CN106277847A - A kind of glass fiber infiltration agent - Google Patents
A kind of glass fiber infiltration agent Download PDFInfo
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- CN106277847A CN106277847A CN201610614590.6A CN201610614590A CN106277847A CN 106277847 A CN106277847 A CN 106277847A CN 201610614590 A CN201610614590 A CN 201610614590A CN 106277847 A CN106277847 A CN 106277847A
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- parts
- agent
- glass fiber
- defoamer
- lubricant
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- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C25/00—Surface treatment of fibres or filaments made from glass, minerals or slags
- C03C25/10—Coating
- C03C25/24—Coatings containing organic materials
- C03C25/26—Macromolecular compounds or prepolymers
- C03C25/32—Macromolecular compounds or prepolymers obtained otherwise than by reactions involving only carbon-to-carbon unsaturated bonds
- C03C25/321—Starch; Starch derivatives
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- Life Sciences & Earth Sciences (AREA)
- Chemical & Material Sciences (AREA)
- General Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Geochemistry & Mineralogy (AREA)
- Materials Engineering (AREA)
- Organic Chemistry (AREA)
- Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
Abstract
The invention discloses a kind of glass fiber infiltration agent, be made up of the component of following weight portion: hydroxypropylation modified starch 40 50 parts, polyaminoester emulsion 20 30 parts, acrylic acid ester emulsion 10 20 parts, vegetable oil 58 parts, coupling agent 35 parts, lubricant 0.5 2 parts, brightener 0.5 1 parts, emulsifying agent 0.5 1 parts, Polyethylene Glycol 0.5 2 parts, polyvinyl alcohol 0 0.5 parts, 0 0.5 parts of antistatic additive, defoamer 0.5 1 parts, water is appropriate.The present invention uses hydroxypropylation modified starch, polyaminoester emulsion; acrylic acid ester emulsion is as film former; there is high cohesive force, good film property and protectiveness; be conducive to protection and collection number that glass fibre collects in high velocity jet and the process of kneading; improve production efficiency, improve the mechanical performance of glass fibre, give glass with good cutting, dispersibility, lubricity, antistatic behaviour, textile and mobility; and decrease the consumption of polyurethane, reduce the cost of wetting agent.
Description
Technical field
The present invention relates to glass fibre production technology, specifically a kind of glass fiber infiltration agent.
Background technology
Glass fibre is dispersed in water or the alcohol of water, ester solution medium, and then is used for producing glassfiber insulation bag
It is contour that package material, glass mat, particularly glass fibre mix manufacture galss fiber reinforced resin with macromolecule resin fiber
Strength-Glass-Fibre composite is a key areas of modem fibreglass application, has wide market prospect and development
Prospect.
At present conventional water dispersable glass fiber sizing mostly use amine or alcohols single compound or with non-from
The mixture of son or cationic surface active agent is as dispersant.Its existence is disadvantageous in that: be difficult to according to industry raw
The practical situation produced is adjusted, it is impossible to meets and disperses all kinds of variety classeses, the glass fibre of chemical composition or glass fibre not
Being actually needed with disperse medium.
The wetting agent in this field of glass fibre used carbamide as wetting agent mostly in the past, and heat stability is poor, under high temperature
Easily produce abnormal flavour, had a strong impact on the use of glass fibre, and easily caused environmental pollution, Application No.
CN201010252613.6 discloses a kind of glass fiber lubricant, the dispersion being made up of two kinds of different nitrogen-containing surfactants
Agent, the protective agent being made up of one or more polyhydroxy or oxo-alcohols, ester, acyl base polymer, it is made up of polyol blends
The silane coupler that wetting agent, lubricant, fiber glass industry are conventional, remainder is distilled water or deionized water, this infiltration
Agent is applicable to various alkali-free, medium-alkali glass fibre in the dispersion of aqueous medium, and the glass dispersion after this product treatment can be good
Good, Heat stability is good and pollution-free, but this kind of wetting agent wellability is poor, and reinforced effects is poor, and production cost is higher.
Summary of the invention
It is an object of the invention to provide a kind of glass fiber infiltration agent, with asking of solving to propose in above-mentioned background technology
Topic.
For achieving the above object, the present invention provides following technical scheme:
A kind of glass fiber infiltration agent, is made up of the component of following weight portion:
Hydroxypropylation modified starch 40-50 part, polyaminoester emulsion 20-30 part, acrylic acid ester emulsion 10-20 part, vegetable oil
5-8 part, coupling agent 3-5 part, lubricant 0.5-2 part, brightener 0.5-1 part, emulsifying agent 0.5-1 part, Polyethylene Glycol 0.5-2 part,
Polyvinyl alcohol 0-0.5 part, antistatic additive 0-0.5 part, defoamer 0.5-1 part, water is appropriate.
A kind of glass fiber infiltration agent, is made up of the component of following weight portion:
Hydroxypropylation modified starch 40 parts, polyaminoester emulsion 20 parts, acrylic acid ester emulsion 10 parts, vegetable oil 5 parts, coupling agent
3 parts, lubricant 0.5 part, brightener 0.5 part, emulsifying agent 0.5 part, Polyethylene Glycol 0.5 part, polyvinyl alcohol 0.1 part, antistatic additive
0.1 part, defoamer 0.5 part, water is appropriate.
A kind of glass fiber infiltration agent, is made up of the component of following weight portion:
Hydroxypropylation modified starch 50 parts, polyaminoester emulsion 30 parts, acrylic acid ester emulsion 20 parts, vegetable oil 8 parts, coupling agent
5 parts, lubricant 2 parts, brightener 1 part, emulsifying agent 1 part, Polyethylene Glycol 2 parts, polyvinyl alcohol 0.5 part, 0.5 part of antistatic additive, disappear
Infusion 1 part, water is appropriate.
A kind of glass fiber infiltration agent, is made up of the component of following weight portion:
Hydroxypropylation modified starch 45 parts, polyaminoester emulsion 25 parts, acrylic acid ester emulsion 16 parts, vegetable oil 7 parts, coupling agent
4 parts, lubricant 1.3 parts, brightener 0.8 part, emulsifying agent 0.7 part, Polyethylene Glycol 1.1 parts, polyvinyl alcohol 0.2 part, antistatic additive
0.2 part, defoamer 0.8 part, water is appropriate.
A kind of glass fiber infiltration agent, is made up of the component of following weight portion:
Hydroxypropylation modified starch 47 parts, polyaminoester emulsion 22 parts, acrylic acid ester emulsion 13 parts, vegetable oil 6 parts, coupling agent
3.5 parts, lubricant 0.9 part, brightener 0.6 part, emulsifying agent 0.9 part, Polyethylene Glycol 1.7 parts, polyvinyl alcohol 0.4 part, antistatic
Agent 0.4 part, defoamer 0.6 part, water is appropriate.
Wherein Polyethylene Glycol and polyvinyl alcohol are as reaction promoter, prevent fibrous fracture, strengthen plasticity and deflection.
Preferably, described coupling agent is silane coupler.
Preferably, described defoamer is phosphate ester defoamer.
Preferably, described lubricant is the imidazoline lubricant of sun.
Preferably, described antistatic additive is made up of with anti-static agent SN lithium nitrate, lithium chloride, ammonium chloride, wherein lithium nitrate,
In lithium chloride, ammonium chloride, the mass ratio with anti-static agent SN is 1:0.5-1:0.5-1:0.02-0.15.
Described glass fiber infiltration agent is adopted and is prepared from the following method, specifically includes following steps:
(1) in lubricant, add 80-90 DEG C of deionized water of its quality 10-15 times, be stirred until homogeneous transparent liquid；
(2) in antistatic additive, add 40-60 DEG C of deionized water of its quality 10-15 times, be stirred until homogeneous transparent liquid；
(3) by whole hydroxypropylation modified starches, polyaminoester emulsion, acrylic acid ester emulsion, vegetable oil, coupling agent, light
Bright dose, emulsifying agent, Polyethylene Glycol, polyvinyl alcohol, defoamer add the deionized water of its quality 100 times, stir；
(4) all substances of above-mentioned steps gained are mixed, stir, regulate solid content, obtain the present invention's
Wetting agent.
Compared with prior art, the invention has the beneficial effects as follows: the present invention uses hydroxypropylation modified starch, polyurethane breast
Liquid, acrylic acid ester emulsion, as film former, have high cohesive force, good film property and protectiveness, beneficially glass fibre and exist
Protection that high velocity jet and the process of kneading collect and collection number, improve production efficiency, improve the mechanical performance of glass fibre, give glass
Fine with good cutting, dispersibility, lubricity, antistatic behaviour, textile and mobility, and decrease the consumption of polyurethane,
Reduce the cost of wetting agent.
Detailed description of the invention
Embodiment 1
A kind of glass fiber infiltration agent, is made up of the component of following weight portion:
Hydroxypropylation modified starch 40 parts, polyaminoester emulsion 20 parts, acrylic acid ester emulsion 10 parts, vegetable oil 5 parts, coupling agent
3 parts, lubricant 0.5 part, brightener 0.5 part, emulsifying agent 0.5 part, Polyethylene Glycol 0.5 part, polyvinyl alcohol 0.1 part, antistatic additive
0.1 part, defoamer 0.5 part, water is appropriate.
Wherein Polyethylene Glycol and polyvinyl alcohol are as reaction promoter, prevent fibrous fracture, strengthen plasticity and deflection.
Preferably, described coupling agent is silane coupler.
Preferably, described defoamer is phosphate ester defoamer.
Preferably, described lubricant is the imidazoline lubricant of sun.
Preferably, described antistatic additive is made up of with anti-static agent SN lithium nitrate, lithium chloride, ammonium chloride, wherein lithium nitrate,
In lithium chloride, ammonium chloride, the mass ratio with anti-static agent SN is 1:0.5:0.5:0.02.
Described glass fiber infiltration agent is adopted and is prepared from the following method, specifically includes following steps:
(1) in lubricant, add 80-90 DEG C of deionized water of its quality 10-15 times, be stirred until homogeneous transparent liquid；
(2) in antistatic additive, add 40-60 DEG C of deionized water of its quality 10-15 times, be stirred until homogeneous transparent liquid；
(3) by whole hydroxypropylation modified starches, polyaminoester emulsion, acrylic acid ester emulsion, vegetable oil, coupling agent, light
Bright dose, emulsifying agent, Polyethylene Glycol, polyvinyl alcohol, defoamer add the deionized water of its quality 100 times, stir；
(4) all substances of above-mentioned steps gained are mixed, stir, regulate solid content, obtain the present invention's
Wetting agent.
Embodiment 2
A kind of glass fiber infiltration agent, is made up of the component of following weight portion:
Hydroxypropylation modified starch 50 parts, polyaminoester emulsion 30 parts, acrylic acid ester emulsion 20 parts, vegetable oil 8 parts, coupling agent
5 parts, lubricant 2 parts, brightener 1 part, emulsifying agent 1 part, Polyethylene Glycol 2 parts, polyvinyl alcohol 0.5 part, 0.5 part of antistatic additive, disappear
Infusion 1 part, water is appropriate.
Wherein Polyethylene Glycol and polyvinyl alcohol are as reaction promoter, prevent fibrous fracture, strengthen plasticity and deflection.
Preferably, described coupling agent is silane coupler.
Preferably, described defoamer is phosphate ester defoamer.
Preferably, described lubricant is the imidazoline lubricant of sun.
Preferably, described antistatic additive is made up of with anti-static agent SN lithium nitrate, lithium chloride, ammonium chloride, wherein lithium nitrate,
In lithium chloride, ammonium chloride, the mass ratio with anti-static agent SN is 1:1:1:0.15.
Described glass fiber infiltration agent is adopted and is prepared from the following method, specifically includes following steps:
(1) in lubricant, add 80-90 DEG C of deionized water of its quality 10-15 times, be stirred until homogeneous transparent liquid；
(2) in antistatic additive, add 40-60 DEG C of deionized water of its quality 10-15 times, be stirred until homogeneous transparent liquid；
(3) by whole hydroxypropylation modified starches, polyaminoester emulsion, acrylic acid ester emulsion, vegetable oil, coupling agent, light
Bright dose, emulsifying agent, Polyethylene Glycol, polyvinyl alcohol, defoamer add the deionized water of its quality 100 times, stir；
(4) all substances of above-mentioned steps gained are mixed, stir, regulate solid content, obtain the present invention's
Wetting agent.
Embodiment 3
A kind of glass fiber infiltration agent, is made up of the component of following weight portion:
Hydroxypropylation modified starch 45 parts, polyaminoester emulsion 25 parts, acrylic acid ester emulsion 16 parts, vegetable oil 7 parts, coupling agent
4 parts, lubricant 1.3 parts, brightener 0.8 part, emulsifying agent 0.7 part, Polyethylene Glycol 1.1 parts, polyvinyl alcohol 0.2 part, antistatic additive
0.2 part, defoamer 0.8 part, water is appropriate.
Wherein Polyethylene Glycol and polyvinyl alcohol are as reaction promoter, prevent fibrous fracture, strengthen plasticity and deflection.
Preferably, described coupling agent is silane coupler.
Preferably, described defoamer is phosphate ester defoamer.
Preferably, described lubricant is the imidazoline lubricant of sun.
Preferably, described antistatic additive is made up of with anti-static agent SN lithium nitrate, lithium chloride, ammonium chloride, wherein lithium nitrate,
In lithium chloride, ammonium chloride, the mass ratio with anti-static agent SN is 1:0.6:0.6:0.1.
Described glass fiber infiltration agent is adopted and is prepared from the following method, specifically includes following steps:
(1) in lubricant, add 80-90 DEG C of deionized water of its quality 10-15 times, be stirred until homogeneous transparent liquid；
(2) in antistatic additive, add 40-60 DEG C of deionized water of its quality 10-15 times, be stirred until homogeneous transparent liquid；
(3) by whole hydroxypropylation modified starches, polyaminoester emulsion, acrylic acid ester emulsion, vegetable oil, coupling agent, light
Bright dose, emulsifying agent, Polyethylene Glycol, polyvinyl alcohol, defoamer add the deionized water of its quality 100 times, stir；
(4) all substances of above-mentioned steps gained are mixed, stir, regulate solid content, obtain the present invention's
Wetting agent.
Embodiment 4
A kind of glass fiber infiltration agent, is made up of the component of following weight portion:
Hydroxypropylation modified starch 47 parts, polyaminoester emulsion 22 parts, acrylic acid ester emulsion 13 parts, vegetable oil 6 parts, coupling agent
3.5 parts, lubricant 0.9 part, brightener 0.6 part, emulsifying agent 0.9 part, Polyethylene Glycol 1.7 parts, polyvinyl alcohol 0.4 part, antistatic
Agent 0.4 part, defoamer 0.6 part, water is appropriate.
Wherein Polyethylene Glycol and polyvinyl alcohol are as reaction promoter, prevent fibrous fracture, strengthen plasticity and deflection.
Preferably, described coupling agent is silane coupler.
Preferably, described defoamer is phosphate ester defoamer.
Preferably, described lubricant is the imidazoline lubricant of sun.
Preferably, described antistatic additive is made up of with anti-static agent SN lithium nitrate, lithium chloride, ammonium chloride, wherein lithium nitrate,
In lithium chloride, ammonium chloride, the mass ratio with anti-static agent SN is 1:0.8:0.8:0.12.
Glass fiber infiltration agent of the present invention is adopted and is prepared from the following method, specifically includes following steps:
(1) in lubricant, add 80-90 DEG C of deionized water of its quality 10-15 times, be stirred until homogeneous transparent liquid；
(2) in antistatic additive, add 40-60 DEG C of deionized water of its quality 10-15 times, be stirred until homogeneous transparent liquid；
(3) by whole hydroxypropylation modified starches, polyaminoester emulsion, acrylic acid ester emulsion, vegetable oil, coupling agent, light
Bright dose, emulsifying agent, Polyethylene Glycol, polyvinyl alcohol, defoamer add the deionized water of its quality 100 times, stir；
(4) all substances of above-mentioned steps gained are mixed, stir, regulate solid content, obtain the present invention's
Wetting agent.
Claims (10)
1. a glass fiber infiltration agent, it is characterised in that be made up of the component of following weight portion:
Hydroxypropylation modified starch 40-50 part, polyaminoester emulsion 20-30 part, acrylic acid ester emulsion 10-20 part, vegetable oil 5-8
Part, coupling agent 3-5 part, lubricant 0.5-2 part, brightener 0.5-1 part, emulsifying agent 0.5-1 part, Polyethylene Glycol 0.5-2 part, poly-second
Enol 0-0.5 part, antistatic additive 0-0.5 part, defoamer 0.5-1 part, water is appropriate.
Glass fiber infiltration agent the most according to claim 1, it is characterised in that be made up of the component of following weight portion:
Hydroxypropylation modified starch 40 parts, polyaminoester emulsion 20 parts, acrylic acid ester emulsion 10 parts, vegetable oil 5 parts, coupling agent 3 parts,
Lubricant 0.5 part, brightener 0.5 part, emulsifying agent 0.5 part, Polyethylene Glycol 0.5 part, polyvinyl alcohol 0.1 part, antistatic additive 0.1
Part, defoamer 0.5 part, water is appropriate.
Glass fiber infiltration agent the most according to claim 1, it is characterised in that be made up of the component of following weight portion:
Hydroxypropylation modified starch 50 parts, polyaminoester emulsion 30 parts, acrylic acid ester emulsion 20 parts, vegetable oil 8 parts, coupling agent 5 parts,
Lubricant 2 parts, brightener 1 part, emulsifying agent 1 part, Polyethylene Glycol 2 parts, polyvinyl alcohol 0.5 part, 0.5 part of antistatic additive, defoamer 1
Part, water is appropriate.
Glass fiber infiltration agent the most according to claim 1, it is characterised in that be made up of the component of following weight portion:
Hydroxypropylation modified starch 45 parts, polyaminoester emulsion 25 parts, acrylic acid ester emulsion 16 parts, vegetable oil 7 parts, coupling agent 4 parts,
Lubricant 1.3 parts, brightener 0.8 part, emulsifying agent 0.7 part, Polyethylene Glycol 1.1 parts, polyvinyl alcohol 0.2 part, antistatic additive 0.2
Part, defoamer 0.8 part, water is appropriate.
Glass fiber infiltration agent the most according to claim 1, it is characterised in that be made up of the component of following weight portion:
Hydroxypropylation modified starch 47 parts, polyaminoester emulsion 22 parts, acrylic acid ester emulsion 13 parts, vegetable oil 6 parts, coupling agent 3.5
Part, lubricant 0.9 part, brightener 0.6 part, emulsifying agent 0.9 part, Polyethylene Glycol 1.7 parts, polyvinyl alcohol 0.4 part, antistatic additive
0.4 part, defoamer 0.6 part, water is appropriate.
Glass fiber infiltration agent the most according to claim 1, it is characterised in that described coupling agent is silane coupler.
Glass fiber infiltration agent the most according to claim 1, it is characterised in that described defoamer is phosphate ester defoamer.
Glass fiber infiltration agent the most according to claim 1, it is characterised in that described lubricant is imidazoline sun profit
Lubrication prescription.
Glass fiber infiltration agent the most according to claim 1, it is characterised in that described antistatic additive is by lithium nitrate, chlorine
Change lithium, ammonium chloride and anti-static agent SN form, and wherein in lithium nitrate, lithium chloride, ammonium chloride, mass ratio with anti-static agent SN is 1:
0.5-1:0.5-1:0.02-0.15.
Glass fiber infiltration agent the most according to claim 1, it is characterised in that described glass fiber infiltration agent uses
Following method is prepared from, and specifically includes following steps:
(1) in lubricant, add 80-90 DEG C of deionized water of its quality 10-15 times, be stirred until homogeneous transparent liquid；
(2) in antistatic additive, add 40-60 DEG C of deionized water of its quality 10-15 times, be stirred until homogeneous transparent liquid；
(3) by whole hydroxypropylation modified starches, polyaminoester emulsion, acrylic acid ester emulsion, vegetable oil, coupling agent, brightener,
Emulsifying agent, Polyethylene Glycol, polyvinyl alcohol, defoamer add the deionized water of its quality 100 times, stir；
(4) all substances of above-mentioned steps gained are mixed, stir, regulate solid content, obtain the infiltration of the present invention
Agent.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610614590.6A CN106277847A (en) | 2016-07-29 | 2016-07-29 | A kind of glass fiber infiltration agent |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610614590.6A CN106277847A (en) | 2016-07-29 | 2016-07-29 | A kind of glass fiber infiltration agent |
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Cited By (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107365091A (en) * | 2017-08-02 | 2017-11-21 | 山东玻纤集团股份有限公司 | One kind enhancing thermoplasticity short glass fiber size |
| CN108585547A (en) * | 2018-07-19 | 2018-09-28 | 安徽省绩溪县华宇防火滤料有限公司 | A kind of glass fibre high efficiency infiltration agent composition |
| CN108585546A (en) * | 2018-07-19 | 2018-09-28 | 安徽省绩溪县华宇防火滤料有限公司 | A kind of glass fibre infiltration glue |
| CN108726897A (en) * | 2017-04-21 | 2018-11-02 | 巨石攀登电子基材有限公司 | A kind of electronic-grade glass yarn secondary slurry, the glass fiber yarn through its starching and corresponding glass fabric |
| CN108821611A (en) * | 2018-08-09 | 2018-11-16 | 苏州华龙化工有限公司 | A kind of glass fibre interface fiber size for reinforcemeent and preparation method thereof |
| CN109095790A (en) * | 2018-11-07 | 2018-12-28 | 安徽省绩溪县华宇防火滤料有限公司 | A kind of high-quality glass fiber infiltration agent |
| CN110218002A (en) * | 2019-05-17 | 2019-09-10 | 重庆天泽新材料有限公司 | A kind of glass fiber infiltration agent and preparation method thereof |
| CN113150388A (en) * | 2021-04-23 | 2021-07-23 | 江西宏柏新材料股份有限公司 | Method for modifying glass fiber by using cyano silane coupling agent and application of modified glass fiber |
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| Publication number | Priority date | Publication date | Assignee | Title |
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| CN108726897A (en) * | 2017-04-21 | 2018-11-02 | 巨石攀登电子基材有限公司 | A kind of electronic-grade glass yarn secondary slurry, the glass fiber yarn through its starching and corresponding glass fabric |
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| CN107365091A (en) * | 2017-08-02 | 2017-11-21 | 山东玻纤集团股份有限公司 | One kind enhancing thermoplasticity short glass fiber size |
| CN108585547A (en) * | 2018-07-19 | 2018-09-28 | 安徽省绩溪县华宇防火滤料有限公司 | A kind of glass fibre high efficiency infiltration agent composition |
| CN108585546A (en) * | 2018-07-19 | 2018-09-28 | 安徽省绩溪县华宇防火滤料有限公司 | A kind of glass fibre infiltration glue |
| CN108821611A (en) * | 2018-08-09 | 2018-11-16 | 苏州华龙化工有限公司 | A kind of glass fibre interface fiber size for reinforcemeent and preparation method thereof |
| CN109095790A (en) * | 2018-11-07 | 2018-12-28 | 安徽省绩溪县华宇防火滤料有限公司 | A kind of high-quality glass fiber infiltration agent |
| CN110218002A (en) * | 2019-05-17 | 2019-09-10 | 重庆天泽新材料有限公司 | A kind of glass fiber infiltration agent and preparation method thereof |
| CN113150388A (en) * | 2021-04-23 | 2021-07-23 | 江西宏柏新材料股份有限公司 | Method for modifying glass fiber by using cyano silane coupling agent and application of modified glass fiber |
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Application publication date: 20170104 |
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