CN106283085A - A kind of brightening rust removing agent - Google Patents

A kind of brightening rust removing agent Download PDF

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Publication number
CN106283085A
CN106283085A CN201610652318.7A CN201610652318A CN106283085A CN 106283085 A CN106283085 A CN 106283085A CN 201610652318 A CN201610652318 A CN 201610652318A CN 106283085 A CN106283085 A CN 106283085A
Authority
CN
China
Prior art keywords
parts
acid
removing agent
rust removing
brightening
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Withdrawn
Application number
CN201610652318.7A
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Chinese (zh)
Inventor
周仁勇
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Individual
Original Assignee
Individual
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Individual filed Critical Individual
Priority to CN201610652318.7A priority Critical patent/CN106283085A/en
Publication of CN106283085A publication Critical patent/CN106283085A/en
Withdrawn legal-status Critical Current

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Classifications

    • CCHEMISTRY; METALLURGY
    • C23COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23FNON-MECHANICAL REMOVAL OF METALLIC MATERIAL FROM SURFACE; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL; MULTI-STEP PROCESSES FOR SURFACE TREATMENT OF METALLIC MATERIAL INVOLVING AT LEAST ONE PROCESS PROVIDED FOR IN CLASS C23 AND AT LEAST ONE PROCESS COVERED BY SUBCLASS C21D OR C22F OR CLASS C25
    • C23F3/00Brightening metals by chemical means
    • C23F3/04Heavy metals
    • C23F3/06Heavy metals with acidic solutions
    • CCHEMISTRY; METALLURGY
    • C23COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23GCLEANING OR DE-GREASING OF METALLIC MATERIAL BY CHEMICAL METHODS OTHER THAN ELECTROLYSIS
    • C23G1/00Cleaning or pickling metallic material with solutions or molten salts
    • C23G1/02Cleaning or pickling metallic material with solutions or molten salts with acid solutions
    • C23G1/04Cleaning or pickling metallic material with solutions or molten salts with acid solutions using inhibitors
    • C23G1/06Cleaning or pickling metallic material with solutions or molten salts with acid solutions using inhibitors organic inhibitors
    • C23G1/061Cleaning or pickling metallic material with solutions or molten salts with acid solutions using inhibitors organic inhibitors nitrogen-containing compounds
    • CCHEMISTRY; METALLURGY
    • C23COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23GCLEANING OR DE-GREASING OF METALLIC MATERIAL BY CHEMICAL METHODS OTHER THAN ELECTROLYSIS
    • C23G1/00Cleaning or pickling metallic material with solutions or molten salts
    • C23G1/02Cleaning or pickling metallic material with solutions or molten salts with acid solutions
    • C23G1/08Iron or steel
    • C23G1/088Iron or steel solutions containing organic acids

Landscapes

  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Mechanical Engineering (AREA)
  • Metallurgy (AREA)
  • Organic Chemistry (AREA)
  • Detergent Compositions (AREA)
  • Cleaning And De-Greasing Of Metallic Materials By Chemical Methods (AREA)

Abstract

The present invention relates to a kind of brightening rust removing agent, the most composed of the following components: hydrochloric acid 45 60 parts, phosphatase 24 5 parts, hexamethylenetetramine 0.4 0.6 parts, sodium lauryl sulphate 0.4 0.6 parts, triethanolamine 0.15 0.4 parts, citric acid 0.4 0.6 parts, oleic acid 0.5 1.2 parts, oxalic acid 0.8 1.6 parts, thiourea 0.5 3 parts, 3 10 parts of tartaric acid, sulfamic acid 16 parts, 20 70 parts of water.The present invention is with low cost, can use, be not likely to produce acid mist under room temperature state, the most friendly to human body and environment, and destroys minimum to sheet material, simple to operate.

Description

A kind of brightening rust removing agent
Technical field
The present invention relates to a kind of rust remover, a kind of brightening rust removing agent.
Background technology
Along with steel and iron industry and the manufacturing development of iron and steel, the corrosion problem of steel becomes increasingly conspicuous, the whole world every year due to The weight of corrosion and the metal material scrapped and equipment is about the 20%-30% of metal annual production, and up to 1 × 108 More than t.Right Before metallic article takes various anti-corrosion measure, rust cleaning is necessary processing step.Current derusting method predominantly organic tool method, change The big class of method two.Mechanical Method is that shortcoming is that labor intensity is big, efficiency is low, dust pollution by manually striking shovel, polishing and blasting treatment Seriously, and being limited by Components Shape, the rust of limit, corner angle, re-entrant angle and capillary inside diameter is difficult to clean off totally.Chemical method has effect The best, the series of advantages such as efficiency is high, and technological operation is simple, low cost, are the developing direction of current rust remover.But chemical method is also There is the danger of " hydrogen embrittlement ", contaminated air, after rust cleaning, workpiece need to be cleaned multiple times, and integrated treatment to be made the most also can Get rusty, have a strong impact on the adhesive force of follow-up coating, especially prominent to skin of paint.Derusting method uses impregnated mostly, uses this The method of kind, first needs to build huge immersion trough, and construction investment is very big, also has the most more seriously giving up after changing tank liquor Liquid processes.Therefore, current chemical method is difficult to requiring higher sector application, especially the shipbuilding etc. to outsize workpiece rust cleaning Industry.So needing a kind of brightening rust removing agent badly to solve the problems referred to above.
Summary of the invention
Not enough for above-mentioned prior art, the present invention provides a kind of brightening rust removing agent.
A kind of brightening rust removing agent that the present invention provides is achieved through the following technical solutions:
A kind of brightening rust removing agent, it is characterised in that the most composed of the following components: hydrochloric acid 45-60 part, phosphatase 24-5 parts, six Methenamine 0.4-0.6 part, sodium lauryl sulphate 0.4-0.6 part, triethanolamine 0.15-0.4 part, citric acid 0.4-0.6 Part, oleic acid 0.5-1.2 part, oxalic acid 0.8-1.6 part, thiourea 0.5-3 part, tartaric acid 3-10 part, sulfamic acid 1-6 part, water 20-70 Part.
The invention has the beneficial effects as follows: with low cost, can use under room temperature state, be not likely to produce acid mist, to human body and Environment is the most friendly, and destroys minimum to sheet material, simple to operate;Use the hydrochloric acid of high concentration, the speed that eliminates rust can be accelerated, improve raw Producing efficiency, on the other hand, rust cleaning speed speeds the corrosion that the most relatively slow down workpiece, and the addition of phosphoric acid can be effectively in complex solution Bivalence and ferric ion, extend solution service life;Restrainer plays association by compounding to itself and hexamethylenetetramine Same-action;The addition of corrosion inhibiter neither affects the removing of article surface oxide, can effectively protect again product matrix few rotten Erosion, reduces the hydrogen embrittlement harm to product;The complexed surfactant chosen can be dissolved in acid solution, contributes to dispersion and the rusty scale of greasy dirt Come off, also function to suppress acid mist effect;The addition of oleic acid can slow down the corrosion of workpiece.
Detailed description of the invention
By embodiment, technical scheme will be clearly and completely described below, it is clear that described reality Execute a part of embodiment rather than whole embodiments that example is only the present invention.Based on the embodiment in the present invention, this area skill The every other embodiment that art personnel are obtained under not making creative work premise, broadly falls into the model of present invention protection Enclose.
Embodiment 1: a kind of brightening rust removing agent, the most composed of the following components: hydrochloric acid 45 parts, phosphatase 24 part, six methylenes Urotropine 0.4 part, sodium lauryl sulphate 0.4 part, triethanolamine 0.15 part, citric acid 0.4 part, oleic acid 0.5 part, oxalic acid 0.8 Part, thiourea 0.5 part, 3 parts of tartaric acid, sulfamic acid 1 part, 20 parts of water.
Embodiment 2: a kind of brightening rust removing agent, the most composed of the following components: hydrochloric acid 52 parts, phosphatase 24 .5 part, six is sub- Tetramine 0.5 part, sodium lauryl sulphate 0.5 part, triethanolamine 0.25 part, citric acid 0.5 part, oleic acid 0.8 part, oxalic acid 1.2 parts, thiourea 2 parts, 6.5 parts of tartaric acid, sulfamic acid 3.5 parts, 45 parts of water.
Embodiment 3: a kind of brightening rust removing agent, the most composed of the following components: hydrochloric acid 60 parts, phosphoric acid 5 parts, six methylenes Urotropine 0.6 part, sodium lauryl sulphate 0.6 part, triethanolamine 0.4 part, citric acid 0.6 part, oleic acid 1.2 parts, oxalic acid 1.6 Part, thiourea 3 parts, 10 parts of tartaric acid, sulfamic acid 6 parts, 70 parts of water.
Embodiment described above only represents embodiments of the present invention, and it describes more concrete and detailed, but can not manage Solve as limitation of the scope of the invention.It should be pointed out that, for a person skilled in the art, without departing from structure of the present invention On the premise of think of, it is also possible to make some deformation and improvement, these broadly fall into scope.

Claims (1)

1. a brightening rust removing agent, it is characterised in that the most composed of the following components: hydrochloric acid 45-60 part, phosphatase 24-5 parts, Hexamethylenetetramine 0.4-0.6 part, sodium lauryl sulphate 0.4-0.6 part, triethanolamine 0.15-0.4 part, citric acid 0.4- 0.6 part, oleic acid 0.5-1.2 part, oxalic acid 0.8-1.6 part, thiourea 0.5-3 part, tartaric acid 3-10 part, sulfamic acid 1-6 part, water 20-70 part.
CN201610652318.7A 2016-08-11 2016-08-11 A kind of brightening rust removing agent Withdrawn CN106283085A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201610652318.7A CN106283085A (en) 2016-08-11 2016-08-11 A kind of brightening rust removing agent

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201610652318.7A CN106283085A (en) 2016-08-11 2016-08-11 A kind of brightening rust removing agent

Publications (1)

Publication Number Publication Date
CN106283085A true CN106283085A (en) 2017-01-04

Family

ID=57668156

Family Applications (1)

Application Number Title Priority Date Filing Date
CN201610652318.7A Withdrawn CN106283085A (en) 2016-08-11 2016-08-11 A kind of brightening rust removing agent

Country Status (1)

Country Link
CN (1) CN106283085A (en)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107475726A (en) * 2017-08-30 2017-12-15 南通润德机械科技有限公司 A kind of Development of New Extruder rust remover

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107475726A (en) * 2017-08-30 2017-12-15 南通润德机械科技有限公司 A kind of Development of New Extruder rust remover

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PB01 Publication
WW01 Invention patent application withdrawn after publication
WW01 Invention patent application withdrawn after publication

Application publication date: 20170104