CN106298991A - Silicon chip and preparation method thereof and device - Google Patents

Silicon chip and preparation method thereof and device Download PDF

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Publication number
CN106298991A
CN106298991A CN201610652752.5A CN201610652752A CN106298991A CN 106298991 A CN106298991 A CN 106298991A CN 201610652752 A CN201610652752 A CN 201610652752A CN 106298991 A CN106298991 A CN 106298991A
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Prior art keywords
silicon chip
corundum
gully
diamond wire
guide wheel
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CN201610652752.5A
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CN106298991B (en
Inventor
黄强
金善明
郑雄久
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Wuhu Gcl Integrated New Energy Technology Co ltd
GCL System Integration Technology Co Ltd
GCL System Integration Technology Suzhou Co Ltd
Original Assignee
Suzhou Gcl System Integration Technology Industrial Application Research Institute Co Ltd
Zhangjiagang Xiexin Integrated Technology Co Ltd
GCL System Integration Technology Co Ltd
GCL System Integration Technology Suzhou Co Ltd
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    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01LSEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L31/00Semiconductor devices sensitive to infrared radiation, light, electromagnetic radiation of shorter wavelength or corpuscular radiation and specially adapted either for the conversion of the energy of such radiation into electrical energy or for the control of electrical energy by such radiation; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof
    • H01L31/02Details
    • H01L31/0236Special surface textures
    • H01L31/02363Special surface textures of the semiconductor body itself, e.g. textured active layers
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B24GRINDING; POLISHING
    • B24BMACHINES, DEVICES, OR PROCESSES FOR GRINDING OR POLISHING; DRESSING OR CONDITIONING OF ABRADING SURFACES; FEEDING OF GRINDING, POLISHING, OR LAPPING AGENTS
    • B24B27/00Other grinding machines or devices
    • B24B27/06Grinders for cutting-off
    • B24B27/0633Grinders for cutting-off using a cutting wire
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B24GRINDING; POLISHING
    • B24DTOOLS FOR GRINDING, BUFFING OR SHARPENING
    • B24D99/00Subject matter not provided for in other groups of this subclass
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B28WORKING CEMENT, CLAY, OR STONE
    • B28DWORKING STONE OR STONE-LIKE MATERIALS
    • B28D5/00Fine working of gems, jewels, crystals, e.g. of semiconductor material; apparatus or devices therefor
    • B28D5/04Fine working of gems, jewels, crystals, e.g. of semiconductor material; apparatus or devices therefor by tools other than rotary type, e.g. reciprocating tools
    • B28D5/045Fine working of gems, jewels, crystals, e.g. of semiconductor material; apparatus or devices therefor by tools other than rotary type, e.g. reciprocating tools by cutting with wires or closed-loop blades
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02EREDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E10/00Energy generation through renewable energy sources
    • Y02E10/50Photovoltaic [PV] energy

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  • Engineering & Computer Science (AREA)
  • Mechanical Engineering (AREA)
  • Processing Of Stones Or Stones Resemblance Materials (AREA)
  • Photovoltaic Devices (AREA)
  • Physics & Mathematics (AREA)
  • Condensed Matter Physics & Semiconductors (AREA)
  • Electromagnetism (AREA)
  • General Physics & Mathematics (AREA)
  • Computer Hardware Design (AREA)
  • Microelectronics & Electronic Packaging (AREA)
  • Power Engineering (AREA)

Abstract

The present invention relates to photovoltaic art, specifically disclose a kind of silicon chip, the facet of this silicon chip has the some cut channel patterns arranged in the first direction;Cut channel pattern is connected or interconnection by the bending of some strias.Above-mentioned silicon chip, owing to its cut channel pattern is connected or interconnection by the bending of some strias, after conventional soda acid process for etching, could be formed with the light trapping structure of effect, so that diamond wire cutting technique is compatible with conventional soda acid process for etching.The invention also discloses the preparation method of a kind of above-mentioned silicon chip and a kind of silicon slice wire cutting apparatus.

Description

Silicon chip and preparation method thereof and device
Technical field
The present invention relates to photovoltaic art, particularly relate to a kind of silicon chip and preparation method thereof and device.
Background technology
At present, the cutting of silicon crystal line is typically all and uses the cutting of free abrasive line, i.e. cutting steel wire to carry mortar fortune at a high speed Dynamic, the free abrasive in mortar, under the pressure of cutting steel wire and the drive of speed, is ground type processing to silicon materials, thus Realize silicon crystal cutting.During Gai, cutting steel wire itself be not involved in cutting, due to the free abrasive in mortar and silicon materials Real contact area is less, and therefore relatively low to the clearance of rapidoprint, process time is longer, and production efficiency is low.It addition, cutting After silicon chip surface damage relatively big, that side collapses limit is big and many, causes Si wafer quality to decline.Also having and be exactly, above-mentioned technology also needs multiple Miscellaneous equipment reclaims abrasive material and cutting liquid;Silicon chip surface after cutting has carborundum, cutting liquid, metal ion, causes follow-up cleaning Trouble.
In order to overcome disadvantages mentioned above, silicon wafer cut by diamond wire technology the most progressively replaces traditional free abrasive line cutting skill Art.But, current diamond wire cutting technique cuts the silicon chip obtained, the follow-up soda acid process for etching system that can not use routine Floss, carries out making herbs into wool according to conventional soda acid process for etching, and its battery efficiency does not promote and declines on the contrary.At present, diamond wire cutting The silicon chip obtained can only use plasma reaction etching (RIE) or metal catalytic chemical attack (MCCE) method to carry out making herbs into wool, But due to above two process for etching, equipment investment is high or technology stability is poor and is difficult to promote.
Therefore, the technology of a kind of compatible diamond wire cutting and conventional soda acid process for etching is needed badly.
Summary of the invention
Based on this, it is necessary to problem that cannot be compatible for the cutting of existing diamond wire and conventional soda acid process for etching, carry Diamond wire cutting and the follow-up silicon chip using conventional soda acid making herbs into wool is used for a kind of.
A kind of silicon chip, the facet of described silicon chip has the some cut channel patterns arranged in the first direction;Described cut channel Pattern is connected by the bending of some strias or interconnection forms.
Above-mentioned silicon chip, owing to its cut channel pattern is connected or interconnection by the bending of some strias, through conventional soda acid After process for etching, could be formed with the light trapping structure of effect, so that diamond wire cutting technique is held concurrently with conventional soda acid process for etching Hold.
Wherein in an embodiment, the facet of described silicon chip is additionally provided with gully the most spaced apart; Described gully extends in a second direction, and described second direction is vertical with described first direction;Stria at described gully is parallel.
Wherein in an embodiment, the degree of depth in described gully is 5~50 μm;The width in described gully be 0.1~ 1.5mm。
Present invention also offers the preparation method of a kind of silicon chip.
The preparation method of a kind of silicon chip, comprises the steps:
Silicon crystal diamond wire is carried out line cutting;
In described line cutting process, the corundum on described diamond wire is made to vibrate in the first direction, to form cut channel figure Case.
The preparation method of above-mentioned silicon chip, the follow-up soda acid process for etching that can directly use routine carrys out making herbs into wool, makes diamond wire Cutting technique is mutually compatible with conventional soda acid process for etching, and then reduces the cost of manufacture of photovoltaic cell.
Wherein in an embodiment, it is additionally included in described line cutting process, makes the corundum on described diamond wire only Move in a second direction, to form gully.
Present invention also offers a kind of silicon slice wire cutting apparatus.
A kind of silicon slice wire cutting apparatus, including:
Two guide wheels, be arranged in parallel;At least one in said two guide wheel is non-circular guide wheel, described non-circular guide wheel Surface each point be a to the maximum difference of the distance of the rotary shaft of described non-circular guide wheel, 0 < a < 1mm;
And diamond wire, it is tensioned between two guide wheels, and moves under the drive of guide wheel.
Above-mentioned silicon slice wire cutting apparatus, owing to special guide wheel is arranged, can make corundum on diamond wire along the While one direction is moved, vibrate the most in a second direction, thus form the cut channel pattern of the present invention at silicon chip surface, make Buddha's warrior attendant Wire cutting technology can be compatible with conventional soda acid process for etching, and then reduces the cost of manufacture of photovoltaic cell.
Wherein in an embodiment, said two guide wheel is all in regular polygon.
Wherein in an embodiment, described guide wheel includes rounded base wheel and scalable is connected to described base wheel Surface on some projections.
Wherein in an embodiment, the metal base undulate of described diamond wire.
Wherein in an embodiment, the corundum of described diamond wire includes the first corundum and the second corundum, institute The ratio stating the first corundum and described second corundum is 9:1~1:1.
Accompanying drawing explanation
Fig. 1 is the facet schematic diagram of the silicon chip of diamond wire cutting in prior art.
Fig. 2 is the facet schematic diagram of the silicon chip of an embodiment of the present invention.
Fig. 3 is the structural representation of the silicon wafer cutting device of an embodiment of the present invention.
Fig. 4 is the structural representation of the line of cut of the silicon wafer cutting device of an embodiment of the present invention.
Detailed description of the invention
In order to make the purpose of the present invention, technical scheme and advantage clearer, below in conjunction with detailed description of the invention, right The present invention is further elaborated.Should be appreciated that detailed description of the invention described herein only in order to explain the present invention, It is not intended to limit the present invention.
It should be noted that when element is referred to as " being fixed on " another element, and it can be directly on another element Or element placed in the middle can also be there is.When an element is considered as " connection " another element, and it can be to be directly connected to To another element or may be simultaneously present centering elements.
Unless otherwise defined, all of technology used herein and scientific terminology and the technical field belonging to the present invention The implication that technical staff is generally understood that is identical.The term used the most in the description of the invention is intended merely to describe tool The purpose of the embodiment of body, it is not intended that in limiting the present invention.Term as used herein " and/or " include one or more phase Arbitrary and all of combination of the Listed Items closed.
The silicon chip of existing diamond wire cutting, after conventional soda acid process for etching, its battery efficiency does not promotes Decline on the contrary.The present inventor finds through research, sees Fig. 1, the silicon chip 100 ' of existing diamond wire cutting, cuts shape The stria 101 ' of a plurality of parallel arrangement become, the spacing between these strias 101 ' is about 1.6 μm, and stria 101 ' it Between there is the silicon chip surface of similar mirror portion.After conventional soda acid process for etching, owing to soda acid making herbs into wool utilizes soda acid Corrosion anisotropy on crystal orientation, adds these stria 101 ' parallel arrangements, and the facet of the silicon chip after making herbs into wool becomes on the contrary Smooth, do not form light trapping structure.The reason that this namely diamond wire cutting is incompatible with conventional soda acid process for etching.
See Fig. 2, the silicon chip 100 of an embodiment of the present invention, diamond wire cutting form, it has facet.This is cut There is on face some cut channel patterns 110.Cut channel pattern 110 (namely the Y-direction in Fig. 2) periodic arrangement in the first direction. Cut channel pattern 110 is made up of diamond wire cutting stria in cutting process.
The cut channel pattern 110 of the present invention is in " non-linear ", namely cut channel pattern 110 is connected by the bending of some strias or intersected It is formed by connecting.The mutually continued access such as such as " it ", " mutually ", " work ", " witch ", X-shaped, worm shape forms.The cut channel pattern of the present invention, After conventional soda acid process for etching, form the light trapping structure of surface rule change.
Usually, the damage of cut channel pattern 110 is in Nano/micron level, after conventional soda acid process for etching, corresponding Ground light trapping structure is also Nano/micron level.
In order to optimize the performance of silicon chip 100 further, the silicon chip 100 of present embodiment, its facet is additionally provided with along The gully 104 that one direction is spaced apart;Gully, gully 104 extends in a second direction, and second direction is vertical with first direction Direction (namely the X-direction in second direction Fig. 2).Stria at gully 104 is parallel.
Specifically, the position in gully 104 and quantity, position and quantity according to the main gate line of photovoltaic cell are designed.Example As, the bar number in gully is 2,3,4,5 ... 18 etc..
Owing to gully 104 is correspondingly arranged up and down with main gate line, the stria at gully 104 is parallel (i.e. with existing diamond wire The stria of cutting is the same), after conventional soda acid process for etching, become more smooth, so can reduce reduction main Recombination-rate surface under grid line and reduction main gate line resistance, thus promote photovoltaic cell electricity conversion.
Preferably, the degree of depth in gully 104 is 5~50 μm;The width in gully 104 is 0.1~1.5mm.
In the present embodiment, the number in gully is 4, and the degree of depth in gully is 15 μm, and the width in gully is 0.8mm.
It is, of course, understood that in some cases, the present invention can also be not provided with gully 104.
Silicon chip provided by the present invention, owing to its cut channel pattern is connected by the bending of some strias or intersected to form, is passing through After conventional soda acid process for etching, could be formed with the light trapping structure of effect, so that diamond wire cutting technique and conventional soda acid Process for etching is compatible, and then reduces the cost of manufacture of photovoltaic cell.
Present invention also offers the preparation method of a kind of silicon chip.
The preparation method of a kind of silicon chip, carries out line cutting including by silicon crystal diamond wire.
Wherein, diamond wire includes metal base and the corundum being fixedly arranged on metal base;During cutting on line, make Corundum (Y-direction in figure) in the first direction vibrates, to form cut channel pattern.
Owing to corundum is while moving in X direction, also vibrate along Y-direction, so each corundum is at silicon chip surface The stria generated not is a straight line in X direction, after the stria superposition of different corundum, i.e. forms some strias curved Folding connects or cross-coupled cut channel pattern.
In order to optimize the performance of silicon chip further, during cutting on line, also include making corundum only move in a second direction Dynamic, stria now is the stria at gully.I.e. when needs form gully, in certain period of time, only control corundum Move along Y-direction.
Specifically, gully can be come by the method that constant cutting position repeats to cut or constant cutting tension force repeats to cut Realize.
The preparation method of above-mentioned silicon chip, the follow-up soda acid process for etching that can directly use routine carrys out making herbs into wool, makes diamond wire Cutting technique is mutually compatible with conventional soda acid process for etching.It addition, the preparation method of the silicon chip of the present invention, be applicable to monocrystalline and This efficiency cutting of polycrystalline manufactures.
Present invention also offers a kind of silicon wafer cutting device for preparing above-mentioned silicon chip.
Seeing Fig. 3, silicon wafer cutting device 1000 includes two guide wheels 310,320, and diamond wire 400.
Wherein, the Main Function of two guide wheels 310,320 is, by diamond wire 400 tensioning, and drives diamond wire 400 basic X-direction along figure is moved.Specifically, two guide wheels 310,320 be arranged in parallel, and are spaced a distance so that by silicon wafer Body 200 is placed between two guide wheels 310,320.
Seeing Fig. 4, diamond wire 400 includes metal base 410 and corundum 420, and corundum 420 is fixedly arranged at metal base On 410.The Main Function of metal base 410 is, as the carrier of corundum.Metal base 410 does not the most produce dissection, Play dissection is the corundum being fixedly arranged on metal base 410.
In cutting process, the run-in synchronism of two guide wheels 310,320, drive diamond wire 400 high-speed motion simultaneously, so that Corundum 420 high-speed motion, produces cutting to silicon crystal 200.
It is, of course, understood that usually, silicon wafer cutting device 1000 also includes spray coolant device (not shown) And silicon crystal hold-down devices (not shown) etc..These devices all can use structure known in those skilled in the art, This repeats no more.
In the present invention, at least one in two guide wheels 310,320 is non-circular guide wheel, i.e. two guide wheels 310,320 In at least one be non-circular.The surface each point of non-circular guide wheel is a to the maximum difference of the distance of rotary shaft, 0 < a < 1mm. It is, a be in non-circular guide pulley surface distance rotary shaft point furthest in distance and the non-circular guide pulley surface of rotary shaft The distance nearest point of rotary shaft is to the difference of the distance of rotary shaft.So owing to each point is apart from the distance not phase of the rotary shaft of guide wheel With, diamond wire is in motor process, while corundum 420 moves the most only along an X, also has and vibrates along Y-direction, and Y side To vibration control within certain amplitude, thus on the facet of silicon chip, form the cut channel pattern of the present invention, and avoid The phenomenon that in prior art, diamond wire cutting stria is parallel.
It is highly preferred that span 3~17 μm of a.So can promote the performance of silicon chip further.
In a preferred embodiment, two guide wheels are all in regular polygon.It is of course also possible to be simply a guide wheel in just Polygon.
The operation principle of the silicon wafer cutting device of the present invention is described with the guide wheel of positive 300 limit shapes below.
Two guide wheels in silicon wafer cutting device are identical, a length of 200mm in its footpath, and the spacing between two guide wheels is 400mm. Owing to guide wheel is positive 300 limit shapes.The most positive 300 Xing Zhong summits, limit are 100mm to the distance of rotary shaft, in positive 300 Xing Zhong limits, limit Point is 99.995mm to the distance of rotary shaft.It is, the distance of rotary shaft is arrived at positive 300 Xing Zhong summits, limit and midpoint, limit respectively Difference a be 5 μm.
Two guide wheels are controlled by electric rotating machine, and synchronous rotary.Guide wheel drives diamond wire to move with the X-direction of 17m/s. Owing to positive 300 Xing Zhong summits, limit are different from the distance that rotary shaft is arrived at midpoint, limit respectively, cause the corundum on diamond wire in X side While motion, there is again periodic Y-direction motion (vibration the most in the Y direction).
It is computed, owing to guide wheel is that positive 300 limit shapes, i.e. guide wheel are often revolved and turned around, has the Y-direction in 300 cycles to move. The difference of the distance arriving rotary shaft respectively due to positive 300 Xing Zhong summits, limit and midpoint, limit is 5 μm.It is to say, along with 17m/ The X-direction motion of s, corundum amplitude in the Y direction is 5 μm.
As a example by silicon chip width is as 156mm, then corundum length every about 500 μm in silicon chip X-direction makees one Individual amplitude is the stria of 5 μm.By the stria of different corundum, finally form cut channel pattern on the surface of silicon chip.
It is it is, of course, understood that guide wheel is not limited to regular polygon, it is also possible to be other shape, such as oval, Also the partial arc section or on the circumference of guide wheel, straightway or arc section by one or more are (bent with the arc section being replaced Rate is different) or oval segmental arc or other geometrical curve replace.Replacement can be the uniform replacement kept at a certain distance away, also or Irregular replacement.
It is, of course, also possible to be guide wheel include rounded base wheel and scalable be connected on base wheel surface some convex Rise.When this projection stretches out the periphery of base wheel, the corundum on diamond wire, while X-direction moves, vibrates in the Y direction, Now can form the cut channel pattern of the present invention.When this projection is retracted in the periphery of base wheel, now guide wheel recovers periphery, Corundum on diamond wire only moves in X-direction, now can form the stria at gully.
Preferably, metal base 410 is in wavy, namely " non-linear ".In the present invention, metal base 410 can be plane Interior wave, can also be three-dimensional spatially spiral wave.
Use the metal base 410 of wave design, the obstruction in X-Y direction can be buffered, it is simple to " self adaptation " walks around silicon Hard spot on crystal 200, is conducive to improving cutting speed, and avoids the hard spot disconnection problem that existing diamond wire cuts, from And the beneficially yield of output silicon chip, cost and production capacity.Meanwhile, wave design combines with the design of guide wheel of the present invention, makes Cutting movement spatial alternation, and then form regular surface damage and making herbs into wool effect, promote power conversion efficiency (pce) further.
In the present embodiment, the wavelength of metal base 410 is 3mm, and the difference in height between trough and crest is 7 μm.
Preferably, corundum 420 on metal base 410 in non-uniform Distribution, at crest, the trough of metal base 410 Place is simultaneously or optionally one distribution is closeer.In the present embodiment, corundum 420 density at crest, trough is higher.
In the present embodiment, corundum 420 includes the first corundum 421 and the second corundum 422, the first corundum 421 and second corundum 422 be the corundum of two kinds of different sizes.Specifically, the particle diameter of the first corundum 421 is less than the second gold medal The particle diameter of emery 422.
It is highly preferred that the ratio of the first corundum 421 and the second corundum 422 is 9:1~1:1.
Above-mentioned silicon slice wire cutting apparatus, owing to special guide wheel is arranged, can make corundum on diamond wire along the While one direction is moved, vibrate the most in a second direction, thus form the cut channel pattern of the present invention at silicon chip surface, make Buddha's warrior attendant Wire cutting technology can be compatible with conventional soda acid process for etching, and then reduces the cost of manufacture of photovoltaic cell.
Each technical characteristic of the above embodiment can combine arbitrarily, for making description succinct, not to above-mentioned The all possible combination of each technical characteristic in embodiment is all described, but, if the combination of these technical characteristics There is not contradiction, be all considered to be the scope that this specification is recorded.
The above embodiment only have expressed the several embodiments of the present invention, and it describes more concrete and detailed, but Can not therefore be construed as limiting the scope of the patent.It should be pointed out that, for those of ordinary skill in the art For, without departing from the inventive concept of the premise, it is also possible to make some deformation and improvement, these broadly fall into the guarantor of the present invention Protect scope.Therefore, the protection domain of patent of the present invention should be as the criterion with claims.

Claims (10)

1. a silicon chip, it is characterised in that there are on the facet of described silicon chip the some cut channel patterns arranged in the first direction; Described cut channel pattern is connected by the bending of some strias or interconnection forms.
Silicon chip the most according to claim 1, it is characterised in that between being additionally provided with in the first direction on the facet of described silicon chip Gully every distribution;Described gully extends in a second direction, and described second direction is vertical with described first direction;At described gully Stria parallel.
Silicon chip the most according to claim 1, it is characterised in that the degree of depth in described gully is 5~50 μm;The width in described gully Degree is 0.1~1.5mm.
4. the preparation method of the silicon chip described in a claim 1, it is characterised in that comprise the steps:
Silicon crystal diamond wire is carried out line cutting;
In described line cutting process, the corundum on described diamond wire is made to vibrate in the first direction, to form cut channel pattern.
Silicon chip preparation method the most according to claim 4, it is characterised in that be additionally included in described line cutting process, make Corundum on described diamond wire only moves, in a second direction to form gully.
6. a silicon slice wire cutting apparatus, it is characterised in that including:
Two guide wheels, be arranged in parallel;At least one in said two guide wheel is non-circular guide wheel, the table of described non-circular guide wheel Face each point is a to the maximum difference of the distance of the rotary shaft of described non-circular guide wheel, 0 < a < 1mm;
And diamond wire, it is tensioned between two guide wheels, and moves under the drive of guide wheel.
Silicon slice wire cutting apparatus the most according to claim 6, it is characterised in that said two guide wheel is all in regular polygon.
Silicon slice wire cutting apparatus the most according to claim 6, it is characterised in that described guide wheel include rounded base wheel, And scalable be connected to described base wheel surface on some projections.
Silicon slice wire cutting apparatus the most according to claim 6, it is characterised in that the metal base of described diamond wire is wave Shape.
Silicon slice wire cutting apparatus the most according to claim 9, it is characterised in that the corundum of described diamond wire includes One corundum and the second corundum, described first corundum is 9:1~1:1 with the ratio of described second corundum.
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CN107263750B (en) * 2017-08-07 2020-01-10 苏州赛万玉山智能科技有限公司 Cutting method of solar silicon wafer and three-dimensional solar silicon wafer
CN110625835A (en) * 2019-09-12 2019-12-31 西安奕斯伟硅片技术有限公司 Silicon wafer forming processing method

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