CN106278138A - A kind of high rigidity ceramic tile and preparation method thereof - Google Patents

A kind of high rigidity ceramic tile and preparation method thereof Download PDF

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Publication number
CN106278138A
CN106278138A CN201610635731.2A CN201610635731A CN106278138A CN 106278138 A CN106278138 A CN 106278138A CN 201610635731 A CN201610635731 A CN 201610635731A CN 106278138 A CN106278138 A CN 106278138A
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parts
ball
ceramic tile
oxide
high rigidity
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王智君
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Foshan Kaiser Avenue Ceramics Co Ltd
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Foshan Kaiser Avenue Ceramics Co Ltd
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Abstract

The invention discloses a kind of high rigidity ceramic tile, it is made up of the raw material of following weight parts: clay 15 25 parts, Kaolin 20 30 parts, light ceramic 20 40 parts, zirconium oxide 15 parts, aluminium oxide 5 10 parts, silicon oxide 15 parts, carborundum 15 parts, titanium carbide 15 parts, rare earth oxide 13 parts and binding agent 5 10 parts.Accordingly, invention additionally discloses above-mentioned high rigidity ceramic tile preparation method.The present invention can alleviate the weight of ceramic tile significantly, and compared with common ceramic tile, its weight can reduce 50%.And, the hardness of described ceramic tile is high, and the modulus of rupture, breakdown strength, bending strength are the most ideal.

Description

A kind of high rigidity ceramic tile and preparation method thereof
Technical field
The present invention relates to Ceramic Tiles field, particularly to a kind of high rigidity ceramic tile and preparation method thereof.
Background technology
Along with the raising of ceramic tile production technology, the kind of tile product gets more and more, including polished bricks, glazed tile, entire body Brick, vitrified tile, ceramic mosaic tile etc..The range of application of ceramic tile is wider, from local-style dwelling houses to office building, from indoor to open air, arrives Place is it can be seen that the figure of ceramic tile.
But the hardness of existing ceramic tile is the highest, it is easily damaged during transport and installation.And existing hardness is high Ceramic tile is the most heavier, considerably increases the cost of transport.The Ceramic Tiles of prior art is difficult under conditions of low production cost, Solve hardness and two technical problems of lightweight simultaneously.
Summary of the invention
The technical problem to be solved is, it is provided that a kind of ceramic tile having high rigidity and two advantages of lightweight concurrently, And the production cost of described ceramic tile is low.
The technical problem to be solved also resides in, it is provided that a kind of ceramic tile having high rigidity and two advantages of lightweight concurrently Preparation method.
For reaching above-mentioned technique effect, the invention provides a kind of high rigidity ceramic tile, it is by the raw material system of following weight parts Become:
Clay 15-25 part, Kaolin 20-30 part, light ceramic 20-40 part, zirconium oxide 1-5 part, aluminium oxide 5-10 part, oxidation Silicon 1-5 part, carborundum 1-5 part, titanium carbide 1-5 part, rare earth oxide 1-3 part and binding agent 5-10 part.
As the improvement of such scheme, the composition of raw materials of described high rigidity ceramic tile is as follows: clay 18-23 part, Kaolin 22-28 part, light ceramic 25-35 part, zirconium oxide 1-3 part, aluminium oxide 6-8 part, silicon oxide 1-3 part, carborundum 1-3 part, carbonization Titanium 1-3 part, rare earth oxide 1-2 part and binding agent 6-8 part.
As the improvement of such scheme, the composition of raw materials of described high rigidity ceramic tile is as follows: clay 20 parts, Kaolin 25 parts, Light ceramic 30 parts, zirconium oxide 2 parts, aluminium oxide 7 parts, silicon oxide 2 parts, carborundum 3 parts, titanium carbide 3 parts, rare earth oxide 2 parts With binding agent 7 parts.
As the improvement of such scheme, the raw material of described high rigidity ceramic tile also includes antibacterial 1-2 part, and described antibacterial is Zinc oxide, copper oxide, ammonium dihydrogen phosphate or lithium carbonate.
As the improvement of such scheme, described rare earth oxide is yittrium oxide, lanthana, cerium oxide or ytterbium oxide；Described Binding agent is sodium carboxymethyl cellulose.
Accordingly, invention additionally discloses the preparation method of a kind of high rigidity ceramic tile, including:
1, raw material is weighed by following weight parts: clay 15-25 part, Kaolin 20-30 part, light ceramic 20-40 part, zirconium oxide 1-5 part, aluminium oxide 5-10 part, silicon oxide 1-5 part, carborundum 1-5 part, titanium carbide 1-5 part, rare earth oxide 1-3 part and bonding Agent 5-10 part；
2, raw material stirring is mixed 30-60min, obtain compound；
3, compound is carried out four ball millings, obtain ball milling material；
4, by ball milling material under the pressure of 30-50Mpa compressing, obtain base substrate；
5, base substrate is dried process, the water content ＜ 2% of dried base substrate；
6, carry out dried base substrate soaking glaze；
7, being burnt till by the base substrate after leaching glaze, the temperature burnt till is 1200-1500 DEG C, and firing time is 30-60min；
8, the base substrate after burning till through edging, polish, pack, obtain high rigidity ceramic tile finished product.
As the improvement of such scheme, step 3 includes:
The compound zirconia ball grinding stone of a diameter of 60-70mm is carried out ball-milling treatment for the first time；
Compound through first time ball-milling treatment is carried out with the zirconia ball grinding stone of a diameter of 50-59mm at second time ball milling Reason；
Compound through second time ball-milling treatment is carried out with the zirconia ball grinding stone of a diameter of 40-49mm at third time ball milling Reason；
Compound through third time ball-milling treatment is carried out at the 4th ball milling with the zirconia ball grinding stone of a diameter of 30-39mm Reason.
As the improvement of such scheme, step 3 includes:
The compound zirconia ball grinding stone of a diameter of 60mm is carried out ball-milling treatment for the first time；
Compound through first time ball-milling treatment is carried out second time ball-milling treatment with the zirconia ball grinding stone of a diameter of 50mm；
Compound through second time ball-milling treatment is carried out third time ball-milling treatment with the zirconia ball grinding stone of a diameter of 40mm；
Compound through third time ball-milling treatment is carried out the 4th ball-milling treatment with the zirconia ball grinding stone of a diameter of 30mm.
As the improvement of such scheme, described compressing pressure is 38-48Mpa；
The water content ＜ 1% of dried base substrate；
The temperature burnt till is 1350-1450 DEG C, and firing time is 40-50min.
Enforcement there is advantages that
The present invention provides a kind of high rigidity ceramic tile, and its composition of raw materials is: clay 15-25 part, Kaolin 20-30 part, light ceramic 20-40 part, zirconium oxide 1-5 part, aluminium oxide 5-10 part, silicon oxide 1-5 part, carborundum 1-5 part, titanium carbide 1-5 part, rare-earth oxidation Thing 1-3 part and binding agent 5-10 part.Use above-mentioned composition of raw materials, can significantly alleviate the weight of ceramic tile, with common ceramic tile phase Ratio, its weight can reduce 50%.And, the hardness of described ceramic tile is high, and case hardness is 1600-2000HV, and the modulus of rupture reaches 110-150MPa, breakdown strength is 1800-2000N, and bending strength is 400-450 Mpa.
Additionally, the preparation technology of described high rigidity ceramic tile is simple, process control is simple, and equipment requirements is simple, effectively Save production cost, applied range.
Detailed description of the invention
For making the object, technical solutions and advantages of the present invention clearer, the present invention will be made the most detailed below Describe.
The invention discloses a kind of high rigidity ceramic tile, it is made up of the raw material of following weight parts:
Clay 15-25 part, Kaolin 20-30 part, light ceramic 20-40 part, zirconium oxide 1-5 part, aluminium oxide 5-10 part, oxidation Silicon 1-5 part, carborundum 1-5 part, titanium carbide 1-5 part, rare earth oxide 1-3 part and binding agent 5-10 part.
Preferably, the composition of raw materials of described high rigidity ceramic tile is as follows: clay 18-23 part, Kaolin 22-28 part, Lightweight ceramic Grain 25-35 part, zirconium oxide 1-3 part, aluminium oxide 6-8 part, silicon oxide 1-3 part, carborundum 1-3 part, titanium carbide 1-3 part, rare earth oxygen Compound 1-2 part and binding agent 6-8 part.
More preferably, the composition of raw materials of described high rigidity ceramic tile is as follows: clay 20 parts, Kaolin 25 parts, light ceramic 30 Part, zirconium oxide 2 parts, aluminium oxide 7 parts, silicon oxide 2 parts, carborundum 3 parts, titanium carbide 3 parts, rare earth oxide 2 parts and binding agent 7 Part.
It should be noted that light ceramic, using clay or flyash, biological sludge is primary raw material, is roasted by high temperature Burn, expanded form, light ceramic as a kind of light-weight aggregate, have that density is little, intensity is high, water absorption rate is big, be incubated, heat insulation, fire-resistant, The features such as antidetonation.
It is excellent that zirconia material itself has high rigidity, high temperature, high tenacity, high wearability and chemical resistance etc. Physical and chemical performance；And aluminium oxide itself also possesses that mechanical strength is high, hardness greatly, dielectric loss is little frequently, high-temperature insulation resistance is high, resistance to Chemical corrosivity and the heat conductivity excellent combination technical performance such as well.
Titanium carbide has high rigidity, high-melting-point and anti abrasive performance；Carborundum has stable chemical performance, heat conductivity The advantages such as height, thermal coefficient of expansion is little, anti-wear performance good, high rigidity (Mohs' hardness is 9.5 grades).Tests prove that, by above-mentioned material The ceramic material that material obtains with zirconium oxide, silicon oxide and alumina composite, can significantly improve the hardness of ceramic tile.
To sum up, the present invention, based on clay and Kaolin, adds a certain amount of light ceramic, and is aided with special ratios Zirconium oxide, aluminium oxide, silicon oxide, carborundum and titanium carbide, can effectively reduce the weight of ceramic tile, and can also ensure that it has height Hardness.
Further, the raw material of described high rigidity ceramic tile also includes antibacterial 1-2 part, and described antibacterial is zinc oxide, oxidation Copper, ammonium dihydrogen phosphate or lithium carbonate.Described antibacterial acts on jointly with other raw materials of high rigidity ceramic tile so that high rigidity ceramic tile Having antibiotic and sterilizing ability, the survival rate of the antibacterial on its surface is less than 50%, and the survival rate of mycete is less than 30%.
Described rare earth oxide is preferably yittrium oxide, lanthana, cerium oxide or ytterbium oxide, but is not limited to this.
Described binding agent is preferably sodium carboxymethyl cellulose, but is not limited to this.
Accordingly, invention additionally discloses the preparation method of a kind of high rigidity ceramic tile, including:
1, raw material is weighed by following weight parts: clay 15-25 part, Kaolin 20-30 part, light ceramic 20-40 part, zirconium oxide 1-5 part, aluminium oxide 5-10 part, silicon oxide 1-5 part, carborundum 1-5 part, titanium carbide 1-5 part, rare earth oxide 1-3 part and bonding Agent 5-10 part；
Preferably, the composition of raw materials of described high rigidity ceramic tile is as follows: clay 18-23 part, Kaolin 22-28 part, light ceramic 25-35 part, zirconium oxide 1-3 part, aluminium oxide 6-8 part, silicon oxide 1-3 part, carborundum 1-3 part, titanium carbide 1-3 part, rare-earth oxidation Thing 1-2 part and binding agent 6-8 part.
More preferably, the composition of raw materials of described high rigidity ceramic tile is as follows: clay 20 parts, Kaolin 25 parts, light ceramic 30 Part, zirconium oxide 2 parts, aluminium oxide 7 parts, silicon oxide 2 parts, carborundum 3 parts, titanium carbide 3 parts, rare earth oxide 2 parts and binding agent 7 Part.
Further, the raw material of described high rigidity ceramic tile also includes antibacterial 1-2 part, and described antibacterial is zinc oxide, oxidation Copper, ammonium dihydrogen phosphate or lithium carbonate.Therefore, described high rigidity ceramic tile also has antibiotic and sterilizing ability, depositing of the antibacterial on its surface Motility rate is less than 50%, and the survival rate of mycete is less than 30%.
Described rare earth oxide is preferably yittrium oxide, lanthana, cerium oxide or ytterbium oxide, but is not limited to this.
Described binding agent is preferably sodium carboxymethyl cellulose, but is not limited to this.
2, raw material stirring is mixed 30-60min, obtain compound.
3, compound is carried out four ball millings, obtain ball milling material.
Concrete, described four ball millings include:
The compound zirconia ball grinding stone of a diameter of 60-70mm is carried out ball-milling treatment for the first time；
Compound through first time ball-milling treatment is carried out with the zirconia ball grinding stone of a diameter of 50-59mm at second time ball milling Reason；
Compound through second time ball-milling treatment is carried out with the zirconia ball grinding stone of a diameter of 40-49mm at third time ball milling Reason；
Compound through third time ball-milling treatment is carried out at the 4th ball milling with the zirconia ball grinding stone of a diameter of 30-39mm Reason.
As the further preferred scheme of four ball millings, comprising:
The compound zirconia ball grinding stone of a diameter of 60mm is carried out ball-milling treatment for the first time；
Compound through first time ball-milling treatment is carried out second time ball-milling treatment with the zirconia ball grinding stone of a diameter of 50mm；
Compound through second time ball-milling treatment is carried out third time ball-milling treatment with the zirconia ball grinding stone of a diameter of 40mm；
Compound through third time ball-milling treatment is carried out the 4th ball-milling treatment with the zirconia ball grinding stone of a diameter of 30mm.
4, by ball milling material under the pressure of 30-50Mpa compressing, obtain base substrate；
Preferably, described compressing pressure is 38-48Mpa.
5, base substrate is dried process, the water content ＜ 2% of dried base substrate；
Preferably, the water content ＜ 1% of dried base substrate.
6, carry out dried base substrate soaking glaze.
7, being burnt till by the base substrate after leaching glaze, the temperature burnt till is 1200-1500 DEG C, and firing time is 30-60min；
Preferably, the temperature burnt till is 1350-1450 DEG C, and firing time is 40-50min.
8, the base substrate after burning till through edging, polish, pack, obtain high rigidity ceramic tile finished product.
With specific embodiment, the present invention is further elaborated below
Embodiment 1
One, formula: clay 15 parts, Kaolin 20 parts, light ceramic 20 parts, zirconium oxide 1 part, aluminium oxide 5 parts, silicon oxide 1 part, Carborundum 1 part, titanium carbide 1 part, rare earth oxide 1 part and binding agent 5 parts.
Two, preparation method:
1, raw material is weighed by following weight parts: clay 15 parts, Kaolin 20 parts, light ceramic 20 parts, zirconium oxide 1 part, aluminium oxide 5 parts, silicon oxide 1 part, carborundum 1 part, titanium carbide 1 part, rare earth oxide 1 part and binding agent 5 parts；
2, raw material stirring is mixed 30min, obtain compound；
3, compound is carried out four ball millings, obtain ball milling material；
Wherein, four ball millings include:
The compound zirconia ball grinding stone of a diameter of 60mm is carried out ball-milling treatment for the first time；
Compound through first time ball-milling treatment is carried out second time ball-milling treatment with the zirconia ball grinding stone of a diameter of 50mm；
Compound through second time ball-milling treatment is carried out third time ball-milling treatment with the zirconia ball grinding stone of a diameter of 40mm；
Compound through third time ball-milling treatment is carried out the 4th ball-milling treatment with the zirconia ball grinding stone of a diameter of 30mm；
4, by ball milling material under the pressure of 30Mpa compressing, obtain base substrate；
5, base substrate is dried process, the water content ＜ 2% of dried base substrate；
6, carry out dried base substrate soaking glaze；
7, being burnt till by the base substrate after leaching glaze, the temperature burnt till is 1200 DEG C, and firing time is 30min；
8, the base substrate after burning till through edging, polish, pack, obtain high rigidity ceramic tile finished product.
Embodiment 2
One, formula: clay 18 parts, Kaolin 22 parts, light ceramic 25 parts, zirconium oxide 2 parts, aluminium oxide 7 parts, silicon oxide 2 parts, Carborundum 2 parts, titanium carbide 2 parts, rare earth oxide 2 parts, binding agent 7 parts, antibacterial 1 part；
Two, preparation method:
1, raw material is weighed by following weight parts: clay 18 parts, Kaolin 22 parts, light ceramic 25 parts, zirconium oxide 2 parts, aluminium oxide 7 parts, silicon oxide 2 parts, carborundum 2 parts, titanium carbide 2 parts, rare earth oxide 2 parts, binding agent 7 parts, antibacterial 1 part；
2, raw material stirring is mixed 40min, obtain compound；
3, compound is carried out four ball millings, obtain ball milling material；
Wherein, four ball millings include:
The compound zirconia ball grinding stone of a diameter of 60mm is carried out ball-milling treatment for the first time；
Compound through first time ball-milling treatment is carried out second time ball-milling treatment with the zirconia ball grinding stone of a diameter of 50mm；
Compound through second time ball-milling treatment is carried out third time ball-milling treatment with the zirconia ball grinding stone of a diameter of 40mm；
Compound through third time ball-milling treatment is carried out the 4th ball-milling treatment with the zirconia ball grinding stone of a diameter of 30mm；
4, by ball milling material under the pressure of 40Mpa compressing, obtain base substrate；
5, base substrate is dried process, the water content ＜ 2% of dried base substrate；
6, carry out dried base substrate soaking glaze；
7, being burnt till by the base substrate after leaching glaze, the temperature burnt till is 1350 DEG C, and firing time is 50min；
8, the base substrate after burning till through edging, polish, pack, obtain high rigidity ceramic tile finished product.
Embodiment 3
One, formula: clay 20 parts, Kaolin 25 parts, light ceramic 30 parts, zirconium oxide 3 parts, aluminium oxide 8 parts, silicon oxide 3 parts, Carborundum 3 parts, titanium carbide 3 parts, rare earth oxide 2 parts and binding agent 8 parts.
Two, preparation method:
1, raw material is weighed by following weight parts: clay 20 parts, Kaolin 25 parts, light ceramic 30 parts, zirconium oxide 3 parts, aluminium oxide 8 parts, silicon oxide 3 parts, carborundum 3 parts, titanium carbide 3 parts, rare earth oxide 2 parts and binding agent 8 parts；
2, raw material stirring is mixed 50min, obtain compound；
3, compound is carried out four ball millings, obtain ball milling material；
Wherein, four ball millings include:
The compound zirconia ball grinding stone of a diameter of 60mm is carried out ball-milling treatment for the first time；
Compound through first time ball-milling treatment is carried out second time ball-milling treatment with the zirconia ball grinding stone of a diameter of 50mm；
Compound through second time ball-milling treatment is carried out third time ball-milling treatment with the zirconia ball grinding stone of a diameter of 40mm；
Compound through third time ball-milling treatment is carried out the 4th ball-milling treatment with the zirconia ball grinding stone of a diameter of 30mm；
4, by ball milling material under the pressure of 45Mpa compressing, obtain base substrate；
5, base substrate is dried process, the water content ＜ 2% of dried base substrate；
6, carry out dried base substrate soaking glaze；
7, being burnt till by the base substrate after leaching glaze, the temperature burnt till is 1400 DEG C, and firing time is 50min；
8, the base substrate after burning till through edging, polish, pack, obtain high rigidity ceramic tile finished product.
Embodiment 4
One, formula: clay 22 parts, Kaolin 28 parts, light ceramic 35 parts, zirconium oxide 4 parts, aluminium oxide 9 parts, silicon oxide 4 parts, carbon SiClx 4 parts, titanium carbide 4 parts, rare earth oxide 3 parts, binding agent 9 parts, antibacterial 2 parts；
Two, preparation method:
1, raw material is weighed by following weight parts: clay 22 parts, Kaolin 28 parts, light ceramic 35 parts, zirconium oxide 4 parts, aluminium oxide 9 Part, silicon oxide 4 parts, carborundum 4 parts, titanium carbide 4 parts, rare earth oxide 3 parts, binding agent 9 parts, antibacterial 2 parts；
2, raw material stirring is mixed 60min, obtain compound；
3, compound is carried out four ball millings, obtain ball milling material；
Wherein, four ball millings include:
The compound zirconia ball grinding stone of a diameter of 60mm is carried out ball-milling treatment for the first time；
Compound through first time ball-milling treatment is carried out second time ball-milling treatment with the zirconia ball grinding stone of a diameter of 50mm；
Compound through second time ball-milling treatment is carried out third time ball-milling treatment with the zirconia ball grinding stone of a diameter of 40mm；
Compound through third time ball-milling treatment is carried out the 4th ball-milling treatment with the zirconia ball grinding stone of a diameter of 30mm；
4, by ball milling material under the pressure of 50Mpa compressing, obtain base substrate；
5, base substrate is dried process, the water content ＜ 2% of dried base substrate；
6, carry out dried base substrate soaking glaze；
7, being burnt till by the base substrate after leaching glaze, the temperature burnt till is 1450 DEG C, and firing time is 50min；
8, the base substrate after burning till through edging, polish, pack, obtain high rigidity ceramic tile finished product.
Embodiment 5
One, formula: clay 25 parts, Kaolin 30 parts, light ceramic 40 parts, zirconium oxide 5 parts, aluminium oxide 10 parts, silicon oxide 5 parts, Carborundum 5 parts, titanium carbide 5 parts, rare earth oxide 3 parts and binding agent 10 parts.
Two, preparation method:
1, raw material is weighed by following weight parts: clay 25 parts, Kaolin 30 parts, light ceramic 40 parts, zirconium oxide 5 parts, aluminium oxide 10 parts, silicon oxide 5 parts, carborundum 5 parts, titanium carbide 5 parts, rare earth oxide 3 parts and binding agent 10 parts；
2, raw material stirring is mixed 60min, obtain compound；
3, compound is carried out four ball millings, obtain ball milling material；
Wherein, four ball millings include:
The compound zirconia ball grinding stone of a diameter of 60mm is carried out ball-milling treatment for the first time；
Compound through first time ball-milling treatment is carried out second time ball-milling treatment with the zirconia ball grinding stone of a diameter of 50mm；
Compound through second time ball-milling treatment is carried out third time ball-milling treatment with the zirconia ball grinding stone of a diameter of 40mm；
Compound through third time ball-milling treatment is carried out the 4th ball-milling treatment with the zirconia ball grinding stone of a diameter of 30mm；
4, by ball milling material under the pressure of 50Mpa compressing, obtain base substrate；
5, base substrate is dried process, the water content ＜ 2% of dried base substrate；
6, carry out dried base substrate soaking glaze；
7, being burnt till by the base substrate after leaching glaze, the temperature burnt till is 1500 DEG C, and firing time is 60min；
8, the base substrate after burning till through edging, polish, pack, obtain high rigidity ceramic tile finished product.
The ceramic tile (a size of 60*60cm, thickness is 0.8-1cm) of embodiment 1-5 gained is done technology for detection, and result is such as Under:
Embodiment 1 Embodiment 2 Embodiment 3 Embodiment 4 Embodiment 5
Case hardness 1700HV 1680HV 1850HV 1950HV 1750HV
The modulus of rupture 120MPa 145MPa 131MPa 148MPa 137MPa
Breakdown strength 1870N 1900N 1980N 1950N 1920N
Bending strength 405 Mpa 410Mpa 440Mpa 430Mpa 420Mpa
Weight 3.7kg 3.7kg 3.7kg 3.7kg 3.7kg
It should be noted that described weight measurement is a size of 60*60cm, thickness is the weight of the ceramic tile of 1cm.
In sum, the present invention provides a kind of high rigidity ceramic tile, can significantly alleviate the weight of ceramic tile, with common ceramic tile phase Ratio, its weight can reduce 50%.And, the hardness of described ceramic tile is high, and the modulus of rupture, breakdown strength, bending strength are the most more managed Think.Additionally, the preparation technology of described high rigidity ceramic tile is simple, process control is simple, and equipment requirements is simple, effectively saves life Produce cost, applied range.
The above is the preferred embodiment of the present invention, it is noted that for those skilled in the art For, under the premise without departing from the principles of the invention, it is also possible to make some improvements and modifications, these improvements and modifications are also considered as Protection scope of the present invention.

Claims (9)

1. a high rigidity ceramic tile, it is characterised in that it is made up of the raw material of following weight parts:
Clay 15-25 part, Kaolin 20-30 part, light ceramic 20-40 part, zirconium oxide 1-5 part, aluminium oxide 5-10 part, oxidation Silicon 1-5 part, carborundum 1-5 part, titanium carbide 1-5 part, rare earth oxide 1-3 part and binding agent 5-10 part.
2. high rigidity ceramic tile as claimed in claim 1, it is characterised in that the composition of raw materials of described high rigidity ceramic tile is as follows: viscous Soil 18-23 part, Kaolin 22-28 part, light ceramic 25-35 part, zirconium oxide 1-3 part, aluminium oxide 6-8 part, silicon oxide 1-3 part, Carborundum 1-3 part, titanium carbide 1-3 part, rare earth oxide 1-2 part and binding agent 6-8 part.
3. high rigidity ceramic tile as claimed in claim 2, it is characterised in that the composition of raw materials of described high rigidity ceramic tile is as follows: viscous 20 parts of soil, Kaolin 25 parts, light ceramic 30 parts, zirconium oxide 2 parts, aluminium oxide 7 parts, silicon oxide 2 parts, carborundum 3 parts, carbonization Titanium 3 parts, rare earth oxide 2 parts and binding agent 7 parts.
4. high rigidity ceramic tile as claimed in claim 3, it is characterised in that the raw material of described high rigidity ceramic tile also includes antibacterial 1-2 part, described antibacterial is zinc oxide, copper oxide, ammonium dihydrogen phosphate or lithium carbonate.
5. high rigidity ceramic tile as claimed in claim 3, it is characterised in that described rare earth oxide is yittrium oxide, lanthana, oxygen Change cerium or ytterbium oxide；
Described binding agent is sodium carboxymethyl cellulose.
6. the preparation method of the high rigidity ceramic tile as described in any one of claim 1-5, it is characterised in that including:
1, raw material is weighed by following weight parts: clay 15-25 part, Kaolin 20-30 part, light ceramic 20-40 part, zirconium oxide 1-5 part, aluminium oxide 5-10 part, silicon oxide 1-5 part, carborundum 1-5 part, titanium carbide 1-5 part, rare earth oxide 1-3 part and bonding Agent 5-10 part；
2, raw material stirring is mixed 30-60min, obtain compound；
3, compound is carried out four ball millings, obtain ball milling material；
4, by ball milling material under the pressure of 30-50Mpa compressing, obtain base substrate；
5, base substrate is dried process, the water content ＜ 2% of dried base substrate；
6, carry out dried base substrate soaking glaze；
7, being burnt till by the base substrate after leaching glaze, the temperature burnt till is 1200-1500 DEG C, and firing time is 30-60min；
8, the base substrate after burning till through edging, polish, pack, obtain high rigidity ceramic tile finished product.
7. the preparation method of high rigidity ceramic tile as claimed in claim 6, it is characterised in that step 3 includes:
The compound zirconia ball grinding stone of a diameter of 60-70mm is carried out ball-milling treatment for the first time；
Compound through first time ball-milling treatment is carried out with the zirconia ball grinding stone of a diameter of 50-59mm at second time ball milling Reason；
Compound through second time ball-milling treatment is carried out with the zirconia ball grinding stone of a diameter of 40-49mm at third time ball milling Reason；
Compound through third time ball-milling treatment is carried out at the 4th ball milling with the zirconia ball grinding stone of a diameter of 30-39mm Reason.
8. the preparation method of high rigidity ceramic tile as claimed in claim 7, it is characterised in that step 3 includes:
The compound zirconia ball grinding stone of a diameter of 60mm is carried out ball-milling treatment for the first time；
Compound through first time ball-milling treatment is carried out second time ball-milling treatment with the zirconia ball grinding stone of a diameter of 50mm；
Compound through second time ball-milling treatment is carried out third time ball-milling treatment with the zirconia ball grinding stone of a diameter of 40mm；
Compound through third time ball-milling treatment is carried out the 4th ball-milling treatment with the zirconia ball grinding stone of a diameter of 30mm.
9. the preparation method of high rigidity ceramic tile as claimed in claim 7, it is characterised in that described compressing pressure is 38-48Mpa；
The water content ＜ 1% of dried base substrate；
The temperature burnt till is 1350-1450 DEG C, and firing time is 40-50min.
CN201610635731.2A 2016-08-05 2016-08-05 A kind of high rigidity ceramic tile and preparation method thereof Pending CN106278138A (en)

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CN111499198A (en) * 2020-04-29 2020-08-07 佛山科学技术学院 High-strength ceramic glaze for splicing ceramic body and preparation method thereof
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Application publication date: 20170104