CN106290438B - 一种x射线荧光光谱熔融法测定萤石中氟化钙含量的方法 - Google Patents
一种x射线荧光光谱熔融法测定萤石中氟化钙含量的方法 Download PDFInfo
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- CN106290438B CN106290438B CN201610822238.1A CN201610822238A CN106290438B CN 106290438 B CN106290438 B CN 106290438B CN 201610822238 A CN201610822238 A CN 201610822238A CN 106290438 B CN106290438 B CN 106290438B
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- WUKWITHWXAAZEY-UHFFFAOYSA-L calcium difluoride Chemical compound [F-].[F-].[Ca+2] WUKWITHWXAAZEY-UHFFFAOYSA-L 0.000 title claims abstract description 83
- 239000010436 fluorite Substances 0.000 title claims abstract description 61
- 238000000034 method Methods 0.000 title claims abstract description 33
- 229910001634 calcium fluoride Inorganic materials 0.000 title claims abstract description 22
- 238000004876 x-ray fluorescence Methods 0.000 title claims abstract description 20
- 238000001228 spectrum Methods 0.000 title claims abstract description 12
- 238000007500 overflow downdraw method Methods 0.000 title claims abstract description 10
- AMXOYNBUYSYVKV-UHFFFAOYSA-M lithium bromide Chemical compound [Li+].[Br-] AMXOYNBUYSYVKV-UHFFFAOYSA-M 0.000 claims abstract description 22
- 238000002844 melting Methods 0.000 claims abstract description 20
- 230000008018 melting Effects 0.000 claims abstract description 20
- 238000004458 analytical method Methods 0.000 claims abstract description 18
- 238000005259 measurement Methods 0.000 claims abstract description 18
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 10
- 239000005357 flat glass Substances 0.000 claims abstract description 9
- 239000006185 dispersion Substances 0.000 claims abstract description 8
- 229910052731 fluorine Inorganic materials 0.000 claims abstract description 4
- BASFCYQUMIYNBI-UHFFFAOYSA-N platinum Substances [Pt] BASFCYQUMIYNBI-UHFFFAOYSA-N 0.000 claims abstract description 4
- 229910052697 platinum Inorganic materials 0.000 claims abstract description 4
- 239000011737 fluorine Substances 0.000 claims abstract description 3
- 230000003595 spectral effect Effects 0.000 claims abstract description 3
- PXGOKWXKJXAPGV-UHFFFAOYSA-N Fluorine Chemical compound FF PXGOKWXKJXAPGV-UHFFFAOYSA-N 0.000 claims abstract 2
- 230000004907 flux Effects 0.000 claims description 26
- PSHMSSXLYVAENJ-UHFFFAOYSA-N dilithium;[oxido(oxoboranyloxy)boranyl]oxy-oxoboranyloxyborinate Chemical compound [Li+].[Li+].O=BOB([O-])OB([O-])OB=O PSHMSSXLYVAENJ-UHFFFAOYSA-N 0.000 claims description 8
- 229940059936 lithium bromide Drugs 0.000 claims description 6
- HZRMTWQRDMYLNW-UHFFFAOYSA-N lithium metaborate Chemical compound [Li+].[O-]B=O HZRMTWQRDMYLNW-UHFFFAOYSA-N 0.000 claims description 6
- 239000000155 melt Substances 0.000 claims description 5
- 239000013078 crystal Substances 0.000 claims description 4
- 238000002156 mixing Methods 0.000 claims description 4
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 abstract description 12
- OSGAYBCDTDRGGQ-UHFFFAOYSA-L calcium sulfate Chemical compound [Ca+2].[O-]S([O-])(=O)=O OSGAYBCDTDRGGQ-UHFFFAOYSA-L 0.000 abstract description 12
- 229910000019 calcium carbonate Inorganic materials 0.000 abstract description 6
- 235000011132 calcium sulphate Nutrition 0.000 abstract description 6
- 239000003153 chemical reaction reagent Substances 0.000 abstract description 3
- 150000001669 calcium Chemical class 0.000 abstract description 2
- 239000001175 calcium sulphate Substances 0.000 abstract description 2
- 239000003054 catalyst Substances 0.000 abstract description 2
- 230000002349 favourable effect Effects 0.000 abstract description 2
- 239000004615 ingredient Substances 0.000 abstract description 2
- 239000007788 liquid Substances 0.000 abstract description 2
- 239000002699 waste material Substances 0.000 abstract description 2
- 239000012046 mixed solvent Substances 0.000 abstract 1
- 239000000523 sample Substances 0.000 description 37
- 239000011324 bead Substances 0.000 description 10
- 239000011521 glass Substances 0.000 description 9
- 239000000126 substance Substances 0.000 description 9
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 description 6
- 230000000694 effects Effects 0.000 description 6
- 238000009614 chemical analysis method Methods 0.000 description 5
- 238000012360 testing method Methods 0.000 description 5
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 4
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 description 3
- 239000002253 acid Substances 0.000 description 3
- 239000011575 calcium Substances 0.000 description 3
- 229910052791 calcium Inorganic materials 0.000 description 3
- 238000004090 dissolution Methods 0.000 description 3
- 238000002474 experimental method Methods 0.000 description 3
- 238000002360 preparation method Methods 0.000 description 3
- 239000013062 quality control Sample Substances 0.000 description 3
- KRHYYFGTRYWZRS-UHFFFAOYSA-N Fluorane Chemical compound F KRHYYFGTRYWZRS-UHFFFAOYSA-N 0.000 description 2
- 238000005266 casting Methods 0.000 description 2
- 238000001816 cooling Methods 0.000 description 2
- 230000001419 dependent effect Effects 0.000 description 2
- 238000002189 fluorescence spectrum Methods 0.000 description 2
- 229910052500 inorganic mineral Inorganic materials 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
- 238000010309 melting process Methods 0.000 description 2
- 239000011707 mineral Substances 0.000 description 2
- 235000010755 mineral Nutrition 0.000 description 2
- 238000002203 pretreatment Methods 0.000 description 2
- 239000000377 silicon dioxide Substances 0.000 description 2
- PUZPDOWCWNUUKD-UHFFFAOYSA-M sodium fluoride Chemical compound [F-].[Na+] PUZPDOWCWNUUKD-UHFFFAOYSA-M 0.000 description 2
- 239000007787 solid Substances 0.000 description 2
- 238000004448 titration Methods 0.000 description 2
- HLLSOEKIMZEGFV-UHFFFAOYSA-N 4-(dibutylsulfamoyl)benzoic acid Chemical compound CCCCN(CCCC)S(=O)(=O)C1=CC=C(C(O)=O)C=C1 HLLSOEKIMZEGFV-UHFFFAOYSA-N 0.000 description 1
- DDFHBQSCUXNBSA-UHFFFAOYSA-N 5-(5-carboxythiophen-2-yl)thiophene-2-carboxylic acid Chemical compound S1C(C(=O)O)=CC=C1C1=CC=C(C(O)=O)S1 DDFHBQSCUXNBSA-UHFFFAOYSA-N 0.000 description 1
- ZOXJGFHDIHLPTG-UHFFFAOYSA-N Boron Chemical compound [B] ZOXJGFHDIHLPTG-UHFFFAOYSA-N 0.000 description 1
- BVKZGUZCCUSVTD-UHFFFAOYSA-L Carbonate Chemical compound [O-]C([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-L 0.000 description 1
- YCKRFDGAMUMZLT-UHFFFAOYSA-N Fluorine atom Chemical compound [F] YCKRFDGAMUMZLT-UHFFFAOYSA-N 0.000 description 1
- 241000254158 Lampyridae Species 0.000 description 1
- WHXSMMKQMYFTQS-UHFFFAOYSA-N Lithium Chemical compound [Li] WHXSMMKQMYFTQS-UHFFFAOYSA-N 0.000 description 1
- DQMUQFUTDWISTM-UHFFFAOYSA-N O.[O-2].[Fe+2].[Fe+2].[O-2] Chemical compound O.[O-2].[Fe+2].[Fe+2].[O-2] DQMUQFUTDWISTM-UHFFFAOYSA-N 0.000 description 1
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 description 1
- 239000000853 adhesive Substances 0.000 description 1
- 230000001070 adhesive effect Effects 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 230000037396 body weight Effects 0.000 description 1
- 229910052796 boron Inorganic materials 0.000 description 1
- 239000004566 building material Substances 0.000 description 1
- 230000015556 catabolic process Effects 0.000 description 1
- 239000004568 cement Substances 0.000 description 1
- 239000000919 ceramic Substances 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 239000000470 constituent Substances 0.000 description 1
- 238000012937 correction Methods 0.000 description 1
- 230000007797 corrosion Effects 0.000 description 1
- 238000005260 corrosion Methods 0.000 description 1
- 238000002425 crystallisation Methods 0.000 description 1
- 230000008025 crystallization Effects 0.000 description 1
- 230000007812 deficiency Effects 0.000 description 1
- 230000002950 deficient Effects 0.000 description 1
- 238000007865 diluting Methods 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 230000005284 excitation Effects 0.000 description 1
- 229910001672 fluorine mineral Inorganic materials 0.000 description 1
- 230000004927 fusion Effects 0.000 description 1
- 150000002366 halogen compounds Chemical class 0.000 description 1
- 238000012417 linear regression Methods 0.000 description 1
- 229910052744 lithium Inorganic materials 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- 238000012544 monitoring process Methods 0.000 description 1
- -1 plating Substances 0.000 description 1
- 238000007747 plating Methods 0.000 description 1
- 239000011148 porous material Substances 0.000 description 1
- 238000004321 preservation Methods 0.000 description 1
- 238000004445 quantitative analysis Methods 0.000 description 1
- 238000005057 refrigeration Methods 0.000 description 1
- 239000002893 slag Substances 0.000 description 1
- 239000011775 sodium fluoride Substances 0.000 description 1
- 235000013024 sodium fluoride Nutrition 0.000 description 1
- 238000004611 spectroscopical analysis Methods 0.000 description 1
- 238000010183 spectrum analysis Methods 0.000 description 1
- 238000010561 standard procedure Methods 0.000 description 1
- 238000009628 steelmaking Methods 0.000 description 1
- 239000004575 stone Substances 0.000 description 1
- 238000010998 test method Methods 0.000 description 1
- 230000007704 transition Effects 0.000 description 1
- 238000005303 weighing Methods 0.000 description 1
- 239000002023 wood Substances 0.000 description 1
Classifications
-
- G—PHYSICS
- G01—MEASURING; TESTING
- G01N—INVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
- G01N23/00—Investigating or analysing materials by the use of wave or particle radiation, e.g. X-rays or neutrons, not covered by groups G01N3/00 – G01N17/00, G01N21/00 or G01N22/00
- G01N23/22—Investigating or analysing materials by the use of wave or particle radiation, e.g. X-rays or neutrons, not covered by groups G01N3/00 – G01N17/00, G01N21/00 or G01N22/00 by measuring secondary emission from the material
- G01N23/223—Investigating or analysing materials by the use of wave or particle radiation, e.g. X-rays or neutrons, not covered by groups G01N3/00 – G01N17/00, G01N21/00 or G01N22/00 by measuring secondary emission from the material by irradiating the sample with X-rays or gamma-rays and by measuring X-ray fluorescence
-
- G—PHYSICS
- G01—MEASURING; TESTING
- G01N—INVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
- G01N2223/00—Investigating materials by wave or particle radiation
- G01N2223/07—Investigating materials by wave or particle radiation secondary emission
- G01N2223/076—X-ray fluorescence
-
- G—PHYSICS
- G01—MEASURING; TESTING
- G01N—INVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
- G01N2223/00—Investigating materials by wave or particle radiation
- G01N2223/10—Different kinds of radiation or particles
- G01N2223/101—Different kinds of radiation or particles electromagnetic radiation
- G01N2223/1016—X-ray
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- Physics & Mathematics (AREA)
- Health & Medical Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Chemical & Material Sciences (AREA)
- Analytical Chemistry (AREA)
- Biochemistry (AREA)
- General Health & Medical Sciences (AREA)
- General Physics & Mathematics (AREA)
- Immunology (AREA)
- Pathology (AREA)
- Analysing Materials By The Use Of Radiation (AREA)
Abstract
Description
样品编号 | 分析项目 | 化学分析方法结果/% | 本法结果/% | 偏差 |
萤石1# | CaF<sub>2</sub> | 56.23 | 56.03 | -0.20 |
萤石2# | CaF<sub>2</sub> | 66.58 | 66.65 | 0.07 |
萤石3# | CaF<sub>2</sub> | 73.95 | 73.81 | -0.14 |
萤石4# | CaF<sub>2</sub> | 87.43 | 87.30 | -0.13 |
萤石5# | CaF<sub>2</sub> | 94.87 | 94.95 | 0.08 |
Claims (3)
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CN201610822238.1A CN106290438B (zh) | 2016-09-13 | 2016-09-13 | 一种x射线荧光光谱熔融法测定萤石中氟化钙含量的方法 |
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CN110389145A (zh) * | 2018-04-23 | 2019-10-29 | 中国科学院大连化学物理研究所 | 一种检测溶液中无机氰化物含量的方法 |
CN108680593A (zh) * | 2018-08-02 | 2018-10-19 | 龙岩学院 | 一种x射线荧光光谱快速测定花岗岩中主、次、微量成分的方法 |
CN112730365A (zh) * | 2020-12-29 | 2021-04-30 | 天津天钢联合特钢有限公司 | 一种冶金石灰氧化钙分析方法 |
Citations (2)
Publication number | Priority date | Publication date | Assignee | Title |
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CN101498675A (zh) * | 2009-03-05 | 2009-08-05 | 天津钢铁有限公司 | 连铸保护渣x射线荧光光谱分析方法 |
CN102507287A (zh) * | 2011-11-21 | 2012-06-20 | 山东省地质科学实验研究院 | X射线荧光光谱分析中用于萤石样品的制样熔剂 |
Family Cites Families (1)
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RU2308024C2 (ru) * | 2003-08-01 | 2007-10-10 | Ригаку Индастриал Корпорейшн | Держатель образца для рентгеновского флуоресцентного анализа, способ рентгеновского флуоресцентного анализа и рентгеновский флуоресцентный спектрометр с использованием такого держателя |
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CN101498675A (zh) * | 2009-03-05 | 2009-08-05 | 天津钢铁有限公司 | 连铸保护渣x射线荧光光谱分析方法 |
CN102507287A (zh) * | 2011-11-21 | 2012-06-20 | 山东省地质科学实验研究院 | X射线荧光光谱分析中用于萤石样品的制样熔剂 |
Non-Patent Citations (2)
Title |
---|
《X射线荧光光谱法测定萤石中氟化钙、二氧化硅、氧化铝、全铁的含量》;李韶梅等;《理化检验-化学分册》;20111231;第47卷(第10期);正文第1163-1164页 |
《X射线荧光光谱法测定萤石中氟化钙》;袁家义;《岩矿测试》;20071031;第26卷(第5期);全文 |
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Address after: 243000 Xitang Road, Ma'anshan Economic Development Zone, Anhui, No. 666 Co-patentee after: HUAWEI METAL MINERAL RESOURCE EFFICIENT RECYCLING UTILIZATION NATIONAL ENGINEERING RESEARCH CENTER Co.,Ltd. Patentee after: MAANSHAN Mine Research Institute Co.,Ltd. Address before: 243000 Xitang Road, Ma'anshan Economic Development Zone, Anhui, No. 666 Co-patentee before: HUAWEI METAL MINERAL RESOURCE EFFICIENT RECYCLING UTILIZATION NATIONAL ENGINEERING RESEARCH CENTER Co.,Ltd. Patentee before: SINOSTEEL MAANSHAN INSTITUTE OF MINING RESEARCH Co.,Ltd. |