CN106223068A - A kind of production technology of TR spandex fabric woollen mixed blanket - Google Patents
A kind of production technology of TR spandex fabric woollen mixed blanket Download PDFInfo
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- CN106223068A CN106223068A CN201610664981.9A CN201610664981A CN106223068A CN 106223068 A CN106223068 A CN 106223068A CN 201610664981 A CN201610664981 A CN 201610664981A CN 106223068 A CN106223068 A CN 106223068A
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
- D06P1/38—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using reactive dyes
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06B—TREATING TEXTILE MATERIALS USING LIQUIDS, GASES OR VAPOURS
- D06B15/00—Removing liquids, gases or vapours from textile materials in association with treatment of the materials by liquids, gases or vapours
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06B—TREATING TEXTILE MATERIALS USING LIQUIDS, GASES OR VAPOURS
- D06B21/00—Successive treatments of textile materials by liquids, gases or vapours
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06B—TREATING TEXTILE MATERIALS USING LIQUIDS, GASES OR VAPOURS
- D06B3/00—Passing of textile materials through liquids, gases or vapours to effect treatment, e.g. washing, dyeing, bleaching, sizing, impregnating
- D06B3/10—Passing of textile materials through liquids, gases or vapours to effect treatment, e.g. washing, dyeing, bleaching, sizing, impregnating of fabrics
- D06B3/18—Passing of textile materials through liquids, gases or vapours to effect treatment, e.g. washing, dyeing, bleaching, sizing, impregnating of fabrics combined with squeezing, e.g. in padding machines
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
- D06P1/0032—Determining dye recipes and dyeing parameters; Colour matching or monitoring
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
- D06P1/16—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using dispersed, e.g. acetate, dyestuffs
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
- D06P1/44—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders
- D06P1/52—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders using compositions containing synthetic macromolecular substances
- D06P1/5207—Macromolecular compounds obtained by reactions involving only carbon-to-carbon unsaturated bonds
- D06P1/525—Polymers of unsaturated carboxylic acids or functional derivatives thereof
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- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
- D06P1/44—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders
- D06P1/52—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders using compositions containing synthetic macromolecular substances
- D06P1/5264—Macromolecular compounds obtained otherwise than by reactions involving only unsaturated carbon-to-carbon bonds
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
- D06P1/44—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders
- D06P1/673—Inorganic compounds
- D06P1/67333—Salts or hydroxides
- D06P1/67341—Salts or hydroxides of elements different from the alkaline or alkaline-earth metals or with anions containing those elements
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P3/00—Special processes of dyeing or printing textiles, or dyeing leather, furs, or solid macromolecular substances in any form, classified according to the material treated
- D06P3/82—Textiles which contain different kinds of fibres
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Abstract
The present invention relates to the production technology of a kind of TR spandex fabric woollen mixed blanket, including raw material, spinning, warp knit, cut, repair, starching setting, preshearing rolling, printing and dyeing, gas steaming, washing, tentering, check, open hair, napping, scald cut, cutting, raw material is TR spandex fabric composite material.The present invention is made that improvement for the dyeing in conventional woollen mixed blanket production, by to resistance to highly basic, resistance to high salinity disperse dyes and the screening of high temperature resistant reactive dye, coordinate special levelling agent and color fixing agent, optimize dyeing, realize the activity of T/R fabric, disperse dye one-bath dyeing, to improve dye utilization rate, the features such as present invention process high integration, production stay in grade, energy consumption are low, the TR spandex fabric product coloured light produced controls accurate, surface smoothness reduction energy consumption good, effective and disposal of pollutants.
Description
Technical field
The present invention relates to the production technology of a kind of fabric, particularly relate to a kind of coloured light control accurately, surface smoothness good, fall
Low industrial water and energy consumption, thus reduce the production technology of the TR spandex fabric woollen mixed blanket of production cost.
Background technology
With social development, consumer is for consumption quality and consumption diversification, and variation requires more and more higher, traditional sense
Upper cotton fiber can not meet this type of consumer demand, and therefore blend fibre is received by increasing consumers in general
With like, as the color-woven fabric that textile is medium-to-high grade, the operation involved due to it and finishing functions are more, therefore for face
The quality requirements of color and yarn is the highest.
Tradition spun polyester thread dyeing due to: production procedure is long, and labor intensity is relatively high, and dyeing quality is poor, and filoplume is more,
The problems such as color is forbidden, and layer difference is relatively big and the most poor and production efficiency are low, have therefore had influence on exploitation and the life of Yarn-dyed fabric
Produce.
In recent years, China's textile industry ecological circulation economic development contradiction, the particularly dependence to water resource
The environmental problem caused with maximum discharge seriously governs the sustainable development of the sector.Owing to traditional colouring method is with water for being situated between
Matter, washes with water after dyeing, and water consumption is big, and the chemicals of use is many, administers difficulty.
Summary of the invention
The invention aims to solve existing dyeing water consumption big, environmental pollution is more serious, color after dyeing
Defect that fastness is poor and provide a kind of coloured light to control accurately, surface smoothness good, reduce industrial water and energy consumption, thus drop
The production technology of the TR spandex fabric woollen mixed blanket of low production cost.
To achieve these goals, the present invention is by the following technical solutions:
A kind of production technology of TR spandex fabric woollen mixed blanket, including raw material, spinning, warp knit, cut, repair, starching setting, preshearing
Rolling, printing and dyeing, gas steaming, washing, tentering, check, open hair, napping, scald cut, cutting, raw material is TR spandex fabric composite material；Described
Dye formulation used by printing and dyeing is: reactive brilliant yellow K-6G 2.8-3.2g/L, disperse red SF-2G 2.8-3.9g/L, disperse brown 2BL
1.1-1.3g/L, TF-2 thickening agent 0.45-0.56g/L, levelling agent 0.12-0.25g/L and dyeing assistant 5-10g/L.
As preferably, described dyeing assistant is made up of the raw material of following weight portion: 20-30 part polymethacrylates, 30-
40 parts of polyaniline-modified nano indium oxides, 15-20 part amino silicone alkanes coupling agent, 1-5 part peregal 0,3-6 part organosilicons change
Property nano-cerium oxide and 120-150 part water.In the technical program, the addition of polyaniline-modified nano indium oxide can carry
High staining efficiency, improves dyestuff exhaustion rate in dyeing and degree of fixation, saves the usage amount of dyestuff；
As preferably, the preparation method of described polyaniline-modified nano indium oxide is: Indium sesquioxide. is dissolved in diethylene glycol and obtains
Reaction system, is then slowly added into sodium hydroxide, is warming up to 140-160 DEG C after stirring 1-3h in 2-2.5h, after reaction 1-3h
Cooling；The centrifugal precipitate obtained is successively with the ethanol of volume ratio 1:2 and methyl acetate mixed solution, acetone, deionization washing
Washing, vacuum drying obtains base core nano indium oxide；Then, by nano oxidized for base core chlorine ultrasonic disperse in dehydrated alcohol, addition contains
There is the ethanol solution of polyaniline, drip strong aqua ammonia, stirring reaction 1-1.5h, the precipitation being centrifugally separating to obtain at 85-95 DEG C
Thing with dehydrated alcohol, deionized water wash, is pulverized after roasting and is obtained polyaniline-coated nano indium oxide successively.
As preferably, the preparation method of organic-silicon-modified nano-cerium oxide is:
(1) by ceria nanoparticles, the dimethyl formamide solution of mass concentration 30-50% and acid solution according to 1g:25-
The solid-liquid ratio mixing of 30mL:10-12mL, controls stirring mixing 30-50min at temperature 120-135 DEG C, filters, respectively with water and
Absolute ethanol washing, is vacuum dried 30-60min and obtains primary modified oxidized cerium granule at 130-150 DEG C；
(2) primary modified nano cerium oxide granule is mixed according to the solid-liquid ratio of 1g:15-30mL with chemical shearing liquid, be heated to
120-150 DEG C, hydro-thermal reaction 30-45min, cooling, washing, obtain secondary modified nano cerium oxide granule；
(3) secondary modified nano cerium oxide granule and 3-(2,3-epoxy the third oxygen) propyl trimethoxy silicane are according to 1g:20-30g
Quality than mix homogeneously, be heated to 180-220 DEG C keep 3 hours, cooling, filter, washing, after vacuum drying modified Nano
Inorganic compound particle.
In the technical program, step (1) is by the dimethylformamide of ceria nanoparticles Yu mass concentration 30-50%
Solution and acid solution mixing, be aided with stirring, to expand the contact surface of nm inorganic compound granule and liquid so that nanometer simultaneously
Cerium oxide particle is uniformly dispersed, the dimethyl formamide solution of mass concentration 30-50% and the specific solvent assembly of acid solution
System, it is possible to make ceria nanoparticles to disperse evenly in system, is prevented effectively from ceria nanoparticles and reunites.
Ceria nanoparticles is first uniformly dispersed by step (1), the most beneficially the shearing of step (2), step (1) is disperseed
Uniform ceria nanoparticles and the present invention specific chemical shearing liquid hydro-thermal reaction, can effectively cut off nano-cerium oxide
Grain, it is thus achieved that the homogenization ceria nanoparticles of length more uniform (length is about at 100-150nm) left and right；Nano-cerium oxide
Grain is separated from each other and is come out by its surface high reaction activity, thus realizes selectively functionalized.It is similar with surfactant,
Have amphipathic, assist ceria nanoparticles dispersion, thus be greatly improved the color additive dispersed performance in dyestuff.
As preferably, described acid solution is that the concentrated sulphuric acid of concentrated nitric acid and the mass concentration 98% of mass concentration 70% is according to 1-
The mixture of the volume ratio of 2:1；Described chemical shearing liquid is sodium molybdate solution and concentration 0.3-of concentration 0.5-0.8moL/L
The silicomolybdic acid solution of 0.5moL/L is according to the mixture of the volume ratio of 1:1.
As preferably, the compound method of described dyeing assistant is: add polymethacrylates, ammonia in 50-60 part water
Base silane class coupling agent and peregal 0 add water and remaining component of surplus after stirring 30-45min, at the frequency of 55-75Khz
Ultrasonic vibration 15-30min under rate.
As preferably, dyeing and printing process is: stamp--pads and--dries--decatize+oil pressure (High Temperature High Pressure)--immersion--soap
Wash--washing----washing preliminary drying--drying of soaping；Technological parameter: pad: with printing machine speed sync, the rate of padding is
80%--85%, speed 10-12m/min；
Dry: temperature: 140-150 DEG C, speed 10-12m/min；
Decatize+oil pressure: temperature 120-130 DEG C, time light color 10-12m/min, dark: 15-20m/min, pressure 0.3-
0.5Mpa；Oil pump oil pressure 2-4Mpa；The normal 0.3-0.5Mpa of compressed air pressure；
Soak----washing--soaping--washing: speed 10-15m/min, pressure 0.4-0.5Mpa, temperature is respectively 40-of soaping
50 DEG C, 70-80 DEG C, 50-60 DEG C, the hairbrush rotating speed 350-400 that soaps turns/min；
Preliminary drying--dry: preliminary drying temperature 115-120 DEG C, dry 145-150 DEG C, speed 30-40m/min.
Beneficial effects of the present invention: the present invention is made that improvement for the dyeing in conventional woollen mixed blanket production,
By to resistance to highly basic, resistance to high salinity disperse dyes and the screening of high temperature resistant reactive dye, coordinate special levelling agent and color fixing agent,
Optimize dyeing, it is achieved the activity of T/R fabric, disperse dye one-bath dye, to improve dye utilization rate, present invention process
The features such as high integration, production stay in grade, energy consumption are low, the TR spandex fabric product coloured light produced controls accurately, surfacing
Spending, effectively reduce energy consumption and disposal of pollutants, thus reduce production cost, having good is field effect.
Detailed description of the invention
Technical scheme in the embodiment of the present invention will be carried out clear, complete description below, it is clear that described enforcement
Example is only a part of embodiment of the present invention rather than whole embodiments.Based on the embodiment in the present invention, this area is common
All other embodiments that technical staff is obtained under not making creative work premise, broadly fall into the model of present invention protection
Enclose.
In the present invention, agents useful for same is all commercially available.
The improvement that the present invention makes in the conventional production process of woollen mixed blanket.
Embodiment 1
A kind of production technology of TR spandex fabric woollen mixed blanket, including raw material, spinning, warp knit, cut, repair, starching setting, preshearing
Rolling, printing and dyeing, gas steaming, washing, tentering, check, open hair, napping, scald cut, cutting, raw material is TR spandex fabric composite material；Described
Dye formulation used by printing and dyeing is: reactive brilliant yellow K-6G 2.8g/L, disperse red SF-2G 2.8g/L, disperse brown 2BL 1.1g/L,
TF-2 thickening agent 0.45g/L, levelling agent 0.12g/L and dyeing assistant 5g/L.
Described dyeing assistant is made up of the raw material of following weight portion: 20 parts of polymethacrylates, 30 parts polyaniline-modified
Nano indium oxide, 15 parts of amino silicone alkanes coupling agents, 0,3 parts of organic-silicon-modified nano-cerium oxides of 1 part of peregal and 120 parts
Water.
The preparation method of described polyaniline-modified nano indium oxide is: Indium sesquioxide. is dissolved in diethylene glycol and obtains reactant
System, is then slowly added into sodium hydroxide, is warming up to 140 DEG C after stirring 1h in 2h, cool down after reaction 1h；The centrifugal precipitation obtained
Thing with the ethanol of volume ratio 1:2 and methyl acetate mixed solution, acetone, deionized water wash, is vacuum dried and obtains base core successively
Nano indium oxide；Then, by nano oxidized for base core chlorine ultrasonic disperse in dehydrated alcohol, the dehydrated alcohol containing polyaniline is added
Solution, drips strong aqua ammonia, and stirring reaction 1h at 85 DEG C, the precipitate being centrifugally separating to obtain is successively with dehydrated alcohol, deionized water
Washing, pulverizes after roasting and obtains polyaniline-coated nano indium oxide.
The preparation method of organic-silicon-modified nano-cerium oxide is:
(1) by ceria nanoparticles, the dimethyl formamide solution of mass concentration 30% and acid solution according to 1g:25mL:
The solid-liquid ratio mixing of 10mL, controls stirring mixing 30min at temperature 120 DEG C, filters, respectively with water and absolute ethanol washing, and 130
It is vacuum dried 30min at DEG C and obtains primary modified oxidized cerium granule；
(2) primary modified nano cerium oxide granule is mixed according to the solid-liquid ratio of 1g:15mL with chemical shearing liquid, be heated to 120
DEG C, hydro-thermal reaction 30min, cooling, washing, obtain secondary modified nano cerium oxide granule；
(3) secondary modified nano cerium oxide granule and 3-(2,3-epoxy the third oxygen) propyl trimethoxy silicane are according to the matter of 1g:20g
Measure ratio mix homogeneously, be heated to 180 DEG C and keep 3 hours, cooling, filter, washing, after vacuum drying, obtain modified Nano inorganic chemical
Composition granule.
Described acid solution is the concentrated nitric acid of mass concentration 70% with the concentrated sulphuric acid of mass concentration 98% according to the volume ratio of 1:1
Mixture；Described chemical shearing liquid be the sodium molybdate solution of concentration 0.5moL/L with the silicomolybdic acid solution of concentration 0.3moL/L by
Mixture according to the volume ratio of 1:1.
The compound method of described dyeing assistant is: add polymethacrylates, amino silicone alkanes coupling in 50 parts of water
Agent and peregal 0 add water and remaining component of surplus, ultrasonic vibration 15min under the frequency of 55Khz after stirring 30min.
Dyeing and printing process is: stamp--pads and--dries--decatize+oil pressure (High Temperature High Pressure)--immersion--soap--washing--
Soap--washing preliminary drying--dry；Technological parameter: pad: with printing machine speed sync, the rate of padding is 80%, speed 10m/
min；
Dry: temperature: 140 DEG C, speed 10m/min；
Decatize+oil pressure: temperature 120 DEG C, time light color 10m/min, dark: 15m/min, pressure 0.3Mpa；Oil pump oil pressure 2Mpa；
The normal 0.3Mpa of compressed air pressure；
Soak--soap--washing--soaping--washing: speed 10m/min, pressure 0.4Mpa, temperature be respectively 40 DEG C, 70 DEG C,
50 DEG C, soap 350 turns/min of hairbrush rotating speed；
Preliminary drying--dry: preliminary drying temperature 115 DEG C, dry 145 DEG C, speed 30m/min.
Embodiment 2
A kind of production technology of TR spandex fabric woollen mixed blanket, including raw material, spinning, warp knit, cut, repair, starching setting, preshearing
Rolling, printing and dyeing, gas steaming, washing, tentering, check, open hair, napping, scald cut, cutting, raw material is TR spandex fabric composite material；Described
Dye formulation used by printing and dyeing is: reactive brilliant yellow K-6G 3g/L, disperse red SF-2G 3.4g/L, disperse brown 2BL 1.2g/L,
TF-2 thickening agent 0.51g/L, levelling agent 0.18g/L and dyeing assistant 7g/L.
Described dyeing assistant is made up of the raw material of following weight portion: 25 parts of polymethacrylates, 35 parts polyaniline-modified
Nano indium oxide, 18 parts of amino silicone alkanes coupling agents, 0,4 parts of organic-silicon-modified nano-cerium oxides of 2 parts of peregals and 130 parts
Water.
The preparation method of described polyaniline-modified nano indium oxide is: Indium sesquioxide. is dissolved in diethylene glycol and obtains reactant
System, is then slowly added into sodium hydroxide, is warming up to 150 DEG C after stirring 2h in 2h, cool down after reaction 2h；The centrifugal precipitation obtained
Thing with the ethanol of volume ratio 1:2 and methyl acetate mixed solution, acetone, deionized water wash, is vacuum dried and obtains base core successively
Nano indium oxide；Then, by nano oxidized for base core chlorine ultrasonic disperse in dehydrated alcohol, the dehydrated alcohol containing polyaniline is added
Solution, drips strong aqua ammonia, and stirring reaction 1.5h at 90 DEG C, the precipitate being centrifugally separating to obtain is successively with dehydrated alcohol, deionization
Water washs, and pulverizes and obtain polyaniline-coated nano indium oxide after roasting.
The preparation method of organic-silicon-modified nano-cerium oxide is:
(1) by ceria nanoparticles, the dimethyl formamide solution of mass concentration 40% and acid solution according to 1g:28mL:
The solid-liquid ratio mixing of 11mL, controls stirring mixing 40min at temperature 130 DEG C, filters, respectively with water and absolute ethanol washing, and 140
It is vacuum dried 40min at DEG C and obtains primary modified oxidized cerium granule；
(2) primary modified nano cerium oxide granule is mixed according to the solid-liquid ratio of 1g:20mL with chemical shearing liquid, be heated to 130
DEG C, hydro-thermal reaction 40min, cooling, washing, obtain secondary modified nano cerium oxide granule；
(3) secondary modified nano cerium oxide granule and 3-(2,3-epoxy the third oxygen) propyl trimethoxy silicane are according to the matter of 1g:25g
Measure ratio mix homogeneously, be heated to 200 DEG C and keep 3 hours, cooling, filter, washing, after vacuum drying, obtain modified Nano inorganic chemical
Composition granule.
Described acid solution is the concentrated nitric acid of mass concentration 70% with the concentrated sulphuric acid of mass concentration 98% according to the volume of 1.5:1
The mixture of ratio；Described chemical shearing liquid is the sodium molybdate solution silicomolybdic acid solution with concentration 0.4moL/L of concentration 0.6moL/L
Mixture according to the volume ratio of 1:1.
The compound method of described dyeing assistant is: add polymethacrylates, amino silicone alkanes coupling in 55 parts of water
Agent and peregal 0 add water and remaining component of surplus, ultrasonic vibration 25min under the frequency of 60Khz after stirring 40min.
Dyeing and printing process is: stamp--pads and--dries--decatize+oil pressure (High Temperature High Pressure)--immersion--soap--washing--
Soap--washing preliminary drying--dry；Technological parameter: pad: with printing machine speed sync, the rate of padding is 82%, speed 11m/
min；
Dry: temperature: 145 DEG C, speed 11m/min；
Decatize+oil pressure: temperature 123 DEG C, time light color 11m/min, dark: 17m/min, pressure 0.4Mpa；Oil pump oil pressure 3Mpa；
The normal 0.4Mpa of compressed air pressure；
Soak--soap--washing--soaping--washing: speed 13m/min, pressure 0.45Mpa, temperature be respectively 45 DEG C, 73 DEG C,
54 DEG C, soap 380 turns/min of hairbrush rotating speed；
Preliminary drying--dry: preliminary drying temperature 118 DEG C, dry 147 DEG C, speed 33m/min.
Embodiment 3
A kind of production technology of TR spandex fabric woollen mixed blanket, including raw material, spinning, warp knit, cut, repair, starching setting, preshearing
Rolling, printing and dyeing, gas steaming, washing, tentering, check, open hair, napping, scald cut, cutting, raw material is TR spandex fabric composite material；Described
Dye formulation used by printing and dyeing is: reactive brilliant yellow K-6G 3.2g/L, disperse red SF-2G 3.9g/L, disperse brown 2BL 1.3g/L,
TF-2 thickening agent 0.56g/L, levelling agent 0.25g/L and dyeing assistant 10g/L.
Described dyeing assistant is made up of the raw material of following weight portion: 30 parts of polymethacrylates, 40 parts polyaniline-modified
Nano indium oxide, 20 parts of amino silicone alkanes coupling agents, 0,6 parts of organic-silicon-modified nano-cerium oxides of 5 parts of peregals and 150 parts
Water.
The preparation method of described polyaniline-modified nano indium oxide is: Indium sesquioxide. is dissolved in diethylene glycol and obtains reactant
System, is then slowly added into sodium hydroxide, is warming up to 160 DEG C after stirring 3h in 2.5h, cool down after reaction 3h；Centrifugal obtain heavy
Shallow lake thing with the ethanol of volume ratio 1:2 and methyl acetate mixed solution, acetone, deionized water wash, is vacuum dried and obtains base successively
Core nano indium oxide；Then, by nano oxidized for base core chlorine ultrasonic disperse in dehydrated alcohol, the anhydrous second containing polyaniline is added
Alcoholic solution, drip strong aqua ammonia, at 95 DEG C stirring reaction 1.5h, the precipitate being centrifugally separating to obtain successively with dehydrated alcohol, go from
Sub-water washs, and pulverizes and obtain polyaniline-coated nano indium oxide after roasting.
The preparation method of organic-silicon-modified nano-cerium oxide is:
(1) by ceria nanoparticles, the dimethyl formamide solution of mass concentration 50% and acid solution according to 1g:30mL:
The solid-liquid ratio mixing of 12mL, controls stirring mixing 50min at temperature 135 DEG C, filters, respectively with water and absolute ethanol washing, and 150
It is vacuum dried 60min at DEG C and obtains primary modified oxidized cerium granule；
(2) primary modified nano cerium oxide granule is mixed according to the solid-liquid ratio of 1g:30mL with chemical shearing liquid, be heated to 150
DEG C, hydro-thermal reaction 45min, cooling, washing, obtain secondary modified nano cerium oxide granule；
(3) secondary modified nano cerium oxide granule and 3-(2,3-epoxy the third oxygen) propyl trimethoxy silicane are according to the matter of 1g:30g
Measure ratio mix homogeneously, be heated to 220 DEG C and keep 3 hours, cooling, filter, washing, after vacuum drying, obtain modified Nano inorganic chemical
Composition granule.
Described acid solution is the concentrated nitric acid of mass concentration 70% with the concentrated sulphuric acid of mass concentration 98% according to the volume ratio of 2:1
Mixture；Described chemical shearing liquid be the sodium molybdate solution of concentration 0.8moL/L with the silicomolybdic acid solution of concentration 0.5moL/L by
Mixture according to the volume ratio of 1:1.
The compound method of described dyeing assistant is: add polymethacrylates, amino silicone alkanes coupling in 60 parts of water
Agent and peregal 0 add water and remaining component of surplus, ultrasonic vibration 30min under the frequency of 75Khz after stirring 45min.
Dyeing and printing process is: stamp--pads and--dries--decatize+oil pressure (High Temperature High Pressure)--immersion--soap--washing--
Soap--washing preliminary drying--dry；Technological parameter: pad: with printing machine speed sync, the rate of padding is 85%, speed 12m/
min；
Dry: temperature: 150 DEG C, speed 12m/min；
Decatize+oil pressure: temperature 130 DEG C, time light color 12m/min, dark: 20m/min, pressure 0.5Mpa；Oil pump oil pressure 4Mpa；
The normal 0.5Mpa of compressed air pressure；
Soak--soap--washing--soaping--washing: speed 15m/min, pressure 0.5Mpa, temperature be respectively 50 DEG C, 80 DEG C,
60 DEG C, soap 400 turns/min of hairbrush rotating speed；
Preliminary drying--dry: preliminary drying temperature 120 DEG C, dry 150 DEG C, speed 40m/min.
It should be appreciated that to those skilled in the art, can be improved according to the above description or be become
Change, and all these modifications and variations all should belong to the protection domain of claims of the present invention.
Claims (7)
1. a production technology for TR spandex fabric woollen mixed blanket, including raw material, spinning, warp knit, cut, repair, starching setting, pre-
Be cut into volume, printing and dyeing, gas steaming, washing, tentering, check, open hair, napping, scald cut, cutting, it is characterised in that raw material is TR spandex fabric
Composite material；Dye formulation used by described printing and dyeing is: reactive brilliant yellow K-6G 2.8-3.2g/L, disperse red SF-2G2.8-
3.9g/L, disperse brown 2BL 1.1-1.3g/L, TF-2 thickening agent 0.45-0.56g/L, levelling agent 0.12-0.25g/L help with dyeing
Agent 5-10g/L.
The production technology of a kind of TR spandex fabric woollen mixed blanket the most according to claim 1, it is characterised in that described dyeing helps
Agent is made up of the raw material of following weight portion: 20-30 part polymethacrylates, the nano indium oxide that 30-40 part is polyaniline-modified,
Nano-cerium oxide that 15-20 part amino silicone alkanes coupling agent, 1-5 part peregal 0,3-6 part are organic-silicon-modified and 120-150 part
Water.
The production technology of a kind of TR spandex fabric woollen mixed blanket the most according to claim 2, it is characterised in that described polyphenyl
The preparation method of the nano indium oxide that amine is modified is: Indium sesquioxide. is dissolved in diethylene glycol and obtains reaction system, be then slowly added into hydrogen
Sodium oxide, is warming up to 140-160 DEG C after stirring 1-3h in 2-2.5h, cools down after reaction 1-3h；The centrifugal precipitate obtained depends on
The ethanol of secondary volume ratio 1:2 and methyl acetate mixed solution, acetone, deionized water wash, vacuum drying obtains base core nanometer
Indium sesquioxide.；Then, by nano oxidized for base core chlorine ultrasonic disperse in dehydrated alcohol, the ethanol solution containing polyaniline is added,
Dropping strong aqua ammonia, stirring reaction 1-1.5h at 85-95 DEG C, the precipitate being centrifugally separating to obtain is successively with dehydrated alcohol, deionization
Water washs, and pulverizes and obtain polyaniline-coated nano indium oxide after roasting.
The production technology of a kind of TR spandex fabric woollen mixed blanket the most according to claim 2, it is characterised in that organic-silicon-modified
The preparation method of nano-cerium oxide be:
(1) by ceria nanoparticles, the dimethyl formamide solution of mass concentration 30-50% and acid solution according to 1g:25-
The solid-liquid ratio mixing of 30mL:10-12mL, controls stirring mixing 30-50min at temperature 120-135 DEG C, filters, respectively with water and
Absolute ethanol washing, is vacuum dried 30-60min and obtains primary modified oxidized cerium granule at 130-150 DEG C；
(2) primary modified nano cerium oxide granule is mixed according to the solid-liquid ratio of 1g:15-30mL with chemical shearing liquid, be heated to
120-150 DEG C, hydro-thermal reaction 30-45min, cooling, washing, obtain secondary modified nano cerium oxide granule；
(3) secondary modified nano cerium oxide granule and 3-(2,3-epoxy the third oxygen) propyl trimethoxy silicane are according to 1g:20-30g
Quality than mix homogeneously, be heated to 180-220 DEG C keep 3 hours, cooling, filter, washing, after vacuum drying modified Nano
Inorganic compound particle.
The production technology of a kind of TR spandex fabric woollen mixed blanket the most according to claim 4, it is characterised in that described acid solution
For the concentrated nitric acid of mass concentration 70% and the concentrated sulphuric acid of mass concentration 98% according to the mixture of the volume ratio of 1-2:1；Describedization
Learn and shear the silicomolybdic acid solution of sodium molybdate solution and concentration 0.3-0.5moL/L that liquid is concentration 0.5-0.8moL/L according to 1:1's
The mixture of volume ratio.
The production technology of a kind of TR spandex fabric woollen mixed blanket the most according to claim 2, it is characterised in that described dyeing helps
The compound method of agent is: add polymethacrylates in 50-60 part water, amino silicone alkanes coupling agent stirs with peregal 0
Water and remaining component of surplus, ultrasonic vibration 15-30min under the frequency of 55-75Khz is added after 30-45min.
The production technology of a kind of TR spandex fabric woollen mixed blanket the most according to claim 1 and 2, it is characterised in that printing and dyeing work
Skill is: stamp--pads and--dries that--decatize+oil pressure (High Temperature High Pressure)--soaks that--soaping,--washing--soaping--washing is pre-
Dry--dry；Technological parameter: pad: with printing machine speed sync, the rate of padding is 80%--85%, speed 10-12m/min；
Dry: temperature: 140-150 DEG C, speed 10-12m/min；
Decatize+oil pressure: temperature 120-130 DEG C, time light color 10-12m/min, dark: 15-20m/min, pressure 0.3-
0.5Mpa；Oil pump oil pressure 2-4Mpa；The normal 0.3-0.5Mpa of compressed air pressure；
Soak----washing--soaping--washing: speed 10-15m/min, pressure 0.4-0.5Mpa, temperature is respectively 40-of soaping
50 DEG C, 70-80 DEG C, 50-60 DEG C, the hairbrush rotating speed 350-400 that soaps turns/min；
Preliminary drying--dry: preliminary drying temperature 115-120 DEG C, dry 145-150 DEG C, speed 30-40m/min.
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Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN117431683A (en) * | 2023-12-20 | 2024-01-23 | 吴江市双盈化纺实业有限公司 | High-color-fastness wear-resistant four-side stretch fabric and production process thereof |
Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104828953A (en) * | 2015-04-14 | 2015-08-12 | 浙江海洋学院 | Water treatment agent and preparation method thereof |
| CN105078099A (en) * | 2015-08-27 | 2015-11-25 | 宿迁市神龙家纺有限公司 | Blended Raschel blanket technology |
| CN105155297A (en) * | 2015-08-25 | 2015-12-16 | 浙江繁盛超纤制品有限公司 | Method for preparation of waterborne polyurethane impregnated superfine fiber synthetic leather base |
| CN105198754A (en) * | 2015-09-15 | 2015-12-30 | 浙江希尔化工股份有限公司 | Method for preparing N,N-dimethyl-1,3-diaminopropane |
| CN105803828A (en) * | 2016-04-22 | 2016-07-27 | 浙江嘉欣丝绸股份有限公司 | Disperse/activated one-emulsion paste printing dye and printing technology thereof |
-
2016
- 2016-08-12 CN CN201610664981.9A patent/CN106223068B/en active Active
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104828953A (en) * | 2015-04-14 | 2015-08-12 | 浙江海洋学院 | Water treatment agent and preparation method thereof |
| CN105155297A (en) * | 2015-08-25 | 2015-12-16 | 浙江繁盛超纤制品有限公司 | Method for preparation of waterborne polyurethane impregnated superfine fiber synthetic leather base |
| CN105078099A (en) * | 2015-08-27 | 2015-11-25 | 宿迁市神龙家纺有限公司 | Blended Raschel blanket technology |
| CN105198754A (en) * | 2015-09-15 | 2015-12-30 | 浙江希尔化工股份有限公司 | Method for preparing N,N-dimethyl-1,3-diaminopropane |
| CN105803828A (en) * | 2016-04-22 | 2016-07-27 | 浙江嘉欣丝绸股份有限公司 | Disperse/activated one-emulsion paste printing dye and printing technology thereof |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN117431683A (en) * | 2023-12-20 | 2024-01-23 | 吴江市双盈化纺实业有限公司 | High-color-fastness wear-resistant four-side stretch fabric and production process thereof |
| CN117431683B (en) * | 2023-12-20 | 2024-03-12 | 吴江市双盈化纺实业有限公司 | High-color-fastness wear-resistant four-side stretch fabric and production process thereof |
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