CN106279796A - A kind of anti-skidding liberation footwear calendering type black rubber foxing glue - Google Patents
A kind of anti-skidding liberation footwear calendering type black rubber foxing glue Download PDFInfo
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- CN106279796A CN106279796A CN201510358409.5A CN201510358409A CN106279796A CN 106279796 A CN106279796 A CN 106279796A CN 201510358409 A CN201510358409 A CN 201510358409A CN 106279796 A CN106279796 A CN 106279796A
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- China
- Prior art keywords
- skidding
- glue
- liberation footwear
- foxing glue
- foxing
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Abstract
The invention discloses a kind of anti-skidding liberation footwear calendering type black rubber foxing glue, it is characterized in that, calculate in parts by weight, including: standard rubbers 70-90, cis-butadiene cement 10-30, zinc oxide 5-10, stearic acid 1-3, white carbon black 5, industry fat 8-10, anti-aging agent RD 1-3, sulfur 1-1.5, captax 0.8-1.2, altax 1.0-1.5, diphenylguanidine 0.3-0.4, coumarone 4-5, calcium carbonate 110-130.Gum base ingredients use the 70-90 extraordinary standard rubbers of part adhesive force, make foxing glue have good bond properties, can under the motion of high intensity life-time service, situation about will not come unglued；Gum base ingredients uses the 4-5 extraordinary coumarone of part tack, makes foxing glue have good bond properties；Therefore, anti-skidding its adhesive force of liberation footwear and the cohesive that produce with this foxing formula are higher, and the service life of anti-skidding liberation footwear can be greatly improved.
Description
Technical field
The present invention relates to elastomeric material preparation field, relate to footwear limit glue formula, particularly relate to a kind of anti-skidding liberation footwear calendering type black rubber foxing glue.
Background technology
For liberating the foxing glue of footwear limit glue, combination adhesive force of the binding agent glue on upper of a shoe requires higher with sole rubber and brush for it, and tearing strength requires higher, to adapt to activity and the motion of high intensity, it is ensured that limit glue and upper of a shoe do not come unglued, not degumming, without from limit phenomenon.Especially for anti-skidding liberation footwear, foxing glue is not enough due to existing foxing adhesive tension with the combination at the anti-skidding big end, often comes unglued, situation from limit in wearing process.
Summary of the invention
It is an object of the invention to for the deficiencies in the prior art, and a kind of anti-skidding liberation footwear calendering type black rubber foxing glue is provided, its adhesive force of foxing glue produced with this formula is higher, higher with the bonding strength at the anti-skidding big end, wearing process is not susceptible to come unglued, situation from limit, the service life of anti-skidding liberation footwear can be greatly improved.
The technical scheme realizing the object of the invention is:
A kind of anti-skidding liberation footwear calendering type black rubber foxing glue, calculates in parts by weight, including:
Standard rubbers 70-90, cis-butadiene cement 10-30, zinc oxide 5-10, stearic acid 1-3, white carbon black 5, industry fat 8-10, anti-aging agent RD 1-3, sulfur 1-1.5, captax
0.8-1.2, altax
1.0-1.5, diphenylguanidine
0.3-0.4, coumarone
4-5, calcium carbonate 110-130.
Compared with prior art, it is an advantage of the current invention that: gum base ingredients use the 70-90 extraordinary standard rubbers of part adhesive force, make foxing glue have good bond properties, can under the motion of high intensity life-time service, situation about will not come unglued；Gum base ingredients uses the 4-5 extraordinary coumarone of part tack, makes foxing glue have good bond properties；Therefore, anti-skidding its adhesive force of liberation footwear and the cohesive that produce with this foxing formula are higher, and the service life of anti-skidding liberation footwear can be greatly improved.
Detailed description of the invention
Below by embodiment, present invention is further elaborated, but is not limitation of the invention.
A kind of anti-skidding liberation footwear calendering type black rubber foxing glue, calculates in parts by weight, including:
Standard rubbers 70-90, cis-butadiene cement 10-30, zinc oxide 5-10, stearic acid 1-3, white carbon black 5, industry fat 8-10, anti-aging agent RD 1-3, sulfur 1-1.5, captax
0.8-1.2, altax
1.0-1.5, diphenylguanidine
0.3-0.4, coumarone
4-5, calcium carbonate 110-130.
This formula can carry out two sections by banbury mixing to be completed, to improve the cohesive of sizing material.
Standard rubbers is No. 20 standard rubbers, and standard rubbers, cis-butadiene cement add up to content to be 100 weight portions.
Embodiment 1:
A kind of anti-skidding liberation footwear calendering type black rubber foxing glue, calculates in parts by weight, including:
No. 20 standard rubbers 70, cis-butadiene cement 10, zinc oxide 5, stearic acid 1, white carbon black 5, industry fat 8, anti-aging agent RD 1, sulfur 1, captax
0.8, altax
1.0, diphenylguanidine
0.3, coumarone
4, calcium carbonate 110.
After tested, physical data is as follows for this foxing glue:
Shore hardness/degree: 60；
Pull apart strength/MPa:8.0；
Elongation at break %:465；
Setafter break %:25；
Conditions of vulcanization: 143 DEG C × 60 '；
Deflect (secondary/just to split): 15500；
Adhesive force (kN/m): 2.7.
Wherein, adhesive force (kN/m): 2.7 are more than 2.2, and adhesive force is higher.
Embodiment 2:
A kind of anti-skidding liberation footwear calendering type black rubber foxing glue, calculates in parts by weight, including:
No. 20 standard rubbers 80, cis-butadiene cement 20, zinc oxide 8, stearic acid 2, white carbon black 5, industry fat 9, anti-aging agent RD 2, sulfur 1.25, captax
1.0, altax
1.3, diphenylguanidine
0.35, coumarone
4.5, calcium carbonate 120.
After tested, physical data is as follows for this foxing glue:
Shore hardness/degree: 65；
Pull apart strength/MPa:8.1；
Elongation at break %:470；
Setafter break %:26；
Conditions of vulcanization: 143 DEG C × 60 '；
Deflect (secondary/just to split): 15600；
Adhesive force (kN/m): 2.8.
Wherein, adhesive force (kN/m): 2.8 are more than 2.2, and adhesive force is higher.
Embodiment 3:
A kind of anti-skidding liberation footwear calendering type black rubber foxing glue, calculates in parts by weight, including:
No. 20 standard rubbers 90, cis-butadiene cement 30, zinc oxide 10, stearic acid 3, white carbon black 5, industry fat 10, anti-aging agent RD 3, sulfur 1.5, captax 1.2, altax
1.5, diphenylguanidine
0.4, coumarone
5, calcium carbonate 130.
After tested, physical data is as follows for this foxing glue:
Shore hardness/degree: 68；
Pull apart strength/MPa:8.2；
Elongation at break %:475；
Setafter break %:26；
Conditions of vulcanization: 143 DEG C × 60 '；
Deflect (secondary/just to split): 15700；
Adhesive force (kN/m): 2.8.
Wherein, adhesive force (kN/m): 2.8 are more than 2.2, and adhesive force is higher.
Claims (2)
1. an anti-skidding liberation footwear calendering type black rubber foxing glue, it is characterised in that calculate in parts by weight, including:
Standard rubbers 70-90, cis-butadiene cement 10-30, zinc oxide 5-10, stearic acid 1-3, white carbon black 5, industry fat 8-10, anti-aging agent RD 1-3, sulfur 1-1.5, captax 0.8-1.2, altax 1.0-1.5, diphenylguanidine 0.3-0.4, coumarone 4-5, calcium carbonate 110-130.
Anti-skidding liberation footwear calendering type black rubber foxing glue the most according to claim 1, it is characterised in that calculate in parts by weight, including:
No. 20 standard rubbers 80, cis-butadiene cement 20, zinc oxide 8, stearic acid 2, white carbon black 5, industry fat 9, anti-aging agent RD 2, sulfur 1.25, captax 1.0, altax 1.3, diphenylguanidine 0.35, coumarone 4.5, calcium carbonate 120.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201510358409.5A CN106279796A (en) | 2015-06-25 | 2015-06-25 | A kind of anti-skidding liberation footwear calendering type black rubber foxing glue |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201510358409.5A CN106279796A (en) | 2015-06-25 | 2015-06-25 | A kind of anti-skidding liberation footwear calendering type black rubber foxing glue |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN106279796A true CN106279796A (en) | 2017-01-04 |
Family
ID=57650249
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201510358409.5A Withdrawn CN106279796A (en) | 2015-06-25 | 2015-06-25 | A kind of anti-skidding liberation footwear calendering type black rubber foxing glue |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN106279796A (en) |
-
2015
- 2015-06-25 CN CN201510358409.5A patent/CN106279796A/en not_active Withdrawn
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| WW01 | Invention patent application withdrawn after publication |
Application publication date: 20170104 |
|
| WW01 | Invention patent application withdrawn after publication |