CN106221807A - A kind of coke gasification produces the method and apparatus of coal gas - Google Patents
A kind of coke gasification produces the method and apparatus of coal gas Download PDFInfo
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- CN106221807A CN106221807A CN201610631554.0A CN201610631554A CN106221807A CN 106221807 A CN106221807 A CN 106221807A CN 201610631554 A CN201610631554 A CN 201610631554A CN 106221807 A CN106221807 A CN 106221807A
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
- C10J3/00—Production of combustible gases containing carbon monoxide from solid carbonaceous fuels
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
- C10J3/00—Production of combustible gases containing carbon monoxide from solid carbonaceous fuels
- C10J3/02—Fixed-bed gasification of lump fuel
- C10J3/20—Apparatus; Plants
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
- C10J3/00—Production of combustible gases containing carbon monoxide from solid carbonaceous fuels
- C10J3/72—Other features
- C10J3/74—Construction of shells or jackets
- C10J3/76—Water jackets; Steam boiler-jackets
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10K—PURIFYING OR MODIFYING THE CHEMICAL COMPOSITION OF COMBUSTIBLE GASES CONTAINING CARBON MONOXIDE
- C10K1/00—Purifying combustible gases containing carbon monoxide
- C10K1/02—Dust removal
- C10K1/026—Dust removal by centrifugal forces
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10K—PURIFYING OR MODIFYING THE CHEMICAL COMPOSITION OF COMBUSTIBLE GASES CONTAINING CARBON MONOXIDE
- C10K1/00—Purifying combustible gases containing carbon monoxide
- C10K1/04—Purifying combustible gases containing carbon monoxide by cooling to condense non-gaseous materials
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10K—PURIFYING OR MODIFYING THE CHEMICAL COMPOSITION OF COMBUSTIBLE GASES CONTAINING CARBON MONOXIDE
- C10K1/00—Purifying combustible gases containing carbon monoxide
- C10K1/04—Purifying combustible gases containing carbon monoxide by cooling to condense non-gaseous materials
- C10K1/046—Reducing the tar content
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
- C10J2300/00—Details of gasification processes
- C10J2300/09—Details of the feed, e.g. feeding of spent catalyst, inert gas or halogens
- C10J2300/0913—Carbonaceous raw material
- C10J2300/093—Coal
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
- C10J2300/00—Details of gasification processes
- C10J2300/09—Details of the feed, e.g. feeding of spent catalyst, inert gas or halogens
- C10J2300/0913—Carbonaceous raw material
- C10J2300/0943—Coke
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P20/00—Technologies relating to chemical industry
- Y02P20/10—Process efficiency
- Y02P20/129—Energy recovery, e.g. by cogeneration, H2recovery or pressure recovery turbines
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- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Combustion & Propulsion (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Cyclones (AREA)
Abstract
A kind of coke gasification produces the method for coal gas and is separated by oil-containing dirt raw gas entrance cyclone separator, obtains in every cubic metre of raw gas the content of oil dirt at the raw gas of 1 80mg and oil-containing dirt;Oil-containing dirt is enriched to the bottom of cyclone separator, uses coal gas or inert atmosphere ash can be pressurized to consistent with cyclone separator pressure, open oil-containing dirt drain valve and oil-containing dirt is entered ash can;The raw gas obtained enters integral type waste heat recoverer, reclaims heat by superheater, heat regenerator II, heat regenerator I classification, reclaims heat generation low pressure pressure saturated, middle saturated, the steam of overheated Three Estate.The present invention has without washing gas liquor generation, recycling gradable to coal gas waste thermal energy, the advantage of the different brackets steam produced simultaneously.
Description
Technical field
The invention belongs to a kind of coke gasification and produce the method and apparatus of coal gas.
Background technology
Crushed coal pressurized-gasification furnace is a kind of fixed bed coal gasifier, owing to requiring low to feed coal, i.e. except heavy caking coal
Outward, remaining coal can gasify, particularly low-order coal and the colm of high ash melting point and Jiao of gasifying.This gasification furnace is by extensively
Be applied to coal synthesis ammonia, methanol, dimethyl ether, synthesis oil and gas natural gas field.But the broken coal of industry park plan at present
The crushed coal pressure gasifying technology used in pressure gasification process is suitable for gasifying and has the coal of dry distilling, drying layer, dry in gasification
Absorbing heat when dry, dry distilling, top of gasification furnace temperature is unlikely to exceed more than gasification furnace material bearing temperature, and coke is anti-in addition
Answer poor activity, as such as the entrained flow bed gasification technologies such as Shell, GSP, space flight stove, water-coal-slurry and fluidized gasification technology are difficult to completely
Reaction (efficiency of carbon con version is low), is not suitable for coke gasification, and in the face of the most lonely coke industry, exploitation coke gasification technology is to compel
The problem of the eyebrows and eyelashes.
At present crushed coal pressure gasifying technique use in dedusting, removing oil operation for Modern Coal-based Chemical technical manual second
Version, fixed bed gasification technological process in 5 introduced in page 424 to 428, all use water washing dedust, removing oil work technique, cause thick
The display loss amount of coal gas, is unfavorable for heat recovery and utilization, also makes that gas liquor circulating load is big, operating cost is high.Patent: coal system
The technique of clean gas and device, the patent No.: the cyclone dust removal of patent use, removing oil disclosed in 201410767710.7, but
Cyclone dust removal structure is undisclosed, raw gas outlet temperature easily occurs tar condensing time low, cause slag-drip opening blocking, be difficult to stable fortune
OK.Patent: Dual tangential circulating flow type cyclone dust remover, the patent No.: make in cyclonic separation disclosed in 01243740.9 and above-mentioned patent
Cyclone dust removal, removing oil there is the same problem.Along with China's rapid industrial development, chemical plant installations is progressively towards high temperature, height
Pressure, the development of large-scale, particularly Coal Gasification Technology require vapor pressure at least more than 40 kilograms, day coal feeding amount reach thousand
Tonne, the fat coal organic C storage adding gasification is fewer and feweri, and colm ratio is stepped up on the contrary, and particularly ash fusion point is more than
The ratio of the coal of more than 1500 degree is stepped up so that gasification gas or the temperature of follow-up waste gas, pressure the most correspondingly improve,
Patent name: a kind of High Temperature High Pressure waste heat boiler, application number: the patent of 201110462710.2 solves high pressure, high temperature problem, but
The heat recovering process that uses of our current fixed bed gasification and equipment: the Modern Coal-based Chemical technical manual second edition, the 424th to
It is all one-level recuperation of heat that page 428 introduce typical fixed bed gasification technological process in 5, produces the steam of a kind of grade, coke gas
Change coal gas thick mouth temperature high, use former flow process not only to cause the wasting of resources, the most also pollute environment.Patent name: pressing gas
With waste heat boiler, application number: the patent of 200510010273.5 is mainly used in solving coal gasification, improves heat recovery efficiency,
But remain one-level recuperation of heat, produce the steam of single-grade, fail fully Waste Heat Recovery to be utilized.
Summary of the invention
The purpose of the present invention is contemplated to overcome the shortcoming and defect in above-mentioned technology, it is provided that a kind of without washing coal gas Aquatic product
Raw, recycling gradable to coal gas waste thermal energy, the coke gasification of the different brackets steam simultaneously produced produces the method for coal gas
And equipment.
The method of the present invention, comprises the steps:
(1) with coke as raw material, through crushed coal pressure gasifying generate pressure be 1.0-8.0MPa, temperature be 500-650 DEG C
Oil-containing dirt raw gas;
(2) cyclone separator that oil-containing dirt raw gas enters in dedusting cyclone separator is separated, oil in coal gas
Dirt is affected with unexpected reduction of speed dual function when leaving inner barrel by centrifugal force, makes oil dirt and portion gas from inner barrel and urceolus
The gap of body returns conic tube and carries out spin separation, and the gas after separation mixes with the oil-containing dirt raw gas entering cyclone separator
And again separate, obtain in every cubic metre of raw gas the content of oil dirt at the raw gas of 1-80mg and oil-containing dirt;
(3) oil-containing dirt is enriched to bottom the outer cylinder body of cyclone separator, uses coal gas or inert atmosphere that ash can is carried out
It is pressurized to consistent with cyclone separator pressure, opens oil-containing dirt drain valve and carry out ash discharge, after drained ash, close oil-containing dirt drain valve,
Unload ash pressure tank, after normal pressure, oil-containing dirt is discharged ash can;
(4) raw gas step (2) obtained enters integral type waste heat recoverer, successively by superheater, heat regenerator
II, it is discharged to lower procedure by recovery used heat raw gas outlet 3 after heat is reclaimed in heat regenerator I classification, reclaims heat generation low
Pressing pressure saturated, middle saturated, the steam of overheated Three Estate, the condensed fluid of generation is discharged integral type used heat through discard solution discharge port and is returned
Receive device.
Carry out crushed coal pressure gasifying with coke for raw material as mentioned above and refer to that coke adds crushed coal pressurized-gasification furnace, rely on weight
Power effect slowly decline and from top to bottom through being dried, dry distilling, methanation, gasification and carbon residue burn each bed, gasifying agent warp
Gasification agent inlet enter gasification furnace carry out series reaction, ultimately generate pressure be 1.0-8.0MPa, temperature be 500-650 DEG C
Oil-containing dirt raw gas.
The crushed coal pressurized-gasification furnace that crushed coal pressure gasifying as above uses refers on match ancient cooking vessel stove or the basis of lurgi gasifier
On, extending the height 1-3 rice of gasification furnace, Bo Siman sleeve uses water leg structure.
Entering the oil-containing dirt raw gas speed of cyclone separator in dedusting cyclone separator as mentioned above is 15-27m/s.
Cyclone dust extractor as above and ash can all use chuck double-decker, maintain cyclone dust extractor outer cylinder body inwall
With the wall temperature of ash top tank structure is between 180-240 DEG C, prevents oil-containing dirt from condensing.
Dedusting cyclone separator means as above, it includes cyclone dust extractor 201 and ash can 213, cyclone dust extractor
1 includes outer cylinder body 211 and inner barrel 205, and the top of outer cylinder body 211 is straight tube, and bottom is inverted cone, and outer cylinder body 211 is by urceolus
External wall 208 and outer cylinder body inwall 209 form, and are formed jacket structured, and inner barrel 205 is fixed on urceolus by tensioning member 210
On internal wall 209, oil-containing dirt raw gas import 202 is communicated with inner barrel 205 bottom by outer cylinder body 211, raw gas outlet 203
Being positioned at outer cylinder body 211 top, cyclone dust extractor hot water outlet 207 is arranged at outer cylinder body outer wall 208 top, and cyclone dust extractor heat is arranged at bottom
Water inlet 206, the bottom end outlet of outer cylinder body 211 is connected with ash can 213 top by oil-containing dirt drain valve 204.
Inner barrel 205 as above is conic tube structure, little in top, the big cone barrel in bottom.
The angle α of oil-containing dirt raw gas import 202 as above and outer cylinder body inwall 209 is between 75-89 degree.
Ash can 213 as above includes ash discharging hole 214, ash can chuck admission port 215, ash can chuck discharge outlet 216, puts down
Weighing apparatus gas import 217, Balance Air outlet 218, the bottom of ash can 213 is ash discharging hole 214, and the top of ash can 213 is oil dirt entrance
212, the perpendicular shape in top of ash can 213, bottom is inverted cone, and uses chuck double-decker, the top of ash can 213 to have balance
Gas import 217 and Balance Air outlet 218, ash can chuck discharge outlet 216 is arranged at the top of ash can 213, and ash can is arranged at the bottom of ash can 213
Chuck admission port 215.
Ash can 213 chuck double-decker as above is made up of ash top tank structure 219 and ash tank wall 220.
The a diameter of benchmark of 1m of cylinder inboard wall 209, other structure relative parameter such as table beyond cyclone dust extractor 201 of the present invention
1。
Table 1 cyclone dust extractor design structural parameters
Sequence number | Structure title | Structure relative parameter (unit m) |
1 | Outer cylinder body inwall 209 diameter | 1.0 |
2 | Oil-containing dirt raw gas import 202 position (is measured) bottom outer cylinder body straight tube | 0.25-0.50 |
3 | Oil-containing dirt raw gas import 202 diameter | 0.2-0.25 |
4 | Inner barrel 205 height | 0.5-0.85 |
5 | Outer cylinder body 211 straight tube height | 1.5-1.6 |
6 | Raw gas exports 203 diameters | 0.25-0.30 |
7 | Outer cylinder body 211 cone height | 2.2-2.5 |
8 | The bottom end outlet diameter of outer cylinder body 211 | 0.30-0.35 |
9 | Inner barrel 205 and the spacing of outer cylinder body inwall 209 | 0.2-0.3 |
Integral type waste heat recoverer as above, it includes the raw gas import 302 except dirt, reclaims used heat raw gas
Outlet 303, discard solution discharge port 304 and housing 301, it is characterised in that there is the raw gas import 302 except dirt on housing 301 top,
There is discard solution discharge port 304 bottom, and recovery used heat raw gas outlet 303 is arranged at bottom, and superheater 307 is arranged at top, and middle part is from top to bottom
There are heat regenerator II 306 and heat regenerator I 305.
Superheater 307 as above has middle pressure steam entrance 312 and superheated steam outlet 313.
Heat regenerator II 306 as above has heat regenerator II admission port 310 and middle pressure steam outlet 311.
Heat regenerator I 305 as above has heat regenerator I admission port 308 and low-pressure steam outlet 309.
The present invention can set up different heat exchange areas according to follow-up steam quality requirements, produces varying number and grade
Steam.
Beneficial effects of the present invention
1, oil-containing dirt in the raw gas that dry method abjection crushed coal pressure gasifying produces, it is to avoid a large amount of washing gas liquors produce and place
Reason.
2, technological process is short, energy consumption is low, gas heat loss is few, and beneficially used heat classification is reclaimed.
3, integral type waste heat recoverer floor space is little, it is low to invest, and heat recovery efficiency is high.
Accompanying drawing explanation
Fig. 1 is the method flow diagram of the present invention.
Fig. 2 is the dedusting cyclone separator means structural representation of the present invention.
Fig. 3 is the integral type waste heat recoverer structural representation of the present invention.
As it can be seen, 201-cyclone dust extractor, 202-oil-containing dirt raw gas import, the outlet of 203-raw gas, 204-oil-containing
Dirt drain valve, 205-inner barrel, 206-cyclone dust extractor hot water inlet, 207-cyclone dust extractor hot water outlet, 208-outer cylinder body
Outer wall, 209-outer cylinder body inwall, 210-tensioning member, 211-outer cylinder body, 212-oil dirt entrance, 213-ash can, 214-ash discharging hole,
215-ash can chuck admission port, 216-ash can chuck discharge outlet, 217-balance gas inlet, 218-balance gas exit, 219-
Ash top tank structure, 220-ash tank wall, α-raw gas passage and cyclone dust extractor outer cylinder body inwall angle
301-housing, 302-is except the raw gas import of dirt, and 303-reclaims the outlet of used heat raw gas, 304-discharging of waste liquid
Mouthful, 305-heat regenerator I, 306-heat regenerator II, 307-superheater, 308-heat regenerator I admission port, 309-low-pressure steam goes out
Mouthful, 310-heat regenerator II admission port, 311-middle pressure steam exports, 312-middle pressure steam entrance, and 313-superheated steam exports
Detailed description of the invention
The present invention is further illustrated it should be understood that these embodiments are only to use below by specific embodiment
In in more detail, specifically describe and be used, and be not to be construed as limiting in any form the present invention.
This part to used in the present invention to material and test method carry out general description.Although for realizing
Many materials used in the present invention and operational approach are to it is known in the art that but the present invention still makees the most detailed at this
Describe.It will be apparent to those skilled in the art that within a context, if not specified, material therefor of the present invention and operational approach are
Well known in the art.
Below in conjunction with accompanying drawing, the detailed description of the invention of the present invention is done more detailed description.
Embodiment 1
Crushed coal pressurized-gasification furnace refers to that the height of lurgi gasifier prolongs 2.9 meters, and Bo Siman sleeve uses water leg structure.
Dedusting cyclone separator means, it includes cyclone dust extractor 201 and ash can 213, and cyclone dust extractor 1 includes outer cylinder body
211 and inner barrel 205, the top of outer cylinder body 211 is straight tube, and bottom is inverted cone, and outer cylinder body 211 is by outer cylinder body outer wall 208 He
Outer cylinder body inwall 209 forms, and is formed jacket structured, and inner barrel 205 is fixed on outer cylinder body inwall 209 by tensioning member 210,
Oil-containing dirt raw gas import 202 is communicated with inner barrel 205 bottom by outer cylinder body 211, and raw gas outlet 203 is positioned at outer cylinder body
211 tops, cyclone dust extractor hot water outlet 207 is arranged at outer cylinder body outer wall 208 top, and cyclone dust extractor hot water inlet 206 is arranged at bottom,
The bottom end outlet of outer cylinder body 211 is connected with ash can 213 top by oil-containing dirt drain valve 204.
Described inner barrel 205 is conic tube structure, little in top, the big cone barrel in bottom.
Described oil-containing dirt raw gas import 202 is 75 degree with the angle α of outer cylinder body inwall 209.
Described ash can 213 includes ash discharging hole 214, ash can chuck admission port 215, ash can chuck discharge outlet 216, Balance Air
Import 217, Balance Air outlet 218, the bottom of ash can 213 is ash discharging hole 214, and the top of ash can 213 is oil dirt entrance 212, ash
The perpendicular shape in top of tank 213, bottom is inverted cone, and uses chuck double-decker, the top of ash can 213 to have Balance Air import
217 and Balance Air outlet 218, ash can chuck discharge outlet 216 is arranged at the top of ash can 213, the bottom of ash can 213 have ash can chuck to
The mouth of a river 215.
Described ash can 213 chuck double-decker is made up of ash top tank structure 219 and ash tank wall 220.
The wall temperature of described outer cylinder body inwall 209 and ash top tank structure 219 is at 183 DEG C.
The a diameter of benchmark of 1m of cylinder inboard wall 209, other structure relative parameter such as table beyond cyclone dust extractor 201 of the present invention
2。
Table 2 cyclone dust extractor design structural parameters
Sequence number | Structure title | Structure relative parameter (unit m) |
1 | Outer cylinder body inwall 209 diameter | 1.0 |
2 | Oil-containing dirt raw gas import 202 position (is measured) bottom outer cylinder body straight tube | 0.47 |
3 | Oil-containing dirt raw gas import 202 diameter | 0.25 |
4 | Inner barrel 205 height | 0.79 |
5 | Outer cylinder body 211 straight tube height | 1.5 |
6 | Raw gas exports 203 diameters | 0.25 |
7 | Outer cylinder body 211 cone height | 2.21 |
8 | The bottom end outlet diameter of outer cylinder body 211 | 0.30 |
9 | Inner barrel 205 and the spacing of outer cylinder body inwall 209 | 0.22 |
Integral type waste heat recoverer, it includes the raw gas import 302 except dirt, recovery used heat raw gas outlet 303, gives up
Liquid floss hole 304 and housing 301, it is characterised in that there is the raw gas import 302 except dirt on housing 301 top, and there is waste liquid bottom
Floss hole 304, recovery used heat raw gas outlet 303 is arranged at bottom, and superheater 307 is arranged at top, and middle part has heat regenerator from top to bottom
II 306 and heat regenerator I 305.
Described superheater 307 has middle pressure steam entrance 312 and superheated steam outlet 313.
Described heat regenerator II 306 has heat regenerator II admission port 310 and middle pressure steam outlet 311.
Described heat regenerator I 305 has heat regenerator I admission port 308 and low-pressure steam outlet 309.
(1) with coke as raw material, through crushed coal pressure gasifying generate pressure be 6.5MPa, temperature be the oil-containing dirt of 600 DEG C
Raw gas.
(2) cyclone separator 201 that oil-containing dirt raw gas enters in dedusting cyclone separator with the speed of 18m/s is entered
Row separates, and in coal gas, oil dirt is affected with unexpected reduction of speed dual function when leaving inner barrel 205 by centrifugal force, makes oil dirt and part
Gas returns conic tube and carries out spin separation, the gas after separation and entrance whirlwind from the gap of inner barrel 205 and outer cylinder body 211
The oil-containing dirt raw gas mixing of separator 201 also separates again, obtains in every cubic metre of raw gas the content of oily dirt 50mg's
Raw gas and oil-containing dirt;
(3) oil-containing dirt is enriched to bottom the outer cylinder body of cyclone separator, uses coal gas or inert atmosphere that ash can is carried out
It is pressurized to consistent with cyclone separator pressure, opens oil-containing dirt drain valve and carry out ash discharge, after drained ash, close oil-containing dirt drain valve,
Unload ash pressure tank, after normal pressure, oil-containing dirt is discharged ash can;
(4) raw gas step (2) obtained enters integral type waste heat recoverer, successively by superheater, heat regenerator
II, it is discharged to lower procedure by recovery used heat raw gas outlet 3 after heat is reclaimed in heat regenerator I classification, reclaims heat process raw
Become 1.5MPa, the low-pressure saturated steam of 198.2 DEG C, 7.0MPa, the middle pressure steam of 285.7 DEG C and 6.4MPa, the overheated steaming of 540 DEG C
The steam of vapour Three Estate, the condensed fluid of generation discharges integral type waste heat recoverer through discard solution discharge port.
Embodiment 2
Crushed coal pressurized-gasification furnace is extended height 1.1 meters on match ancient cooking vessel furnace foundation, and Bo Siman sleeve uses water leg structure.
It is 76 degree that oil-containing dirt raw gas import 202 and outer cylinder body inwall 209 form angle α.Outer cylinder body inwall 209 and ash can
The wall temperature of inwall 219 is at 273 DEG C.
The a diameter of benchmark of 1m of cylinder inboard wall 209, other structure relative parameter such as table beyond cyclone dust extractor 201 of the present invention
3。
Table 3 cyclone dust extractor design structural parameters
(1) with coke as raw material, through crushed coal pressure gasifying generate pressure be 7.8MPa, temperature be the oil-containing dirt of 640 DEG C
Raw gas;
(2) cyclone separator 201 that oil-containing dirt raw gas enters in dedusting cyclone separator with the speed of 26m/s is entered
Row separates, and in coal gas, oil dirt is affected with unexpected reduction of speed dual function when leaving inner barrel 205 by centrifugal force, makes oil dirt and part
Gas returns conic tube and carries out spin separation, the gas after separation and entrance whirlwind from the gap of inner barrel 205 and outer cylinder body 211
The oil-containing dirt raw gas mixing of separator 201 also separates again, obtains in every cubic metre of raw gas the content of oily dirt 75mg's
Raw gas and oil-containing dirt;
(3) oil-containing dirt is enriched to bottom the outer cylinder body of cyclone separator, uses coal gas or inert atmosphere that ash can is carried out
It is pressurized to consistent with cyclone separator pressure, opens oil-containing dirt drain valve and carry out ash discharge, after drained ash, close oil-containing dirt drain valve,
Unload ash pressure tank, after normal pressure, oil-containing dirt is discharged ash can;
(4) raw gas step (2) obtained enters integral type waste heat recoverer, successively by superheater, heat regenerator
II, it is discharged to lower procedure by recovery used heat raw gas outlet 3 after heat is reclaimed in heat regenerator I classification, reclaims heat process raw
Become to generate 0.6MPa, the low-pressure saturated steam of 158.7 DEG C, 6.0MPa, the middle pressure steam of 275.4 DEG C and 7.8MPa, the mistake of 340 DEG C
The steam of vapours Three Estate, the condensed fluid of generation discharges integral type waste heat recoverer through discard solution discharge port.
Embodiment 3
Crushed coal pressurized-gasification furnace is the extended height 2.5 meters of match ancient cooking vessel stove, and Bo Siman sleeve uses water leg structure.
It is 82 degree that oil-containing dirt raw gas import 202 and outer cylinder body inwall 209 form angle α.Outer cylinder body inwall 209 and ash can
The wall temperature of inwall 219 is at 225 DEG C.
The a diameter of benchmark of 1m of cylinder inboard wall 209, other structure relative parameter such as table beyond cyclone dust extractor 201 of the present invention
4。
Table 4 cyclone dust extractor design structural parameters
Sequence number | Structure title | Structure relative parameter (unit m) |
1 | Outer cylinder body inwall 209 diameter | 1.0 |
2 | Oil-containing dirt raw gas import 202 position (is measured) bottom outer cylinder body straight tube | 0.40 |
3 | Oil-containing dirt raw gas import 202 diameter | 0.23 |
4 | Inner barrel 205 height | 0.78 |
5 | Outer cylinder body 211 straight tube height | 1.56 |
6 | Raw gas exports 203 diameters | 0.27 |
7 | Outer cylinder body 211 cone height | 2.3 |
8 | The bottom end outlet diameter of outer cylinder body 211 | 0.32 |
9 | Inner barrel 205 and the spacing of outer cylinder body inwall 209 | 0.24 |
(1) with coke as raw material, through crushed coal pressure gasifying generate pressure be 1.1MPa, temperature be the oil-containing dirt of 515 DEG C
Raw gas;
(2) cyclone separator 201 that oil-containing dirt raw gas enters in dedusting cyclone separator with the speed of 26m/s is entered
Row separates, and in coal gas, oil dirt is affected with unexpected reduction of speed dual function when leaving inner barrel 205 by centrifugal force, makes oil dirt and part
Gas returns conic tube and carries out spin separation, the gas after separation and entrance whirlwind from the gap of inner barrel 205 and outer cylinder body 211
The oil-containing dirt raw gas mixing of separator 201 also separates again, obtains in every cubic metre of raw gas the content of oily dirt 32mg's
Raw gas and oil-containing dirt;
(3) oil-containing dirt is enriched to bottom the outer cylinder body of cyclone separator, uses coal gas or inert atmosphere that ash can is carried out
It is pressurized to consistent with cyclone separator pressure, opens oil-containing dirt drain valve and carry out ash discharge, after drained ash, close oil-containing dirt drain valve,
Unload ash pressure tank, after normal pressure, oil-containing dirt is discharged ash can;
(4) raw gas step (2) obtained enters integral type waste heat recoverer, successively by superheater, heat regenerator
II, it is discharged to lower procedure by recovery used heat raw gas outlet 3 after heat is reclaimed in heat regenerator I classification, reclaims heat process raw
Become to generate 1.2MPa, the low-pressure saturated steam of 187.8 DEG C, 2.1MPa, the middle pressure steam of 212.2 DEG C and 3.2MPa, the mistake of 380 DEG C
The steam of vapours Three Estate, the condensed fluid of generation discharges integral type waste heat recoverer through discard solution discharge port.
Pot removal process generate 1.2MPa, the low-pressure saturated steam of 187.8 degree, 2.1MPa, the middle pressure steam of 212.2 degree with
3.2MPa, the steam of superheated steam Three Estate of 380 degree, reclaim condensed fluid that used heat raw gas produces through discard solution discharge port
304 discharge integral type waste heat recoverer.
Embodiment 4
Crushed coal pressurized-gasification furnace refers to match the extended height 1.5 meters of ancient cooking vessel stove, and Bo Siman sleeve uses water leg structure.
It is 86 degree that oil-containing dirt raw gas import 202 and outer cylinder body inwall 209 form angle α.Outer cylinder body inwall 209 and ash can
The wall temperature of inwall 219 is at 273 DEG C.
The a diameter of benchmark of 1m of cylinder inboard wall 209, other structure relative parameter such as table beyond cyclone dust extractor 201 of the present invention
5。
Table 5 cyclone dust extractor design structural parameters
(1) with coke as raw material, through crushed coal pressure gasifying generate pressure be 3.0MPa, temperature be the oil-containing dirt of 580 DEG C
Raw gas;
(2) cyclone separator 201 that oil-containing dirt raw gas enters in dedusting cyclone separator with the speed of 19m/s is entered
Row separates, and in coal gas, oil dirt is affected with unexpected reduction of speed dual function when leaving inner barrel 205 by centrifugal force, makes oil dirt and part
Gas returns conic tube and carries out spin separation, the gas after separation and entrance whirlwind from the gap of inner barrel 205 and outer cylinder body 211
The oil-containing dirt raw gas mixing of separator 201 also separates again, obtains in every cubic metre of raw gas the content of oily dirt 21mg's
Raw gas and oil-containing dirt;
(3) oil-containing dirt is enriched to bottom the outer cylinder body of cyclone separator, uses coal gas or inert atmosphere that ash can is carried out
It is pressurized to consistent with cyclone separator pressure, opens oil-containing dirt drain valve and carry out ash discharge, after drained ash, close oil-containing dirt drain valve,
Unload ash pressure tank, after normal pressure, oil-containing dirt is discharged ash can;
(4) raw gas step (2) obtained enters integral type waste heat recoverer, successively by superheater, heat regenerator
II, it is discharged to lower procedure by recovery used heat raw gas outlet 3 after heat is reclaimed in heat regenerator I classification, reclaims heat process raw
Become 0.8MPa, the low-pressure saturated steam of 170.4 DEG C, 4.0MPa, the middle pressure steam of 250.3 DEG C and 4.0MPa, the overheated steaming of 400 DEG C
The steam of vapour Three Estate, the condensed fluid of generation discharges integral type waste heat recoverer through discard solution discharge port.
Embodiment 5
Crushed coal pressurized-gasification furnace refers to match the extended height 2.1 meters of ancient cooking vessel stove, and Bo Siman sleeve uses water leg structure.
It is 81 degree that oil-containing dirt raw gas import 202 and outer cylinder body inwall 209 form angle α.Outer cylinder body inwall 209 and ash can
The wall temperature of inwall 219 is at 218 DEG C.
The a diameter of benchmark of 1m of cylinder inboard wall 209, other structure relative parameter such as table beyond cyclone dust extractor 201 of the present invention
6。
Table 6 cyclone dust extractor design structural parameters
Sequence number | Structure title | Structure relative parameter (unit m) |
1 | Outer cylinder body inwall 209 diameter | 1.0 |
2 | Oil-containing dirt raw gas import 202 position (is measured) bottom outer cylinder body straight tube | 0.32 |
3 | Oil-containing dirt raw gas import 202 diameter | 0.24 |
4 | Inner barrel 205 height | 0.62 |
5 | Outer cylinder body 211 straight tube height | 1.52 |
6 | Raw gas exports 203 diameters | 0.27 |
7 | Outer cylinder body 211 cone height | 2.4 |
8 | The bottom end outlet diameter of outer cylinder body 211 | 0.33 |
9 | Inner barrel 205 and the spacing of outer cylinder body inwall 209 | 0.27 |
(1) with coke as raw material, through crushed coal pressure gasifying generate pressure be 4.3MPa, temperature be the oil-containing dirt of 540 DEG C
Raw gas;
(2) cyclone separator 201 that oil-containing dirt raw gas enters in dedusting cyclone separator with the speed of 23m/s is entered
Row separates, and in coal gas, oil dirt is affected with unexpected reduction of speed dual function when leaving inner barrel 205 by centrifugal force, makes oil dirt and part
Gas returns conic tube and carries out spin separation, the gas after separation and entrance whirlwind from the gap of inner barrel 205 and outer cylinder body 211
The oil-containing dirt raw gas mixing of separator 201 also separates again, obtains in every cubic metre of raw gas thick at 4mg of the content of oily dirt
Coal gas and oil-containing dirt;
(3) oil-containing dirt is enriched to bottom the outer cylinder body of cyclone separator, uses coal gas or inert atmosphere that ash can is carried out
It is pressurized to consistent with cyclone separator pressure, opens oil-containing dirt drain valve and carry out ash discharge, after drained ash, close oil-containing dirt drain valve,
Unload ash pressure tank, after normal pressure, oil-containing dirt is discharged ash can;
(4) raw gas step (2) obtained enters integral type waste heat recoverer, successively by superheater, heat regenerator
II, it is discharged to lower procedure by recovery used heat raw gas outlet 3 after heat is reclaimed in heat regenerator I classification, reclaims heat process raw
Become to generate 1.1MPa, the low-pressure saturated steam of 180.2 DEG C, the middle pressure saturated vapor of 5.0MPa 263.8 DEG C, 5.0MPa, 440 DEG C
Superheated steam, the condensed fluid of generation through discard solution discharge port discharge integral type waste heat recoverer.
Claims (14)
1. the method that a coke gasification produces coal gas, it is characterised in that comprise the steps:
(1) with coke as raw material, through crushed coal pressure gasifying generate pressure be 1.0-8.0MPa, temperature be 500-650 DEG C contain
Oil dirt raw gas;
(2) cyclone separator that oil-containing dirt raw gas enters in dedusting cyclone separator is separated, obtain every cubic metre
In raw gas, the content of oil dirt is at the raw gas of 1-80mg and oil-containing dirt;
(3) oil-containing dirt is enriched to bottom the outer cylinder body of cyclone separator, uses coal gas or inert atmosphere that ash can is carried out pressurising
To consistent with cyclone separator pressure, open oil-containing dirt drain valve and carry out ash discharge, close oil-containing dirt drain valve after drained ash, unload ash
Oil-containing dirt is discharged ash can after normal pressure by pressure tank;
(4) raw gas step (2) obtained enters integral type waste heat recoverer, successively by superheater, heat regenerator II, heat
Withdrawer I classification is discharged to lower procedure by recovery used heat raw gas outlet (3) after reclaiming heat, reclaims heat generation low pressure and satisfies
Saturated with, middle pressure, the steam of overheated Three Estate, the condensed fluid of generation discharges integral type Waste Heat Recovery through discard solution discharge port
Device.
The technique that a kind of coke gasification the most as claimed in claim 1 produces synthesis gas, it is characterised in that described broken coal pressurization
On the basis of the crushed coal pressurized-gasification furnace that gasification uses is match ancient cooking vessel stove or lurgi gasifier, extend the height 1-3 rice of gasification furnace, Bo Siman
Sleeve uses water leg structure.
The technique that a kind of coke gasification the most as claimed in claim 1 produces synthesis gas, it is characterised in that described entrance dedusting is revolved
In wind segregation apparatus, the oil-containing dirt raw gas speed of cyclone separator is 15-27m/s.
The technique that a kind of coke gasification the most as claimed in claim 1 produces synthesis gas, it is characterised in that described outer cylinder body inwall
With the wall temperature of ash top tank structure is between 180-240 DEG C.
5. a dedusting cyclone separator means, it includes cyclone dust extractor (201) and ash can (213), and its domestic animal feature is in whirlwind
Cleaner unit 1 includes outer cylinder body (211) and inner barrel (205), and the top of outer cylinder body (211) is straight tube, and bottom is inverted cone, urceolus
Body (211) is made up of outer cylinder body outer wall (208) and outer cylinder body inwall (209), and is formed jacket structured, and inner barrel (205) passes through
Tensioning member (210) is fixed on outer cylinder body inwall (209), and oil-containing dirt raw gas import (202) passes through outer cylinder body (211) and inner core
Body (205) bottom communicates, and raw gas outlet (203) is positioned at outer cylinder body (211) top, and whirlwind is arranged at outer cylinder body outer wall (208) top
Cleaner unit hot water outlet (207), cyclone dust extractor hot water inlet (206) is arranged at bottom, and the bottom end outlet of outer cylinder body (211) is by containing
Oil dirt drain valve (204) is connected with ash can (213) top.
6. a kind of dedusting cyclone separator means as claimed in claim 5, it is characterised in that described inner barrel 205 is cone cylinder
Body structure, little in top, the big cone barrel in bottom.
7. a kind of dedusting cyclone separator means as claimed in claim 5, it is characterised in that described oil-containing dirt raw gas enters
The angle α of mouth (202) and outer cylinder body inwall (209) is between 75-89 degree.
8. a kind of dedusting cyclone separator means as claimed in claim 5, it is characterised in that described ash can (213) includes row
Ash mouth (214), ash can chuck admission port (215), ash can chuck discharge outlet (216), Balance Air import (217), Balance Air outlet
(218), the bottom of ash can (213) is ash discharging hole (214), and the top of ash can (213) is oil dirt entrance (212), ash can (213)
The perpendicular shape in top, bottom is inverted cone, and uses chuck double-decker, and Balance Air import (217) is arranged at the top of ash can (213)
Exporting (218) with Balance Air, the top of ash can (213) has ash can chuck discharge outlet (216), the bottom of ash can (213) to have ash can
Chuck admission port (215).
9. a kind of dedusting cyclone separator means as claimed in claim 8, it is characterised in that described ash can (213) chuck is double
Rotating fields is made up of ash top tank structure (219) and ash tank wall (220).
10. a kind of dedusting cyclone separator means as claimed in claim 5, it is characterised in that beyond cyclone dust extractor (201)
The a diameter of benchmark of 1m of cylinder inboard wall (209), other structure is as follows:
Measuring bottom outer cylinder body straight tube, oil-containing dirt raw gas import (202) position is 0.25-0.50;Oil-containing dirt raw gas enters
Mouth (202) a diameter of 0.2-0.25;Inner barrel (205) height is 0.5-0.85;Outer cylinder body (211) straight tube height is 1.5-1.6;
Raw gas outlet (203) a diameter of 0.25-0.30;Outer cylinder body (211) cone height is 2.2-2.5;The bottom of outer cylinder body (211)
Outlet diameter is 0.30-0.35;Inner barrel (205) and spacing 0.2-0.3 of outer cylinder body inwall (209).
11. integral type waste heat recoverers, it includes the raw gas import (302) except dirt, reclaims the outlet of used heat raw gas
(303), discard solution discharge port (304) and housing (301), it is characterised in that there is the raw gas import except dirt on housing (301) top
(302), there is discard solution discharge port (304) bottom, and recovery used heat raw gas outlet (303) is arranged at bottom, and superheater (307) is arranged at top,
Middle part has heat regenerator II (306) and heat regenerator I (305) from top to bottom.
12. integral type waste heat recoverers as claimed in claim 11, it is characterised in that described superheater (307) has middle pressure to steam
Vapour entrance (312) and superheated steam outlet (313).
13. integral type waste heat recoverers as claimed in claim 11, it is characterised in that described heat regenerator II (306) has heat
Withdrawer II admission port (310) and middle pressure steam outlet (311).
14. integral type waste heat recoverers as claimed in claim 11, it is characterised in that described heat regenerator I (305) has heat
Withdrawer I admission port (308) and low-pressure steam outlet (309).
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