CN106243307A - A kind of mining macromolecule reinforcement material, filing provision and reinforcement means - Google Patents
A kind of mining macromolecule reinforcement material, filing provision and reinforcement means Download PDFInfo
- Publication number
- CN106243307A CN106243307A CN201610662058.1A CN201610662058A CN106243307A CN 106243307 A CN106243307 A CN 106243307A CN 201610662058 A CN201610662058 A CN 201610662058A CN 106243307 A CN106243307 A CN 106243307A
- Authority
- CN
- China
- Prior art keywords
- component
- flexible pipe
- mining
- injection
- hybrid
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 239000000463 material Substances 0.000 title claims abstract description 107
- 230000002787 reinforcement Effects 0.000 title claims abstract description 77
- 238000005065 mining Methods 0.000 title claims abstract description 58
- 229920002521 macromolecule Polymers 0.000 title claims abstract description 50
- 239000003245 coal Substances 0.000 claims abstract description 66
- 230000003014 reinforcing effect Effects 0.000 claims abstract description 34
- 239000003063 flame retardant Substances 0.000 claims abstract description 21
- 238000006243 chemical reaction Methods 0.000 claims abstract description 20
- 239000000203 mixture Substances 0.000 claims abstract description 19
- -1 isooctyl Chemical group 0.000 claims abstract description 16
- 150000003077 polyols Chemical class 0.000 claims abstract description 13
- 229920002545 silicone oil Polymers 0.000 claims abstract description 13
- 239000004721 Polyphenylene oxide Substances 0.000 claims abstract description 12
- 229920000570 polyether Polymers 0.000 claims abstract description 12
- 229920005862 polyol Polymers 0.000 claims abstract description 12
- 239000003054 catalyst Substances 0.000 claims abstract description 10
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 claims abstract description 7
- 239000002253 acid Substances 0.000 claims abstract description 7
- 229910052700 potassium Inorganic materials 0.000 claims abstract description 7
- 239000011591 potassium Substances 0.000 claims abstract description 7
- 239000012948 isocyanate Substances 0.000 claims abstract description 6
- 150000002513 isocyanates Chemical class 0.000 claims abstract description 6
- 238000002347 injection Methods 0.000 claims description 79
- 239000007924 injection Substances 0.000 claims description 79
- 239000011435 rock Substances 0.000 claims description 74
- 238000007569 slipcasting Methods 0.000 claims description 41
- 239000002002 slurry Substances 0.000 claims description 23
- 238000002156 mixing Methods 0.000 claims description 10
- 239000000126 substance Substances 0.000 claims description 10
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 9
- 238000007599 discharging Methods 0.000 claims description 9
- 238000013461 design Methods 0.000 claims description 7
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 claims description 6
- DOIRQSBPFJWKBE-UHFFFAOYSA-N dibutyl phthalate Chemical compound CCCCOC(=O)C1=CC=CC=C1C(=O)OCCCC DOIRQSBPFJWKBE-UHFFFAOYSA-N 0.000 claims description 6
- 230000004044 response Effects 0.000 claims description 6
- 238000007789 sealing Methods 0.000 claims description 6
- 238000000151 deposition Methods 0.000 claims description 5
- 239000000155 melt Substances 0.000 claims description 4
- XNGIFLGASWRNHJ-UHFFFAOYSA-N phthalic acid Chemical compound OC(=O)C1=CC=CC=C1C(O)=O XNGIFLGASWRNHJ-UHFFFAOYSA-N 0.000 claims description 4
- 239000000843 powder Substances 0.000 claims description 4
- 238000010008 shearing Methods 0.000 claims description 4
- 238000012360 testing method Methods 0.000 claims description 4
- ZCJGQPJZNXDTGT-UHFFFAOYSA-N N1C=CC=C1.C=12C(=C3C(=CC1)C3)C2 Chemical class N1C=CC=C1.C=12C(=C3C(=CC1)C3)C2 ZCJGQPJZNXDTGT-UHFFFAOYSA-N 0.000 claims description 3
- 239000004698 Polyethylene Substances 0.000 claims description 3
- 239000004743 Polypropylene Substances 0.000 claims description 3
- YSMRWXYRXBRSND-UHFFFAOYSA-N TOTP Chemical compound CC1=CC=CC=C1OP(=O)(OC=1C(=CC=CC=1)C)OC1=CC=CC=C1C YSMRWXYRXBRSND-UHFFFAOYSA-N 0.000 claims description 3
- URYYVOIYTNXXBN-UPHRSURJSA-N cyclooctene Chemical compound C1CCC\C=C/CC1 URYYVOIYTNXXBN-UPHRSURJSA-N 0.000 claims description 3
- 239000004913 cyclooctene Substances 0.000 claims description 3
- 125000003963 dichloro group Chemical group Cl* 0.000 claims description 3
- 239000011256 inorganic filler Substances 0.000 claims description 3
- 229910003475 inorganic filler Inorganic materials 0.000 claims description 3
- NLYAJNPCOHFWQQ-UHFFFAOYSA-N kaolin Chemical compound O.O.O=[Al]O[Si](=O)O[Si](=O)O[Al]=O NLYAJNPCOHFWQQ-UHFFFAOYSA-N 0.000 claims description 3
- 229910052622 kaolinite Inorganic materials 0.000 claims description 3
- 229920000573 polyethylene Polymers 0.000 claims description 3
- 229920001155 polypropylene Polymers 0.000 claims description 3
- 210000002966 serum Anatomy 0.000 claims description 3
- 235000012239 silicon dioxide Nutrition 0.000 claims description 3
- 239000000377 silicon dioxide Substances 0.000 claims description 3
- 239000000454 talc Substances 0.000 claims description 3
- 235000012222 talc Nutrition 0.000 claims description 3
- 229910052623 talc Inorganic materials 0.000 claims description 3
- 238000009434 installation Methods 0.000 claims description 2
- 238000005086 pumping Methods 0.000 claims description 2
- XLJMAIOERFSOGZ-UHFFFAOYSA-M cyanate Chemical compound [O-]C#N XLJMAIOERFSOGZ-UHFFFAOYSA-M 0.000 claims 1
- 150000002148 esters Chemical class 0.000 claims 1
- 150000005846 sugar alcohols Polymers 0.000 claims 1
- 230000035699 permeability Effects 0.000 abstract description 5
- 230000007613 environmental effect Effects 0.000 abstract description 3
- 230000008901 benefit Effects 0.000 abstract description 2
- 239000012466 permeate Substances 0.000 abstract description 2
- 238000007596 consolidation process Methods 0.000 description 22
- 230000000694 effects Effects 0.000 description 17
- 230000035882 stress Effects 0.000 description 15
- 238000005516 engineering process Methods 0.000 description 10
- 238000000034 method Methods 0.000 description 9
- 239000000047 product Substances 0.000 description 8
- 238000004519 manufacturing process Methods 0.000 description 7
- 230000008859 change Effects 0.000 description 6
- 238000011049 filling Methods 0.000 description 6
- 230000007246 mechanism Effects 0.000 description 5
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 5
- MQIUGAXCHLFZKX-UHFFFAOYSA-N Di-n-octyl phthalate Natural products CCCCCCCCOC(=O)C1=CC=CC=C1C(=O)OCCCCCCCC MQIUGAXCHLFZKX-UHFFFAOYSA-N 0.000 description 4
- 230000003487 anti-permeability effect Effects 0.000 description 4
- BJQHLKABXJIVAM-UHFFFAOYSA-N bis(2-ethylhexyl) phthalate Chemical compound CCCCC(CC)COC(=O)C1=CC=CC=C1C(=O)OCC(CC)CCCC BJQHLKABXJIVAM-UHFFFAOYSA-N 0.000 description 4
- 238000000280 densification Methods 0.000 description 4
- 230000006870 function Effects 0.000 description 4
- 239000011440 grout Substances 0.000 description 4
- 239000007788 liquid Substances 0.000 description 4
- 230000008569 process Effects 0.000 description 4
- 238000007711 solidification Methods 0.000 description 4
- 230000008023 solidification Effects 0.000 description 4
- HHDUMDVQUCBCEY-UHFFFAOYSA-N 4-[10,15,20-tris(4-carboxyphenyl)-21,23-dihydroporphyrin-5-yl]benzoic acid Chemical compound OC(=O)c1ccc(cc1)-c1c2ccc(n2)c(-c2ccc(cc2)C(O)=O)c2ccc([nH]2)c(-c2ccc(cc2)C(O)=O)c2ccc(n2)c(-c2ccc(cc2)C(O)=O)c2ccc1[nH]2 HHDUMDVQUCBCEY-UHFFFAOYSA-N 0.000 description 3
- 239000000853 adhesive Substances 0.000 description 3
- 230000001070 adhesive effect Effects 0.000 description 3
- 230000032683 aging Effects 0.000 description 3
- 230000015572 biosynthetic process Effects 0.000 description 3
- 239000003795 chemical substances by application Substances 0.000 description 3
- 230000006835 compression Effects 0.000 description 3
- 238000007906 compression Methods 0.000 description 3
- 238000011161 development Methods 0.000 description 3
- 230000018109 developmental process Effects 0.000 description 3
- 238000012423 maintenance Methods 0.000 description 3
- 229920000642 polymer Polymers 0.000 description 3
- 230000035939 shock Effects 0.000 description 3
- 239000007787 solid Substances 0.000 description 3
- 230000009466 transformation Effects 0.000 description 3
- 229920002472 Starch Polymers 0.000 description 2
- 238000002485 combustion reaction Methods 0.000 description 2
- 239000012141 concentrate Substances 0.000 description 2
- 238000010276 construction Methods 0.000 description 2
- 238000009792 diffusion process Methods 0.000 description 2
- 239000003292 glue Substances 0.000 description 2
- 230000008595 infiltration Effects 0.000 description 2
- 238000001764 infiltration Methods 0.000 description 2
- 230000007774 longterm Effects 0.000 description 2
- 229920002635 polyurethane Polymers 0.000 description 2
- 239000004814 polyurethane Substances 0.000 description 2
- 235000019698 starch Nutrition 0.000 description 2
- 238000003756 stirring Methods 0.000 description 2
- 238000012795 verification Methods 0.000 description 2
- 241000167854 Bourreria succulenta Species 0.000 description 1
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 1
- 229910000831 Steel Inorganic materials 0.000 description 1
- 230000000903 blocking effect Effects 0.000 description 1
- 230000037396 body weight Effects 0.000 description 1
- 235000019693 cherries Nutrition 0.000 description 1
- 238000004140 cleaning Methods 0.000 description 1
- 239000002817 coal dust Substances 0.000 description 1
- 230000000052 comparative effect Effects 0.000 description 1
- 230000008602 contraction Effects 0.000 description 1
- 238000006073 displacement reaction Methods 0.000 description 1
- 230000009977 dual effect Effects 0.000 description 1
- 238000013467 fragmentation Methods 0.000 description 1
- 238000006062 fragmentation reaction Methods 0.000 description 1
- 230000006872 improvement Effects 0.000 description 1
- 230000010354 integration Effects 0.000 description 1
- 230000035800 maturation Effects 0.000 description 1
- 230000000149 penetrating effect Effects 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 230000035484 reaction time Effects 0.000 description 1
- 238000011160 research Methods 0.000 description 1
- 239000011347 resin Substances 0.000 description 1
- 229920005989 resin Polymers 0.000 description 1
- DCKVNWZUADLDEH-UHFFFAOYSA-N sec-butyl acetate Chemical compound CCC(C)OC(C)=O DCKVNWZUADLDEH-UHFFFAOYSA-N 0.000 description 1
- 239000000243 solution Substances 0.000 description 1
- 230000007480 spreading Effects 0.000 description 1
- 238000003892 spreading Methods 0.000 description 1
- 239000008107 starch Substances 0.000 description 1
- 238000009955 starching Methods 0.000 description 1
- 239000010959 steel Substances 0.000 description 1
- 238000005728 strengthening Methods 0.000 description 1
- 239000000725 suspension Substances 0.000 description 1
- 238000003325 tomography Methods 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
- C08G18/40—High-molecular-weight compounds
- C08G18/48—Polyethers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/08—Processes
- C08G18/16—Catalysts
- C08G18/166—Catalysts not provided for in the groups C08G18/18 - C08G18/26
- C08G18/168—Organic compounds
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/49—Phosphorus-containing compounds
- C08K5/51—Phosphorus bound to oxygen
- C08K5/52—Phosphorus bound to oxygen only
- C08K5/521—Esters of phosphoric acids, e.g. of H3PO4
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J11/00—Features of adhesives not provided for in group C09J9/00, e.g. additives
- C09J11/02—Non-macromolecular additives
- C09J11/04—Non-macromolecular additives inorganic
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J11/00—Features of adhesives not provided for in group C09J9/00, e.g. additives
- C09J11/02—Non-macromolecular additives
- C09J11/06—Non-macromolecular additives organic
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J11/00—Features of adhesives not provided for in group C09J9/00, e.g. additives
- C09J11/08—Macromolecular additives
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J175/00—Adhesives based on polyureas or polyurethanes; Adhesives based on derivatives of such polymers
- C09J175/04—Polyurethanes
- C09J175/08—Polyurethanes from polyethers
-
- E—FIXED CONSTRUCTIONS
- E21—EARTH OR ROCK DRILLING; MINING
- E21B—EARTH OR ROCK DRILLING; OBTAINING OIL, GAS, WATER, SOLUBLE OR MELTABLE MATERIALS OR A SLURRY OF MINERALS FROM WELLS
- E21B33/00—Sealing or packing boreholes or wells
- E21B33/10—Sealing or packing boreholes or wells in the borehole
- E21B33/13—Methods or devices for cementing, for plugging holes, crevices or the like
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/014—Additives containing two or more different additives of the same subgroup in C08K
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/02—Flame or fire retardant/resistant
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Engineering & Computer Science (AREA)
- Life Sciences & Earth Sciences (AREA)
- Geology (AREA)
- Mining & Mineral Resources (AREA)
- Physics & Mathematics (AREA)
- Environmental & Geological Engineering (AREA)
- Fluid Mechanics (AREA)
- General Life Sciences & Earth Sciences (AREA)
- Geochemistry & Mineralogy (AREA)
- Inorganic Chemistry (AREA)
- Consolidation Of Soil By Introduction Of Solidifying Substances Into Soil (AREA)
Abstract
The present invention proposes a kind of mining macromolecule reinforcement material, filing provision and reinforcement means, mining macromolecule reinforcement material includes component A and B component, and component A content by mass percentage includes following material composition: polyether polyol 75 85%, fire retardant 12 20%, catalyst 2 3.5%, organotin 0.1 0.8%, isooctyl acid potassium 0.2 1% and silicone oil 0.5 1%；B component content by mass percentage includes following material composition: isocyanates 85 92% and fire retardant 8 15%；Component A and B component are formed according to volume ratio 1:1 hybrid reaction and reinforce serosity.Reinforcement material of the present invention does not only rely on the concentration pressure difference of pump function and permeates, and rely on the expansion characteristics of material itself to produce the second permeation of self, serosity is spread to surrounding, have that permeability is strong, cohesive force is high, good-toughness, superhigh intensity and the advantage such as flame-retarding, environmental protection, the reinforcing of the most described reinforcement material is swift to operate, can adapt to the coal seam under the conditions of various complicated coal mining geologies reinforce, wide market.
Description
Technical field
The present invention relates to technical field of function materials, be specifically related to a kind of reinforcement material, a kind of mining high score
Sub-reinforcement material, filing provision and coal (rock) layer reinforcement means.
Background technology
As a big coal country, coal still will not change as the status of China's main energy sources, but China's coal-mine safety
Production form is fundamentally improved the most not yet, and annual mine safety accidents often occurs, and the mortality rate of coal mining accident is high.
The property safety of Safety of Coal Mine Production, the life security of protection miner and country is always in the weight of national security production protection it
Weight.Potential safety hazard in colliery has all many-sides, such as: gas, permeable, landslide etc..
New mine product material and technology are to eliminate the effective ways of the underground coal mine disasters such as gas, roof fall, fire and top board
One of, external new mine product Materials is with a long history, all has ripe use in the state such as Australian, Russian, German.With
That coal industry safety in production information and technology internationalization exchange increasingly extensively with go deep into, the ore deposit of Application comparison maturation abroad
Start incoming domestic with new material, the seventies in last century, Hebei Kai Luan group equipment Imported From German EMH Company product and technology, at Fan Ge village coal
Water blockoff has been carried out with macromolecular material under mine.Later, though this technology has been in progress in terms of scientific research, but there is no spread
And industrialization.Until 2000, Haoke Mining Engineering Appts. Co Ltd, Jining introduces and absorbs France's macromolecular material and technology,
The most progressively go on Independent Innovation.Through the development of more than ten years, new mine product material is as the elder generation solving Safety of Coal Mine Production
Enter technology, by domestic introduction, digest, absorb, the most mining macromolecule reinforcement material collapses and emits improvement and top solving work surface
In the safety problems such as plate is safeguarded, country rock solidification under reinforcing laneway and unfavorable geological condition, with its spy such as safe efficient and quick
Point obtains promotion and application widely.
Coal production proposes the higher target of renewal to safety management at present, and coal body reinforcing, gas control, water damage are prevented
The solution of model, roof control, fire extinguishing etc. safety engineering is increasing to the demand of safe new material, range of application
Increasingly wider, but now widely used mining macromolecule reinforcement material is buying, various in style, product technology and product matter
Measuring very different, be not easy to the integrated management of mine safety, the most current mining macromolecule reinforcement material is in use
It is primarily present following shortcoming:
(1) fractured coal and rock after reinforcing to stand repeatedly acutely mine pressure impact, to the volume contraction after material consolidation, glues
Knotting strength and comprcssive strength require the highest, but existing mining macromolecule reinforcement material is unable to reach this requirement of strength；
(2) the flash-point characteristic of existing mining macromolecule reinforcement material, flame-retarding characteristic cannot meet mine safety requirement；
(3) the rapid hardening characteristic of existing mining macromolecule reinforcement material cannot meet chemical consolidation and digging construction and quickly propels phase
In conjunction with use requirement；
(4) harmful components of reinforcement material are required that strict, current mining macromolecule is reinforced by current underground ventilating limited space
Material cannot meet mine environmental requirement.
Summary of the invention
The present invention based on above-mentioned prior art problem, the proposing a kind of brand-new mining macromolecule reinforcement material, add of innovation
Note equipment and coal (rock) layer reinforcement means, described mining macromolecule reinforcement material can expand self, automatically generates serosity
Second permeation pressure in coal and rock crack, its concentration pressure difference not only relying on pump function is permeated, and can be depended on
Expansion characteristics by material itself produces the second permeation of self so that serosity spreads to surrounding, so that described mining height
The range of scatter of molecule reinforcement material and pack densification, compared to existing common reinforcement material several times to be exceeded, have permeability
By force, cohesive force height, good-toughness, superhigh intensity and the unique advantage such as flame-retarding, environmental protection, and be exclusively used in institute by innovation
State the filing provision of mining macromolecule reinforcement material so that the reinforcing of described mining macromolecule reinforcement material is swift to operate simply,
Can adapt to the reinforcing under the conditions of various complicated coal mining geologies, wide market.
It is as follows that the present invention solves the technical scheme that above-mentioned technical problem taked:
A kind of mining macromolecule reinforcement material, including component A and B component, wherein component A content by mass percentage includes as follows
Material composition: polyether polyol 75-85%, fire retardant 12-20%, catalyst 2-3.5%, organotin 0.1-0.8%, isooctyl acid potassium
0.2-1% and silicone oil 0.5-1%；Wherein B component content by mass percentage includes following material composition: isocyanates 85-92% and
Fire retardant 8-15%；Component A and B component are formed according to volume ratio 1:1 hybrid reaction and reinforce serosity simultaneously.
Further according to mining macromolecule reinforcement material of the present invention, wherein component A content by mass percentage
Including following material composition: polyether polyol 80%, fire retardant 16%, catalyst 2.2%, organotin 0.5%, isooctyl acid potassium 0.6% and
Silicone oil 0.7%；Wherein B component content by mass percentage includes following material composition: isocyanates 90% and fire retardant 10%.
Further according to mining macromolecule reinforcement material of the present invention, the wherein described polyether polyols in component A
Alcohol uses MN-500 type polyether polyol, and described catalyst uses dibutyl phthalate or dioctyl phthalate, institute
State silicone oil and use CGYM-1 type silicone oil.
Further according to mining macromolecule reinforcement material of the present invention, the wherein fire retardant in component A and B component
For tricresyl phosphate (2-chloropropyl) ester.
Further according to mining macromolecule reinforcement material of the present invention, the wherein fire retardant in component A and B component
It is in the polypropylene of 11-15g/10min, mass percentage content by the melt index that mass percentage content is 65%-70%
For 5%-8% melt index the polyethylene of 1.8-2.0g/10min, mass percentage content be 15%-20% selected from powder
At least one inorganic filler in powder Talcum, kaolinite, sericite, silicon dioxide and kieselguhr and mass percentage content
For 5%-8% selected from decabrominated dipheny base ether, ten dichloro ten dihydro dimethano benzene azoles cyclo-octene or the organic fire-resistings of its mixture
Halogenide is mixed to prepare.
Further according to mining macromolecule reinforcement material of the present invention, wherein the serum density of component A is 1.010
～1.040 g/cm3, the initial viscosity of component A is 130～260mPa s, and the serum density of B component is 1.220～1.240
g/cm3, the initial viscosity of B component is 240～359mPa s, and the maximum temperature of component A and B component mixing is less than 140
DEG C, the response time of component A and B component is less than 120 seconds, the pressure resistance reinforcing serosity that component A and B component hybrid reaction are formed
Degree is more than 3.0Mpa more than 15MPa, shearing strength more than 15MPa, adhesion strength more than 40MPa, tensile strength.
A kind of filing provision being exclusively used in mining macromolecule reinforcement material of the present invention, including a double-component chemistry note
Stock pump and biliquid injection hybrid gun, described double-component chemical grouting pump by component A and B component according to predetermined mixed proportion
Pumping is injected in described biliquid injection hybrid gun, and described biliquid injection hybrid gun realizes the hybrid reaction of component A and B component,
And the reinforcing serosity obtained after hybrid reaction is filled into destination locations.
Further according to filing provision of the present invention, wherein said double-component chemical grouting pump includes the first barrel
1, second barrel the 2, first suction flexible pipe the 3, second suction flexible pipe 4, multifunctional air pump 5, first flow controller 6, second flow
Controller the 7, first discharge flexible pipe 8 and the second discharge flexible pipe 9, described first barrel 1 is used for depositing described component A, and described second
Barrel 2 is used for depositing described B component, and described first suction flexible pipe 3 is connected between the first barrel 1 and multifunctional air pump 5, described
Second suction flexible pipe 4 is connected between the second barrel 2 and multifunctional air pump 5, described first discharge flexible pipe 8 and the second discharge flexible pipe
9 are connected to described multifunctional air pump 5, are provided with described first flow controller 6, described on described first discharge flexible pipe 8
Be provided with described second flow controller 7 on second discharge flexible pipe 9, described multifunctional air pump 5 by the first suction flexible pipe 3 by the
Component A in one barrel 1 is drawn in the first discharge flexible pipe 8, soft to the first discharge by first flow controller 6 control and suck
The volume flow of the component A in pipe 8, the B component in the second barrel 2 is taken out by described multifunctional air pump 5 by the second suction flexible pipe 4
It is drawn onto in the second discharge flexible pipe 9, by the volume of the B component in second flow controller 7 control and suck to the second discharge flexible pipe 9
Flow；Described biliquid injection hybrid gun includes that the first injection pipeline 10, second injects pipeline 13 and hybrid injection pipeline 16, described
The discharge end of the first injection pipeline 10 and the second injection pipeline 13 is communicated in described hybrid injection pipeline 16 jointly, and described biliquid is noted
Penetrate hybrid gun and be integrally formed into Y-shaped structure, described first injection pipeline 10 and the second injection pipeline 13 are provided with valve,
The discharging opening of described first discharge flexible pipe 8 is connected to the charging aperture of described first injection pipeline 10, described second discharge flexible pipe 9
Discharging opening is connected to the charging aperture of described second injection pipeline 13, is injected into the component A in described first injection pipeline 10 and note
The B component entered to the second injection pipeline 13 carries out uniform hybrid reaction in hybrid injection pipeline 16 and generates reinforcing serosity, and
Reinforcing serosity is filled into destination locations by blended injection pipeline 16.
A kind of reinforcement means, uses filing provision of the present invention by mining macromolecule reinforcement material of the present invention
Fill to coal seam, rock stratum or coal rock layer crack.
Further according to reinforcement means of the present invention, specifically include following steps:
Step one, carry out the design of position, hole, determine the design including injected hole position, slip casting hole depth, slip casting aperture, hole sealing depth
Parameter；
Step 2, position, the hole parameter determined according to step one, hole；
Step 3, selection one boring insert syringe and injection floral tube, and install hole packer, described injection according to hole sealing depth
Floral tube is connected to syringe front end；
Step 4, air-supply pipeline and the filing provision described in claim 7 or 8 are installed, first carry out double-component in filing provision
The installation learning grouting pump and biliquid injection hybrid gun connects, and then biliquid is injected the discharging of hybrid injection pipeline in hybrid gun
Mouth is connected in step 3 the charging aperture of the syringe arranged, and finally carries out pressure-drop in pipeline test；
Step 5, startup filing provision start slip casting, will reinforce serosity and inject inside coal seam, rock stratum or coal rock layer；
Step 6, reach to stop to stop slip casting after note requires；
Step 7, select another hole repeated execution of steps three to step 6, carry out changing hole slip casting；
Step 8, after the slip casting of porose position completes, clean all devices.
Technical scheme has original creation feature and prominent effect, these features and effect in the following areas necessarily
Mining macromolecule reinforcement material of the present invention and the innovation of filing provision thereof is implied in degree:
(1) present invention proposes a kind of brand-new mining macromolecule reinforcement material, is made up of two kinds of components of A, B, two kinds of component reactions
Front is pure liquid, has good permeability, may penetrate in small crack, and after two kinds of components mixing, the response time is extremely short,
Can be rapidly solidified and reach fastening strength requirement, during simultaneous reactions, thermal discharge is low, and the solidfied material formed after reaction is strong
Degree height, strong cohesive property can ensure that the high adhesion with rock stratum, good pliability can bear the long term of strata pressure,
And there is strong anti-permeability performance, wear-resistant, shock resistance and ageing resistace such that it is able to reach to consolidate for a long time the mesh of rock mass
, belong to a kind of preferable mining reinforcement material.
(2) mining macromolecule reinforcement material of the present invention meeting the National Development and Reform Commission, " adjust by the industrial structure
Whole guidance list (basis in 2011) " the 3rd article of mine disaster of the first kind " encouragement class " Section 3 coal (gas, coal dust, mine water,
Fire, country rock, ground temperature, bump etc.) preventing and treating, belong to country and encourage developing industry, meet the requirement of national industrial policies, and through Shan
The many successes verification experimental verification of each getting working face in down-hole in each mining area of western Changwu Ting Nan coal industry Co., Ltd, described mining
Macromolecule reinforcement material can as solving the staple product of the Safety of Coal Mine Production problems such as Roof Control, fire, gas and water damage,
Product technology is advanced, and anti-evil is respond well.
(3) mining macromolecule reinforcement material of the present invention can carry out grouting and reinforcing to improve to top, tunnel side and cherry coal district
Existing supporting means can be carried out strengthening supporting by slip casting by bulk strength, portion of side, top shortcake is dissipated country rock body weight and is newly cured as
One entirety, substantially increases the bearing capacity that coal body is overall, enhances coal body comprcssive strength, effectively reduce surrouding rock deformation, its
Main consolidation effect is embodied in the following aspects:
(3-1) the network skeleton effect of slurry consolidation body
Mining macromolecule reinforcement material serosity of the present invention through extruding or penetrate in the crack that country rock is crisscross with coal seam,
Forming slurry consolidation body/slurry consolidation material behind rock stratum or coal rock layer consolidation, slurry consolidation body is lamellar or the bar that thin and thick differs
Shape, almost can be interconnected formation network skeleton, thus forms network skeleton structure, simultaneously slurry consolidation body in whole country rock
Having good toughness and caking property, when outer load increases, slurry consolidation body deforms but does not destroys, and load is mainly by intensity
Higher coal and rock undertakes, the failure condition of such country rock by original crack plane of weakness strength condition to close to coal mass strength condition
Convert.When stress in coal bed exceedes coal mass strength generation moderate finite deformation, the network of slurry consolidation body is with its good toughness and glues
Knotting strength plays skeleton function, improves the residual strength of country rock, limits the extension of surrounding rock failure, thus improves its maintenance situation.
(3-2) filling densification and the effect of transformation surrounding rock failure mechanism
Mining macromolecule reinforcement material serosity of the present invention is under the effect of pump pressure, except the fracture filling that some are bigger is full
Outward, it is also possible to by some fillings less than closing crack and rimala compression, even make it close, thus substantially increase country rock
Elastic modelling quantity and intensity.Concrete after slip casting solidifies, it is full of slurry consolidation material in crack, adds slurry consolidation material
Cementation to fissure-plane, makes the stress of end, crack concentrate and significantly weakens or disappear, so that the failure mechanism of country rock is sent out
Raw transformation.Additionally when there is bigger crack in country rock, the rock mass near crack is in two dimensional stress state, when being full of in crack
After curing materials or densification, three-dimensional stress state will be become, and the strength ratio two that rock mass is when three-dimensional stress state to time notable
Increase, and fragility weakens, plasticity strengthen, from the point of view of stress, slip casting solidification also play transformation rock mass damage mechanism and
Improve the effect of Surrounding Rock Strength.
(3-3) rockbolt stress state is improved
Mining macromolecule reinforcement material of the present invention uses filing provision to make existing by the effect such as slurry infiltration, slip casting press-in
The end anchor formula anchor pole having in supporting in form is changed into full length fastening or the extensible bolting length, solid by injecting paste material in bolthole
Knot body reacts on country rock, stops it to deform, thus produces restriction country rock change at Anchor Agent, injecting paste material on country rock contact surface
The shear stress of shape so that anchor pole forms an entirety with country rock, gives full play to suspension roof support effect.
(3-4) rock mass strength is enclosed in raising
After mining macromolecule reinforcement material of the present invention enters coal rock layer by slip casting, it is possible to change the mechanical property of its plane of weakness
Can, i.e. improve the cohesive strength between crack and coal and rock and internal friction angle, increase the resistance of relative displacement between rock mass internal block, from
And improve the stability in the large of roof rock mass.
(3-5) carrying structure is formed
Mining macromolecule reinforcement material of the present invention passes through grouting and reinforcing, and loose rock mass can be made again to be cemented to entirety, shape
Become and carry structure, and give full play to the self-stable ability of country rock, effectively utilize infiltration and the diffusion of serosity, closure country rock to split
Gap, can stop aqueous vapor to invade internal rock mass, prevents water damage and the air slaking further impact on coal body, to keeping coffer mechanics
Can, realize the most significant.Mining macromolecule reinforcement material 100% solid content the most of the present invention, ungauged regions, with
Time comply fully with the flame-retardancy requirements in colliery.
Accompanying drawing explanation
Accompanying drawing 1 is the structural representation of filing provision of the present invention；
Accompanying drawing 2 is the flow chart of reinforcement means of the present invention；
In figure, the implication of each reference is as follows:
1-the first barrel, 2-the second barrel, 3-the first suction flexible pipe, 4-the second suction flexible pipe, 5-multifunctional air pump, 6-is first-class
Amount controller, 7-second flow controller, 8-the first discharge flexible pipe, 9-the second discharge flexible pipe, 10-first injects pipeline, 11-
One check valve, 12-the first ball valve, 13-second injects pipeline, 14-the second check valve, 15-the second ball valve, 16-hybrid injection pipe
Road, 17-syringe.
Detailed description of the invention
Hereinafter technical scheme is described in detail, so that those skilled in the art can more clearly manage
Solve the present invention, but the most therefore limit the scope of the invention.
First composition of mining macromolecule reinforcement material of the present invention and preparation method thereof it is shown in detail in.Described mining
Macromolecule reinforcement material belongs to liquid macroimolecule resin material, and including two kinds of components of A, B, wherein component A contains by mass percentage
Measure and include following material composition:
Polyether polyol 75-85% fire retardant 12-20%
Catalyst 2-3.5% organotin 0.1-0.8%
Isooctyl acid potassium 0.2-1% silicone oil 0.5-1%；
Wherein B component content by mass percentage includes following material composition:
Isocyanates 85-92% fire retardant 8-15%；
Wherein polyether polyol preferably employs MN-500 type polyether polyol, and described catalyst preferably uses phthalic acid two
Butyl ester (DBP) or dioctyl phthalate (DOP), described silicone oil is preferably CGYM-1 type silicone oil, and described fire retardant is preferred
Use tricresyl phosphate (2-chloropropyl) ester, i.e. TCPP, or the described fire retardant innovated further is (fire-retardant by mass percentage content
The mass percent of agent self) it is that the melt index of 65%-70% is in the polypropylene of 11-15g/10min, mass percent contains
Amount is being selected from of 15%-20% for the melt index of 5%-8% in polyethylene, the mass percentage content of 1.8-2.0g/10min
At least one inorganic filler and mass percent in powdered talc, kaolinite, sericite, silicon dioxide and kieselguhr contain
Amount for 5%-8% selected from decabrominated dipheny base ether, ten dichloro ten dihydro dimethano benzene azoles cyclo-octene or organic resistances of its mixture
Combustion halogenide is mixed to prepare
Further preferably wherein component A content by mass percentage includes following material composition:
Polyether polyol (MN-500) 80% fire retardant (TCPP) 16%
Catalyst (DBP, DOP) 2.2% organotin 0.5%
Isooctyl acid potassium 0.6% silicone oil (CGYM-1) 0.7%；
B component content by mass percentage includes following material composition:
Isocyanates 90% fire retardant (TCPP) 10%.
Described component A and B component in use, are mixed by described mining macromolecule reinforcement material according to volume ratio 1:1
Closing, after mixing, component A and B component react generation adhesive for polyurethane reinforcing serosity, described reinforcing serosity within the extremely short time
There is good resistance to compression, tension, shearing resistance and adhesion strength, it is possible to be well applied to the reinforcing in coal petrography crack, the most described resistance
The interpolation of combustion agent also makes described reinforcing serosity have good flame-retarding characteristic, concrete described component A, B component and reaction thereof
After the adhesive for polyurethane that obtains reinforce the characteristic of serosity as shown in Table 1 and Table 2.
Table 1 component A, the material property of B component and response time thereof
The reinforcing slurry characteristics testing result obtained after table 2 component A and B component reaction
Two kinds of components that visible mining macromolecule reinforcement material of the present invention includes have good permeability, permeable
In small crack, two kinds of component response time are extremely short simultaneously, it is possible to fast reaction becomes to reinforce serosity, described reinforcing serosity
Comprcssive strength is more than 40MPa, and tensile strength is more than 15MPa, and shearing strength is more than 15MPa, and adhesion strength is more than 3.0MPa, high-strength
Degree, high-adhesion ensure that reinforcing serosity can realize high-strength adhesive with coal rock layer and form slurry consolidation body, reinforce simultaneously and see slurry
Liquid has good pliability, stronger anti-permeability performance, wear-resistant, shock resistance and ageing resistace, and flame-retarding characteristic is excellent
Good, meet the high strength reinforcement requirement of various complex condition, described reinforcing serosity is handed in length and breadth through extruding or penetrating into country rock
Forming slurry consolidation body with coal seam, rock stratum or coal rock layer after consolidating in wrong crack, described slurry consolidation body is that thin and thick differs
Lamellar or strip, almost can be interconnected formation network skeleton, thus forms network skeleton structure in whole country rock, starches simultaneously
Liquid-solid knot body has good toughness and caking property, and when outer load increases, slurry consolidation body deforms but do not destroys, load master
To be undertaken by the coal and rock that intensity is higher, the failure condition of such country rock by original crack plane of weakness strength condition to close to coal body
Strength condition converts.When stress in coal bed exceedes coal mass strength generation moderate finite deformation, the network of slurry consolidation body is good with it
Toughness and adhesion strength play skeleton function, improve the residual strength of country rock, limit the extension of surrounding rock failure, thus improve maintenance
Situation.The most described reinforcing serosity pump pressure effect under, except the fracture filling that some are bigger completely in addition to, it is also possible to by some
Filling less than closing crack and rimala compression, even make it close, thus substantially increase the elastic modelling quantity of country rock and strong
Degree, and after slip casting solidifies, in crack, it is full of slurry consolidation material, add that the bonding of fissure-plane is made by slurry consolidation material
With, make the stress of end, crack concentrate and significantly weaken or disappear, so that the failure mechanism of country rock changes.Additionally work as country rock
During the bigger crack of middle existence, the rock mass near crack is in two dimensional stress state, after being full of curing materials or densification in crack,
To become three-dimensional stress state, and the strength ratio two that rock mass is when three-dimensional stress state to time significantly increase, and fragility weakens,
Plasticity strengthens, and from the point of view of stress, slip casting solidification also plays and changes rock mass damage mechanism and improve the effect of Surrounding Rock Strength.
The most described reinforcing serosity can also improve rockbolt stress state, improve and enclose rock mass strength, formation high intensity after injecting coal rock layer
Carrying structure.
Present invention further propose that reinforcement technique based on described mining macromolecule reinforcement material, the present invention described above creates
It is pure liquid under room temperature before new macromolecule reinforcement material reaction, there is good permeability, may penetrate in small crack,
Only mix when reinforcing, and the hybrid reaction time is short, it is possible to be rapidly solidified and reach to need intensity, heat release in course of reaction
Measuring low, after consolidation, solidfied material intensity is high, and strong cohesive property can guarantee that the high adhesion with rock stratum, good pliability can bear ground
The long term of stressor layer, and there is strong anti-permeability performance, wear-resistant, shock resistance and ageing resistace, thus reach permanent
The purpose of firm rock mass.
Polymer chemistry grouting reinforcement technique is one and is very practical and the engineering of applied range, its profit
By hydraulic pressure, air pressure principle, polymer chemistry serosity is evenly injected into the coal with the weak structure such as hole, crack, joint
In rock mass, coal and rock, in modes such as filling, permeate and be compacted, is cemented to an entirety so that coal and rock forms intensity by serosity
The new construction body high, anti-permeability performance is good, stability is high, thus improve the physico-mechanical properties of coal and rock, improve its globality and
Intensity.
The reinforcement technique of mining macromolecular material of the present invention belongs to a kind of polymer chemistry grouting reinforcement technique, is adopted
Equipment include a double-component chemical grouting pump and biliquid injection hybrid gun, can be dried or in moist environment
Use.Described double-component chemical grouting pump as shown in Figure 1, including first barrel the 1, second barrel the 2, first suction flexible pipe
3, the second suction flexible pipe 4, multifunctional air pump 5, first flow controller 6, second flow controller the 7, first discharge flexible pipe 8 and
Two discharge flexible pipes 9, have deposited above-mentioned component A, have been used for depositing above-mentioned B component in described second barrel 2 in described first barrel 1,
Described first suction flexible pipe 3 is connected between the first barrel 1 and multifunctional air pump 5, and described second suction flexible pipe 4 is connected to second
Between barrel 2 and multifunctional air pump 5, described first discharge flexible pipe 8 and the second discharge flexible pipe 9 are connected to described multifunctional air pump 5,
Described first discharge flexible pipe 8 is provided with described first flow controller 6, described second discharge flexible pipe 9 is arranged
Stating second flow controller 7, described multifunctional air pump 5 is Pneumatic grouting pump, is carried out by driving multiple piston below air motor
Suction material, the component A in the first barrel 1 is drawn into the first discharge flexible pipe by the first suction flexible pipe 3 by described multifunctional air pump 5
In 8, by the volume flow of the component A in first flow controller 6 control and suck to the first discharge flexible pipe 8, described multi-functional
B component in second barrel 2 is drawn in the second discharge flexible pipe 9 by air pump 5 by the second suction flexible pipe 4, passes through second flow
Controller 7 control and suck is to the volume flow of the B component in the second discharge flexible pipe 9, thus the first discharge flexible pipe 8 and the second discharge
Flexible pipe 9 can export component A and B component respectively according to predetermined discharging ratio.Described biliquid injection hybrid gun includes first
Injection pipeline 10, second injects pipeline 13 and hybrid injection pipeline 16, described first injection pipeline 10 and the second injection pipeline 13
One end be jointly communicated in described hybrid injection pipeline 16, described biliquid injection hybrid gun is integrally formed into Y-shaped structure, in institute
State and on the first injection pipeline 10, be provided with the first check valve 11 and the first ball valve 12, inject described second and be provided with on pipeline 13
Second check valve 14 and the second ball valve 15, the discharging opening of described first discharge flexible pipe 8 is connected to described first injection pipeline 10
Pan feeding port, the discharging opening of described second discharge flexible pipe 9 is connected to the pan feeding port of described second injection pipeline 13, by first
Component A is provided to the first injection pipeline 10 by discharge flexible pipe 8, controls the first note by the first check valve 11 and the first ball valve 12
Penetrate the material conveying in pipeline 10, by the second discharge flexible pipe 9, B component is provided to the second injection pipeline 13, by second
Check valve 14 and the second ball valve 15 control in the second injection pipeline 13 material conveying, first injection pipeline 10 in component A and
B component in second injection pipeline 13 carries out uniform hybrid reaction in hybrid injection pipeline 16 and generates reinforcing serosity, and by mixing
Close injection pipeline 16 and be injected into reinforcing serosity in the Grouting Pipe 17 inserted in coal petrography crack, connected by Grouting Pipe 17 or its front end
The grouting tube connect is reinforced serosity the most at last and is injected in coal petrography crack.During work control first injection pipeline 10 in component A and
B component in second injection pipeline 13 enters in hybrid injection pipeline 16 according to the volume ratio of 1:1, finally by hybrid injection pipeline
Reinforcing slurry injection is filled into destination locations by 16.Described biliquid injection hybrid gun collection material conveying, stirring mixing and valve
Gate is formed on one, has safely, quickly and feature accurately, biliquid injection hybrid gun achieve the aperture of double-component serosity from
Dynamic proportioning mixing, serosity reaches the dual purpose of mixing and uniform stirring by hybrid gun.
The slip casting of the mining macromolecule reinforcement material that 2 explanations are carried out based on filing provision of the present invention below in conjunction with the accompanying drawings
Reinforcement means, grouting process determines according to geological conditions, site environment and slip casting purpose on the whole.Ratio is linked up for crack
Preferably coal and rock can use interval to jump hole grouting mode, reduces grout leaking, improves slip casting effect；Should adopt for wide area
Use first periphery, rear internal grouting sequence；Depth hole can be used to coordinate grouting mode for Fragmentation Coal Pillar integral reinforcing；For splitting
Gap comparative development, runs the slip casting carrier that grout liquor ratio is more serious, can use first superficial part slip casting, in the quick shape of superficial part after serosity diffusion
Become similar " wall for grouting " has the overall coal body only starching effect, then deep slip casting, it is ensured that deep grout mixing and slip casting
Pressure.As shown in Figure 2, concrete grouting and reinforcing operating process is divided into following 8 steps:
(1) position, hole design: for different coal seams, rock stratum or coal rock layer reinforcement criteria, appropriate design grouting parameter, including slip casting
The parameters such as Kong Wei, slip casting hole depth, azimuth, aperture, hole sealing depth；
(2) boring: boring need to be tried one's best and be carried out according to injected hole position design parameter, can directly use from boring for collapse hole critical regions
Formula syringe realizes boring and slip casting integration is carried out；
(3) syringe is installed: connect syringe and injection floral tube, and insert it in boring, then according to hole sealing depth peace
Dress hole packer, described syringe preferably uses seamless steel pipe, and specifications and models are preferably Φ 25 × 3.5 × 1000mm, described
Injection floral tube is connected to the front end of syringe, and sidewall is formed with some through holes, is used for exporting reinforcing serosity, described injection floral tube
Specifications and models are preferably Φ 25 × 3.5 × 1000mm, described syringe and injection floral tube and will be left in coal body after slip casting
In improve maintenance effects in reinforcement mode.And for ensureing preferably to control effect in slip casting implementation process, preferably can adopt
With novel anchor rod support pattern hollow grouting anchor, under grouting mode, carry out total length anchor pouring reinforcement.
(4) connect equipment air-supply pipeline and filing provision: concrete by the double-component chemical grouting pump in filing provision and
Biliquid injection hybrid gun is attached according to the scheme shown in accompanying drawing 1, and biliquid is injected the hybrid injection pipeline 16 of hybrid gun
Outfan be connected to the entrance of the syringe that step (3) is arranged, carry out grouting pipeline mud jacking test after having connected, to check
With determine the validity and reliability of filing provision and pipeline, and in mud jacking is tested, observe A, the mixed proportion of B component, it is ensured that
Slip casting effect.
(5) start filing provision and start slip casting: need to be adjusted in time according to slip casting principle during slip casting, close observation
The coal and rock change of slip casting region, occurs that material leakage, grout leaking phenomenon to process in time；
(6) reach to stop to stop after note requires slip casting: generally according to grouting pressure, grouting amount and return slurry situation scene determine stop note time
Machine；
(7) hole slip casting is changed: change injected hole position, then repeat step (3)-(6) and carry out changing hole slip casting.It should be noted that and change hole
Slip casting needs in time, and needs slightly to pump a little single slurry before extracting biliquid injection hybrid gun and rinse its hybrid injection pipeline and prevent from blocking up
Plug；
(8) slip casting is complete, cleans all devices (including double-component chemical grouting pump and biliquid injection hybrid gun) and adnexa, at note
Starch the complete abluent preparing abundance before, illustrate to carry out equipment cleaning according to filing provision and materials'use.
(9) wind regime site clearing are closed.
The present invention has innovated a kind of mining macromolecule reinforcement material being made up of two kinds of components of A, B, has innovated filling simultaneously
Equipment, injects loose or broken coal gap body after being mixed by fixed mixing ratio by two kinds of component materials of A, B by special filing provision
In crack, reinforce serosity quick solidification in coal gap body crack, reached good consolidation effect, reinforcement material of the present invention
And ruggedized equipment can be used in reinforcing, and serious inbreak is loose and fractured coal and rock, reinforced roadway and getting working face, advance reinforcement
Tomography, crushed zone and caving ground, reinforcing crossdrift are taken off matchmaker, are removed frame passage and bog-head coal post, and can construct dash within the specific limits
Wall, the extent of spreading amd application is wide.
Below it is only that the preferred embodiment of the present invention is described, technical scheme is not limited to
This, any known deformation that those skilled in the art are made on the basis of the major technique of the present invention is conceived broadly falls into the present invention
Claimed technology category, the protection domain that the present invention is concrete is as the criterion with the record of claims.
Claims (10)
1. a mining macromolecule reinforcement material, it is characterised in that including component A and B component, wherein component A presses percent mass
Following material composition is included: polyether polyol 75-85%, fire retardant 12-20%, catalyst 2-3.5%, organotin 0.1-than content
0.8%, isooctyl acid potassium 0.2-1% and silicone oil 0.5-1%；Wherein B component content by mass percentage includes following material composition: different
Cyanate 85-92% and fire retardant 8-15%；Component A and B component are formed according to volume ratio 1:1 hybrid reaction and reinforce serosity simultaneously.
Mining macromolecule reinforcement material the most according to claim 1, it is characterised in that wherein component A is by mass percentage
Content includes following material composition: polyether polyol 80%, fire retardant 16%, catalyst 2.2%, organotin 0.5%, isooctyl acid potassium
0.6% and silicone oil 0.7%；Wherein B component content by mass percentage includes following material composition: isocyanates 90% and fire retardant
10%。
Mining macromolecule reinforcement material the most according to claim 1 and 2, it is characterised in that wherein described poly-in component A
Ethoxylated polyhydric alcohol uses MN-500 type polyether polyol, and described catalyst uses dibutyl phthalate or phthalic acid two pungent
Ester, described silicone oil uses CGYM-1 type silicone oil.
Mining macromolecule reinforcement material the most according to claim 3, it is characterised in that the fire retardant in component A and B component
For tricresyl phosphate (2-chloropropyl) ester.
Mining macromolecule reinforcement material the most according to claim 3, it is characterised in that the fire retardant in component A and B component
It is in the polypropylene of 11-15g/10min, mass percentage content by the melt index that mass percentage content is 65%-70%
For 5%-8% melt index the polyethylene of 1.8-2.0g/10min, mass percentage content be 15%-20% selected from powder
At least one inorganic filler in powder Talcum, kaolinite, sericite, silicon dioxide and kieselguhr and mass percentage content
For 5%-8% selected from decabrominated dipheny base ether, ten dichloro ten dihydro dimethano benzene azoles cyclo-octene or the organic fire-resistings of its mixture
Halogenide is mixed to prepare.
6. according to the mining macromolecule reinforcement material described in any one of claim 1-5, it is characterised in that the wherein slurry of component A
Liquid-tight degree is 1.010～1.040 g/cm3, the initial viscosity of component A is 130～260mPa s, and the serum density of B component is
1.220～1.240 g/cm3, the initial viscosity of B component is 240～359mPa s, component A and the highest response of B component mixing
Temperature is less than 140 DEG C, and the response time of component A and B component is less than 120 seconds, the reinforcing that component A and B component hybrid reaction are formed
The comprcssive strength of serosity is more than more than 15MPa, adhesion strength more than 15MPa, shearing strength more than 40MPa, tensile strength
3.0Mpa。
7. one kind is exclusively used in the filing provision of mining macromolecule reinforcement material described in any one of claim 1-6, it is characterised in that
Including a double-component chemical grouting pump and a biliquid injection hybrid gun, described double-component chemical grouting pump is by component A and B group
Part is injected in described biliquid injection hybrid gun according to predetermined mixed proportion pumping, and described biliquid injection hybrid gun realizes A group
Part and the hybrid reaction of B component, and the reinforcing serosity obtained after hybrid reaction is filled into destination locations.
Filing provision the most according to claim 7, it is characterised in that described double-component chemical grouting pump includes the first barrel
(1), the second barrel (2), the first suction flexible pipe (3), the second suction flexible pipe (4), multifunctional air pump (5), first flow controller
(6), second flow controller (7), the first discharge flexible pipe (8) and the second discharge flexible pipe (9), described first barrel (1) is used for depositing
Putting described component A, described second barrel (2) is used for depositing described B component, and described first suction flexible pipe (3) is connected to the first material
Between cylinder (1) and multifunctional air pump (5), described second suction flexible pipe (4) is connected to the second barrel (2) and multifunctional air pump (5)
Between, described first discharge flexible pipe (8) and the second discharge flexible pipe (9) are connected to described multifunctional air pump (5), at described first row
It is provided with described first flow controller (6) on material flexible pipe (8), described second discharge flexible pipe (9) is provided with described second
Flow controller (7), the component A in the first barrel (1) is aspirated by described multifunctional air pump (5) by the first suction flexible pipe (3)
In the first discharge flexible pipe (8), by the component A in first flow controller (6) control and suck to the first discharge flexible pipe (8)
Volume flow, the B component in the second barrel (2) is drawn into second by the second suction flexible pipe (4) by described multifunctional air pump (5)
In discharge flexible pipe (9), by the volume flow of the B component in second flow controller (7) control and suck to the second discharge flexible pipe (9)
Amount；Described biliquid injection hybrid gun includes the first injection pipeline (10), the second injection pipeline (13) and hybrid injection pipeline (16),
The discharge end of described first injection pipeline (10) and the second injection pipeline (13) is communicated in described hybrid injection pipeline (16) jointly,
Described biliquid injection hybrid gun is integrally formed into Y-shaped structure, described first injection pipeline (10) and the second injection pipeline (13)
On be provided with valve, the discharging opening of described first discharge flexible pipe (8) be connected to described first injection pipeline (10) charging aperture,
The discharging opening of described second discharge flexible pipe (9) is connected to the charging aperture of described second injection pipeline (13), is injected into described first
Component A and the B component being injected in the second injection pipeline (13) in injection pipeline (10) are entered in hybrid injection pipeline (16)
The uniform hybrid reaction of row generates reinforces serosity, and reinforcing serosity is filled into destination locations by blended injection pipeline (16).
9. a reinforcement means, it is characterised in that use the filing provision described in claim 7 or 8 that claim 1-6 is arbitrary
Mining macromolecule reinforcement material described in Xiang fills to coal seam, rock stratum or coal rock layer crack.
Reinforcement means the most according to claim 9, it is characterised in that specifically include following steps:
Step one, carry out the design of position, hole, determine the design including injected hole position, slip casting hole depth, slip casting aperture, hole sealing depth
Parameter；
Step 2, position, the hole parameter determined according to step one, hole；
Step 3, selection one boring insert syringe and injection floral tube, and install hole packer, described injection according to hole sealing depth
Floral tube is connected to syringe front end；
Step 4, air-supply pipeline and the filing provision described in claim 7 or 8 are installed, first carry out double-component in filing provision
The installation learning grouting pump and biliquid injection hybrid gun connects, and then biliquid is injected the discharging of hybrid injection pipeline in hybrid gun
Mouth is connected in step 3 the charging aperture of the syringe arranged, and finally carries out pressure-drop in pipeline test；
Step 5, startup filing provision start slip casting, will reinforce serosity and inject inside coal seam, rock stratum or coal rock layer；
Step 6, reach to stop to stop slip casting after note requires；
Step 7, select another hole repeated execution of steps three to step 6, carry out changing hole slip casting；
Step 8, after the slip casting of porose position completes, clean all devices.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610662058.1A CN106243307A (en) | 2016-08-14 | 2016-08-14 | A kind of mining macromolecule reinforcement material, filing provision and reinforcement means |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610662058.1A CN106243307A (en) | 2016-08-14 | 2016-08-14 | A kind of mining macromolecule reinforcement material, filing provision and reinforcement means |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN106243307A true CN106243307A (en) | 2016-12-21 |
Family
ID=57593426
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201610662058.1A Pending CN106243307A (en) | 2016-08-14 | 2016-08-14 | A kind of mining macromolecule reinforcement material, filing provision and reinforcement means |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN106243307A (en) |
Cited By (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107597462A (en) * | 2017-09-30 | 2018-01-19 | 京华派克邯郸机械科技有限公司 | A kind of foamed glue uses technique |
| CN109139045A (en) * | 2018-08-14 | 2019-01-04 | 山东科技大学 | Two-component for supporting coal mine down-hole tunnel mixes gunite material and its refractory gunning equipment and method |
| CN110374057A (en) * | 2019-06-29 | 2019-10-25 | 郑州大学 | A kind of big depth percolating water quick blocking slip casting spray head of dykes and dams and grouting method |
| CN111271083A (en) * | 2019-04-27 | 2020-06-12 | 石家庄国盛矿业科技有限公司 | Construction process for treating coal roadway roof area by using high-molecular grouting material |
| CN112664246A (en) * | 2020-12-19 | 2021-04-16 | 山东新升实业发展有限责任公司 | Rock anchor rod for advance support and construction method |
| CN113482664A (en) * | 2021-08-17 | 2021-10-08 | 华能铜川照金煤电有限公司西川煤矿分公司 | Pressure concentration area surrounding rock grouting reinforcement method |
| CN114805728A (en) * | 2022-05-05 | 2022-07-29 | 徐州市洛克尔化工科技有限公司 | Polymer chemical coal rock mass reinforcing agent for coal mine and injection method thereof |
| CN115558079A (en) * | 2022-10-17 | 2023-01-03 | 山西浩博瑞新材料有限公司 | Material for coal mine reinforcing coal rock mass and preparation device |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103408721A (en) * | 2013-08-26 | 2013-11-27 | 大同煤矿集团有限责任公司 | High polymer chemistry coal and rock mass reinforcer for coal mines |
| CN104193949A (en) * | 2014-07-30 | 2014-12-10 | 苏州市雄林新材料科技有限公司 | Nano-antibacterial TPU (Thermoplastic Polyurethane) material and preparation method thereof |
-
2016
- 2016-08-14 CN CN201610662058.1A patent/CN106243307A/en active Pending
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103408721A (en) * | 2013-08-26 | 2013-11-27 | 大同煤矿集团有限责任公司 | High polymer chemistry coal and rock mass reinforcer for coal mines |
| CN104193949A (en) * | 2014-07-30 | 2014-12-10 | 苏州市雄林新材料科技有限公司 | Nano-antibacterial TPU (Thermoplastic Polyurethane) material and preparation method thereof |
Non-Patent Citations (3)
| Title |
|---|
| 于少峰等: "破碎矿体中化学注浆扩散规律研究及应用", 《岩石力学与工程学报》 * |
| 刘益军: "《聚氨酯原料及助剂手册》", 30 April 2005, 化学工业出版社 * |
| 景剑峰: "固安特注浆技术在加固综采工作面顶板中的应用", 《煤矿支护》 * |
Cited By (12)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107597462A (en) * | 2017-09-30 | 2018-01-19 | 京华派克邯郸机械科技有限公司 | A kind of foamed glue uses technique |
| CN109139045A (en) * | 2018-08-14 | 2019-01-04 | 山东科技大学 | Two-component for supporting coal mine down-hole tunnel mixes gunite material and its refractory gunning equipment and method |
| CN111271083A (en) * | 2019-04-27 | 2020-06-12 | 石家庄国盛矿业科技有限公司 | Construction process for treating coal roadway roof area by using high-molecular grouting material |
| CN111271083B (en) * | 2019-04-27 | 2021-04-06 | 石家庄国盛矿业科技有限公司 | Construction process for treating coal roadway roof area by using high-molecular grouting material |
| CN110374057A (en) * | 2019-06-29 | 2019-10-25 | 郑州大学 | A kind of big depth percolating water quick blocking slip casting spray head of dykes and dams and grouting method |
| CN110374057B (en) * | 2019-06-29 | 2024-03-19 | 郑州大学 | Quick plugging grouting nozzle for large-depth water leakage of dam and grouting method |
| CN112664246A (en) * | 2020-12-19 | 2021-04-16 | 山东新升实业发展有限责任公司 | Rock anchor rod for advance support and construction method |
| CN112664246B (en) * | 2020-12-19 | 2022-07-08 | 山东新升实业发展有限责任公司 | Rock anchor rod for advance support and construction method |
| CN113482664A (en) * | 2021-08-17 | 2021-10-08 | 华能铜川照金煤电有限公司西川煤矿分公司 | Pressure concentration area surrounding rock grouting reinforcement method |
| CN114805728A (en) * | 2022-05-05 | 2022-07-29 | 徐州市洛克尔化工科技有限公司 | Polymer chemical coal rock mass reinforcing agent for coal mine and injection method thereof |
| CN114805728B (en) * | 2022-05-05 | 2023-09-15 | 徐州市洛克尔化工科技有限公司 | Polymer chemical coal-rock mass reinforcing agent for coal mine and injection method thereof |
| CN115558079A (en) * | 2022-10-17 | 2023-01-03 | 山西浩博瑞新材料有限公司 | Material for coal mine reinforcing coal rock mass and preparation device |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN106243307A (en) | A kind of mining macromolecule reinforcement material, filing provision and reinforcement means | |
| CN102287198B (en) | Construction method for river-crossing shield tunnel crushed stratum communication channel | |
| CN110374606B (en) | Advanced grouting pressure maintaining construction method for broken seabed stratum of slurry shield | |
| CN101260672B (en) | Weak surface rock slope grouting method and anchor tube for grouting | |
| CN105041325A (en) | Construction method of high-tension water-rich extra-large-section weak breccia tunnel | |
| CN108240234A (en) | A kind of Along Railway underlies coal mine gob Grouting method | |
| CN106050185B (en) | A kind of coal mining bottom plate meets the control method that tomography produces water inrush channel | |
| CN105155541B (en) | A kind of dual slurry closure construction method of catch pit | |
| CN105178285B (en) | A kind of method for expanding ground grouting and reinforcing and antiseepage extent of congestion | |
| KR101907141B1 (en) | Sealing composition for umbrella arch method and process for preparing the same | |
| US10227746B2 (en) | Method of limiting permeability of a matrix to limit liquid and gas inflow | |
| CN103291354B (en) | Filling and reinforcing method for floor roadway cross-layer pressure-relief borehole | |
| CN202023532U (en) | Hole packer for reinforcing for grouting in coal mine | |
| CN104176976A (en) | Antifriction slurry for rectangular jacking pipe with large section, preparation method of antifriction slurry and grouting construction method | |
| CN108129943A (en) | A kind of the composite spraying material and framework and implementation of the filling of underground fast blockage | |
| CN104863166B (en) | Reinforcing emergency work construction method after the landslide of soil-slope landslide | |
| Martinelli et al. | Conditioning of fractured rock masses for the excavation with EPB shields | |
| CN106351661A (en) | Pre-supporting technology used in tunnel engineering construction | |
| CN205591226U (en) | String of beads formula karst bubble mixes pump sending of light material and fills structure | |
| Yokota et al. | Verification of reinforcing effects of a tunnel face reinforcement method by centrifuge model tests and numerical analysis | |
| CN205532693U (en) | Rock cross -cut coal uncovering section coal body subtracts dirt reinforced structure | |
| CN109137883A (en) | Goaf perfusion loess consolidating agent prevents spontaneous combustion system and its grouting method | |
| Northcroft | Innovative materials and methods for ground support, consolidation and water sealing for the mining industry | |
| Bezuijen et al. | Mechanisms that determine between fracture and compaction grouting in sand | |
| Asakura et al. | Development of new grouting material for tunnel rehabilitation |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| RJ01 | Rejection of invention patent application after publication |
Application publication date: 20161221 |
|
| RJ01 | Rejection of invention patent application after publication |