CN106313265B

CN106313265B - The method of full Eucalyptus leftover pieces production high temperature resistant oriented wood chipboard

Info

Publication number: CN106313265B
Application number: CN201610746809.8A
Authority: CN
Inventors: 陈正照
Original assignee: Guangxi Hengxian Xinweilin Plate Industry Co Ltd
Current assignee: Guangxi Hengxian Xinweilin Plate Industry Co Ltd
Priority date: 2016-08-29
Filing date: 2016-08-29
Publication date: 2018-12-28
Anticipated expiration: 2036-08-29
Also published as: CN106313265A

Abstract

The present invention provides a kind of method of full Eucalyptus leftover pieces production high temperature resistant oriented wood chipboard, including stock, dry, peeling removal of impurities, sorting storage, watch core layer respectively gluing, classification mat formation, the processes such as pre- hot-forming, sanding facing, wherein surface layer coating is isocyanates wood powder end composite adhesive, sandwich layer coating is high temperature resistant composite urea formaldehyde resin adhesive, sandwich layer wood shavings are divided into 3-tier architecture, including sandwich layer middle layer, sandwich layer upper epidermis and sandwich layer layer, sandwich layer middle layer is that longitudinal direction is mated formation, and sandwich layer upper epidermis and sandwich layer layer and surface layer are laterally to mat formation.The oriented wood chipboard being prepared by the method for the invention, the static bending strength of parallel direction are 31~40MPa, and parallel flexible modulus is 4605~4776MPa；Vertical spring modulus is 1501~1770MPa, and thickness swelling rate is 10%~18% for 24 hours, and vertical nail-holding ability is up to 89009N, dimensional stability and good reliability.Also, the oriented wood chipboard that the method for the present invention is prepared also has excellent heat resistance.

Description

The method of full Eucalyptus leftover pieces production high temperature resistant oriented wood chipboard

Technical field

The invention belongs to wood-based plate manufacturing field, especially a kind of full Eucalyptus leftover pieces production high temperature resistant oriented wood chipboard Method.

Background technique

Oriented wood chipboard is one of particieboard new varieties.Wood shavings are mated formation when forming, two surface layers up and down of oriented wood chipboard Glue mixing wood shavings are arranged by its machine direction stringer, and sandwich layer wood shavings are transversely arranged, form three-decker plate embryo, and then hot pressing At oriented wood chipboard.The wood shavings shape need length and width of this particieboard are bigger, and thickness is more thicker than the wood shavings of ordinary particle board.

Oriented wood chipboard is that log is removed the peel, is cut into the flaking with certain geometrical shape, flaking ruler along grain direction Very little is usually long 40~140 mm, wide 5~20 mm, 0.40~0.60 mm of thickness, then through drying and applies synthetic resin gum And waterproofing agent, simulate natural timber fiber direction it is oriented mat formation into slab after, then through one kind made of high temperature hot pressing Artificial engineering structural panel.

Shape, the size of oriented wood chipboard watch core layer wood shavings are the same, only use orienting spreading, and sandwich layer wood shavings are laterally arranged Column, surface layer wood shavings longitudinal arrangement, watch core layer wood shavings form certain orientation angle, to make the mechanics of oriented wood chipboard all directions Performance is identical, and the orienting spreading of oriented wood chipboard makes oriented wood chipboard have intensity height, good stability of the dimension, processing performance good The features such as, the advantages of glued board and ordinary particle board, is combined into one, the wooden unit for both having merged glued board is longer, level point Feature bright, arranged in a uniform, while the spy that ordinary particle board process is simple and easy to operate, is produced on a large scale has been drawn again Point often replaces glued board to do structural wood use.

The raw material for making oriented wood chipboard includes wood particulate, adhesive and additive, and wood particulate accounts for plate dry weight 90% or more, adhesive and additive account for 10% or so；Wood particulate is derived from forest zone thinnings more, (diameter is usually 8 for small dimension wood Centimetre or less), logging residue and wood machining residues etc..Wood particulate includes slabbing, strip, needle-shaped, granular wood Piece, wood shavings, wood wool, sawdust etc..Adhesive uses modified urea-formaldehyde resin glue or melamine glue or two kinds of glue to be used in conjunction with more.

Shaving shape is the deciding factor of oriented wood chipboard quality, therefore first has to produce qualified wood shavings.Timber The wood shavings of residue can be used as the sandwich layer of particieboard through reprocessing in processing.Surface layer wood shavings are mainly with advanced in felling or processing Residue (timber butt, edges of boards etc.) specially produce by processing.Length, thickness, the wide dimensions of wood shavings because of production method and are used for Make sandwich layer or surface layer etc. and it is different.The process equipment for preparing wood shavings has wood chipping equipment, desintegrator, sander and defibrator, cuts The mode of cutting has cutting, cutting and is crushed.It, be by processes such as just broken, polishing, broken again and screenings to obtain high-quality wood shavings.

Manufactured goods oriented wood chipboard does not need to dry again, can directly use, and sound-absorbing and sound insulation value are also fine.But it Also have the shortcomings that its is intrinsic, because of edge roughness, be easy moisture absorption, so just seeming special with the edge sealing of furniture technique of particle boards to manufacturing It is unimportant.It is larger additionally, due to particieboard volume, with its Hepplewhite, for other plates, also than heavier.

In recent years, the provinces such as Guangdong and Guangxi Provinces, Yunnan, Fujian, Guizhou, Hainan of south China start to introduce a fine variety by the state-owned east gate woods in Guangxi Field is cultivated and the fast-growing eucalyptus kind in Guangdong, and fast-growing Eucalyptus is a kind of leaf wood of light color, and wood grain is close and irregular, sapwood layer ratio It is wider, in white to pale pink；The light brown red that heartwood has.The fast-growing eucalyptus speed of growth is fast at present, can become a useful person within 3 years, hill farmer is big Amount plantation, 50% or more of timber can be utilized by having accounted for south, in addition the arboreal growths such as original tree species such as pine tree, Chinese fir, margosa It is relatively slow, it is no longer able to haggle as wildwood and cut down, and the timber yield of 1 mu of fast-growing eucalyptus is equivalent to 5 mu or more of natural forest products Amount, eucalyptus only account for the 13.7% of forest in Guangxi area, but solve the timber demand in 80% or more Guangxi, 20% or more the whole nation.

So fast-growing eucalyptus plate manufacturing enterprise rapid emergence, production method are to be peeled into plate after cutting down eucalyptus, do Plate is bonded into multi-layer board with adhesive again after dry, this multi-layer board is also referred to as solid wood board, can be used as good office appliance, wood Floor, furniture and building-supporting plate multiple use, but multiple-plate production process generates a large amount of corner timber, either In cutting, rotary-cut or adhesion process, many particles can be all generated, these multi-layer board factories, particle can only be burnt up as fuel, Cause the great wasting of resources.

Chinese patent discloses some methods for using culled wood to produce oriented wood chipboard for raw material, such as:

1, Chinese patent, application number: 201510061938.9；Applicant: Lu Li wood industry Co., Ltd of Shouguang City；Invention Title: one kind can facing oriented wood chipboard and its preparation process；Abstract: the present invention relates to one kind can facing oriented wood chipboard and its Preparation process, can facing oriented wood chipboard include sandwich layer and surface layer, core layer raw material selects remaining rotation during plywood production Singulation plate leftover bits and pieces, top layer raw material select integrated timber, core-board, the sawdust generated in particieboard or medium density fiberboard production process, Wood shavings, useless fiber, sanding powder, the raw material through drying, screening, be glued, mat formation, be made after slab saw is cut out and hot pressing can facing it is fixed To particieboard, the static bending strength of oriented wood chipboard parallel direction can reach 22~30MPa, and elasticity modulus can reach 3500~ 4800Mpa, surface roughness less than 0.8 μm, can be directly used for processing facing, can also replace extensively glued board, core-board, The wood-based plates such as particieboard, medium density fiberboard.

2, Chinese patent, application number: 201410578503.7；Applicant's Dieffenbacher mechanical equipment service (Beijing) has Limit company；Denomination of invention: a kind of oriented structure chipboard production method and system；Abstract: the invention discloses a kind of orientation knots Structure wood shavings plate producing process, comprising the following steps: S10, by plywood production when the broken veneer strip veneer longitudinal shear that generates Machine carries out length slice；S15, width slice is carried out to broken veneer strip using veneer cross cut shears；S20, pass through primary screening Obtain the wood shavings of qualified size；S30, pass through the dry wood shavings of drying machine；S35, surface layer wood shavings and core are sub-elected by postsearch screening Layer wood shavings；S40, surface layer wood shavings and sandwich layer wood shavings are glued respectively；S45, by oriented paving machine to the wood shavings for having applied glue It is oriented and mats formation；S50, hot pressing is carried out using hot press to the slab laid；S55, by the oriented structure wood shavings after hot pressing Plate cuts into specification.The present invention can produce high-intensitive oriented structure chipboard using broken veneer strip, improve timber Comprehensive utilization ratio.The invention also discloses a kind of oriented structure chipboard production systems.

3, Chinese patent, application number: 201110084640.1；Applicant: Luli Group Co., Ltd；Denomination of invention: one Kind oriented wood chipboard and preparation process；Abstract: the invention discloses a kind of oriented wood chipboard and preparation process, the particieboard For the three-decker by adhesive bond together, including upper and lower two surface layers and an intermediate sandwich layer；The preparation work Skill is using rotary cut venner leftover bits and pieces remaining during plywood production as raw material, instead of path dimension stock, to save a large amount of Timber, reduced production cost；Meanwhile the length of oriented shaving can be lengthened by this method, to improve oriented shaving In plate mechanical performance index, make it have stronger bearing capacity；The present invention has the advantages that with rotary cut venner leftover bits and pieces For raw material, so that a large amount of timber has been saved, reduced production cost, the static bending strength and elasticity of oriented wood chipboard produced Modulus is synchronous to be increased, and bearing capacity substantially improves.

Oriented wood chipboard disclosed in above-mentioned document is disclosed is got a foothold using rotary cut venner remaining during plywood production The broken veneer strip that material generates when being raw material or plywood production is the method that raw material is pressed into oriented wood chipboard, but is had no The corner timber of fast-growing eucalyptus production process of plate is used to produce the report of full Eucalyptus leftover pieces oriented wood chipboard for raw material, and not See that production has the oriented wood chipboard of high temperature resistant function.Because existing oriented wood chipboard encounters high temperature and often becomes currently on the market Shape, encounters high-strength ultraviolet irradiation or the irradiation of long-time ultraviolet light is often cracked, and makes troubles to people's lives production, and Cause economic loss.

Summary of the invention

For above-mentioned technological deficiency, fast-growing eucalyptus plate production process is used the object of the present invention is to provide a kind of Corner timber be raw material production have high temperature resistant function full Eucalyptus leftover pieces oriented wood chipboard method.

The technical solution adopted by the invention is as follows:

The method of full Eucalyptus leftover pieces production high temperature resistant oriented wood chipboard, includes the following steps:

1) by the leftover pieces for producing Eucalyptus plate through first separation metal and stone, chip, wood chip is sent to after simple screening deposits It puts storehouse and carries out transition storage, be then sent to veneer longitudinal shear machine with transporter and carry out length slice, by above-mentioned leftover pieces along vertical It is 50-80 millimeters of wood shavings to length is cut into；Wood shavings after length is sliced are transported to veneer cross cut shears to carry out Wood shavings are transversely cut into the wood shavings that width is 5-20 millimeters by width slice；Again through transporter be sent in wet wood shavings feed bin into Row transition storage；The water content percent by weight of wet wood shavings should be maintained at 20% or less；

The leftover pieces of above-described production Eucalyptus plate are cannot benefit during making more Eucalyptus laminates after rotary-cut Eucalyptus plate Waste material.

2) wet wood shavings are sent in roller drier through transporter is dried, and the moisture content for controlling wood shavings is 3.0%- 5.0%；

3) wood shavings after drying are isolated into wood skin；Second of separation metal and sandstone；

The method of the separation wood skin uses winnowing machine, and wood skin is blown off since specific gravity is smaller in winnowing machine, wood Skin can be used as the fuel of hot-blast stove；It separates metal and sandstone uses gravity screening machine.

4) pass through screening and sorting, watch core of the length in 50-80 millimeters and width at 5-20 millimeters by dry wood shavings The dry wood shavings of layer are sent to the dry wood shavings material transitional storehouse of watch core layer by transporter and store, and length is more than 80 millimeters and width is more than 20 millimeters Wood shavings are sent to the dry wood shavings material transitional storehouse storage of watch core layer after shearing again；

5) the qualified dry wood shavings of watch core layer are transported through transporter, are sent in glue mixer, are used after the metering of chip metering feed bin Mechanical glue mixing is respectively glued surface layer and sandwich layer, and surface layer applies isocyanates wood powder end composite adhesive, resin added It is 4%~8%, for resin added on the basis of mass ratio of the over dry glue to over dry wood shavings, sandwich layer applies high temperature resistant composite urea formaldehyde resin glue Glutinous agent, applied amount are 3%~6%, and applied amount is on the basis of mass ratio of the over dry glue to over dry wood shavings；

6) wood shavings after being glued, which are sent through belt conveyer to mechanical classification spreading machine, mats formation surface layer wood shavings and sandwich layer wood shavings, table Layer wood shavings are longitudinally mated formation, and center core layer wood shavings are divided into 3-tier architecture, including sandwich layer middle layer, sandwich layer upper epidermis and sandwich layer layer, Mat formation core material when, sandwich layer middle layer be it is longitudinal mat formation, the upper and lower surface layer of sandwich layer is mated formation sandwich layer wood shavings, laterally to mat formation, The upper and lower surfaces of sandwich layer are mated formation surface layer wood shavings, are obtained the particle mat of uniform ground, are determined particieboard according to hot press size Slab size specification；

7) particle mat is subjected to precompressed, the pressure of precompressed is 0.8~0.9MPa, 5~8min of time；Finally carry out Hot pressing, 2.5~3MPa of hot pressing pressure, temperature are 200~210 DEG C, and hot pressing time is every millimeter of plate thickness 80s~85s, is then sent It is quenched into balance library, particieboard substrate is made；

8) the particieboard substrate of step 7) is subjected to coarse sand sanding, sand falls 0.8-1.5 millimeters；Then by the wood shavings after coarse sand Plate substrate carries out fine sand sanding, and sand falls 0.5-0.8 millimeters, obtains sanding substrate；Toward sanding substrate coating isocyanates wood powder end Composite adhesive pastes the poplar decoration panel of 8mm thickness, obtains poplar skin thick china, is that 13-15 MPa carries out cold pressing 2 in cold pressing pressure After a hour, hot-forming, hot pressing pressure 15-20MPa is carried out using hot pressing pressure machine, temperature is 110-120 DEG C, last fine sand Side is sawed in polishing, and sorting is packaged, and obtains high temperature resistant oriented wood chipboard.

Above-mentioned steps 5) and step 8) described in isocyanates wood powder end composite adhesive, be with isocyanates for this Body will be added to isocyanic acid by the wood powder end of processing according to the 10-20% that wood powder end additive amount is isocyanate weight In ester, after mixing evenly, uniform isocyanates wood powder end composite adhesive is formed.

The process at the wood powder end are as follows: by length in wood chip shear history less than 50 millimeters and width less than 5 The wood shavings of millimeter are ground into wood powder end, and controlling its partial size is 0.1-3 microns, and wood powder end drying to moisture content is less than 3% or less.

High temperature resistant composite urea formaldehyde resin adhesive described in step 5), is made of the raw material of following parts by weight:

50~100 parts of cyanurotriamide modified urea resin；

20~30 parts of oxidized starch；

1~3 part of polyvinyl alcohol；

3~8 parts of hydrogenated rosin；

2~3 parts of propanediol polyoxypropylene polyvinylether；

4~6 parts of polyisocyanate；

0.5~5 part of isobutyl triethoxy silane；

5~10 parts of phenolate lignin；

100~200 parts of clear water；

2~5 parts of high temperature resistant filler.

The high temperature resistant filler is one of flake asbestos, mica powder and titanium dioxide powder or combinations thereof object.

The clear water of parts by weight: being first put into reaction kettle by the production method of above-mentioned high temperature resistant composite urea formaldehyde resin, heating To 80-100 DEG C, hydrogenated rosin, isobutyl triethoxy silane and the poly- second of propanediol polyoxypropylene of parts by weight is then added Alkene ether stirs 10 minutes to 30 minutes, adds polyvinyl alcohol, the phenolate lignin of parts by weight, be allowed to dissolve, and adds weight Cyanurotriamide modified urea resin, oxidized starch and the high temperature resistant filler of number are measured, is kept for 80-90 DEG C and is stirred to react 2-5 hours, In the polyisocyanate using first 10-20 minutes addition parts by weight, being mixed evenly be can be used.

Cyanurotriamide modified urea resin of the present invention is studied using Guangxi Nanning Green Park Beilin Wood Industry Co., Ltd. Cyanurotriamide modified urea resin, number of patent application: CN 201310353442.X；The applying date: 2013.08.14；It is open (public Accuse) number: CN 103408711A；Apply for (patent right) people: Guangxi Nanning Green Park Beilin Wood Industry Co., Ltd., the melamine change Property Lauxite primary raw material be formaldehyde, melamine and urea, using formaldehyde is added at one time, several times be added urea and The method of melamine controls reaction rate, avoids the generation of gelatin phenomenon, promote the complete reaction of formaldehyde.Urine is repeatedly added Element, the polymerization rate and condition of the urea and formaldehyde that are added every time are all different, after can be divided into prepolymerization, polymerization and polymerization Phase three phases, the amount that urea is added in each stage is different, and reaction temperature is also different, by this technique, avoids The generation of polymerization process gelatin phenomenon, resulting Lauxite narrow molecular weight distribution, residual formaldehyde is low, artificial for producing Plate can reduce the burst size of methanal of wood-based plate.

Above-described high temperature resistant composite urea formaldehyde resin adhesive, the function of each raw material are as follows:

Cyanurotriamide modified urea resin is adhesive major ingredient.Urea-formaldehyde resin adhesive is a kind of thermosetting polymer glue Stick.The advantages that due to its simple process, raw material is cheap, and adhesive strength is high, colorless and transparent is widely used in glued board, plane The industries such as card, medium density fibre board (MDF), the production of artificial board and interior decoration can be bought in Market of Adhesives.Band The melamine of shape molecule is introduced into Lauxite, is formed tridimensional network, is enclosed many hydrophilic radicals, change resin Skeleton structure promotes resin crosslinking, thus achieved the purpose that the adhesion strength, water resistance and the ageing resistance that improve resin, The shortcomings that in turn avoiding simple melamine resin higher cost simultaneously.

Oxidized starch is that starch acts in acid, alkali, neutral medium with oxidant, makes a kind of change obtained from starch oxidation Property starch.Oxidized starch product colour is pure white, pastes transparent, good film-forming property, freeze-thaw resistance is good, is the thickening of low viscosity high concentration Agent is widely used in weaving, papermaking, food and Fine Chemical.Oxidized starch has more aldehyde radical and carboxyl, can be multiple During closing Lauxite polymer reaction, acetal and hemiacetal structure are generated, to improve the ageing-resistant performance of Lauxite； Simultaneous oxidation starch can reduce free formaldehyde content in conjunction with the free formaldehyde in cyanurotriamide modified urea resin；Oxidation On the other hand starch, and can be used as sticky complexing agent, can reduce cyanurotriamide modified urea resin additional amount, reduce production Cost.

Polyvinyl alcohol is toughener, so that the oriented wood chipboard intensity produced increases.

Hydrogenated rosin is antioxidant, so that the oriented wood chipboard produced does not allow perishable, the extension service life, is prevented old Change.

Propanediol polyoxypropylene polyvinylether is defoaming agent, prevents having the generation of bubble cavity in adhesive use process.

Polyisocyanate is curing agent, its main feature is that having very high wearability, and chemical property is stablized, intensity is high, The performance of the heat-resisting of adhesive, water, plasticizer and solvent can be improved in the crosslinked action itself having.

Bridging agent selects isobutyl triethoxy silane, and one end can be in conjunction with Lauxite carbonyl, and the other end can be with The hydroxy combining of starch enhances its plank intensity.

Lignin molecular mass after phenolate is reacted reduces, and increases reaction active groups, can eliminate part free formaldehyde. Phenolate lignin the preparation method comprises the following steps: will be placed in separation vessel using the black liquid of alkaline boiling method slurrying, removed with sieve Undissolved suspended matter settles 4 hours after stirring, discharges lower layer's silt, takes black liquor vacuum drying of the upper layer containing alkali lignin Machine carries out vacuum spray drying processing, obtains powdery alkali lignin；It takes powdery alkali lignin to be put into acidifier, is added 70wt% sulfuric acid is warming up to 140-160 DEG C, sulfonating reaction 1-2 hours after mixing evenly；It is evaporated by standard vertical-tubes Device, circulation rate 0.4m/s-0.5m/s, control discharging moisture content is 30wt%, and precipitating is filtered, dried to water content For 15wt%；By lignin: phenol weight ratio be 1:1 be added phenol, control 85-95 DEG C of temperature, insulation reaction 1 hour, Finally pH to 6.5-7.0 is adjusted up to phenolate lignin with 30wt% sodium hydroxide.

The preparation of the oxidized starch:

(1), it selects glass apparatus and assembles synthesizer:

JJ600 electronic balance；Digital display thermostat water bath；Digital display constant speed stirrer；Three-necked flask；Electric heating constant temperature forced air drying Case；NDJ-79 Rotary Viscosimeter.

(2) reagent chemicals:

Raw material: tapioca (moisture 13.8%)；

Reagent: hydrogen peroxide (30%), Kocide SD, copper sulphate, sodium hydrogensulfite (being AR).

(3) preparation principle:

Starch is under oxidant effect, and the hydroxyl on glucose unit is oxidable at carboxyl (- COOH), it makes to bond The stability of agent be improved significantly.Oxidation reduces the quantity of hydroxyl in starch molecule, and molecular association is made to be obstructed, from And reduce the binding ability of intermolecular hydrogen chain.Meanwhile glucosides chain break, making macromolecules degradation, starch molecule amount reduces, from And increase dissolubility, mobility and caking property.In the presence of liquid alkaline, with hydroxy combining not oxidized in starch, portion is destroyed Divide hydrogen bond, make declines between macromolecular, thus be easy swelling gelatinization, assigns its caking property.

Preparation step is as follows:

200g tapioca is weighed in 1000mL three-necked flask, water is added to be tuned into the starch milk of 18~21 ° of B é, stirring is equal It is even, the sodium hydroxide solution of a certain amount of 5%~7% concentration is slowly added dropwise.After water-bath rises to set temperature, 0.01% sulfuric acid is added Copper.Then a certain amount of hydrogen peroxide is added, after a certain period of time, 0.4g sodium hydrogensulfite is added in isothermal reaction, and stirring 10min is terminated Reaction.It after reaction, is 5.5~6.0 with dilute hydrochloric acid neutralization reaction liquid pH value.Dehydration is filtered, washes clean is placed in baking oven It is dried at 40-50 DEG C, crushes, sieves up to product.The above-mentioned oxidized starch used can be produced with the reactor of large capacity.

Compared with prior art, the positive effect of the present invention is:

1, using rotary-cut Eucalyptus plate multilayer Eucalyptus plate during unavailable waste material --- i.e. Eucalyptus leftover pieces heat Pressure production oriented wood chipboard is peeled into plate since Eucalyptus is a kind of fast growing wood after felling, it is dry after again with adhesive by plate It is bonded into this multi-layer board and is also referred to as solid wood board, can be used as a variety of of good office appliance, timber floor, furniture and building-supporting plate Purposes, but multiple-plate production process generates largely either in cutting, rotary-cut or adhesion process, can all generate many broken Material, these multi-layer board factories, particle can only be burnt up as fuel, cause the great wasting of resources, present invention effective use Waste material in Eucalyptus material process, forms the zero-emission of timber waste, and cost of material reduces by 55% or so, both saved Resource, and environment is protected, it is a kind of very high Resource comprehensive utilization method of benefit in today that wood raw material increasingly lacks, And manufacturing procedure is simple, reasonable, processing cost is low, and energy consumption reduces at least 15%, and cost of labor reduces at least 10%, processing quality Height is suitable for industrialized production.

2, for eucalyptus bark problem, we remove bark using using winnowing machine, enhance product performance.

3, the present invention adds isocyanide using surface layer for save the cost (isocyanates is no aldehyde adhesive, and cost is high) Acid esters wood powder end adhesive, the method that sandwich layer uses fire-retardant composite urea formaldehyde resin adhesive,

4, in the present invention, isocyanates gluing agent is dispersed in wood powder end, utilizes the porous of wood powder end surface Carbimide gluing agent is adsorbed onto tiny wood powder end, forms uniform isocyanates wood powder end compound adhesive by structure Glutinous agent, reduces the permeability of isocyanates gluing agent.

5, it in the present invention, is used according to the characteristic of Eucalyptus plate (leftover pieces that the raw material of oriented wood chipboard is Eucalyptus) production Cyanurotriamide modified urea resin has simple process as adhesive major ingredient, and raw material is cheap, and adhesive strength is high, colorless and transparent The advantages that, and low formaldehyde gas discharges, and is a kind of environmental type resin, the water resistance of Lauxite can be improved, and prevent Glue-line, which is shunk, reduces internal stress, improves ageing-resistant performance, increases glue solid content, viscosity and tack, extends working life.And it uses Hydrogenated rosin is antioxidant, so that the oriented wood chipboard produced does not allow perishable, extension service life, anti-aging；Using poly- Vinyl alcohol is toughener, so that the oriented wood chipboard intensity produced increases；Using propanediol polyoxypropylene polyvinylether, it is Defoaming agent prevents having the generation of bubble cavity in adhesive use process；Use polyisocyanate for curing agent；Select isobutyl group three Ethoxysilane is as bridging agent, and one end can be in conjunction with Lauxite carbonyl, and the other end can enhance with the hydroxy combining of starch Its plank intensity；Part free formaldehyde can be eliminated as formaldehyde catching agent containing a large amount of active groups in phenolate lignin； Cyanurotriamide modified urea resin additional amount can be reduced as sticky complexing agent using oxidized starch, save cost；Asbestos One of powder, mica powder and titanium dioxide powder or combinations thereof object, as high temperature resistant filler of the invention, organic-inorganic high temperature resistant Raw material combines, so that heat-resisting effect is more preferably.

6, the oriented wood chipboard being prepared by the method for the invention, residual formaldehyde amount is low, and flame retardant property is good, intensity/hard Degree is 3-5 times of conventional panels, and automobile is all pressed constantly, and bearing is good, and indeformable, Hepplewhite durability is good, processing performance It is good, it can saw, can dig, can bore, can follow closely, engraving milling, fluting, engraving, being suitable for timber structure room, decorations, furniture floor, load-bearing knot Structure material automobile, container floor etc..

7, the oriented wood chipboard being prepared by the method for the invention, with 2440 × 1220 × 15(mm of product specification), it holds Support plate material measures under the conditions of drying regime, and burst size of methanal is 0.114~0.116 mg/ m³, the quiet Qu Qiang of parallel direction Degree is 31~40 MPa, and parallel flexible modulus is 4605~4776 MPa；Vertical spring modulus is 1501~1770MPa, 24 h Thickness swelling rate is 10%~18%, has excellent water resistance, and vertical nail-holding ability is up to 89009N, dimensional stability and Good reliability, its every mechanical property and expansion character and burst size of methanal are superior to standard known to above-mentioned data.Also, The oriented wood chipboard that the method for the present invention is prepared also has excellent heat resistance, in high temperature, high-strength ultraviolet irradiation or length The irradiation of time ultraviolet light is lower without obvious cracking situation, reduces economic loss.

Specific embodiment

Embodiment 1

5) the qualified dry wood shavings of watch core layer are transported through transporter, are sent in glue mixer, are used after the metering of chip metering feed bin Mechanical glue mixing is respectively glued surface layer and sandwich layer, and surface layer applies isocyanates wood powder end composite adhesive, resin added It is 4%, for resin added on the basis of mass ratio of the over dry glue to over dry wood shavings, sandwich layer applies high temperature resistant composite urea formaldehyde resin gluing Agent, applied amount 3%, applied amount is on the basis of mass ratio of the over dry glue to over dry wood shavings；

7) particle mat is subjected to precompressed, the pressure of precompressed is 0.8MPa, time 8min；Hot pressing is finally carried out, heat Pressure pressure 2.5MPa, temperature be 210 DEG C, hot pressing time be every millimeter of plate thickness 80s~85s, then send to balance library in it is quenched, Particieboard substrate is made；

8) the particieboard substrate of step 7) is subjected to coarse sand sanding, sand falls 0.8-1.5 millimeters；Then by the wood shavings after coarse sand Plate substrate carries out fine sand sanding, and sand falls 0.5-0.8 millimeters, obtains sanding substrate；Toward sanding substrate coating isocyanates wood powder end Composite adhesive, paste 8mm thickness poplar decoration panel, obtain poplar skin thick china, in cold pressing pressure be 13 MPa carry out be cold-pressed it is 2 small Shi Hou carries out hot-forming, hot pressing pressure 15MPa using hot pressing pressure machine, and temperature is 120 DEG C, and side is sawed in last fine sand polishing, Sorting is packaged, and obtains high temperature resistant oriented wood chipboard.

Above-mentioned steps 5) and step 8) described in isocyanates wood powder end composite adhesive, be with isocyanates for this Body will be added to isocyanates by the wood powder end of processing according to 10% that wood powder end additive amount is isocyanate weight In, after mixing evenly, form uniform isocyanates wood powder end composite adhesive.

50 parts of cyanurotriamide modified urea resin；

20 parts of oxidized starch；

1 part of polyvinyl alcohol；

3 parts of hydrogenated rosin；

2 parts of propanediol polyoxypropylene polyvinylether；

4 parts of polyisocyanate；

0.5 part of isobutyl triethoxy silane；

5 parts of phenolate lignin；

100 parts of clear water；

1 part of flake asbestos；

1 part of mica powder.

The clear water of parts by weight: being first put into reaction kettle by the production method of above-mentioned high temperature resistant composite urea formaldehyde resin, heating To 80 DEG C, hydrogenated rosin, isobutyl triethoxy silane and the propanediol polyoxypropylene polyvinylether of parts by weight is then added, Stirring 30 minutes, adds polyvinyl alcohol, the phenolate lignin of parts by weight, is allowed to dissolve, adds the trimerization of parts by weight Cyanamide modified urea-formaldehyde resin, oxidized starch, flake asbestos and mica powder are kept for 80 DEG C and are stirred to react 5 hours, are using preceding 10-20 The polyisocyanate of parts by weight is added in minute, and being mixed evenly can be used.

Embodiment 2

5) the qualified dry wood shavings of watch core layer are transported through transporter, are sent in glue mixer, are used after the metering of chip metering feed bin Mechanical glue mixing is respectively glued surface layer and sandwich layer, and surface layer applies isocyanates wood powder end composite adhesive, resin added It is 6%, for resin added on the basis of mass ratio of the over dry glue to over dry wood shavings, sandwich layer applies high temperature resistant composite urea formaldehyde resin gluing Agent, applied amount 5%, applied amount is on the basis of mass ratio of the over dry glue to over dry wood shavings；

7) particle mat is subjected to precompressed, the pressure of precompressed is 0.8MPa, time 7min；Hot pressing is finally carried out, heat Pressure pressure 2.8MPa, temperature be 205 DEG C, hot pressing time be every millimeter of plate thickness 80s~85s, then send to balance library in it is quenched, Particieboard substrate is made；

8) the particieboard substrate of step 7) is subjected to coarse sand sanding, sand falls 0.8-1.5 millimeters；Then by the wood shavings after coarse sand Plate substrate carries out fine sand sanding, and sand falls 0.5-0.8 millimeters, obtains sanding substrate；Toward sanding substrate coating isocyanates wood powder end Composite adhesive, paste 8mm thickness poplar decoration panel, obtain poplar skin thick china, in cold pressing pressure be 14MPa carry out be cold-pressed it is 2 small Shi Hou carries out hot-forming, hot pressing pressure 18MPa using hot pressing pressure machine, and temperature is 115 DEG C, and side is sawed in last fine sand polishing, Sorting is packaged, and obtains high temperature resistant oriented wood chipboard.

Above-mentioned steps 5) and step 8) described in isocyanates wood powder end composite adhesive, be with isocyanates for this Body will be added to isocyanates by the wood powder end of processing according to 15% that wood powder end additive amount is isocyanate weight In, after mixing evenly, form uniform isocyanates wood powder end composite adhesive.

80 parts of cyanurotriamide modified urea resin；

25 parts of oxidized starch；

2 parts of polyvinyl alcohol；

5 parts of hydrogenated rosin；

2.5 parts of propanediol polyoxypropylene polyvinylether；

5 parts of polyisocyanate；

3 parts of isobutyl triethoxy silane；

8 parts of phenolate lignin；

150 parts of clear water；

2 parts of mica powder；

2 parts of titanium dioxide powder.

The clear water of parts by weight: being first put into reaction kettle by the production method of above-mentioned high temperature resistant composite urea formaldehyde resin, heating To 90 DEG C, hydrogenated rosin, isobutyl triethoxy silane and the propanediol polyoxypropylene polyvinylether of parts by weight is then added, Stirring 20 minutes, adds polyvinyl alcohol, the phenolate lignin of parts by weight, is allowed to dissolve, adds the trimerization of parts by weight Cyanamide modified urea-formaldehyde resin, oxidized starch, mica powder and titanium dioxide powder are kept for 85 DEG C and are stirred to react 3 hours, before use The polyisocyanate of parts by weight is added within 10-20 minutes, being mixed evenly can be used.

Embodiment 3

5) the qualified dry wood shavings of watch core layer are transported through transporter, are sent in glue mixer, are used after the metering of chip metering feed bin Mechanical glue mixing is respectively glued surface layer and sandwich layer, and surface layer applies isocyanates wood powder end composite adhesive, resin added It is 8%, for resin added on the basis of mass ratio of the over dry glue to over dry wood shavings, sandwich layer applies high temperature resistant composite urea formaldehyde resin gluing Agent, applied amount 6%, applied amount is on the basis of mass ratio of the over dry glue to over dry wood shavings；

7) particle mat is subjected to precompressed, the pressure of precompressed is 0.9MPa, time 5min；Hot pressing is finally carried out, heat Pressure pressure 3MPa, temperature are 210 DEG C, and hot pressing time is every millimeter of plate thickness 80s~85s, then send, system quenched into balance library Obtain particieboard substrate；

8) the particieboard substrate of step 7) is subjected to coarse sand sanding, sand falls 0.8-1.5 millimeters；Then by the wood shavings after coarse sand Plate substrate carries out fine sand sanding, and sand falls 0.5-0.8 millimeters, obtains sanding substrate；Toward sanding substrate coating isocyanates wood powder end Composite adhesive, paste 8mm thickness poplar decoration panel, obtain poplar skin thick china, in cold pressing pressure be 15 MPa carry out be cold-pressed it is 2 small Shi Hou carries out hot-forming, hot pressing pressure 20MPa using hot pressing pressure machine, and temperature is 120 DEG C, and side is sawed in last fine sand polishing, Sorting is packaged, and obtains high temperature resistant oriented wood chipboard.

Above-mentioned steps 5) and step 8) described in isocyanates wood powder end composite adhesive, be with isocyanates for this Body will be added to isocyanates by the wood powder end of processing according to 20% that wood powder end additive amount is isocyanate weight In, after mixing evenly, form uniform isocyanates wood powder end composite adhesive.

100 parts of cyanurotriamide modified urea resin；

30 parts of oxidized starch；

3 parts of polyvinyl alcohol；

8 parts of hydrogenated rosin；

3 parts of propanediol polyoxypropylene polyvinylether；

6 parts of polyisocyanate；

5 parts of isobutyl triethoxy silane；

10 parts of phenolate lignin；

200 parts of clear water；

5 parts of titanium dioxide powder.

The clear water of parts by weight: being first put into reaction kettle by the production method of above-mentioned high temperature resistant composite urea formaldehyde resin, heating To 100 DEG C, hydrogenated rosin, isobutyl triethoxy silane and the propanediol polyoxypropylene polyethylene of parts by weight is then added Ether stirs 10 minutes, adds polyvinyl alcohol, the phenolate lignin of parts by weight, be allowed to dissolve, add the three of parts by weight Poly cyanamid modified urea-formaldehyde resin, oxidized starch and titanium dioxide powder are kept for 90 DEG C and are stirred to react 2 hours, are using preceding 10-20 points The polyisocyanate of parts by weight is added in clock, and being mixed evenly can be used.

Comparative example 3

The method of full Eucalyptus leftover pieces production oriented wood chipboard, includes the following steps:

5) the qualified dry wood shavings of watch core layer are transported through transporter, are sent in glue mixer, are used after the metering of chip metering feed bin Mechanical glue mixing is respectively glued surface layer and sandwich layer, and surface layer applies isocyanates wood powder end composite adhesive, resin added It is 8%, on the basis of mass ratio of the over dry glue to over dry wood shavings, sandwich layer applies urea-formaldehyde resin adhesive and (is purchased from Zibo resin added Hua Sen adhesive Co., Ltd), applied amount 6%, applied amount is on the basis of mass ratio of the over dry glue to over dry wood shavings；

8) the particieboard substrate of step 7) is subjected to coarse sand sanding, sand falls 0.8-1.5 millimeters；Then by the wood shavings after coarse sand Plate substrate carries out fine sand sanding, and sand falls 0.5-0.8 millimeters, obtains sanding substrate；Toward sanding substrate coating isocyanates wood powder end Composite adhesive, paste 8mm thickness poplar decoration panel, obtain poplar skin thick china, in cold pressing pressure be 15 MPa carry out be cold-pressed it is 2 small Shi Hou carries out hot-forming, hot pressing pressure 20MPa using hot pressing pressure machine, and temperature is 120 DEG C, and side is sawed in last fine sand polishing, Sorting is packaged, and obtains oriented wood chipboard.

According to LY/T1580-2000 " oriented wood chipboard " to embodiment and comparison implement in products obtained therefrom (drying regime Under the conditions of carry plate) related mechanical property be measured, the product specification of embodiment and comparative example is 2440 × 1220 × 15(mm), the measurement of burst size of methanal is according to 1m³Climate box method is provided to carry out by GB 18580；Test specimen is from constant temperature and humidity After case takes out, vertically it is placed in the water that temperature is 20 DEG C ± 2 DEG C immediately and impregnates ± 1 h of 72h, then test specimen is at -12 DEG C to -20 DEG C ± 0.25h for 24 hours is freezed in refrigerator, dry ± 1 h of 72h is put into the drying box of temperature 70 C ± 1 DEG C after frost, after three circulations Carry out the measurement of static bending strength；Elasticity modulus is measured according to the regulation of GB/T 17657；It is measured according to the regulation of GB/T 17657 Vertical nail-holding ability；24 h thickness swelling rates are measured according to the regulation of GB/T 17657, under 300 DEG C of test temperatures, observation The deformation and cracking situation of oriented wood chipboard.Three times, data are averaged each product testing, every testing result such as following table It is shown:

By the data of above-described embodiment 1-3 it is found that the oriented wood chipboard being prepared by the method for the invention, is advised with product 2440 × 1220 × 15(mm of lattice), plate is carried, is measured under the conditions of drying regime, burst size of methanal is 0.114~0.116 mg/ m³, the static bending strength of parallel direction is 31~40 MPa, and parallel flexible modulus is 4605~4776 MPa；It is vertical spring Modulus is 1501~1770MPa, and 24 h thickness swelling rates are 10%~18%, has excellent water resistance, vertically holds nail Power is up to 89009N, dimensional stability and good reliability, by its mechanical property every known to above-mentioned data and expansion character and Burst size of methanal is superior to standard.

By the data of comparative example 3 it is found that 0.345 mg/ m of its burst size of methanal³The significantly larger than peak of standard 0.124 mg/ m³, static bending strength, 24 h thickness swelling rates, elasticity modulus (parallel), elasticity modulus (vertical) and vertical This several mechanical properties of nail-holding ability and standard difference are little, but under 300 DEG C of test temperatures, oriented wood chipboard serious cracking, Deformation is big, and high temperature resistant is out of condition.

Therefore, by finding out in upper table, during producing high temperature resistant oriented wood chipboard by means of the present invention, this hair Bright high temperature resistant composite urea formaldehyde resin and isocyanates wood powder end composite adhesive production high temperature resistant oriented wood chipboard relative to Common urea-formaldehyde resin adhesive and the oriented wood chipboard of isocyanates wood powder end composite adhesive preparation have the advantages that protrusion, Be mainly manifested in: the high temperature resistant oriented wood chipboard of method production of the invention has stable structure, is unlikely to deform, water resistance is excellent It is different, the characteristics of stability and good reliability；There are also excellent high temperature resistances, have preferable application and popularization value.

Claims

1. the method for full Eucalyptus leftover pieces production high temperature resistant oriented wood chipboard, characterized by the following steps:

1) by the leftover pieces for producing Eucalyptus plate through first separation metal and stone, chip, be sent to wood chip storage compartment after simple screening Transition storage is carried out, then veneer longitudinal shear machine is sent to transporter and carries out length slice, above-mentioned leftover pieces are cut along longitudinal direction The wood shavings for being 50-80 millimeters at length；Wood shavings after length is sliced are transported to veneer cross cut shears and carry out width Wood shavings are transversely cut into the wood shavings that width is 5-20 millimeters by slice；It is sent in wet wood shavings feed bin and carried out through transporter again Cross storage；The water content percent by weight of wet wood shavings should be maintained at 20% or less；

It is above-described production Eucalyptus plate leftover pieces refer to rotary-cut Eucalyptus prepare it is multiple-plate during generate cannot be abundant The wood waste utilized；

2) wet wood shavings are sent in roller drier through transporter is dried, and the moisture content for controlling wood shavings is 3.0%-5.0%；

The method of the separation wood skin uses winnowing machine, and wood skin is blown off since specific gravity is smaller in winnowing machine, and wood skin can Using the fuel as hot-blast stove；It separates metal and sandstone uses gravity screening machine；

4) by dry wood shavings by screening and sorting, length is dry in 5-20 millimeters of watch core layer in 50-80 millimeters and width Wood shavings are sent to the dry wood shavings material transitional storehouse of watch core layer by transporter and store, and length is more than 80 millimeters and width is more than 20 millimeters of wood shavings The dry wood shavings material transitional storehouse storage of watch core layer is sent to after shearing again；

5) the qualified dry wood shavings of watch core layer are transported through transporter, are sent in glue mixer after the metering of chip metering feed bin, using machinery Formula glue mixing is respectively glued surface layer and sandwich layer, and surface layer applies isocyanates wood powder end composite adhesive, resin added 4% ~8%, for resin added on the basis of mass ratio of the over dry glue to over dry wood shavings, sandwich layer applies high temperature resistant composite urea formaldehyde resin adhesive, Applied amount is 3%~6%, and applied amount is on the basis of mass ratio of the over dry glue to over dry wood shavings；

The high temperature resistant composite urea formaldehyde resin adhesive, is made of: melamine modified urea-formaldehyde the raw material of following parts by weight 50~100 parts of resin；20~30 parts of oxidized starch；1~3 part of polyvinyl alcohol；3~8 parts of hydrogenated rosin；Propanediol polyoxypropylene 2~3 parts of polyvinylether；4~6 parts of polyisocyanate；0.5~5 part of isobutyl triethoxy silane；5~10 parts of phenolate lignin； 100~200 parts of clear water；2~5 parts of high temperature resistant filler.

6) wood shavings after being glued, which are sent through belt conveyer to mechanical classification spreading machine, mats formation surface layer wood shavings and sandwich layer wood shavings, surface layer plane Longitudinal direction is spent to mat formation, center core layer wood shavings are divided into 3-tier architecture, including sandwich layer middle layer, sandwich layer upper epidermis and sandwich layer layer, mat formation When core material, sandwich layer middle layer be it is longitudinal mat formation, the upper and lower surface layer of sandwich layer is mated formation sandwich layer wood shavings, laterally to mat formation, sandwich layer Upper and lower surfaces mat formation surface layer wood shavings, obtain the particle mat of uniform ground, particle mat determined according to hot press size Size specification；

7) particle mat is subjected to precompressed, the pressure of precompressed is 0.8~0.9MPa, 5~8min of time；Finally carry out heat Pressure, 2.5~3MPa of hot pressing pressure, temperature be 200~210 DEG C, hot pressing time be every millimeter of plate thickness 80s~85s, then send to Balance quenched in library, obtained particieboard substrate；

8) the particieboard substrate of step 7) is subjected to coarse sand sanding, sand falls 0.8-1.5 millimeters；Then by the particieboard base after coarse sand Plate carries out fine sand sanding, and sand falls 0.5-0.8 millimeters, obtains sanding substrate；It is compound toward sanding substrate coating isocyanates wood powder end Adhesive, paste 8mm thickness poplar decoration panel, obtain poplar skin thick china, in cold pressing pressure be 13-15 MPa carry out be cold-pressed it is 2 small Shi Hou carries out hot-forming, hot pressing pressure 15-20MPa using hot pressing pressure machine, and temperature is 110-120 DEG C, and last fine sand is thrown Light saws side, and sorting is packaged, and obtains high temperature resistant oriented wood chipboard；

Isocyanates wood powder end composite adhesive described in step 5) and step 8), is using isocyanates as ontology, according to wood Bran powder additive amount is that the 10-20% of isocyanate weight will be added in isocyanates by the wood powder end of processing, is stirred After uniformly, uniform isocyanates wood powder end composite adhesive is formed；The process at the wood powder end are as follows: by wood chip Length is less than 50 millimeters in shear history and wood shavings of the width less than 5 millimeters are ground into wood powder end, and controlling its partial size is 0.1-3 Micron, and wood powder end is dried to moisture content less than 3% or less.

2. the method for full Eucalyptus leftover pieces production high temperature resistant oriented wood chipboard according to claim 1, it is characterised in that: institute The high temperature resistant filler stated is one of flake asbestos, mica powder and titanium dioxide powder or combinations thereof object.

3. the method for full Eucalyptus leftover pieces production high temperature resistant oriented wood chipboard according to claim 1, it is characterised in that: on It states the production method of high temperature resistant composite urea formaldehyde resin: first the clear water of parts by weight being put into reaction kettle, is heated to 80-100 DEG C, Then hydrogenated rosin, isobutyl triethoxy silane and the propanediol polyoxypropylene polyvinylether of parts by weight, stirring 10 is added Minute to 30 minutes, adds polyvinyl alcohol, the phenolate lignin of parts by weight, is allowed to dissolve, adds the three of parts by weight Poly cyanamid modified urea-formaldehyde resin, oxidized starch and high temperature resistant agent are kept for 80-90 DEG C and are stirred to react 2-5 hours, are using preceding 10- The polyisocyanate of parts by weight is added within 20 minutes, being mixed evenly can be used.