CN106242440A - High intensity pervious concrete and preparation method thereof - Google Patents
High intensity pervious concrete and preparation method thereof Download PDFInfo
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- CN106242440A CN106242440A CN201610791903.5A CN201610791903A CN106242440A CN 106242440 A CN106242440 A CN 106242440A CN 201610791903 A CN201610791903 A CN 201610791903A CN 106242440 A CN106242440 A CN 106242440A
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- China
- Prior art keywords
- high intensity
- pervious concrete
- naphthalene sulfonate
- sodium naphthalene
- intensity pervious
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Classifications
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- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B28/00—Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements
- C04B28/02—Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements containing hydraulic cements other than calcium sulfates
- C04B28/04—Portland cements
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2111/00—Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
- C04B2111/00241—Physical properties of the materials not provided for elsewhere in C04B2111/00
- C04B2111/00284—Materials permeable to liquids
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2111/00—Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
- C04B2111/00474—Uses not provided for elsewhere in C04B2111/00
- C04B2111/0075—Uses not provided for elsewhere in C04B2111/00 for road construction
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2111/00—Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
- C04B2111/20—Resistance against chemical, physical or biological attack
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2201/00—Mortars, concrete or artificial stone characterised by specific physical values
- C04B2201/50—Mortars, concrete or artificial stone characterised by specific physical values for the mechanical strength
- C04B2201/52—High compression strength concretes, i.e. with a compression strength higher than about 55 N/mm2, e.g. reactive powder concrete [RPC]
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- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Ceramic Engineering (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Inorganic Chemistry (AREA)
- Materials Engineering (AREA)
- Structural Engineering (AREA)
- Organic Chemistry (AREA)
- Curing Cements, Concrete, And Artificial Stone (AREA)
- Soil Conditioners And Soil-Stabilizing Materials (AREA)
Abstract
The invention discloses a kind of high intensity pervious concrete and preparation method thereof, described high intensity pervious concrete is prepared from by the raw material of following weight parts: cement 95 105 parts, basaltic broken stone 440 540 parts, styrene-butadiene latex 1 10 parts, water reducer 1 10 parts, nanocomposite filler 10 30 parts, 28 38 parts of water.The high intensity pervious concrete that the present invention provides, by rational proportioning, preferably go out the water reducer of applicable high intensity pervious concrete, nanocomposite filler kind and consumption, this pervious concrete has comprcssive strength and the coefficient of permeability of excellence, disclosure satisfy that various requirement of engineering concrete being had to permeable requirement, beneficially maintaining ecological balance and realize sustainable development.
Description
Technical field
The present invention relates to technical field of concrete, particularly relate to a kind of high intensity pervious concrete and preparation method thereof.
Background technology
In Process of Urbanization Construction, the earth's surface of modern city is progressively covered by the hardening of the material water-proof material such as building and concrete
Lid, defines " the artificial desert " on ecology, means of transportation easily, lays smooth road and bringing to the trip of people
The most simultaneously, these fluid-tight road surfaces bring negative effect greatly also to the ecological environment in city.First, tradition
Ground pavement it is emphasised that the sturdy and durable and usability on ground, but the impermeability of this kind of paving by valuable from
So precipitation completely with lower soil and subsoil water blocking-up, precipitation major part enters rivers,lakes and seas etc. by sewerage system pipe network
In earth surface water source, the excess extraction of urban groundwater, causes Urban Underground water level more and more lower, defines geologically in addition
" funnel type " level of ground water, causes ground to decline, and coastal area also results in inwelling, and this has just had a strong impact on having of rainwater
Effect utilize, during the most waterproof ground pavement rainfall rainwater be first pass through ground drainage grade or ground show that ditch enters lower water
Road, rainwater could enter Urban Underground drainage system through the rainwash of relatively long distance before entering sewer.This process
The rainwater making initial relative clean dissolves in substantial amounts of urban surface pollutant, the secondary pollution produced in this runoff process, logical
Cross sewerage system and enter peripheral ground natural water, increased the weight of the pollution level of natural water, have impact on urban surface and plant
The growth of thing, destroys urban surface ecological balance;Secondly the ground pavement of this surface compact is unfavorable for alleviating making an uproar of city
Sound pollutes, the noise mainly produced from road traffic;The rainy day due to can not draining in time, cause surface gathered water, make rain
It driving produces the phenomenons such as " drift is sliding ", " splashing ", " Night Glare ", travels to pedestrian's trip and vehicle and makes troubles;Additionally this
Kind is fluid-tight mats formation and the common effect of surrounding cities building, can increase city " tropical island effect ";Also have due to its color
Gloomy, lack anger, modern city is also referred to as " heat island of Lycoperdon polymorphum Vitt ".
Need now one can meet pavement performance, simultaneously again can be comfortable for people's class formation with natural environment coordinated growth
The paving material of living environment.Permeable concrete is a kind of environmental environment-friendly concrete.It is a kind of through special work
What skill was made has the concrete of continuous gap.Its existing certain intensity, has again certain ventilative water permeability, can be fine
Alleviate the waterproof impact that environment is caused of mating formation.
Pervious concrete is also known as celluar concrete, non-fine concrete, permeable terrace.It is by aggregate, cement and water mixing
A kind of porous light concrete become, it does not contains fine aggregate, coarse aggregate Surface coating a thin layer cement mortar mutually bonds and shape
Become the equally distributed alveolate texture in hole, therefore there is ventilative, permeable and lightweight feature.
Pervious concrete by American-European, Japan and other countries for the defect on the road surface of former urban road, the one of application
Rainwater can be allowed to flow into underground, effective recharge of groundwater, alleviate some urban environments of the level of ground water drastically decline etc. in city
Problem.And the harm of the environmental pollutions such as ground oil compounds can be effectively eliminated;Meanwhile, it is protection subsoil water, dimension
Protect ecological balance, the excellent pavement material of urban heat land effect can be alleviated;It is conducive to the benign development of environment for human survival
And in the work such as urban rainwater management and water prevention and cure of pollution, there is special significance.
Pervious concrete system has series colour formula, and the intention of matching design, for varying environment and individual demand
Decorated style carry out laying construction.This is that tradition is mated formation and the irrealizable special pavement material of general water-permeable brick.
Pervious concrete begins to research and application in the U.S. from the 1970s and 1980s in last century, and many countries are all in a large number
Promote, as the road reformation of 90% to be become pervious concrete by Germany's expection in a short time, change and destroy urban ecology in the past
Ground is laid, and makes pervious concrete pavement depend on to obtain social benefit widely.
Nano material is little due to size so that it is has special performance in terms of structure, physics and chemical property, is current
The focus of materialogy area research, is described as " century the most promising material " by scientists.The invention provides high intensity saturating
Water coagulation soil, has the physical and mechanical properties of excellence.
Summary of the invention
For above-mentioned deficiency present in prior art, the technical problem to be solved is to provide a kind of high intensity
Pervious concrete and preparation method thereof.
The present invention seeks to be achieved through the following technical solutions:
A kind of high intensity pervious concrete, is prepared from by the raw material of following weight parts: cement 95-105 part, basalt are broken
Stone 440-540 part, styrene-butadiene latex 1-10 part, water reducer 1-10 part, nanocomposite filler 10-30 part, water 28-38 part.
Preferably, described cement is P.O 42.5 cement.
Preferably, the particle diameter of described basaltic broken stone is 2.2-4.8mm.
Preferably, the total solid substance of described styrene-butadiene latex is 44-54wt%, and vitrification point is 2-12 DEG C.
Preferably, described water reducer be three (1-Methylethyl) sodium naphthalene sulfonate, 6-hydroxyl-2-sodium naphthalene sulfonate, 2,6-bis-
The mixture of one or more in t-butyl naphthalin sodium sulfonate.
It is highly preferred that described water reducer by three (1-Methylethyl) sodium naphthalene sulfonate, 6-hydroxyl-2-sodium naphthalene sulfonate, 2,6-
Di-t-butyl sodium naphthalene sulfonate mixes, described three (1-Methylethyl) sodium naphthalene sulfonate, 6-hydroxyl-2-sodium naphthalene sulfonate, 2,6-bis-
The mass ratio of t-butyl naphthalin sodium sulfonate is (1-3): (1-3): (1-3).
Preferably, described nanocomposite filler is the mixture of one or more in titanium phosphate, Cupric wolframate., cupric oxalate.
It is highly preferred that described nanocomposite filler is mixed by titanium phosphate, Cupric wolframate., cupric oxalate, described titanium phosphate,
Cupric wolframate., the mass ratio of cupric oxalate are (1-3): (1-3): (1-3).
Present invention also offers the preparation method of above-mentioned high intensity pervious concrete: water reducer, styrene-butadiene latex are added water
In be uniformly mixed, obtain mixed liquor;Cement, basaltic broken stone, nanocomposite filler addition concrete mixer will be stirred
Mix mix homogeneously, be subsequently adding mixed liquor and continue to stir to mix homogeneously and get final product.
The high intensity pervious concrete that the present invention provides, by rational proportioning, preferably goes out the permeable coagulation of applicable high intensity
Water reducer, nanocomposite filler kind and the consumption of soil, this pervious concrete has comprcssive strength and coefficient of permeability, the energy of excellence
Enough meet various requirement of engineering concrete being had to permeable requirement, beneficially maintaining ecological balance and realize sustainable development.
Detailed description of the invention
Below in conjunction with embodiment, the present invention is described further, the following stated, is only the preferable enforcement to the present invention
Example, not does the restriction of other forms to the present invention, and any those skilled in the art are possibly also with the disclosure above
Technology contents be changed to the Equivalent embodiments that changes on an equal basis.Every without departing from the present invention program content, according to the present invention
Technical spirit any simple modification that following example are done or equivalent variations, all fall within protection scope of the present invention.
Each raw material introduction in embodiment:
Three (1-Methylethyl) sodium naphthalene sulfonate, No. CAS: 1323-19-9.
6-hydroxyl-2-sodium naphthalene sulfonate, No. CAS: 135-76-2.
2,6-di-t-butyl sodium naphthalene sulfonates, No. CAS: 14992-59-7.
Titanium phosphate, No. CAS: 15578-51-5, particle diameter 30nm.
Cupric wolframate., also known as: oxidation tungsten copper, No. CAS: 13587-35-4, particle diameter 30nm.
Cupric oxalate, No. CAS: 814-91-5, particle diameter 30nm.
Cement, uses P.O 42.5 cement that Anhui Conch Cement limited company produces.
Basaltic broken stone, particle diameter is 3mm.
Styrene-butadiene latex, uses number of patent application: in 200610112833.2 prepared by the method for embodiment 1, and total solid substance is
48.8wt%, vitrification point is 7.2 DEG C.
Embodiment 1
High intensity pervious concrete raw material (weight portion): P.O 42.5 cement 100 parts, basaltic broken stone 500 parts, butadiene-styrene rubber
Breast 8 parts, water reducer 5.4 parts, nanocomposite filler 18 parts, 33 parts of water.
Described water reducer is by three (1-Methylethyl) sodium naphthalene sulfonate, 6-hydroxyl-2-sodium naphthalene sulfonate, 2,6-di-t-butyl naphthalin
Sodium sulfonate is uniformly mixed for 1:1:1 in mass ratio and obtains.
Described nanocomposite filler is uniformly mixed for 1:1:1 in mass ratio by titanium phosphate, Cupric wolframate., cupric oxalate
Arrive.
The preparation of high intensity pervious concrete: water reducer, styrene-butadiene latex are added to the water and are uniformly mixed, mixed
Liquid;P.O 42.5 cement, basaltic broken stone, nanocomposite filler addition concrete mixer will be uniformly mixed, then
Add mixed liquor to continue to stir to mix homogeneously and get final product.
Embodiment 2
Substantially the same manner as Example 1, differ only in: described water reducer by 6-hydroxyl-2-sodium naphthalene sulfonate, 2,6-bis-uncle
Sodium butylnaphthalenesulfonate is uniformly mixed for 1:1 in mass ratio and obtains.Obtain the high intensity pervious concrete of embodiment 2.
Embodiment 3
Substantially the same manner as Example 1, differ only in: described water reducer by three (1-Methylethyl) sodium naphthalene sulfonate, 2,
6-di-t-butyl sodium naphthalene sulfonate is uniformly mixed for 1:1 in mass ratio and obtains.Obtain the permeable coagulation of high intensity of embodiment 3
Soil.
Embodiment 4
Substantially the same manner as Example 1, differ only in: described water reducer is by three (1-Methylethyl) sodium naphthalene sulfonate, 6-
Hydroxyl-2-sodium naphthalene sulfonate is uniformly mixed for 1:1 in mass ratio and obtains.Obtain the high intensity pervious concrete of embodiment 4.
Embodiment 5
Substantially the same manner as Example 1, differ only in: described nanocomposite filler by Cupric wolframate., cupric oxalate by quality
Obtain than being uniformly mixed for 1:1.Obtain the high intensity pervious concrete of embodiment 5.
Embodiment 6
Substantially the same manner as Example 1, differ only in: described nanocomposite filler by titanium phosphate, cupric oxalate by quality
Obtain than being uniformly mixed for 1:1.Obtain the high intensity pervious concrete of embodiment 6.
Embodiment 7
Substantially the same manner as Example 1, differ only in: described nanocomposite filler by titanium phosphate, Cupric wolframate. by quality
Obtain than being uniformly mixed for 1:1.Obtain the high intensity pervious concrete of embodiment 7.
Test case 1
High intensity pervious concrete conventional index comprcssive strength that embodiment 1-7 is prepared, water penetration, resisting chloride ion penetration
Permeance property is tested.With reference to the clear Master's thesis of sweet ice, " match ratio of pervious concrete sets the test of comprcssive strength, water penetration
Meter and performance study " in 2.3 joint in method carry out;Chloride-penetration resistance testing method is with reference to master's opinion of Xu Qinglei
In literary composition " nano silicon is on the impact of cement-based material performance and Study on mechanism " 2.2.5 chloride-penetration resistance test into
OK, concrete test result is shown in Table 1.
Table 1: conventional index test result table
Comparing embodiment 1 and embodiment 2-4, embodiment 1 (three (1-Methylethyl) sodium naphthalene sulfonate, 6-hydroxyl-2-LOMAR PWA EINECS 246-676-2
Sodium, 2,6-di-t-butyl sodium naphthalene sulfonate are compounding) conventional index comprcssive strength, water penetration, Anti-Chloride Ion Penetration be substantially better than
Embodiment 2-4 is (in three (1-Methylethyl) sodium naphthalene sulfonate, 6-hydroxyl-2-sodium naphthalene sulfonate, 2,6-di-t-butyl sodium naphthalene sulfonate arbitrarily
The two is compounding).Comparing embodiment 1 and embodiment 5-7, embodiment 1 (titanium phosphate, Cupric wolframate., cupric oxalate are compounding) conventional index resists
Compressive Strength, water penetration, Anti-Chloride Ion Penetration are substantially better than embodiment 5-7 (in titanium phosphate, Cupric wolframate., cupric oxalate any two
Person compounds).
Claims (9)
1. a high intensity pervious concrete, it is characterised in that be prepared from by the raw material of following weight parts: cement 95-105
Part, basaltic broken stone 440-540 part, styrene-butadiene latex 1-10 part, water reducer 1-10 part, nanocomposite filler 10-30 part, water 28-
38 parts.
2. high intensity pervious concrete as claimed in claim 1, it is characterised in that: described cement is P.O 42.5 cement.
3. high intensity pervious concrete as claimed in claim 1, it is characterised in that: the particle diameter of described basaltic broken stone is
2.2-4.8mm。
4. high intensity pervious concrete as claimed in claim 1, it is characterised in that: the total solid substance of described styrene-butadiene latex is
44-54wt%, vitrification point is 2-12 DEG C.
5. high intensity pervious concrete as claimed in claim 1, it is characterised in that: described water reducer is three (1-methyl second
Base) sodium naphthalene sulfonate, 6-hydroxyl-2-sodium naphthalene sulfonate, the mixture of one or more in 2,6-di-t-butyl sodium naphthalene sulfonate.
6. high intensity pervious concrete as claimed in claim 5, it is characterised in that: described water reducer is by three (1-methyl second
Base) sodium naphthalene sulfonate, 6-hydroxyl-2-sodium naphthalene sulfonate, 2,6-di-t-butyl sodium naphthalene sulfonate mixes, described three (1-Methylethyls)
Sodium naphthalene sulfonate, 6-hydroxyl-2-sodium naphthalene sulfonate, the mass ratio of 2,6-di-t-butyl sodium naphthalene sulfonate are (1-3): (1-3): (1-3).
7. the high intensity pervious concrete as according to any one of claim 1-6, it is characterised in that: described nano combined fill out
Material is the mixture of one or more in titanium phosphate, Cupric wolframate., cupric oxalate.
8. high intensity pervious concrete as claimed in claim 7, it is characterised in that: described nanocomposite filler is by phosphoric acid
Titanium, Cupric wolframate., cupric oxalate mix, and described titanium phosphate, Cupric wolframate., the mass ratio of cupric oxalate are (1-3): (1-3): (1-3).
9. the preparation method of high intensity pervious concrete as according to any one of claim 1-8, it is characterised in that: by diminishing
Agent, styrene-butadiene latex are added to the water and are uniformly mixed, and obtain mixed liquor;Cement, basaltic broken stone, nanocomposite filler are added
Concrete mixer is uniformly mixed, is subsequently adding mixed liquor and continues to stir to mix homogeneously and get final product.
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Cited By (3)
Publication number | Priority date | Publication date | Assignee | Title |
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CN106892618A (en) * | 2017-03-17 | 2017-06-27 | 安宁鼎翔新材料科技有限公司 | A kind of high intensity pervious concrete and preparation method thereof |
CN108424091A (en) * | 2018-05-16 | 2018-08-21 | 合肥慧林建材有限公司 | A kind of high intensity pervious concrete and preparation method thereof |
CN110950610A (en) * | 2019-01-24 | 2020-04-03 | 邢台建工商品混凝土有限公司 | Sponge body pervious concrete and preparation method and application thereof |
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CN103601426A (en) * | 2013-11-11 | 2014-02-26 | 北京新奥混凝土集团有限公司 | C15 permeable concrete prepared by use of building waste and preparation method thereof |
CN104710135A (en) * | 2013-12-11 | 2015-06-17 | 河北建设集团有限公司 | Permeable concrete and preparation method thereof |
CN106220049A (en) * | 2016-07-08 | 2016-12-14 | 黄毅 | Nanometer strengthens permeable concrete |
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2016
- 2016-08-31 CN CN201610791903.5A patent/CN106242440A/en active Pending
Patent Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
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CN103601426A (en) * | 2013-11-11 | 2014-02-26 | 北京新奥混凝土集团有限公司 | C15 permeable concrete prepared by use of building waste and preparation method thereof |
CN104710135A (en) * | 2013-12-11 | 2015-06-17 | 河北建设集团有限公司 | Permeable concrete and preparation method thereof |
CN106220049A (en) * | 2016-07-08 | 2016-12-14 | 黄毅 | Nanometer strengthens permeable concrete |
Cited By (4)
Publication number | Priority date | Publication date | Assignee | Title |
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CN106892618A (en) * | 2017-03-17 | 2017-06-27 | 安宁鼎翔新材料科技有限公司 | A kind of high intensity pervious concrete and preparation method thereof |
CN106892618B (en) * | 2017-03-17 | 2019-07-23 | 安宁鼎翔新材料科技有限公司 | A kind of high intensity pervious concrete and preparation method thereof |
CN108424091A (en) * | 2018-05-16 | 2018-08-21 | 合肥慧林建材有限公司 | A kind of high intensity pervious concrete and preparation method thereof |
CN110950610A (en) * | 2019-01-24 | 2020-04-03 | 邢台建工商品混凝土有限公司 | Sponge body pervious concrete and preparation method and application thereof |
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