CN106259549B

CN106259549B - Air purification composition

Info

Publication number: CN106259549B
Application number: CN201610645131.4A
Authority: CN
Inventors: 王婧宁
Original assignee: Individual
Current assignee: Shanghai Borunke Biotechnology Co ltd
Priority date: 2016-08-08
Filing date: 2016-08-08
Publication date: 2017-05-17
Anticipated expiration: 2036-08-08
Also published as: CN106259549A; WO2018028275A1

Abstract

The invention provides an air purification composition. The air purification composition is prepared from, by weight, an extract of a mixture of saponin and fresh orange peels, an extract of a mixture of chinaberry and robinia pseudoacacia, an extract of a mixture of Italy black populous nigra and eucalyptus, 2-8 parts of a chrysanthemum extract, 0.1-3 parts of artemisinin, 4-8 parts of sophocarpidine, 0.1-1 part of tea tree essential oil and 0.1-1 part of a vanilla extract.

Description

Air purifying composition

Technical field

The present invention relates to a kind of air purifying composition, more particularly to a kind of purification of air combination containing plant extracts Thing, more further to B01D fields.

Background technology

With gradually stepping up for living standard, the quality of opposite air ambient is but gradually reduced, the requirement to purification of air Also more and more higher.The principle of the purification of air for existing at this stage has three kinds：Absorbent-type, covering type and breakdown type.Absorbent-type air Cleanser is gone using performances such as the physical absorption similar to materials such as activated carbons, chemisorbed, oxidation, catalysis oxidation and reduction Except pollutants in air.The shortcoming of this kind of air purifying preparation be can not long-term use, it is necessary to regularly replace air purifying preparation, while Pollutant is still pollutant, and inorganic matter is not decomposed into further.Covering type air purifying preparation is fragrant using having The material that the volatile materials of taste will have peculiar smell is covered, so as to artificial into a kind of illusion of purification of air.Breakdown type is empty Gas cleanser is that have similar to TiO in air purifying preparation₂Material, can be under the irradiation of sunshine and oxygen or moisture Son generation hydroxyl radical free radical and superoxide radical, hydroxyl radical free radical and superoxide radical have very strong redox ability, from And harmful substance in air can be carried out oxidation Decomposition, the advantage of such air purifying preparation can be by the pollutant in air Oxidation Decomposition is carried out, has the disadvantage that the energy gap of titanium dioxide reaches more than 3.0, this kind of oxidation can be just carried out under ultraviolet light The reaction of reduction.

Regarding to the issue above, the present invention provide one kind can slowly discharge, with sterilizing ability, again can with long-term use, Without the air purifying composition changed.

The content of the invention

First aspect present invention provides a kind of air purifying composition, and by weight, it is included：

The extract of gleditsia sinensis and fresh orange peel mixture；With

China tree and the extract of locust tree mixture；With

Italian black poplar and the extract of eucalyptus mixture；With

The chrysanthemum extract of 2-8 weight portions, the qinghaosu of 0.1-3 weight portions, the matrine of 4-18 weight portions, 0.1-1 weights Measure the tea tree ethereal oil, the vanilla extract of 0.1-1 weight portions of part；

Wherein gleditsia sinensis is 1-10 weight portions, and fresh orange peel is 10-20 weight portions, and China tree is 3-14 weight portions, and locust tree is 5-15 Weight portion, Italian black poplar is 0.1-5 weight portions, and eucalyptus is 0.1-4 weight portions.

Used as one embodiment of the present invention, described air purifying composition, by weight, it is included：

The extract of gleditsia sinensis and fresh orange peel mixture；With

China tree and the extract of locust tree mixture；With

Italian black poplar and the extract of eucalyptus mixture；With

The chrysanthemum extract of 2-7 weight portions, the qinghaosu of 0.1-2.5 weight portions, the matrine of 4-16.5 weight portions, 0.1- The tea tree ethereal oil of 0.5 weight portion, the vanilla extract of 0.5-1 weight portions；

Wherein gleditsia sinensis is 1-8.5 weight portions, and fresh orange peel is 10-18.5 weight portions, and China tree is 3-12 weight portions, and locust tree is 8- 15 weight portions, Italian black poplar is 0.1-3.5 weight portions, and eucalyptus is 0.1-3.5 weight portions.

Used as one embodiment of the present invention, the air purifying composition is also included：

The weight ratio of 5-10 weight portions is 1：1.5：2：The spontaneous fermentation of 2.8 grape fruit, peppermint, aloe and fresh orange peel is produced Thing mixture.

As one embodiment of the present invention, the preparation method of the extract of the gleditsia sinensis and fresh orange peel mixture be by , by weight mixing, explosion is crushed to 100-200 mesh, and 2-mercaptobenzothiazole blending, uses ethanol conduct for gleditsia sinensis and fresh orange peel Solvent is extracted.

Used as one embodiment of the present invention, the preparation method of the extract of the China tree and locust tree mixture is：Will China tree and locust tree are cleaned, chopping, after being soaked with ammoniacal liquor, add ethanol, and flow back 1-3h, filters while hot, are concentrated into without ethanol, i.e., .

As one embodiment of the present invention, the preparation method of the extract of the Italian black poplar and eucalyptus mixture For：Italian black poplar and eucalyptus powder are weighed, ethanol is added, extracting through microwave heating is used 2-3 times after immersion 2-3h, filtering, filter Liquid is obtained final product through being concentrated under reduced pressure into without ethanol.

Used as one embodiment of the present invention, the tea tree ethereal oil is obtained by extraction by the way of distillation.

Used as one embodiment of the present invention, the composition is also included：The particle diameter of 0.01-0.1 weight portions is in 1-3nm The nano-Ag particles of left and right.

Used as one embodiment of the present invention, the composition is also included：Spearmint and numb seed extract.

The second aspect of the present invention provides a kind of air purifying preparation, and it is prepared by above-mentioned air purifying composition.

Specific embodiment

The participation in the election detailed description for being preferable to carry out method of the invention below and including embodiment this hair can be more easily understood Bright content.Unless otherwise defined, all technologies used herein and scientific terminology have common with art of the present invention The identical implication that technical staff is generally understood that.When there is contradiction, the definition in this specification is defined.

As used herein term " by ... prepare " it is synonymous with "comprising".Term "comprising" used herein, " including ", " having ", " containing " or its any other deformation, it is intended that cover including for non-exclusionism.For example, the combination comprising listed elements Thing, step, method, product or device are not necessarily limited to those key elements, and can be including not expressly listed other key elements or This kind of composition, step, method, product or the intrinsic key element of device.

Conjunction " Consists of " excludes any key element do not pointed out, step or component.If be used in claim, this Phrase will make claim be closed, it is not included the material in addition to the material that those are described, but relative normal Except rule impurity.When phrase " Consists of " is appeared in be rather than immediately following after theme in the clause of claim main body, It is only limited to the key element described in the clause；Other key elements are not excluded outside as the overall claim.

Equivalent, concentration or other values or parameter are excellent with scope, preferred scope or a series of upper limit preferred values and lower limit During the Range Representation that choosing value is limited, this is appreciated that and specifically discloses by any range limit or preferred value and any scope All scopes that any pairing of lower limit or preferred value is formed, regardless of whether whether the scope separately discloses.For example, when open During scope " 1 to 5 ", described scope should be interpreted as including scope " 1 to 4 ", " 1 to 3 ", " 1 to 2 ", " 1 to 2 and 4 to 5 ", " 1 to 3 and 5 " etc..When number range is described herein, unless otherwise indicated, otherwise the scope is intended to include its end Value and all integers and fraction within the range.

Singulative includes that plural number discusses object, unless the context clearly dictates otherwise.It is " optional " or " any It is a kind of " refer to that the item that describes thereafter or event may or may not occur, and the description include situation that event occurs and The situation that event does not occur.

Approximate term in specification and claims is used for modifying quantity, represents that the present invention is not limited to this specific Quantity, also including the acceptable part without cause the amendment of the change of related basic function close to the quantity.Phase Answer, a numerical value is modified with " about ", " about " etc., mean the invention is not restricted to the exact numerical.In some examples, approximately Term likely corresponds to the precision of the instrument of measured value.In present specification and claims, scope is limited can be with Combine and/or exchange, these scopes include all subranges contained therebetween if not stated otherwise.

Additionally, the indefinite article " one kind " and " one " before key element of the present invention or component are to key element or the quantitative requirement of component (i.e. occurrence number) unrestriction.Therefore " one " or " one kind " should be read as including one or at least one, and odd number The key element or component of form also include plural form, unless the obvious purport of the quantity refers to singulative.

" polymer " means the polymerizable compound prepared by the monomer by the identical or different type that is polymerized.Generic term " polymer " includes term " homopolymers ", " copolymer ", " terpolymer " and " EVA ".

" EVA " means the polymer prepared by least two different monomers that are polymerized.Generic term " EVA " includes (its is general with term " terpolymer " for term " copolymer " (it is typically used to refer to the polymer prepared by two kinds of different monomers) It is used to refer to the polymer prepared by three kinds of different monomers).Its polymerization for also being manufactured comprising monomer is planted by polymerization four or more Thing." blend " means the polymerization that two or more polymer is mixed and formed jointly by physics or chemistry method Thing.

The first aspect of the present invention provides a kind of air purifying composition, and by weight, it is included：

The extract of gleditsia sinensis and fresh orange peel mixture；With

China tree and the extract of locust tree mixture；With

Italian black poplar and the extract of eucalyptus mixture；With

Italian black poplar

Italian black poplar is also known as Italian willow, and megaphanerophyte of falling leaves, tree crown long avette, bark taupe is shallow to split.Blade three It is angular.

In the present invention, the extract of the Italian black poplar is ground, powder to obtain Italian black poplar limb It is broken.The powder of Italian black poplar is added in ethanol, immersion uses extracting through microwave heating 2-3 times after 2-3 hours, filtering, filter Liquid is obtained final product through being concentrated under reduced pressure into without ethanol.

Microwave is electromagnetic wave of the frequency about in 300MHz~300GHz, i.e. wavelength in the range of 100cm~1mm, its position In electromagnetic spectrum (light wave) and radio wave between.Microwave is a very special electromagnetic wave band, the approximate sunshine of its performance Property, velocity of wave is identical with the light velocity, is all 3 × 10⁸M/s, wavelength is 12.24cm, and frequency of oscillation is 24.5 hundred million times per second.

Microwave abstracting, also known as microwave auxiliary extraction refer to that the fuel factor of main applied microwave is entered to sample and its organic solvent Row heating, a kind of method that component to be measured is extracted from sample matrices.From macroscopically saying, microwave abstracting is actually main Be microwave to extractant and the heat effect of sample, it can penetrate extractant and material makes whole system more uniformly Heating：From microcosmic, electromagnetic field acceleration diffusion rate of the sample to extractant interface produced by microwave.

The mechanism of microwave abstracting can be from from the aspect of two：On the one hand, the electromagnetic field produced by microwave accelerates to be extracted part To extractant interface diffusion rate, when using water as solvent, under microwave field, hydrone high-speed rotation turns into excitation state to composition, This is a kind of high-energy unstable state, or hydrone gasification, strengthens the driving force of extracted component；Or hydrone is released in itself Exoergic amount returns to ground state, and the energy transmission for being discharged gives other material molecules, accelerates its warm-up movement, shortens the molecule of extracted component The time at extractant interface is diffused into by sample interior, so that extraction rate improves several times, while also reducing extraction temperature Degree, ensures the quality of extraction to greatest extent.On the other hand, microwave energy is that a kind of rotation by Ion transfer and dipole causes molecule The non-ionising radiation energy of motion.When it is acted on molecule, the rotational motion of molecule is promoted, if molecule now has one Fixed polarity, instantaneous polarization is just produced under microwave electromagnetic field action, and does reversal with the speed of 24.5 hundred million times/second and transported It is dynamic, so as to produce the phase mutual friction between the vibration of key, tear and particle, collision, promote molecular activity part (polar portion) Better contact with and react, while being quickly generated substantial amounts of heat energy.Due to absorbing microwave energy, cell interior temperature rises rapidly, Its cell interior pressure is set to exceed cell wall expansion ability to bear, cell rupture.Intracellular active ingredient freely flows out, shorter Time in spe medium be captured and dissolve.

Locust tree extract

Locust tree, also known as acacia, pulse family, robinia deciduous tree, bark taupe are shallow to split to deep lobe to dark brown, dilute It is smooth.By assortment, locust tree is divided into straight-bar locust tree, gold leaf locust tree, bent scolus Chinese scholartree, column locust tree, spherical crown locust tree, tortoise plastron skin again Locust tree, safflower locust tree, stingless locust tree, leaflet locust tree, arrow shaft locust tree, yellow leaf locust tree, ball Chinese scholartree, pink blossom locust tree and deep gloomy Chinese scholartree.

In the present invention, the locust tree selection gold leaf locust tree, pink blossom locust tree and safflower locust tree are 0.5 according to weight part ratio： 0.8：1.2 blendings are extracted.

The leaf and flower of the locust tree extract preferred pair locust tree are extracted.

The preparation method of specific locust tree extract is as follows：

1st, by the leaf of the leaf of gold leaf locust tree, the leaf of pink blossom locust tree and safflower locust tree according to weight part ratio be 0.5： 0.8：1.2 blendings, clean, chopping, after then being moistened with ammoniacal liquor, add ethanol, flow back 1-3 hours, filter while hot, are concentrated into nothing Ethanol, obtains final product the extract of the leaf of locust tree.

2nd, by the flower of the flower of gold leaf locust tree, the flower of pink blossom locust tree and safflower locust tree according to weight part ratio be 0.5：0.8：1.2 Blending, clean, chopping, add honey, flow back 1-3 hours, filter while hot, are concentrated into without ethanol, obtain final product the extraction of the flower of locust tree Thing.

3rd, by the extract blending of the extract of the leaf of locust tree and flower in step 1 and step 2, ethanol, ultrasonic agitation are added 2.5 hours, it is concentrated into without ethanol, obtains final product the extract of locust tree.

Extractives From Melia Azedarach L

China tree is the magaphanerophytes of Meliaceae Melia, also known as bitter Siberian cocklebur, FRUCTUS TOOSENDAN, Zhan wingceltises, gloomy tree.The compound found in China tree Type has phenolic constituent, terpene, steroidal and neolignan.China tree is high 10-20 meters, bark crineous, lobe, old branch purple.

Used as one embodiment of the present invention, the Extractives From Melia Azedarach L is azedarach, chinaberry and China tree according to weight Amount part is 1.2：0.5：0.8 mixing is extracted.

Azedarach is the dry root skin and bark of China tree, season in spring and autumn two strips, dries, or removes tertia, is dried, also known as Chinaberry wood skin, chinaberry branch skin, the white skin of margosa, eastbound chinaberry root white skin, chinaberry skin, chinaberry root skin, chinaberry root wood skin, melia.Azedarach In main composition be triterpenes, flavonoids, phenoloid.Mainly there be triterpene substance in azedarach：China tree terpene ketone lactone, China tree terpene alcoholic lactone, azedarach terpene ketone, China tree terpene acid methyl esters, print chinaberry ripple spirit A, print chinaberry ripple spirit B, Ash skin ketone, Ge Youning, chinaberry Triol etc..

Except triterpene compound, some other compounds is also contained in azedarach, for example：Forulic acid tetracosanol Ester, forulic acid pentacosyl alcohol ester, forulic acid hexacosyl alcohol ester, forulic acid heptacosanol ester, cluytyl ferulate, paddy steroid Alcohol, stigmasterol and campesterol.

Azedarach bitter, cold in nature, Return liver, spleen, stomach is the good medicine of desinsection eliminating dampness.Roundworm is cured mainly, pinworm can be also driven, controlled Urticaria heat toxin, rubella dislikes sore, its simultaneous energy heat-clearing and damp-drying drug.

Chinaberry is the dry mature fruit of China tree, and its is bitter in taste, is trembled with fear, poisonous, Return liver, spleen, stomach.Contain hardship in fruit Chinaberry ketone, melianol, chinaberry lactone, 7- tricosanols, cachou extract, lupeol, cupreol, cupreol -3-O- Glycoside, vanillic aldehyde, cinnamic acid, seed of Azadirachta indica element, 1- cinnamyl chinaberry alcohol ketone, chinaberry glycol, melianoninol.In seed New element -1, the 5- diene -3-O-L- rhamnopyranoses of the β -15- epoxies chinaberry of -11- hydroxyl -7- of acetoxyl group containing 6- ketone groups -14 Glucoside, prints chinaberry Sha Lanlin, prints chinaberry moral woods, new element -1, the 5- diene -3-O- of the β -15- epoxies chinaberry of 6- acetoxyl group -7- ketone groups -14 D- xylopyranose glucosides, new element -1, the 5- diene -3-O- pyrans Portugal of the β 15- epoxies chinaberry of 6,11- diacetoxy -7- ketone groups -14 Grape glucoside.Seed oil contains various aliphatic acid, and wherein unsaturated acids accounts for 85%, and main component is linoleic acid, oleic acid；Fruit oil contains Myristic acid, linoleic acid, oleic acid, palmitic acid, palmitoleic acid.

China tree is that drying for China tree is spent, and has many compositions in China tree, for example：Octane, 2,6- dimethyl heptanes, 2,5- Dimethyl heptane, 2- methyl-propyls pentamethylene, 2- methyloctanes, hexanal, 3- methyloctanes, 2,2,4- trimethylheptanes, 2,2, 6- trimethylheptanes, 3,3- dimethyl octane, 2,3,6- trimethylheptanes, 2,2,2,6- tetramethyls base heptane, 2,2,4,6,6- five Methyl heptane, 2,5,6- trimethyls octane, 2,2,7- trimethyls nonane, 2,2,6- trimethyls octane, 1,2,3- trimethylbenzenes, 2,6- Dimethyl octane, 2,2,11,11- tetramethyls dodecane, 3,7- dimethylnonanes, 2,6- dimethyl hendecane, 2,2,4- front threes Base decane, 3,6- dimethyl hendecane, 2,7- dimethyl hendecane, 2,9- dimethyl hendecane, 2,2,3- trimethyls nonane, 2, 8- dimethyl hendecane, 2,8,8- norfarnesanes, aldehyde C-9, the tetradecane, 2,2,8- norfarnesanes, ring hendecane, 1, 4- dimethoxy benzenes, ten aldehyde, hexadecane, cloves alkene, 1S, the ring of 2S, 5R-1,4,4- trimethyl three, dodecylene, pentadecane, 3, Carbon triolefin -3- the alcohol of 7,11- trimethyls -1,6,10- 12, nerolidol, ledol, acetic acid (3,7,11- trimethyl -1,6, 10-) enol ester of 12 carbon three, the ketone of 6,10,14- trimethyls -2- 15,2- methyl octadecane, adjacent dibenzoic acid diisobutyl ester, ten Nine alkane, 2,6,10- trimethyl tetradecyls, Palmitic acid, 2- methyl eicosane, 3,7,11,15- tetramethyl -2- hexadecylenes alcohol, two Ten alkane, Palmitic acid butyl ester, 3,7,11,15- tetramethyl -2- hexadecylenes alcohol, volatile oil extracted from eucalyptus' leaves or twigs enol, heneicosane, lignocerane, 20 Five alkane, Palmitic acid isobutyl ester, Palmitic acid cyclohexyl, 2,21- dimethyl docosane, adipic acid two (2- ethyls) own ester, 9- butyl docosane, octacosane.

In the present invention, the specific preparation method of the Extractives From Melia Azedarach L is：By azedarach, chinaberry and China tree according to weight Amount part is 1.2：0.5：0.8 blending, cleans, chopping, after being soaked with ammoniacal liquor, adds ethanol, and flow back 1-3h, filters while hot, concentrates To without ethanol, obtain final product.

Eucalyptus extracts

Eucalyptus, also known as You Jiali trees, is the general designation of Myrtaceae cup fruit tree category, umbrella room category and eucalyptus, original producton location print The ground such as Buddhist nun and Australia.Eucalyptus has many types, for example, have arid sclerophyll high forest type, moistening sclerophyll arbor type, dilute Tree Types of Grassland, arid sclerophyll arbor type, mesophorbium, coryphile type.

Heretofore described eucalyptus extracts are that eucalyptus leaves and eucalyptus barks are 1 according to weight portion：1.3 blendings, extract.

Main composition is pentacyclic triterpene compound in eucalyptus barks, for example malol, betulinic acid, oleanolic acid, ursolic acid, Betulic acid, birch resin acid, betulonic acid, 3- β-O- are trans to hydroxy cinnamate acyl group -12- alkene -28- oleanolic acids, 3- β-O- It is trans to -2 σ of hydroxy cinnamate acyl group-hydroxyl -12- alkene stamen-ursolic acid.

Eucalyptus leaf volatile oil main component is 1,8- Cineoles, firpene, aromadendrene, cumaldehyde, pinocarveol and 1- acetyl -4- Isopropylidene cyclopentene etc., but containing rutin, quercitrin, Quercetin, homoserine, also separate eucalyptin.In folium eucalypti other into Point, such as terpene, flavonoids, tannin, phloroglucinol derivatives and glycoside also have abundant bioactivity.

Used as a kind of preferred embodiment of the invention, in the present invention, the eucalyptus barks are selected from eucalyptus robusta and Eucalyptus urophylla, and both Weight ratio is 1：3.

Used as a kind of preferred embodiment of the invention, in the present invention, the eucalyptus leaves is selected from alpine ash, gray gum and Liu An, and The eucalyptus leaves is plucked by spring, and the age of tree is life in 3 years；As one embodiment of the present invention, the alpine ash, gray gum and willow The weight ratio of eucalyptus is 1：1.5：1.3.

The preparation method of the eucalyptus extracts is：Weigh synthesis weight than eucalyptus barks and eucalyptus leaves powder, add Ethanol, extracting through microwave heating is used 2-3 times after immersion 2-3h, filtering, and filtrate obtains final product through being concentrated under reduced pressure into without ethanol.

Fructus Gleditsiae Abnormalis extract

Gleditsia sinensis, also known as Chinese honey locust, Gleditsia officinalis belongs to Rosales, pulse family deciduous tree or dungarunga,

Chinese honey locust is containing triterpenoid saponin, tannin, ceryl alcohol, nonacosane, stigmasterol, sitosterol etc..Saponin(e element contained in Chinese honey locust It is triterpene alkenes and oligosaccharide.The chemical composition of Chinese honey locust is mainly terpene, flavonoids, phenolic acid class, steroid etc..

Pod soap containing triterpene formula：Gledinin, glucoside glucoside unit is gledigenin, gleditschiasaponin.Still containing cerinic acid, nonacosane, just Heptacosane, stigmasterol, sitosterol, tannin etc..Saponin has gledinin, and glucoside unit and gleditschiasaponin are obtained after hydrolysis, and glucoside is obtained after hydrolysis Unit and arabinose.Additionally, still containing ceryl alcohol, nonacosane, stigmasterol, sitosterol etc..

In the present invention, the Fructus Gleditsiae Abnormalis extract is that the pod of gleditsia sinensis, seed, scolus three are extracted；The change of Chinese honey locust Study point predominantly terpene, flavonoids, phenolic acid class, steroid etc..

Terpene：Terpenoid is mainly pentacyclic triterpene and its glucoside compound in Chinese honey locust plant, for example：Sapogenin is pierced Capsule acid, oleanolic acid, echinocystic acid, rhamnose, glucose, arabinose, xylitol.

Flavonoids：Flavonoids is, for example, double hydrogen Kaempferols, Eriodictyol, Quercetin, 3,3 ', 5,5 ' in gleditsia sinensis plant, 7- penta hydroxy groups flavanonol, epicatechin.

Phenolic acid compound：Progallin A, caffeic acid, 3-O- methyl ellagic acid -4 '-(5 '-acetyl group)-α-L- Ahs The phenolic acid compounds such as the primary glucosides of the drawing,-O- alpha-L-rhamnosides of 3-O- methyl ellagic acid -4 ', wherein 3-O- methyl ellagic acid - 4 '-(5 "-acetyl group)-α-L-arabinose glycosides.

Steroid compound：Stigmasterol, cupreol etc. are separated in Chinese honey locust.

Polysaccharide：Arabin, galactomannans and galactan.

In the present invention, the method for the Fructus Gleditsiae Abnormalis extract is：Gleditsia sinensis explosion is crushed to 100-200 mesh, and 2- sulfydryl benzene And thiazole is blended, and is extracted as solvent with ethanol.

Fresh orange peel extract

The main component of fresh orange peel is the monocyclic terpenes for being limonene (metering system cyclohexene), and boiling point is 175.5-176 DEG C, with oranges and tangerines (lemon) fruit aroma, lemon oil is water insoluble in itself, with water arbitrary proportion mixture after addition activating agent.

Contain substantial amounts of vitamin C and essential oil in orange peel, tangerine peel contains volatile oil, and the main component in oil is lemon Alkene, citral, also river dried orange peel ketone, hesperidine, inositol, vitamin B1 etc..There is the stimulation of mitigation to alimentary canal, be conducive to The discharge of gastrointestinal pneumatosis.Promote the secretion of gastric juice；Diastole bronchus.Tangerine peel congee, the power for having regulating qi-flowing for eliminating phlegm, enhancing stomach invigorating nourishing the stomach it Effect.Reducing blood lipid, liter blood pressure or the treatment to acute mastitis.

Orange peel is separated at present to go out more than 30 to plant material, wherein mainly having：Flavonoids, monoterpene, cumarin, carotenoid, Class propyl alcohol, acridone, glycerose lipid etc..

Flavonoids：Flavonoids contained by citrus fruit has three types：I type is the general flavones as representative with rutin Class；II type is hesperidin, aurantiin etc the distinctive flavanones of citrus fruit；III type be in other vegetable and fruits so far not yet It was found that and the special Flavonoid substances containing polymethoxy such as tangeritin that only citrus just has.

Carotenoids：It is well known that contain carotenoid in many veterinary antibiotics, this be have to health it is important The composition of effect.Quickly, China has also utilized this kind of thing to the research developed recently of physiological function and its mechanism to carotenoid Matter is developed into some health foods and realizes industrialized production.

Cumarin：Contained cumarin is the cancer-resisting substance affirmed fully by scientist at present in oranges and tangerines.Research knot Fruit shows that the anti-cancer function forming feature of cumarin mainly has two：One is that cumarin makes cancer material solution by the effect of detoxication enzyme Poison；Two is the activation for suppressing its metabolism with cancer material antagonism.The main initial period in cancer of effect of these two aspects produces suppression Effect processed.

Contain a large amount of terpenoids with limonene as representative in monoterpene, triterpene oranges and tangerines.Terpene is to constitute the unique virtue of oranges and tangerines Fragrant material, with the effect for making the nervous centralis calmnessization of people.

Limonin：Limonin is the bitter principle of orange peel.

In the present invention, the preparation method of the orange bark extract is：Fresh orange peel explosion is crushed to 100-200 mesh, and 2- Mercaptobenzothiazoler is blended, and is extracted as solvent with ethanol.

Chrysanthemum extract

Chrysanthemum, is the perennial herb plant of composite family, Chrysanthemum in Plant Taxonomy.It is divided into bull by planting form Chrysanthemum, the solely cultivated form such as this chrysanthemum, Chrysanthemum morifolium Ramat, cliff chrysanthemum, skill chrysanthemum, Desk Chrysanthemum Applying.It is cool in nature, bitter, pungent, Return liver, the heart channel of Hang-Shaoyin.

The chemical composition of chrysanthemum is divided into：Volatile oil component, flavones ingredient, liposoluble ingredient and other compositions.

The composition of volatile oil is mainly monoterpene alkenes, sesquiterpene and its containing oxygen derivative and aliphatic compound etc., Also containing chrysanthemum lactone, chrysanthemum alcohol, chrysanthemum triol, chrysanthemum ketone, cis- helicene alcohol ether, trans- helicene alcohol ether, Radix Angelicae Sinensis acyl ambrosin B, Radix Angelicae Sinensis acyl Asia chrysanthemum element, Scotland artemisin A, ambrosin A, ursolic acid, cupreol etc..

Flavones ingredient：Main component has wooden slippers glycosides displayed, linarin, cyanidenon, apiolin, acacetin -7- mouse Lee's sugar glycoside, cyanidenon -7- glycosides, Quercetin glucoside, apigenin-7-O-beta-D-glucopyranoside, spiceleaf wood Element -7-O- β-D- the glucopyranosides,-O- β-D- glucopyranosides of Quercetin -3,7- two, eriodictyol -7-O- β-D- glucopyranoses Thuja acid, 1- phenyl -2,3- butanediol -3-O- β-D- glucopyranosides and hesperetin -7-O- beta d glucopyranosiduronic acid glycosides.

Liposoluble ingredient：There are 3-O- caffeoyl quinic acids, 4-O- caffeoyl quinic acids, 5-0- coffee acyl quinines Acid, 3,5-diCQA methyl esters, 3,5-diCQA, 3,5- bis- cis caffeoylquinic acids, 1,5- bis- coffee Coffee acyl quininic acid, 1,3-Dicaffeoylquinic acid and chlorogenic acid etc..

Other compositions：In addition to volatile oil composition, flavones ingredient and liposoluble ingredient, also contain various micro units Element, such as Ca, Mg, Fe, also contain protein, amino acid, choline, stachydrine, purine, tannin, vitamin, chlorophyll, carrot Element, mountain arrow acid glyceride and brown eleostearic acid etc..

The method of chrysanthemum extract has many kinds, for example：Reflux extraction, ultrasonic extraction, steam distillation, microwave Extraction method, historrhexis's extraction method and supercritical carbon dioxide extraction method.

In the present invention, the chrysanthemum extract mainly uses microwave loss mechanisms：Appropriate chrysanthemum is weighed, is shredded, add ethanol, Extracting through microwave heating is used after immersion 2-3h 2-3 times, filtering, filtrate obtains final product through being concentrated under reduced pressure into without ethanol.

Qinghaosu：

Extract a kind of colourless acicular crystal for obtaining from compound inflorescence plant Artemisia annua, chemical name for (3R, 5aS, 6R, 8aS, 9R, 12S, 12aR)-octahydro -3,6,9- trimethyl -3,12- bridging oxygen -12H- pyrans (4,3-j) -1,2- benzos two fill in - 10 (3H) -one.Molecular formula is C₁₅H₂₂O₅, belong to sesquiterpene lactone, with peroxide bridge and 6- lactonic rings, there is one to include peroxide In interior 1,2,4- tri- oh alkyl structure unit, this is very rare in nature, and 7 chiral centres are included in molecule, and it is special It is A to levy, and B rings are in cis relationship with end of the bridge hydrogen along connection, isopropyl.It is 156-157 DEG C, [a] D17=+66.3 ° of (C=to prepare fusing point 1.64 chloroform).Chloroform, acetone, acetic acid, ethyl ester and benzene are soluble in, ethanol, ether is dissolved in, cold petroleum ether is slightly soluble in, hardly It is dissolved in water.Because it has special peroxy-radical, it is easily influenceed and is decomposed by wet, hot and reducing substances to thermally labile.

In the present invention, the qinghaosu is bought in Shaanxi Sen Lang biochemical industries Co., Ltd.

Matrine

Matrine is made up through Solvent Extract methods such as ethanol of the dry root of legume kuh-seng, plant, fruit, is Alkaloid.Generally Banlangen, its main component has various biologies such as matrine, sophocarpine, N-Oxysophocarpine, Sophoridine Alkali, with matrine, oxymatrine concentration highest.Other sources are subprostrate sophora and subprostrate sophora aerial part, and sterling outward appearance is white Color powder.

Kuh-seng is the root of the dry root of cassia leguminous plant kuh-seng, tool cylinder and the usual bifurcated in bottom, a length of 10-30 lis Rice, a diameter of 1-2.5 centimetres, outward appearance sepia or taupe brown, cork is very thin and often rupture can be bent outwardly, easy fall in flakes Expose the micro- glossiness endothelium of yellow, quality is very hard not to allow frangibility, and section is that yellow-white is in fibroid, and woody part has radial Texture.Alias have water Chinese scholartree, Chinese scholartree and white lotus, its bitter cold in nature enters the heart, spleen, the warp of kidney three, its main chemical compositions be alkaloid and The major class of flavones two, in addition with other compounds such as volatile oil, a small amount of quinones, soaping agents and amino acid.

Most of kuh-seng alkaloid is quinolizidine kind, and minority is Bispiperidines, mainly including matrine, Oxymatrine Alkali, sophocarpine, N-Oxysophocarpine etc., minority are Bispiperidines alkaloid, mainly broom top alkaline, lupin alkaline, the claws of a hawk Beans alkaline, aloperine type and bitter western alkaline of reviving.

Next to that flavones ingredient, comprising most flavanone and flavanone alcohol component, also a small amount of Huang Keto-alcohol, isoflavones, chalcone and its alcohols.At present, anthraquinone, aliphatic acid, amino acid, volatilization are also successfully separated out from kuh-seng Oil, organic acid, sugar, triterpene compound and phenolic compound etc..

Kuh-seng alkaloid belong to quinoline in western pyridine analog derivative alkali, in its alkaloid mainly include matrine, Oxymatrine Alkali, N-Oxysophocarpine etc..Their skeleton structure type is that chemical formula is C₁₅H₂₄N₂The matrine of O, equivalent to monoacidic base, i.e. parent nucleus In there are two nitrogen-atoms, a nitrogen-atoms is amide nitrogen, and another nitrogen-atoms is tertiary amine nitrogen, therefore it has certain alkali Property.

The extracting method of kuh-seng alkaloid has solvent extraction method, macroreticular resin absorbing method, ion-exchange-resin process, ultrasonic wave Extraction method, supercritical fluid extraction, semi-bionic extraction or microwave―assisted extraction.

It is main in the present invention that kuh-seng alkaloid is extracted using supercritical fluid extraction.

Supercritical fluid refers to that material is in a kind of special state for more than its critical-temperature and critical pressure being formed Fluid, is characterized in its various physicochemical properties between gas and liquid and the characteristics of having both concurrently.Shooting flow Body abstraction technique have extraction efficiency high, nontoxic, no solvent residue, it is pollution-free many advantages, such as.By changing operating condition, can The active ingredient in natural products is targetedly extracted, its selectivity more preferably, can increase substantially the quality of extract and carry Take rate, be particularly suited for conventional method cannot separating-purifying natural prodcuts separation and purification.

During extracting operation, material to be extracted is fitted into extractor, after discharging all foreign gases, injects shooting flow Body, and make it under the driving of compressor mechanical, circulated between extractor and separator.From extractor top leave dissolved with molten The high-pressure fluid of matter is throttled through choke valve, its step-down is separated out solute, and enters separator, and solute is arranged from separator bottom Go out, supercritical fluid then enters back into compressor mechanical, extractor is entered after compression and is recycled.

In the present invention, the parameter of main extraction is：Extraction time 3.0h, 55 DEG C of extraction temperature, extracting pressure 35MPa, CO₂ Flow 40-45kg/h.

Tea tree ethereal oil

Tea tree ethereal oil originates in Australia, is the extract of tea tree, topmost chemical composition be to Meng's ethene, dipentene, Limonene, cineol, sesame oil brain, anisoxide.

In the present invention, the tea tree ethereal oil is extract by the way of distillation from spray and tender leaf.

Specifically preparation method is：

1st, tea free is cleaned, is crushed to granularity for 20-80 mesh, add organic solvent, seepage pressure effects, by extract solution mistake Filter；

2nd, above-mentioned filtrate normal pressure is concentrated, recycling design；Vacuum concentration, produces tea tree medicinal extract；

3rd, tea tree medicinal extract is carried out into molecular distillation, successively desolvation and polymer substance, obtain tea tree ethereal oil.

Further, grinding particle size is 40 mesh in above-mentioned steps 1；Organic solvent is petroleum ether, and its consumption is raw tea material 6~9 times of leaf quality.

Above-mentioned steps 2 are specifically included：

Normal pressure is concentrated：Filtrate is added in alembic, heating, while recycling design, be concentrated into vapor (steam) temperature for 40 DEG C when Terminate；

Vacuum concentration：By in concentrate addition evaporative flask, constant temperature water bath is heated, 50 DEG C of heating-up temperature, and evaporative flask rotating speed is 55 turns per minute, vacuum is -0.095MPa, is terminated when dripless is dripped into returnable bottle, and at this moment the material in evaporative flask is Tea tree medicinal extract；

The amount of tea tree medicinal extract is 4%~6% or so of quality of medicinal material, preferably 5%.

The condition of desolvation is in above-mentioned steps 3：40 DEG C of feeding temperature, system vacuum 15Pa, distillation column temperature 50 DEG C, knifing machine rotating speed 250r/min, distillation speed 1ml/min.

The condition of removing polymer substance is in above-mentioned steps 3：50 DEG C of feeding temperature, 25 DEG C of chilling temperature, system vacuum Degree 1.5Pa, distills 125 DEG C of column temperature, knifing machine rotating speed 300r/min, distillation speed 1ml/min.

Used as one embodiment of the present invention, the tea tree ethereal oil is bought in Shanghai Hui En International Trading Company Ltd.

Vanilla extract

Vanilla, is a kind of perennial climbing vine plant also known as vanilla, vanilla, Vanilla annamica, flat leaf vanilla, It is a kind of large-scale orchid family spice berry in typical tropical rain forest.Stem slightly plump or meat, often saves raw 1 piece of leaf and 1 gas life Root.Ye great, meat has short handle, and flakey is deteriorated to sometimes.Raceme is born in axil, and tool number is spent to spending more；Spend generally compared with Greatly, reverse, often have 1 absciss layer between ovary and perianth；Sepal is similar to petal, from life, launches；Hypochil edge Chang Yurui The symphysis of post edge, symphysis part is several up to whole stamen column length sometimes, thus lip is in often horn-like, and front portion does not conform to first portion and often expands Greatly, 3 split sometimes.Fruit is pod shape, and meat does not ftracture or ftractures.The thick exosper of seed tool, it is aptery often in black.

Vanilla Bean contain vanillic aldehyde (or vanillon) and carbon hydrocarbon compound, alcohols, carboxyl compound, esters, The 150-170 kind compositions such as phenols, acids, phenolic ether class and heterocyclic compound.The seed of vanilla contains：

1st, volatile oil composition：Vanilla, vanillic acid, vanillyl alcohol, Acetovanillone, cinnamic acid, cinnamyl alcohol, methyl cinnamic acid Ester, myristic acid, anisic acid, anise alcohol, fennel methyl esters, guaiacol, 4- methyl guaiacol and 4s, parahydroxyben-zaldehyde；

2nd, glucosides constituents：It is glucovanillin glycosides, vanillic acid glucoside, guaiacyl-β-D-Glucose glycosides, right Tolyl-β-D-Glucose glycosides, phenethyl -2- glucosides, p-nitrophenyl glucoside etc..

The extract of vanilla also contains：Ethyl vanillin ether, methyl vanilla ether, to hydroxybenzyl ethyl ester etc..

Vanilla is rare tropical natural perfume material, pod orchid Fruit pod contain vanillic aldehyde (or pandan paste) and carbon hydrocarbon compound, 15 to 17 kinds of compositions such as alcohols, lipid, phenols, acids and heterocyclic compound and amino acid needed by human.Pod is blue with extremely strong The medical effect such as benefit stomach, appetizing, de-swelling, invigorating the spleen, be a kind of natural nourishing beauty treatment good medicine.

Contain more than 200 kinds of volatile materials in vanilla, in addition with many to flavours contributing fixedness component, Wherein topmost fragrance component is vanillic aldehyde.Vanillic aldehyde chemical name is Vanillin, is a kind of white Or light yellow needles.The fragrance components such as vanillic aldehyde are the glucose glycoside materials present in blue or green vanilla bean through glucoside Enzyme hydrolysis and produce.

Vanillic aldehyde containing 1%-2.5% in vanilla bean after fermentation curing.It has been generally acknowledged that 0.75% vanillic aldehyde is molten Liquid has identical aroma strength with the vanilla extract containing 0.25% vanillic aldehyde, it is clear that vanillic fragrance is denseer than vanillic aldehyde Much.Because in vanilla hundreds of other components booster action, what definitely not single vanillic aldehyde to be reached, association Work is made us in the plentiful fine and smooth sense of the vanilla fragrance that same-action is formed so far cannot imitate allotment.Have now been found that some trace contents Confrontation vanilla fragrance is of crucial importance, mainly has：Anisaldehyde, benzaldehyde, heliotropin, vanillic alcohol, vanillyl methyl ether, vanillyl Ether, p-Methoxybenzoic acid methyl ester etc..

Different processing methods cause vanilla fragrance component constitute and content on difference, but generally speaking or include with Under several classes：Alkane (from heptane to docosane etc.), alcohols (benzyl carbinol, geraniol, anise alcohol, vanillyl alcohol, isophytol etc.), phenol Class (phenol, guaiacol etc.), aldoketones (aldehyde, α-heptanone, acetovanillon, parahydroxyben-zaldehyde, vanillic aldehyde, syringaldehyde Deng), esters (acetic acid ethyl ester), phthalic acid isobutyl ester, brown eleostearic acid ethyl ester, ethyl linoleate etc.), acids (acetic acid, isoamyl Acid, n-caproic acid, octanoic acid, vanillic acid, linoleic acid, hexadecanoic acid etc.), also a small amount of benzene, alkene, ethers etc..

The leach extraction method of vanillic active ingredient includes：Conventional solvent extraction, supercritical CO₂Fluid extraction etc..This hair Mainly supercritical CO is used in bright₂The method of fluid extraction is extracted.Actual conditions is：Optimal conditions are：Temperature is 45 DEG C, Pressure is 2.0 × 10⁴KPa, the time is 90 minutes.

Spontaneous fermentation thing

Grape fruit：Grape fruit, also known as grapefruit, belong to Rutaceae, are one of big oranges and tangerines monoids in the world four.Grape fruit is a kind of rue Fragrant section, citrus plant, dungarunga, branch are slightly hung down loosely, without hair.Leaf similar with shaddock leaf with quality, winged petiole is also narrower and short, tender leaf Winged petiole middle arteries by short fine, soft fur.Raceme, rare or single flower axillary；Calyx is without hair；Petal is more slightly smaller than pomelo flower.

The presence of the material such as Polyphenols, terpenes, cumarin and carrotene in grape fruit.Its main component is terpenes Class compound, with limonene as representative, content accounts for the 80%-98% of total amount；There is a small amount of oxygenatedchemicals in essential oil, contain Amount accounts for 1%-10% or so, including materials such as alcohols (linalool etc.), aldehydes (certain herbaceous plants with big flowers aldehyde, citral etc.), ketone and esters.

Peppermint：Peppermint is Labiatae mint, also known as fish mint, luxuriant lotus leaf, rising Yang grass, night breath flower etc..Complete stool has There is strong cooling fragrance, be a kind of adaptability extremely strong, distributed more widely and with the plant resources of special aromatic odor.Peppermint is A kind of important spice berry, its dry aerial parts can be used to be used as medicine, and be one of conventional traditional Chinese medicine of China.On peppermint Record can review earliest in《Tang materia medica》, peppermint have functions that dispelling wind, radiating, removing toxic substances, for treat anemopyretic cold, headache, The diseases such as hot eyes, abscess of throat, toothache.Peppermint is perennial vertical herbage, 10~100cm high, tool section, upright or crawl ground Face.Main chemical compositions are the compounds such as alcohol, ketone, ester, terpenes, terpane class in peppermint.Main composition is left-handed menthones, is contained In 77-87%, levorotatory menthol, content is 10% to amount.Also contain different peppermint, pulegone, menthyl acetate, amphene, lemon Alkene, firpene, piperitenone, decyl acetate, methyl benzoate, β-thujene, 3- amylalcohols, 2- hexenes, 3- octanols, dextrorotation bay Alkene, Cineole, alpha-terpineol, carvol etc..

Aloe：Aloe be Liliaceae drought tolerance herbaceous plant, be distributed mainly on the ground such as Africa, with antibacterial, anti-inflammatory and The effect of defaecation, is usually used in treatment liver heat, flatulence, constipation, headache, wet tinea and calculus etc..Polysaccharide and anthraquinones are new Rich content in fresh aloe, is chief active position.Aloe gel contains substantial amounts of carbohydrate content, is mostly different types of Portugal The mannosan of sweet glycan, wherein acetylation has bioactivity higher.Other monose for containing then for common arabinose, Galactolipin, glucose, mannose and rhamnose etc..Being distributed in anthraquinones in subcutaneous palisade tissue, with barbaloin and reed more Based on luxuriant growth rheum emodin, they are partly combined into glycoprotein with polysaccharide, partly exist in the form of enzyme, such as hydroxyl peptase, peroxidating Oxygenase, cellulase and superoxide dismutase etc., also contain lactic acid, butanedioic acid, malic acid, p-Coumaric Acid, fourth two in aloe Acid and citric acid etc..

Spontaneous fermentation：It is the process fermented using the microorganism in natural environment.

Fermentation step：By grape fruit, peppermint, aloe and fresh orange peel according to certain weight ratio, chopping is put into aseptic triangular flask In, spontaneous fermentation at room temperature.Spontaneous fermentation can experience earlier fermentation, ferment middle and fermentation later stage three phases, wait fermentation Without when substantially foaming rises in liquid, that is, terminate fermentation, take zymotic fluid.

Weight ratio every in grape fruit, peppermint, aloe and fresh orange peel spontaneous fermentation product mixtures is 1 in the present invention： 1.5：2：2.8.

Nano Silver

Silver system nano-particle (Ag NPs) generally has the less particle diameter no more than 100nm, contains 20-15000 silver Atom.Skin effect, quantum effect, small-size effect, great specific surface area that Nano Silver possesses, make it compare other antibacterials Agent has more preferable antibacterial effect, and security is higher, and effect is more longlasting.In addition to antibacterial effect, Nano Silver also has disease-resistant Poison, anti-inflammatory, antitumor, anti-angiogenesis etc. are acted on, therefore Nano Silver is widely used in surgical wound treatment, gynaecology and life Grow many fields such as medical science, burn, medicine equipment, weaving, purification of water quality, room spray agent.

In the present invention, the preparation method of the nano silver particles can mainly be occurred under conditions of illumination point using silver nitrate Solution reaction, the silver-colored simple substance of reaction generation.

Main preparation method：The aqueous solution of silver nitrate is placed under agitation and irradiates 10-20 minutes under ultraviolet source, i.e., Can obtain nano silver particles.

The ultraviolet source is tungsten lamp, hydrogen lamp, xenon lamp, helium lamp or krypton lamp.

Used as one embodiment of the present invention, the concentration of silver nitrate is 0.16-16g/L in the silver nitrate aqueous solution.

Used as a kind of preferred embodiment of the invention, the concentration of silver nitrate is 1.6-4.8g/L in the silver nitrate aqueous solution.

Spearmint

Spearmint, also known as spearmint, savoury, spearmint, blue or green peppermint, Mentha spicata L, tomentosecalyx elsholtzia leaf.It is that a kind of Labiatae is straight Vertical herbaceos perennial, stem is upright, purple or white flowers, the month at florescence 7-9.Acclimation temperature scope is big, happiness moistening, light, fits Suitable faintly acid soil.Stem, leaf are through the extractable spearmint oil of distillation.

Active site to Labiatae mint spearmint carries out system research.Using solvent method and various chromatography sides Method.As a result：Isolated 7 compounds, are identified respectively as ursane, 3- methoxyl group -4- tolyl aldehydes, veratric acid, 5- hydroxyls Base -6,7,3', 4'- tetramethoxy flavones, diosmetin, 5,6,4 '-trihydroxy -7,8,3'- trimethoxy flavones, daucosterol.

Plant contains aromatic oil, oil content 0.6-0.7%, and its oil claims spearmint oil or oleum menthae viridis, and main component is fragrant drought Celery seed oil mushroom ketone (content is 60-65%), also there is limonene, Chinese celery sesame oil hydrocarbon etc. in addition, is mainly used to candy, toothpaste spices, Also for pharmaceutical.Leaf, spray or herb are also used as medicine, and cure cold heating, cough, cough due to consumptive disease, cold, headache, pharyngalgia, god Through property headache, flatulence, bruise stasis caused pain, the peppery pain of hot eyes, nosebleed epistaxis, crow treatment, total numbness and children's boil.

Herb (spearmint)：It is pungent, sweet, tepor.Expelling wind and clearing away cold, cough-relieving, subdhing swelling and detoxicating.For catching a cold, cough, stomachache, abdomen It is swollen, nervous headache；It is used for treating swelling and pain by traumatic injury, hot eyes erythralgia, children's boil outward.

In the present invention, the preparation method of the spearmint extract is：Spearmint powder is weighed, ethanol is added, 2- is soaked Extracting through microwave heating is used after 3h 2-3 times, filtering, filtrate obtains final product through being concentrated under reduced pressure into without ethanol.

Numb seed

Numb seed, alias hemp seed, winter fiber crops seed, fire fiber crops seed etc., it is sweet, flat, it is nontoxic.Fiery fiber crops category Cannabaceae, is commonly called as hemp, and Claim cold fiber crops, hemp, chief fiber crops, dew fiber crops, Chinese fiber crops etc., be a kind of short, annual sunshine, leaf palmation and mostly dioecious grass This plant, with impoverishment tolerant, resistance feature, growth scope is wide, has light photograph, photosynthetic efficiency in terms of biology Characteristic high, growth conditions are vigorous under conditions of sunshine is long, and plant height may be up to 3.5m.Fiery fiber crops can be divided into fiber use, medicine With with seed with three kinds.

Flaxseed oil is at normal temperatures the translucent oily liquids of yellow green, puts and becomes yellowish-brown long afterwards, special with fiery fiber crops seed Faint scent.

Common fire fiber crops seed benevolence oil content is 30%-40%, and, close to 2.5, this ratio is for linoleic acid and linolenic ratio The optimal proportion of needed by human body aliphatic acid, while respective metabolic activity product linoleic acid and stearic acid content also quite enrich. In the aliphatic acid composition of fiery flaxseed oil, predominantly C16 and C18 aliphatic acid, two unsaturated linoleic acid and three unsaturated linolenic Amount fraction is up to 85.80%, with degree of unsaturation high.Identification at present, contains 29 kinds of compounds, wherein aliphatic acid in fiery flaxseed oil There are 18 kinds, account for the 99.12% of total content, saturated fatty acid l1 kinds put acid, stearic acid, based on arachidic acid with palm fibre, and content is respectively 8.81%th, 2.76%, 0.59%, totally 7 kinds of unrighted acid accounts for 87% of total content or so, and monounsaturated fatty acids is palm fibre Oleic acid, oleic acid, arachidonic acid are put, content is respectively 0.08%, 8.92%, 0.26%.Polyunsaturated fatty acid be respectively γ- Leukotrienes, leukotrienes, linoleic acid, content are respectively 0.61%, 24.42%, 52.32% and 20 carbon -5,8,11,14,17- five Olefin(e) acid, content is 0.34%, and the liposoluble constituent in fiery flaxseed oil also includes 4 kinds of ketone, 2 kinds of alcohol and 3 kinds of hydrocarbons.Except this it Outward, also identify acid dimethyl, enanthic acid, 2 methyl valeric acid and 20 carbon-5,8,1l, 14,17-five olefin(e) acid and ketone, hydrocarbon, 13 kinds of compositions such as alcohol.

At this stage, the method for extracting flaxseed oil has a lot, for example：Aqueous enzymatic method, supercritical fluid extraction, extraction Method, milling process etc..

In the present invention, aqua method is mainly taken to extract flaxseed oil.

Main extraction step is in the present invention：

(1) pretreatment of raw material and baking

Toasted under certain temperature and time again after fiery fiber crops seed is eluriated totally, baking is denatured protein, can Soluble proteins become insoluble protein, and tissue originally is destroyed.Globulin changes in oil plant, is transferred to hydrophilic group Irregular distribution, hydrophobic group is transferred to outside, is included in the grease inside globulin and is exposed to surface and assembles.Therefore toast It is easy to the extraction of grease.

(2) crush

When oil is carried using aqua method, it is necessary to be ground to fiery fiber crops seed broken, oil plant cell is fully ruptured, so as to Converting slurry when slurry stirs oil and being sufficiently mixed with slurry makes non-oil substances and water fully be combined, and extracts grease completely as far as possible and ensures the matter of oil Amount.

(3) slurry stirring is converted

Mix with the running water of uniform temperature by a certain percentage after fiery fiber crops seed is crushed first, be sufficiently stirred for mixing, fully Dispersing and dissolving is in water.Now, the exposed grease in fiery fiber crops seed surface is extracted, and then the grease in pulverized particles is entered Traveling onestep extraction.Homogenate is stirred under uniform temperature and mixing speed, the grease in homogenate is extracted to greatest extent, carry out constant temperature During stirring, with reference to hydrophilic protein matter in water immersion fire fiber crops seed particle, the position of grease in fiery fiber crops seed cell is instead of Put, so that grease is discharged from slurry.

(4) centrifugation

Slurry will be obtained under the conditions of 4000r/min, 20min will be centrifuged, obtain upper strata oil reservoir, lower floor's material residue will obtain numb seed Oil.

In the present invention, used as a kind of preferred embodiment, the preparation method of the extract of the gleditsia sinensis and fresh orange peel mixture is By gleditsia sinensis and fresh orange peel by weight mixing, explosion is crushed to 100-200 mesh, and 2-mercaptobenzothiazole blending, is made with ethanol For solvent is extracted.

In the present invention, used as a kind of preferred embodiment, the preparation method of the extract of the China tree and locust tree mixture is：Will China tree and locust tree are cleaned, chopping, after being soaked with ammoniacal liquor, add ethanol, and flow back 1-3h, filters while hot, are concentrated into without ethanol, i.e., .

In the present invention, as a kind of preferred embodiment, the preparation side of the extract of the Italian black poplar and eucalyptus mixture Method is：Italian black poplar and eucalyptus powder are weighed, ethanol is added, extracting through microwave heating is used 2-3 times after immersion 2-3h, filtering, Filtrate obtains final product through being concentrated under reduced pressure into without ethanol.

As a kind of preferred embodiment of the invention, the mixture A of the Italian black poplar extract and eucalyptus extracts with Extractives From Melia Azedarach L, the mixture B of locust tree extract are blended, and in the case of ultrasound, are stirred 1-2 days, obtain mixture C；

In the present invention, spontaneous fermentation product, the tea of the fresh orange peel extract and grape fruit, peppermint, aloe and fresh orange peel Tree essential oil needs be stirred under ultrasound, be blended, and stirs 1-2 days, obtains mixture D；

By surplus materials：Fructus Gleditsiae Abnormalis extract, chrysanthemum extract, qinghaosu, matrine and vanilla extract are under ultrasound It is blended with mixture C, mixture D, 0.5-5 hours, you can obtain the air purifying composition.

In the present invention, the air purifying composition can be used for preparing air purifying preparation, the air purifying preparation Concrete form be not specifically limited, for example：Paste, liquid, foam-like, spray form etc..

Used as one embodiment of the present invention, the air purifying composition also includes：20-28wt%1,2- the third two Alcohol, 10-15wt% palmitic acids, 6-8wt% stearic acid, 2.0-4.0wt% NaOH, 0.05-0.2wt% acetate vitamins The water of E and surplus.

As inventors herein have recognized that, the tannin in eucalyptus extracts can be to the smell substance in air Generation is esterified or ester exchange reaction, such that it is able to take the peculiar smell being chemically removed in air, rather than simple physics Absorption；Biological alkali precipitation can be caused plus tannin, so that the stability of matrine and Extractives From Melia Azedarach L is improved, it is additional Tea tree ethereal oil and vanilla extract, can stablize the slow release speed of the air purifying composition, when improving the use of product Between；The distinctive special Flavonoid substances containing polymethoxy in orange peel, live outward plus in spontaneous fermentation product containing reaction Property functional group compound and terpenoid very high, decompose with pernicious gas molecule, are polymerized, replacing, replacing and addition Deng chemical reaction, so that the air purifying composition obtained in the present invention, with slow release, with sterilizing ability, can be grown again The effect that phase uses, need not change.Meanwhile, the material of the slow release of the present invention can make an initiative sally tiny with micronic dust in air The particulates such as particle, bacterium are combined, and these materials can be made to produce energy transfer or structure change, so as to effectively remove micronic dust, are allowed Micronic dust is settled in time.

Implementation method 1：A kind of air purifying composition, by weight, it is included：

The extract of gleditsia sinensis and fresh orange peel mixture；With

China tree and the extract of locust tree mixture；With

Italian black poplar and the extract of eucalyptus mixture；With

The chrysanthemum extract of 2-8 weight portions, 0.1-3 qinghaosus, the matrine of 4-18 weight portions, the tea of 0.1-1 weight portions Tree essential oil, the vanilla extract of 0.1-1 weight portions；

Implementation method 2：Air purifying composition as tdescribed in embodiment 1, by weight, it is included：

The extract of gleditsia sinensis and fresh orange peel mixture；With

China tree and the extract of locust tree mixture；With

Italian black poplar and the extract of eucalyptus mixture；With

The chrysanthemum extract of 2-7 weight portions, 0.1-2.5 qinghaosus, the matrine of 4-16.5 weight portions, 0.1-0.5 weight The tea tree ethereal oil, the vanilla extract of 0.5-1 weight portions of part；

Implementation method 3：Air purifying composition as tdescribed in embodiment 1, the air purifying composition is also included：

Implementation method 4：Air purifying composition as tdescribed in embodiment 1, the gleditsia sinensis and fresh orange peel mixture are carried The preparation method for taking thing is that explosion is crushed to 100-200 mesh, and 2- sulfydryl benzo thiophenes by weight mixing by gleditsia sinensis and fresh orange peel Azoles is blended, and is extracted as solvent with ethanol.

Implementation method 5：Air purifying composition as tdescribed in embodiment 1, the extraction of the China tree and locust tree mixture The preparation method of thing is：China tree and locust tree are cleaned, are shredded, after being soaked with ammoniacal liquor, add ethanol, flow back 1-3h, filters while hot, It is concentrated into without ethanol, obtains final product.

Implementation method 6：Air purifying composition as tdescribed in embodiment 1, the Italian black poplar and eucalyptus mixture The preparation method of extract be：Italian black poplar and eucalyptus powder are weighed, ethanol is added, heating using microwave is used after immersion 2-3h Extract 2-3 times, filtering, filtrate obtains final product through being concentrated under reduced pressure into without ethanol.

Implementation method 7：Air purifying composition as tdescribed in embodiment 1, the tea tree ethereal oil is extracted by the way of distillation Obtain.

Implementation method 8：Air purifying composition as tdescribed in embodiment 1, the composition is also included：0.01-0.1 weights Measure the nano-Ag particles of the particle diameter in 1-3nm or so of part.

Implementation method 9：Air purifying composition as tdescribed in embodiment 1 is also included：Spearmint and numb seed extract.

Implementation method 10：Air purifying composition as tdescribed in embodiment 1, the locust tree selection gold leaf locust tree, pink blossom Locust tree and safflower locust tree are 0.5 according to weight part ratio：0.8：1.2 blendings are extracted.

Implementation method 11：Air purifying composition as tdescribed in embodiment 1, the Extractives From Melia Azedarach L is azedarach, hardship Chinaberry and China tree are 1.2 according to weight portion：0.5：0.8 mixing is extracted.

Implementation method 12：Air purifying composition as tdescribed in embodiment 1, the eucalyptus extracts are eucalyptus leaves and eucalyptus Bark is 1 according to weight portion：1.3 blendings, extract.

Implementation method 13：Air purifying composition as described in implementation method 12, the eucalyptus leaves is selected from alpine ash, gray gum And Liu An, and the eucalyptus leaves, by spring harvesting, the age of tree is life in 3 years.

Implementation method 14：Air purifying composition as described in implementation method 13, the weight of the alpine ash, gray gum and Liu An Amount is than being 1：1.5：1.3.

Implementation method 15：A kind of air purifying preparation, its composition as described in implementation method any one of 1-9 is prepared.

The present invention is specifically described below by embodiment.Be necessary it is pointed out here that, following examples are only used In the invention will be further described, it is impossible to be interpreted as limiting the scope of the invention, professional and technical personnel in the field Some nonessential modifications and adaptations that content according to the invention described above is made, still fall within protection scope of the present invention.

In addition, if without other explanations, raw materials used is all commercially available, and number used by following material is weight Part.

Embodiment 1：A kind of air purifying preparation, it has air purifying composition to prepare.

The air purifying composition, by weight, it is included：The extract of gleditsia sinensis and fresh orange peel mixture；With

China tree and the extract of locust tree mixture；With

Italian black poplar and the extract of eucalyptus mixture；With

The chrysanthemum extract of 6 weight portions, 2 qinghaosus, the matrine of 10 weight portions, the tea tree ethereal oil of 0.5 weight portion, 0.5 The vanilla extract of weight portion；

Wherein gleditsia sinensis is 8 weight portions, and fresh orange peel is 15 weight portions, and China tree is 10 weight portions, and locust tree is 10 weight portions, and meaning is big Sharp black poplar is 3 weight portions, and eucalyptus is 2 weight portions, and the weight ratio of 8 weight portions is 1：1.5：2：2.8 grape fruit, peppermint, aloe With the spontaneous fermentation product mixtures of fresh orange peel, the particle diameter of 0.05 weight portion 1-3nm or so nano-Ag particles, 0.03 weight The spearmint extract of part, the numb seed extract of 0.03 weight portion.

Wherein, the preparation method of the extract of the gleditsia sinensis and fresh orange peel mixture be by gleditsia sinensis and fresh orange peel by weight Mixing, explosion is crushed to 100-200 mesh, and 2-mercaptobenzothiazole blending, is extracted as solvent with ethanol；

The preparation method of the extract of the China tree and locust tree mixture is：China tree and locust tree are cleaned, is shredded, use ammoniacal liquor After wetting, ethanol is added, flow back 1-3h, filters while hot, is concentrated into without ethanol, obtains final product；

The preparation method of the extract of the Italian black poplar and eucalyptus mixture is：Weigh Italian black poplar and eucalyptus powder End, adds ethanol, and extracting through microwave heating is used 2-3 times after immersion 2-3h, filtering, and filtrate obtains final product through being concentrated under reduced pressure into without ethanol；

The tea tree ethereal oil is obtained by extraction by the way of distillation.

Wherein, the locust tree selection gold leaf locust tree, pink blossom locust tree and safflower locust tree are 0.5 according to weight part ratio：0.8：1.2 Blending is extracted,

The preparation method of specific locust tree extract is as follows：

The Extractives From Melia Azedarach L is that azedarach, chinaberry and China tree are 1.2 according to weight portion：0.5：0.8 mixing is carried out Extract.

The eucalyptus extracts are that eucalyptus leaves and eucalyptus barks are 1 according to weight portion：1.3 blendings, extract, the eucalyptus barks choosing From eucalyptus robusta and Eucalyptus urophylla, and both weight ratios are 1：3, the weight ratio of the alpine ash, gray gum and Liu An is 1：1.5：1.3.

The chrysanthemum extract mainly uses microwave loss mechanisms：Appropriate chrysanthemum is weighed, is shredded, add ethanol, soak 2-3h Use extracting through microwave heating 2-3 times afterwards, filtering, filtrate obtains final product through being concentrated under reduced pressure into without ethanol.

The qinghaosu is bought in Shaanxi Sen Lang biochemical industries Co., Ltd.

The matrine uses supercritical fluid extraction, and the parameter of main extraction is：Extraction time 3.0h, extraction temperature 55 DEG C, extracting pressure 35MPa, CO₂Flow 40-45kg/h.

The tea tree ethereal oil is bought in Shanghai Hui En International Trading Company Ltd.

The vanilla uses supercritical CO₂The method of fluid extraction is extracted.Actual conditions is：Optimal conditions are： Temperature is 45 DEG C, and pressure is 2.0 × 10⁴KPa, the time is 90 minutes.

The preparation method of the spearmint extract is：Spearmint powder is weighed, ethanol is added, using micro- after immersion 2-3h Wave heating is extracted 2-3 times, and filtering, filtrate obtains final product through being concentrated under reduced pressure into without ethanol.

The extracting method of the numb seed：

(1) pretreatment of raw material and baking

(2) crush

(3) slurry stirring is converted

(4) centrifugation

The concentration of the preparing raw material silver nitrate of the Nano Silver is 3.2g/L.

The preparation method of the air purifying preparation：

1st, the mixture A and Extractives From Melia Azedarach L of the Italian black poplar extract and eucalyptus extracts, locust tree extract Mixture B is blended, and in the case of ultrasound, is stirred 1-2 days, obtains mixture C；

2nd, the spontaneous fermentation product of the fresh orange peel extract and grape fruit, peppermint, aloe and fresh orange peel, tea tree ethereal oil are needed To be stirred under ultrasound, be blended, stirred 1-2 days, obtain mixture D；

3rd, Fructus Gleditsiae Abnormalis extract, chrysanthemum extract, qinghaosu, matrine and vanilla extract under ultrasound and mixture C, Mixture D, surplus materials blending, stir 0.5-5 hours；

4th, the mixture for obtaining step 3, mixes with silver nitrate solution, and 1min is irradiated under ultraviolet light, then room temperature again Lower stirring 0.5-5 hours, add 30 weight portions 20wt%1,2- propane diols, 10wt% palmitic acids, 6wt% stearic acid, The water of 2.0wt% NaOH, 0.05wt% acetate vitamin e and surplus, obtains thick slurry, repeatedly lifting drying, Can obtain the air purifying preparation.

Embodiment 2：It is substantially the same manner as Example 1, except the preparation method of the Fructus Gleditsiae Abnormalis extract, fresh orange peel extract be by Gleditsia sinensis and fresh orange peel explosion are crushed to 100-200 mesh, are extracted as solvent with ethanol.

Embodiment 3：Substantially the same manner as Example 1, the Fructus Gleditsiae Abnormalis extract and fresh orange peel extract are separately extracted.

Embodiment 4：Substantially the same manner as Example 1, the Extractives From Melia Azedarach L and locust tree extract are separately extracted.

Embodiment 5：Substantially the same manner as Example 1, the Italian black poplar extract and eucalyptus extracts are separately extracted.

Embodiment 6：It is substantially the same manner as Example 1, without Nano Silver.

Embodiment 7：It is substantially the same manner as Example 1, without spontaneous fermentation thing.

Embodiment 8：Substantially the same manner as Example 1, the raw material of locust tree extract only has gold leaf locust tree.

Embodiment 9：It is substantially the same manner as Example 1, locust tree selection gold leaf locust tree, pink blossom locust tree and safflower locust tree according to Weight part ratio is 1：3：1.2 blendings are extracted.

Embodiment 10：Substantially the same manner as Example 1, the raw material of the Extractives From Melia Azedarach L only has azedarach.

Embodiment 11：It is substantially the same manner as Example 1, the Extractives From Melia Azedarach L be azedarach, chinaberry and China tree according to Weight portion is 1.2：1：1 mixing is extracted.

Embodiment 12：Substantially the same manner as Example 1, the eucalyptus leaves and eucalyptus barks are 1 according to weight portion：1.5 blendings are carried Take eucalyptus extracts.

Embodiment 13：Substantially the same manner as Example 1, the eucalyptus leaves only has alpine ash leaf.

Embodiment 14：Substantially the same manner as Example 1, the weight ratio of the alpine ash, gray gum and Liu An is 1：1.5：1.5.

Embodiment 15：Substantially the same manner as Example 1, the preparation method of the air purifying preparation is：Prepared above-mentioned Various materials extract together simple physical blending, heating, repeatedly lifting drying, obtain final product.

Test：The above-mentioned air purifying preparation for preparing is carried out into purification of air test

1st, air purifying composition validity duration experiment：

1.1 removal experimental test conditions are as follows：In 1m³In the experiment bin of sealing, the pure formaldehyde of injection certain volume chemistry (or Benzene or ammonia), storehouse internal fan is opened, gas concentration is initial concentration in the storehouse of sampling test immediately after 1 hour.In 1m³The reality of sealing In testing position, obtained air purifying preparation (or after obtained air purifying preparation is placed 2880 hours) will just be put into the storehouse, note Enter the chemical pure formaldehyde (or benzene or ammonia) of same volume, gas concentration in the storehouse of sampling test immediately, calculates clearance after 72 hours. Clearance=(initial concentration-sample solution concentration) × 100/ initial concentration, test result is shown in Tables 1 and 2.

1.2 air sterillizations are tested：In about 50m³It is in laboratory, obtained air purifying preparation is (or net by obtained air After agent is placed 2880 hours) release acts on 48 hours with natural bacteria in atmosphere, sterilizing rate=(average bacterium number-examination before experiment Average bacterium number after testing) the preceding average bacterium number of × 100/ experiment.Test result is shown in Table 3.

TVOC is total volatile organism, all indoor organic gas materials.

The just obtained air purifying preparation clearance test of table 1

Clearance after air purifying preparation obtained in table 2 is placed 2880 hours is tested

The sterilizing rate test of air purifying preparation obtained in table 3

As can be seen from the table, the air purifying composition in the present invention, to containing specific order of preparation method and group The method of box-like extraction plant extract, and in Fructus Gleditsiae Abnormalis extract, the fresh orange peel extract for adding 2-mercaptobenzothiazole, It has slow release, with sterilizing ability, again can be with long-term use, the characteristic without changing.

Foregoing example is merely illustrative, some features of the feature for explaining the disclosure.Appended claim The scope as wide as possible for requiring to be contemplated that is intended to, and embodiments as presented herein is only according to all possible embodiment Combination selection implementation method explanation.Therefore, the purpose of applicant is appended claim not by the explanation present invention Feature example selectional restriction.And the progress in science and technology by formed language performance it is inaccurate due to and not The possible equivalent or son being presently considered are replaced, and these changes should also be interpreted by appended in the conceived case Claim is covered.

Claims

1. air purifying composition, by weight, it is included：

The extract of gleditsia sinensis and fresh orange peel mixture；With

China tree and the extract of locust tree mixture；With

Italian black poplar and the extract of eucalyptus mixture；With

The chrysanthemum extract of 2-7 weight portions, the qinghaosu of 0.1-2.5 weight portions, the matrine of 4-16.5 weight portions, 0.1-0.5 The tea tree ethereal oil of weight portion, the vanilla extract of 0.5-1 weight portions；

Wherein gleditsia sinensis is 1-8.5 weight portions, and fresh orange peel is 10-18.5 weight portions, and China tree is 3-12 weight portions, and locust tree is 8-15 weights Amount part, Italian black poplar is 0.1-3.5 weight portions, and eucalyptus is 0.1-3.5 weight portions；

The weight ratio of 5-10 weight portions is 1：1.5：2：The spontaneous fermentation product of 2.8 grape fruit, peppermint, aloe and fresh orange peel is mixed Compound；

The preparation method of the extract of the Italian black poplar and eucalyptus mixture is：Italian black poplar and eucalyptus powder are weighed, Ethanol is added, extracting through microwave heating is used 2-3 times after immersion 2-3h, filtering, filtrate obtains final product through being concentrated under reduced pressure into without ethanol.

2. the preparation method of the extract of the air purifying composition described in claim 1, the gleditsia sinensis and fresh orange peel mixture It is that explosion is crushed to 100-200 mesh, and 2-mercaptobenzothiazole blending, uses ethanol by weight mixing by gleditsia sinensis and fresh orange peel Extracted as solvent.

3. the preparation method of the extract of the air purifying composition described in claim 1, the China tree and locust tree mixture is： China tree and locust tree are cleaned, is shredded, after being soaked with ammoniacal liquor, add ethanol, flow back 1-3h, filters while hot, is concentrated into without ethanol, i.e., .

4. the air purifying composition described in claim 1, the tea tree ethereal oil is obtained by extraction by the way of distillation.

5. the air purifying composition described in claim 1, the composition is also included：The particle diameter of 0.01-0.1 weight portions is in 1- The nano-Ag particles of 3nm or so.

6. the air purifying composition described in claim 1, the composition is also included：Spearmint and numb seed extract.

7. a kind of air purifying preparation, its composition as described in claim any one of 1-6 is prepared.