CN106220909A - Wiping slurry grass green rubber and preparation method thereof reprocessed by liberation Foxing strip for rubber shoes slurry - Google Patents
Wiping slurry grass green rubber and preparation method thereof reprocessed by liberation Foxing strip for rubber shoes slurry Download PDFInfo
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- CN106220909A CN106220909A CN201610713024.0A CN201610713024A CN106220909A CN 106220909 A CN106220909 A CN 106220909A CN 201610713024 A CN201610713024 A CN 201610713024A CN 106220909 A CN106220909 A CN 106220909A
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L7/00—Compositions of natural rubber
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29B—PREPARATION OR PRETREATMENT OF THE MATERIAL TO BE SHAPED; MAKING GRANULES OR PREFORMS; RECOVERY OF PLASTICS OR OTHER CONSTITUENTS OF WASTE MATERIAL CONTAINING PLASTICS
- B29B7/00—Mixing; Kneading
- B29B7/74—Mixing; Kneading using other mixers or combinations of mixers, e.g. of dissimilar mixers ; Plant
- B29B7/7476—Systems, i.e. flow charts or diagrams; Plants
- B29B7/7495—Systems, i.e. flow charts or diagrams; Plants for mixing rubber
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C43/00—Compression moulding, i.e. applying external pressure to flow the moulding material; Apparatus therefor
- B29C43/22—Compression moulding, i.e. applying external pressure to flow the moulding material; Apparatus therefor of articles of indefinite length
- B29C43/24—Calendering
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J3/00—Processes of treating or compounding macromolecular substances
- C08J3/20—Compounding polymers with additives, e.g. colouring
- C08J3/22—Compounding polymers with additives, e.g. colouring using masterbatch techniques
- C08J3/226—Compounding polymers with additives, e.g. colouring using masterbatch techniques using a polymer as a carrier
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2307/00—Characterised by the use of natural rubber
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2409/00—Characterised by the use of homopolymers or copolymers of conjugated diene hydrocarbons
- C08J2409/06—Copolymers with styrene
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
- C08L2205/025—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group containing two or more polymers of the same hierarchy C08L, and differing only in parameters such as density, comonomer content, molecular weight, structure
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
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- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Mechanical Engineering (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Footwear And Its Accessory, Manufacturing Method And Apparatuses (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Abstract
The invention discloses a kind of liberation Foxing strip for rubber shoes slurry and reprocess wiping slurry grass green rubber, it includes with 2# standard rubber, butadiene-styrene rubber, sulfur, vulcanization accelerator, superfine active zinc oxide, stearic acid, age resistor, high-phenylethylene, potter's clay, precipitated calcium carbonate and grass green coloring rubber master batch for preparing raw material.The present invention, by reasonably filtering out applicable component, show that wiping slurry grass green rubber and preparation method thereof reprocessed by a kind of liberation Foxing strip for rubber shoes slurry, can significantly improve the hardness of rubber erasers using this material as rubber erasers, improve work efficiency and operation quality.Realizing exposing of rubber overshoes upper of a shoe and do not stay heterochromatic vestige when rubber cement is reprocessed, presentation quality is good, solves defect present in existing liberation rubber overshoes upper foxing slurry rework process.The present invention is simple, with low cost, and using effect is good.
Description
Technical field
The present invention relates to a kind of field of rubber technology, wiping slurry grass green rubber reprocessed by especially a kind of liberation Foxing strip for rubber shoes slurry
Glue and preparation method thereof.
Background technology
Hot vulcanized rubber boots must use in manufacturing process bonding rubber cement to bond foxing rubber and shoe last surface cloth, due to
Swabbing operation can not complete to accomplish the uniform of rubber cement and foxing table edge, and must be formed at foxing film coverage rate and expose
Rubber cement is to represent that bonding firmly, therefore, is often exposed irregular swabbing curve at foxing position suitable for reading, affected rubber overshoes finished product
Attractive in appearance.
Generally, during upper of a shoe is bonded the curve rubber cement repairing neatly above foxing.Use vulcanization
Rubber eraser is except repairing so that it is keep and foxing rubber oriented parallel suitable for reading.And vulcanization rubber is not enough due to hardness, in wiping
During, often work efficiency is low, foxing heap suitable for reading slurry is reprocessed irregular, reprocesses of poor quality.The color of additional vulcanite and upper of a shoe
Fiber is different, causes grass green upper of a shoe surface remaining heterochromatic, has a strong impact on rubber overshoes aesthetics.
Summary of the invention
It is an object of the invention to: provide one liberation Foxing strip for rubber shoes slurry to reprocess wiping slurry grass green rubber and preparation side thereof
Method, it can improve the hardness of rubber erasers, improve work efficiency and operation quality, it is achieved the exposing of rubber overshoes upper of a shoe is not stayed heterochromatic when rubber cement is reprocessed
Vestige, presentation quality is good, to overcome the deficiencies in the prior art.
The present invention is achieved in that wiping slurry grass green rubber reprocessed by liberation Foxing strip for rubber shoes slurry, calculates in parts by weight,
It includes with 2# standard rubber 75-85 part, butadiene-styrene rubber 15-25 part, sulfur 35-40 part, vulcanization accelerator 4.5-5.5 part, ultra-fine
Activated zinc oxide 2.5-3.5 part, stearic acid 1.5-2.0 part, age resistor 1-2 part, high-phenylethylene 46-50 part, potter's clay 180-200
Part, precipitated calcium carbonate 25-30 part and grass green coloring rubber master batch 9-11 part are for preparing raw material.
Optimally, it includes with 2# standard rubber 80 parts, 20 parts of butadiene-styrene rubber, 38 parts of sulfur, vulcanization accelerator 5 parts, ultra-fine
Activated zinc oxide 3 parts, stearic acid 1.8 parts, 1.5 parts of age resistor, high-phenylethylene 48 parts, 190 parts of potter's clay, precipitated calcium carbonate 28 parts and
Grass green coloring rubber master batch 10 parts is for preparing raw material.
Also bag calcium grease 2-3 part and 46# machine oil 4-5 part.
Every 70 parts of grass greens coloring rubber master batch is by butadiene-styrene rubber 35 parts, 2.0 parts of paraffin, high wear-resistant carbon black 2.0 parts, phthalein viridescent 1.0
Part and medium chrome yellow 30 parts composition；Every 5 parts of vulcanization accelerators are by 1.5 parts of accelerant CZs, 2 parts of altaxs and 1.5 parts of diphenylguanidine S
Composition；Every 1.5 parts of age resistor are made up of 1 part of age resistor CD and 0.5 part of age resistor KY-405L.
The preparation method wiping slurry grass green rubber reprocessed by liberation Foxing strip for rubber shoes slurry, takes each component by above-mentioned mass fraction,
Comprise the steps:
1) broken-down rubber is prepared: 2# standard rubber and high-phenylethylene are pressed in the banbury that temperature is 100-110 DEG C refining 6-7 divide
Clock, is allowed to be formed mixture, then through opening rubber mixing machine thin logical 6 roads under 0 roll spacing, reel is deposited, and obtains broken-down rubber；
2) preparation of elastomeric compound: broken-down rubber and butadiene-styrene rubber are put in banbury, adds sulfur, vulcanization accelerator, surpasses
Activity zinc oxide, stearic acid and age resistor, under the conditions of temperature 85-100 DEG C, pressure refining 1-1.5 minute, adds potter's clay, lightweight carbon
Acid calcium and grass green coloring rubber master batch, refine 3-4 minute, and by mixed material in opening rubber mixing machine, turn refining under 4-5mm roll spacing 8-
9 roads, refining is to smooth surface, and tabletting is deposited, and must liberate Foxing strip for rubber shoes slurry and reprocess that to wipe slurry grass green rubber mixed；
3) preparation wiping slurry grass green rubber reprocessed by liberation Foxing strip for rubber shoes slurry: liberation Foxing strip for rubber shoes slurry is reprocessed wiping slurry and uses
Rubber mixed thickness 5-6mm, width 18-20mm, the length 50-55mmm sheet rubber of being pressed on calender of grass green, natural
It is cooled to room temperature, vulcanizes 30 minutes under liberation rubber overshoes hot-air steam cure process conditions, take out to cool down i.e. to obtain and liberate Foxing strip for rubber shoes slurry
Reprocess wiping slurry grass green rubber.
In step 2) described in when preparing elastomeric compound, add calcium grease 2-3 part and 46# machine oil 4-5 part.
Step 3) described in liberation rubber overshoes hot-air steam cure technique be, use vulcanizing tank carry out free vulcanization, in sulfidation,
Within first 15 minutes, use hot air, within latter 15 minutes, use saturated vapor and hot-air Hybrid Heating.
One, test data screening process:
1. coloring rubber master batch material mixture ratio and consumption test
1) properties contrast
Table 1
| Sequence number | Rubber kind | Refining colloidality energy and feature |
| 1 | 1# standard rubber | Refining gluing roller, color is normal |
| 2 | 2# standard rubber | Refine gluing roller, be a bit darkish in color abnormal |
| 3 | Butadiene-styrene rubber | Refining glue is normal, and color is normal |
| 4 | Butadiene rubber | Refining glue roll release, color is normal |
| 5 | Nitrile rubber | Refining glue shrinks big, and color is normal |
Table 1 result shows, uses butadiene-styrene rubber to make material of main part in coloring agent, and processing performance is optimal.
2) proportioning test of main coloring pigment in coloring rubber master batch
According to rubber preparing device practical situation, 75 liter banburies are selected to carry out colouring the refining glue conduct of rubber master batch, it is thus determined that
35 parts of butadiene-styrene rubbers are used to carry out the research work of other toner consumption as main body material.
Table 2
Being drawn by table 2 contrast, coloring rubber master batch material construction optimum proportioning is: 35 parts of butadiene-styrene rubbers, 2.0 parts of paraffin, white carbon black
(high abrasion) 2.0 parts, phthalein dark green 1.0 parts, medium chrome yellow 30 parts.
3) coloring rubber master batch consumption and color relationship
Table 3
| Sequence number | Grass green coloring rubber master batch (number) | Form and aspect state |
| 1 | 2 | Color is the most shallow |
| 2 | 4 | Color is the most shallow |
| 3 | 6 | Color is the most shallow |
| 4 | 8 | Color is the most shallow |
| 5 | 10 | Color is normal |
| 6 | 12 | Form and aspect are the deepest |
Proving through implementing contrast, when coloring rubber master batch consumption is 10 parts, sizing material color meets liberation footwear grass green upper of a shoe color
Requirement mutually.
2. rubber framework material consumption and property relationship
1) natural rubber and rubber polymer proportioning test
Table 4
Table 4 draws, in rubber proportioning, 2# standard rubber 80 parts, butadiene-styrene rubber 20 parts, gained properties of rubber is optimal.
2) Hardening agent high-phenylethylene consumption contrast test
Table 5
Table 2 draws, high-phenylethylene consumption, 46-50 part, is provided that the corresponding performance of rubber, is in optimum amount scope.
3. reinforcing agent quantity research
A basic recipe: 2# standard rubber 80 parts, 20 parts of butadiene-styrene rubber, high-phenylethylene 48 parts, vulcanization accelerator 5 parts, ultra-fine work
Property zinc oxide 3 parts, stearic acid 1.8 parts, 1.5 parts of age resistor, precipitated calcium carbonate 28 parts, grass green coloring rubber master batch 10 parts.Sulfur
(38), potter's clay (190) variable.
B testing program:
Table 6
Being drawn by table 1, test material optimum proportioning is: 38 parts of sulfur, 19 parts of potter's clay.
It is best that this proportioning reaches using effect, and processing performance is normal.
(2) vulcanizing system contrast test A basic recipe: 2# standard rubber 80 parts, 20 parts of butadiene-styrene rubber, high-phenylethylene 48 parts,
38 parts of sulfur, 19 parts of potter's clay, 1.5 parts of age resistor, precipitated calcium carbonate 28 parts, grass green coloring rubber master batch 10 parts.Accelerator system, work
Gonosome system, variable
B Experimental Comparison table
Table 2
Table 2 result illustrates, vulcanizing system and reactive systems optimal period's consumption be: altax 2 parts, captax 1 part, promote
Enter agent CZ1.5 part, diphenylguanidine S 1.5 parts, superfine active zinc oxide 3 parts, stearic acid 1.8 parts.
(3) filler and age resistor with test
A basic recipe: 2# standard rubber 80 parts, 20 parts of butadiene-styrene rubber, high-phenylethylene 48 parts, 38 parts of sulfur, 19 parts of potter's clay, anti-
Old agent 1.5 parts, altax 2 parts, captax 1 part, accelerant CZ 1.5 parts, diphenylguanidine S 1.5 parts, superfine active zinc oxide 3
Part, stearic acid 1.8 parts, grass green coloring rubber master batch 10 parts, precipitated calcium carbonate, age resistor variable.
B Experimental Comparison table
Table 3
Table 3 result draws, filler optimum proportioning is: precipitated calcium carbonate 28 parts, age resistor CD1.0 part, age resistor KY-
405L0.5 part.Using effect reaches best level, can take into account projects performance requirement.
(4) natural gum flexibility contrast test
Table 4
Table 4 shows, natural rubber is not plasticated, and can take into account processing performance, use prescription, belong to optimal bar
Conclusion (of pressure testing):
Being drawn by above-mentioned test, optimum formula and process conditions are as follows:
1) optimum formula: 2# standard rubber 80 parts, 20 parts of butadiene-styrene rubber, high-phenylethylene 48 parts, 38 parts of sulfur, 19 parts of potter's clay,
1.5 parts of age resistor, altax 2 parts, captax 1 part, accelerant CZ 1.5 parts, diphenylguanidine S 1.5 parts, superfine active aoxidize
3 parts of zinc, stearic acid 1.8 parts, grass green coloring rubber master batch 10 parts, precipitated calcium carbonate 28 parts, age resistor CD1.0 part, age resistor KY-
405L0.5 part.
2) process control condition: sulfuration starting point 3 ' 10 "-3 ' 30 ", need not plasticating of natural rubber.
Two, the research of preparation technology
1.2# standard rubber and high-phenylethylene close mixing condition test
1) equipment is used: 75 found banbury and XK-400 opening rubber mixing machine
2) mixing condition contrast is closed
Upper table illustrates, glue furnacing temperature is in the range of 100-110, and refined sizing material is best in quality, time optimal.
2. close refining glue 0 roll spacing thin logical number of times contrast
| Close refining glue thin channel number | Sizing material quality |
| 0 | Rough surface |
| 1 | Rough surface |
| 2 | Surface roughness reduces |
| 4 | The most smooth |
| 5 | Essentially smooth, good dispersion |
| 6 | Smooth, good dispersion |
| 7 | Smooth, good dispersion |
| 8 | Smooth, good dispersion |
Upper table shows, closes refining glue thin logical number of times under 0 roll spacing and reaches more than 6 roads, and guarantee has face smooth, reaches sizing material
Prescription.
Conclusion (of pressure testing):
Being drawn by above-mentioned test, optimum formula and process conditions are as follows:
Optimum formula: 2# standard rubber 80 parts, 20 parts of butadiene-styrene rubber, 38 parts of sulfur, vulcanization accelerator 5 parts, superfine active oxygen
Change 3 parts of zinc, stearic acid 1.8 parts, 1.5 parts of age resistor, high-phenylethylene 48 parts and 190 parts of potter's clay, precipitated calcium carbonate 28 parts, grass green
Coloring rubber master batch 10 parts, calcium grease 2.5 parts, 4.5 parts of 46# machine oil.
Selection process:
(1) broken-down rubber is prepared: by 80 parts of 2# standard rubbers and 48 parts of high-phenylethylenes in the banbury that temperature is 100-110 DEG C
Pressure refining 6-7 minute, is allowed to be formed mixture, then through XK-400 opening rubber mixing machine thin logical 6 roads under 0 roll spacing, reel is deposited,
Obtain broken-down rubber；
(2) preparation of elastomeric compound: 128 points of broken-down rubbers, 20 parts of butadiene-styrene rubbers are promoted with 38 parts of sulfur, sulfuration in banbury
Agent 5 parts, superfine active zinc oxide 3 parts, stearic acid 1.8 parts, 1.5 parts of age resistor, pressure refining 1-1.5 under the conditions of temperature 85-100 DEG C
Minute, add 190 parts of potter's clay, precipitated calcium carbonate 28 parts, grass green coloring rubber master batch 10 parts, calcium grease 2.5 parts, 46# machine oil 4.5
Part, refine 3-4 minute, by mixed material in XK-400 opening rubber mixing machine, turn refining under 4-5mm roll spacing 8-9 road, refining to table
Face is smooth, and tabletting is deposited, must liberate Foxing strip for rubber shoes slurry reprocess wiping slurry grass green rubber mixed；
(3) liberation Foxing strip for rubber shoes slurry reprocess wiping the slurry grass green vulcanization of rubber prepare: by liberation Foxing strip for rubber shoes starch reprocess wiping
Slurry grass green is rubber mixed is pressed into thickness 5-6mm, width 18-20mm, length 50-55mmm sheet rubber on calender,
Be cooled to room temperature, be put in liberation rubber overshoes hot-air steam cure process conditions under vulcanize 30 minutes, take out cool down i.e. obtain liberate rubber overshoes enclose
Wiping slurry grass green rubber reprocessed by bar slurry.
Owing to have employed technique scheme, compared with prior art, the present invention is by reasonably filtering out applicable group
Point, show that a kind of liberation Foxing strip for rubber shoes slurry reprocesses wiping slurry grass green rubber and preparation method thereof, using this material as rubber erasers energy
Significantly improve the hardness of rubber erasers, improve work efficiency and operation quality.Realize exposing of rubber overshoes upper of a shoe and when rubber cement is reprocessed, do not stay heterochromatic trace
Mark, presentation quality is good, solves defect present in existing liberation rubber overshoes upper foxing slurry rework process.The present invention is the easiest
OK, with low cost, using effect is good.
Detailed description of the invention
Embodiments of the invention 1: wiping slurry grass green rubber reprocessed by liberation Foxing strip for rubber shoes slurry, calculates in parts by weight, it
Including with 2# standard rubber 80 parts, 20 parts of butadiene-styrene rubber, 38 parts of sulfur, vulcanization accelerator 5 parts, superfine active zinc oxide 3 parts, tristearin
Acid 1.8 parts, 1.5 parts of age resistor, high-phenylethylene 48 parts, 190 parts of potter's clay, precipitated calcium carbonate 28 parts, grass green coloring rubber master batch 10 parts,
Calcium grease 2.5 parts and 4.5 parts of 46# machine oil are for preparing raw material；Wherein, every 70 parts of grass greens coloring rubber master batch is by butadiene-styrene rubber 35 parts, stone
2.0 parts of wax, high wear-resistant carbon black 2.0 parts, phthalein dark green 1.0 parts and medium chrome yellow 30 parts composition (taking according to quantity)；Every 5 parts of vulcanization accelerators
It is made up of 1.5 parts of accelerant CZs, 2 parts of altaxs and 1.5 parts of diphenylguanidine S；Every 1.5 parts of age resistor by 1 part of age resistor CD and
0.5 part of age resistor KY-405L composition.
The preparation method wiping slurry grass green rubber reprocessed by liberation Foxing strip for rubber shoes slurry, takes each component by above-mentioned mass fraction,
Comprise the steps:
1) broken-down rubber is prepared: 2# standard rubber and high-phenylethylene are pressed in the banbury that temperature is 100-110 DEG C refining 6-7 divide
Clock, is allowed to be formed mixture, then through opening rubber mixing machine thin logical 6 roads under 0 roll spacing, reel is deposited, and obtains broken-down rubber；
2) preparation of elastomeric compound: broken-down rubber and butadiene-styrene rubber are put in banbury, adds sulfur, vulcanization accelerator, surpasses
Activity zinc oxide, stearic acid and age resistor, under the conditions of temperature 85-100 DEG C, pressure refining 1-1.5 minute, adds potter's clay, lightweight carbon
Acid calcium, grass green coloring rubber master batch, calcium grease and 46# machine oil, refine 3-4 minute, by mixed material in opening rubber mixing machine, in 4-
Turn refining under 5mm roll spacing 8-9 road, refining to smooth surface, and tabletting is deposited, and must liberate Foxing strip for rubber shoes slurry and reprocess wiping slurry grass green
Rubber mixed；
3) preparation wiping slurry grass green rubber reprocessed by liberation Foxing strip for rubber shoes slurry: liberation Foxing strip for rubber shoes slurry is reprocessed wiping slurry and uses
Rubber mixed thickness 5-6mm, width 18-20mm, the length 50-55mmm sheet rubber of being pressed on calender of grass green, natural
It is cooled to room temperature, vulcanizes 30 minutes under liberation rubber overshoes hot-air steam cure process conditions, take out to cool down i.e. to obtain and liberate Foxing strip for rubber shoes slurry
Reprocess wiping slurry grass green rubber；Described liberation rubber overshoes hot-air steam cure technique is, uses vulcanizing tank to carry out free vulcanization, sulfuration
During, within first 15 minutes, use hot air, within latter 15 minutes, use saturated vapor and hot-air Hybrid Heating.
Embodiments of the invention 2: wiping slurry grass green rubber reprocessed by liberation Foxing strip for rubber shoes slurry, calculates in parts by weight, it
Including with 2# standard rubber 82 parts, 18 parts of butadiene-styrene rubber, 40 parts of sulfur, vulcanization accelerator 5 parts, superfine active zinc oxide 3 parts, tristearin
Acid 1.8 parts, 1.5 parts of age resistor, high-phenylethylene 48 parts, 190 parts of potter's clay, precipitated calcium carbonate 25 parts, grass green coloring rubber master batch 10 parts,
Calcium grease 2.0 parts and 4.5 parts of 46# machine oil are for preparing raw material；Wherein, every 70 parts of grass greens coloring rubber master batch is by butadiene-styrene rubber 35 parts, stone
2.0 parts of wax, high wear-resistant carbon black 2.0 parts, phthalein dark green 1.0 parts and medium chrome yellow 30 parts composition (taking according to quantity)；Every 5 parts of vulcanization accelerators
It is made up of 1.5 parts of accelerant CZs, 2 parts of altaxs and 1.5 parts of diphenylguanidine S；Every 1.5 parts of age resistor by 1 part of age resistor CD and
0.5 part of age resistor KY-405L composition.
Preparation method is with embodiment 1.
Claims (7)
1. wiping slurry grass green rubber reprocessed by a liberation Foxing strip for rubber shoes slurry, it is characterised in that: calculating in parts by weight, it includes
With 2# standard rubber 75-85 part, butadiene-styrene rubber 15-25 part, sulfur 35-40 part, vulcanization accelerator 4.5-5.5 part, superfine active oxygen
Change zinc 2.5-3.5 part, stearic acid 1.5-2.0 part, age resistor 1-2 part, high-phenylethylene 46-50 part, potter's clay 180-200 part, lightweight
Calcium carbonate 25-30 part and grass green coloring rubber master batch 9-11 part are for preparing raw material.
Wiping slurry grass green rubber reprocessed by liberation Foxing strip for rubber shoes the most according to claim 1 slurry, it is characterised in that: it includes
With 2# standard rubber 80 parts, 20 parts of butadiene-styrene rubber, 38 parts of sulfur, vulcanization accelerator 5 parts, superfine active zinc oxide 3 parts, stearic acid
1.8 parts, 1.5 parts of age resistor, high-phenylethylene 48 parts, 190 parts of potter's clay, precipitated calcium carbonate 28 parts and grass green coloring rubber master batch 10 parts are
Prepare raw material.
Wiping slurry grass green rubber reprocessed by liberation Foxing strip for rubber shoes the most according to claim 1 and 2 slurry, it is characterised in that: also
Bag calcium grease 2-3 part and 46# machine oil 4-5 part.
Wiping slurry grass green rubber reprocessed by liberation Foxing strip for rubber shoes the most according to claim 1 and 2 slurry, it is characterised in that: every
70 parts of grass green coloring rubber master batch are by butadiene-styrene rubber 35 parts, 2.0 parts of paraffin, high wear-resistant carbon black 2.0 parts, phthalein dark green 1.0 parts and medium chrome yellow
30 parts of compositions；Every 5 parts of vulcanization accelerators are made up of 1.5 parts of accelerant CZs, 2 parts of altaxs and 1.5 parts of diphenylguanidine S；Every 1.5
Part age resistor is made up of 1 part of age resistor CD and 0.5 part of age resistor KY-405L.
5. the preparation method wiping slurry grass green rubber reprocessed by liberation Foxing strip for rubber shoes as claimed in claim 1 or 2 slurry, its
It is characterised by: take each component by above-mentioned mass fraction, comprise the steps:
1) broken-down rubber is prepared: 2# standard rubber and high-phenylethylene are pressed refining 6-7 minute in the banbury that temperature is 100-110 DEG C,
It is allowed to be formed mixture, then through opening rubber mixing machine thin logical 6 roads under 0 roll spacing, reel is deposited, and obtains broken-down rubber；
2) preparation of elastomeric compound: broken-down rubber and butadiene-styrene rubber are put in banbury, adds sulfur, vulcanization accelerator, ultra-fine work
Property zinc oxide, stearic acid and age resistor, pressure refining 1-1.5 minute under the conditions of temperature 85-100 DEG C, add potter's clay, precipitated calcium carbonate
And grass green coloring rubber master batch, refine 3-4 minute, by mixed material in opening rubber mixing machine, turn refining under 4-5mm roll spacing 8-9 road,
Refining is to smooth surface, and tabletting is deposited, and must liberate Foxing strip for rubber shoes slurry and reprocess that to wipe slurry grass green rubber mixed；
3) preparation wiping slurry grass green rubber reprocessed by liberation Foxing strip for rubber shoes slurry: liberation Foxing strip for rubber shoes slurry is reprocessed wiping slurry with grass green
Color is rubber mixed is pressed into thickness 5-6mm, width 18-20mm, length 50-55mmm sheet rubber, natural cooling on calender
To room temperature, vulcanize 30 minutes under liberation rubber overshoes hot-air steam cure process conditions, take out cool down and i.e. obtain liberation Foxing strip for rubber shoes and starch and reprocess
Wipe slurry grass green rubber.
Preparation method the most according to claim 5, it is characterised in that: in step 2) described in when preparing elastomeric compound, add
Calcium grease 2-3 part and 46# machine oil 4-5 part.
Preparation method the most according to claim 5, it is characterised in that: step 3) described in liberation rubber overshoes hot-air steam cure technique
It is to use vulcanizing tank to carry out free vulcanization, in sulfidation, within first 15 minutes, uses hot air, within latter 15 minutes, use saturated
Water vapour and hot-air Hybrid Heating.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610713024.0A CN106220909A (en) | 2016-08-24 | 2016-08-24 | Wiping slurry grass green rubber and preparation method thereof reprocessed by liberation Foxing strip for rubber shoes slurry |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610713024.0A CN106220909A (en) | 2016-08-24 | 2016-08-24 | Wiping slurry grass green rubber and preparation method thereof reprocessed by liberation Foxing strip for rubber shoes slurry |
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| Publication Number | Publication Date |
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| CN106220909A true CN106220909A (en) | 2016-12-14 |
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| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN112143411A (en) * | 2020-09-29 | 2020-12-29 | 际华三五三七有限责任公司 | Cloth brushing aqueous adhesive cement for folding grass-color heel strip cloth of rubber shoes and preparation method thereof |
Citations (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102952297A (en) * | 2012-10-15 | 2013-03-06 | 广州市邦尔福鞋材有限公司 | Double-hardness sole and making method thereof |
| CN104311900A (en) * | 2014-10-30 | 2015-01-28 | 际华三五三七制鞋有限责任公司 | Calendering grass green rubber foxing adhesive for wear-resistant liberation shoes as well as preparation method and application thereof |
| CN104387624A (en) * | 2014-10-30 | 2015-03-04 | 际华三五三七制鞋有限责任公司 | Calendered leaf-yellow rubber strip surrounding rubber for wear-resisting liberation shoes as well as preparation method and application of calendered leaf-yellow rubber strip surrounding rubber |
| CN104448442A (en) * | 2014-11-26 | 2015-03-25 | 青岛崂乡茶制品有限公司 | High-hardness wear-resistant rubber shoe sole |
| CN105037850A (en) * | 2015-07-23 | 2015-11-11 | 易宝（福建）高分子材料股份公司 | Butadiene styrene rubber, natural rubber and high-styrene resin combined obturator secondary foaming material and preparing method thereof |
| CN105131362A (en) * | 2015-10-09 | 2015-12-09 | 际华三五三七制鞋有限责任公司 | Wear-resisting folding-resisting type inter-steam vulcanization black covering strip rubber for shoes and preparation method and application of wear-resisting folding-resisting type inter-steam vulcanization black covering strip rubber |
| CN105131360A (en) * | 2015-10-09 | 2015-12-09 | 际华三五三七制鞋有限责任公司 | Wear-resisting folding-resisting type black covering strip rubber for shoes and preparation method and application of wear-resisting folding-resisting type black covering strip rubber |
-
2016
- 2016-08-24 CN CN201610713024.0A patent/CN106220909A/en active Pending
Patent Citations (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102952297A (en) * | 2012-10-15 | 2013-03-06 | 广州市邦尔福鞋材有限公司 | Double-hardness sole and making method thereof |
| CN104311900A (en) * | 2014-10-30 | 2015-01-28 | 际华三五三七制鞋有限责任公司 | Calendering grass green rubber foxing adhesive for wear-resistant liberation shoes as well as preparation method and application thereof |
| CN104387624A (en) * | 2014-10-30 | 2015-03-04 | 际华三五三七制鞋有限责任公司 | Calendered leaf-yellow rubber strip surrounding rubber for wear-resisting liberation shoes as well as preparation method and application of calendered leaf-yellow rubber strip surrounding rubber |
| CN104448442A (en) * | 2014-11-26 | 2015-03-25 | 青岛崂乡茶制品有限公司 | High-hardness wear-resistant rubber shoe sole |
| CN105037850A (en) * | 2015-07-23 | 2015-11-11 | 易宝（福建）高分子材料股份公司 | Butadiene styrene rubber, natural rubber and high-styrene resin combined obturator secondary foaming material and preparing method thereof |
| CN105131362A (en) * | 2015-10-09 | 2015-12-09 | 际华三五三七制鞋有限责任公司 | Wear-resisting folding-resisting type inter-steam vulcanization black covering strip rubber for shoes and preparation method and application of wear-resisting folding-resisting type inter-steam vulcanization black covering strip rubber |
| CN105131360A (en) * | 2015-10-09 | 2015-12-09 | 际华三五三七制鞋有限责任公司 | Wear-resisting folding-resisting type black covering strip rubber for shoes and preparation method and application of wear-resisting folding-resisting type black covering strip rubber |
Non-Patent Citations (2)
| Title |
|---|
| 王梦姣、龚怀耀、薛广智: "《橡胶工业手册 第二分册 配合剂》", 31 October 1989 * |
| 约翰 S. 迪克: "《提高橡胶胶料性能实用方案1500例》", 31 March 2013 * |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN112143411A (en) * | 2020-09-29 | 2020-12-29 | 际华三五三七有限责任公司 | Cloth brushing aqueous adhesive cement for folding grass-color heel strip cloth of rubber shoes and preparation method thereof |
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