CN106280124A - The formula of a kind of PVC glove and production technology thereof - Google Patents

The formula of a kind of PVC glove and production technology thereof Download PDF

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Publication number
CN106280124A
CN106280124A CN201610747809.XA CN201610747809A CN106280124A CN 106280124 A CN106280124 A CN 106280124A CN 201610747809 A CN201610747809 A CN 201610747809A CN 106280124 A CN106280124 A CN 106280124A
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CN
China
Prior art keywords
parts
pvc glove
pvc
thinner
petiolus trachycarpi
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201610747809.XA
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Chinese (zh)
Inventor
池永涛
王艳婷
郑淑春
于洋洋
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SHANDONG YINGKE MEDICAL PRODUCT Co Ltd
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SHANDONG YINGKE MEDICAL PRODUCT Co Ltd
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Priority to CN201610747809.XA priority Critical patent/CN106280124A/en
Publication of CN106280124A publication Critical patent/CN106280124A/en
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    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00Use of organic ingredients
    • AHUMAN NECESSITIES
    • A41WEARING APPAREL
    • A41DOUTERWEAR; PROTECTIVE GARMENTS; ACCESSORIES
    • A41D19/00Gloves
    • A41D19/015Protective gloves
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00Use of organic ingredients
    • C08K5/04Oxygen-containing compounds
    • C08K5/10Esters; Ether-esters
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00Use of organic ingredients
    • C08K5/04Oxygen-containing compounds
    • C08K5/10Esters; Ether-esters
    • C08K5/12Esters; Ether-esters of cyclic polycarboxylic acids

Abstract

The present invention proposes formula and the production technology thereof of a kind of PVC glove, includes following components by weight: PVC paste resin 48 parts 52 parts, DOTP plasticizer 29 parts 31 parts, Ca Zn stabilizer 0.8 part 1.2 parts, thinner 10 parts 13 parts and Petiolus Trachycarpi grease 68 parts.PVC glove production technology, comprises the steps: to prepare plasticized paste;Plasticized paste squeezes into standing tank;Plasticized paste squeezes into secondary material agitator tank, opens blender, rotating speed, puts into thinner, regulates viscosity, continuously stirred;Plasticized paste squeezes into Debubbling tank, vacuum defoamation;Plasticized paste squeezes into singlehanded mould PVC glove production line and both hands mould PVC glove production line, carries out PVC glove production.The present invention, on the premise of ensureing PVC glove quality, reduces PVC glove production cost.

Description

The formula of a kind of PVC glove and production technology thereof
Technical field
The present invention relates to PVC glove production technical field, especially relate to the formula of a kind of PVC glove and produce work Skill.
Background technology
Along with developing rapidly of economic construction, the self-protection consciousness of people strengthens, and health, convenient becomes living habit. Nowadays, PVC glove is good as protection effect in disposable protective gloves, without anaphylactogen, the one of low cost, in the world It is widely used in the industries such as medical treatment and nursing, food processing, food and drink, daily cleaning, printing and dyeing, laboratory and electronic product machining, Especially Systems in Certain Developed Countries, area, its application is universal just as paper extraction.This continues to bring out out cost in just promoting global range Less expensive, use higher PVC glove product more convenient, functional.
At present, China's Mainland has become as the PVC glove production base in the world, is the world's topmost PVC glove supply Area.Along with progress and the gradual perfection of supporting industries of modern petrochemical technology, and not the turning off of New-type adjuvant product Sending out application, the scale production process of PVC glove reaches its maturity, and PVC glove manufacturing enterprise constantly seeks ensureing PVC glove product The method reducing PVC glove production cost on the premise of matter.
The method reducing PVC glove production cost mainly includes two aspects, and one is that large-scale production cost reduces, and two are The cost of raw material reduces.In terms of cost of raw material reduction, most common method is just introduced into new raw material.Available new raw material has BASF DINCH series, citrate series, epoxy aliphatic acid methyl ester series etc..But, BASF DINCH series, citric acid Ester series is relatively costly, and epoxy aliphatic acid methyl ester exists, with PVC paste resin, the problem that the compatibility is bad.
Summary of the invention
For overcoming the deficiency in above manufacturing technique method, it is an object of the invention to provide a kind of PVC glove formula and Its production technology, on the premise of ensureing PVC glove quality, reduces PVC glove production cost.
A kind of technical scheme of the present invention is achieved in that
The formula of a kind of PVC glove, includes following components by weight: PVC paste resin 48 parts-52 parts, DOTP plasticising Agent 29 parts-31 parts, Ca-Zn stabilizer 0.8 part-1.2 parts, thinner 10 parts-13 parts and Petiolus Trachycarpi grease 6-8 part.
As the preferred technical scheme of one, include following components by weight: PVC paste resin 48 parts, DOTP plasticising Agent 29 parts, Ca-Zn stabilizer 0.8 part, thinner 10 parts and Petiolus Trachycarpi grease 6 parts.
As the preferred technical scheme of one, include following components by weight: PVC paste resin 50 parts, DOTP plasticising Agent 30 parts, Ca-Zn stabilizer 1 part, thinner 12 parts and Petiolus Trachycarpi grease 7.5 parts.
As the preferred technical scheme of one, include following components by weight: PVC paste resin 52 parts, DOTP plasticising Agent 31 parts, Ca-Zn stabilizer 1.2 parts, thinner 13 parts and Petiolus Trachycarpi grease 6-8 part.
As the preferred technical scheme of one, described Petiolus Trachycarpi grease is modified Petiolus Trachycarpi grease, and its modified technique is Petiolus Trachycarpi oil Ester passes through flash-point more than 205 DEG C, and boiling point more than 235 DEG C, ebuillition of heated, when temperature reaches 240 DEG C, liquid color does not become black green Color, obtains modified Petiolus Trachycarpi grease.
As the preferred technical scheme of one, described thinner is thinner D70.
The another kind of technical scheme of the present invention is achieved in that the production technology of a kind of PVC glove, including walking as follows Rapid:
(1) preparation plasticized paste, specifically includes following steps;
1. according to parts by weight, put into DOTP plasticizer and Petiolus Trachycarpi grease at a defective material agitator tank, open blender, rotating speed It is set as 0.8kr/min-0.9kr/min;
2. according to parts by weight, PVC paste resin, continuously stirred 2h-2.5h, rotating speed 1.2kr/min-1.4kr/min are put into;
3. according to parts by weight, Ca-Zn stabilizer, continuously stirred 1h-1.5h are put into;
4. according to parts by weight, thinner, continuously stirred 2h-2.5h are put into;
(2) plasticized paste squeezes into standing tank, stands 24h-48h;
(3) plasticized paste squeezes into secondary material agitator tank, opens blender, rotating speed 0.8kr/min-0.9kr/min, puts into viscosity reduction Agent, regulates viscosity, continuously stirred 2h-2.5h;
(4) plasticized paste squeezes into Debubbling tank, vacuum defoamation;
(5) plasticized paste squeezes into singlehanded mould PVC glove production line and both hands mould PVC glove production line, carries out PVC glove raw Produce.
As the preferred technical scheme of one, described Petiolus Trachycarpi grease is modified Petiolus Trachycarpi grease, and its modified technique is Petiolus Trachycarpi oil Ester passes through flash-point more than 205 DEG C, and boiling point more than 235 DEG C, ebuillition of heated, when temperature reaches 240 DEG C, liquid color does not become black green Color, obtains modified Petiolus Trachycarpi grease.
As the preferred technical scheme of one, described thinner is thinner D70.
Have employed technique scheme, the invention have the benefit that
Good with PVC paste resin, DOTP plasticizer, Ca-Zn stabilizer and the thinner compatibility through modified Petiolus Trachycarpi grease Good, the PVC glove produced is best in quality, and because the cost of Petiolus Trachycarpi grease own is the lowest so that the raw material of PVC glove becomes Originally it is greatly lowered, improves the PVC glove competitiveness of product in market.
Detailed description of the invention
Below in conjunction with the embodiment of the present invention, the technical scheme in the embodiment of the present invention is clearly and completely described, Obviously, described embodiment is only a part of embodiment of the present invention rather than whole embodiments.Based in the present invention Embodiment, the every other embodiment that those of ordinary skill in the art are obtained under not making creative work premise, all Belong to the scope of protection of the invention.
Embodiment 1
The formula of a kind of PVC glove, includes following components by weight: PVC paste resin 48 parts, DOTP plasticizer 29 Part, Ca-Zn stabilizer 0.8 part, D70 thinner 10 parts and Petiolus Trachycarpi grease 6 parts.
Embodiment 2
The formula of a kind of PVC glove, includes following components by weight: PVC paste resin 50 parts, DOTP plasticizer 30 Part, Ca-Zn stabilizer 1 part, D70 thinner 12 parts and Petiolus Trachycarpi grease 7.5 parts.
Embodiment 3
The formula of a kind of PVC glove, includes following components by weight: PVC paste resin 52 parts, DOTP plasticizer 31 Part, Ca-Zn stabilizer 1.2 parts, D70 thinner 13 parts and Petiolus Trachycarpi grease 6-8 part.
Embodiment 4
The formula of a kind of PVC glove, includes following components by weight: PVC paste resin 50 parts, DOTP plasticizer 30 Part, Ca-Zn stabilizer 1 part, D70 thinner 12 parts and Petiolus Trachycarpi grease 7.5 parts.Petiolus Trachycarpi grease is modified Petiolus Trachycarpi grease, and it is modified Technique is that Petiolus Trachycarpi grease passes through flash-point more than 205 DEG C, and boiling point more than 235 DEG C, ebuillition of heated, temperature reaches liquid face when 240 DEG C Color does not become blackish green, obtains modified Petiolus Trachycarpi grease.
Embodiment 5
The production technology of a kind of PVC glove, comprises the steps:
(1) preparation plasticized paste, specifically includes following steps;
1. according to the parts by weight proportioning of embodiment 1, put into DOTP plasticizer and Petiolus Trachycarpi grease at a defective material agitator tank, open Opening blender, speed setting is 0.8kr/min;
2. according to the parts by weight proportioning of embodiment 1, PVC paste resin, continuously stirred 2h, rotating speed 1.2kr/min are put into;
3. according to the parts by weight proportioning of embodiment 1, Ca-Zn stabilizer, continuously stirred 1h are put into;
4. according to the parts by weight proportioning of embodiment 1, thinner, continuously stirred 2h are put into;
(2) plasticized paste squeezes into standing tank, stands 24h;
(3) plasticized paste squeezes into secondary material agitator tank, opens blender, rotating speed 0.8kr/min, puts into thinner, and regulation is viscous Degree, continuously stirred 2h;
(4) plasticized paste squeezes into Debubbling tank, vacuum defoamation;
(5) plasticized paste squeezes into singlehanded mould PVC glove production line and both hands mould PVC glove production line, carries out PVC glove raw Produce.
Embodiment 6
The production technology of a kind of PVC glove, comprises the steps:
(1) preparation plasticized paste, specifically includes following steps;
1. according to the parts by weight proportioning of embodiment 2, put into DOTP plasticizer and Petiolus Trachycarpi grease at a defective material agitator tank, open Opening blender, speed setting is 0.85kr/min;
2. according to the parts by weight proportioning of embodiment 2, PVC paste resin, continuously stirred 2.2h, rotating speed 1.3kr/min are put into;
3. according to the parts by weight proportioning of embodiment 2, Ca-Zn stabilizer, continuously stirred 1.2h are put into;
4. according to the parts by weight proportioning of embodiment 2, thinner, continuously stirred 2.2h are put into;
(2) plasticized paste squeezes into standing tank, stands 36h;
(3) plasticized paste squeezes into secondary material agitator tank, opens blender, rotating speed 0.85kr/min, puts into thinner, and regulation is viscous Degree, continuously stirred 2.2h;
(4) plasticized paste squeezes into Debubbling tank, vacuum defoamation;
(5) plasticized paste squeezes into singlehanded mould PVC glove production line and both hands mould PVC glove production line, carries out PVC glove raw Produce.
Embodiment 7
The production technology of a kind of PVC glove, comprises the steps:
(1) preparation plasticized paste, specifically includes following steps;
1. according to the parts by weight proportioning of embodiment 3, put into DOTP plasticizer and Petiolus Trachycarpi grease at a defective material agitator tank, open Opening blender, speed setting is 0.8kr/min;
2. according to the parts by weight proportioning of embodiment 3, PVC paste resin, continuously stirred 2h, rotating speed 1.2kr/min are put into;
3. according to the parts by weight proportioning of embodiment 3, Ca-Zn stabilizer, continuously stirred 1h are put into;
4. according to the parts by weight proportioning of embodiment 3, thinner, continuously stirred 2.5h are put into;
(2) plasticized paste squeezes into standing tank, stands 48h;
(3) plasticized paste squeezes into secondary material agitator tank, opens blender, rotating speed 0.9kr/min, puts into thinner, and regulation is viscous Degree, continuously stirred 2h;
(4) plasticized paste squeezes into Debubbling tank, vacuum defoamation;
(5) plasticized paste squeezes into singlehanded mould PVC glove production line and both hands mould PVC glove production line, carries out PVC glove raw Produce.
Embodiment 8
The production technology of a kind of PVC glove, comprises the steps:
(1) preparation plasticized paste, specifically includes following steps;
1. according to the parts by weight proportioning of embodiment 4, put into DOTP plasticizer and Petiolus Trachycarpi grease at a defective material agitator tank, open Opening blender, speed setting is 0.9kr/min;
2. according to the parts by weight proportioning of embodiment 4, PVC paste resin, continuously stirred 2.5h, rotating speed 1.4kr/min are put into;
3. according to the parts by weight proportioning of embodiment 4, Ca-Zn stabilizer, continuously stirred 1.5h are put into;
4. according to the parts by weight proportioning of embodiment 4, thinner, continuously stirred 2.5h are put into;
(2) plasticized paste squeezes into standing tank, stands 48h;
(3) plasticized paste squeezes into secondary material agitator tank, opens blender, rotating speed 0.9kr/min, puts into thinner, and regulation is viscous Degree, continuously stirred 2.5h;
(4) plasticized paste squeezes into Debubbling tank, vacuum defoamation;
(5) plasticized paste squeezes into singlehanded mould PVC glove production line and both hands mould PVC glove production line, carries out PVC glove raw Produce.
By above-described embodiment, its performance test data are as shown in the table:
Physical data
Embodiment Tensile strength/MPa Elongation percentage/%
Embodiment 1 22.0 483.5
Embodiment 2 22.3 485.3
Embodiment 3 23.1 496.3
Embodiment 4 22.6 490.5
The foregoing is only presently preferred embodiments of the present invention, not in order to limit the present invention, all essences in the present invention Within god and principle, any modification, equivalent substitution and improvement etc. made, should be included within the scope of the present invention.

Claims (9)

1. the formula of a PVC glove, it is characterised in that include following components by weight: PVC paste resin 48 parts-52 parts, DOTP plasticizer 29 parts-31 parts, Ca-Zn stabilizer 0.8 part-1.2 parts, thinner 10 parts-13 parts and Petiolus Trachycarpi grease 6-8 part.
Formula in a kind of PVC glove the most as claimed in claim 1, it is characterised in that include following components by weight: PVC paste resin 48 parts, DOTP plasticizer 29 parts, Ca-Zn stabilizer 0.8 part, thinner 10 parts and Petiolus Trachycarpi grease 6 parts.
Formula in a kind of PVC glove the most as claimed in claim 1, it is characterised in that include following components by weight: PVC paste resin 50 parts, DOTP plasticizer 30 parts, Ca-Zn stabilizer 1 part, thinner 12 parts and Petiolus Trachycarpi grease 7.5 parts.
Formula in a kind of PVC glove the most as claimed in claim 1, it is characterised in that include following components by weight: PVC paste resin 52 parts, DOTP plasticizer 31 parts, Ca-Zn stabilizer 1.2 parts, thinner 13 parts and Petiolus Trachycarpi grease 6-8 part.
Formula in a kind of PVC glove the most as claimed in claim 1, it is characterised in that described Petiolus Trachycarpi grease is modified Petiolus Trachycarpi Grease, its modified technique is that Petiolus Trachycarpi grease passes through flash-point more than 205 DEG C, and boiling point more than 235 DEG C, ebuillition of heated, temperature reaches 240 DEG C time liquid color do not become blackish green, obtain modified Petiolus Trachycarpi grease.
Formula in a kind of PVC glove the most as claimed in claim 1, it is characterised in that described thinner is thinner D70.
7. the production technology producing PVC glove described in claim 1, it is characterised in that comprise the steps:
(1) preparation plasticized paste, specifically includes following steps;
1. according to parts by weight, put into DOTP plasticizer and Petiolus Trachycarpi grease at a defective material agitator tank, open blender, speed setting For 0.8kr/min-0.9kr/min;
2. according to parts by weight, PVC paste resin, continuously stirred 2h-2.5h, rotating speed 1.2kr/min-1.4kr/min are put into;
3. according to parts by weight, Ca-Zn stabilizer, continuously stirred 1h-1.5h are put into;
4. according to parts by weight, thinner, continuously stirred 2h-2.5h are put into;
(2) plasticized paste squeezes into standing tank, stands 24h-48h;
(3) plasticized paste squeezes into secondary material agitator tank, opens blender, rotating speed 0.8kr/min-0.9kr/min, puts into thinner, Regulation viscosity, continuously stirred 2h-2.5h;
(4) plasticized paste squeezes into Debubbling tank, vacuum defoamation;
(5) plasticized paste squeezes into singlehanded mould PVC glove production line and both hands mould PVC glove production line, carries out PVC glove production.
A kind of production technology producing PVC glove described in claim 1, it is characterised in that described Petiolus Trachycarpi grease is modified Petiolus Trachycarpi grease, and its modified technique is that Petiolus Trachycarpi grease passes through flash-point more than 205 DEG C, and boiling point more than 235 DEG C adds Heat boiling, when temperature reaches 240 DEG C, liquid color does not become blackish green, obtains modified Petiolus Trachycarpi grease.
A kind of production technology producing PVC glove described in claim 1, it is characterised in that described Thinner is thinner D70.
CN201610747809.XA 2016-08-29 2016-08-29 The formula of a kind of PVC glove and production technology thereof Pending CN106280124A (en)

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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108192236A (en) * 2017-12-29 2018-06-22 山东蓝帆新材料有限公司 A kind of disposable photodegradable PVC glove and preparation method thereof
CN111234421A (en) * 2020-03-31 2020-06-05 安徽和佳医疗用品科技有限公司 PVC gloves with antibacterial function and preparation method thereof

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102504437A (en) * 2011-10-19 2012-06-20 江南大学 Preparation method of environmentally-friendly disposable polyvinyl chloride glove
CN103724858A (en) * 2012-10-15 2014-04-16 无锡新亚安全用品有限公司 Method for preparing soft disposable PVC (polyvinyl chloride) gloves
CN105778331A (en) * 2016-03-14 2016-07-20 江苏华源手套有限公司 Antistatic environmentally-friendly bamboo charcoal polyvinyl chloride gloves and shaping technology thereof

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102504437A (en) * 2011-10-19 2012-06-20 江南大学 Preparation method of environmentally-friendly disposable polyvinyl chloride glove
CN103724858A (en) * 2012-10-15 2014-04-16 无锡新亚安全用品有限公司 Method for preparing soft disposable PVC (polyvinyl chloride) gloves
CN105778331A (en) * 2016-03-14 2016-07-20 江苏华源手套有限公司 Antistatic environmentally-friendly bamboo charcoal polyvinyl chloride gloves and shaping technology thereof

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108192236A (en) * 2017-12-29 2018-06-22 山东蓝帆新材料有限公司 A kind of disposable photodegradable PVC glove and preparation method thereof
CN108192236B (en) * 2017-12-29 2020-10-30 山东蓝帆新材料有限公司 Disposable photodegradable PVC (polyvinyl chloride) glove and preparation method thereof
CN111234421A (en) * 2020-03-31 2020-06-05 安徽和佳医疗用品科技有限公司 PVC gloves with antibacterial function and preparation method thereof
CN111234421B (en) * 2020-03-31 2021-11-02 安徽和佳医疗用品科技有限公司 PVC gloves with antibacterial function and preparation method thereof

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