CN106280559A - A kind of insect protected composite calcium carbonate and preparation method thereof - Google Patents
A kind of insect protected composite calcium carbonate and preparation method thereof Download PDFInfo
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- CN106280559A CN106280559A CN201610637505.8A CN201610637505A CN106280559A CN 106280559 A CN106280559 A CN 106280559A CN 201610637505 A CN201610637505 A CN 201610637505A CN 106280559 A CN106280559 A CN 106280559A
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- calcium carbonate
- modifying agent
- preparation
- isooctylthioglycolate
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09C—TREATMENT OF INORGANIC MATERIALS, OTHER THAN FIBROUS FILLERS, TO ENHANCE THEIR PIGMENTING OR FILLING PROPERTIES ; PREPARATION OF CARBON BLACK ; PREPARATION OF INORGANIC MATERIALS WHICH ARE NO SINGLE CHEMICAL COMPOUNDS AND WHICH ARE MAINLY USED AS PIGMENTS OR FILLERS
- C09C1/00—Treatment of specific inorganic materials other than fibrous fillers; Preparation of carbon black
- C09C1/02—Compounds of alkaline earth metals or magnesium
- C09C1/021—Calcium carbonates
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09C—TREATMENT OF INORGANIC MATERIALS, OTHER THAN FIBROUS FILLERS, TO ENHANCE THEIR PIGMENTING OR FILLING PROPERTIES ; PREPARATION OF CARBON BLACK ; PREPARATION OF INORGANIC MATERIALS WHICH ARE NO SINGLE CHEMICAL COMPOUNDS AND WHICH ARE MAINLY USED AS PIGMENTS OR FILLERS
- C09C3/00—Treatment in general of inorganic materials, other than fibrous fillers, to enhance their pigmenting or filling properties
- C09C3/006—Combinations of treatments provided for in groups C09C3/04 - C09C3/12
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09C—TREATMENT OF INORGANIC MATERIALS, OTHER THAN FIBROUS FILLERS, TO ENHANCE THEIR PIGMENTING OR FILLING PROPERTIES ; PREPARATION OF CARBON BLACK ; PREPARATION OF INORGANIC MATERIALS WHICH ARE NO SINGLE CHEMICAL COMPOUNDS AND WHICH ARE MAINLY USED AS PIGMENTS OR FILLERS
- C09C3/00—Treatment in general of inorganic materials, other than fibrous fillers, to enhance their pigmenting or filling properties
- C09C3/06—Treatment with inorganic compounds
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09C—TREATMENT OF INORGANIC MATERIALS, OTHER THAN FIBROUS FILLERS, TO ENHANCE THEIR PIGMENTING OR FILLING PROPERTIES ; PREPARATION OF CARBON BLACK ; PREPARATION OF INORGANIC MATERIALS WHICH ARE NO SINGLE CHEMICAL COMPOUNDS AND WHICH ARE MAINLY USED AS PIGMENTS OR FILLERS
- C09C3/00—Treatment in general of inorganic materials, other than fibrous fillers, to enhance their pigmenting or filling properties
- C09C3/08—Treatment with low-molecular-weight non-polymer organic compounds
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09C—TREATMENT OF INORGANIC MATERIALS, OTHER THAN FIBROUS FILLERS, TO ENHANCE THEIR PIGMENTING OR FILLING PROPERTIES ; PREPARATION OF CARBON BLACK ; PREPARATION OF INORGANIC MATERIALS WHICH ARE NO SINGLE CHEMICAL COMPOUNDS AND WHICH ARE MAINLY USED AS PIGMENTS OR FILLERS
- C09C3/00—Treatment in general of inorganic materials, other than fibrous fillers, to enhance their pigmenting or filling properties
- C09C3/10—Treatment with macromolecular organic compounds
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- Organic Chemistry (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Chemical And Physical Treatments For Wood And The Like (AREA)
Abstract
The invention discloses a kind of insect protected composite calcium carbonate and preparation method thereof, including following raw material: calcium carbonate, modified polyurethane resin, Hydroxylated acrylic resin, montmorillonite powder, barium sulfate, isooctylthioglycolate, eugenol, ethylene glycol, butanol, modifying agent, water are appropriate;Its preparation method comprises the following steps: it is stand-by that (1) prepares premix material;(2) mixed liquor is prepared;(3) modifying agent is prepared;(4) premix material, mixed liquor and modifying agent are mixed, stir, grind, dry, be ground into superfines and get final product.The present invention, by being combined by the combination property preferably materials such as calcium carbonate and barium sulfate, modified polyurethane resin, Hydroxylated acrylic resin, isooctylthioglycolate, improves production technology, uses modifying agent etc. to effectively increase the insect protected performance of compositions;Its production technology is simple, and with short production cycle, steady quality, production cost is low, and using value is higher.
Description
Technical field
The present invention relates to industrial filler field, particularly relate to a kind of insect protected composite calcium carbonate and preparation method thereof.
Background technology
Calcium carbonate is a kind of inorganic compound, CaCO3It is commonly called as: lime stone, limestone, stone powder, marble etc., be by calcium ion
Combining with carbanion and to generate, be the important functional inorganic filling of a class, industrial purposes is very wide, has price low
Honest and clean, rich reserves, stable performance, easily processing, the advantage such as nontoxic, it is possible to significantly improve drawing abillity, physical property
And reduce production cost etc., it is widely used in the fields such as plastics, rubber, coating, papermaking.
In the application of calcium carbonate, most products belongs to the category of polymer, but, calcium carbonate particle surface distributed
There is the hydroxyl of strongly hydrophilic, show as alkalescence, different with the interfacial property of organic polymer host material, poor compatibility, it is difficult to
Host material it is uniformly dispersed and forms strong adhesion with host material, causing the boundary defect between two materials, make
Some mechanical properties decrease of composite.It is thus desirable to change the performance of tradition calcium carbonate product, improve its application performance with full
Foot new material, the needs of development of new techniques, be calcium carbonate industry urgent problem.
Summary of the invention
It is an object of the invention to, it is provided that a kind of insect protected composite calcium carbonate and preparation method thereof, by by combination property relatively
Good material is combined, and improves production technology, uses modifying agent etc. to effectively increase the insect protected performance of compositions.
To achieve these goals, the technical solution used in the present invention is as follows:
A kind of insect protected composite calcium carbonate and preparation method thereof, including the raw material of following weight portion: calcium carbonate 50~80 parts, change
Property polyurethane resin 2~4 parts, Hydroxylated acrylic resin 1~3 parts, montmorillonite powder 1~3 parts, barium sulfate 3~5 parts, ethyl thioglycollic acid
Different monooctyl ester 4~6 parts, eugenol 2~3 parts, ethylene glycol 1~1.5 parts, butanol 1~2 parts, modifying agent 5~8 parts, water are fitted
Amount;Wherein said modifying agent is made up of the raw material of following weight portion: nano titanium oxide 30~50 parts, bamboo charcoal powder 2~4 parts, penta
Dialdehyde 3~5 parts, acrylate and vinyl acetate emulsion 2~5 parts, alkyl quaternary ammonium salts 1~3 parts, disodium hydrogen phosphate 3~5 parts, butanone 2~4 parts;
Its preparation method comprises the following steps:
(1) calcium carbonate, modified polyurethane resin, Hydroxylated acrylic resin, montmorillonite powder mix homogeneously are added sand mill
In, it is ground to 300~400 mesh, obtains premix material stand-by;
(2) putting in batch mixer by barium sulfate, isooctylthioglycolate, eugenol, be warming up to 75~85 DEG C, mixing is stirred
Mix half an hour, be subsequently adding ethylene glycol, butanol, be continuously heating to 120~140 DEG C, stir, obtain mixed liquor;
(3) nano titanium oxide, bamboo charcoal powder, glutaraldehyde, acrylate and vinyl acetate emulsion are added suitable quantity of water stirring, and be warming up to 75~85
DEG C, it being stirring evenly and then adding into alkyl quaternary ammonium salts, disodium hydrogen phosphate, butanone, continue to be heated to 120~140 DEG C, mix and blend is equal
Even, obtain modifying agent;
(4) mixed liquor that the premix material that step (1) obtained, step (2) obtain and the modifying agent that step (3) obtains mix
Close, stir, grind, dry, be ground into superfines and get final product.
The invention have the benefit that
The present invention is by by different pungent to calcium carbonate and barium sulfate, modified polyurethane resin, Hydroxylated acrylic resin, ethyl thioglycollic acid
The combination properties such as ester preferably material is combined, and improves production technology, uses modifying agent etc. to effectively increase compositions
Insect protected performance;Production technology of the present invention is simple, and production process is environment friendly and pollution-free, it is achieved that making full use of of resource and the energy, raw
The product cycle is short, steady quality, and production cost is low, and using value is higher.
Detailed description of the invention:
With specific embodiment, technical scheme is described below, but protection scope of the present invention is not limited to this:
Embodiment 1:
A kind of insect protected composite calcium carbonate and preparation method thereof, including the raw material of following weight portion: calcium carbonate 50 parts, modification gather
Urethane resin 2 parts, Hydroxylated acrylic resin 1 part, montmorillonite powder 1 part, 3 parts of barium sulfate, isooctylthioglycolate 4 parts, Oleum Caryophylli
2 parts of phenol, ethylene glycol 1 part, 1 part of butanol, modifying agent 5 parts, water are appropriate;Wherein said modifying agent is by the raw material of following weight portion
Make: nano titanium oxide 30 parts, bamboo charcoal powder 2 parts, glutaraldehyde 3 parts, acrylate and vinyl acetate emulsion 2 parts, alkyl quaternary ammonium salts 1 part, phosphoric acid hydrogen two
3 parts of sodium, butanone 2 parts;
Its preparation method comprises the following steps:
(1) calcium carbonate, modified polyurethane resin, Hydroxylated acrylic resin, montmorillonite powder mix homogeneously are added sand mill
In, it is ground to 300~400 mesh, obtains premix material stand-by;
(2) barium sulfate, isooctylthioglycolate, eugenol are put in batch mixer, be warming up to 75 DEG C, mix and blend half
Hour, it is subsequently adding ethylene glycol, butanol, is continuously heating to 140 DEG C, stirs, obtain mixed liquor;
(3) nano titanium oxide, bamboo charcoal powder, glutaraldehyde, acrylate and vinyl acetate emulsion are added suitable quantity of water stirring, and be warming up to 85 DEG C, stir
Add alkyl quaternary ammonium salts, disodium hydrogen phosphate, butanone after mixing uniformly, continue to be heated to 120 DEG C, mixing and stirring, obtain modified
Agent;
(4) mixed liquor that the premix material that step (1) obtained, step (2) obtain and the modifying agent that step (3) obtains mix
Close, stir, grind, dry, be ground into superfines and get final product.
Embodiment 2:
A kind of insect protected composite calcium carbonate and preparation method thereof, including the raw material of following weight portion: calcium carbonate 80 parts, modification gather
Urethane resin 4 parts, Hydroxylated acrylic resin 3 parts, montmorillonite powder 3 parts, 5 parts of barium sulfate, isooctylthioglycolate 6 parts, Oleum Caryophylli
3 parts of phenol, ethylene glycol 1.5 parts, 2 parts of butanol, modifying agent 8 parts, water are appropriate;Wherein said modifying agent is former by following weight portion
Material is made: nano titanium oxide 50 parts, bamboo charcoal powder 4 parts, glutaraldehyde 5 parts, acrylate and vinyl acetate emulsion 5 parts, alkyl quaternary ammonium salts 3 parts, phosphoric acid hydrogen
Disodium 5 parts, butanone 4 parts;
Its preparation method comprises the following steps:
(1) calcium carbonate, modified polyurethane resin, Hydroxylated acrylic resin, montmorillonite powder mix homogeneously are added sand mill
In, it is ground to 300~400 mesh, obtains premix material stand-by;
(2) barium sulfate, isooctylthioglycolate, eugenol are put in batch mixer, be warming up to 85 DEG C, mix and blend half
Hour, it is subsequently adding ethylene glycol, butanol, is continuously heating to 120 DEG C, stirs, obtain mixed liquor;
(3) nano titanium oxide, bamboo charcoal powder, glutaraldehyde, acrylate and vinyl acetate emulsion are added suitable quantity of water stirring, and be warming up to 75 DEG C, stir
Add alkyl quaternary ammonium salts, disodium hydrogen phosphate, butanone after mixing uniformly, continue to be heated to 140 DEG C, mixing and stirring, obtain modified
Agent;
(4) mixed liquor that the premix material that step (1) obtained, step (2) obtain and the modifying agent that step (3) obtains mix
Close, stir, grind, dry, be ground into superfines and get final product.
Above example is only in order to illustrate technical scheme, rather than limiting the scope of the invention, although
Make to explain to the present invention with reference to preferred embodiment, it will be understood by those within the art that, can be to this
Bright technical scheme is modified or equivalent, without deviating from the spirit and scope of technical solution of the present invention.
Claims (1)
1. insect protected composite calcium carbonate and preparation method thereof, it is characterised in that include the raw material of following weight portion: calcium carbonate 50
~80 parts, modified polyurethane resin 2~4 parts, Hydroxylated acrylic resin 1~3 parts, montmorillonite powder 1~3 parts, barium sulfate 3~5 parts,
Isooctylthioglycolate 4~6 parts, eugenol 2~3 parts, ethylene glycol 1~1.5 parts, butanol 1~2 parts, modifying agent 5~8
Part, water appropriate;Wherein said modifying agent is made up of the raw material of following weight portion: nano titanium oxide 30~50 parts, bamboo charcoal powder 2~
4 parts, glutaraldehyde 3~5 parts, acrylate and vinyl acetate emulsion 2~5 parts, alkyl quaternary ammonium salts 1~3 parts, disodium hydrogen phosphate 3~5 parts, butanone 2~4
Part;
Its preparation method comprises the following steps:
(1) calcium carbonate, modified polyurethane resin, Hydroxylated acrylic resin, montmorillonite powder mix homogeneously are added in sand mill, grind
It is milled to 300~400 mesh, obtains premix material stand-by;
(2) barium sulfate, isooctylthioglycolate, eugenol are put in batch mixer, be warming up to 75~85 DEG C, mix and blend half
Hour, it is subsequently adding ethylene glycol, butanol, is continuously heating to 120~140 DEG C, stirs, obtain mixed liquor;
(3) nano titanium oxide, bamboo charcoal powder, glutaraldehyde, acrylate and vinyl acetate emulsion are added suitable quantity of water stirring, and be warming up to 75~85 DEG C, stir
Add alkyl quaternary ammonium salts, disodium hydrogen phosphate, butanone after mixing uniformly, continue to be heated to 120~140 DEG C, mixing and stirring,
Modifying agent;
(4) mixed liquor that the premix material that step (1) obtained, step (2) obtain and the modifying agent mixing that step (3) obtains, stir
Mix uniformly, grind, dry, be ground into superfines and get final product.
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CN201610637505.8A CN106280559A (en) | 2016-08-05 | 2016-08-05 | A kind of insect protected composite calcium carbonate and preparation method thereof |
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CN201610637505.8A CN106280559A (en) | 2016-08-05 | 2016-08-05 | A kind of insect protected composite calcium carbonate and preparation method thereof |
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Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP2401340A1 (en) * | 2009-02-26 | 2012-01-04 | Arkema, Inc. | Composite polymer modifiers |
CN104130595A (en) * | 2014-07-01 | 2014-11-05 | 青阳县永诚钙业有限责任公司 | Antibacterial insect-preventing modified calcium carbonate and preparation method thereof |
CN104987755A (en) * | 2015-06-05 | 2015-10-21 | 安徽雪城超细碳酸钙有限公司 | Modified calcium carbonate with good mildew-resistant and insect-preventing effects and preparation method thereof |
-
2016
- 2016-08-05 CN CN201610637505.8A patent/CN106280559A/en active Pending
Patent Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP2401340A1 (en) * | 2009-02-26 | 2012-01-04 | Arkema, Inc. | Composite polymer modifiers |
CN104130595A (en) * | 2014-07-01 | 2014-11-05 | 青阳县永诚钙业有限责任公司 | Antibacterial insect-preventing modified calcium carbonate and preparation method thereof |
CN104987755A (en) * | 2015-06-05 | 2015-10-21 | 安徽雪城超细碳酸钙有限公司 | Modified calcium carbonate with good mildew-resistant and insect-preventing effects and preparation method thereof |
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Application publication date: 20170104 |
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