, and energy shortage situation is day by day serious, and various countries are recognized the most one after another That knows to fuel-saving technique is important.At present, China is accelerating the research and development paces of new forms of energy and fungible energy source always, to alleviate oil Energy supply and demand contradiction, alleviates petroleum import pressure, alleviates resource environment constraint, ensures energy security, promotes that China's economy can be held Supervention exhibition is significant.In this context, market occurs in that a lot of methanol gasoline, biogasoline, alcohol fuel etc. are new The energy, but all there is the shortcomings such as calorific value layering low, easy, perishable, production cost is high, it is difficult to obtain spread.Nanometer is multiple Close gasoline also known as water mixing gasoline, as far back as at the beginning of eighties of last century just it has been suggested that water is mixed and fuel oil improves burning this sets Think, but due to formula and the defect of technique, the distribution of its nano particle diameter be wide, easily reunite, especially with time be difficult to ensure that It is still completely in nano-scale range, thus loses nanoparticle high-ratio surface, highly active characteristic, easily causes simultaneously and sends out The problems such as motivation cylinder wear and blocking oil circuit, cause it not obtain large-scale industrialization application.

Summary of the invention

A kind of new nano composite gasoline formula of offer that has a problem in that to be solved by this invention, provides a kind of nanometer simultaneously The preparation method of composite gasoline, uses the composite nanoparticle uniform particle sizes of nano composite gasoline prepared by this formula and technique, The most still can keep nanoscale dispersity, can effectively reduce the exhaust emissions in gasoline combustion process, it is to avoid be stifled Plug oil circuit.

For solving above-mentioned technical problem, the present invention uses following technical scheme:

A kind of nano composite gasoline, it is made up of the raw material of following composition by weight: water 5-10 part, GB gasoline 40-50 part, oleic acid 15-20 part, barbadosnut seed oil 15-20 part, ethanol 10-15 part, solvent naphtha 21-28 part, isobutanol 10-15 part, n-butyl alcohol 10-12 Part, n-octyl alcohol 7-9 part, ethylene glycol monomethyl ether 8-10 part, ether 10-15 part, acetone 12-18 part, benzotriazole 0.5-0.7 part, Tricresyl phosphate fat 5-7 part, antioxidant 2-4 part.

In above-mentioned nano composite gasoline, it is preferred that described raw material is: 10 parts of water, 50 parts of GB gasoline, oleic acid 20 parts, Barbadosnut seed oil 20 parts, ethanol 15 parts, solvent naphtha 25 parts, isobutanol 14 parts, n-butyl alcohol 11 parts, n-octyl alcohol 8 parts, ethylene glycol first 9 parts of ether, ether 13 parts, 15 parts of acetone, benzotriazole 0.6 part, 6 parts of tricresyl phosphate fat, 3 parts of antioxidant.

In above-mentioned nano composite gasoline, described antioxidant is 502A or T501.

The preparation method of a kind of nano composite gasoline, comprises the following steps:

(1) by GB gasoline, ethanol, water, barbadosnut seed oil, solvent naphtha, isobutanol, n-butyl alcohol, n-octyl alcohol, ethylene glycol monomethyl ether, Ether, acetone, benzotriazole, tricresyl phosphate fat, antioxidant add in reactor, are slow added into oleic acid, start circulation shear Pump be sufficiently stirred for 50～60 minutes to oil product limpid transparent；

(2) oil product produced is stood ripening 24～48 hours, observe oil product the most limpid transparent, get product；If any white Precipitation or become cloudy, adds a small amount of oleic acid and to be stirred well to oil product limpid transparent, get product.

Beneficial effects of the present invention: compared with prior art, the primary raw material that the present invention uses is ethanol, water, oleic acid etc. Reproducible biological material, produces easy and raw material sources is wide, and cost is relatively low, and preparation technology is simple, in use fires Burn abundant and nontoxic smokelessly production process do not have any waste residue, waste liquid, waste gas etc. " three wastes " produce, free from environmental pollution, cleaning Environmental protection, calorific value is high, limpid transparent, and water-resistance is strong, and long term storage is not stratified, never degenerate, and product quality leading indicator entirely reaches Petrochemical industry gasoline national standard, alternative GB 93#, 97# gasoline, use as fuel in vehicles equipped with gasoline engine, belonging to cleaning can The renewable sources of energy, low cost and beneficially environmental conservation.

Below in conjunction with detailed description of the invention, the present invention is further illustrated.

Detailed description of the invention

Embodiment 1: fetch water 10 parts, 50 parts of GB 93# gasoline, oleic acid 20 parts, barbadosnut seed oil 20 parts, ethanol 15 parts, 200# solvent naphtha 25 parts, isobutanol 14 parts, n-butyl alcohol 11 parts, n-octyl alcohol 8 parts, ethylene glycol monomethyl ether 9 parts, ether 3 parts, acetone 15 Part, benzotriazole 0.6 part, 6 parts of tricresyl phosphate fat, 3 parts of 502A antioxidant.According to the above ratio by GB 93# gasoline, ethanol, fiber crops Crazy seeds of trees oil, water, 200# solvent naphtha, isobutanol, n-butyl alcohol, n-octyl alcohol, ethylene glycol monomethyl ether, ether, acetone, benzotriazole, Tricresyl phosphate fat, 502A antioxidant add in reactor, are slow added into oleic acid, start circulation shear pump and are sufficiently stirred for 50 minutes left sides Right to oil product limpid transparent；Again the oil product produced is stood ripening 36 hours at reactor or storage tank, observe oil product still Limpid transparent, get product；If any white precipitate or become cloudy, then explanation oil product ingredients is uneven or reacts insufficient, adds A small amount of oleic acid to be stirred well to oil product limpid transparent, gets product.

The water that the present invention adds can play following effect: one is cracking energization effect: water is made up of hydrogen and oxygen, under high temperature The hydrogen that can crack out high several times than gasoline energy participates in burning；Two are confession oxygen effect: the oxygen of cracking is that fuel adds more Many comburant oxygens；Three is effect of micro-explosion: when producing the steam of 1700 times volumes bigger than self during water vapor, can break through oil film and make Oil is atomized once again, thus more fully burns；Four is water gas effect: water vapour is converted into dioxy with the carbon monoxide failing to burn Change carbon and highly exothermic；Five is equal heat effect: steam can effectively reduce cylinder localized hyperthermia and protect body, reduces friction resistance Power, alleviates coking；Six is environmental protection and energy saving effect: water instead of part of fuel oil, has huge energy-conservation and environment protection significance, right Save limited petroleum resources significant.

Embodiment 2: fetch water 5 parts, 40 parts of GB 93# gasoline, oleic acid 15 parts, barbadosnut seed oil 15 parts, ethanol 10 parts, 200# Solvent naphtha 21 parts, isobutanol 10 parts, n-butyl alcohol 10 parts, n-octyl alcohol 7 parts, ethylene glycol monomethyl ether 8 parts, ether 10 parts, 12 parts of acetone, benzene A pair of horses going side by side triazole 0.5 part, 5 parts of tricresyl phosphate fat, 2 parts of T501 antioxidant.According to the above ratio by GB 93# gasoline, barbadosnut seed oil, second Alcohol, water, 200# solvent naphtha, isobutanol, n-butyl alcohol, n-octyl alcohol, ethylene glycol monomethyl ether, ether, acetone, benzotriazole, tricresyl phosphate Fat, T501 antioxidant add in reactor, are slow added into oleic acid, start circulation shear pump be sufficiently stirred for 50 minutes clear to oil product Bright transparent till；Again the oil product produced is stood ripening 24 hours at reactor or storage tank, observe oil product the most limpid transparent, i.e. Obtain finished product；If any white precipitate or become cloudy, then explanation oil product ingredients is uneven or reacts insufficient, adds a small amount of oleic acid and fills Divide stirring limpid transparent to oil product, get product.

Embodiment 3: fetch water 10 parts, 50 parts of GB 93# gasoline, oleic acid 20 parts, barbadosnut seed oil 20 parts, ethanol 15 parts, 200# solvent naphtha 28 parts, isobutanol 15 parts, n-butyl alcohol 12 parts, n-octyl alcohol 9 parts, ethylene glycol monomethyl ether 10 parts, ether 15 parts, acetone 18 Part, benzotriazole 0.7 part, 7 parts of tricresyl phosphate fat, 4 parts of T501 antioxidant.According to the above ratio by GB 93# gasoline, barbadosnut seed Oil, ethanol, water, 200# solvent naphtha, isobutanol, n-butyl alcohol, n-octyl alcohol, ethylene glycol monomethyl ether, ether, acetone, benzotriazole, phosphorus Acid three fat, T501 antioxidant add in reactor, are slow added into oleic acid, start circulation shear pump and are sufficiently stirred for 60 minutes to oil Product limpid transparent till；Again the oil product produced is stood ripening 48 hours at reactor or storage tank, observe oil product the most limpid Bright, get product；If any white precipitate or become cloudy, then explanation oil product ingredients is uneven or reacts insufficient, adds a small amount of oil Acid to be stirred well to oil product limpid transparent, gets product.

Claims (4)

1. a nano composite gasoline, it is characterised in that be made up of the raw material of following composition by weight: water 5-10 part, GB gasoline 40-50 part, oleic acid 15-20 part, barbadosnut seed oil 15-20 part, ethanol 10-15 part, solvent naphtha 21-28 part, isobutanol 10-15 Part, n-butyl alcohol 10-12 part, n-octyl alcohol 7-9 part, ethylene glycol monomethyl ether 8-10 part, ether 10-15 part, acetone 12-18 part, benzene a pair of horses going side by side three Nitrogen azoles 0.5-0.7 part, tricresyl phosphate fat 5-7 part, antioxidant 2-4 part.

Nano composite gasoline the most according to claim 1, it is characterised in that described raw material is: 10 parts of water, GB gasoline 50 Part, oleic acid 20 parts, barbadosnut seed oil 20 parts, ethanol 15 parts, solvent naphtha 25 parts, isobutanol 14 parts, n-butyl alcohol 11 parts, the most pungent Alcohol 8 parts, ethylene glycol monomethyl ether 9 parts, ether 13 parts, 15 parts of acetone, benzotriazole 0.6 part, 6 parts of tricresyl phosphate fat, antioxidant 3 Part.

Nano composite gasoline the most according to claim 1, it is characterised in that described antioxidant is 502A or T501.

4. the preparation method of nano composite gasoline as claimed in claim 1 or 2, it is characterised in that comprise the following steps:

(1) by GB gasoline, ethanol, water, barbadosnut seed oil, solvent naphtha, isobutanol, n-butyl alcohol, n-octyl alcohol, ethylene glycol monomethyl ether, Ether, acetone, benzotriazole, tricresyl phosphate fat, antioxidant add in reactor, are slow added into oleic acid, start circulation shear Pump be sufficiently stirred for 50～60 minutes to oil product limpid transparent；

(2) oil product produced is stood ripening 24～48 hours, observe oil product the most limpid transparent, get product；If any white Precipitation or become cloudy, adds a small amount of oleic acid and to be stirred well to oil product limpid transparent, get product.