CN106220310A - Water soluble composite fertilizer calcium boron suspending agent and preparation method thereof - Google Patents
Water soluble composite fertilizer calcium boron suspending agent and preparation method thereof Download PDFInfo
- Publication number
- CN106220310A CN106220310A CN201610549281.5A CN201610549281A CN106220310A CN 106220310 A CN106220310 A CN 106220310A CN 201610549281 A CN201610549281 A CN 201610549281A CN 106220310 A CN106220310 A CN 106220310A
- Authority
- CN
- China
- Prior art keywords
- calcium
- boron
- water
- composite fertilizer
- water soluble
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C05—FERTILISERS; MANUFACTURE THEREOF
- C05G—MIXTURES OF FERTILISERS COVERED INDIVIDUALLY BY DIFFERENT SUBCLASSES OF CLASS C05; MIXTURES OF ONE OR MORE FERTILISERS WITH MATERIALS NOT HAVING A SPECIFIC FERTILISING ACTIVITY, e.g. PESTICIDES, SOIL-CONDITIONERS, WETTING AGENTS; FERTILISERS CHARACTERISED BY THEIR FORM
- C05G5/00—Fertilisers characterised by their form
- C05G5/20—Liquid fertilisers
- C05G5/27—Dispersions, e.g. suspensions or emulsions
-
- C—CHEMISTRY; METALLURGY
- C05—FERTILISERS; MANUFACTURE THEREOF
- C05C—NITROGENOUS FERTILISERS
- C05C5/00—Fertilisers containing other nitrates
- C05C5/04—Fertilisers containing other nitrates containing calcium nitrate
-
- C—CHEMISTRY; METALLURGY
- C05—FERTILISERS; MANUFACTURE THEREOF
- C05D—INORGANIC FERTILISERS NOT COVERED BY SUBCLASSES C05B, C05C; FERTILISERS PRODUCING CARBON DIOXIDE
- C05D3/00—Calcareous fertilisers
-
- C—CHEMISTRY; METALLURGY
- C05—FERTILISERS; MANUFACTURE THEREOF
- C05G—MIXTURES OF FERTILISERS COVERED INDIVIDUALLY BY DIFFERENT SUBCLASSES OF CLASS C05; MIXTURES OF ONE OR MORE FERTILISERS WITH MATERIALS NOT HAVING A SPECIFIC FERTILISING ACTIVITY, e.g. PESTICIDES, SOIL-CONDITIONERS, WETTING AGENTS; FERTILISERS CHARACTERISED BY THEIR FORM
- C05G3/00—Mixtures of one or more fertilisers with additives not having a specially fertilising activity
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Life Sciences & Earth Sciences (AREA)
- Pest Control & Pesticides (AREA)
- Dispersion Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Inorganic Chemistry (AREA)
- Fertilizers (AREA)
Abstract
The present invention provides a kind of water soluble composite fertilizer calcium boron suspending agent, its component includes Calcium pyroborate, wetting agent, antifreezing agent, dispersant, defoamer, thickening agent and water, wherein, in described water soluble composite fertilizer calcium boron suspending agent, the mass volume ratio concentration of calcium constituent is 120 g/L～the mass volume ratio concentration of 230 g/L, described boron element is 10 g/L～40 g/L.The present invention also provides for the preparation method of a kind of above-mentioned water soluble composite fertilizer calcium boron suspending agent, and including mixing and high shear whipping step, described preparation method step is simple.The above-mentioned water soluble composite fertilizer calcium boron suspending agent that the present inventor provides has that dissolution velocity is fast, stability and dispersive property is good, active component content is high, calcium Boron contents is adjustable, the advantage of hot storage cold storage stable performance, has and replenishes the calcium, mends that boron speed is fast, fertilizer amount is little, plant absorption is effective and advantages of environment protection.
Description
Technical field
The present invention relates to technical field of fertilizers, specifically, relate to a kind of water soluble composite fertilizer calcium boron suspending agent and
Preparation method.
Background technology
Growth stage desired nutritional each to multiple kinds of crops and disease research and analyse display, and middle trace element deficiency causes
Nutritional deficiency disease especially pronounced in crops Diseases at Medium-late Growth.Crops nourish and grow progressively transfer reproductive growth to during right
Calcium, the demand of boron increase.Due to the mistake in understanding or think little of, in soil available calcium constituent and boron element lack because of
This is to improving crop yield and quality impacts.Calcium in plant has several functions, such as the tune to biological membrane permeability
Joint function, calcium is relevant with the formation of cell wall；Boron is trace element respectfully, and the content in plant is little, but boron element
Cell elongation and histo-differentiation, participation carbohydrate transport and protein metabolism, promotion root growth and flower can be promoted
Powder is sprouted and pollen tube growth, can improve crop anti-adversity and resistance against diseases.
Present stage, the lime application mode of China's vast fruit and vegetables plant husbandry in traditional soil application mode is still
Main, mainly use calcareous fertilisers based on calcium magnesium phosphate, calcium superphosphate, Calx, Gypsum Fibrosum.And using at boron fertilizer is the most just to be subject to
Plantation family is paid close attention to, and uses based on Borax.Owing to the mode of application process many employings soil application is used.Soil application method by
In absorbing slowly, absorbing incomplete reason, it is adaptable to the prevention element such as calcium, boron lacks.And consumption and assimilation effect are difficult to hold
Easily cause again proportional imbalance and the waste of various element, even cause soil compaction and crop failure.By the time crop because of calcium deficiency,
When pathological changes occurs in boron deficiency, the most arrive the more serious degree of ratio, the most only carried out water-soluble drip irrigation and foliage applying could be effectively
Control.Water-fertilizer integral and foliage-spray are main with calcium nitrate, calcium chloride and four water eight sodium borate, but the two mixture content is slightly
High easily crystallization, precipitation, become the white solid being insoluble in water, cause both quickly to be absorbed by crops, very
To because of the large particulate matter generated, it will cause blocking water-fertilizer integral pipeline, cause serious consequence.
In order to solve with present on problem, people are seeking a kind of preferably technical solution always.
Summary of the invention
It is an object of the invention to for the deficiencies in the prior art, thus a kind of high-load, environment-friendly type, easily absorption, profit are provided
High by rate and use step to save time, labour-saving water soluble composite fertilizer calcium boron suspending agent and preparation method thereof.
To achieve these goals, the technical solution adopted in the present invention is: a kind of water soluble composite fertilizer calcium boron suspending agent,
Its component includes Calcium pyroborate, wetting agent, antifreezing agent, dispersant, defoamer, thickening agent and water, wherein, multiple at described water solublity
In the calcium boron suspending agent of Hefei, the mass volume ratio concentration of calcium constituent is 120 g/L～230 g/L, the mass body of described boron element
Long-pending specific concentration is 10 g/L～40 g/L.
Based on above-mentioned, the mass percent of described wetting agent is 1%～7%, the mass percent of described antifreezing agent be 1%～
5%, the mass percent of described dispersant be 4%～10%, the mass percent of described defoamer be 0.1%～1.0%, described increasing
The mass percent of thick dose is 0.1%～2.0%, the mass percent of described water is 15%～25%.
Based on above-mentioned, described calcium constituent is from water-soluble Ca salt, and described water-soluble Ca salt includes calcium chloride, calcium nitrate, second
The combination of one or more in acid calcium, calcium formate, calcium oxide.
Based on above-mentioned, described boron element is from water-soluble borate, and described water-soluble borate includes sodium borate, boric acid
The combination of one or more in potassium, four water eight sodium borate, four water eight potassium borates, ammonium borate, boric acid.
Based on above-mentioned, described wetting agent includes nonyl phenol ethoxy compound, phenethyl phenol polyethenoxy ether condensation substance, alkane
Base phenol polyethenoxy ether formaldehyde condensation products, phenethyl phenol polyethenoxy ether sodium sulfate, alkylphenol-polyethenoxy base sodium sulfate, polyoxy
Vinyl alkyl 2, 2-Oxydiphenol, polyoxyethylene aliphatic alcohol ether, polyoxyethylene polyoxypropylene block alkyl sodium sulfate, sodium alkyl benzene sulfonate, alkane
The combination of one or more in base sodium phosphate copolymer.
Based on above-mentioned, described dispersant includes fatty acid polyethylene glycol ester, fatty alcohol ether phosphate ester, nonyl phenol ether phosphoric acid
Ester, fatty alcohol ether succinic acid half ester sodium sulfonate, naphthalenesulfonic acid-formaldehyde condensate, nonyl phenolic ester succinic acid half ester sodium sulfonate, 12
Alkyl sodium sulfate, dialkyl napthalene sulfonic acids sodium, sodium lignin sulfonate, sulfomethylated lignin acid amide, Negel formaldehyde condensation products, benzene
Ethyl phenol polyoxyethylene ether formaldehyde condensation products, triethyl group hexyl phosphoric acid, methyl anyl alcohol, cellulose derivative, polyacrylamide, poly-
The combination of one or more in oxygen ethylene polyoxypropylene block copolymers.
Based on above-mentioned, described antifreezing agent include be ethylene glycol, propylene glycol, glycerol, Polyethylene Glycol, Ethylene glycol methyl ether,
The combination of one or more in mannitol, Sorbitol.
Based on above-mentioned, described defoamer includes that organosilicon, propylene glycol, oleic acid, sec-butyl alcohol, tributyl phosphate, tricresyl phosphate are pungent
The combination of one or more in ester, polyoxyethylene carboxylate, polypropylene glycol and derivant thereof.
Based on above-mentioned, described thickening agent includes xanthan gum, carrageenan, guar gum, carboxymethyl cellulose, hydroxy ethyl fiber
The combination of one or more in element, methylcellulose, polyvinyl acetate.
The present invention also provides for the preparation method of a kind of water soluble composite fertilizer calcium boron suspending agent, and it comprises the following steps: at height
Under the conditions of speed shear agitation, according to the component of above-mentioned mass fraction, first water-soluble Ca salt or water-soluble borate are dissolved in
Basis of formation solution in water；Then in described base soln, wetting agent, antifreezing agent, dispersant, defoamer it are separately added at a high speed
Shear agitation forms mixed solution；Secondly in described mixing, it is slowly added to described water-soluble borate or water-soluble Ca salt high speed
Shear agitation prepares stable water soluble Calcium pyroborate solution；The most backward described stable water soluble Calcium pyroborate solution adds thickening agent high
Speed shear agitation prepares stable described water soluble composite fertilizer calcium boron suspending agent.
Wherein, in the preparation method of described water soluble composite fertilizer calcium boron suspending agent, the step that described high shear agitation processes
Suddenly using high speed shearing homogenizing device to carry out, the minimum speed of its main shaft should be not less than 4000 rev/min.Reaction produces
Calcium pyroborate by high shear agitation process be dispersed as molecule, in combination with described wetting agent, described antifreezing agent, institute
State the medicament such as dispersant, described defoamer so that the Calcium pyroborate of molecule preferably disperses in aqueous, thus be prepared
Compound fertilizer's calcium boron suspending agent that good stability, water solublity are good creates condition.
Hinge structure of the present invention has prominent substantive distinguishing features and significantly progress, and specifically, the present invention is former
Water-soluble Ca salt and water-soluble boron salt in material are respectively provided with good water solublity, wetting agent, antifreezing agent, dispersant, defoamer, increasing
Thick dose is environment-friendly type medicament, uses rear farmland residual quantity less；Meanwhile, the high speed in preparation method provided by the present invention is cut
Cutting stir process, the Calcium pyroborate that reaction can be made to produce is dispersed as molecule, thus ensure that described water soluble composite fertilizer
Calcium boron suspending agent has that dissolution velocity is fast, dispersive property good；Other method, this water soluble composite fertilizer calcium boron suspending agent also has work
Property constituent content is high, calcium Boron contents is adjustable, hot storage cold storage stable performance, replenish the calcium that boron speed is fast, fertilizer amount is little, assimilation effect
Get well and advantages of environment protection, and apply this water soluble composite fertilizer calcium boron suspending agent as the melon and fruit good looking appearance of fertilizer.
Detailed description of the invention
Below by detailed description of the invention, technical scheme is described in further detail.
Embodiment 1
The present embodiment provides a kind of water soluble composite fertilizer calcium boron suspending agent, and it includes the component of following mass percent: phenethyl
Phenol polyethenoxy etherate 4%, fatty alcohol ether succinic acid half ester sodium sulfonate 2.7%, dialkyl napthalene sulfonic acids sodium 2%, Polyethylene Glycol
1.4%, tributyl phosphate 0.6%, sodium carboxymethyl cellulose 0.2%, water 15%, calcium nitrate 70.9%, four water eight sodium borate 3.2%, and
The mass volume ratio concentration of effective calcium of described water soluble composite fertilizer calcium boron suspending agent is 200 g/L, the quality volume of effective boron
Specific concentration is 10 g/L.
The present embodiment also provides for the preparation method of a kind of above-mentioned water soluble composite fertilizer calcium boron suspending agent, specifically includes following step
Rapid:
Weigh the calcium nitrate of above-mentioned mass percent, phenethyl phenol polyethenoxy etherate, fatty alcohol ether succinic acid half respectively
Ester sodium sulfonate, dialkyl napthalene sulfonic acids sodium, Polyethylene Glycol, tributyl phosphate and water, mix above-mentioned raw materials and to pour high shear into equal
Change device to be stirred, whipping process be slowly added into four water eight sodium borate of described mass percent, stir to equal phase time again to
The sodium carboxymethyl cellulose wherein adding described mass percent is sufficiently stirred for.Stirring pours stirring gained solution into sand after terminating
Grinding machine carries out sand milling and prepares described water soluble composite fertilizer calcium boron suspending agent.
Use EDTA volumetric method to the present embodiment prepare described water soluble composite fertilizer calcium boron suspending agent composition in effective
Calcium content and effective boron content detect, and result shows: the quality of effective calcium of described water soluble composite fertilizer calcium boron suspending agent
Volume by volume concentration is 200 g/L, the mass volume ratio concentration of effective boron is 10 g/L, and the most after testing, the pH value of this product is
6.5, topple over rear residue < 2%, residual special < 0.01% after washing；And enter water 1～molten clear, acceleration heat storage in 2 minutes and add quickly cooling storage
Qualified stability.In actual applications for preventing and treating the grape berry crack caused because of Fructus Vitis viniferae calcium deficiency and because what boron deficiency disease caused falls in a large number
The diseases such as flower bud, young sprout top tendril dry up, used at calcium deficiency, boron deficiency initial stage, and fertilizer application amount is every liter of water consumption 0.5 mL～1 mL
Carrying out foliar spray, prevention effect is 85%～90%.
Embodiment 2
The present embodiment provides a kind of water soluble composite fertilizer calcium boron suspending agent, and it includes the component of following mass percent: nonyl phenol
Ethoxy compound 4%, alkyl phosphoric acid sodium 2%, phenethyl phenol polyethenoxy ether formaldehyde condensation products 5%, Polyethylene Glycol 2%, propylene glycol
1%, sodium hydroxyethyl cellulose 0.35%, water 15.15%, calcium chloride dihydrate 45.5%, sodium borate 25%, and described water soluble composite fertilizer
The mass volume ratio concentration of effective calcium of calcium boron suspending agent is 182 g/L, the mass volume ratio concentration of effective boron is 21 g/L.
A kind of water soluble composite fertilizer calcium boron suspending agent preparation method that the present embodiment is provided is with the preparation side in embodiment 1
Method.
Use EDTA volumetric method to the present embodiment prepare described water soluble composite fertilizer calcium boron suspending agent composition in effective
Calcium content and effective boron content detect, and result shows the mass body of effective calcium of described water soluble composite fertilizer calcium boron suspending agent
Long-pending specific concentration is 182 g/L, the mass volume ratio concentration of effective boron is 21 g/L, and the most after testing, the pH value of this product is
6.8, topple over rear residue < 2%, residual special < 0.01% after washing；And enter water 1-2 minute molten clear, accelerate heat storage and to add quickly cooling storage steady
Qualitative qualified.Sick because of water core, the pox spots of the appearance of Fructus Mali pumilae calcium deficiency for preventing and treating in actual applications；And the contracting caused because of boron deficiency
Fruit disease, and use at calcium deficiency, boron deficiency initial stage, fertilizer application amount is every liter of water consumption 0.5 mL～1 mL carries out foliar spray, preventing and treating effect
Fruit is 85%～90%.
Embodiment 3
The present embodiment provides a kind of water soluble composite fertilizer calcium boron suspending agent, and it includes the component of following mass percent: nonyl phenol
Ethoxy compound 3.5%, nonyl phenol ether phosphate 3%, sodium lignin sulfonate 1.1% part, glycerol 1.12%, organosilicon 0.58%,
Xanthan gum 0.1%, water 20%, calcium nitrate 62.2%, four water eight sodium borate 8.4%, and described water soluble composite fertilizer calcium boron suspending agent
The mass volume ratio concentration of effective calcium is 201 g/L, the mass volume ratio concentration of effective boron is 10 g/L.
A kind of water soluble composite fertilizer calcium boron suspending agent preparation method that the present embodiment is provided is with the preparation side in embodiment 1
Method.
Use EDTA volumetric method to the present embodiment prepare described water soluble composite fertilizer calcium boron suspending agent composition in effective
Calcium content and effective boron content detect, and result shows the mass body of effective calcium of described water soluble composite fertilizer calcium boron suspending agent
Long-pending specific concentration is 201 g/L, the mass volume ratio concentration of effective boron is 10 g/L, and the most after testing, the pH value of this product is
6.6, topple over rear residue < 2%, residual special < 0.01% after washing；And enter water 1-2 minute molten clear, accelerate heat storage and to add quickly cooling storage steady
Qualitative qualified.It is used for dehiscent fruit, leaf margin die back disease that preventing and treating occurs because of Citrullus vulgaris calcium deficiency in actual applications；And because boron deficiency causes
Fruit-shrink disease, and use at calcium deficiency, boron deficiency initial stage, fertilizer application amount is every liter of water consumption 0.5 mL～1 mL carries out foliar spray, preventing and treating
Effect is 85%～90%.
Embodiment 4
The present embodiment provides a kind of water soluble composite fertilizer calcium boron suspending agent, and it includes the component of following mass percent: nonyl phenol
Ethoxy compound 4%, fatty alcohol ether succinic acid half ester sodium sulfonate 2.7%, sodium lignin sulfonate 2%, Polyethylene Glycol 1.4%, the third two
Alcohol 0.7%, carrageenan 0.1%, water 15.1%, calcium nitrate 64.3%, four water eight sodium borate 9.7%, and described water soluble composite fertilizer calcium boron
The mass volume ratio concentration of effective calcium of suspending agent is 160 g/L, the mass volume ratio concentration of effective boron is 31 g/L.
A kind of water soluble composite fertilizer calcium boron suspending agent preparation method that the present embodiment is provided is with the preparation side in embodiment 1
Method.
Use EDTA volumetric method to the present embodiment prepare described water soluble composite fertilizer calcium boron suspending agent composition in effective
Calcium content and effective boron content detect, and result shows the mass body of effective calcium of described water soluble composite fertilizer calcium boron suspending agent
Long-pending specific concentration is 160 g/L, the mass volume ratio concentration of effective boron is 31 g/L, and the most after testing, the pH value of this product is
6.7, topple over rear residue < 2%, residual special < 0.01% after washing；And enter water 1-2 minute molten clear, accelerate heat storage and to add quickly cooling storage steady
Qualitative qualified.The Fructus Lycopersici esculenti blossom-end rot occurred because of Fructus Lycopersici esculenti calcium deficiency for preventing and treating in actual applications；And the growth caused because of boron deficiency
Point necrosis, and use at calcium deficiency, boron deficiency initial stage, fertilizer application amount is every liter of water consumption 0.5 mL～1 mL carries out foliar spray, preventing and treating
Effect is 85%～90%.
Embodiment 5
The present embodiment provides a kind of water soluble composite fertilizer calcium boron suspending agent, and it includes the component of following mass percent: phenethyl
Phenol polyethenoxy etherate 3.7%, nonyl phenolic ester succinic acid half ester sodium sulfonate 3.5% part, fatty alcohol ether phosphate ester 2%, ethylene glycol
1.2%, organosilicon 0.6%, sodium carboxymethyl cellulose 0.25% part, water 20%, calcium chloride dihydrate 36.42%, ten water sodium borate
32.33%, and the mass volume ratio concentration of effective calcium of described water soluble composite fertilizer calcium boron suspending agent be 161 g/L, effective boron
Mass volume ratio concentration is 30 g/L.
A kind of water soluble composite fertilizer calcium boron suspending agent preparation method that the present embodiment is provided is with the preparation side in embodiment 1
Method.
Use EDTA volumetric method to the present embodiment prepare described water soluble composite fertilizer calcium boron suspending agent composition in effective
Calcium content and effective boron content detect, and result shows the mass body of effective calcium of described water soluble composite fertilizer calcium boron suspending agent
Long-pending specific concentration is 161 g/L, the mass volume ratio concentration of effective boron is 30 g/L, and the most after testing, the pH value of this product is
6.8, topple over rear residue < 2%, residual special < 0.01% after washing；And enter water 1-2 minute molten clear, accelerate heat storage and to add quickly cooling storage steady
Qualitative qualified.The Fructus Lycopersici esculenti blossom-end rot occurred because of Fructus Solani melongenae calcium deficiency for preventing and treating in actual applications；And the growth caused because of boron deficiency
Point necrosis, and use at calcium deficiency, boron deficiency initial stage, fertilizer application amount is every liter of water consumption 0.5 mL～1 mL carries out foliar spray, preventing and treating
Effect is 85%～90%.
Embodiment 6
The present embodiment provides a kind of water soluble composite fertilizer calcium boron suspending agent, and it includes the component of following mass percent: nonyl phenol
Ethoxy compound 3%, fatty alcohol ether succinic acid half ester sodium sulfonate 3.4%, sodium lignin sulfonate 2%, Polyethylene Glycol 1.2%, second two
Alcohol 0.6%, tributyl phosphate 0.6%, xanthan gum 0.1%, water 20%, calcium chloride dihydrate 35%, ten water sodium borate 31.2% and four water eight
Sodium borate 2.9%, and the mass volume ratio concentration of effective calcium of described water soluble composite fertilizer calcium boron suspending agent is 161 g/L, effectively
The mass volume ratio concentration of boron is 40 g/L.
A kind of water soluble composite fertilizer calcium boron suspending agent preparation method that the present embodiment is provided is with the preparation side in embodiment 1
Method.
Use EDTA volumetric method to the present embodiment prepare described water soluble composite fertilizer calcium boron suspending agent composition in effective
Calcium content and effective boron content detect, and result shows the mass body of effective calcium of described water soluble composite fertilizer calcium boron suspending agent
Long-pending specific concentration is 161 g/L, the mass volume ratio concentration of effective boron is 40 g/L, and the most after testing, the pH value of this product is
7.1, topple over rear residue < 2%, residual special < 0.01% after washing；And enter water 1-2 minute molten clear, accelerate heat storage and to add quickly cooling storage steady
Qualitative qualified.The Fructus Capsici blossom-end rot occurred because of Fructus Capsici calcium deficiency for preventing and treating in actual applications；And the sarcocarp caused because of boron deficiency
Suberification, and use at calcium deficiency, boron deficiency initial stage, fertilizer application amount is every liter of water consumption 0.5 mL～1 mL carries out foliar spray, preventing and treating
Effect is 85%～90%.
Finally should be noted that: above example is only in order to illustrate that technical scheme is not intended to limit；To the greatest extent
The present invention has been described in detail by pipe with reference to preferred embodiment, and those of ordinary skill in the field are it is understood that still
The detailed description of the invention of the present invention can be modified or portion of techniques feature is carried out equivalent；Without deviating from this
The spirit of bright technical scheme, it all should be contained in the middle of the technical scheme scope that the present invention is claimed.
Claims (10)
1. a water soluble composite fertilizer calcium boron suspending agent, it is characterised in that its component include Calcium pyroborate, wetting agent, antifreezing agent,
Dispersant, defoamer, thickening agent and water, wherein, in described water soluble composite fertilizer calcium boron suspending agent, the quality volume of calcium constituent
Specific concentration is 120 g/L～the mass volume ratio concentration of 230 g/L, described boron element is 10 g/L～40 g/L.
Water soluble composite fertilizer calcium boron suspending agent the most according to claim 1, it is characterised in that the quality hundred of described wetting agent
Mark is 1%～7%, the mass percent of described antifreezing agent is 1%～5%, the mass percent of described dispersant is 4%～10%,
The mass percent of described defoamer is 0.1%～1.0%, the mass percent of described thickening agent is 0.1%～2.0%, described water
Mass percent be 15%～25%.
Water soluble composite fertilizer calcium boron suspending agent the most according to claim 2, it is characterised in that described calcium constituent is from water-soluble
Property calcium salt, described water-soluble Ca salt includes the group of one or more in calcium chloride, calcium nitrate, calcium acetate, calcium formate, calcium oxide
Close.
4. according to the water soluble composite fertilizer calcium boron suspending agent described in Claims 2 or 3, it is characterised in that described boron element from
Water-soluble borate, described water-soluble borate includes sodium borate, potassium borate, four water eight sodium borate, four water eight potassium borates, boric acid
The combination of one or more in ammonium, boric acid.
Water soluble composite fertilizer calcium boron suspending agent the most according to claim 4, it is characterised in that described wetting agent includes nonyl
Phenol ethoxy compound, phenethyl phenol polyethenoxy ether condensation substance, alkylphenol polyoxyethylene formaldehyde condensation products, phenethyl phenol are poly-
Oxygen vinyl Ether sodium sulfate, alkylphenol-polyethenoxy base sodium sulfate, polyoxyethylated alkyl phenol, polyoxyethylene aliphatic alcohol ether, polyoxy
The combination of one or more in ethylene oxypropylene block alkyl sodium sulfate, sodium alkyl benzene sulfonate, alkyl phosphoric acid sodium copolymer.
Water soluble composite fertilizer calcium boron suspending agent the most according to claim 5, it is characterised in that described dispersant includes fat
Acid polyethylene glycol ester, fatty alcohol ether phosphate ester, nonyl phenol ether phosphate, fatty alcohol ether succinic acid half ester sodium sulfonate, sodium naphthalene sulfonate
Formaldehyde condensation products, nonyl phenolic ester succinic acid half ester sodium sulfonate, sodium lauryl sulphate, dialkyl napthalene sulfonic acids sodium, lignin sulfonic acid
Sodium, sulfomethylated lignin acid amide, Negel formaldehyde condensation products, phenethyl phenol polyethenoxy ether formaldehyde condensation products, triethyl group are own
One in base phosphoric acid, methyl anyl alcohol, cellulose derivative, polyacrylamide, polyoxyethylene polyoxypropylene block copolymer or
Several combinations.
Water soluble composite fertilizer calcium boron suspending agent the most according to claim 6, it is characterised in that described antifreezing agent includes it being second
The group of one or more in glycol, propylene glycol, glycerol, Polyethylene Glycol, Ethylene glycol methyl ether, mannitol, Sorbitol
Close.
8. according to the water soluble composite fertilizer calcium boron suspending agent described in claim 6 or 7, it is characterised in that described defoamer includes
Organosilicon, propylene glycol, oleic acid, sec-butyl alcohol, tributyl phosphate, trioctyl phosphate, polyoxyethylene carboxylate, polypropylene glycol and
The combination of one or more in derivant.
Water soluble composite fertilizer calcium boron suspending agent the most according to claim 8, it is characterised in that described thickening agent includes xanthan
One in glue, carrageenan, guar gum, carboxymethyl cellulose, hydroxyethyl cellulose, methylcellulose, polyvinyl acetate
Or several combinations.
10. a preparation method for the water soluble composite fertilizer calcium boron suspending agent described in any one of claim 1～9, it include with
Lower step: under high shear agitation conditions, be first dissolved in the water basis of formation by water-soluble Ca salt or water-soluble borate
Solution；Then in described base soln, it is separately added into wetting agent, antifreezing agent, dispersant, the formation of defoamer high shear agitation
Mixed solution；Secondly in described mixing, it is slowly added to described water-soluble borate or water-soluble Ca salt high shear agitation prepares
Stable water soluble Calcium pyroborate solution；The most backward described stable water soluble Calcium pyroborate solution adds thickening agent high shear agitation system
Described water soluble composite fertilizer calcium boron suspending agent that must be stable.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610549281.5A CN106220310A (en) | 2016-07-13 | 2016-07-13 | Water soluble composite fertilizer calcium boron suspending agent and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610549281.5A CN106220310A (en) | 2016-07-13 | 2016-07-13 | Water soluble composite fertilizer calcium boron suspending agent and preparation method thereof |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN106220310A true CN106220310A (en) | 2016-12-14 |
Family
ID=57520245
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201610549281.5A Pending CN106220310A (en) | 2016-07-13 | 2016-07-13 | Water soluble composite fertilizer calcium boron suspending agent and preparation method thereof |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN106220310A (en) |
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN110078558A (en) * | 2019-05-16 | 2019-08-02 | 东北农业大学 | A kind of production method of thixotropic paste compound fertilizer |
| CN111470902A (en) * | 2020-04-17 | 2020-07-31 | 华南农业大学 | High-activity organic calcium boron liquid compound fertilizer and preparation method and application thereof |
| CN111978125A (en) * | 2020-09-28 | 2020-11-24 | 湖北富邦科技股份有限公司 | Nitrogen-free high-calcium water-soluble fertilizer and preparation method thereof |
| CN112225602A (en) * | 2020-10-20 | 2021-01-15 | 青岛埃图农业科技有限公司 | Calcium boronated aminobutyric acid fertilizer and preparation method thereof |
| CN113896592A (en) * | 2021-09-30 | 2022-01-07 | 东莞一翔液体肥料有限公司 | Liquid calcium fertilizer and preparation method and application thereof |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101302129A (en) * | 2008-05-22 | 2008-11-12 | 东莞市施普旺生物科技有限公司 | Calcium hydrophosphate suspending agent |
| CN102180723A (en) * | 2011-05-04 | 2011-09-14 | 陈忠慧 | Calcium-boron compound fertilizer and preparation method thereof |
-
2016
- 2016-07-13 CN CN201610549281.5A patent/CN106220310A/en active Pending
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101302129A (en) * | 2008-05-22 | 2008-11-12 | 东莞市施普旺生物科技有限公司 | Calcium hydrophosphate suspending agent |
| CN102180723A (en) * | 2011-05-04 | 2011-09-14 | 陈忠慧 | Calcium-boron compound fertilizer and preparation method thereof |
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN110078558A (en) * | 2019-05-16 | 2019-08-02 | 东北农业大学 | A kind of production method of thixotropic paste compound fertilizer |
| CN111470902A (en) * | 2020-04-17 | 2020-07-31 | 华南农业大学 | High-activity organic calcium boron liquid compound fertilizer and preparation method and application thereof |
| CN111978125A (en) * | 2020-09-28 | 2020-11-24 | 湖北富邦科技股份有限公司 | Nitrogen-free high-calcium water-soluble fertilizer and preparation method thereof |
| CN112225602A (en) * | 2020-10-20 | 2021-01-15 | 青岛埃图农业科技有限公司 | Calcium boronated aminobutyric acid fertilizer and preparation method thereof |
| CN113896592A (en) * | 2021-09-30 | 2022-01-07 | 东莞一翔液体肥料有限公司 | Liquid calcium fertilizer and preparation method and application thereof |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN106220310A (en) | Water soluble composite fertilizer calcium boron suspending agent and preparation method thereof | |
| CN104261988B (en) | A kind of salt-soda soil special-purpose suspension liquid composite fertilizer and preparation method thereof | |
| CN103641577B (en) | Compound liquid fertilizer with high suspension degree, and preparation method and application thereof | |
| CN101665390B (en) | Suspension type liquid compound fertilizer and preparation method thereof | |
| CN102273484B (en) | Tea-oil tree fruit retention agent and application method thereof | |
| CN105819947A (en) | Energy-saving and environmental-protection organic suspension composite fertilizer and preparation method thereof | |
| CN101913935B (en) | Compound fertilizer special for drip irrigation of cucumber in greenhouse and preparation method thereof | |
| CN101302129B (en) | Calcium hydrophosphate suspending agent | |
| CN107056423A (en) | A kind of sun-proof blade face fluid fertilizer and preparation method thereof | |
| CN101898912A (en) | Compound fertilizer dedicated for trickle irrigation of greenhouse tomato | |
| WO2010057372A1 (en) | Plant nutriment effervescent composition and preparation method thereof | |
| CN101898914A (en) | Special compound fertilizer for drip irrigation on greenhouse grapes and preparation method thereof | |
| CN101823922A (en) | Soil improvement nutrient solution for reducing heavy metal cadmium content of vegetables | |
| CN105016919A (en) | Soil maturation method for saline-alkaline land using pearlite soil subsoiling agent | |
| US20180339948A1 (en) | Microgranular Water-soluble Fertilizer Co-produced from Potassium Nitrate by Tower Melt and Method of Preparing the Same | |
| CN105646040A (en) | Full-nutritional and full-water-soluble drip-irrigation special fertilizer for wine grapes | |
| CN109111287A (en) | A kind of Water-solubility foliar fertilizer and preparation method thereof promoting crop growth | |
| CN104250180A (en) | Grape compound fertilizer with high utilization rate and preparation method thereof | |
| CN106478300B (en) | A kind of acid soil improvement drop cadmium fertilizer reducing cadmium content in rice rice | |
| CN101898913B (en) | Special compound fertilizer for drip irrigation on greenhouse pepper and preparation method thereof | |
| CN101913934B (en) | Compound fertilizer special for drop irrigation of plum trees by facility and preparation method thereof | |
| CN104987222A (en) | Sustained-release synergist for multifunctional synergistic nitrogen fertilizer | |
| CN105272711A (en) | Special efficient fertilizer for shiitake and preparation method thereof | |
| CN108892594A (en) | A kind of plant nutrition liquid enhancing sprigging survival rate | |
| CN106588442A (en) | Special compound fertilizer for drip irrigation of facility long jujubes and preparation method thereof |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| CB02 | Change of applicant information | ||
| CB02 | Change of applicant information |
Address after: 463300 Henan Province Zhumadian Runan County Industrial Park Runan heerfeng fluid fertilizer Co.,Ltd. Applicant after: RUNAN HEERFENG FLUID FERTILIZER CO.,LTD. Address before: Zhumadian City, Henan province 463300 Ru'nan County Industrial Park, Ru'nan Wo Fung Fluid Fertilizer Co Ltd Lovell Applicant before: RUNAN HEERFENG FLUID FERTILIZER Co.,Ltd. |
|
| RJ01 | Rejection of invention patent application after publication | ||
| RJ01 | Rejection of invention patent application after publication |
Application publication date: 20161214 |