CN106279836A - A kind of automotive friction material - Google Patents

A kind of automotive friction material Download PDF

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Publication number
CN106279836A
CN106279836A CN201610668578.3A CN201610668578A CN106279836A CN 106279836 A CN106279836 A CN 106279836A CN 201610668578 A CN201610668578 A CN 201610668578A CN 106279836 A CN106279836 A CN 106279836A
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China
Prior art keywords
parts
friction material
hours
warming
sorghum
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CN201610668578.3A
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Chinese (zh)
Inventor
何沂桂
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Guangxi Nanning Shengqian Technology Development Co Ltd
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Guangxi Nanning Shengqian Technology Development Co Ltd
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Priority to CN201610668578.3A priority Critical patent/CN106279836A/en
Publication of CN106279836A publication Critical patent/CN106279836A/en
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    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L9/00Compositions of homopolymers or copolymers of conjugated diene hydrocarbons
    • C08L9/06Copolymers with styrene
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F16ENGINEERING ELEMENTS AND UNITS; GENERAL MEASURES FOR PRODUCING AND MAINTAINING EFFECTIVE FUNCTIONING OF MACHINES OR INSTALLATIONS; THERMAL INSULATION IN GENERAL
    • F16DCOUPLINGS FOR TRANSMITTING ROTATION; CLUTCHES; BRAKES
    • F16D13/00Friction clutches
    • F16D13/58Details
    • F16D13/60Clutching elements
    • F16D13/64Clutch-plates; Clutch-lamellae
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F16ENGINEERING ELEMENTS AND UNITS; GENERAL MEASURES FOR PRODUCING AND MAINTAINING EFFECTIVE FUNCTIONING OF MACHINES OR INSTALLATIONS; THERMAL INSULATION IN GENERAL
    • F16DCOUPLINGS FOR TRANSMITTING ROTATION; CLUTCHES; BRAKES
    • F16D69/00Friction linings; Attachment thereof; Selection of coacting friction substances or surfaces
    • F16D69/02Composition of linings ; Methods of manufacturing
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2201/00Properties
    • C08L2201/08Stabilised against heat, light or radiation or oxydation
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00Polymer mixtures characterised by other features
    • C08L2205/03Polymer mixtures characterised by other features containing three or more polymers in a blend

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  • Engineering & Computer Science (AREA)
  • General Engineering & Computer Science (AREA)
  • Mechanical Engineering (AREA)
  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Compositions Of Macromolecular Compounds (AREA)

Abstract

The invention discloses a kind of automotive friction material, including the component of following parts by weight: butadiene-styrene rubber 60~70 parts, glass fibre 10~20 parts, composite fibre 10~20 parts, polypropylene 5~10 parts, silicone oil 5~10 parts, sorghum stalk activated carbon powder 10~15 parts, Pulvis Talci 5~10 parts, molybdenum bisuphide 5~10 parts, fire retardant 2~5 parts and three vanadium oxides 1~2 parts.The re-optimization of the present invention combination formula of current friction material, and take full advantage of the by-product sorghum stalk of Sorghum vulgare Pers., carried out carbonization, graphitization, make activated carbon powder, succedaneum as natural graphite powder joins in friction material, effectively reducing the production cost of friction material, that widens sorghum stalk utilizes channel, improves the economic benefit of sorghum stalk.

Description

A kind of automotive friction material
Technical field
The present invention relates to a kind of automotive friction material.
Background technology
Friction material is widely used in various transport facility (such as automobile, train, aircraft etc.) and various plant equipment Brake, clutch and friction gearing in brake material.It is broadly divided into brake liner by the position of function and installation Sheet and clutch surface.Friction material belongs to crucial safety member in the automotive industry, the startup of automobile, braking and parking all from Not opening friction material, the quality of friction material, quality can the people's lives and property safety by direct relation, and its function status is not sayed And explain.But traditional Automotive Friction Material exists some defects, such as asbestos Automotive Friction Material, because asbestos are a kind of natural Mineral fibres, it has higher thermostability and mechanical strength, but asbestos have certain danger to health.Because of this person The friction material without asbestos that begins one's study, the component formula of friction material is adjusted, improves, select composite fibre Or metallic fiber etc..
It addition, along with industrialized development, the usage amount of friction material is increasing, the usage amount of its filler---graphite Also it is to increase year by year.But the price of native graphite is the highest, people also begin to the succedaneum to native graphite and carry out Further investigation.
Sorghum vulgare Pers., Latin literary fame: Sorghum bicolor (L.) Moench grass family, sorghum annual herb are planted Thing.Stalk is more sturdy, and uprightly, the upper tool of base portion joint supports root.Sheath is without hair or slightly white lead;Tip of a leaf dura mater matter, tip circle, edge has Cilium.[1] property happiness is warm, drought resisting, waterlogging.Grain sorghum, the sugar class such as Sorghum vulgare Pers., broom sorghum can be divided into by character and purposes. Chinese cultivated is relatively wide, is most with various places, northeast.Grain sorghum grain is edible, wine brewing.After harvesting Sorghum vulgare Pers., can produce a large amount of By-product---sorghum stalk.Generally people's processing mode is directly to burn, although this mode has carried out certain utilization to it, But it is big to burn the flue dust produced, and pollutes environment to a certain extent.And containing a large amount of carbon sources in sorghum stalk, if using Sorghum vulgare Pers. The carbon dust that stalk is made replaces graphite and adds in friction material, will greatly reduce the production cost of friction material.
Summary of the invention
It is an object of the invention to provide a kind of automotive friction material.The re-optimization of the present invention group of current friction material Close formula, and take full advantage of the by-product of Sorghum vulgare Pers.---sorghum stalk, carried out carbonization, graphitization, made activated carbon powder, Succedaneum as natural graphite powder joins in friction material, effectively reduces the production cost of friction material, widens Sorghum vulgare Pers. Stalk utilize channel, improve the economic benefit of sorghum stalk.
To achieve these goals, present invention employs techniques below scheme:
A kind of automotive friction material, including the component of following parts by weight: butadiene-styrene rubber 60~70 parts, glass fibre 10~20 Part, composite fibre 10~20 parts, polypropylene 5~10 parts, silicone oil 5~10 parts, sorghum stalk activated carbon powder 10~15 parts, Pulvis Talci 5 ~10 parts, molybdenum bisuphide 5~10 parts, fire retardant 2~5 parts and three vanadium oxides 1~2 parts.
As the scheme that the present invention is further preferred, this automotive friction material, including the component of following parts by weight: butylbenzene Rubber 65 parts, glass fibre 15 parts, composite fibre 15 parts, polypropylene 7 parts, silicone oil 8 parts, sorghum stalk activated carbon powder 13 parts, Talcum 7 parts of powder, molybdenum bisuphide 7 parts, fire retardant 3 parts and three vanadium oxides 1 part.
Further illustrate, described sorghum stalk activated carbon powder be by the most cleaned for sorghum stalk drying, pulverize briquet, The carbon dust obtained after carbonization treatment, graphitization processing.
Further illustrating, described carbonization treatment carries out carbonization treatment particularly as follows: sorghum stalk block is put into oxygen deprivation stove;Humidity discharging Phase rises to 150 DEG C from igniting to furnace temperature, and the time is 5 hours;Then heat to 250 DEG C, open aerator, to air blast in stove, The primary carbided time is 4 hours, and aerator leaves 30 minutes, stops 30 minutes, circulates 4 times;Being warming up to 500 DEG C, the heating-up time is 2 little Time, after temperature rises to 500 DEG C, it being incubated 2 hours, then be warming up to 650 DEG C, the heating-up time is 4 hours, when being warming up to 650 DEG C, air blast Machine leaves 1 hour, stops 1 hour, circulates 2 times, then is warming up to 850 DEG C, after 1 hour, opens ventilation blower, sends into air and water vapour, Progressively cool down, generate carbon, come out of the stove after 6 hours.
Further illustrating, described graphitization processing, particularly as follows: put in graphitizing furnace after the carbon cooling after coming out of the stove, is entered Row graphitization processing;First it is warming up to 350 DEG C with the speed of 2 DEG C/min, pressurising 4MPa, then heat up with the speed of 1 DEG C/min 550 DEG C, it is incubated 2 hours, then under argon shield, is warming up to 2500 DEG C carries out graphitization, then naturally cool to room temperature, then grind Make the carbon dust of 200 mesh.
Fire retardant in the present invention uses the aluminium hydroxide type fire retardant generally sold on market.Add a small amount of Three vanadium oxides can effectively improve the intensity of friction material.
Advantages of the present invention:
1. the combination matching of composition is optimized by the automotive friction material of the present invention, has good thermostability, wearability, No longer use asbestos component, environment protection health.
2. raw material sources are extensive, production cost is low;Take full advantage of the by-product of Sorghum vulgare Pers. plant husbandry---sorghum stalk, by it Carrying out carbonization, graphitization, make people's activated carbon powder, the succedaneum as natural graphite powder joins in friction material, effectively drops The low production cost of friction material, improves the economic benefit of sorghum stalk.The activated carbon powder made with sorghum stalk, can as filler To increase the toughness of friction material, promote its performance and braking effect, stable friction factor, the noise produced when reducing friction And it is environment friendly and pollution-free.
Detailed description of the invention
Below in conjunction with embodiment, the present invention is further described.
Embodiment 1:
A kind of automotive friction material, including the component of following parts by weight: 60 parts of butadiene-styrene rubber, glass fibre 10 parts, compound fibre Tie up 10 parts, polypropylene 5 parts, silicone oil 5 parts, sorghum stalk activated carbon powder 10 parts, Pulvis Talci 5 parts, molybdenum bisuphide 5 parts, fire retardant 2 parts and Three vanadium oxides 1 part.
Described sorghum stalk activated carbon powder is by the most cleaned for sorghum stalk drying, pulverizes briquet, carbonization treatment, stone The carbon dust that inkization obtains after processing.Described carbonization treatment is particularly as follows: put into oxygen deprivation stove by sorghum stalk block and carry out at carbonization Reason;The humidity discharging phase rises to 150 DEG C from igniting to furnace temperature, and the time is 5 hours;Then heat to 250 DEG C, open aerator, to stove Interior air blast, the primary carbided time is 4 hours, and aerator leaves 30 minutes, stops 30 minutes, circulates 4 times;It is warming up to 500 DEG C, during intensification Between be 2 hours, after temperature rises to 500 DEG C, be incubated 2 hours, then be warming up to 650 DEG C, the heating-up time is 4 hours, is warming up to 650 DEG C Time, aerator leaves 1 hour, stops 1 hour, circulates 2 times, then is warming up to 850 DEG C, after 1 hour, opens ventilation blower, send into air and Water vapour, progressively cools down, and generates carbon, comes out of the stove after 6 hours.Described graphitization processing is particularly as follows: after the carbon cooling after coming out of the stove Put in graphitizing furnace, carry out graphitization processing;First it is warming up to 350 DEG C with the speed of 2 DEG C/min, pressurising 4MPa, then with 1 DEG C/min speed heat up 550 DEG C, be incubated 2 hours, then under argon shield, is warming up to 2500 DEG C carries out graphitization, more naturally It is cooled to room temperature, is then milled into the carbon dust of 200 mesh.
Embodiment 2:
A kind of automotive friction material, including the component of following parts by weight: 70 parts of butadiene-styrene rubber, glass fibre 20 parts, compound fibre Tie up 20 parts, polypropylene 10 parts, silicone oil 10 parts, sorghum stalk activated carbon powder 15 parts, Pulvis Talci 10 parts, molybdenum bisuphide 10 parts, fire retardant 5 Part and three vanadium oxide 2 parts.
Described sorghum stalk activated carbon powder is by the most cleaned for sorghum stalk drying, pulverizes briquet, carbonization treatment, stone The carbon dust that inkization obtains after processing.Described carbonization treatment is particularly as follows: put into oxygen deprivation stove by sorghum stalk block and carry out at carbonization Reason;The humidity discharging phase rises to 150 DEG C from igniting to furnace temperature, and the time is 5 hours;Then heat to 250 DEG C, open aerator, to stove Interior air blast, the primary carbided time is 4 hours, and aerator leaves 30 minutes, stops 30 minutes, circulates 4 times;It is warming up to 500 DEG C, during intensification Between be 2 hours, after temperature rises to 500 DEG C, be incubated 2 hours, then be warming up to 650 DEG C, the heating-up time is 4 hours, is warming up to 650 DEG C Time, aerator leaves 1 hour, stops 1 hour, circulates 2 times, then is warming up to 850 DEG C, after 1 hour, opens ventilation blower, send into air and Water vapour, progressively cools down, and generates carbon, comes out of the stove after 6 hours.Described graphitization processing is particularly as follows: after the carbon cooling after coming out of the stove Put in graphitizing furnace, carry out graphitization processing;First it is warming up to 350 DEG C with the speed of 2 DEG C/min, pressurising 4MPa, then with 1 DEG C/min speed heat up 550 DEG C, be incubated 2 hours, then under argon shield, is warming up to 2500 DEG C carries out graphitization, more naturally It is cooled to room temperature, is then milled into the carbon dust of 200 mesh.
Embodiment 3:
A kind of automotive friction material, including the component of following parts by weight: 65 parts of butadiene-styrene rubber, glass fibre 15 parts, compound fibre Tie up 15 parts, polypropylene 7 parts, silicone oil 8 parts, sorghum stalk activated carbon powder 13 parts, Pulvis Talci 7 parts, molybdenum bisuphide 7 parts, fire retardant 3 parts and Three vanadium oxides 1 part.
Described sorghum stalk activated carbon powder is by the most cleaned for sorghum stalk drying, pulverizes briquet, carbonization treatment, stone The carbon dust that inkization obtains after processing.Described carbonization treatment is particularly as follows: put into oxygen deprivation stove by sorghum stalk block and carry out at carbonization Reason;The humidity discharging phase rises to 150 DEG C from igniting to furnace temperature, and the time is 5 hours;Then heat to 250 DEG C, open aerator, to stove Interior air blast, the primary carbided time is 4 hours, and aerator leaves 30 minutes, stops 30 minutes, circulates 4 times;It is warming up to 500 DEG C, during intensification Between be 2 hours, after temperature rises to 500 DEG C, be incubated 2 hours, then be warming up to 650 DEG C, the heating-up time is 4 hours, is warming up to 650 DEG C Time, aerator leaves 1 hour, stops 1 hour, circulates 2 times, then is warming up to 850 DEG C, after 1 hour, opens ventilation blower, send into air and Water vapour, progressively cools down, and generates carbon, comes out of the stove after 6 hours.Described graphitization processing is particularly as follows: after the carbon cooling after coming out of the stove Put in graphitizing furnace, carry out graphitization processing;First it is warming up to 350 DEG C with the speed of 2 DEG C/min, pressurising 4MPa, then with 1 DEG C/min speed heat up 550 DEG C, be incubated 2 hours, then under argon shield, is warming up to 2500 DEG C carries out graphitization, more naturally It is cooled to room temperature, is then milled into the carbon dust of 200 mesh.

Claims (5)

1. an automotive friction material, it is characterised in that include the component of following parts by weight: butadiene-styrene rubber 60~70 parts, glass Glass fiber 10~20 parts, composite fibre 10~20 parts, polypropylene 5~10 parts, silicone oil 5~10 parts, sorghum stalk activated carbon powder 10~ 15 parts, Pulvis Talci 5~10 parts, molybdenum bisuphide 5~10 parts, fire retardant 2~5 parts and three vanadium oxides 1~2 parts.
Automotive friction material the most according to claim 1, it is characterised in that include the component of following parts by weight: butylbenzene Rubber 65 parts, glass fibre 15 parts, composite fibre 15 parts, polypropylene 7 parts, silicone oil 8 parts, sorghum stalk activated carbon powder 13 parts, Talcum 7 parts of powder, molybdenum bisuphide 7 parts, fire retardant 3 parts and three vanadium oxides 1 part.
Automotive friction material the most according to claim 1 and 2, it is characterised in that: described sorghum stalk activated carbon powder be by The carbon dust obtained after the most cleaned drying of sorghum stalk, pulverizing briquet, carbonization treatment, graphitization processing.
Automotive friction material the most according to claim 3, it is characterised in that: described carbonization treatment is particularly as follows: by Sorghum vulgare Pers. Stalk block is put into oxygen deprivation stove and is carried out carbonization treatment;The humidity discharging phase rises to 150 DEG C from igniting to furnace temperature, and the time is 5 hours;Then heat up To 250 DEG C, opening aerator, to air blast in stove, the primary carbided time is 4 hours, and aerator leaves 30 minutes, stops 30 minutes, follows Ring 4 times;Being warming up to 500 DEG C, the heating-up time is 2 hours, after temperature rises to 500 DEG C, is incubated 2 hours, then is warming up to 650 DEG C, rises The temperature time is 4 hours, and when being warming up to 650 DEG C, aerator leaves 1 hour, stops 1 hour, circulates 2 times, then is warming up to 850 DEG C, 1 hour After, open ventilation blower, send into air and water vapour, progressively cool down, generate carbon, come out of the stove after 6 hours.
Automotive friction material the most according to claim 4, it is characterised in that: described graphitization processing is particularly as follows: handle goes out Put in graphitizing furnace after the carbon cooling of furnace rear, carry out graphitization processing;First it is warming up to 350 DEG C with the speed of 2 DEG C/min, Pressurising 4MPa, then heat up 550 DEG C with the speed of 1 DEG C/min, is incubated 2 hours, then is warming up to 2500 DEG C under argon shield and carries out Graphitization, then naturally cool to room temperature, then it is milled into the carbon dust of 200 mesh.
CN201610668578.3A 2016-08-16 2016-08-16 A kind of automotive friction material Pending CN106279836A (en)

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Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103939511A (en) * 2014-05-04 2014-07-23 中国矿业大学 Formula and manufacturing method for car soft magnetic brake pad
CN104696399A (en) * 2015-02-11 2015-06-10 江苏金麦穗新能源科技股份有限公司 Rice and wheat straw active carbon powder artificial graphite friction material brake pad and manufacturing method thereof
CN104803375A (en) * 2015-02-11 2015-07-29 江苏金麦穗新能源科技股份有限公司 Preparation method of rice and wheat straw active carbon powder synthetic graphite friction material

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103939511A (en) * 2014-05-04 2014-07-23 中国矿业大学 Formula and manufacturing method for car soft magnetic brake pad
CN104696399A (en) * 2015-02-11 2015-06-10 江苏金麦穗新能源科技股份有限公司 Rice and wheat straw active carbon powder artificial graphite friction material brake pad and manufacturing method thereof
CN104803375A (en) * 2015-02-11 2015-07-29 江苏金麦穗新能源科技股份有限公司 Preparation method of rice and wheat straw active carbon powder synthetic graphite friction material

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