CN106243828A - A kind of water color ink - Google Patents
A kind of water color ink Download PDFInfo
- Publication number
- CN106243828A CN106243828A CN201610749366.8A CN201610749366A CN106243828A CN 106243828 A CN106243828 A CN 106243828A CN 201610749366 A CN201610749366 A CN 201610749366A CN 106243828 A CN106243828 A CN 106243828A
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- China
- Prior art keywords
- parts
- color ink
- water
- water color
- weight ratio
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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Classifications
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/02—Printing inks
- C09D11/10—Printing inks based on artificial resins
- C09D11/106—Printing inks based on artificial resins containing macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
- C09D11/107—Printing inks based on artificial resins containing macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds from unsaturated acids or derivatives thereof
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/02—Printing inks
- C09D11/03—Printing inks characterised by features other than the chemical nature of the binder
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/02—Printing inks
- C09D11/03—Printing inks characterised by features other than the chemical nature of the binder
- C09D11/033—Printing inks characterised by features other than the chemical nature of the binder characterised by the solvent
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/02—Printing inks
- C09D11/10—Printing inks based on artificial resins
- C09D11/102—Printing inks based on artificial resins containing macromolecular compounds obtained by reactions other than those only involving unsaturated carbon-to-carbon bonds
- C09D11/103—Printing inks based on artificial resins containing macromolecular compounds obtained by reactions other than those only involving unsaturated carbon-to-carbon bonds of aldehydes, e.g. phenol-formaldehyde resins
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- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Inks, Pencil-Leads, Or Crayons (AREA)
Abstract
The invention discloses a kind of water color ink, including the material of following weight portion: pigment 10 25 parts, link stuff 25 40 parts, solvent 35 70 parts, defoamer 13 parts, levelling agent 13 parts, 25 parts of 5A molecular sieve, aerosil 12 parts, dispersant 25 parts, adhesion promoter 0.5 1.5 parts, ethanolamine 13 parts, triethylamine 35 parts, 2 amino 2 methyl 1 propanol 13 parts, 23 parts of anti-desiccant, colloid oil 12 parts.Can strengthen the adhesive force of ink in the present invention, prevent ink from ink bleed occur, changing the phenomenons such as ink, stability is strong, and the storage time is long, has certain anti-drying ability, pollutes little.
Description
Technical field
The present invention relates to technical field of ink, particularly relate to a kind of water color ink.
Background technology
The uniform slurry like material that water color ink is made up of materials such as link stuff, pigment, auxiliary agents.Link stuff offer ink must
The transfer performance wanted, pigment gives ink with color.The link stuff of water color ink is broadly divided into two types: water dilution type and water
Decentralized.The resinous type that the former can use has a variety of.The link stuff of water-dispersion type is by the monomer of emulsifying in water
Polymerization gained, it is two-phase system, and wherein oil phase disperses in aqueous phase with graininess, though can not be dissolved in water, but can be by
Water dilutes, so it is also assumed that be O/w emulsion type, water color ink with water as solvent, content of volatile organic compound pole
Low, environmental pollution is little；Oil-based ink is with organic solvent as solvent, big for environment pollution.Therefore, water color ink is increasingly subject to
Welcome；But at present, water color ink generally performance deficiency in dispersibility, glossiness, water-resistance, when solidification, the time is longer, fall
Low service efficiency, adds cost, and the storage effect of ink is also the problem merited attention simultaneously, simultaneously the storage effect of ink
Fruit is also the problem merited attention.
Summary of the invention
The technical problem existed based on background technology, the present invention proposes a kind of water color ink.
A kind of water color ink that the present invention proposes, including the material of following weight portion: pigment 10-25 part, link stuff 25-40
Part, solvent 35-70 part, defoamer 1-3 part, levelling agent 1-3 part, 5A molecular sieve 2-5 part, aerosil 1-2 part, dispersant
2-5 part, adhesion promoter 0.5-1.5 part, ethanolamine 1-3 part, triethylamine 3-5 part, 2-amino-2-methyl-1-propanol 1-3
Part, anti-desiccant 2-3 part, colloid oil 1-2 part.
Preferably, described link stuff be water soluble acrylic resin, malein acid ester resin and water-compatible amino resin according to
Weight ratio is 4:1:1 mixing composition.
Preferably, described solvent includes deionized water, ethanol and butyl glycol ether and is 3:1:1 mixing group according to weight ratio
Become.
Preferably, described defoamer is polyether-modified silicon.
Preferably, described levelling agent be polydimethylsiloxane and fluorinated siloxane be 2:1 mixing composition according to weight ratio.
Preferably, described adhesion promoter be amino silane and epoxy radicals silicone hydride be 1:2 mixing composition according to weight ratio.
Preferably, described dispersant is oleamide.
Preferably, described anti-desiccant be p-phenylenediamine, catechol and betanaphthol be 1:2:1 mixing group according to weight ratio
Become.
Preferably, described pigment is organic pigment or inorganic pigment.
The present invention compared with prior art, the Advantageous Effects having:
In the present invention, select oleamide can reduce resin particle molding melting viscosity as dispersant, disperse those
It is poorly soluble inorganic, the solid of organic pigment in liquid and liquid particles, also can prevent sedimentation and the cohesion of granule simultaneously, change
Enter mobility to have the function of slip agent simultaneously concurrently and can reduce ink pellet surface coefficient of friction；Owing to ink the most easily rises
The quality that impact of steeping oneself-meeting is printed, the polyether-modified silicon of defoamer combines polyethers with the advantage of both organic silicon defoamers, acid and alkali resistance
And inorganic salt, can be used for the froth breaking under harsh conditions, it is possible to decrease diagram of system surface tension, make oneself to be prone to the surface spreading at liquid
And absorption, thus reduce liquid surface film-strength to reach froth breaking purpose；Levelling agent can make ink during drying and forming-film
Forming a film smooth, smooth, uniform, using polydimethylsiloxane and fluorinated siloxane is that 2:1 mixes according to weight ratio
Being combined into, polydimethylsiloxane possesses good apparent condition control ability, but shrinkage cavity can often occurs, adds fluorination silica
Then can improve the wettability of base material after alkane, improve anti-shrinkage cavity ability；Add aerosil to play in ink system
Preferably anti-settling effect, but the levelability that more aerosil can make ink is deteriorated, and now adds 5A molecular sieve
Can improve the stability of ink, the polarity of the silicone hydroxyl on 5A molecular sieve hole wall can make 5A molecular sieve and with polar group
Link stuff between there is the good compatibility so that the existence of molecular sieve can make link stuff pass through chemical bond and molecular sieve even
Picking up, the supply chain network structure making ink is more perfect, improves the storage time of ink；Link stuff uses water-soluble acrylic tree
Fat, malein acid ester resin and water-compatible amino resin are 4:1:1 mixing composition according to weight ratio, water soluble acrylic resin's price
Low, use safety, can save resource and the energy, reduce environmental pollution and public hazards, and water-compatible amino resin is water white transparency viscosity liquid
Body, good water solubility, can have higher activity with infinite dilution；Solvent include deionized water, ethanol and butyl glycol ether and by
Being 3:1:1 mixing composition according to weight ratio, amalgamation is good each other, for relatively single solvent, has the strongest to link stuff resin
Dissolving power, major part organic volatile solvent is replaced by deionized water, thus reaches to be greatly lowered the purpose of atmospheric pollution；
Adhesion promoter be amino silane and epoxy radicals silicone hydride be 1:2 mixing composition according to weight ratio, epoxy radicals silicone hydride is novel
Epoxy radicals coupling agent, has reaction active groups, has good yellowing resistance characteristic, and amino silane has two kinds of functional groups,
I.e. amino and ethyoxyl, wherein three hydrolyzable groups (ethyoxyl), the most first hydrolysis generates silanol, owing to silanol is unstable
Fixed, the easily hydroxy combining with inorganic matter or metal surface is dehydrated, thus combines with inorganic matter or metal, on amino with
Two active hydrogens can react with various polymer, thus by chemical bond by two kinds of diverse material tight of character
Combine, both are with the use of improving the adhesive force of resin link stuff further, prevent ink from ink bleed occur, changing ink
Etc. phenomenon；Colloid oil can improve the set speed of ink, good stability, can be used to adjust ink body bone and gloss；Anti-dry
Agent is p-phenylenediamine, catechol and betanaphthol according to weight ratio is 1:2:1 mixing composition, for more single anti-desiccant,
It has antioxygenic property more widely, ink setting can be avoided too fast and cause the ink setting peeling on printing press；
Owing to stability and the viscosity of ink are had a great impact by the size of pH value, add ethanolamine, triethylamine and 2-amino-2-first
The pH value of base-1-propanol scalable water color ink makes it maintain between 8.0-9.5, wherein 2-amino-2-methyl-1-propanol and
Ethanolamine and water-base resin happens is that amidation process reaches to neutralize, and triethylamine and water-base resin happens is that esterification
Reach to neutralize.
Detailed description of the invention
Below in conjunction with specific embodiment, the present invention is explained orally further.
Embodiment 1
In the present embodiment, a kind of water color ink, including the material of following weight portion: pigment 10 parts, link stuff 25 parts, solvent
35 parts, defoamer 1 part, levelling agent 1 part, 2 parts of 5A molecular sieve, aerosil 1 part, dispersant 2 parts, adhesion promoter
0.5 part, ethanolamine 1 part, triethylamine 3 parts, 2-amino-2-methyl-1-propanol 1 part, 2 parts of anti-desiccant, colloid oil 1 part.
Link stuff be water soluble acrylic resin, malein acid ester resin and water-compatible amino resin be 4:1 according to weight ratio:
1 mixing composition, solvent includes deionized water, ethanol and butyl glycol ether and is 3:1:1 mixing composition according to weight ratio, defoamer
For polyether-modified silicon, levelling agent is polydimethylsiloxane and fluorinated siloxane is 2:1 mixing composition according to weight ratio, adhesive force
Accelerator be amino silane and epoxy radicals silicone hydride be 1:2 mixing composition according to weight ratio, dispersant is oleamide, anti-desiccant
Be p-phenylenediamine, catechol and betanaphthol according to weight ratio being 1:2:1 mixing composition, pigment is the phthalocyanine in organic pigment
Blue.
Embodiment 2
In the present embodiment, a kind of water color ink, including the material of following weight portion: pigment 17.5 parts, link stuff 32.5 parts,
Solvent 52.5 parts, defoamer 2 parts, levelling agent 2 parts, 3.5 parts of 5A molecular sieve, aerosil 1.5 parts, dispersant 3.5 parts, attached
Adhesion promoter 1 part, ethanolamine 2 parts, triethylamine 4 parts, 2-amino-2-methyl-1-propanol 2 parts, 2.5 parts of anti-desiccant, colloid
Oil 1.5 parts.
Link stuff be water soluble acrylic resin, malein acid ester resin and water-compatible amino resin be 4:1 according to weight ratio:
1 mixing composition, solvent includes deionized water, ethanol and butyl glycol ether and is 3:1:1 mixing composition according to weight ratio, defoamer
For polyether-modified silicon, levelling agent is polydimethylsiloxane and fluorinated siloxane is 2:1 mixing composition according to weight ratio, adhesive force
Accelerator be amino silane and epoxy radicals silicone hydride be 1:2 mixing composition according to weight ratio, dispersant is oleamide, anti-desiccant
Be p-phenylenediamine, catechol and betanaphthol according to weight ratio be 1:2:1 mixing composition, pigment be the lithol in organic pigment you
Red.
Embodiment 3
In the present embodiment, a kind of water color ink, including the material of following weight portion: pigment 25 parts, link stuff 40 parts, solvent
70 parts, defoamer 3 parts, levelling agent 3 parts, 5 parts of 5A molecular sieve, aerosil 2 parts, dispersant 5 parts, adhesion promoter
1.5 parts, ethanolamine 3 parts, triethylamine 5 parts, 2-amino-2-methyl-1-propanol 3 parts, 3 parts of anti-desiccant, colloid oil 2 parts.
Link stuff be water soluble acrylic resin, malein acid ester resin and water-compatible amino resin be 4:1 according to weight ratio:
1 mixing composition, solvent includes deionized water, ethanol and butyl glycol ether and is 3:1:1 mixing composition according to weight ratio, defoamer
For polyether-modified silicon, levelling agent is polydimethylsiloxane and fluorinated siloxane is 2:1 mixing composition according to weight ratio, adhesive force
Accelerator be amino silane and epoxy radicals silicone hydride be 1:2 mixing composition according to weight ratio, dispersant is oleamide, anti-desiccant
Be p-phenylenediamine, catechol and betanaphthol according to weight ratio being 1:2:1 mixing composition, pigment is the titanium white in inorganic pigment
Powder.
The above, the only present invention preferably detailed description of the invention, but protection scope of the present invention is not limited thereto,
Any those familiar with the art in the technical scope that the invention discloses, according to technical scheme and
Inventive concept equivalent or change in addition, all should contain within protection scope of the present invention.
Claims (9)
1. a water color ink, it is characterised in that include the material of following weight portion: pigment 10-25 part, link stuff 25-40 part,
Solvent 35-70 part, defoamer 1-3 part, levelling agent 1-3 part, 5A molecular sieve 2-5 part, aerosil 1-2 part, dispersant 2-5
Part, adhesion promoter 0.5-1.5 part, ethanolamine 1-3 part, triethylamine 3-5 part, 2-amino-2-methyl-1-propanol 1-3 part, instead
Desiccant 2-3 part, colloid oil 1-2 part.
A kind of water color ink the most according to claim 1, it is characterised in that: described link stuff is water-soluble acrylic tree
Fat, malein acid ester resin and water-compatible amino resin are 4:1:1 mixing composition according to weight ratio.
A kind of water color ink the most according to claim 1, it is characterised in that: described solvent include deionized water, ethanol and
Butyl glycol ether and according to weight ratio be 3:1:1 mixing composition.
A kind of water color ink the most according to claim 1, it is characterised in that: described defoamer is polyether-modified silicon.
A kind of water color ink the most according to claim 1, it is characterised in that: described levelling agent be polydimethylsiloxane and
Fluorinated siloxane is 2:1 mixing composition according to weight ratio.
A kind of water color ink the most according to claim 1, it is characterised in that: described adhesion promoter be amino silane and
Epoxy radicals silicone hydride is 1:2 mixing composition according to weight ratio.
A kind of water color ink the most according to claim 1, it is characterised in that: described dispersant is oleamide.
A kind of water color ink the most according to claim 1, it is characterised in that: described anti-desiccant is p-phenylenediamine, adjacent benzene
Diphenol and betanaphthol are 1:2:1 mixing composition according to weight ratio.
A kind of water color ink the most according to claim 1, it is characterised in that: described pigment is organic pigment or inorganic face
Material.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610749366.8A CN106243828A (en) | 2016-08-29 | 2016-08-29 | A kind of water color ink |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610749366.8A CN106243828A (en) | 2016-08-29 | 2016-08-29 | A kind of water color ink |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN106243828A true CN106243828A (en) | 2016-12-21 |
Family
ID=57596683
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201610749366.8A Pending CN106243828A (en) | 2016-08-29 | 2016-08-29 | A kind of water color ink |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN106243828A (en) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN113619307A (en) * | 2021-07-14 | 2021-11-09 | 江苏新亚彩印包装有限公司 | Environment-friendly printing process for carton |
| CN116445035A (en) * | 2023-04-25 | 2023-07-18 | 苏州中亚油墨有限公司 | Flexible plate water-based ink and preparation method thereof |
Citations (4)
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|---|---|---|---|---|
| CN101984008A (en) * | 2010-10-29 | 2011-03-09 | 沈阳化工大学 | Organic nano anti-corrosion coating and preparation method thereof |
| CN103436079A (en) * | 2013-07-23 | 2013-12-11 | 王景泉 | Environmental-friendly water-based nylon printing ink used for screen printing and preparation method thereof |
| CN103589233A (en) * | 2012-08-14 | 2014-02-19 | 成都普瑞斯特新材料有限公司 | Gravure alcohol ester plastic in-print environment-friendly ink |
| CN104974594A (en) * | 2015-07-13 | 2015-10-14 | 深圳市容大感光科技股份有限公司 | Printing ink composition with water-soluble solvent, application of printing ink composition, and printed circuit board |
-
2016
- 2016-08-29 CN CN201610749366.8A patent/CN106243828A/en active Pending
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101984008A (en) * | 2010-10-29 | 2011-03-09 | 沈阳化工大学 | Organic nano anti-corrosion coating and preparation method thereof |
| CN103589233A (en) * | 2012-08-14 | 2014-02-19 | 成都普瑞斯特新材料有限公司 | Gravure alcohol ester plastic in-print environment-friendly ink |
| CN103436079A (en) * | 2013-07-23 | 2013-12-11 | 王景泉 | Environmental-friendly water-based nylon printing ink used for screen printing and preparation method thereof |
| CN104974594A (en) * | 2015-07-13 | 2015-10-14 | 深圳市容大感光科技股份有限公司 | Printing ink composition with water-soluble solvent, application of printing ink composition, and printed circuit board |
Non-Patent Citations (2)
| Title |
|---|
| 凌云星等: "《油墨技术手册（上）》", 31 May 2009, 印刷工业出版社 * |
| 楚高利: "《特种印刷技术》", 30 September 2009, 印刷工业出版社 * |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN113619307A (en) * | 2021-07-14 | 2021-11-09 | 江苏新亚彩印包装有限公司 | Environment-friendly printing process for carton |
| CN116445035A (en) * | 2023-04-25 | 2023-07-18 | 苏州中亚油墨有限公司 | Flexible plate water-based ink and preparation method thereof |
| CN116445035B (en) * | 2023-04-25 | 2024-02-06 | 苏州中亚油墨有限公司 | Flexible plate water-based ink and preparation method thereof |
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