CN106316690A - Method for produce liquid organic fertilizer with starch wastewater to improve saline and alkaline land - Google Patents

Method for produce liquid organic fertilizer with starch wastewater to improve saline and alkaline land Download PDF

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Publication number
CN106316690A
CN106316690A CN201610710440.5A CN201610710440A CN106316690A CN 106316690 A CN106316690 A CN 106316690A CN 201610710440 A CN201610710440 A CN 201610710440A CN 106316690 A CN106316690 A CN 106316690A
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China
Prior art keywords
starch
starch wastewater
organic fertilizer
weight portion
liquid organic
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Pending
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CN201610710440.5A
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Chinese (zh)
Inventor
王胜
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Shandong Sunway Garden Technology Co Ltd
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Shandong Sunway Garden Technology Co Ltd
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Priority to CN201610710440.5A priority Critical patent/CN106316690A/en
Publication of CN106316690A publication Critical patent/CN106316690A/en
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    • CCHEMISTRY; METALLURGY
    • C05FERTILISERS; MANUFACTURE THEREOF
    • C05GMIXTURES OF FERTILISERS COVERED INDIVIDUALLY BY DIFFERENT SUBCLASSES OF CLASS C05; MIXTURES OF ONE OR MORE FERTILISERS WITH MATERIALS NOT HAVING A SPECIFIC FERTILISING ACTIVITY, e.g. PESTICIDES, SOIL-CONDITIONERS, WETTING AGENTS; FERTILISERS CHARACTERISED BY THEIR FORM
    • C05G3/00Mixtures of one or more fertilisers with additives not having a specially fertilising activity
    • C05G3/80Soil conditioners
    • CCHEMISTRY; METALLURGY
    • C05FERTILISERS; MANUFACTURE THEREOF
    • C05BPHOSPHATIC FERTILISERS
    • C05B15/00Organic phosphatic fertilisers
    • CCHEMISTRY; METALLURGY
    • C05FERTILISERS; MANUFACTURE THEREOF
    • C05GMIXTURES OF FERTILISERS COVERED INDIVIDUALLY BY DIFFERENT SUBCLASSES OF CLASS C05; MIXTURES OF ONE OR MORE FERTILISERS WITH MATERIALS NOT HAVING A SPECIFIC FERTILISING ACTIVITY, e.g. PESTICIDES, SOIL-CONDITIONERS, WETTING AGENTS; FERTILISERS CHARACTERISED BY THEIR FORM
    • C05G5/00Fertilisers characterised by their form
    • C05G5/20Liquid fertilisers

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  • Life Sciences & Earth Sciences (AREA)
  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Pest Control & Pesticides (AREA)
  • Soil Sciences (AREA)
  • Fertilizers (AREA)

Abstract

The invention discloses a method for produce liquid organic fertilizer with starch wastewater to improve saline and alkaline land. Through the strainer filtration, anaerobic biological filter fermentation, solar aeration biological filter fermentation, starch phosphate and PPFC hydrolysis, microbial fermentation agent fermentation and other deep treatments, the starch wastewater can become liquid microbial fertilizer containing rich beneficial microbial flora and many kinds of secondary metabolites. After the application of such fertilizer, the reduction of microbial population in improved secondary saline-alkali land can be alleviated, which may increase the productivity by 20%-30%; therefore, cost can be saved and soil depletion, hardening and salinization can be alleviated with the trend of energy saving, environmental protection and sustainable development is satisfied.

Description

Utilize the method that starch wastewater produces the liquid organic fertilizer for improveing salt-soda soil
Technical field
The present invention relates to technical field of fertilizer, specially utilize starch wastewater to produce organic for improveing the liquid in salt-soda soil The method of fertilizer.
Background technology
Wheaten starch and corn starch extensively use in commercial production and daily life, but can produce in its production process Raw substantial amounts of waste water, containing organic components such as a certain amount of starch, pentosan, protein in waste water, direct discharge can cause sternly The environmental pollution of weight.At present the processing method of starch wastewater all uses the processing method of sanitary sewage, i.e. activated sludge process, Can discharge after COD is up to standard.The research of utilization of starch wastewater is a lot, as utilized starch wastewater to produce biogas, due to natural pond Liquid cannot effectively utilize and process, and the processing method of this maturation is the most gradually abandoned.Starch wastewater is also utilized to produce micro- Biological flocculant, single cell protein, pulullan polysaccharide, microbial insecticide etc., because complex process, the reasons such as product cost is high Also cannot implement.
Saline-alkali soil is salinization or a class soil of alkalization formation, including solonchak, alkaline earth and various salinized soil.In arid And the salinity contained by semiarid zone, underearth and subsoil water, due to evaporation from land effect, along with soil capillarity makes The surface layer that is raised to waterborne of contained salinity, after moisture evaporation, makes salinity stay upper soll layer, builds up and form salt-soda soil.Strand Stain is invaded due to resident sea water in area, and salt-soda soil is distributed more widely, and salt content is high, gathers too much solvable in upper soll layer or the soil body Property salt.Salt-soda soil surface soil is dried more, white, even forms salt incrustation, be full of cracks of hardening, and salinity is high, and corrosivity is strong, Can destroy plant cell tissue, hinder plant growing, high salt basicity soil even can directly make root system of plant rot to cause plant Dead.More seriously the microbial population of secondary salinization of land soil reduces.Soil microorganism and soil fertility have and Close relationship, higher microbial activity is the important symbol of fertile soil.Therefore, soil microorganism is fertile at soil and soil Power is formed and plays an important role in evolution.Secondary salinization of land increases the weight of along with saline and alkaline degree, the work of soil microorganism Property substantially reduces, and population quantity drastically reduces.Particularly aerobic microbiological, owing to air capacity reduces, oxygen is not enough, and quantity is obvious Decline.
If starch wastewater being carried out advanced treating, not only can solve problem of environmental pollution, and can turn waste into wealth, Improve the crop yield in salt-soda soil.
Summary of the invention
The technical problem to be solved in the present invention be to provide a kind of utilize starch wastewater produce for the liquid improveing salt-soda soil The method of organic fertilizer, step is as follows:
1), by the starch wastewater strainer filtering of 100~200 mesh;
2), waste water is passed through in anaerobic biofilter processes;Described anaerobic biofilter is provided with its specific surface Amass is 500~600m2/m3, porosity is the cellular macromolecule resin filler of 95~98%;Waste water is in anaerobic biofilter The time of staying be 2~6h;
3), the water outlet of anaerobic biofilter processes in entering solar energy aeration biofilter;Described solar energy aeration Gas-water ratio in biofilter is 3: 1~10: 1;Waste water residence time in solar energy aeration biofilter is 4~10h;
4), in the water outlet of solar energy aeration biofilter, add starch phosphate and poly-phosphorus iron chloride processes;Preferably, The mass ratio of starch phosphate and poly-phosphorus iron chloride is 9:4~5;It is furthermore preferred that described step 4) in starch phosphate and poly-phosphorus The addition of iron chloride is the 5%~12% of wastewater quality;
5), to every 100 weight portions starch wastewater add bean cake 20~40 weight portion, mixing grass meal 10~20 weight portion, Flyash 10~15 weight portion, magnesium sulfate 3~5 weight portion, microbial fermentation inoculum 10~20 weight portion, ferment 3~5 days;Micro- Biofermentation microbial inoculum is made up of nitrogen-fixing bacteria, bacillus subtilis and Bacillus licheniformis and bacillus cereus.Preferably, described micro-life In thing fermenting agent the mass ratio of nitrogen-fixing bacteria, bacillus subtilis and Bacillus licheniformis and bacillus cereus be 2:5:2~4:3~ 6.Preferably, bean cake 30 weight portion, mixing grass meal 15 weight portion, flyash 12 weight are added to the starch wastewater of every 100 weight portions Amount part, magnesium sulfate 4 weight portion, microbial fermentation inoculum 15 weight portion, ferment 3~5 days.
The present invention by filtration, anaerobic biofilter, solar energy aeration biofilter, starch phosphate and poly-phosphorus chlorination Some row advanced treating such as molten iron solution, microbial fermentation inoculum so that starch wastewater become as rich in beneficial microbe colony and The liquid microbe fertilizer of multiple secondary metabolites, improves the microbial population minimizing of secondary salinization of land soil after using Problem, can make secondary salinization of land volume increase 20%~30%, both provided cost savings, the most do not alleviate soil depletion, harden, saline and alkaline Change, meet the trend of energy-saving and environmental protection, sustainable development.
Detailed description of the invention
Hereinafter the preferred embodiments of the present invention are illustrated, it will be appreciated that preferred embodiment described herein is only used In the description and interpretation present invention, it is not intended to limit the present invention.
Embodiment 1
A kind of method utilizing starch wastewater to produce the liquid organic fertilizer for improveing salt-soda soil, step is as follows:
1), by the starch wastewater strainer filtering of 100 mesh;
2), waste water is passed through in anaerobic biofilter processes;Described anaerobic biofilter is provided with its specific surface Amass as 500m2/m3, porosity is the cellular macromolecule resin filler of 95~98%;Waste water stop in anaerobic biofilter Time is 6h;
3), the water outlet of anaerobic biofilter processes in entering solar energy aeration biofilter;Described solar energy aeration Gas-water ratio in biofilter is 3: 1;Waste water residence time in solar energy aeration biofilter is 4h;
4), in the water outlet of solar energy aeration biofilter, add starch phosphate and poly-phosphorus iron chloride processes;Preferably, The mass ratio of starch phosphate and poly-phosphorus iron chloride is 9:4;The addition of starch phosphate and poly-phosphorus iron chloride is wastewater quality 5%;
5), bean cake 20 weight portion, mixing grass meal 10 weight portion, flyash 10 are added to the starch wastewater of every 100 weight portions Weight portion, magnesium sulfate 3 weight portion, microbial fermentation inoculum 10 weight portion, ferment 3 days;Microbial fermentation inoculum is by nitrogen-fixing bacteria, withered Grass bacillus and Bacillus licheniformis and bacillus cereus form.
Embodiment 2
A kind of method utilizing starch wastewater to produce the liquid organic fertilizer for improveing salt-soda soil, step is as follows:
1), by the starch wastewater strainer filtering of 200 mesh;
2), waste water is passed through in anaerobic biofilter processes;Described anaerobic biofilter is provided with its specific surface Amass as 600m2/m3, porosity is the cellular macromolecule resin filler of 98%;The waste water time of staying in anaerobic biofilter For 2h;
3), the water outlet of anaerobic biofilter processes in entering solar energy aeration biofilter;Described solar energy aeration Gas-water ratio in biofilter is 10: 1;Waste water residence time in solar energy aeration biofilter is 10h;
4), in the water outlet of solar energy aeration biofilter, add starch phosphate and poly-phosphorus iron chloride processes;Preferably, The mass ratio of starch phosphate and poly-phosphorus iron chloride is 9:5;The addition of starch phosphate and poly-phosphorus iron chloride is wastewater quality 12%;
5), bean cake 40 weight portion, mixing grass meal 20 weight portion, flyash 15 are added to the starch wastewater of every 100 weight portions Weight portion, magnesium sulfate 5 weight portion, microbial fermentation inoculum 20 weight portion, ferment 3~5 days;Microbial fermentation inoculum is by fixed nitrogen Bacterium, bacillus subtilis and Bacillus licheniformis and bacillus cereus composition.Nitrogen-fixing bacteria, bacillus subtilis and Bacillus licheniformis and wax The mass ratio of sample bacillus cereus is 2:5:4:6.
Embodiment 3
A kind of method utilizing starch wastewater to produce the liquid organic fertilizer for improveing salt-soda soil, step is as follows:
1), by the starch wastewater strainer filtering of 150 mesh;
2), waste water is passed through in anaerobic biofilter processes;Described anaerobic biofilter is provided with its specific surface Amass as 550m2/m3, porosity is the cellular macromolecule resin filler of 96%;The waste water time of staying in anaerobic biofilter For 4h;
3), the water outlet of anaerobic biofilter processes in entering solar energy aeration biofilter;Described solar energy aeration Gas-water ratio in biofilter is 6: 1;Waste water residence time in solar energy aeration biofilter is 8h;
4), in the water outlet of solar energy aeration biofilter, add starch phosphate and poly-phosphorus iron chloride processes;Preferably, The mass ratio of starch phosphate and poly-phosphorus iron chloride is 9:4;The addition of powder phosphate ester and poly-phosphorus iron chloride is wastewater quality 8%;
5), bean cake 30 weight portion, mixing grass meal 15 weight portion, flyash 12 are added to the starch wastewater of every 100 weight portions Weight portion, magnesium sulfate 4 weight portion, microbial fermentation inoculum 15 weight portion, ferment 3~5 days.Microbial fermentation inoculum is by mass ratio Nitrogen-fixing bacteria, bacillus subtilis and Bacillus licheniformis and bacillus cereus composition for 2:5:3:4.
Finally it is noted that the foregoing is only the preferred embodiments of the present invention, it is not limited to the present invention, Although being described in detail the present invention with reference to previous embodiment, for a person skilled in the art, it still may be used So that the technical scheme described in foregoing embodiments to be modified, or wherein portion of techniques feature is carried out equivalent. All within the spirit and principles in the present invention, any modification, equivalent substitution and improvement etc. made, should be included in the present invention's Within protection domain.

Claims (8)

1. utilize the method that starch wastewater produces the liquid organic fertilizer for improveing salt-soda soil, it is characterised in that include as follows Step:
1), by the starch wastewater strainer filtering of 100~200 mesh;
2), waste water is passed through in anaerobic biofilter processes;Being provided with its specific surface area in described anaerobic biofilter is 500~600m2/m3, porosity is the cellular macromolecule resin filler of 95~98%;
3), the water outlet of anaerobic biofilter processes in entering solar energy aeration biofilter;Described solar energy aeration is biological Gas-water ratio in filter tank is 3: 1~10: 1;
4), in the water outlet of solar energy aeration biofilter, add starch phosphate and poly-phosphorus iron chloride processes;
5), bean cake 20~40 weight portion, mixing grass meal 10~20 weight portion, fine coal are added to the starch wastewater of every 100 weight portions Ash 10~15 weight portions, magnesium sulfate 3~5 weight portion, microbial fermentation inoculum 10~20 weight portion, ferment 3~5 days.
Utilize the method that starch wastewater produces the liquid organic fertilizer for improveing salt-soda soil the most as claimed in claim 1, its Being characterised by, the waste water time of staying in anaerobic biofilter is 2~6h.
Utilize the method that starch wastewater produces the liquid organic fertilizer for improveing salt-soda soil the most as claimed in claim 2, its Being characterised by, in solar energy aeration biofilter, residence time is 4~10h.
Utilize the method that starch wastewater produces the liquid organic fertilizer for improveing salt-soda soil the most as claimed in claim 1, its Being characterised by, described microbial fermentation inoculum is made up of nitrogen-fixing bacteria, bacillus subtilis and Bacillus licheniformis and bacillus cereus.
Utilize the method that starch wastewater produces the liquid organic fertilizer for improveing salt-soda soil the most as claimed in claim 4, its It is characterised by, nitrogen-fixing bacteria, bacillus subtilis and Bacillus licheniformis and the matter of bacillus cereus in described microbial fermentation inoculum Amount ratio is 2:5:2~4:3~6.
Utilize the method that starch wastewater produces the liquid organic fertilizer for improveing salt-soda soil the most as claimed in claim 1, its Be characterised by, described step 4) in the mass ratio of starch phosphate and poly-phosphorus iron chloride be 9:4~5.
Utilize the method that starch wastewater produces the liquid organic fertilizer for improveing salt-soda soil the most as claimed in claim 5, its Be characterised by, described step 4) in starch phosphate and addition is wastewater quality 5%~the 12% of poly-phosphorus iron chloride.
Utilize the method that starch wastewater produces the liquid organic fertilizer for improveing salt-soda soil the most as claimed in claim 1, its Be characterised by, described step 5) in every 100 weight portions starch wastewater add bean cake 30 weight portion, mixing grass meal 15 weight Part, flyash 12 weight portion, magnesium sulfate 4 weight portion, microbial fermentation inoculum 15 weight portion, ferment 3~5 days.
CN201610710440.5A 2016-08-24 2016-08-24 Method for produce liquid organic fertilizer with starch wastewater to improve saline and alkaline land Pending CN106316690A (en)

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Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107651758A (en) * 2017-11-15 2018-02-02 广西南宁荣威德新能源科技有限公司 A kind of method that organic fertilizer is prepared using starch wastewater
CN107651759A (en) * 2017-11-15 2018-02-02 广西南宁荣威德新能源科技有限公司 A kind of method for handling starch wastewater
CN108863590A (en) * 2018-08-17 2018-11-23 佛山市森昂生物科技有限公司 A method of compound fertilizer is prepared using waste water

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102134143A (en) * 2011-01-28 2011-07-27 北京市水利科学研究所 Method and device for treating sewage in anaerobic bio-filter and solar aeration bio-filter
CN103435138A (en) * 2013-08-26 2013-12-11 苏州富奇诺水治理设备有限公司 Starch phosphate-containing papermaking wastewater treatment agent
CN103642501A (en) * 2013-12-23 2014-03-19 滨州市智和生产力促进中心 Saline-alkali soil improving agent
CN105039194A (en) * 2015-03-20 2015-11-11 甘肃明德伟业生物科技有限公司 Yeast fused strain mixed bacterial agent and method of fermenting organic waste water therewith to prepare liquid fertilizer

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102134143A (en) * 2011-01-28 2011-07-27 北京市水利科学研究所 Method and device for treating sewage in anaerobic bio-filter and solar aeration bio-filter
CN103435138A (en) * 2013-08-26 2013-12-11 苏州富奇诺水治理设备有限公司 Starch phosphate-containing papermaking wastewater treatment agent
CN103642501A (en) * 2013-12-23 2014-03-19 滨州市智和生产力促进中心 Saline-alkali soil improving agent
CN105039194A (en) * 2015-03-20 2015-11-11 甘肃明德伟业生物科技有限公司 Yeast fused strain mixed bacterial agent and method of fermenting organic waste water therewith to prepare liquid fertilizer

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107651758A (en) * 2017-11-15 2018-02-02 广西南宁荣威德新能源科技有限公司 A kind of method that organic fertilizer is prepared using starch wastewater
CN107651759A (en) * 2017-11-15 2018-02-02 广西南宁荣威德新能源科技有限公司 A kind of method for handling starch wastewater
CN108863590A (en) * 2018-08-17 2018-11-23 佛山市森昂生物科技有限公司 A method of compound fertilizer is prepared using waste water

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Application publication date: 20170111