CN106206823B - It is a kind of to be used to improve reflective membrane of cell piece generated output and preparation method thereof - Google Patents

It is a kind of to be used to improve reflective membrane of cell piece generated output and preparation method thereof Download PDF

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Publication number
CN106206823B
CN106206823B CN201610741940.5A CN201610741940A CN106206823B CN 106206823 B CN106206823 B CN 106206823B CN 201610741940 A CN201610741940 A CN 201610741940A CN 106206823 B CN106206823 B CN 106206823B
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layer
reflective membrane
reflective
pvc
abs
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CN106206823A (en
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朱广和
赵卫东
赵雅
费春燕
赵枫
赵霞
李向华
王燕
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JIANGSU ECONESS ENERGY CO Ltd
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JIANGSU ECONESS ENERGY CO Ltd
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    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01LSEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L31/00Semiconductor devices sensitive to infrared radiation, light, electromagnetic radiation of shorter wavelength or corpuscular radiation and specially adapted either for the conversion of the energy of such radiation into electrical energy or for the control of electrical energy by such radiation; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof
    • H01L31/04Semiconductor devices sensitive to infrared radiation, light, electromagnetic radiation of shorter wavelength or corpuscular radiation and specially adapted either for the conversion of the energy of such radiation into electrical energy or for the control of electrical energy by such radiation; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof adapted as photovoltaic [PV] conversion devices
    • H01L31/054Optical elements directly associated or integrated with the PV cell, e.g. light-reflecting means or light-concentrating means
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01LSEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L31/00Semiconductor devices sensitive to infrared radiation, light, electromagnetic radiation of shorter wavelength or corpuscular radiation and specially adapted either for the conversion of the energy of such radiation into electrical energy or for the control of electrical energy by such radiation; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof
    • H01L31/02Details
    • H01L31/0216Coatings
    • H01L31/02161Coatings for devices characterised by at least one potential jump barrier or surface barrier
    • H01L31/02167Coatings for devices characterised by at least one potential jump barrier or surface barrier for solar cells
    • H01L31/02168Coatings for devices characterised by at least one potential jump barrier or surface barrier for solar cells the coatings being antireflective or having enhancing optical properties for the solar cells
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01LSEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L31/00Semiconductor devices sensitive to infrared radiation, light, electromagnetic radiation of shorter wavelength or corpuscular radiation and specially adapted either for the conversion of the energy of such radiation into electrical energy or for the control of electrical energy by such radiation; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof
    • H01L31/18Processes or apparatus specially adapted for the manufacture or treatment of these devices or of parts thereof
    • H01L31/1876Particular processes or apparatus for batch treatment of the devices
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02EREDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E10/00Energy generation through renewable energy sources
    • Y02E10/50Photovoltaic [PV] energy
    • Y02E10/52PV systems with concentrators
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02PCLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P70/00Climate change mitigation technologies in the production process for final industrial or consumer products
    • Y02P70/50Manufacturing or production processes characterised by the final manufactured product

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  • Engineering & Computer Science (AREA)
  • Computer Hardware Design (AREA)
  • Physics & Mathematics (AREA)
  • Condensed Matter Physics & Semiconductors (AREA)
  • Electromagnetism (AREA)
  • General Physics & Mathematics (AREA)
  • Microelectronics & Electronic Packaging (AREA)
  • Power Engineering (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Sustainable Development (AREA)
  • Manufacturing & Machinery (AREA)
  • Sustainable Energy (AREA)
  • Photovoltaic Devices (AREA)

Abstract

A kind of reflective membrane for being used to improve cell piece generated output of the present invention, the reflective membrane is with layer of PVC(1)As base material, in layer of PVC(1)Obverse and reverse be bonded with TPU layer(2), in layer of PVC(1)Positive TPU layer(2)Adhered thereto has abs layer(3), the catoptric arrangement of reflected sunlight is hot pressed on the surface of the abs layer(4), in catoptric arrangement(4)Surface be coated with layer of metal reflective membrane(5), in reflective metal film(5)Surface even application have the insulating protective layer of layer of transparent(6).The present invention changes the base materials such as traditional glass fibre and utilizes the glue not environmentally technique such as compound, production cost is made low, not only it is environmentally friendly but also anti-aging, the good reflectorized strip film of corrosion-resistant also insulating properties, not only technique is simple, easy to operate, production line balance efficiency high, equally reduce production cost, and without glue it is compound after, solve environmental pollution and higher cost that solvent-borne type glue water tape comes.

Description

It is a kind of to be used to improve reflective membrane of cell piece generated output and preparation method thereof
Technical field
The present invention relates to a kind of reflective membrane for being used to improve cell piece generated output and preparation method thereof.Belong to solar energy Volt field.
Background technology
Current crystal silicon solar photovoltaic cell industrialization has formed scale, and photovoltaic industry is quickly grown, and technology also compares It is more ripe, according to national latest report data, end in September, 2015, China adds up photovoltaic generation installation and reaches 37.95GW.But, At this stage because current cost is also higher before solar energy power generating, photovoltaic project must could realize profit, institute by subsidy To improve solar photovoltaic assembly transformation efficiency, reduce the early investment cost of photovoltaic project, be to realize photovoltaic electric power " par One of necessary approach of online ".
Reduce early investment cost, improve photovoltaic module conversion efficiency, except silicon chip in itself in addition to, lot of domestic and international producer Also think hard from manufacturing process.By the innovation to grid line printed design, the innovation to component manufacturing process technology is improved, right The innovation of raw material manufacture and courageously on probation, it is achieved thereby that the reduction and the raising of efficiency of cost, in recent years in, solar energy Photovoltaic module transformation efficiency can reduce 12% from 14.1% quantity for bringing up to photovoltaic arrays in 16.2%, 1MW generator units. Reduce in cost, the application and preparation of crystal-silicon battery slice grid line design and reflecting strips is one of key factor.Solar cell The grid line design of piece smooth surface is should be thicker, more intensive better in order to collect photoelectric current, i.e. grid line to greatest extent, but this must The light-receiving area of cell piece is so reduced, the contradiction of high shading is formed.And in the factor of influence photovoltaic module production cost, it is brilliant The cost of silicon cell positive electrode grid line silver or silver-colored aluminum slurry accounts for about the 20% of totle drilling cost, and influences the effect of solar energy power generating The problems such as rate is mainly solar radiation quantity, the conversion ratio maximal power tracing of battery component, the welding of conventional photovoltaic assemblies is direct It is welded on cell piece, and adjacent cell piece is interconnected, welding has certain width in itself, can cover in cell piece Part light-receiving area, influences the utilization of light, can not also reflect away the light on welding surface, improves light utilization, increases Plus component efficiency, and the popularization and application of reflecting strips also relate to the performance of its selection of material, cost performance, preparation technology, production effect Rate, enables reflecting strips to reduce unit cost of electricity-generating indirectly to greatest extent, improves the solar energy power generating rate of exchange.Therefore seek There is one kind low shading rate, low cost, high transformation efficiency cell piece point-like main gate line to interconnect reflective battery component and its preparation side Method is particularly important.
The content of the invention
The technical problems to be solved by the invention are to provide a kind of for improving cell piece generating for above-mentioned prior art Reflective membrane of power and preparation method thereof, not only technique is simple, easy to operate, production line balance efficiency high, while reducing production Cost and environmental pollution.
The present invention the used technical scheme that solves the above problems is:It is a kind of to be used to improve the reflective of cell piece generated output Film, the reflective membrane is bonded with thermoplastic polyurethane material's system using layer of PVC as base material in the obverse and reverse of layer of PVC Into TPU layer, have abs layer in the positive TPU layer adhered thereto of layer of PVC, reflected sunlight be hot pressed on the surface of the abs layer Catoptric arrangement, be coated with layer of metal reflective membrane on the surface of catoptric arrangement, have one in the surface even application of reflective metal film The transparent insulating protective layer of layer.
Preferably, there is insulation tank apart from the upper surface of reflective membrane both sides equidistant position from reflective metal film is down-set.
The present invention also provides a kind of method for preparing above-mentioned reflective membrane, the described method comprises the following steps:
Step 1: by ABS plastic, thermoplastic polyurethane TPU, PVC and thermoplastic polyurethane TPU according to top-down side Formula melts the basic unit's body for being combined into layer structure, and heating roller temperature control is at 145 DEG C -150 DEG C during melting, and linear velocity is every Minutes 280-300 meters, the after cooling big volume of harvest;
Step 2: preparing minute surface mold pressing roll, ABS surface is hot pressed into the reflection knot of reflected solar energy using minute surface mold pressing roll Structure, molding roll temperature is 145-150 DEG C, 280-300 ms/min of linear velocity;
Step 3: plating layer of metal reflective membrane in the reflective structured surface of step 2 using electroplating technology;
Step 4: the polyurethane film for the reflective metal film surface even application layer of transparent electroplated in step 3, Polyurethane liquid temperature is 165-170 DEG C, and spout pressure is 2-2.4kg;
Step 5: hot forming after compound and the again electroplated big cut roll of reflective membrane into the strip of certain size, cutting Tension force is 0.15-0.40kg, and linear velocity is 380-400 ms/min;
Step 6: the strip reflective membrane both sides equidistant position apart from step 5 from the upper table of reflective metal film downwards, Respectively one insulation tank of etching, completes the preparation of reflecting strips.
Preferably, the catoptric arrangement in step 2 is the isosceles triangular structure that base angle is 30-45 °, and its density is In 1-2.8mm2In the range of have 10-12 isosceles triangular structure.
Compared with prior art, the advantage of the invention is that:
1st, using the reflectorized strip film manufacturing process technology of novel and unique, the base materials such as traditional glass fibre and profit are changed Not environmentally technique is waited with glue is compound, it is low to be made production cost, not only environmentally friendly but also anti-aging, good anti-of corrosion-resistant also insulating properties Striation film, not only technique is simple, easy to operate, production line balance efficiency high, equally reduces production cost, and multiple without glue After conjunction, environmental pollution and higher cost that solvent-borne type glue water tape comes are solved.
2nd, open up insulation tank using reflecting strips two ends and avoid the short-circuit conditions that are likely to occur between cell piece well, really Protect the security performance of battery component.
3rd, transparent insulating layer is sprayed using reflecting strips layer on surface of metal, had both ensured that reflecting strips had good insulating properties, Protect reflecting strips metal level well again, improve the anti-aging and decay resistance of reflecting strips metal level, its service life can Up to more than 30 years.
Brief description of the drawings
Fig. 1 is structural representation of the invention.
Embodiment
The present invention is described in further detail with reference to embodiments.
Referring to Fig. 1, the present invention relates to a kind of reflective membrane for being used to improve cell piece generated output, the reflective membrane is with PVC Layer 1 is bonded with the TPU layer 2 that thermoplastic polyurethane material is made, in PVC as base material in the obverse and reverse of layer of PVC 1 The 1 positive adhered thereto of TPU layer 2 of layer has abs layer 3, and the general thickness of four-layer structure is 120 microns, on the surface of the abs layer It is hot pressed into the catoptric arrangement 4 of reflected sunlight, catoptric arrangement is micro- shape isosceles triangular structure, or other micro-structurals, anti- The surface for penetrating structure 4 is coated with layer of metal reflective membrane 5, and the thickness of reflective metal film is 0.35 micron, while in reflective metal film 5 Surface even application have layer of transparent polyurethane material insulating protective layer 6, in the both sides of reflective membrane from reflective metal film 5 Upper surface abs layer is provided with insulation tank 7, the width of the insulation tank 7 is 0.1mm, and depth is 0.2mm, the work of insulation tank With predominantly avoiding adjacent cell piece from being connected by reflective membrance current, short circuit is caused.The TPU layer of the reflective membrane is that instead of glue Two layers of effect above and below heat fused, and transparent insulation performance is good, and adhesion is very strong, and concavo-convex with micro- shape isosceles triangle sample Structured metal surface layer is played, plays and the light for projecting its surface is reflexed into preceding glass sheet and then battery is reflexed to again, so as to increase Plus the components above power of light utilization efficiency 5% and 2.5%.Intermediate layer is synthesized with ABS and PVC material, plays strong basis and barriers function effect, And form firm reflecting strips, and reduced by the bonding of reflecting strips and welding so as to enhance the toughness and intensity of welding The welding fracture that aging is formed because of the influence of natural environment, extends photovoltaic module service life.
A kind of preparation method of above-mentioned reflecting strips is additionally provided in the present embodiment, be the described method comprises the following steps:
Step 1: by ABS plastic, thermoplastic polyurethane TPU, PVC and thermoplastic polyurethane TPU according to top-down side Formula melts the basic unit's body for being combined into layer structure, and the gross thickness of basic unit's body is 120 microns, and heating roller temperature is controlled during melting At 145 DEG C-150 DEG C, linear velocity is 280-300 meters per minute, after cooling the big volume of harvest, the complex than glass fibre or The stiffness of other plastics composite beds and tough Soft Bonding, tensile strength are good, and the peel strength of each layer is up to 25kg/cm, resistance to old Change performance is good, and service life can surpass 30 years;
Step 2: preparing minute surface mold pressing roll, ABS surface is hot pressed into the reflection knot of reflected solar energy using minute surface mold pressing roll Structure, its surface is micro- shape isosceles triangular structure, and roller die parameter is:Temperature is 145-150 DEG C, 280-300 ms/min of linear velocity Clock, 1-2.8mm2In the range of to be pressed into 10-12 base angle be 30-45 ° of isosceles triangular structure;
Step 3: plating layer of metal reflective membrane, wherein metal in the reflective structured surface of step 2 using electroplating technology The thickness of reflective membrane is 0.35 micron;
Step 4: the big volume of basic unit's body electroplated in step 3 is moved into polyurethane coating machine, in reflective metal film table The polyurethane film of face even application layer of transparent(Insulating protective layer), reflective metal film insulation is covered, polyurethane spray Polyurethane liquid temperature is 165-170 DEG C in painting machine charging basket, and spout pressure is 2-2.4kg;
Step 5: using import cutting machine that compound rear hot forming is simultaneously again electroplated according to battery strings welding width specifications The big cut roll of reflective membrane into the strip of certain size, the cutting tension force of cutting machine is 0.15-0.40kg, linear velocity is 380- 400 ms/min;
Step 6: the strip reflective membrane that will cut formation is downward along reflective metal film top with precise laser etching apparatus, And apart from respectively one insulation tank of etching, the preparation of completion reflecting strips of strip reflective membrane both lateral sides equidistant position, carve absolutely The width of edge groove is 0.1mm, and depth is 0.2mm, and the effect of this insulation tank predominantly avoids adjacent cell piece from passing through reflecting strips Electric current is connected, and causes short circuit.
It is conventional according to test and measuring and calculating project photovoltaic module ratio of the present invention after above-mentioned reflecting strips are applied on battery component Photovoltaic module not only reduces cost 5%, also reduces shading surface 5%, and also improve light efficiency 5% and add component work( Rate more than 2.5%, and innovation prepared by reflectorized strip film not only reduces cost more than 15%, also improves the tensile strength of reflectorized strip film With stripping degree of rising, and other performance index.The generation of welding crack conditions is also reduced simultaneously, extends the use of photovoltaic module In 5 years life-spans, overall economic efficiency is drastically increased, the application and development of solar energy power generating have been promoted energetically.
In addition to the implementation, present invention additionally comprises have other embodiment, all use equivalents or equivalence replacement The technical scheme that mode is formed, all should fall within the scope of the hereto appended claims.

Claims (3)

1. a kind of preparation method for being used to improve the reflective membrane of cell piece generated output, the reflective membrane is with layer of PVC(1)It is used as base Layer material, in layer of PVC(1)Obverse and reverse be bonded with the TPU layer that thermoplastic polyurethane material is made(2), in layer of PVC(1) Positive TPU layer(2)Adhered thereto has abs layer(3), the catoptric arrangement of reflected sunlight is hot pressed on the surface of the abs layer (4), in catoptric arrangement(4)Surface be coated with layer of metal reflective membrane(5), in reflective metal film(5)Surface even application have The insulating protective layer of layer of transparent(6), it is characterised in that:It the described method comprises the following steps:
Step 1: ABS plastic, thermoplastic polyurethane TPU, PVC and thermoplastic polyurethane TPU are melted according to top-down mode Melt the basic unit's body for being combined into layer structure, heating roller temperature control is at 145 DEG C -150 DEG C during melting, and linear velocity is per minute 280-300 meters, the after cooling big volume of harvest;
Step 2: preparing minute surface mold pressing roll, ABS surface is hot pressed into the catoptric arrangement of reflected solar energy using minute surface mold pressing roll, It is 145-150 DEG C to be molded roll temperature, 280-300 ms/min of linear velocity,
Step 3: plating layer of metal reflective membrane in the reflective structured surface of step 2 using electroplating technology;
Step 4: the polyurethane film for the reflective metal film surface even application layer of transparent electroplated in step 3, poly- ammonia Ester liquid temperature is 165-170 DEG C, and spout pressure is 2-2.4kg;
Step 5: hot forming after compound and the again electroplated big cut roll of reflective membrane are cut tension force into the strip of certain size For 0.15-0.40kg, linear velocity is 380-400 ms/min;
Step 6: the strip reflective membrane both sides equidistant position apart from step 5 from the upper table of reflective metal film downwards, it is each to carve An insulation tank is lost, the preparation of reflecting strips is completed.
2. a kind of preparation method for being used to improve the reflective membrane of cell piece generated output according to claim 1, its feature It is:Apart from reflective membrane both sides equidistant position from reflective metal film(5)Upper surface down-set have insulation tank(7).
3. a kind of preparation method for being used to improve the reflective membrane of cell piece generated output according to claim 1, its feature It is:Catoptric arrangement in step 2 is in 1-2.8mm2In the range of to be pressed into 10-12 base angle be 30-45 ° of isoceles triangle Shape structure.
CN201610741940.5A 2016-08-26 2016-08-26 It is a kind of to be used to improve reflective membrane of cell piece generated output and preparation method thereof Active CN106206823B (en)

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Publication number Priority date Publication date Assignee Title
CN106653904A (en) * 2017-01-03 2017-05-10 浚丰太阳能(江苏)有限公司 Reflective photovoltaic module
CN116682869B (en) * 2023-05-29 2023-12-15 浙江夜光明光电科技股份有限公司 Reflective film for double-glass solar backboard and preparation method thereof

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WO2005091379A3 (en) * 2004-03-16 2005-10-27 Vhf Technologies Sa Electric energy generating modules with a two-dimensional profile and method of fabricating the same
CN102569451A (en) * 2010-10-20 2012-07-11 苏州尚善新材料科技有限公司 Solar module back veneer comprising non-solvent bonding layers and manufacturing method thereof
CN103413861A (en) * 2013-07-18 2013-11-27 常州大学 Light reflecting thin film of photovoltaic module and method for fixing light reflecting thin film and soldering strip
CN103943708A (en) * 2014-04-24 2014-07-23 英利能源(中国)有限公司 Light reflecting film and photovoltaic module
CN204204887U (en) * 2014-11-28 2015-03-11 英利能源(中国)有限公司 A kind of photovoltaic reflective membrane with discontinuity insulation

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CN103022170A (en) * 2012-12-29 2013-04-03 常州大学 Reflective strip of photovoltaic module and method for implementing reflective strip

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Publication number Priority date Publication date Assignee Title
WO2005091379A3 (en) * 2004-03-16 2005-10-27 Vhf Technologies Sa Electric energy generating modules with a two-dimensional profile and method of fabricating the same
CN102569451A (en) * 2010-10-20 2012-07-11 苏州尚善新材料科技有限公司 Solar module back veneer comprising non-solvent bonding layers and manufacturing method thereof
CN103413861A (en) * 2013-07-18 2013-11-27 常州大学 Light reflecting thin film of photovoltaic module and method for fixing light reflecting thin film and soldering strip
CN103943708A (en) * 2014-04-24 2014-07-23 英利能源(中国)有限公司 Light reflecting film and photovoltaic module
CN204204887U (en) * 2014-11-28 2015-03-11 英利能源(中国)有限公司 A kind of photovoltaic reflective membrane with discontinuity insulation

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