CN106305752A - Herbicide composition containing halauxifen-methyl and nicosulfuron - Google Patents
Herbicide composition containing halauxifen-methyl and nicosulfuron Download PDFInfo
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- CN106305752A CN106305752A CN201610709035.1A CN201610709035A CN106305752A CN 106305752 A CN106305752 A CN 106305752A CN 201610709035 A CN201610709035 A CN 201610709035A CN 106305752 A CN106305752 A CN 106305752A
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- Prior art keywords
- oil
- herbicidal composition
- oleum
- nicosulfuron
- agent
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- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N47/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid
- A01N47/08—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid the carbon atom having one or more single bonds to nitrogen atoms
- A01N47/28—Ureas or thioureas containing the groups >N—CO—N< or >N—CS—N<
- A01N47/36—Ureas or thioureas containing the groups >N—CO—N< or >N—CS—N< containing the group >N—CO—N< directly attached to at least one heterocyclic ring; Thio analogues thereof
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/34—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one nitrogen atom as the only ring hetero atom
- A01N43/40—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one nitrogen atom as the only ring hetero atom six-membered rings
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/64—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with three nitrogen atoms as the only ring hetero atoms
- A01N43/647—Triazoles; Hydrogenated triazoles
- A01N43/653—1,2,4-Triazoles; Hydrogenated 1,2,4-triazoles
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- Life Sciences & Earth Sciences (AREA)
- Agronomy & Crop Science (AREA)
- Pest Control & Pesticides (AREA)
- Plant Pathology (AREA)
- Health & Medical Sciences (AREA)
- Engineering & Computer Science (AREA)
- Dentistry (AREA)
- General Health & Medical Sciences (AREA)
- Wood Science & Technology (AREA)
- Zoology (AREA)
- Environmental Sciences (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
Abstract
The invention discloses a herbicide composition containing halauxifen-methyl and nicosulfuron comprising, by weight, 5-15 parts of halauxifen-methyl, 2-9 parts of nicosulfuron, 1-5 parts of flupoxam, 0.5-2 parts of clopyralid and 50-100 parts of auxiliary agent. The invention takes halauxifen-methyl, nicosulfuron, flupoxam, clopyralid and auxiliary agent as the raw materials. The herbicidal activities of the raw materials are not simple superposition, but a significant efficiency increase. The herbicide composition containing halauxifen-methyl and nicosulfuron prepared can expand the control spectrum of weeds and improve the control effect of corn field; in addition, the herbicide composition is safe to crops and meets the safety requirement of pesticide preparings.
Description
Technical field
The present invention relates to corn field herbicide field, particularly relate to a kind of containing fluorine chloropyridine ester and the weeding of nicosulfuron
Agent compositions.
Background technology
Semen Maydis is the cereal crops that China is important, is also important forage crop and the raw material of industry, along with animal husbandry, food
The development of the industries such as product processing, wine-making industry and biodiesel, the market demand of Semen Maydis is continuously increased.The weeds of corn field occur general
Time, of a great variety, when Maize Seedling is by Weed infestation, plant is short and small, and bar spire is yellow, causes middle and late stage corn growth bad, sternly
The heavily underproduction, therefore, the chemical prevention of corn field weed all after broadcasting before Seedling and Seedling after two critical periods of getting up early carry out.At present
Corn field weed management system in, herbicide still plays very important effect.But corn field herbicide weed control spectrum at present
Limited, poor to the preventive effect of weeds.
Summary of the invention
In view of this, it is an object of the invention to provide a kind of containing fluorine chloropyridine ester and the combinations of herbicides of nicosulfuron
Thing, it is possible to solve existing corn field herbicide weed control spectrum limited, the technical problem to the prevention effect difference of weeds.
To achieve these goals, the present invention provides following technical scheme:
A kind of containing fluorine chloropyridine ester and the herbicidal composition of nicosulfuron, including the raw material of following parts by weight:
Preferably, described auxiliary agent includes surfactant, diluent, defoamer, antifreezing agent, antisettling agent, preservative
And stabilizer.
Preferably, described surfactant is selected from poly styrene sulfonate, polyoxyethylene alkyl ether, polyoxyethylensorbitan fatty acid
One or more in ester, alkylsulfonate, alkyl biphenyl sulphate, polyoxyethylene hydrogenated Oleum Ricini.
Preferably, described diluent is selected from olive oil, Semen Maydis oil, soybean oil, Oleum Ricini, Fructus Caricae oil, Camellia oil, Cortex cocois radicis
One in oil, Oleum sesami, Semen Maydis oil, Testa oryzae oil, Oleum Arachidis hypogaeae semen, Oleum Gossypii semen, rapeseed oil, Semen Lini oil, Oleum Verniciae fordii, Oleum helianthi or
Multiple.
Preferably, described defoamer includes zeolite powder, waterglass, stearic acid, silicon dioxide and coke.
Preferably, one or more in ethylene glycol, propylene glycol, glycerol of described antifreezing agent.
Preferably, one or more in montmorillonite, rectorite, Silicon stone of described antisettling agent.
Preferably, described preservative is in sodium benzoate, Nepal's tortoise beetle ester, formaldehyde, polyhydroxy benzenes propyl formate
One or more.
Preferably, one or more in epoxychloropropane, organic acid, organic base of described stabilizer.
Preferably, the preparation of described herbicidal composition is cream, aqueous suspension agent, oil-suspending agent, wettable powder, granule
Agent or water dispersible granules.
It is a kind of containing fluorine chloropyridine ester and the herbicidal composition of nicosulfuron, including 5~15 weight that the present invention provides
Part fluorine chloropyridine ester, 2~9 nicosulfuron, 1~5 flupoxam, 0.5~2 dichloro pyrroles of weight portion of weight portion of weight portion
Pyridine acid and the auxiliary agent of 50~100 weight portions.The present invention with fluorine chloropyridine ester, nicosulfuron, flupoxam, clopyralid, help
Agent is raw material, and the activity of weeding of above-mentioned raw materials and effect are more than simple superposition, but show potentiation significantly,
Prepare containing fluorine chloropyridine ester and the herbicidal composition of nicosulfuron, it is possible to expand control of weeds spectrum, improve Semen Maydis
The prevention effect in field;It addition, good to crop safety, meet the security requirement of pesticidal preparations.
Detailed description of the invention
In order to further appreciate that the present invention, below in conjunction with embodiment, the preferred embodiments of the invention are described, but
Should be appreciated that these describe simply as further illustrating the features and advantages of the present invention rather than to patent requirements of the present invention
Limit.
The invention provides a kind of containing fluorine chloropyridine ester and the herbicidal composition of nicosulfuron, including following weight portion
The raw material of number:
The present invention with fluorine chloropyridine ester, nicosulfuron, flupoxam, clopyralid, auxiliary agent as raw material, above-mentioned raw materials
Activity of weeding and effect are more than simple superposition, but show potentiation significantly, prepare containing fluorine chlorine
Pyridine ester and the herbicidal composition of nicosulfuron, it is possible to expand control of weeds spectrum, improve the prevention effect of corn field;It addition,
Good to crop safety, meet the security requirement of pesticidal preparations.
In the present invention, the parts by weight of fluorine chloropyridine ester are 5~15 parts;In an embodiment of the present invention, fluorine chloropyridine
The parts by weight of ester are 8~12 parts.
In the present invention, the parts by weight of nicosulfuron are 2~9 parts;In other embodiments of the invention, nicosulfuron
Parts by weight are 4~7 parts.
In the present invention, the parts by weight of flupoxam are 1~5 part;In an embodiment of the present invention, the weight of flupoxam
Amount number is 2~4 parts.
In the present invention, the parts by weight of clopyralid are 0.5~2 part;In an embodiment of the present invention, dichloropyridine
The parts by weight of acid are 1~1.5 part.
In the present invention, the parts by weight of auxiliary agent are 50~100 parts;In an embodiment of the present invention, the weight portion of auxiliary agent
Number is 65~85 parts.
In an embodiment of the present invention, auxiliary agent include surfactant, diluent, defoamer, antifreezing agent, antisettling agent,
Preservative and stabilizer;In other embodiments of the invention, surfactant, diluent, defoamer, antifreezing agent, anti-settling
The mass ratio of agent, preservative and stabilizer is (1~3): (4~6): (0.1~0.3): (0.05~0.2): (0.1~0.5):
(0.05~0.15): (0.2~0.6).
In an embodiment of the present invention, surfactant is selected from poly styrene sulfonate, polyoxyethylene alkyl ether, sorbose
One or more in alcohol fatty acid ester, alkylsulfonate, polyoxyethylene hydrogenated Oleum Ricini;Other embodiments in the present invention
In, surfactant is selected from kayexalate, alkylpolyoxyethylene, anhydrous sorbitol laurate, dodecane
One or both in base sodium sulfonate, polyoxyethylene hydrogenated Oleum Ricini.
In order to reduce the bubble in herbicide, in an embodiment of the present invention, diluent is selected from olive oil, Semen Maydis oil, big
Oleum Glycines, Oleum Ricini, Fructus Caricae oil, Camellia oil, Oleum Cocois, Oleum sesami, Testa oryzae oil, Oleum Arachidis hypogaeae semen, Oleum Gossypii semen, rapeseed oil, Semen Lini
One or more in oil, Oleum Verniciae fordii, Oleum helianthi;In other embodiments of the invention, diluent is selected from olive oil, Semen Maydis
Oil, soybean oil, Oleum Ricini, Fructus Caricae oil, Camellia oil, Oleum Cocois, Oleum sesami, Testa oryzae oil, Oleum Arachidis hypogaeae semen, Oleum Gossypii semen, rapeseed oil, Asia
One or both in flaxseed oil, Oleum Verniciae fordii, Oleum helianthi.
In order to thoroughly eliminate the bubble in herbicide, in an embodiment of the present invention, defoamer includes zeolite powder, water glass
Glass, stearic acid, silicon dioxide and coke.
In an embodiment of the present invention, the mass ratio of zeolite powder, waterglass, stearic acid, silicon dioxide and coke is (0.5
~1): (0.3~0.7): (5~10): (0.1~0.5): (0.1~0.3).
In an embodiment of the present invention, one or more in ethylene glycol, propylene glycol, glycerol of antifreezing agent;At this
In other bright embodiments, antifreezing agent one in ethylene glycol, propylene glycol, glycerol.
In an embodiment of the present invention, one or more in montmorillonite, rectorite, Silicon stone of antisettling agent;At this
In inventive embodiment, antisettling agent is selected from one or both in montmorillonite, rectorite, Silicon stone.
In an embodiment of the present invention, preservative is selected from sodium benzoate, Nepal's tortoise beetle ester, formaldehyde, polyhydroxy benzenes formic acid
One or more in propyl ester;In other embodiments of the invention, preservative is sodium benzoate, Nepal's tortoise beetle ester, formaldehyde
Or polyhydroxy benzenes propyl formate.
In an embodiment of the present invention, one or more in epoxychloropropane, organic acid, organic base of stabilizer;
In other embodiments of the invention, stabilizer is epoxychloropropane, formic acid, acetic acid, triethylamine or triethylene diamine.
In an embodiment of the present invention, the preparation of herbicidal composition is cream, aqueous suspension agent, oil-suspending agent, wettability
Powder, granule or water dispersible granules.
In order to further illustrate the present invention, below in conjunction with embodiment the present invention is provided phonetic containing fluorine chloropyridine ester and cigarette
The grand herbicidal composition of sulphur is described in detail, but they can not be interpreted as limiting the scope of the present invention.
Raw material used in following example is commercially available.
Embodiment 1
Weigh 5g fluorine chloropyridine ester, 9g nicosulfuron, 5g flupoxam, 1.5g clopyralid, 27.43g polystyrene
Sodium sulfonate, 36.57g olive oil, 0.2g zeolite powder, 0.12g waterglass, 1.96g stearic acid, 0.4g silicon dioxide, 0.04g are burnt
Charcoal, 1.83g ethylene glycol, 4.57g montmorillonite, 1.37g sodium benzoate, 5.49g epoxychloropropane, mix above-mentioned component, pulverizes
Obtain the wettable powder of the corn field herbicide composition of fluorine-containing chloropyridine ester and nicosulfuron.
Embodiment 2
Weigh 8g fluorine chloropyridine ester, 5g nicosulfuron, 4g flupoxam, 1g clopyralid, 23.17g dodecyl gather
Oxygen vinyl Ether, 36.41g Camellia oil, 0.13g zeolite powder, 0.09g waterglass, 1.3g stearic acid, 0.43g silicon dioxide, 0.04g
Coke, 1.49g propylene glycol, 2.48g montmorillonite, 1.16g Nepal tortoise beetle ester, 3.31g triethylamine, mix above-mentioned component, powder
The wettable powder of the broken corn field herbicide composition i.e. obtaining fluorine-containing chloropyridine ester and nicosulfuron.
Embodiment 3
Weigh 10g fluorine chloropyridine ester, 7g nicosulfuron, 3g flupoxam, 0.5g clopyralid, 18.66g dodecyl
Sodium sulfonate, 30.14g rapeseed oil, 0.12g zeolite powder, 0.09g waterglass, 1.22g stearic acid, 0.52g silicon dioxide, 0.05 Jiao
Charcoal, 1.08g glycerol, 1.23g rectorite, 2g Silicon stone, 0.43g formaldehyde, 0.5g sodium benzoate, 3.95g formic acid, mix above-mentioned component
Close, and carry out spray congealing molding and spray drying granulation, obtain fluorine-containing chloropyridine ester and the corn field herbicide of nicosulfuron
The water dispersible granules of compositions.
Embodiment 4
Weigh 12g fluorine chloropyridine ester, 2g nicosulfuron, 2g flupoxam, 2g clopyralid, 8.77g anhydrous sorbitol
Laurate, 10g dodecyl sodium sulfate, 25.2g Semen Lini oil, 10g Oleum Verniciae fordii, 0.12g zeolite powder, 0.09g waterglass,
1.16g stearic acid, 0.58g silicon dioxide, 0.02g coke, 1.1g ethylene glycol, 1.13g montmorillonite, 2g Silicon stone, 0.94g polyhydroxy
Propyl benzoate, 3.91g acetic acid, mix above-mentioned component, pulverizes and i.e. obtains the corn field of fluorine-containing chloropyridine ester and nicosulfuron and remove
The wettable powder of grass agent compositions.
Embodiment 5
Weigh 15g fluorine chloropyridine ester, 4g nicosulfuron, 1g flupoxam, 1.2g clopyralid, 9.33g polystyrene
Sodium sulfonate, 9.33g alkylpolyoxyethylene, 24.78g Semen Maydis oil, 20g soybean oil, 0.12g zeolite powder, 0.09g water glass
Glass, 1.17g stearic acid, 0.65g silicon dioxide, 0.02g coke, 0.12g ethylene glycol, 1g glycerol, 1.26g montmorillonite, the tired torr of 2g
Stone, 0.93g sodium benzoate, 4.2g triethylene diamine, mix above-mentioned component, and carries out spray congealing molding and spray drying is made
Grain, obtains the water dispersible granules of the corn field herbicide composition of fluorine-containing chloropyridine ester and nicosulfuron.
Embodiment 6
Weigh 8g fluorine chloropyridine ester, 5.5g nicosulfuron, 4g flupoxam, 1.4g clopyralid, 9.39g dodecyl
Sodium sulfonate, 10g polyoxyethylene hydrogenated Oleum Ricini, 23.87g Oleum Verniciae fordii, 30g Oleum helianthi, 0.14g zeolite powder, 0.09g waterglass,
1.35g stearic acid, 0.54g silicon dioxide, 0.02g coke, 0.54g ethylene glycol, 0.54g glycerol, 1.23g rectorite, 2g silicon
Stone, 0.97g polyhydroxy benzenes propyl formate, 4.31g epoxychloropropane, mix above-mentioned component, and carry out spray congealing molding and
Spray drying granulation, obtains the water dispersible granules of the corn field herbicide composition of fluorine-containing chloropyridine ester and nicosulfuron.
Embodiment 7
Weigh 9g fluorine chloropyridine ester, 7g nicosulfuron, 5g flupoxam, 1g clopyralid, 8.83g dodecyl polyoxy
Vinyl Ether, 8.83g dodecyl sodium sulfate, 30.6g Oleum Gossypii semen, 30.6g Testa oryzae oil, 0.13g zeolite powder, 0.09g waterglass,
1.3g stearic acid, 0.56g silicon dioxide, 0.04g coke, 0.53g glycerol, 0.53g glycerol, 1.47g montmorillonite, 1.47g tire out
Torr stone, 0.94g formaldehyde, 4.12g triethylamine, mix above-mentioned component, and carry out emulsifying, obtain fluorine-containing chloropyridine ester and the phonetic sulphur of cigarette
The cream of grand corn field herbicide composition.
Embodiment 8
Weigh 10g fluorine chloropyridine ester, 6g nicosulfuron, 1g flupoxam, 1.2g clopyralid ketone, 18.18g dodecane
Base sodium sulfonate, 31.43g Oleum Cocois, 40g olive oil, 0.1g zeolite powder, 0.07g waterglass, 0.99g stearic acid, 0.62g dioxy
SiClx, 0.03g coke, 1.04g ethylene glycol, 1.3g montmorillonite, 1.3g Silicon stone, 0.91g Nepal tortoise beetle ester, 3.9g acetic acid, will
Above-mentioned component mixes, and carries out drying-granulating, obtains the corn field herbicide composition of fluorine-containing chloropyridine ester and nicosulfuron
Granule.
Embodiment 9
Weigh 11g fluorine chloropyridine ester, 5g nicosulfuron, 2g flupoxam, 1.6g clopyralid, 7.85g Sorbitan
Alcohol laurate, 27.96g Oleum sesami, 10g Oleum Arachidis hypogaeae semen, 0.05g zeolite powder, 0.04g waterglass, 0.54g stearic acid, 0.12g bis-
Silicon oxide, 0.02g coke, 0.39g propylene glycol, 0.98g Silicon stone, 0.19g Nepal tortoise beetle ester, 0.2g formaldehyde, 4.09g formic acid,
Above-mentioned component is mixed, stirring, obtain the aqueous suspension agent of the corn field herbicide composition of fluorine-containing chloropyridine ester and nicosulfuron.
Embodiment 10
Weigh 12g fluorine chloropyridine ester, 4g nicosulfuron, 3g flupoxam, 1.3g clopyralid, 11.3g Sorbitan
Alcohol laurate, 34g Fructus Caricae oil, 34g rapeseed oil, 0.08g zeolite powder, 0.07g waterglass, 0.81g stearic acid, 0.13g bis-
Silicon oxide, 0..04g coke, 0.57g glycerol, 1.13g rectorite, 0.27g sodium benzoate, 0.3g polyhydroxy benzenes propyl formate,
4.52g triethylene diamine, mixes above-mentioned component, and carries out drying-granulating, obtains fluorine-containing chloropyridine ester and the jade of nicosulfuron
The granule of rice field herbicidal composition.
Herbicide embodiment 1~10 prepared and commercially available mass ratio are fluorine chloropyridine ester and the phonetic sulphur of cigarette of 1:1
The grand preventing and treating experiment carrying out corn field weed, experiment condition, environment are identical, in Semen Maydis 2~4 phase, weeds 2~5 leaf phase dispenser, medicine
Latter 30 days, the results are shown in Table 1 (wherein, blank is not for using herbicide).
Table 1 Semen Maydis control of weeds experimental result
As shown in Table 1, on the premise of herbicide consumption of the present invention is less than each single dose consumption, the medicine of controlling weeds of the present invention
Effect height, the prevention effect of the corn field herbicide composition of fluorine-containing chloropyridine ester and nicosulfuron is high, it is possible to decrease dosage, reduces
Cost, environmentally friendly.
A kind of herbicidal composition containing fluorine chloropyridine ester and nicosulfuron provided the present invention above has been carried out in detail
Thin introduction, principle and the embodiment of the present invention are set forth by specific case used herein, above example
Method and the core concept thereof being only intended to help to understand the present invention is described, it is noted that for the common skill of the art
For art personnel, under the premise without departing from the principles of the invention, it is also possible to the present invention is carried out some improvement and modification, these change
Enter and modify in the protection domain also falling into the claims in the present invention.
Claims (10)
1. one kind contains fluorine chloropyridine ester and the herbicidal composition of nicosulfuron, it is characterised in that include following parts by weight
Raw material:
2. herbicidal composition as claimed in claim 1, it is characterised in that described auxiliary agent includes surfactant, dilution
Agent, defoamer, antifreezing agent, antisettling agent, preservative and stabilizer.
3. herbicidal composition as claimed in claim 2, it is characterised in that described surfactant is selected from polystyrolsulfon acid
Salt, polyoxyethylene alkyl ether, sorbitan fatty acid ester, alkylsulfonate, alkyl biphenyl sulphate, polyethylene glycol hydrogenated
One or more in Oleum Ricini.
4. herbicidal composition as claimed in claim 2, it is characterised in that described diluent is selected from olive oil, soybean oil, castor
Oleum Sesami, Fructus Caricae oil, Camellia oil, Oleum Cocois, Oleum sesami, Semen Maydis oil, Testa oryzae oil, Oleum Arachidis hypogaeae semen, Oleum Gossypii semen, rapeseed oil, Semen Lini
One or more in oil, Oleum Verniciae fordii, Oleum helianthi.
5. herbicidal composition as claimed in claim 2, it is characterised in that described defoamer include zeolite powder, waterglass,
Stearic acid, silicon dioxide and coke.
6. herbicidal composition as claimed in claim 2, it is characterised in that described antifreezing agent is selected from ethylene glycol, propylene glycol, sweet
One or more in oil.
7. herbicidal composition as claimed in claim 2, it is characterised in that described antisettling agent selected from montmorillonite, rectorite,
One or more in Silicon stone.
8. herbicidal composition as claimed in claim 2, it is characterised in that described preservative is selected from sodium benzoate, Nepal
One or more in tortoise beetle ester, formaldehyde, polyhydroxy benzenes propyl formate.
9. herbicidal composition as claimed in claim 2, it is characterised in that described stabilizer is selected from epoxychloropropane, organic
One or more in acid, organic base.
10. the combinations of herbicides group as described in any one of claim 1~9, it is characterised in that the system of described herbicidal composition
Agent is cream, aqueous suspension agent, oil-suspending agent, wettable powder, granule or water dispersible granules.
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CN201610709035.1A CN106305752A (en) | 2016-08-23 | 2016-08-23 | Herbicide composition containing halauxifen-methyl and nicosulfuron |
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Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP2514313A1 (en) * | 2007-08-27 | 2012-10-24 | Dow AgroSciences LLC | Synergistic herbicidal composition containing certain pyridine or pyrimidine carboxylic acids and certain cereal and rice herbicides |
CN105104375A (en) * | 2015-08-14 | 2015-12-02 | 京博农化科技股份有限公司 | Glycerine-containing herbicidal composition |
CN105813460A (en) * | 2013-12-12 | 2016-07-27 | 美国陶氏益农公司 | Selective weed control with halauxifen |
-
2016
- 2016-08-23 CN CN201610709035.1A patent/CN106305752A/en active Pending
Patent Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP2514313A1 (en) * | 2007-08-27 | 2012-10-24 | Dow AgroSciences LLC | Synergistic herbicidal composition containing certain pyridine or pyrimidine carboxylic acids and certain cereal and rice herbicides |
CN105813460A (en) * | 2013-12-12 | 2016-07-27 | 美国陶氏益农公司 | Selective weed control with halauxifen |
CN105104375A (en) * | 2015-08-14 | 2015-12-02 | 京博农化科技股份有限公司 | Glycerine-containing herbicidal composition |
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