CN106279808A - A kind of marine communication cable material with excellent mechanical performance - Google Patents
A kind of marine communication cable material with excellent mechanical performance Download PDFInfo
- Publication number
- CN106279808A CN106279808A CN201610768524.4A CN201610768524A CN106279808A CN 106279808 A CN106279808 A CN 106279808A CN 201610768524 A CN201610768524 A CN 201610768524A CN 106279808 A CN106279808 A CN 106279808A
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- parts
- crystalline flake
- flake graphite
- clay
- communication cable
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L7/00—Compositions of natural rubber
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
- C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L23/04—Homopolymers or copolymers of ethene
- C08L23/08—Copolymers of ethene
- C08L23/0846—Copolymers of ethene with unsaturated hydrocarbons containing other atoms than carbon or hydrogen atoms
- C08L23/0853—Vinylacetate
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01B—CABLES; CONDUCTORS; INSULATORS; SELECTION OF MATERIALS FOR THEIR CONDUCTIVE, INSULATING OR DIELECTRIC PROPERTIES
- H01B7/00—Insulated conductors or cables characterised by their form
- H01B7/17—Protection against damage caused by external factors, e.g. sheaths or armouring
- H01B7/18—Protection against damage caused by wear, mechanical force or pressure; Sheaths; Armouring
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01B—CABLES; CONDUCTORS; INSULATORS; SELECTION OF MATERIALS FOR THEIR CONDUCTIVE, INSULATING OR DIELECTRIC PROPERTIES
- H01B7/00—Insulated conductors or cables characterised by their form
- H01B7/17—Protection against damage caused by external factors, e.g. sheaths or armouring
- H01B7/28—Protection against damage caused by moisture, corrosion, chemical attack or weather
- H01B7/282—Preventing penetration of fluid, e.g. water or humidity, into conductor or cable
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/011—Nanostructured additives
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/014—Additives containing two or more different additives of the same subgroup in C08K
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2203/00—Applications
- C08L2203/20—Applications use in electrical or conductive gadgets
- C08L2203/202—Applications use in electrical or conductive gadgets use in electrical wires or wirecoating
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
Abstract
The invention discloses a kind of marine communication cable material with excellent mechanical performance, its raw material includes by weight: hydrogenated nitrile-butadiene rubber 10 20 parts, natural rubber 25 45 parts, EVA resin 35 85 parts, nano silicon 4 10 parts, 6 12 parts of flyash, lignin 4 12 parts, clay 45 65 parts, hard (china) clay 10 20 parts, modified crystalline flake graphite 35 55 parts, titanate coupling agent TMC 201 0.5 0.7 parts, maleic anhydride grafted natural rubber 1.5 2.5 parts, tetramethylthiuram disulfide 12 parts, di-t-butyl peroxide 0.8 1.6 parts, magnesium oxide 1.5 2.5 parts, 1.5 2.5 parts of antioxidant, lubricant 13 parts.Water resistance of the present invention is good, and toughness is Jun Heng with hardness, and mechanical property is fabulous.
Description
Technical field
The present invention relates to field of cable technology, particularly relate to a kind of marine communication cable material with excellent mechanical performance.
Background technology
Marine communication cable is owing to being affected by marine harsh conditions for a long time, and it designs, manufacture requirements is the most general
Energising cable, its protective cover material used is maintaining the marine properly functioning aspect of communication cable to play vital effect, marine
The water resistance of communication cable and mechanical property have been largely fixed the length in its service life, in concrete application process
In, protective cover material must be able to the erosion of water, still ensures that it is properly functioning under by strong external force collision simultaneously, how to improve marine logical
The water resistance of news cable becomes to be presently required with mechanical property performance and solves the technical problem that.
Summary of the invention
The technical problem existed based on background technology, the present invention proposes a kind of marine communication with excellent mechanical performance
CABLE MATERIALS, water resistance of the present invention is good, and toughness is Jun Heng with hardness, and mechanical property is fabulous.
A kind of marine communication cable material with excellent mechanical performance that the present invention proposes, its raw material includes by weight:
Hydrogenated nitrile-butadiene rubber 10-20 part, natural rubber 25-45 part, EVA resin 35-85 part, nano silicon 4-10 part, flyash
6-12 part, lignin 4-12 part, clay 45-65 part, hard (china) clay 10-20 part, modified crystalline flake graphite 35-55 part, titanate esters is even
Connection agent TMC-201 0.5-0.7 part, maleic anhydride grafted natural rubber 1.5-2.5 part, tetramethylthiuram disulfide 1-2 part,
Di-t-butyl peroxide 0.8-1.6 part, magnesium oxide 1.5-2.5 part, antioxidant 1.5-2.5 part, lubricant 1-3 part.
Preferably, hydrogenated nitrile-butadiene rubber, natural rubber, EVA resin, tetramethylthiuram disulfide, the tertiary fourth of peroxidating two
Base, the weight ratio of magnesium oxide are 12-18:30-40:40-80:1.5-1.7:1-1.4:1.8-2.2.
Preferably, nano silicon, flyash, lignin, clay, hard (china) clay, modified crystalline flake graphite, titanate esters are occasionally
Connection agent TMC-201, the weight ratio of maleic anhydride grafted natural rubber are 6-8:8-10:6-10:50-60:12-18:40-50:
0.55-0.65:1.8-2.2.
Preferably, its raw material includes by weight: hydrogenated nitrile-butadiene rubber 12-18 part, natural rubber 30-40 part, EVA resin
40-80 part, nano silicon 6-8 part, flyash 8-10 part, lignin 6-10 part, clay 50-60 part, hard (china) clay 12-18
Part, modified crystalline flake graphite 40-50 part, titanate coupling agent TMC-2010.55-0.65 part, maleic anhydride grafted natural rubber
1.8-2.2 part, tetramethylthiuram disulfide 1.5-1.7 part, di-t-butyl peroxide 1-1.4 part, magnesium oxide 1.8-2.2 part,
Antioxidant 1.8-2.2 part, lubricant 1.5-2.5 part.
Preferably, modified crystalline flake graphite uses following technique to prepare: carboxymethyl cellulose, crystalline flake graphite, hydroecium temperature are mixed
Close and stir, heat up, continue stirring, dry, be re-fed into carbonization process under blanket of nitrogen in retort, pulverize, add soybean separation protein
In vain, water mix and blend, add hyaluronic acid, sodium carboxymethyl cellulose mixing and stirring, add glycerol and be uniformly mixing to obtain and change
Property crystalline flake graphite.
Preferably, modified crystalline flake graphite uses following technique to prepare: by weight by 25-45 part carboxymethyl cellulose, 15-
25 parts of crystalline flake graphites, 90-150 part hydroecium temperature mix and blends, heat up, and continues stirring, dries, and is re-fed in retort under blanket of nitrogen
Carbonization processes, and pulverizes, addition 3-7 part soybean protein isolate, 45-65 part water mix and blend, addition 1.5-2.5 part hyaluronic acid,
1.5-2.5 part sodium carboxymethyl cellulose mixing and stirring, add 2-4 part glycerol and be uniformly mixing to obtain modified crystalline flake graphite.
Preferably, modified crystalline flake graphite uses following technique to prepare: by weight by 25-45 part carboxymethyl cellulose, 15-
25 parts of crystalline flake graphites, 90-150 part hydroecium temperature mix and blend 120-160min, be warming up to 80-90 DEG C and continue stirring 35-65min,
110-130 DEG C of drying, is re-fed into carbonization process under blanket of nitrogen in retort, and carbonization temperature is 600-800 DEG C, and carbonization time is
4.5-6.5h, pulverizes, and adds 3-7 part soybean protein isolate, 45-65 part water mix and blend 10-20min, and whipping temp is 90-95
DEG C, adding 1.5-2.5 part hyaluronic acid, 1.5-2.5 part sodium carboxymethyl cellulose mixing and stirring, whipping temp is 60-70
DEG C, add 2-4 part glycerol and be uniformly mixing to obtain modified crystalline flake graphite.
The present invention uses conventional fabrication process to prepare.
The present invention uses EVA resin, natural rubber, hydrogenated nitrile-butadiene rubber and di-t-butyl peroxide, tetramethyl
Thiuram, magnesium oxide carry out mating reaction, and good toughness is the most easy to crack, then with modified crystalline flake graphite mating reaction, can effectively promote
Above-mentioned raw materials is the most dispersed, and water resistance is fabulous with mechanical property；In the modified crystalline flake graphite of the present invention, carboxymethyl cellulose
After element cracking, graphite is coated with, can effectively prevent crystalline flake graphite stratiform from coming off, with the soybean protein isolate of follow-up addition, thoroughly
Bright matter acid not only good dispersion, and mating reaction mechanical property is fabulous, cooperates with sodium carboxymethyl cellulose, it is ensured that product
There is certain hardness and caking property, be eventually adding qs glycerin, and strictly control the addition of glycerol, ensureing modified scale
On the premise of graphite has certain degree of hardness, toughness is fabulous, the most easy to crack, and water resistance is excellent, and resistance to ag(e)ing is good；And it is modified
Crystalline flake graphite and maleic anhydride grafted natural rubber, titanate coupling agent TMC-201 produce cooperative effect, can effectively promote hard
Potter's clay, clay, flyash, lignin, nano silicon and EVA resin, natural rubber, hydrogenated nitrile-butadiene rubber are compatible, mutually
Between mixing uniformity good, mechanical property further enhances, and toughness is Jun Heng with hardness.
Detailed description of the invention
Below, by specific embodiment, technical scheme is described in detail.
Embodiment 1
A kind of marine communication cable material with excellent mechanical performance that the present invention proposes, its raw material includes by weight:
Hydrogenated nitrile-butadiene rubber 10 parts, natural rubber 45 parts, EVA resin 35 parts, nano silicon 10 parts, 6 parts of flyash, lignin 12
Part, clay 45 parts, hard (china) clay 20 parts, modified crystalline flake graphite 35 parts, titanate coupling agent TMC-201 0.7 part, maleic anhydride
Grafted natural rubber 1.5 parts, tetramethylthiuram disulfide 2 parts, di-t-butyl peroxide 0.8 part, magnesium oxide 2.5 parts, antioxygen
Agent 1.5 parts, lubricant 3 parts.
Embodiment 2
A kind of marine communication cable material with excellent mechanical performance that the present invention proposes, its raw material includes by weight:
Hydrogenated nitrile-butadiene rubber 20 parts, natural rubber 25 parts, EVA resin 85 parts, nano silicon 4 parts, 12 parts of flyash, lignin 4
Part, clay 65 parts, hard (china) clay 10 parts, modified crystalline flake graphite 55 parts, titanate coupling agent TMC-201 0.5 part, maleic anhydride
Grafted natural rubber 2.5 parts, tetramethylthiuram disulfide 1 part, di-t-butyl peroxide 1.6 parts, magnesium oxide 1.5 parts, antioxygen
Agent 2.5 parts, lubricant 1 part.
Modified crystalline flake graphite uses following technique to prepare: by carboxymethyl cellulose, crystalline flake graphite, hydroecium temperature mix and blend,
Heat up, continuation stirring, to dry, be re-fed into carbonization process under blanket of nitrogen in retort, pulverize, addition soybean protein isolate, water mix
Close stirring, add hyaluronic acid, sodium carboxymethyl cellulose mixing and stirring, add glycerol and be uniformly mixing to obtain modified scale stone
Ink.
Embodiment 3
A kind of marine communication cable material with excellent mechanical performance that the present invention proposes, its raw material includes by weight:
Hydrogenated nitrile-butadiene rubber 12 parts, natural rubber 40 parts, EVA resin 40 parts, nano silicon 8 parts, 8 parts of flyash, lignin 10
Part, clay 50 parts, hard (china) clay 18 parts, modified crystalline flake graphite 40 parts, titanate coupling agent TMC-201 0.65 part, maleic anhydride
Grafted natural rubber 1.8 parts, tetramethylthiuram disulfide 1.7 parts, di-t-butyl peroxide 1 part, magnesium oxide 2.2 parts, antioxygen
Agent 1.8 parts, lubricant 2.5 parts.
Modified crystalline flake graphite uses following technique to prepare: by weight by 25 parts of carboxymethyl celluloses, 25 parts of crystalline flake graphites,
90 parts of hydroecium temperature mix and blend 160min, are warming up to 80 DEG C and continue stirring 65min, 110 DEG C of drying, be re-fed into nitrogen in retort
Under atmosphere, carbonization processes, and carbonization temperature is 800 DEG C, and carbonization time is 4.5h, pulverizes, and adds 7 parts of soybean protein isolates, 45 parts of water mixed
Closing stirring 20min, whipping temp is 90 DEG C, adds 2.5 parts of hyaluronic acids, 1.5 parts of sodium carboxymethyl cellulose mixing and stirring,
Whipping temp is 70 DEG C, adds 2 parts of glycerol and is uniformly mixing to obtain modified crystalline flake graphite.
Embodiment 4
A kind of marine communication cable material with excellent mechanical performance that the present invention proposes, its raw material includes by weight:
Hydrogenated nitrile-butadiene rubber 18 parts, natural rubber 30 parts, EVA resin 80 parts, nano silicon 6 parts, 10 parts of flyash, lignin 6
Part, clay 60 parts, hard (china) clay 12 parts, modified crystalline flake graphite 50 parts, titanate coupling agent TMC-201 0.55 part, maleic anhydride
Grafted natural rubber 2.2 parts, tetramethylthiuram disulfide 1.5 parts, di-t-butyl peroxide 1.4 parts, magnesium oxide 1.8 parts, anti-
Oxygen agent 2.2 parts, lubricant 1.5 parts.
Modified crystalline flake graphite uses following technique to prepare: by weight by 45 parts of carboxymethyl celluloses, 15 parts of crystalline flake graphites,
150 parts of hydroecium temperature mix and blend 120min, are warming up to 90 DEG C and continue stirring 35min, 130 DEG C of drying, be re-fed into nitrogen in retort
Under atmosphere, carbonization processes, and carbonization temperature is 600 DEG C, and carbonization time is 6.5h, pulverizes, adds 3 parts of soybean protein isolates, 65 parts of water
Mix and blend 10min, whipping temp is 95 DEG C, adds 1.5 parts of hyaluronic acids, 2.5 parts of sodium carboxymethyl cellulose mix and blends equal
Even, whipping temp is 60 DEG C, adds 4 parts of glycerol and is uniformly mixing to obtain modified crystalline flake graphite.
Embodiment 5
A kind of marine communication cable material with excellent mechanical performance that the present invention proposes, its raw material includes by weight:
Hydrogenated nitrile-butadiene rubber 15 parts, natural rubber 35 parts, EVA resin 60 parts, nano silicon 7 parts, 9 parts of flyash, lignin 8
Part, clay 55 parts, hard (china) clay 15 parts, modified crystalline flake graphite 45 parts, titanate coupling agent TMC-201 0.6 part, maleic anhydride
Grafted natural rubber 2 parts, tetramethylthiuram disulfide 1.6 parts, di-t-butyl peroxide 1.2 parts, magnesium oxide 2 parts, antioxidant 2
Part, lubricant 2 parts.
Modified crystalline flake graphite uses following technique to prepare: by weight by 35 parts of carboxymethyl celluloses, 20 parts of crystalline flake graphites,
130 parts of hydroecium temperature mix and blends, heat up, and continue stirring, dry, and are re-fed into carbonization process under blanket of nitrogen in retort, pulverize, add
Enter 5 parts of soybean protein isolates, 55 parts of water mix and blends, add 2 parts of hyaluronic acids, 2 parts of sodium carboxymethyl cellulose mix and blends equal
Even, add 3 parts of glycerol and be uniformly mixing to obtain modified crystalline flake graphite.
The above, the only present invention preferably detailed description of the invention, but protection scope of the present invention is not limited thereto,
Any those familiar with the art in the technical scope that the invention discloses, according to technical scheme and
Inventive concept equivalent or change in addition, all should contain within protection scope of the present invention.
Claims (7)
1. a marine communication cable material with excellent mechanical performance, it is characterised in that its raw material includes by weight: hydrogenation
Nitrile rubber 10-20 part, natural rubber 25-45 part, EVA resin 35-85 part, nano silicon 4-10 part, flyash 6-12
Part, lignin 4-12 part, clay 45-65 part, hard (china) clay 10-20 part, modified crystalline flake graphite 35-55 part, titanate coupling agent
TMC-201 0.5-0.7 part, maleic anhydride grafted natural rubber 1.5-2.5 part, tetramethylthiuram disulfide 1-2 part, peroxide
Change di-t-butyl 0.8-1.6 part, magnesium oxide 1.5-2.5 part, antioxidant 1.5-2.5 part, lubricant 1-3 part.
The most according to claim 1, there is the marine communication cable material of excellent mechanical performance, it is characterised in that hydrogenated butyronitrile rubber
Glue, natural rubber, EVA resin, tetramethylthiuram disulfide, di-t-butyl peroxide, the weight ratio of magnesium oxide are 12-18:
30-40:40-80:1.5-1.7:1-1.4:1.8-2.2.
The marine communication cable material with excellent mechanical performance the most according to claim 1 or claim 2, it is characterised in that nanometer two
Silicon oxide, flyash, lignin, clay, hard (china) clay, modified crystalline flake graphite, titanate coupling agent TMC-201, maleic anhydride
The weight ratio of grafted natural rubber is 6-8:8-10:6-10:50-60:12-18:40-50:0.55-0.65:1.8-2.2.
4. there is according to any one of claim 1-3 the marine communication cable material of excellent mechanical performance, it is characterised in that its
Raw material includes by weight: hydrogenated nitrile-butadiene rubber 12-18 part, natural rubber 30-40 part, EVA resin 40-80 part, nano-silica
SiClx 6-8 part, flyash 8-10 part, lignin 6-10 part, clay 50-60 part, hard (china) clay 12-18 part, modified crystalline flake graphite
40-50 part, titanate coupling agent TMC-201 0.55-0.65 part, maleic anhydride grafted natural rubber 1.8-2.2 part, curing
Tetra methylthiuram 1.5-1.7 part, di-t-butyl peroxide 1-1.4 part, magnesium oxide 1.8-2.2 part, antioxidant 1.8-2.2 part,
Lubricant 1.5-2.5 part.
5. there is according to any one of claim 1-4 the marine communication cable material of excellent mechanical performance, it is characterised in that change
Property crystalline flake graphite use following technique to prepare: by carboxymethyl cellulose, crystalline flake graphite, hydroecium temperature mix and blend, heat up, continue to stir
Mix, dry, be re-fed into carbonization process under blanket of nitrogen in retort, pulverize, add soybean protein isolate, water mix and blend, add
Hyaluronic acid, sodium carboxymethyl cellulose mixing and stirring, add glycerol and be uniformly mixing to obtain modified crystalline flake graphite.
6. there is according to any one of claim 1-5 the marine communication cable material of excellent mechanical performance, it is characterised in that change
Property crystalline flake graphite use following technique prepare: by weight by 25-45 part carboxymethyl cellulose, 15-25 part crystalline flake graphite, 90-
150 parts of hydroecium temperature mix and blends, heat up, and continue stirring, dry, and are re-fed into carbonization process under blanket of nitrogen in retort, pulverize, add
Enter 3-7 part soybean protein isolate, 45-65 part water mix and blend, add 1.5-2.5 part hyaluronic acid, 1.5-2.5 part carboxymethyl fibre
Dimension element sodium mixing and stirring, adds 2-4 part glycerol and is uniformly mixing to obtain modified crystalline flake graphite.
7. there is according to any one of claim 1-3 the marine communication cable material of excellent mechanical performance, it is characterised in that change
Property crystalline flake graphite use following technique prepare: by weight by 25-45 part carboxymethyl cellulose, 15-25 part crystalline flake graphite, 90-
150 parts of hydroecium temperature mix and blend 120-160min, be warming up to 80-90 DEG C continue stirring 35-65min, 110-130 DEG C of drying, then
Sending into carbonization process under blanket of nitrogen in retort, carbonization temperature is 600-800 DEG C, and carbonization time is 4.5-6.5h, pulverizes, and adds
3-7 part soybean protein isolate, 45-65 part water mix and blend 10-20min, whipping temp is 90-95 DEG C, adds 1.5-2.5 part saturating
The acid of bright matter, 1.5-2.5 part sodium carboxymethyl cellulose mixing and stirring, whipping temp is 60-70 DEG C, adds 2-4 part glycerol and stirs
Mix and uniformly obtain modified crystalline flake graphite.
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| CN201610768524.4A CN106279808A (en) | 2016-08-30 | 2016-08-30 | A kind of marine communication cable material with excellent mechanical performance |
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| CN201610768524.4A CN106279808A (en) | 2016-08-30 | 2016-08-30 | A kind of marine communication cable material with excellent mechanical performance |
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Cited By (4)
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| CN107286398A (en) * | 2017-08-01 | 2017-10-24 | 合肥安力电力工程有限公司 | A kind of flame-retardant conductive rubber and preparation method thereof |
| CN107417997A (en) * | 2017-09-29 | 2017-12-01 | 徐州九鼎机电总厂 | A kind of rubber composite of high content graphene |
| CN108239308A (en) * | 2017-11-28 | 2018-07-03 | 安徽华源电缆集团有限公司 | A kind of fire resistant winding cladding cable material |
| CN110591190A (en) * | 2019-09-18 | 2019-12-20 | 周民主 | Environment-friendly wear-resistant cable |
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Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
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| CN107286398A (en) * | 2017-08-01 | 2017-10-24 | 合肥安力电力工程有限公司 | A kind of flame-retardant conductive rubber and preparation method thereof |
| CN107417997A (en) * | 2017-09-29 | 2017-12-01 | 徐州九鼎机电总厂 | A kind of rubber composite of high content graphene |
| CN108239308A (en) * | 2017-11-28 | 2018-07-03 | 安徽华源电缆集团有限公司 | A kind of fire resistant winding cladding cable material |
| CN110591190A (en) * | 2019-09-18 | 2019-12-20 | 周民主 | Environment-friendly wear-resistant cable |
| CN110591190B (en) * | 2019-09-18 | 2021-10-22 | 阳谷鑫辉电缆有限公司 | Environment-friendly wear-resistant cable |
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Application publication date: 20170104 |