CN106221178A - A kind of flame retardant type fibre reinforced polyketone composite - Google Patents
A kind of flame retardant type fibre reinforced polyketone composite Download PDFInfo
- Publication number
- CN106221178A CN106221178A CN201610716926.XA CN201610716926A CN106221178A CN 106221178 A CN106221178 A CN 106221178A CN 201610716926 A CN201610716926 A CN 201610716926A CN 106221178 A CN106221178 A CN 106221178A
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- Prior art keywords
- fibre reinforced
- resin compositions
- weight
- polyketone resin
- flame retardant
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K13/00—Use of mixtures of ingredients not covered by one single of the preceding main groups, each of these compounds being essential
- C08K13/04—Ingredients characterised by their shape and organic or inorganic ingredients
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/32—Phosphorus-containing compounds
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K7/00—Use of ingredients characterised by shape
- C08K7/02—Fibres or whiskers
- C08K7/04—Fibres or whiskers inorganic
- C08K7/06—Elements
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L73/00—Compositions of macromolecular compounds obtained by reactions forming a linkage containing oxygen or oxygen and carbon in the main chain, not provided for in groups C08L59/00 - C08L71/00; Compositions of derivatives of such polymers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/002—Physical properties
- C08K2201/003—Additives being defined by their diameter
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- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Abstract
The invention discloses a kind of fibre reinforced polyketone resin compositions, relative to the polyketone of 100 weight portions, be added with 10 60 parts by weight of carbon fibers, 5 30 weight portion phosphorus flame retardants and other auxiliary agents of 05 weight portions.This polyketone resin compositions mobility, intensity, rigidity and anti-flammability are all good, and mobility is prone to formed product, it is possible to reduce floating fibre；Can be widely used on the product of electromotor housing, tank for gaseous or liquid substances, fuel pipe and thin-walled property.
Description
Technical field
The present invention relates to technical field of polymer materials, be specifically related to a kind of high physical property fire-retardant combination.
Background technology
Polyketone is the novel green polymeric material that (POK) is synthesized by carbon monoxide, alkene (ethylene, propylene), as one
Kind of engineering plastic, has many excellent performances, as excellent chemical resistance and stability to hydrolysis resistance, frictional behaviour, anti-flammability,
Fuel resistance, and there are high heat distortion temperature, high impact, height (gas) barrier etc., can be applicable to industry (gear,
Seat is joined), automotive fuel oil system and bonnet, automobile external assembly, obstructing tube and packaging, electric component etc..In recent years, meter
Numerous industries such as calculation machine, flat board, mobile phone, TV, automobile develop to lighter and thinnerization.It is little, lightweight, firm that carbon fiber has density
Property the characteristic such as strong, increasingly extensive in 3C, automobile and other industries application.In view of this, need to develop a kind of high rigidity POK resin combination
Thing is to solve POK rigidity problem on the low side, and light weight, can thin-walled property, to extend the range of application of POK material.
Summary of the invention
It is an object of the invention to provide a kind of fibre reinforced polyketone (POK) resin combination so that it is obtain in bending
The product that modulus, impact strength and wearability aspect are all good.
The technical problem to be solved is achieved through the following technical solutions:
A kind of fibre reinforced polyketone resin compositions, relative to the polyketone of 100 weight portions, is added with 10-60 weight portion
Carbon fiber, 5-30 weight portion phosphorus flame retardant and other auxiliary agents of 0-5 weight portion.
Alternatively, described polyketone is for being 240 DEG C in ambient temperature, and when load is 2.16Kg, melt index is 30-90g/
10min。
Alternatively, described carbon fiber is chopped carbon fiber or seriality carbon fiber, its a diameter of 0.4-0.9 micron.
Alternatively, the addition of described phosphorus flame retardant is 5-25 weight portion, is more preferably 10-20 weight portion.
Alternatively, at least one during described phosphorus flame retardant is phosphate ester, hypophosphites and phosphonates.
Alternatively, in described phosphorus flame retardant, the weight content of phosphorus is 7-40%.
Alternatively, other auxiliary agents described include lubricant, antistatic agent, antioxidant, UV absorbent, releasing agent and
At least one in coloring agent.
Compared to prior art, a kind of fibre reinforced polyketone resin compositions of the present invention, by adding in polyketone
The carbon fiber of specified quantitative and phosphorus flame retardant, can obtain the polyketone resin combination that mobility, intensity, rigidity and anti-flammability are all good
Thing, the high intensity of said composition, high rigidity can be applied at electromotor housing, tank for gaseous or liquid substances, fuel pipe etc. material chemically-resistant, resistance to
On the product that hydrolysis, resistance to fuel oil, rigid requirements are high, it is possible to be applied on the product of the thin-walled properties such as pen electricity, the flowing of said composition
Property be prone to formed product, it is possible to reduce floating fibre.
Detailed description of the invention
In the fibre reinforced polyketone resin compositions of the present invention, relative to the polyketone of 100 weight portions, it is added with 10-60
Parts by weight of carbon fibers, 5-30 weight portion phosphorus flame retardant and other auxiliary agents of 0-5 weight portion.
Wherein, being 240 DEG C in ambient temperature, when load is 2.16Kg, the melt index of described polyketone is 30-90g/
10min。
Wherein, a diameter of 0.4-0.9 micron of described carbon fiber, the mobility of compositions, intensity and rigidity can be improved, can
Use chopped carbon fiber, it is possible to use continuous carbon fiber.On thin-walled property product, use chopped carbon fiber modification polyketone material
Material, product surface is more excellent.
Wherein, when described phosphorus flame retardant addition is less than 5 weight portion, it is impossible to play flame retardant effect, higher than 30 weight portions,
Then the physical property of compositions declines serious, and the preferably addition of phosphorus flame retardant is 5-25 weight portion, is more preferably 10-20 weight
Part.Described phosphorus flame retardant is at least one in phosphate ester, phosphinate and phosphonates, phosphorus weight in described phosphorus flame retardant
Content is the 7-40% of phosphorus flame retardant weight, can reach more excellent flame retardant effect.
Wherein, described polyketone resin compositions also includes lubricant, antistatic agent, antioxidant, UV absorbent,
At least one in releasing agent and coloring agent.
For the purpose of the present invention, technological means and technology effect there being further understanding, say in conjunction with specific embodiment
Bright as follows.
Embodiment 1
Weigh each component of corresponding weight；Then, single shaft agitator is utilized to stir each component；By said mixture respectively
Join and double screw extruder melt extrudes pelletize.
Embodiment 2
Weigh each component of corresponding weight；Then, single shaft agitator is utilized to stir each component；By said mixture respectively
Join and double screw extruder melt extrudes pelletize.
Embodiment 3
Weigh each component of corresponding weight；Then, single shaft agitator is utilized to stir each component；By said mixture respectively
Join and double screw extruder melt extrudes pelletize.
Comparative example 1
In this comparative example, the glass fibre of circular section shape is the glass of the commercially available circular section shape of Jushi company
Fiber.
Weigh each component of corresponding weight；Then, single shaft agitator is utilized to stir each component；By said mixture respectively
Join and double screw extruder melt extrudes pelletize.
Comparative example 2
Comparative example 2 is commercial goods Du PontHTN 53G50HSLR, is a kind of commercial goods of E.I.Du Pont Company,
The trade markHTN 53G50HSLR, it is the glass of the flattened adding 50% weight in high temperature resistant nylon (PPA)
Glass fiber.
After various embodiments above and comparative example melt extrude pelletize, then injection mo(u)lding GB standard testing sample on injection machine
Bar, by the mechanical performance of GB standard testing resulting materials, and according to UL94 standard testing fire resistance, test result such as table 1 institute
Show:
Table 1: embodiment and the test result of comparative example
| Test event | Embodiment 1 | Embodiment 2 | Embodiment 3 | Comparative example 1 | Comparative example 2 |
| Proportion (g/cm3) | 1.32 | 1.4 | 1.40 | 1.30 | 1.64 |
| Hot strength (MPa) | 200 | 190 | 220 | 85 | 220 |
| Elongation at break (%) | 2.1 | 1.8 | 1.7 | 3.5 | 1.8 |
| Bending strength (MPa) | 260 | 260 | 300 | 130 | 270 |
| Bending modulus (MPa) | 18000 | 20000 | 22500 | 4500 | 16000 |
| Impact strength (KJ/m2) | 9 | 10 | 9.5 | 7.5 | 13 |
| Flame retardant rating | 1.2mm V-0 | 0.8mm V-0 | 1.2mm V-0 | 0.4mm V-0 | 0.4mm V-0 |
| Heat distortion temperature (DEG C) | 245 | 265 | 270 | 230 | 260 |
Above a kind of flame retardant type fibre reinforced polyketone resin compositions provided by the present invention is described in detail.
Principle and the embodiment of the present invention are set forth by specific case used herein, and the explanation of above example is simply used
In helping to understand the core concept of the present invention.It should be pointed out that, for those skilled in the art, without departing from
On the premise of the principle of the invention, it is also possible to the present invention is carried out some improvement and modification, these improve and modification also falls into this
In bright scope of the claims.
Claims (7)
1. a fibre reinforced polyketone resin compositions, it is characterised in that relative to the polyketone of 100 weight portions, be added with 10-
60 parts by weight of carbon fibers, 5-30 weight portion phosphorus flame retardant and other auxiliary agents of 0-5 weight portion.
A kind of fibre reinforced polyketone resin compositions the most according to claim 1, it is characterised in that described polyketone be
Ambient temperature is 240 DEG C, and when load is 2.16Kg, melt index is 30-90g/10min.
A kind of fibre reinforced polyketone resin compositions the most according to claim 1, it is characterised in that described carbon fiber is
Chopped carbon fiber or seriality carbon fiber, its a diameter of 0.4-0.9 micron.
A kind of fibre reinforced polyketone resin compositions the most according to claim 1, it is characterised in that described phosphorous flame-retardant
The addition of agent is 5-25 weight portion, is more preferably 10-20 weight portion.
A kind of fibre reinforced polyketone resin compositions the most according to claim 1, it is characterised in that described phosphorous flame-retardant
Agent is at least one in phosphate ester, hypophosphites and phosphonates.
A kind of fibre reinforced polyketone resin compositions the most according to claim 5, it is characterised in that described phosphorous flame-retardant
In agent, the weight content of phosphorus is 7-40%.
A kind of fibre reinforced polyketone resin compositions the most according to claim 1, it is characterised in that other auxiliary agents described
Including at least one in lubricant, antistatic agent, antioxidant, UV absorbent, releasing agent and coloring agent.
Priority Applications (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610716926.XA CN106221178A (en) | 2016-08-24 | 2016-08-24 | A kind of flame retardant type fibre reinforced polyketone composite |
| PCT/CN2016/111068 WO2018036039A1 (en) | 2016-08-24 | 2016-12-20 | Flame-retardant carbon fiber-reinforced polyketone composite material |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610716926.XA CN106221178A (en) | 2016-08-24 | 2016-08-24 | A kind of flame retardant type fibre reinforced polyketone composite |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN106221178A true CN106221178A (en) | 2016-12-14 |
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Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201610716926.XA Pending CN106221178A (en) | 2016-08-24 | 2016-08-24 | A kind of flame retardant type fibre reinforced polyketone composite |
Country Status (2)
| Country | Link |
|---|---|
| CN (1) | CN106221178A (en) |
| WO (1) | WO2018036039A1 (en) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107033577A (en) * | 2017-03-16 | 2017-08-11 | 广东圆融新材料有限公司 | A kind of 5VA grades of flame-retardant conductive polyketone composite and preparation method thereof |
| WO2018036039A1 (en) * | 2016-08-24 | 2018-03-01 | 五行科技股份有限公司 | Flame-retardant carbon fiber-reinforced polyketone composite material |
Families Citing this family (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN111411417A (en) * | 2020-05-15 | 2020-07-14 | 天津工业大学 | Graphene reinforced polyketone fiber and preparation method thereof |
| CN114058171A (en) * | 2021-12-15 | 2022-02-18 | 黄河三角洲京博化工研究院有限公司 | anti-UV (ultraviolet) aging polyketone material and preparation method thereof |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105199379A (en) * | 2015-10-27 | 2015-12-30 | 北京纳盛通新材料科技有限公司 | Continuous long carbon fiber reinforced thermoplastic nanocomposite and preparation method and application thereof |
| WO2016060511A2 (en) * | 2014-10-17 | 2016-04-21 | (주) 효성 | Polyketone resin composition having excellent conductivity |
Family Cites Families (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105102520B (en) * | 2013-04-01 | 2018-02-13 | 沙特基础全球技术有限公司 | High-modulus laser direct forming composite |
| CN106221178A (en) * | 2016-08-24 | 2016-12-14 | 五行科技股份有限公司 | A kind of flame retardant type fibre reinforced polyketone composite |
-
2016
- 2016-08-24 CN CN201610716926.XA patent/CN106221178A/en active Pending
- 2016-12-20 WO PCT/CN2016/111068 patent/WO2018036039A1/en active Application Filing
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2016060511A2 (en) * | 2014-10-17 | 2016-04-21 | (주) 효성 | Polyketone resin composition having excellent conductivity |
| CN105199379A (en) * | 2015-10-27 | 2015-12-30 | 北京纳盛通新材料科技有限公司 | Continuous long carbon fiber reinforced thermoplastic nanocomposite and preparation method and application thereof |
Non-Patent Citations (3)
| Title |
|---|
| 何建新: "《新型纤维材料学》", 31 December 2014, 东华大学出版社 * |
| 励杭泉，赵静，张晨: "《材料导论》", 31 December 2013, 中国轻工业出版社 * |
| ***、陈开来: "《工程塑料手册 材料卷》", 31 December 2004, 机械工业出版社 * |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2018036039A1 (en) * | 2016-08-24 | 2018-03-01 | 五行科技股份有限公司 | Flame-retardant carbon fiber-reinforced polyketone composite material |
| CN107033577A (en) * | 2017-03-16 | 2017-08-11 | 广东圆融新材料有限公司 | A kind of 5VA grades of flame-retardant conductive polyketone composite and preparation method thereof |
| CN107033577B (en) * | 2017-03-16 | 2019-03-19 | 广东圆融新材料有限公司 | A kind of 5VA grades of flame-retardant conductive polyketone composite material and preparation method |
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| Publication number | Publication date |
|---|---|
| WO2018036039A1 (en) | 2018-03-01 |
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