CN106219748A - A kind of multistage Micro Fluid collection depth-type filtration modified model anaerobic filter - Google Patents
A kind of multistage Micro Fluid collection depth-type filtration modified model anaerobic filter Download PDFInfo
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- 239000012530 fluid Substances 0.000 title claims abstract description 137
- 238000001914 filtration Methods 0.000 title claims abstract description 37
- 238000012856 packing Methods 0.000 claims abstract description 167
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 81
- 239000000463 material Substances 0.000 claims abstract description 37
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 claims abstract description 26
- 238000009826 distribution Methods 0.000 claims abstract description 19
- 239000000945 filler Substances 0.000 claims description 27
- -1 polypropylene Polymers 0.000 claims description 21
- 239000004698 Polyethylene Substances 0.000 claims description 12
- 230000004888 barrier function Effects 0.000 claims description 12
- 239000000203 mixture Substances 0.000 claims description 12
- 229920000573 polyethylene Polymers 0.000 claims description 12
- 239000004743 Polypropylene Substances 0.000 claims description 9
- 229920001155 polypropylene Polymers 0.000 claims description 9
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims description 7
- 238000011049 filling Methods 0.000 claims description 6
- 238000002156 mixing Methods 0.000 claims description 4
- 239000002245 particle Substances 0.000 claims description 4
- 239000011449 brick Substances 0.000 claims description 3
- 239000012634 fragment Substances 0.000 claims description 3
- 239000011257 shell material Substances 0.000 claims 1
- 230000000694 effects Effects 0.000 abstract description 30
- 238000012546 transfer Methods 0.000 abstract description 7
- 239000008346 aqueous phase Substances 0.000 abstract description 5
- 239000007789 gas Substances 0.000 description 25
- 239000002351 wastewater Substances 0.000 description 20
- 238000000034 method Methods 0.000 description 12
- 230000008569 process Effects 0.000 description 9
- 238000012545 processing Methods 0.000 description 9
- 239000010865 sewage Substances 0.000 description 8
- 244000005700 microbiome Species 0.000 description 7
- 239000002028 Biomass Substances 0.000 description 5
- 230000006872 improvement Effects 0.000 description 5
- 238000005243 fluidization Methods 0.000 description 4
- 239000010802 sludge Substances 0.000 description 4
- 230000008859 change Effects 0.000 description 3
- 238000003889 chemical engineering Methods 0.000 description 3
- 230000004060 metabolic process Effects 0.000 description 3
- 239000000126 substance Substances 0.000 description 3
- 238000012360 testing method Methods 0.000 description 3
- 239000002699 waste material Substances 0.000 description 3
- 239000012620 biological material Substances 0.000 description 2
- 239000003344 environmental pollutant Substances 0.000 description 2
- 230000000813 microbial effect Effects 0.000 description 2
- 239000012071 phase Substances 0.000 description 2
- 238000005191 phase separation Methods 0.000 description 2
- 231100000719 pollutant Toxicity 0.000 description 2
- 108010074506 Transfer Factor Proteins 0.000 description 1
- 230000002411 adverse Effects 0.000 description 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 230000004071 biological effect Effects 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 230000015556 catabolic process Effects 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 230000001276 controlling effect Effects 0.000 description 1
- 238000006731 degradation reaction Methods 0.000 description 1
- 238000005265 energy consumption Methods 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 238000011010 flushing procedure Methods 0.000 description 1
- 238000011068 loading method Methods 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 238000012544 monitoring process Methods 0.000 description 1
- 239000010815 organic waste Substances 0.000 description 1
- 230000003647 oxidation Effects 0.000 description 1
- 238000007254 oxidation reaction Methods 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 238000003672 processing method Methods 0.000 description 1
- 238000004080 punching Methods 0.000 description 1
- 238000000746 purification Methods 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 238000007670 refining Methods 0.000 description 1
- 238000010992 reflux Methods 0.000 description 1
- 230000001105 regulatory effect Effects 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 239000004575 stone Substances 0.000 description 1
- 239000000725 suspension Substances 0.000 description 1
- 230000026676 system process Effects 0.000 description 1
- 238000011144 upstream manufacturing Methods 0.000 description 1
- 238000004065 wastewater treatment Methods 0.000 description 1
Classifications
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- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F3/00—Biological treatment of water, waste water, or sewage
- C02F3/28—Anaerobic digestion processes
- C02F3/2826—Anaerobic digestion processes using anaerobic filters
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E50/00—Technologies for the production of fuel of non-fossil origin
- Y02E50/30—Fuel from waste, e.g. synthetic alcohol or diesel
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- Life Sciences & Earth Sciences (AREA)
- Microbiology (AREA)
- Biodiversity & Conservation Biology (AREA)
- Hydrology & Water Resources (AREA)
- Engineering & Computer Science (AREA)
- Environmental & Geological Engineering (AREA)
- Water Supply & Treatment (AREA)
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Purification Treatments By Anaerobic Or Anaerobic And Aerobic Bacteria Or Animals (AREA)
- Biological Treatment Of Waste Water (AREA)
Abstract
The present invention discloses a kind of multistage Micro Fluid collection depth-type filtration modified model anaerobic filter, is sequentially provided with water distribution area, strong Micro Fluid packing area, weak Micro Fluid packing area, filter packing district, exhalant region inside anaerobic filter from top to bottom；The volume of the graininess fluidized packing material that described strong Micro Fluid packing area is uniformly filled accounts for 50% the 60% of described strong Micro Fluid packing area volume；The volume of the graininess fluidized packing material that weak Micro Fluid packing area is uniformly filled accounts for 30% the 50% of described weak Micro Fluid packing area volume；Described exhalant region is arranged over biogas pipeline connection collecting methane system, and the outside of described anaerobic filter is additionally provided with water inlet system and circulation water gas system, and described water inlet system all connects water distribution area with circulation water gas system.The present invention makes weak Micro Fluid packing area by circulation water gas system and produces by force the mutual relation of a kind of disturbance between Micro Fluid packing area and aqueous phase, the internal generation in packing area Micro Fluid effect will be driven, increase mass transfer effect, in reducing filter tank, produce the phenomenons such as channel, short stream, dead band.
Description
Technical field
The present invention relates to a kind of equipment processing the organic used water difficult to degradate of high concentration, particularly relate to a kind of multistage Micro Fluid collection
Depth-type filtration modified model anaerobic filter.
Background technology
Chemical industry waste water comprises high concentration hard-degraded organic waste water more, and there is waste water composition complicated component, waste water more
Difficult degradation, load impact on anaerobic reactor the unfavorable factor such as impact is bigger.Go up many employing anaerobism the most both at home and abroad raw
The processing method of thing degraded.In anaerobic system, the carbon source that microorganism utilizes high concentrated organic wastewater to provide is raw as himself
The long energy substance with metabolism, through the chemical-biological process of series of complex, becomes hardly degraded organic substance into the most inorganic
Little molecule, and produce methane equal energy source gas, real realization becomes useless production capacity.And, at currently used anaerobic treatment reactor
In, anaerobic filter is widely used as the efficient processing equipment of one.Anaerobic filter is as the efficient anaerobic treatment of one
Device, has biological concentration height, microorganism time of staying length, anti impulsion load；After out of service, restart easily；Without dirt
Mud refluxes；The advantages such as operational management is easy, thus it is widely used in the wastewater treatment industry of each large-scale petrochemical treatment plant.But detesting
In the processing procedure of oxygen filter tank, waterpower mass transfer factor is the key factor restricting its high treatment capacity, at long-play
Under loading condiction, anaerobic filter can gradually produce the bad phenomenon such as channel, short stream even dead band, seriously constrains anaerobic filter anti-
Answer the disposal ability of device；And currently when carrying out processing the phenomenons such as channel, short stream, dead band, frequently with flushing or backwash etc.
Technological means, the most seriously increases the resources such as energy consumption, waste water power, and can be to the micro-life in reactor after rinsing backwash
System system can bring bigger adverse effect.Therefore, the internal waterpower mass transfer effect existed of current anaerobic filter reactor is solved
Poor problem be current anaerobic filter can efficient stable operation process key.
The number of patent application that State Intellectual Property Office announced on April 14th, 2014 is 201410149174.4, name
It is referred to as: a kind of biomass filler anaerobic filter tank processing oxidation state pollutant, this patent following technical scheme of proposition: this scheme bag
Include biofilter, biomass filler.Press in current upward direction in biofilter to be sequentially provided with into water relief area, filter
District, water outlet relief area, filter district includes the first filtering area, the second filtering area, the 3rd filtering area, the 4th filtering area, highly
Account for the 20 of filtering area, 50,20 and 10 respectively；Each filtering area fills the biomass filler of different ratios of raw materials respectively,
Biomass filler is made up of sea Na plant biological material and inert filler, and this patent by filling different ratio in filtering area
Biomass filler purifies sewage, owing to not having gas impulse force upwards, there will be channel, short stream and dead band inside anaerobic filter
Etc. phenomenon, make pollutant effluents can not get sufficiently and process, and biological material finally can be broken off, need again to put into.
Summary of the invention
The problem to be solved in the present invention is to provide one and improves that anaerobic filter internal waterpower mass transfer effect is poor, reduce anaerobism filters
The multistage Micro Fluid collection depth-type filtration modified model anaerobic filter of the phenomenons such as channel, short stream, dead band is produced in pond.Propose to this end, existing
Following scheme:
A kind of multistage Micro Fluid collection depth-type filtration modified model anaerobic filter, sets inside described anaerobic filter the most successively
There are the water distribution area with water-locator, filter packing district, exhalant region, the most also set between described water distribution area and filter packing district
There are strong Micro Fluid packing area and weak Micro Fluid packing area, and described weak Micro Fluid packing area, strong Micro Fluid packing area, filter packing
District and exhalant region are equipped with division board between any two；Described strong Micro Fluid packing area uniform filler particles shape fluidized packing material, and
Its volume accounts for the 50%-60% of described strong Micro Fluid packing area volume；Described weak Micro Fluid packing area also uniform filler particles shape
Fluidized packing material, its volume accounts for the 30%-50% of described weak Micro Fluid packing area volume；Described exhalant region is arranged over biogas pipeline
Connection collecting methane system and collecting methane system are provided with gas outlet；
The outside of described anaerobic filter is additionally provided with water inlet system and circulation water gas system, and described water inlet system includes intake pump
And the water sample bucket being connected with intake pump, described intake pump also connects the water-locator of water distribution area；Described circulation water gas system includes
Water-circulating pump and the outlet of exhalant region being connected with water-circulating pump and the gas outlet of collecting methane system, described water-circulating pump
Also the water-locator of water distribution area is connected.
The fluidisation that further improvement of these options, described weak Micro Fluid packing area and strong Micro Fluid packing area are filled is filled out
Material is one or more mixing compositions of polypropylene, polyethylene and modified class filler thereof.
The fluidisation that further improvement of these options, described weak Micro Fluid packing area and strong Micro Fluid packing area are filled is filled out
Material is shaped as hollow cylindrical, and cross section is in protruding many pleats structure, and external diameter is 1-1.2cm, and a length of 1-1.2cm piles up close
Degree is 0.14-0.16g/cm3, wet density is 0.90-0.92g/cm3
Further improvement of these options, the bulky grain inert filler uniformly filled in described filled by filtration district is gravel
Stone, fragment of brick, shell, one or more mixing compositions of activated carbon.
Further improvement of these options, described strong Micro Fluid packing area, weak Micro Fluid packing area and filtration
Packing area is equipped with a sample tap.
Further improvement of these options, described weak Micro Fluid packing area, strong Micro Fluid packing area, filter packing district with
And exhalant region is equipped with porous barrier between any two；Described porous barrier hole is uniformly distributed, aperture less than 1cm and described punching every
Plate is detachable.
The beneficial effects of the present invention is:
(1) control water circulating load size by control water-circulating pump or biogas recirculation amount size makes weak Micro Fluid packing area
And between strong Micro Fluid packing area and aqueous phase, produce the mutual relation of a kind of disturbance, make that packing area is internal produces Micro Fluid effect,
Make the contact between the microorganism on waste water and filler more abundant, more increase anaerobic filter internal waterpower mass transfer effect
Really, and Micro Fluid bring waterpower flowing effect also can solve in anaerobic processes produce biological bubble be trapped fluidisation
Problem between filler, the bubble of upward flow is gradually increased along with current, and participating in inner loop more increases inside anaerobic filter
Waterpower mass transfer effect.
(2) the hydraulic shear effect that Micro Fluid brings also can promote biomembranous formation and the metabolism of filling surface,
Accelerate biomembranous growth and renewal, more promote the disposal ability of the internal microorganism of anaerobic filter, accelerate at useless water purification
Reason.
(3) the fluidized packing material outer surface filled in weak Micro Fluid packing area and strong Micro Fluid packing area protrudes the knot of many pleats
Structure, forms bigger specific surface area, it is possible to the growth for microorganism provides bigger attachment space, and described fluidized packing material tool
Have a bioaffinity, bio-film colonization growth easily, the advantages such as after biofilm microbial activity is high.
(4) filter packing district retains the anaerobic sludge of suspension by filling bulky grain inert filler, it is achieved water, anaerobic sludge
And the three phase separation of bulky grain inert filler, it is not necessary to special three phase separator is set, it is ensured that the effluent quality of anaerobic filter.
(5) arrange porous barrier to be easy to isolate filler and waste water, and play the effect in fixed reactor Zhu Chuan district, moreover it is possible to
Enough make each district packing area volumetric spaces suitable, it is simple to form Micro Fluid pattern.
(6) described weak Micro Fluid packing area, strong Micro Fluid packing area and filter packing district are equipped with a sample tap, arrange
The sample tap of packing area, each district, it is simple to detect the water quality that each district purifies.
(7) circulation water gas system uses water and biogas are all to recycle, treated sewage and the micro-life of anaerobism
The biogas produced after thing reaction is put in the processing procedure of sewage again, it is achieved the self-loopa of resource, it is not necessary to additionally set
Put water distribution system and gas distribution system, more environmentally-friendly, cost-effective.
Accompanying drawing explanation
Fig. 1 is the structural representation that a kind of multistage Micro Fluid collection depth-type filtration of the present invention changes type anaerobic filter.
Fig. 2 is one of the present invention multistage Micro Fluid collection depth-type filtration modified model anaerobic filter strong Micro Fluid packing area
Cross sectional representation with the fluidized packing material that weak Micro Fluid packing area is filled.
Reference: water-locator-1；Strong Micro Fluid packing area-2；Strong Micro Fluid packing area sample tap-3；Weak Micro Fluid is filled out
Material district-4；Weak Micro Fluid packing area sample tap-5；Filter packing district-6；Filter packing district sample tap-7；Porous barrier-8；Water outlet
District-9；Outlet-10；Gas outlet-11；Bulky grain inert filler-12；Anaerobic filter-13；Fluidized packing material-14；Intake pump-15；
Water-circulating pump-16；Water sample bucket-17；Biogas pipeline-18.
Detailed description of the invention
For the technological means making the present invention realize, creation characteristic, reach purpose and be easy to understand with effect, below in conjunction with
Detailed description of the invention, is expanded on further the present invention.
Embodiment 1
One multistage Micro Fluid collection depth-type filtration modified model anaerobic filter 13 as shown in Figure 1, described anaerobic filter 13
Internal be sequentially provided with the water distribution area with water-locator 1 from top to bottom, strong Micro Fluid with strong Micro Fluid packing area sample tap 3 is filled out
Material district 2, the weak Micro Fluid packing area 4 with weak Micro Fluid packing area sample tap 5, the filtration with filter packing district sample tap 7
Packing area 6, with outlet 10 exhalant region 9 and by biogas pipeline 18 connect with exhalant region 9 with gas outlet 11
Collecting methane system (not shown) and described strong Micro Fluid packing area 2, weak Micro Fluid packing area 4, filter packing district 6 and water outlet
District 9 is equipped with a dismountable porous barrier 8 between any two；The hole of porous barrier 8 is uniformly distributed and aperture is less than 1cm, described
The polyacrylic volume of fluidized packing material that weak Micro Fluid packing area 4 is uniformly filled accounts for the 30% of described packing area volume, fluidized packing material
Expansion rate be 30%；The polyacrylic volume of graininess fluidized packing material that strong Micro Fluid packing area 2 is uniformly filled accounts for described filler
The 50% of district's volume, the expansion rate of fluidized packing material is 80%, and described weak Micro Fluid packing area 4 and strong Micro Fluid packing area 2 are filled
Fluidized packing material polypropylene be shaped as hollow cylindrical, cross section in protrude many pleats structure, wherein pleat is triangle pleat, filler
External diameter is 1cm, a length of 1cm, and bulk density is 0.14g/cm3, wet density is 0.90g/cm3；Described filter packing district 6 fills
The gravel of the 100% of described packing area volume, the outside of described anaerobic filter is additionally provided with water inlet system and circulation water gas system, institute
Stating water-locator 1 and connect an intake pump 15, intake pump 15 connects a water sample bucket 17 and constitutes water inlet system；Described water-locator 1 is also connected with
One water-circulating pump 16, the gas outlet 11 of outlet 10 and collecting methane system that described water-circulating pump 16 connects exhalant region 9 is constituted
Circulation water gas system, controls quantity of circulating water size by control water-circulating pump 16 or biogas recirculation amount size makes weak Micro Fluid fill out
Material district 4 and the strong mutual relation producing a kind of disturbance between Micro Fluid packing area 2 and aqueous phase, make the internal generation in packing area Micro Fluid
Effect, and the polyacrylic expansion rate that described strong Micro Fluid packing area 2 and weak Micro Fluid packing area 4 are filled also is by water-circulating pump
16 control quantity of circulating water and biogas recirculation amount realize.
Anaerobic filter described in above-described embodiment processes chemical engineering sewage PTA waste water, wherein COD in PTA waste waterCrConcentration is
5000mg/L, TA concentration is 2400mg/L.Using this PTA waste water as processing object, table 1 below is result table
The table 1 multistage Micro Fluid collection depth-type filtration modified model anaerobic filter treatment effect to PTA waste water
| Testing index | CODCr(mg/l) | TA(mg/l) |
| Former water | 5000 | 2400 |
| Water outlet | 1230 | 660 |
By upper table 1 it can be seen that CODCrPurifying rate is 75.4%, and TA purifying rate is 72.5%, and HRT is 15h, compared to biography
The anaerobic filter of system processes technique CODCrPurifying rate is less than 60%, and TA purifying rate is less than 65%.Hydraulic detention time is that 24h comes
Seeing, the multistage Micro Fluid collection depth-type filtration modified model anaerobic filter described in the present embodiment is not only at CODCrHave with on the purifying rate of TA
Obvious raising, hydraulic shear effect and the biogas upstream of generation that Micro Fluid provides mix the circulation of air flow caused, greatly
Add greatly biomembranous activity in modified model anaerobic filter, enhance metabolism and the circulation of biology, accelerate PTA waste water
Process effect.This is that described multistage Micro Fluid collection depth-type filtration modified model anaerobic filter can improve the important former of disposal ability
Cause.
Embodiment 2
One multistage Micro Fluid collection depth-type filtration modified model anaerobic filter 13 as shown in Figure 1, described anaerobic filter 13
Internal be sequentially provided with the water distribution area with water-locator 1 from top to bottom, strong Micro Fluid with strong Micro Fluid packing area sample tap 3 is filled out
Material district 2, the weak Micro Fluid packing area 4 with weak Micro Fluid packing area sample tap 5, the filtration with filter packing district sample tap 7
Packing area 6, with outlet 10 exhalant region 9 and by biogas pipeline 18 connect with exhalant region 9 with gas outlet 11
Collecting methane system (not shown) and described strong Micro Fluid packing area 2, weak Micro Fluid packing area 4, filter packing district 6 and water outlet
District 9 is equipped with a dismountable porous barrier 8 between any two；The hole of porous barrier 8 is uniformly distributed and aperture is less than 1cm；Described
The graininess fluidized packing material volume ratio that weak Micro Fluid packing area 4 is uniformly filled is the polypropylene of 1: 1 and the mixture of polyethylene accounts for
The 40% of described packing area volume, the expansion rate of the mixture of graininess fluidized packing material polypropylene and polyethylene is 40%；Qiang Wei
The graininess fluidized packing material volume ratio that fluidized packing material district 2 uniformly fills is the polypropylene of 1: 1 and the mixture of polyethylene accounts for described
The 55% of packing area volume, the expansion rate of the mixture of graininess fluidized packing material polypropylene and polyethylene is 90%, described weak micro-
The fluidized packing material that fluidized packing material district 4 and strong Micro Fluid packing area 2 are filled is shaped as hollow cylindrical, and cross section is in protruding many pleats
Structure, wherein pleat is triangle pleat, and filler external diameter is 1cm, a length of 1cm, and bulk density is 0.14g/cm3, wet density is
0.90g/cm3；The activated carbon of 100% is filled in described filter packing district 6, the outside of described anaerobic filter be additionally provided with water inlet system and
Circulation water gas system, described water-locator 1 connects an intake pump 15, and intake pump 15 connects a water sample bucket 17 and constitutes water inlet system；Institute
Stating water-locator 1 and be also connected with a water-circulating pump 16, described water-circulating pump 16 connects outlet 10 and gas outlet 11 constitutes circulation aqueous vapor
System, controls water circulating load size by control water-circulating pump 16 or biogas recirculation amount size makes weak Micro Fluid packing area 4 He
The strong mutual relation producing a kind of disturbance between Micro Fluid packing area 2 and aqueous phase, will drive the internal generation in packing area Micro Fluid effect
Really, and the expansion rate of mixture of the polypropylene filled of described strong Micro Fluid packing area 2 and weak Micro Fluid packing area 4 and polyethylene
Also controlled water circulating load by water-circulating pump 16 and biogas recirculation amount realizes.
Anaerobic filter Refinery Wastewater described in above-described embodiment, wherein COD in refinery(waste) waterCrConcentration is 3000mg/
L, total dissolved solidss (total dissolved solids, TDS) are 950mg/L, using refinery(waste) water as processing object, following table
2 is result table.
The table 2 multistage Micro Fluid collection depth-type filtration modified model anaerobic filter treatment effect to refinery(waste) water
| Testing index | CODCr(mg/l) | TDS(mg/l) |
| Former water | 3000 | 950 |
| Water outlet | 660 | 416 |
Multistage Micro Fluid collection depth-type filtration modified model anaerobic filter Refinery Wastewater, COD is can be seen that by upper table 2CrOnly
Rate can reach 78.0%, and hydraulic detention time is 15h, compares traditional anaerobic filter shorter residence time 37.5%, to refining
In oil factory waste water, the purifying rate of TDS is 56.2%.
Embodiment 3
One multistage Micro Fluid collection depth-type filtration modified model anaerobic filter 13 as shown in Figure 1, described anaerobic filter 13
Internal be sequentially provided with the water distribution area with water-locator 1 from top to bottom, strong Micro Fluid with strong Micro Fluid packing area sample tap 3 is filled out
Material district 2, the weak Micro Fluid packing area 4 with weak Micro Fluid packing area sample tap 5, the filtration with filter packing district sample tap 7
Packing area 6, with outlet 10 exhalant region 9 and by biogas pipeline 18 connect with exhalant region 9 with gas outlet 11
Collecting methane system (not shown) and described strong Micro Fluid packing area 2, weak Micro Fluid packing area 4, filter packing district 6 and water outlet
District 9 is equipped with a dismountable porous barrier 8 between any two；The hole of porous barrier 8 is uniformly distributed and aperture is less than 1cm；Described
The graininess fluidized packing material polyethylene that weak Micro Fluid packing area 4 is uniformly filled accounts for the 50% of described packing area volume, fluidized packing material
Expansion rate be 50%；The graininess fluidized packing material polyethylene that strong Micro Fluid packing area 2 is uniformly filled accounts for described packing area volume
60%, the expansion rate of fluidized packing material is 100%, the fluidisation that described weak Micro Fluid packing area 4 and strong Micro Fluid packing area 2 are filled
Filler polyethylene is shaped as hollow cylindrical, and cross section is in protruding many pleats structure, and wherein pleat is triangle pleat, and filler external diameter is
1cm, a length of 1cm, bulk density is 0.14g/cm3, wet density is 0.90g/cm3；Described filter packing district 6 fills 100%
Fragment of brick, the outside of described anaerobic filter is additionally provided with water inlet system and circulation water gas system, and described water-locator 1 connects an intake pump
15, intake pump 15 connects a water sample bucket 17 and constitutes water inlet system；Described water-locator 1 is also connected with a water-circulating pump 16, and described water follows
Ring pump 16 connects outlet 10 and gas outlet 11 constitutes circulation water gas system, by controlling water-circulating pump quantity of circulating water size or natural pond
Gas circulating load size makes weak Micro Fluid packing area and produces by force the mutual pass of a kind of disturbance between Micro Fluid packing area and aqueous phase
System, will drive the internal generation in packing area Micro Fluid effect, and described strong Micro Fluid packing area 2 and weak Micro Fluid packing area 4 are filled
The expansion rate of polyethylene also controlled quantity of circulating water by water-circulating pump 16 and biogas recirculation amount realizes.
Above-mentioned anaerobic filter processes chemical engineering sewage PTA waste water CODCrConcentration be 5000mg/L, TA concentration be 2400mg/L,
PH is 4.5.Using this PTA waste water as processing object, table 3 below is result table
The table 3 multistage Micro Fluid collection depth-type filtration modified model anaerobic filter treatment effect to PTA waste water
| Testing index | CODCr(mg/l) | TA(mg/l) |
| Former water | 5000 | 2400 |
| Water outlet | 1000 | 500 |
By upper table 3 it can be seen that the anaerobic filter described in the present embodiment processes chemical engineering sewage PTA waste water CODCrPurifying rate is
80%, TA purifying rate is 79.2%.
Multistage Micro Fluid collection depth-type filtration described in above example 1～3 change type anaerobic filter utilize water-circulating pump to
Upper water distribution or upwards gas distribution, by regulating pondage or the size of biogas recirculation amount so that reach varying strength in different bed districts
Micro Fluid effect.This Micro Fluid effect can improve the internal channel, short of producing of anaerobic filter in tradition anaerobic filter running
The problems such as stream, dead band, improve the waterpower mass transfer effect within anaerobic filter.By the hydraulic disturbance of Micro Fluid, make sewage and stream
The biofilm contact changing filling surface is more abundant；The hydraulic shear effect that Micro Fluid produces simultaneously ensures that microorganism is constantly in
Higher biological activity state.And Micro Fluid bring waterpower flowing effect also can solve in anaerobic processes produce biogas
The problem that bubble is trapped between fluidized packing material, the bubble of upward flow is gradually increased along with current, participates in inner loop more
Increase the waterpower mass transfer effect within anaerobic filter
Sewage is through double-deck Micro Fluid packing area, and clean-up effect is wanted more preferably, and the stream as shown in Figure 2 filled
Changing filler polyethylene, polypropylene or the mixture of other modified class fluidized packing materials, outer surface protrudes many pleats and forms specific surface area greatly,
Bigger attachment space can be provided for the growth of microorganism, and described fluidized packing material has bioaffinity, bio-film colonization
Growth easily, the advantages such as after biofilm microbial activity is high.
Waste water through double-deck Micro Fluid packing area is the most purified, but may suspend anaerobic sludge, passes through
Filter packing district 6 retains anaerobic sludge, it is achieved water, mud and the three phase separation of bulky grain inert filler, it is not necessary to separately arrange
Three-phase diverter, it is ensured that the water outlet quality of anaerobic filter.And in described strong Micro Fluid packing area 2, weak Micro Fluid packing area 4,
Filter packing district 6 and exhalant region 9 are respectively provided with a sample tap, it is simple to monitoring in real time purifies water, and monitors clean-up effect.
In strong Micro Fluid packing area 2, weak Micro Fluid packing area 4, filter packing district 6 and exhalant region 9 be all provided with between any two
Put a homogeneous detachable dividing plate 8 of district's porous, the filter of each district can either be played and separate the effect from work, enable to again each layer
Filtering layer volumetric spaces is suitable, it is simple to form Micro Fluid pattern.
The outlet 10 of exhalant region 9 and the gas outlet 11 of collecting methane system are connected to outside described anaerobic filter 13
Water-circulating pump 16, constitutes circulation water gas system, it is achieved the self-loopa of resource, it is not necessary to additionally arrange water distribution system and gas distribution system
System, more environmentally-friendly, cost-effective.
Those of ordinary skill in the art it should be appreciated that above embodiment be intended merely to illustrate the present invention,
And be not used as limitation of the invention, the change as long as in the spirit of the present invention, to embodiment described above
Change, modification all will fall in scope of the presently claimed invention.
Claims (6)
1. a multistage Micro Fluid collection depth-type filtration modified model anaerobic filter, is sequentially provided with inside described anaerobic filter from top to bottom
With the water distribution area of water-locator, filter packing district, exhalant region, it is characterised in that: between described water distribution area and filter packing district from
Under supreme strong Micro Fluid packing area and the weak Micro Fluid packing area of being additionally provided with, and described weak Micro Fluid packing area, strong Micro Fluid filler
District, filter packing district and exhalant region are equipped with division board between any two；Described strong Micro Fluid packing area uniform filler particles shape
Fluidized packing material, and its volume accounts for the 50%-60% of described strong Micro Fluid packing area volume；Described weak Micro Fluid packing area is the most uniform
Filler particles shape fluidized packing material, its volume accounts for the 30%-50% of described weak Micro Fluid packing area volume；Set above described exhalant region
Biogas pipeline connection collecting methane system and collecting methane system is had to be provided with gas outlet；
The outside of described anaerobic filter be additionally provided with water inlet system and circulation water gas system, described water inlet system include intake pump and
The water sample bucket being connected with intake pump, described intake pump also connects the water-locator of water distribution area；Described circulation water gas system includes that water follows
Ring pump and the outlet of exhalant region being connected with water-circulating pump and the gas outlet of collecting methane system, described water-circulating pump also connects
The water-locator of logical water distribution area.
One the most according to claim 1 multistage Micro Fluid collection depth-type filtration modified model anaerobic filter, it is characterised in that: institute
The fluidized packing material stating weak Micro Fluid packing area and the filling of strong Micro Fluid packing area is polypropylene, polyethylene and modified class filler thereof
One or more mixing composition.
One the most according to claim 2 multistage Micro Fluid collection depth-type filtration modified model anaerobic filter, it is characterised in that: institute
The fluidized packing material stating weak Micro Fluid packing area and the filling of strong Micro Fluid packing area is shaped as hollow cylindrical, and cross section is protrusion
Many pleats structure, external diameter is 1-1.2cm, a length of 1-1.2cm, and bulk density is 0.14-0.16g/cm3, wet density is 0.90-
0.92g/cm3。
One the most according to claim 1 multistage Micro Fluid collection depth-type filtration modified model anaerobic filter, it is characterised in that: institute
State one or more mixing compositions that filler in filter packing district is gravel, fragment of brick, shell, activated carbon.
One the most according to claim 1 multistage Micro Fluid collection depth-type filtration modified model anaerobic filter, it is characterised in that: institute
State strong Micro Fluid packing area, weak Micro Fluid packing area and filter packing district and be equipped with a sample tap.
One the most according to claim 1 multistage Micro Fluid collection depth-type filtration modified model anaerobic filter, it is characterised in that: institute
Stating the division board that weak Micro Fluid packing area, strong Micro Fluid packing area, filter packing district and exhalant region be equipped with between any two is
Porous barrier；Described porous barrier hole is uniformly distributed, and aperture is detachable less than 1cm and described porous barrier.
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Cited By (3)
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| CN107399814A (en) * | 2017-09-18 | 2017-11-28 | 杨明 | A kind of embedded multistage denitrification filter pool |
| CN108623088A (en) * | 2018-01-24 | 2018-10-09 | 湖南内特环保科技有限公司 | A kind of small flow medical waste water processing integrated apparatus and its wastewater treatment method |
| CN109095604A (en) * | 2018-11-08 | 2018-12-28 | 正丰源生物科技（苏州）有限公司 | A kind of composite bio-chemical degassing tower |
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| CN102424472A (en) * | 2011-10-28 | 2012-04-25 | 自贡大业高压容器有限责任公司 | Anaerobic biofilter |
| CN203065230U (en) * | 2013-01-22 | 2013-07-17 | 广州大学 | Dispensing gas circulating fluidized biofilter tank |
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| KR100230172B1 (en) * | 1997-03-10 | 1999-11-15 | 노건일 | Two stage reactor combining anaerobic filter medium and flowing biofilm |
| CN102424472A (en) * | 2011-10-28 | 2012-04-25 | 自贡大业高压容器有限责任公司 | Anaerobic biofilter |
| CN203065230U (en) * | 2013-01-22 | 2013-07-17 | 广州大学 | Dispensing gas circulating fluidized biofilter tank |
| CN203922844U (en) * | 2014-04-14 | 2014-11-05 | 杭州电子科技大学 | Process the biomass filler anaerobic filter tank of oxidation state pollutent |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
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| CN107399814A (en) * | 2017-09-18 | 2017-11-28 | 杨明 | A kind of embedded multistage denitrification filter pool |
| CN108623088A (en) * | 2018-01-24 | 2018-10-09 | 湖南内特环保科技有限公司 | A kind of small flow medical waste water processing integrated apparatus and its wastewater treatment method |
| CN109095604A (en) * | 2018-11-08 | 2018-12-28 | 正丰源生物科技（苏州）有限公司 | A kind of composite bio-chemical degassing tower |
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