CN106280102A - A kind of Plant fiber strengthens composite plastic - Google Patents

A kind of Plant fiber strengthens composite plastic Download PDF

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Publication number
CN106280102A
CN106280102A CN201610688620.8A CN201610688620A CN106280102A CN 106280102 A CN106280102 A CN 106280102A CN 201610688620 A CN201610688620 A CN 201610688620A CN 106280102 A CN106280102 A CN 106280102A
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China
Prior art keywords
parts
powder
composite plastic
wood
plant fiber
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CN201610688620.8A
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Chinese (zh)
Inventor
张复光
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Tongcheng City Hong Ye Plastic Co Ltd
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Tongcheng City Hong Ye Plastic Co Ltd
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Priority to CN201610688620.8A priority Critical patent/CN106280102A/en
Publication of CN106280102A publication Critical patent/CN106280102A/en
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    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L27/00Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers
    • C08L27/02Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers not modified by chemical after-treatment
    • C08L27/04Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers not modified by chemical after-treatment containing chlorine atoms
    • C08L27/06Homopolymers or copolymers of vinyl chloride
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L1/00Compositions of cellulose, modified cellulose or cellulose derivatives
    • C08L1/02Cellulose; Modified cellulose
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K2201/00Specific properties of additives
    • C08K2201/011Nanostructured additives
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K2201/00Specific properties of additives
    • C08K2201/014Additives containing two or more different additives of the same subgroup in C08K
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00Polymer mixtures characterised by other features
    • C08L2205/02Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00Polymer mixtures characterised by other features
    • C08L2205/02Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
    • C08L2205/025Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group containing two or more polymers of the same hierarchy C08L, and differing only in parameters such as density, comonomer content, molecular weight, structure
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00Polymer mixtures characterised by other features
    • C08L2205/14Polymer mixtures characterised by other features containing polymeric additives characterised by shape
    • C08L2205/16Fibres; Fibrils

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  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Dry Formation Of Fiberboard And The Like (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
  • Chemical And Physical Treatments For Wood And The Like (AREA)

Abstract

nullThe open a kind of Plant fiber of the present invention strengthens composite plastic,By weight,Including following raw material components: Corvic 50 60 parts、40 65 parts of arghan base、Calcium carbonate 8 15 parts、Carboxyethyl cellulose 10 20 parts、Nano imvite 79 parts、Basalt fibre 35 45 parts、The wood fiber 60 65 parts、Methylisothiazolinone 3.5 4.5 parts、Camphorwood powder 24 parts、Spine stem wood powder 24 parts、Eaglewood powder 0.1 0.2 parts、Melamine cyanurate salt 9 13 parts、Carborundum powder 8 10 parts、Sodium carboxymethyl cellulose 14 20 parts、Meerschaum 37 parts、10 20 parts of asbestos powder、Tributyl 2-acetylcitrate 13 15 parts、Diethylene glycol ether acetate alone 23 parts、Magnesium stearate 12 parts、3 hydroxy benzoic acids 46 parts、Diethylenetriamine 46 parts、Palladous nitrate. 0.2 0.4 parts、Yttrium oxide 0.2 0.4 parts、23 parts of gelatin.The advantages such as it is higher that the composite plastic of the present invention has environmental protection, dimensionally stable, hot strength and impact strength, with low cost.

Description

A kind of Plant fiber strengthens composite plastic
Technical field
The present invention relates to field of material technology, specifically a kind of Plant fiber strengthens composite plastic.
Background technology
Igelite is formed by polymerization of vinyl choride monomer, is one of conventional thermoplastic.Its commodity Referred to as " chlorine is moulded ", english abbreviation is PVC to title.
Pure Corvic is hard thermoplastic, and its decomposition temperature is very close to plasticization temperature, Er Qieji Tool intensity is poor.Therefore, it is impossible to mould product processed with Corvic, it is necessary to add plasticizer, stabilizer, filler etc. to change Kind performance, makes igelite, is then reprocessed into various product.
Natural plant fibre resource is extensive, of a great variety, the master related at composite material of plant fiber area research at present The stem stalk fiber etc. of bast-fibre to be had, bamboo fiber, bagasse fibre, coir and other plant, and the wood fiber Application in field of compound material is still in blank out, and therefore, exploitation Wood Fiber Composites has the most wide answering Use prospect.
In recent years, owing to waste plastic " white pollution " brought that be difficult to degrade is on the rise, cause global extensively General concern, countries in the world have put into effect the relevant laws and regulations limiting or prohibitting the use of non-degradable plastic packing article successively.On the other hand, by Non-renewable resources in manufacturing the raw material oil of conventional plastic, along with a large amount of use of the mankind will be exhausted, thus development with Renewable resource is that raw material, degradable environmental friendliness plastic are extremely urgent.
Summary of the invention
It is an object of the invention to provide a kind of Plant fiber and strengthen composite plastic.
The purpose of the present invention can be achieved through the following technical solutions:
A kind of Plant fiber strengthens composite plastic, by weight, including following raw material components: Corvic 50- 60 parts, arghan base 40-65 part, calcium carbonate 8-15 part, carboxyethyl cellulose 10-20 part, nano imvite 7-9 part, profound Military rock fiber 35-45 part, wood fiber 60-65 part, Methylisothiazolinone 3.5-4.5 part, camphorwood powder 2-4 part, spine stem wood powder 2-4 part, eaglewood powder 0.1-0.2 part, melamine cyanurate salt 9-13 part, carborundum powder 8-10 part, sodium carboxymethyl cellulose 14-20 part, meerschaum 3-7 part, asbestos powder 10-20 part, tributyl 2-acetylcitrate 13-15 part, diethylene glycol monoethyl ether acetic acid Ester 2-3 part, magnesium stearate 1-2 part, 3-hydroxy benzoic acid 4-6 part, diethylenetriamine 4-6 part, Palladous nitrate. 0.2-0.4 part, three oxygen Change two yttrium 0.2-0.4 parts, gelatin 2-3 part.
Preferably, described a kind of Plant fiber strengthens composite plastic, by weight, including following raw material components: poly- Vinyl chloride resin 50 parts, 40 parts of arghan base, calcium carbonate 8 parts, carboxyethyl cellulose 10 parts, nano imvite 7 parts, the Black Warrior Rock fiber 35 parts, the wood fiber 60 parts, Methylisothiazolinone 3.5 parts, camphorwood powder 2 parts, spine stem wood powder 2 parts, eaglewood powder 0.1 Part, melamine cyanurate salt 9 parts, carborundum powder 8 parts, sodium carboxymethyl cellulose 14 parts, meerschaum 3 parts, 10 parts of asbestos powder, second Acyl tributyl citrate 13 parts, diethylene glycol ether acetate alone 2 parts, magnesium stearate 1 part, 3-hydroxy benzoic acid 4 parts, divinyl Triamine 4 parts, Palladous nitrate. 0.2 part, yttrium oxide 0.2 part, 2 parts of gelatin.
Preferably, described a kind of Plant fiber strengthens composite plastic, by weight, including following raw material components: poly- Vinyl chloride resin 60 parts, 65 parts of arghan base, calcium carbonate 15 parts, carboxyethyl cellulose 20 parts, nano imvite 9 parts, profound Military rock fiber 45 parts, the wood fiber 65 parts, Methylisothiazolinone 4.5 parts, camphorwood powder 4 parts, spine stem wood powder 4 parts, eaglewood powder 0.2 part, melamine cyanurate salt 13 parts, carborundum powder 10 parts, sodium carboxymethyl cellulose 20 parts, meerschaum 7 parts, asbestos powder 20 Part, tributyl 2-acetylcitrate 15 parts, diethylene glycol ether acetate alone 3 parts, magnesium stearate 2 parts, 3-hydroxy benzoic acid 6 parts, Diethylenetriamine 6 parts, Palladous nitrate. 0.4 part, yttrium oxide 0.4 part, 3 parts of gelatin.
Preferably, described a kind of Plant fiber strengthens composite plastic, by weight, including following raw material components: poly- Vinyl chloride resin 55 parts, 50 parts of arghan base, calcium carbonate 10 parts, carboxyethyl cellulose 15 parts, nano imvite 8 parts, profound Military rock fiber 35 parts, the wood fiber 60 parts, Methylisothiazolinone 4 parts, camphorwood powder 3 parts, spine stem wood powder 3 parts, eaglewood powder 0.2 Part, melamine cyanurate salt 12 parts, carborundum powder 9 parts, sodium carboxymethyl cellulose 15 parts, meerschaum 4 parts, 15 parts of asbestos powder, Tributyl 2-acetylcitrate 14 parts, diethylene glycol ether acetate alone 2 parts, magnesium stearate 1 part, 3-hydroxy benzoic acid 5 parts, diethyl Alkene triamine 5 parts, Palladous nitrate. 0.4 part, yttrium oxide 0.4 part, 3 parts of gelatin.
Beneficial effects of the present invention: the composite plastic of the present invention has environmental protection, dimensionally stable, hot strength and impact strength Higher, the advantage such as with low cost.
Detailed description of the invention
Below in conjunction with specific embodiment, the present invention is described in further detail.
Embodiment 1
A kind of Plant fiber strengthens composite plastic, by weight, including following raw material components: Corvic 50 Part, 40 parts of arghan base, calcium carbonate 8 parts, carboxyethyl cellulose 10 parts, nano imvite 7 parts, basalt fibre 35 parts, The wood fiber 60 parts, Methylisothiazolinone 3.5 parts, camphorwood powder 2 parts, spine stem wood powder 2 parts, eaglewood powder 0.1 part, cyanuric acid three 9 parts of paracyanogen amine salt, carborundum powder 8 parts, sodium carboxymethyl cellulose 14 parts, meerschaum 3 parts, 10 parts of asbestos powder, acetyl tributyl citrate three Butyl ester 13 parts, diethylene glycol ether acetate alone 2 parts, magnesium stearate 1 part, 3-hydroxy benzoic acid 4 parts, diethylenetriamine 4 parts, nitre Acid palladium 0.2 part, yttrium oxide 0.2 part, 2 parts of gelatin.
The preparation method of the present invention is same as the prior art.
Embodiment 2
A kind of Plant fiber strengthens composite plastic, by weight, including following raw material components: Corvic 60 Part, 65 parts of arghan base, calcium carbonate 15 parts, carboxyethyl cellulose 20 parts, nano imvite 9 parts, basalt fibre 45 parts, The wood fiber 65 parts, Methylisothiazolinone 4.5 parts, camphorwood powder 4 parts, spine stem wood powder 4 parts, eaglewood powder 0.2 part, cyanuric acid three 13 parts of paracyanogen amine salt, carborundum powder 10 parts, sodium carboxymethyl cellulose 20 parts, meerschaum 7 parts, 20 parts of asbestos powder, acetyl tributyl citrate Tributyl 15 parts, diethylene glycol ether acetate alone 3 parts, magnesium stearate 2 parts, 3-hydroxy benzoic acid 6 parts, diethylenetriamine 6 parts, Palladous nitrate. 0.4 part, yttrium oxide 0.4 part, 3 parts of gelatin.
The preparation method of the present invention is same as the prior art.
Embodiment 3
A kind of Plant fiber strengthens composite plastic, by weight, including following raw material components: Corvic 55 Part, 50 parts of arghan base, calcium carbonate 10 parts, carboxyethyl cellulose 15 parts, nano imvite 8 parts, basalt fibre 35 parts, The wood fiber 60 parts, Methylisothiazolinone 4 parts, camphorwood powder 3 parts, spine stem wood powder 3 parts, eaglewood powder 0.2 part, cyanuric acid trimerization Cyanamide salt 12 parts, carborundum powder 9 parts, sodium carboxymethyl cellulose 15 parts, meerschaum 4 parts, 15 parts of asbestos powder, acetyl tributyl citrate three fourth Ester 14 parts, diethylene glycol ether acetate alone 2 parts, magnesium stearate 1 part, 3-hydroxy benzoic acid 5 parts, diethylenetriamine 5 parts, nitric acid Palladium 0.4 part, yttrium oxide 0.4 part, 3 parts of gelatin.
The preparation method of the present invention is same as the prior art.

Claims (4)

1. a Plant fiber strengthens composite plastic, it is characterised in that by weight, including following raw material components: polychlorostyrene second Olefine resin 50-60 part, arghan base 40-65 part, calcium carbonate 8-15 part, carboxyethyl cellulose 10-20 part, nano imvite 7-9 part, basalt fibre 35-45 part, wood fiber 60-65 part, Methylisothiazolinone 3.5-4.5 part, camphorwood powder 2-4 part, spine Stem wood powder 2-4 part, eaglewood powder 0.1-0.2 part, melamine cyanurate salt 9-13 part, carborundum powder 8-10 part, carboxymethyl Sodium cellulosate 14-20 part, meerschaum 3-7 part, asbestos powder 10-20 part, tributyl 2-acetylcitrate 13-15 part, diethylene glycol list Ethyl ether acetate ester 2-3 part, magnesium stearate 1-2 part, 3-hydroxy benzoic acid 4-6 part, diethylenetriamine 4-6 part, Palladous nitrate. 0.2-0.4 Part, yttrium oxide 0.2-0.4 part, gelatin 2-3 part.
A kind of Plant fiber the most according to claim 1 strengthens composite plastic, it is characterised in that by weight, including Following raw material components: Corvic 50 parts, 40 parts of arghan base, calcium carbonate 8 parts, carboxyethyl cellulose 10 parts, receive Rice montmorillonite 7 parts, basalt fibre 35 parts, the wood fiber 60 parts, Methylisothiazolinone 3.5 parts, camphorwood powder 2 parts, spine stem wood 2 parts of powder, eaglewood powder 0.1 part, melamine cyanurate salt 9 parts, carborundum powder 8 parts, sodium carboxymethyl cellulose 14 parts, meerschaum 3 parts, 10 parts of asbestos powder, tributyl 2-acetylcitrate 13 parts, diethylene glycol ether acetate alone 2 parts, magnesium stearate 1 part, 3-hydroxyl Yl benzoic acid 4 parts, diethylenetriamine 4 parts, Palladous nitrate. 0.2 part, yttrium oxide 0.2 part, 2 parts of gelatin.
A kind of Plant fiber the most according to claim 1 strengthens composite plastic, it is characterised in that by weight, including Following raw material components: Corvic 60 parts, 65 parts of arghan base, calcium carbonate 15 parts, carboxyethyl cellulose 20 parts, receive Rice montmorillonite 9 parts, basalt fibre 45 parts, the wood fiber 65 parts, Methylisothiazolinone 4.5 parts, camphorwood powder 4 parts, spine stem wood 4 parts of powder, eaglewood powder 0.2 part, melamine cyanurate salt 13 parts, carborundum powder 10 parts, sodium carboxymethyl cellulose 20 parts, Hai Pao 7 parts of stone, 20 parts of asbestos powder, tributyl 2-acetylcitrate 15 parts, diethylene glycol ether acetate alone 3 parts, magnesium stearate 2 parts, 3- Hydroxy benzoic acid 6 parts, diethylenetriamine 6 parts, Palladous nitrate. 0.4 part, yttrium oxide 0.4 part, 3 parts of gelatin.
A kind of Plant fiber the most according to claim 1 strengthens composite plastic, it is characterised in that by weight, including Following raw material components: Corvic 55 parts, 50 parts of arghan base, calcium carbonate 10 parts, carboxyethyl cellulose 15 parts, receive Rice montmorillonite 8 parts, basalt fibre 35 parts, the wood fiber 60 parts, Methylisothiazolinone 4 parts, camphorwood powder 3 parts, spine stem wood powder 3 Part, eaglewood powder 0.2 part, melamine cyanurate salt 12 parts, carborundum powder 9 parts, sodium carboxymethyl cellulose 15 parts, meerschaum 4 Part, 15 parts of asbestos powder, tributyl 2-acetylcitrate 14 parts, diethylene glycol ether acetate alone 2 parts, magnesium stearate 1 part, 3-hydroxyl 5 parts of benzoic acid, diethylenetriamine 5 parts, Palladous nitrate. 0.4 part, yttrium oxide 0.4 part, 3 parts of gelatin.
CN201610688620.8A 2016-08-18 2016-08-18 A kind of Plant fiber strengthens composite plastic Pending CN106280102A (en)

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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107523079A (en) * 2017-09-05 2017-12-29 桐城市弘业塑胶有限公司 A kind of yarn splits anti-collision foam screen sheath material
CN107746523A (en) * 2017-11-02 2018-03-02 安徽嘉中金属材料有限公司 A kind of environment-friendly PVC composite for building and preparation method thereof

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101367977A (en) * 2008-08-15 2009-02-18 黄山华塑新材料科技有限公司 PVC fine foaming wood-plastic coiled material and method of preparing the same
CN102942797A (en) * 2012-10-17 2013-02-27 广西大学 Plant fiber wood-plastic composite material and preparation method thereof
CN104341692A (en) * 2014-09-30 2015-02-11 大连环美科技集团有限公司 Nanometer calcium carbonate-reinforced ecological wood material and preparation method thereof

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101367977A (en) * 2008-08-15 2009-02-18 黄山华塑新材料科技有限公司 PVC fine foaming wood-plastic coiled material and method of preparing the same
CN102942797A (en) * 2012-10-17 2013-02-27 广西大学 Plant fiber wood-plastic composite material and preparation method thereof
CN104341692A (en) * 2014-09-30 2015-02-11 大连环美科技集团有限公司 Nanometer calcium carbonate-reinforced ecological wood material and preparation method thereof

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107523079A (en) * 2017-09-05 2017-12-29 桐城市弘业塑胶有限公司 A kind of yarn splits anti-collision foam screen sheath material
CN107746523A (en) * 2017-11-02 2018-03-02 安徽嘉中金属材料有限公司 A kind of environment-friendly PVC composite for building and preparation method thereof

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