CN106244119A - A kind of heat-conduction medium - Google Patents
A kind of heat-conduction medium Download PDFInfo
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- CN106244119A CN106244119A CN201610537286.6A CN201610537286A CN106244119A CN 106244119 A CN106244119 A CN 106244119A CN 201610537286 A CN201610537286 A CN 201610537286A CN 106244119 A CN106244119 A CN 106244119A
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- medium
- heat
- oxygen
- alkylbenzene
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
- C09K5/00—Heat-transfer, heat-exchange or heat-storage materials, e.g. refrigerants; Materials for the production of heat or cold by chemical reactions other than by combustion
- C09K5/08—Materials not undergoing a change of physical state when used
- C09K5/10—Liquid materials
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- Chemical Kinetics & Catalysis (AREA)
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- Organic Chemistry (AREA)
- Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
Abstract
The present invention relates to a kind of heat-conduction medium, raw material, interpolation high temperature anti-coking agent and hydrogenation antisludging agent based on alkylaromatic hydrocarbon class material and saturated alkane class material.The Novel hot transmitting medium that the present invention provides; the most aqueous, oxygen and other active group materials; in the temperature control process of anhydrous and oxygen-free reaction, there is any reaction in discord anhydrous and oxygen-free reaction mass, is conducive to protecting oxygen-free environment; and it is corrosion-free to metal; low toxicity, environmental protection, can meet 80~300 DEG C of different temperatures require that operating mode uses according to different ratio; thus same medium can be used in anhydrous and oxygen-free reaction temperature control operating mode, save medium.
Description
Technical field
The present invention relates to a kind of heat-conduction medium, be specifically related to a kind of heat that can use in anhydrous and oxygen-free reaction temperature control operating mode
Transmitting medium.
Background technology
Many special compounds, to water or oxygen sensitive, are met water or chance oxygen can be occurred vigorous reaction;In order to study
The synthesis of this compounds, separation, purification and Analysis and Identification, it is necessary to use special instrument and anhydrous and oxygen-free operating technology.No
Then, even if synthetic route and reaction condition are all suitable, the most also can not get intended product.So, anhydrous and oxygen-free operates
The utilization that technology is wide in organic chemistry and inorganic chemistry.
In the middle of daily Chemical Manufacture, needing to use anhydrous and oxygen-free reaction in part chemosynthesis, this kind of reaction is general all
It it is very exothermic reaction.At present, this kind of chemosynthesis controls temperature typically refrigeration and heating two parts, and refrigerating part is generally adopted
With saline or ethylene glycol as the semi-open type refrigeration system of refrigerant, and heating part generally uses steam as adding thermal medium
Heating system, refrigerant and add thermal medium both media be both needed to enter reacting kettle jacketing, carry out drop mild heat mutual
Switching.But, saline and ethylene glycol solution all contain hydroxyl, chloride ion, moisture, oxygen isoreactivity material, once and anhydrous and oxygen-free
Reaction mass contacts, and just explodes, there is the biggest potential safety hazard;And saline and ethylene glycol solution have stronger metal erosion
Property, life-time service, greatly reduce service life of equipment;Saline is relatively strong because of corrosivity, is typically used as the cryogenic heat transfer of-40~20 DEG C
Medium, ethylene glycol solution is typically used as-20~80 DEG C of temperature ranges, uses temperature range to receive considerable restraint.
Summary of the invention
It is an object of the invention to provide a kind of heat-conduction medium, in order to control the temperature in anhydrous and oxygen-free reaction operating mode.
In order to realize foregoing invention purpose, the technical scheme is that
A kind of heat-conduction medium, it is characterised in that include following component:
With alkylaromatic hydrocarbon class and, raw material based on high-pressure hydrogenation alkanes substance, add high temperature anti-coking agent and hydrogenation scale inhibition
Agent.
Further, being in terms of 100% by heat-conduction medium gross weight, the content of each component is as follows;Alkylaromatic hydrocarbon class material 5%
~90%, high-pressure hydrogenation alkanes substance 7%~92%, high temperature anti-coking agent 1%~2%, it is hydrogenated with antisludging agent 1%~2%.Enter one
Step, described alkylaromatic hydrocarbon class material is alkylbenzene.
Further, described alkylbenzene aromatic hydrocarbon substance is selected from detergent alkylate, propylbenzene and the one of a diethylbenzene
Or it is multiple.
Further, described alkanes base oil is hydrogenation alkanes base oil.
Further, described hydrogenation alkanes base oil is low sulfur and low aromatics special type oil..
Further, described alkylbenzene is detergent alkylate, propylbenzene and a diethylbenzene.
Further, being in terms of 100% by heat-conduction medium gross weight, each constituent content of alkylbenzene is: detergent alkylate 10%,
Propylbenzene 50%, a diethylbenzene 20%.
Further, described alkylbenzene is detergent alkylate and propylbenzene, is in terms of 100% by heat-conduction medium gross weight, alkane
The each constituent content of base benzene is: detergent alkylate 85%, propylbenzene 5%.
Further, described alkylbenzene be between diethylbenzene, be in terms of 100% by heat-conduction medium gross weight, a diethylbenzene
Content is 5%.
The Novel hot transmitting medium that the present invention provides, has saturated hydrocarbons characteristic, the most aqueous, oxygen and other active group things
Matter, and there is not any reaction in anhydrous and oxygen-free reaction mass, protects oxygen-free environment, exempt the potential safety hazard therefore brought;And this
Product is corrosion-free to metal, low toxicity, environmental protection;And this product can meet-80~300 DEG C of different temperatures want according to different ratio
Operating mode is asked to use;Same medium can be used, it is to avoid cooling and adding in anhydrous and oxygen-free reaction temperature control (fall mild heat) operating mode
Heat uses different medium, does not results in because handover operation brings medium to waste.
Detailed description of the invention
Embodiment 1
In terms of heat-conduction medium gross weight 100%, detergent alkylate 10%, propylbenzene 50%, a diethylbenzene 20% is low
Sulfur low aromatic hydrocarbons special type oil SMD60 is 12% (production of Qingjian River petrochemical industry Co., Ltd), and SMD70 is 5% (Qingjian River oil
Work Co., Ltd produces), KX-ZJ-01 high temperature anti-coking agent 1.5% (production of Shandong Ke Xin petrochemical industry company limited), KX-
ZS-03 hydrogenation antisludging agent 1.5% (production of Shandong Ke Xin petrochemical industry company limited).This product low toxicity, antioxidation, low viscosity,
Heat transfer efficiency is high, condensation point≤-85 DEG C, and boiling point >=140 DEG C can be used for-80~135 DEG C of scope temperature control operating modes.
Embodiment 2
In terms of heat-conduction medium gross weight 100%, detergent alkylate 85%, propylbenzene 5%, low sulfur and low aromatics special type oil
SMD60 is 7% (production of Qingjian River petrochemical industry Co., Ltd), KX-ZJ-01 high temperature anti-coking agent 1.5% (Shandong section Arsenicum sablimatum oil
Chemical Co., Ltd. produces), KX-ZS-03 hydrogenation antisludging agent 1.5% (production of Shandong Ke Xin petrochemical industry company limited).This produces
Product low toxicity, antioxidation, resistance to elevated temperatures is good, and heat transfer efficiency is high, condensation point≤-10 DEG C, and boiling point >=300 DEG C can be used for 0~300
DEG C scope temperature control operating mode.
Embodiment 3
In terms of heat-conduction medium gross weight 100%, a diethylbenzene 5%, low sulfur and low aromatics special type oil SMD60 is 87%
(production of Qingjian River petrochemical industry Co., Ltd), SMD70 is 5% (production of Qingjian River petrochemical industry Co., Ltd), KX-
ZJ-01 high temperature anti-coking agent 1.5% (production of Shandong Ke Xin petrochemical industry company limited), KX-ZS-03 is hydrogenated with antisludging agent 1.5% (mountain
Dong Kexin petrochemical industry company limited produces).This product low toxicity, antioxidation, environmental protection, good stability, viscosity is low, condensation point≤-80
DEG C, boiling point >=170 DEG C, can be used for-70~160 DEG C of scope temperature control operating modes.
Embodiment 4
In terms of heat-conduction medium gross weight 100%, a diethylbenzene 5%, it is (clear that low sulfur and low aromatics special type oil SMD60 is 6%
River petrochemical industry Co., Ltd produces), SMD70 is 85% (production of Qingjian River petrochemical industry Co., Ltd), KX-ZJ-
01 high temperature anti-coking agent 1.5% (production of Shandong Ke Xin petrochemical industry company limited), KX-ZS-03 is hydrogenated with antisludging agent 1.5% (Shandong
Ke Xin petrochemical industry company limited produces).This product low toxicity, antioxidation, environmental protection, good stability, viscosity is low, good heat-transfer,
Condensation point≤-60 DEG C, boiling point >=210 DEG C, can be used for-50~200 DEG C of scope temperature control operating modes.
Heat-conduction medium in the application has saturated hydrocarbons characteristic, the most aqueous, oxygen and other active group materials, and nothing
There is not any reaction in water anaerobic reaction mass, protects oxygen-free environment, exempts the potential safety hazard therefore brought;And this product is to gold
Belong to corrosion-free, low toxicity, environmental protection;And this product can meet-80~300 DEG C of different temperatures require that operating mode makes according to different ratio
With, compared with the heating conventional with prior art and cooling medium, the anhydrous and oxygen-free reaction temperature span of control being suitable for is wider;And
Same medium can be used, it is to avoid fall mild heat uses difference to be situated between in anhydrous and oxygen-free reaction temperature control (fall mild heat) operating mode
Matter, it is to avoid cause the medium waste brought because of handover operation.
It is last that it is noted that obviously above-described embodiment is only for clearly demonstrating example of the present invention, and also
The non-restriction to embodiment.For those of ordinary skill in the field, can also do on the basis of the above description
Go out change or the variation of other multi-form.Here without also cannot all of embodiment be given exhaustive.And thus drawn
What Shen went out obviously changes or changes among still in protection scope of the present invention.
Claims (10)
1. a heat-conduction medium, it is characterised in that its component is:
Raw material, interpolation high temperature anti-coking agent and hydrogenation antisludging agent based on alkylaromatic hydrocarbon class material and saturated alkane class material.
Medium the most according to claim 1, it is characterised in that be in terms of 100% by heat-conduction medium gross weight, each component
Content is as follows;Alkylaromatic hydrocarbon class material 5%~90%, high-pressure hydrogenation alkanes substance 7%~92%, high temperature anti-coking agent 1%~
2%, it is hydrogenated with antisludging agent 1%~2%.
Medium the most according to claim 1 and 2, it is characterised in that described alkylaromatic hydrocarbon class material is alkylbenzene.
Medium the most according to claim 3, it is characterised in that described alkylbenzene selected from detergent alkylate, propylbenzene and
One or more in diethylbenzene.
Medium the most according to claim 1 and 2, it is characterised in that described saturated alkane class material is hydrogenation alkanes base
Plinth oil.
Medium the most according to claim 5, it is characterised in that described hydrogenation alkanes base oil is that low sulfur and low aromatics is extraordinary
Oil.
Medium the most according to claim 4, it is characterised in that described alkylbenzene is detergent alkylate, propylbenzene and two
Ethylo benzene.
Medium the most according to claim 7, it is characterised in that be that in terms of 100%, alkylbenzene is each by heat-conduction medium gross weight
Constituent content is: detergent alkylate 10%, propylbenzene 50%, a diethylbenzene 20%.
Medium the most according to claim 4, it is characterised in that described alkylbenzene is detergent alkylate and propylbenzene, with heat
Transmitting medium gross weight is 100% meter, and each constituent content of alkylbenzene is: detergent alkylate 85%, propylbenzene 5%.
Medium the most according to claim 4, it is characterised in that described alkylbenzene be between diethylbenzene, with heat-conduction medium
Gross weight is 100% meter, and a diethylbenzene content is 5%.
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CN201610537286.6A CN106244119A (en) | 2016-07-08 | 2016-07-08 | A kind of heat-conduction medium |
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CN201610537286.6A CN106244119A (en) | 2016-07-08 | 2016-07-08 | A kind of heat-conduction medium |
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Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN109722228A (en) * | 2019-01-25 | 2019-05-07 | 陶普斯化学科技(北京)有限公司 | A kind of heat-conduction medium |
CN113372985A (en) * | 2021-06-30 | 2021-09-10 | 厦门谢田守望新材料有限公司 | Heat conduction oil online high-temperature cleaning agent and preparation method and use method thereof |
Citations (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN1986723A (en) * | 2006-12-20 | 2007-06-27 | 内蒙古海吉氯碱化工股份有限公司 | Coolant for vinyl chloride reactor |
US20080011979A1 (en) * | 2002-11-07 | 2008-01-17 | David Lee Davidson | Heat Transfer Fluids for Application Over a Broad Range of Temperatures |
CN102260485A (en) * | 2010-05-25 | 2011-11-30 | M·阿伦博里 | Heat exchange medium |
CN104893683A (en) * | 2015-06-29 | 2015-09-09 | 成都迈斯拓新能源润滑材料有限公司 | Anti-coking alkylbenzene synthesis heat conduction oil and preparation method thereof |
CN105038719A (en) * | 2015-07-08 | 2015-11-11 | 新疆福克油品股份有限公司 | Chemically synthesized alkyl naphthalene heat transfer fluid composition |
-
2016
- 2016-07-08 CN CN201610537286.6A patent/CN106244119A/en active Pending
Patent Citations (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US20080011979A1 (en) * | 2002-11-07 | 2008-01-17 | David Lee Davidson | Heat Transfer Fluids for Application Over a Broad Range of Temperatures |
CN1986723A (en) * | 2006-12-20 | 2007-06-27 | 内蒙古海吉氯碱化工股份有限公司 | Coolant for vinyl chloride reactor |
CN102260485A (en) * | 2010-05-25 | 2011-11-30 | M·阿伦博里 | Heat exchange medium |
CN104893683A (en) * | 2015-06-29 | 2015-09-09 | 成都迈斯拓新能源润滑材料有限公司 | Anti-coking alkylbenzene synthesis heat conduction oil and preparation method thereof |
CN105038719A (en) * | 2015-07-08 | 2015-11-11 | 新疆福克油品股份有限公司 | Chemically synthesized alkyl naphthalene heat transfer fluid composition |
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN109722228A (en) * | 2019-01-25 | 2019-05-07 | 陶普斯化学科技(北京)有限公司 | A kind of heat-conduction medium |
CN113372985A (en) * | 2021-06-30 | 2021-09-10 | 厦门谢田守望新材料有限公司 | Heat conduction oil online high-temperature cleaning agent and preparation method and use method thereof |
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Application publication date: 20161221 |