CN106196318A - A kind of multi-deck cabinet type air cleaning instrument and method of work thereof - Google Patents
A kind of multi-deck cabinet type air cleaning instrument and method of work thereof Download PDFInfo
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- CN106196318A CN106196318A CN201610562467.4A CN201610562467A CN106196318A CN 106196318 A CN106196318 A CN 106196318A CN 201610562467 A CN201610562467 A CN 201610562467A CN 106196318 A CN106196318 A CN 106196318A
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F24—HEATING; RANGES; VENTILATING
- F24F—AIR-CONDITIONING; AIR-HUMIDIFICATION; VENTILATION; USE OF AIR CURRENTS FOR SCREENING
- F24F8/00—Treatment, e.g. purification, of air supplied to human living or working spaces otherwise than by heating, cooling, humidifying or drying
- F24F8/10—Treatment, e.g. purification, of air supplied to human living or working spaces otherwise than by heating, cooling, humidifying or drying by separation, e.g. by filtering
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/04—Oxygen-containing compounds
- C08K5/10—Esters; Ether-esters
- C08K5/101—Esters; Ether-esters of monocarboxylic acids
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/04—Oxygen-containing compounds
- C08K5/13—Phenols; Phenolates
- C08K5/134—Phenols containing ester groups
- C08K5/1345—Carboxylic esters of phenolcarboxylic acids
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/16—Nitrogen-containing compounds
- C08K5/17—Amines; Quaternary ammonium compounds
- C08K5/19—Quaternary ammonium compounds
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/56—Organo-metallic compounds, i.e. organic compounds containing a metal-to-carbon bond
- C08K5/57—Organo-tin compounds
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F24—HEATING; RANGES; VENTILATING
- F24F—AIR-CONDITIONING; AIR-HUMIDIFICATION; VENTILATION; USE OF AIR CURRENTS FOR SCREENING
- F24F13/00—Details common to, or for air-conditioning, air-humidification, ventilation or use of air currents for screening
- F24F13/28—Arrangement or mounting of filters
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- Polymers & Plastics (AREA)
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- Engineering & Computer Science (AREA)
- Combustion & Propulsion (AREA)
- Mechanical Engineering (AREA)
- General Engineering & Computer Science (AREA)
- Filtering Of Dispersed Particles In Gases (AREA)
- Catalysts (AREA)
Abstract
The invention discloses a kind of multi-deck cabinet type air cleaning instrument and method of work thereof, by air inlet, purify clothes closet, air outlet, overhaul dodge gate, control system forms；Described purification clothes closet sidewall bottom is provided with air inlet, described purification clothes closet front sidewall is arranged over air outlet, described purification clothes closet front sidewall bottom is provided with control system, described purification clothes closet front sidewall interlude is provided with maintenance dodge gate, and described maintenance dodge gate is connected with purifying clothes closet articulate.A kind of multi-deck cabinet type air cleaning instrument of the present invention and method of work novel and reasonable structure thereof, air purification efficiency is efficient, and the scope of application is wide.
Description
Technical field
The invention belongs to indoor environment and purify class field, be specifically related to a kind of multi-deck cabinet type air cleaning instrument and work side thereof
Method.
Background technology
Environmental conservation has become the focus that common people pay close attention to, the spring tide of economic globalization and the cry of solution Global Environmental Problems
Making environment day by day close with the relation of trade, international organization has formulated a series of technical standard being intended to protect environment.How to prevent
Control atmospheric pollution, pure air environment is also the problem that people constantly study.The particularly main energy sources of China is coal, coal-fired
During can produce substantial amounts of coal dust, severe contamination atmospheric environment.In these air, trickle coal dust, the most a diameter of
The floating dust of 2.5 μm～6 μm has high risks to health.It not only can be in pulmonary deposition, it is also possible to is directly entered blood and arrives
The each position of intelligent's body.Various noxious substance also can be adhered in powder dust particle surface, and it once enters human body, will cause various breathing
Systemic disease, harm will be bigger.Therefore, control the discharge of the fine solid particle of the most a diameter of 2.5 μm of dust～6 μm, be me
State's control atmosphere pollution, the Important Action of pure air environment.Additionally, the industry such as electronics, precision instrument processing contains in air
The requirement of dust quantity is higher, is typically desirable that the efficiency of dust collection to submicron order dust reaches more than 99.97%, this to high-effective dust-removing and
The development of ultra high efficiency dedusting technology is had higher requirement.
China is since the tentative discharge standard announcing 13 kinds of materials for the first time in 1973, and each industrial department is made the most in succession
Determine the dust emission standard of the industry.Such as, the discharge standard of Industrial Boiler is according to atmospheric environmental standards one, two, three
Class area determines, the standard (GB3841-83) of nineteen eighty-three be respectively 200,400,600mg/Nm3, the mark of announcement in 1992
Accurate (GB13271 1) be respectively 200 for installation before 1 day August in 1992,300,400mg/Nm3, and peace after August 1
Dress then be respectively 100,250,350mg/Nm3, simultaneously to SO2Concentration of emission it is also proposed requirement.Obviously new standard is reached
It is accomplished by using the cleaner of higher efficiency.
Tiny dust is big to harm relatively coarse granule, and therefore since the seventies, each state all focuses on that research is fine
The big art of control of dust (commonly referred to microgranule), and propose many corresponding technical measures.At U.S.'s pure air in 1992
Clearly proposing in method to classify the dust (PM10) less than 10 μm, its standard area is divided by PM10 with non-standard area.
In non-standard area, moderate requirement is up to standard before the end of the year 1994, more serious requirement is up to standard at the bottom of calendar year 2001.
Toxicity dust is maximum to harm, and before nineteen ninety, NESHAPS only defines standard to 7 kinds of poisonous dirt dyes, its
Include: hydrargyrum, quilt, asbestos, arsenic etc..But (many of which is to propose 189 kinds of toxic pollutants in the pure air method of 1990
Solid-state dust), relate to that the emission of many industrial department, such as coal-burning boiler just has 37 kinds more than.The U.S. in 1988 this
The total amount of a little toxic pollutant discharges is more than 2,400,000,000 pounds.These poisonous substances are not yet formulated standard at present, and pure air method requires to divide
Group after group at different time completed the work of the standard formulation to these poisonous substances in 1 year, and required reduction by 9000 before not formulating, to dust requirement
Reduce by 96%.
Existing conventional air cleaning processing equipment has: mechanical type depurator, gravity purification device, inertia depurator, whirlwind
Separator, filtering type depurator, pocket type purification device, granular layer depurator, electroclarifier, wet cleaner, gravity spray are washed
Device, impact water bath depurator, efficient Venturi tube depurator etc..
Under prior art conditions, the increase of the equipment construction cost and operating cost that process air cleaning will become must
So, existing traditional handicraft, that processing method has technological process is long, controls complexity, takes up an area big, the shortcomings such as processing cost is high.
Summary of the invention
In order to solve above-mentioned technical problem, the present invention provides a kind of multi-deck cabinet type air cleaning instrument, including: air inlet 1, only
Change clothes closet 2, air outlet 3, overhaul dodge gate 4, control system 5；Described purification clothes closet 2 sidewall bottom is provided with air inlet 1, described only
Changing clothes closet 2 front sidewall and be arranged over air outlet 3, described purification clothes closet 2 front sidewall bottom is provided with control system 5, described only
Changing clothes closet 2 front sidewall interlude and be provided with maintenance dodge gate 4, described maintenance dodge gate 4 is connected with purifying clothes closet 2 articulate.
Further, described purification clothes closet 2 includes: air exhauster 2-1, spiral just chimney filter 2-2, dedusting fall haze plate 2-3, air intake
Shower nozzle 2-4, anion generator 2-5, suspended pollution pellet degradation energy force transducer 2-6, bottom dividing plate 2-7, catalyst absorption
Plastochondria 2-8, gaseous contaminant degradation capability sensor 2-9, top layer dividing plate 2-10, movable filter 2-11, outlet swing wind apparatus 2-
12；Described air exhauster 2-1 is positioned at purification clothes closet 2 enclosure interior baseplane, the startup motor on air exhauster 2-1 and control system 5
Polygon control survey connects, and air exhauster 2-1 side is connected with air inlet 1, air exhauster 2-1 opposite side and spiral just chimney filter 2-2 air inlet
It is connected；Chimney filter 2-2 at the beginning of described spiral is positioned at purification clothes closet 2 enclosure interior and is provided with inside chimney filter 2-2 at the beginning of bottom position, spiral
Just filter screen, the spiral just chimney filter 2-2 number of turns is no less than 6 circles, and the internal total flight of spiral just chimney filter 2-2 is no less than 1.5m～2m；
Described dedusting fall haze plate 2-3 is positioned at above spiral just chimney filter 2-2, and dedusting fall haze plate 2-3 and purification clothes closet 2 inner walls are by sliding
Groove is fixing to be connected；Described air intake shower nozzle 2-4 is positioned at dedusting fall haze plate 2-3 overhead surface, air intake shower nozzle 2-4 and spiral just chimney filter 2-
2 air outlets are connected；Described bottom dividing plate 2-7 is positioned at above dedusting fall haze plate 2-3, and bottom dividing plate 2-7 drops haze plate 2-3 with dedusting
Spacing 20cm～40cm, bottom dividing plate 2-7 is connected by chute is fixing with purifying clothes closet 2 inner walls, bottom dividing plate 2-7 surface
Being provided with substantial amounts of filtered orifice, filtered orifice quantity is no less than 200, and filtered orifice diameter range value is between 1mm～3.5mm；Described
Catalyst adsorption particle body 2-8 is positioned at bottom dividing plate 2-7 overhead surface, and adsorption particle body 2-8 is equidistant arranged in parallel for catalyst, catalyst
Adsorption particle body 2-8 is no less than 2 layers, and every number of plies amount is no less than 100；Described catalyst adsorption particle body 2-8 includes: catalyst adsorbs
Ball 2-8-1, catalyst adsorption column 2-8-2；Described catalyst adsorbing sphere 2-8-1 profile is the chondritic of standard, catalyst adsorbing sphere 2-
8-1 diameter range is between 2mm～4mm；Described catalyst adsorption column 2-8-2 is positioned at catalyst adsorbing sphere 2-8-1 spherome surface, catalyst
Adsorption column 2-8-2 profile is the cylindrical-shaped structure of standard, and catalyst adsorption column 2-8-2 is on edge, catalyst adsorbing sphere 2-8-1 surface front and back
Left and right above-below direction is arranged symmetrically with, and catalyst adsorption column 2-8-2 quantity is between 4～20, and catalyst adsorption column 2-8-2 height is with tactile
Matchmaker's adsorbing sphere 2-8-1 diameter ratio is between 0.38:1～0.49:1；Described top layer dividing plate 2-10 is positioned at catalyst adsorption column 2-8-2
Top, top layer dividing plate 2-10 is the most identical with bottom dividing plate 2-7 contour structures size, top layer dividing plate 2-10 and purification clothes closet 2 housing
Inwall connects by chute is fixing；Described movable filter 2-11 between top layer dividing plate 2-10 and bottom dividing plate 2-7, movable every
Net 2-11 can free disassembly, cleaning, movable filter 2-11 is woven by elastomeric material and forms；Described outlet swing wind apparatus 2-12 is positioned at
Purifying clothes closet 2 front sidewall upper interior, outlet swing wind apparatus 2-12 is rotationally connected with purifying clothes closet 2 inwall by pin；Institute
State anion generator 2-5 and suspended pollution pellet degradation energy force transducer 2-6 and be respectively positioned on dedusting fall haze plate 2-3 and bottom dividing plate
In the cavity formed between 2-7, anion generator 2-5 and suspended pollution pellet degradation energy force transducer 2-6 with control is all
5 polygon control survey of uniting connect；Described gaseous contaminant degradation capability sensor 2-9 is positioned at bottom dividing plate 2-7 and top layer dividing plate 2-10
Between formed cavity in, gaseous contaminant degradation capability sensor 2-9 is connected with control system 5 polygon control survey.
Further, described outlet swing wind apparatus 2-12 includes: oscillating motor 2-12-1, oscillating cam 2-12-2, actively
Crank 2-12-3, follower link 2-12-4, induced draft plate 2-12-5；Described oscillating motor 2-12-1 and control system 5 polygon control survey
Connecting, oscillating motor 2-12-1 output spindle end connects has oscillating cam 2-12-2, described oscillating cam 2-12-2 main with output
Eccentric shaft is fixed, and oscillating cam 2-12-2 centrage sets away from output spindle centerline 4cm～8cm, oscillating cam 2-12-2 surface
Driving crank 2-12-3, driving crank 2-12-3 one end is had to be rotationally connected with oscillating cam 2-12-2 by pin, driving crank
The 2-12-3 other end is rotationally connected with follower link 2-12-4 by pin, and described follower link 2-12-4 is by polylith induced draft plate 2-
12-5 is serially connected, and induced draft plate 2-12-5 quantity is no less than 4 pieces, and the uniform equidistant vertical of induced draft plate 2-12-5 arranges, induced draft plate
2-12-5 thickness between 2mm～6mm, adjacent induced draft plate 2-12-5 spacing 2cm～5cm.
Further, described catalyst adsorption particle body 2-8 is by macromolecular material pressing mold molding, catalyst adsorption particle body 2-8
Constituent and manufacture process as follows:
One, catalyst adsorption particle body 2-8 constituent:
Count by weight, polyamidoimide 54～134 parts, α-bromine (2-chlorine) methyl phenylacetate 74～134 parts, acetic acid α-three
Chloromethylbenzene methyl ester 124～234 parts, α-trichloromethyl benzyl alcohol propionic ester 74～184 parts, formic acid-α, alpha-alpha-dimethyl phenethyl ester
64～134 parts, α-(4-hydroxy phenyl) methyl propionate 114～234 parts, concentration is two (to the methyl-benzyls) of 44ppm～84ppm
Stannum dichloride 74～114 parts, Dimethyl allyl p-methylbenzyl ammonium Chloride 64～124 parts, zephiran
64～154 parts, cross-linking agent 84～154 parts, docosyl benzyl chloride 44～124 parts, hexadecyl benzyl
Dimethyl Ammonium 74～164 parts, stearyl dimethyl benzyl ammonium chloride 34～64 parts, docosyl methyl isophthalic acid-myristyl
Ammonium chloride 34～114 parts；
Described cross-linking agent is N-cetyl-N, N-dimethyl benzyl ammonium chloride, N-2,3-glycidyl dimethyl dodecyl base
Ammonium chloride, N, any one in N, N-trimethyl-1-cetyl ammonium bromide；
Two, the manufacture process of catalyst adsorption particle body 2-8, comprises the steps of
1st step: add ultra-pure water 514～1104 parts that electrical conductivity is 0.34 μ S/cm～0.64 μ S/cm in a kettle., start
Agitator in reactor, rotating speed is 84rpm～224rpm, starts heat pump, makes reactor temperature rise to 54 DEG C～64 DEG C；
Being sequentially added into polyamidoimide, α-bromine (2-chlorine) methyl phenylacetate, acetic acid α-trichloromethyl benzene methyl, stirring is to the most molten
Solving, regulation pH value is 1.4～6.4, and agitator speed is adjusted to 114rpm～234rpm, and temperature is 74 DEG C～144 DEG C, and esterification is anti-
Answer 14～24 hours；
2nd step: take α-trichloromethyl benzyl alcohol propionic ester, formic acid-α, alpha-alpha-dimethyl phenethyl ester is pulverized, and powder diameter is
204～634 mesh；Add α-(4-hydroxy phenyl) methyl propionate mix homogeneously, be laid in pallet, tiling thickness be 14mm～
44mm, to use dosage be 1.4kGy～9.4kGy, energy is the alpha ray irradiation 44 of 5.4MeV～14MeV～124 minutes, and
The β x ray irradiation x 64 of Isodose～154 minutes；
3rd step: the mixed-powder processed through the 2nd step is dissolved in two (to methyl-benzyl) stannum dichloride, adds reactor, agitator
Rotating speed is 74rpm～174rpm, and temperature is 84 DEG C～134 DEG C, starts vacuum pump and makes the vacuum of reactor reach-0.34MPa
～-0.74MPa, keep this state response 14～44 hours；Pressure release is also passed through nitrogen, make reacting kettle inner pressure be 0.24MPa～
0.64MPa, insulation stands 14～24 hours；Agitator speed is promoted to 104rpm～244rpm, and simultaneous reactions still pressure release is extremely
0MPa；It is sequentially added into Dimethyl allyl p-methylbenzyl ammonium Chloride, after zephiran is completely dissolved, adds
Cross-linking agent stirring mixing so that the hydrophile-lipophile balance value of reactor solution is 3.4～6.4, and insulation stands 14～24 hours；
4th step: when agitator speed is 124rpm～254rpm, is sequentially added into docosyl benzyl chloride, chlorine
Change cetyl benzyl dimethyl ammonium, stearyl dimethyl benzyl ammonium chloride, docosyl methyl isophthalic acid-myristyl chlorination
Ammonium, promotes reactor pressure so that it is reaching 0.74MPa～1.54MPa, temperature is 124 DEG C～264 DEG C, polyreaction 14～34
Hour；After having reacted, reacting kettle inner pressure is down to 0MPa, is cooled to 24 DEG C～34 DEG C, discharging, enter molding press and can be prepared by
Catalyst adsorption particle body 2-8.
The invention also discloses the method for work of a kind of multi-deck cabinet type air cleaning instrument, the method includes following step
Rapid:
1st step: control system 5 starts air exhauster 2-1 by contaminated air in air inlet 1 inputs purification clothes closet 2, and passes through gas
Gas flow is controlled at 18m by effusion meter3/ h～48m3Between/h；Contaminated air takes the lead in flowing through inside spiral just chimney filter 2-2, position
In the first filter screen within spiral just chimney filter 2-2, contaminated air is carried out prefiltration process；
2nd step: the contaminated air after first filtration enters dedusting fall haze plate 2-3 and bottom dividing plate 2-7 by air intake shower nozzle 2-4
Between in the cavity that formed, now control system 5 starts anion generator 2-5 and launches substantial amounts of anion stream in cavity,
The suspended pollution granule of positively charged in anion stream absorption contaminated air, makes particulate matter constantly build up change weight, causes its disengaging gas molten
State and be deposited to dedusting fall haze plate 2-3 surface；
3rd step: the air containing amounts of residual contamination continues up and flows through catalyst adsorption particle body 2-8, catalyst adsorption particle body 2-8 continues
Gaseous contaminant in contaminated air is carried out further degradation treatment；Control system 5 starts outlet swing wind apparatus 2-12 afterwards
Operating, discharges purification clothes closet 2 by clean gas by air outlet 3；
4th step: during system worked well, the suspended pollution pellet degradation energy force transducer 2-6 degraded energy to suspended pollution granule
Power is monitored in real time, when the degradation capability of suspended pollution granule is less than 38%～58%, and suspended pollution pellet degradation ability
Automatically controlled signal is fed back to control system 5 by sensor 2-6, and control system 5 controls anion generator 2-5 and strengthens anion stream
Emission measure；When suspended pollution pellet degradation energy force transducer 2-6 monitors the degradation capability recovery normal value of suspended pollution granule
Time, automatically controlled signal is fed back to control system 5 by suspended pollution pellet degradation energy force transducer 2-6, and control system 5 controls anion
Generator 2-5 anion stream recovers normal transmission amount；
5th step: the degradation capability of gaseous contaminant is monitored by gaseous contaminant degradation capability sensor 2-9 in real time, works as gas
When the degradation capability of state pollutant is less than 36%～56%, automatically controlled signal is fed back by gaseous contaminant degradation capability sensor 2-9
To control system 5, control system 5 cutting system power supply makes whole device quit work, and sends audio signal, points out work
Personnel open maintenance dodge gate 4 and change catalyst adsorption particle body 2-8；When gaseous contaminant degradation capability sensor 2-9 monitors
When the degradation capability of gaseous contaminant returns to normal value, automatically controlled signal is fed back by gaseous contaminant degradation capability sensor 2-9
To control system 5, control system 5 is connected system power supply and whole device is resumed work.
A kind of multi-deck cabinet type air cleaning instrument and method of work thereof disclosed in patent of the present invention, have an advantage in that:
(1) this device uses multistage purification layer, and air cleaning is more thorough；
(2) this apparatus structure is reasonable in design compact, and integrated level is high；
(3) this device catalyst adsorption particle body uses macromolecular material to prepare, and gaseous contaminant degradation speed promotes notable.
A kind of multi-deck cabinet type air cleaning instrument of the present invention and method of work novel and reasonable structure thereof, air cleaning is imitated
Rate is efficient, and the scope of application is wide.
Accompanying drawing explanation
Fig. 1 is heretofore described a kind of multi-deck cabinet type air cleaning instrument schematic diagram.
Fig. 2 is heretofore described purification clothes closet internal structure schematic diagram.
Fig. 3 is heretofore described catalyst adsorption particle body arrangement schematic diagram.
Fig. 4 is heretofore described catalyst adsorption particle body structural representation.
Fig. 5 is heretofore described outlet swing wind apparatus structural representation.
Fig. 6 is catalyst adsorption particle body material of the present invention and gaseous contaminant degradation speed conservation rate graph of a relation.
In figure 1 above～Fig. 5, air inlet 1, purify clothes closet 2, air exhauster 2-1, spiral just chimney filter 2-2, dedusting fall haze plate 2-
3, air intake shower nozzle 2-4, anion generator 2-5, suspended pollution pellet degradation energy force transducer 2-6, bottom dividing plate 2-7, catalyst
Adsorption particle body 2-8, catalyst adsorbing sphere 2-8-1, catalyst adsorption column 2-8-2, gaseous contaminant degradation capability sensor 2-9, top
Layer dividing plate 2-10, movable filter 2-11, outlet swing wind apparatus 2-12, oscillating motor 2-12-1, oscillating cam 2-12-2, the most bent
Handle 2-12-3, follower link 2-12-4, induced draft plate 2-12-5, air outlet 3, overhauls dodge gate 4, control system 5.
Detailed description of the invention
A kind of multi-deck cabinet type air cleaning instrument provided the present invention with embodiment below in conjunction with the accompanying drawings is carried out furtherly
Bright.
As it is shown in figure 1, be the schematic diagram of a kind of multi-deck cabinet type air cleaning instrument that the present invention provides.Figure is found out, including:
Air inlet 1, purifies clothes closet 2, air outlet 3, overhauls dodge gate 4, control system 5；Described purification clothes closet 2 sidewall bottom is provided with air intake
Mouth 1, described purification clothes closet 2 front sidewall is arranged over air outlet 3, and described purification clothes closet 2 front sidewall bottom is provided with control system
System 5, described purification clothes closet 2 front sidewall interlude is provided with maintenance dodge gate 4, described maintenance dodge gate 4 and purification clothes closet 2 hinge
It is flexibly connected.
As shown in Figure 2, Figure 3, Figure 4, it is heretofore described purification clothes closet internal structure schematic diagram, catalyst adsorption particle
Body arrangement schematic diagram and catalyst adsorption particle body structural representation.Find out from Fig. 2, Fig. 3, Fig. 4 or Fig. 1, described purification clothes closet 2
Including: air exhauster 2-1, spiral just chimney filter 2-2, dedusting fall haze plate 2-3, air intake shower nozzle 2-4, anion generator 2-5, suspend dirt
Dye pellet degradation energy force transducer 2-6, bottom dividing plate 2-7, catalyst adsorption particle body 2-8, gaseous contaminant degradation capability senses
Device 2-9, top layer dividing plate 2-10, movable filter 2-11, outlet swing wind apparatus 2-12；Described air exhauster 2-1 is positioned at purification clothes closet 2 shell
Baseplane, internal portion, the startup motor on air exhauster 2-1 is connected with control system 5 polygon control survey, air exhauster 2-1 side and air intake
Mouth 1 is connected, and air exhauster 2-1 opposite side is connected with spiral just chimney filter 2-2 air inlet；It is vertical that described spiral just chimney filter 2-2 is positioned at purification
Cabinet 2 enclosure interior, near bottom position, is provided with just filter screen inside spiral just chimney filter 2-2, and the spiral just chimney filter 2-2 number of turns is no less than 6
Circle, the internal total flight of spiral just chimney filter 2-2 is no less than 1.5m～2m；Described dedusting fall haze plate 2-3 is positioned at spiral just chimney filter
Above 2-2, dedusting fall haze plate 2-3 is connected by chute is fixing with purifying clothes closet 2 inner walls；Described air intake shower nozzle 2-4 is positioned at
Dedusting fall haze plate 2-3 overhead surface, air intake shower nozzle 2-4 is connected with spiral just chimney filter 2-2 air outlet；Described bottom dividing plate 2-7
Be positioned at above dedusting fall haze plate 2-3, bottom dividing plate 2-7 and dedusting fall haze plate 2-3 spacing 20cm～40cm, bottom dividing plate 2-7 with
Purifying clothes closet 2 inner walls to connect by chute is fixing, bottom dividing plate 2-7 surface is provided with substantial amounts of filtered orifice, filtered orifice quantity
No less than 200, filtered orifice diameter range value is between 1mm～3.5mm；Described catalyst adsorption particle body 2-8 be positioned at bottom every
Plate 2-7 overhead surface, adsorption particle body 2-8 is equidistant arranged in parallel for catalyst, and catalyst adsorption particle body 2-8 is no less than 2 layers, every layer
Quantity is no less than 100；Described catalyst adsorption particle body 2-8 includes: catalyst adsorbing sphere 2-8-1, catalyst adsorption column 2-8-2；Institute
Stating the chondritic that catalyst adsorbing sphere 2-8-1 profile is standard, catalyst adsorbing sphere 2-8-1 diameter range is between 2mm～4mm；
Described catalyst adsorption column 2-8-2 is positioned at catalyst adsorbing sphere 2-8-1 spherome surface, and catalyst adsorption column 2-8-2 profile is the circle of standard
Column structure, catalyst adsorption column 2-8-2 is arranged symmetrically with along above-below direction all around on catalyst adsorbing sphere 2-8-1 surface, catalyst
Adsorption column 2-8-2 quantity is between 4～20, and catalyst adsorption column 2-8-2 height exists with catalyst adsorbing sphere 2-8-1 diameter ratio
Between 0.38:1～0.49:1；Described top layer dividing plate 2-10 is positioned at above catalyst adsorption column 2-8-2, top layer dividing plate 2-10 and bottom
Dividing plate 2-7 contour structures size is the most identical, and top layer dividing plate 2-10 is connected by chute is fixing with purifying clothes closet 2 inner walls；Institute
State movable filter 2-11 between top layer dividing plate 2-10 and bottom dividing plate 2-7, movable filter 2-11 can free disassembly, cleaning, work
Dynamic filter 2-11 is formed by elastomeric material braiding；Described outlet swing wind apparatus 2-12 is positioned at above the sidewall of purification clothes closet 2 front
Portion, outlet swing wind apparatus 2-12 is rotationally connected with purifying clothes closet 2 inwall by pin；Described anion generator 2-5 and suspension
Pollute pellet degradation energy force transducer 2-6 to be respectively positioned between dedusting fall haze plate 2-3 and bottom dividing plate 2-7 in the cavity formed, negative
Ion generator 2-5 and suspended pollution pellet degradation energy force transducer 2-6 is all connected with control system 5 polygon control survey；Described gas
In the cavity that state contaminant degradation energy force transducer 2-9 is formed between bottom dividing plate 2-7 and top layer dividing plate 2-10, gaseous state is dirty
Dye thing degradation capability sensor 2-9 is connected with control system 5 polygon control survey.
As it is shown in figure 5, be heretofore described outlet swing wind apparatus structural representation.Find out from Fig. 5 or Fig. 1, institute
State outlet swing wind apparatus 2-12 to include: oscillating motor 2-12-1, oscillating cam 2-12-2, driving crank 2-12-3, follower link
2-12-4, induced draft plate 2-12-5；Described oscillating motor 2-12-1 is connected with control system 5 polygon control survey, oscillating motor 2-12-1
Output spindle end connects has oscillating cam 2-12-2, described oscillating cam 2-12-2 to fix with output spindle eccentricity, oscillating cam
2-12-2 centrage is provided with driving crank 2-12-3 away from output spindle centerline 4cm～8cm, oscillating cam 2-12-2 surface, main
Dynamic crank 2-12-3 one end is rotationally connected with oscillating cam 2-12-2 by pin, and the driving crank 2-12-3 other end passes through pin
Being rotationally connected with follower link 2-12-4, polylith induced draft plate 2-12-5 is serially connected by described follower link 2-12-4, air inducing
Plate 2-12-5 quantity is no less than 4 pieces, and the uniform equidistant vertical of induced draft plate 2-12-5 arranges, and induced draft plate 2-12-5 thickness is at 2mm～6mm
Between, adjacent induced draft plate 2-12-5 spacing 2cm～5cm.
The work process of a kind of multi-deck cabinet type air cleaning instrument of the present invention is:
1st step: control system 5 starts air exhauster 2-1 by contaminated air in air inlet 1 inputs purification clothes closet 2, and passes through gas
Gas flow is controlled at 18m by effusion meter3/ h～48m3Between/h；Contaminated air takes the lead in flowing through inside spiral just chimney filter 2-2, position
In the first filter screen within spiral just chimney filter 2-2, contaminated air is carried out prefiltration process；
2nd step: the contaminated air after first filtration enters dedusting fall haze plate 2-3 and bottom dividing plate 2-7 by air intake shower nozzle 2-4
Between in the cavity that formed, now control system 5 starts anion generator 2-5 and launches substantial amounts of anion stream in cavity,
The suspended pollution granule of positively charged in anion stream absorption contaminated air, makes particulate matter constantly build up change weight, causes its disengaging gas molten
State and be deposited to dedusting fall haze plate 2-3 surface；
3rd step: the air containing amounts of residual contamination continues up and flows through catalyst adsorption particle body 2-8, catalyst adsorption particle body 2-8 continues
Gaseous contaminant in contaminated air is carried out further degradation treatment；Control system 5 starts outlet swing wind apparatus 2-12 afterwards
Operating, discharges purification clothes closet 2 by clean gas by air outlet 3；
4th step: during system worked well, the suspended pollution pellet degradation energy force transducer 2-6 degraded energy to suspended pollution granule
Power is monitored in real time, when the degradation capability of suspended pollution granule is less than 38%～58%, and suspended pollution pellet degradation ability
Automatically controlled signal is fed back to control system 5 by sensor 2-6, and control system 5 controls anion generator 2-5 and strengthens anion stream
Emission measure；When suspended pollution pellet degradation energy force transducer 2-6 monitors the degradation capability recovery normal value of suspended pollution granule
Time, automatically controlled signal is fed back to control system 5 by suspended pollution pellet degradation energy force transducer 2-6, and control system 5 controls anion
Generator 2-5 anion stream recovers normal transmission amount；
5th step: the degradation capability of gaseous contaminant is monitored by gaseous contaminant degradation capability sensor 2-9 in real time, works as gas
When the degradation capability of state pollutant is less than 36%～56%, automatically controlled signal is fed back by gaseous contaminant degradation capability sensor 2-9
To control system 5, control system 5 cutting system power supply makes whole device quit work, and sends audio signal, points out work
Personnel open maintenance dodge gate 4 and change catalyst adsorption particle body 2-8；When gaseous contaminant degradation capability sensor 2-9 monitors
When the degradation capability of gaseous contaminant returns to normal value, automatically controlled signal is fed back by gaseous contaminant degradation capability sensor 2-9
To control system 5, control system 5 is connected system power supply and whole device is resumed work.
A kind of multi-deck cabinet type air cleaning instrument of the present invention and method of work novel and reasonable structure thereof, air cleaning is imitated
Rate is efficient, and the scope of application is wide.
The following is the embodiment of the manufacture process of catalyst adsorption particle body 2-8 of the present invention, embodiment is to enter one
Step explanation present disclosure, but should not be construed as limitation of the present invention.Without departing substantially from present invention spirit and the situation of essence
Under, the amendment that the inventive method, step or condition are made and replacement, belong to the scope of the present invention.
If not specializing, the conventional means that technological means used in embodiment is well known to those skilled in the art.
Embodiment 1
According to following steps manufacture catalyst adsorption particle body 2-8 of the present invention, and mark meter by weight:
1st step: add the ultra-pure water 513 parts that electrical conductivity is 0.34 μ S/cm in a kettle., start agitator in reactor, turn
Speed is 84rpm, starts heat pump, makes reactor temperature rise to 54 DEG C；It is sequentially added into polyamidoimide 54 parts, α-bromine
(2-chlorine) methyl phenylacetate 74 parts, acetic acid α-trichloromethyl benzene methyl 124 parts, stirring is to being completely dissolved, and regulation pH value is 1.4,
Agitator speed is adjusted to 114rpm, and temperature is 74 DEG C, esterification 14 hours；
2nd step: take α-trichloromethyl benzyl alcohol propionic ester 74 parts, formic acid-α, alpha-alpha-dimethyl phenethyl ester 64 parts is pulverized, powder
Particle diameter is 204 mesh；Adding α-114 parts of mix homogeneously of (4-hydroxy phenyl) methyl propionate, be laid in pallet, tiling thickness is
14mm, the alpha ray irradiation 44 minutes that employing dosage is 1.4kGy, energy is 5.4MeV, and the β x ray irradiation x 64 of Isodose
Minute；
3rd step: the mixed-powder processed through the 2nd step is dissolved in two (to methyl-benzyl) stannum dichloride 74 parts that concentration is 44ppm,
Add reactor, agitator speed is 74rpm, and temperature is 84 DEG C, start vacuum pump make the vacuum of reactor reach-
0.34MPa, keeps this state response 14 hours；Pressure release is also passed through nitrogen, and making reacting kettle inner pressure is 0.24MPa, and insulation stands
14 hours；Agitator speed is promoted to 104rpm, simultaneous reactions still pressure release to 0MPa；It is sequentially added into dimethyl-allyl to methyl
After benzyl ammonium chloride 64 parts, zephiran 64 parts are completely dissolved, add cross-linking agent 84 parts stirring mixing so that
The hydrophile-lipophile balance value of reactor solution is 3.4, and insulation stands 14 hours；
4th step: when agitator speed is 124rpm, is sequentially added into docosyl benzyl chloride 44 parts, chlorination ten
Six alkyl benzyl dimethyl ammoniums 74 parts, stearyl dimethyl benzyl ammonium chloride 34 parts, docosyl methyl isophthalic acid-myristyl
Ammonium chloride 34 parts, promotes reactor pressure so that it is reaching 0.74MPa, temperature is 124 DEG C, polyreaction 14 hours；Reaction completes
After reacting kettle inner pressure is down to 0MPa, be cooled to 24 DEG C, discharging, enter molding press and can be prepared by catalyst adsorption particle body 2-8；
Described cross-linking agent is N-cetyl-N, N-dimethyl benzyl ammonium chloride.
Embodiment 2
According to following steps manufacture catalyst adsorption particle body 2-8 of the present invention, and mark meter by weight:
1st step: add the ultra-pure water 1104 parts that electrical conductivity is 0.64 μ S/cm in a kettle., start agitator in reactor, turn
Speed is 224rpm, starts heat pump, makes reactor temperature rise to 64 DEG C；It is sequentially added into polyamidoimide 134 parts, α-bromine
(2-chlorine) methyl phenylacetate 134 parts, acetic acid α-trichloromethyl benzene methyl 234 parts, stirring is to being completely dissolved, and regulation pH value is 6.4,
Agitator speed is adjusted to 234rpm, and temperature is 144 DEG C, esterification 24 hours；
2nd step: take α-trichloromethyl benzyl alcohol propionic ester 184 parts, formic acid-α, alpha-alpha-dimethyl phenethyl ester 134 parts is pulverized, powder
End particle diameter is 634 mesh；Adding α-234 parts of mix homogeneously of (4-hydroxy phenyl) methyl propionate, be laid in pallet, tiling thickness is
44mm, the alpha ray irradiation 124 minutes that employing dosage is 9.4kGy, energy is 14MeV, and the β x ray irradiation x of Isodose
154 minutes；
3rd step: the mixed-powder processed through the 2nd step is dissolved in two (to methyl-benzyl) stannum dichloride 114 parts that concentration is 84ppm
In, add reactor, agitator speed is 174rpm, and temperature is 134 DEG C, start vacuum pump make the vacuum of reactor reach-
0.74MPa, keeps this state response 44 hours；Pressure release is also passed through nitrogen, and making reacting kettle inner pressure is 0.64MPa, and insulation stands
24 hours；Agitator speed is promoted to 244rpm, simultaneous reactions still pressure release to 0MPa；It is sequentially added into dimethyl-allyl to methyl
After benzyl ammonium chloride 124 parts, zephiran 154 parts are completely dissolved, add cross-linking agent 154 parts stirring mixing,
The hydrophile-lipophile balance value making reactor solution is 6.4, and insulation stands 24 hours；
4th step: when agitator speed is 254rpm, is sequentially added into docosyl benzyl chloride 124 parts, chlorination ten
Six alkyl benzyl dimethyl ammoniums 164 parts, stearyl dimethyl benzyl ammonium chloride 64 parts, docosyl methyl isophthalic acid-tetradecane
Ammonium chloride 114 parts, promotes reactor pressure so that it is reaching 1.54MPa, temperature is 264 DEG C, polyreaction 34 hours；Reaction
After completing, reacting kettle inner pressure is down to 0MPa, is cooled to 34 DEG C, discharging, enter molding press and can be prepared by catalyst adsorption particle body 2-
8；
Described cross-linking agent is N, N, N-trimethyl-1-cetyl ammonium bromide.
Embodiment 3
According to following steps manufacture catalyst adsorption particle body 2-8 of the present invention, and mark meter by weight:
1st step: add the ultra-pure water 904 parts that electrical conductivity is 0.54 μ S/cm in a kettle., start agitator in reactor, turn
Speed is 124rpm, starts heat pump, makes reactor temperature rise to 58 DEG C；It is sequentially added into polyamidoimide 104 parts, α-bromine
(2-chlorine) methyl phenylacetate 94 parts, acetic acid α-trichloromethyl benzene methyl 134 parts, stirring is to being completely dissolved, and regulation pH value is 3.4,
Agitator speed is adjusted to 134rpm, and temperature is 94 DEG C, esterification 18 hours；
2nd step: take α-trichloromethyl benzyl alcohol propionic ester 124 parts, formic acid-α, alpha-alpha-dimethyl phenethyl ester 104 parts is pulverized, powder
End particle diameter is 434 mesh；Adding α-134 parts of mix homogeneously of (4-hydroxy phenyl) methyl propionate, be laid in pallet, tiling thickness is
24mm, the alpha ray irradiation 64 minutes that employing dosage is 6.4kGy, energy is 10MeV, and the β x ray irradiation x 124 of Isodose
Minute；
3rd step: the mixed-powder processed through the 2nd step is dissolved in two (to methyl-benzyl) stannum dichloride 94 parts that concentration is 64ppm,
Add reactor, agitator speed is 124rpm, and temperature is 114 DEG C, start vacuum pump make the vacuum of reactor reach-
0.64MPa, keeps this state response 34 hours；Pressure release is also passed through nitrogen, and making reacting kettle inner pressure is 0.54MPa, and insulation stands
18 hours；Agitator speed is promoted to 144rpm, simultaneous reactions still pressure release to 0MPa；It is sequentially added into dimethyl-allyl to methyl
After benzyl ammonium chloride 94 parts, zephiran 94 parts are completely dissolved, add cross-linking agent 94 parts stirring mixing so that
The hydrophile-lipophile balance value of reactor solution is 5.4, and insulation stands 18 hours；
4th step: when agitator speed is 154rpm, is sequentially added into docosyl benzyl chloride 94 parts, chlorination ten
Six alkyl benzyl dimethyl ammoniums 94 parts, stearyl dimethyl benzyl ammonium chloride 54 parts, docosyl methyl isophthalic acid-myristyl
Ammonium chloride 64 parts, promotes reactor pressure so that it is reaching 1.34MPa, temperature is 164 DEG C, polyreaction 24 hours；Reaction completes
After reacting kettle inner pressure is down to 0MPa, be cooled to 30 DEG C, discharging, enter molding press and can be prepared by catalyst adsorption particle body 2-8；
Described cross-linking agent is N-2,3-glycidyl dimethyl dodecyl ammonium chloride.
Reference examples
Reference examples is the catalyst adsorption particle body processing procedure for gaseous contaminant of certain brand commercially available.
Embodiment 4
Catalyst adsorption particle body described in catalyst adsorption particle body 2-8 embodiment 1～3 prepared and reference examples is used for gas
The service condition of state Pollutant Treatment process contrasts, and with catalytic polymerization degree, use duration, degradation rate, corrosion resistant rate as skill
Art index is added up, and result is as shown in table 1:
Table 1 is every in gaseous contaminant processing procedure of the catalyst adsorption particle body described in embodiment 1～3 and reference examples
The comparing result of parameter, as seen from Table 1, catalyst adsorption particle body 2-8 of the present invention, its catalytic polymerization degree, use duration,
Degradation rate, corrosion resistant rate are above the product that prior art produces.
Additionally, as shown in Figure 6, it is catalyst adsorption particle body 2-8 material of the present invention and gaseous contaminant degraded speed
Degree conservation rate graph of a relation.Figure is found out, macromolecule catalyst adsorption particle body 2-8 used by embodiment 1～3, drop at gaseous contaminant
Solve speed conservation rate aspect and be better than existing product.
Claims (5)
1. a multi-deck cabinet type air cleaning instrument, including: air inlet (1), purify clothes closet (2), air outlet (3), overhaul dodge gate
(4), control system (5)；It is characterized in that, described purification clothes closet (2) sidewall bottom is provided with air inlet (1), described purification clothes closet
(2) front sidewall is arranged over air outlet (3), and described purification clothes closet (2) front sidewall bottom is provided with control system (5), described
Purify clothes closet (2) front sidewall interlude and be provided with maintenance dodge gate (4), described maintenance dodge gate (4) and purification clothes closet (2) hinge
It is flexibly connected.
A kind of multi-deck cabinet type air cleaning instrument the most according to claim 1, it is characterised in that described purification clothes closet (2) is wrapped
Include: air exhauster (2-1), spiral just chimney filter (2-2), dedusting fall haze plate (2-3), air intake shower nozzle (2-4), anion generator (2-
5), suspended pollution pellet degradation energy force transducer (2-6), bottom dividing plate (2-7), catalyst adsorption particle body (2-8), gaseous contamination
Thing degradation capability sensor (2-9), top layer dividing plate (2-10), movable filter (2-11), outlet swing wind apparatus (2-12)；Described take out
Blower fan (2-1) is positioned at purification clothes closet (2) enclosure interior baseplane, and the startup motor on air exhauster (2-1) is led with control system (5)
Line traffic control connects, and air exhauster (2-1) side is connected with air inlet (1), air exhauster (2-1) opposite side and spiral just chimney filter (2-2)
Air inlet is connected；Chimney filter (2-2) at the beginning of described spiral is positioned at purification clothes closet (2) enclosure interior near chimney filter at the beginning of bottom position, spiral
(2-2) inside is provided with just filter screen, and spiral just chimney filter (2-2) number of turns is enclosed no less than 6, the internal total spiral row of the first chimney filter (2-2) of spiral
Journey is no less than 1.5m～2m；Described dedusting fall haze plate (2-3) is positioned at spiral just chimney filter (2-2) top, dedusting fall haze plate (2-3) with
Purify clothes closet (2) inner walls to connect by chute is fixing；Described air intake shower nozzle (2-4) is positioned at dedusting fall haze plate (2-3) top
Surface, air intake shower nozzle (2-4) is connected with spiral just chimney filter (2-2) air outlet；Described bottom dividing plate (2-7) is positioned at dedusting fall haze
Plate (2-3) top, bottom dividing plate (2-7) and dedusting fall haze plate (2-3) spacing 20cm～40cm, bottom dividing plate (2-7) and purification
Clothes closet (2) inner walls connects by chute is fixing, and bottom dividing plate (2-7) surface is provided with substantial amounts of filtered orifice, filtered orifice quantity
No less than 200, filtered orifice diameter range value is between 1mm～3.5mm；Described catalyst adsorption particle body (2-8) is positioned at bottom
Dividing plate (2-7) overhead surface, catalyst adsorption particle body (2-8) is equidistant arranged in parallel, and catalyst adsorption particle body (2-8) is no less than
2 layers, every number of plies amount is no less than 100；Described catalyst adsorption particle body (2-8) including: catalyst adsorbing sphere (2-8-1), and catalyst is inhaled
Attached column (2-8-2)；Described catalyst adsorbing sphere (2-8-1) profile is the chondritic of standard, catalyst adsorbing sphere (2-8-1) diameter model
It is trapped among between 2mm～4mm；Described catalyst adsorption column (2-8-2) is positioned at catalyst adsorbing sphere (2-8-1) spherome surface, and catalyst adsorbs
Post (2-8-2) profile is the cylindrical-shaped structure of standard, catalyst adsorption column (2-8-2) on catalyst adsorbing sphere (2-8-1) surface along front
The right above-below direction of rear left is arranged symmetrically with, and catalyst adsorption column (2-8-2) quantity is between 4～20, and catalyst adsorption column (2-8-2) is high
Degree and catalyst adsorbing sphere (2-8-1) diameter ratio are between 0.38:1～0.49:1；Described top layer dividing plate (2-10) is positioned at catalyst
Adsorption column (2-8-2) top, top layer dividing plate (2-10) is the most identical with bottom dividing plate (2-7) contour structures size, top layer dividing plate (2-
10) it is connected by chute is fixing with purification clothes closet (2) inner walls；Described movable filter (2-11) is positioned at top layer dividing plate (2-10)
And between bottom dividing plate (2-7), movable filter (2-11) can free disassembly, cleaning, activity filter (2-11) is woven by elastomeric material
Form；Described outlet swing wind apparatus (2-12) is positioned at purification clothes closet (2) front sidewall upper interior, outlet swing wind apparatus (2-12)
It is rotationally connected with purifying clothes closet (2) inwall by pin；Described anion generator (2-5) and suspended pollution pellet degradation ability
Sensor (2-6) is respectively positioned between dedusting fall haze plate (2-3) and bottom dividing plate (2-7) in the cavity formed, anion generator
(2-5) and suspended pollution pellet degradation energy force transducer (2-6) is all connected with control system (5) polygon control survey；Described gaseous state is dirty
Dye thing degradation capability sensor (2-9) is positioned between bottom dividing plate (2-7) and top layer dividing plate (2-10) cavity formed, gaseous state
Contaminant degradation energy force transducer (2-9) is connected with control system (5) polygon control survey.
A kind of multi-deck cabinet type air cleaning instrument the most according to claim 2, it is characterised in that described outlet swing wind apparatus
(2-12) including: oscillating motor (2-12-1), oscillating cam (2-12-2), driving crank (2-12-3), follower link (2-12-
4), induced draft plate (2-12-5)；Described oscillating motor (2-12-1) is connected with control system (5) polygon control survey, oscillating motor (2-
12-1) output spindle end connects oscillating cam (2-12-2), and described oscillating cam (2-12-2) is fixed with output spindle eccentricity,
Oscillating cam (2-12-2) centrage is provided with the most bent away from output spindle centerline 4cm～8cm, oscillating cam (2-12-2) surface
Handle (2-12-3), driving crank (2-12-3) one end is rotationally connected with oscillating cam (2-12-2) by pin, driving crank (2-
12-3) other end is rotationally connected with follower link (2-12-4) by pin, and described follower link (2-12-4) is by polylith air inducing
Plate (2-12-5) is serially connected, and induced draft plate (2-12-5) quantity is no less than 4 pieces, induced draft plate (2-12-5) uniformly equidistant vertical row
Row, induced draft plate (2-12-5) thickness between 2mm～6mm, adjacent induced draft plate (2-12-5) spacing 2cm～5cm.
A kind of multi-deck cabinet type air cleaning instrument the most according to claim 2, it is characterised in that described catalyst adsorption particle body
(2-8) by macromolecular material pressing mold molding, constituent and the manufacture process of catalyst adsorption particle body (2-8) are as follows:
One, catalyst adsorption particle body (2-8) constituent:
Count by weight, polyamidoimide 54～134 parts, α-bromine (2-chlorine) methyl phenylacetate 74～134 parts, acetic acid α-three
Chloromethylbenzene methyl ester 124～234 parts, α-trichloromethyl benzyl alcohol propionic ester 74～184 parts, formic acid-α, alpha-alpha-dimethyl phenethyl ester
64～134 parts, α-(4-hydroxy phenyl) methyl propionate 114～234 parts, concentration is two (to the methyl-benzyls) of 44ppm～84ppm
Stannum dichloride 74～114 parts, Dimethyl allyl p-methylbenzyl ammonium Chloride 64～124 parts, zephiran
64～154 parts, cross-linking agent 84～154 parts, docosyl benzyl chloride 44～124 parts, hexadecyl benzyl
Dimethyl Ammonium 74～164 parts, stearyl dimethyl benzyl ammonium chloride 34～64 parts, docosyl methyl isophthalic acid-myristyl
Ammonium chloride 34～114 parts；
Described cross-linking agent is N-cetyl-N, N-dimethyl benzyl ammonium chloride, N-2,3-glycidyl dimethyl dodecyl base
Ammonium chloride, N, any one in N, N-trimethyl-1-cetyl ammonium bromide；
Two, the manufacture process of catalyst adsorption particle body (2-8), comprises the steps of
1st step: add ultra-pure water 514～1104 parts that electrical conductivity is 0.34 μ S/cm～0.64 μ S/cm in a kettle., start
Agitator in reactor, rotating speed is 84rpm～224rpm, starts heat pump, makes reactor temperature rise to 54 DEG C～64 DEG C；
Being sequentially added into polyamidoimide, α-bromine (2-chlorine) methyl phenylacetate, acetic acid α-trichloromethyl benzene methyl, stirring is to the most molten
Solving, regulation pH value is 1.4～6.4, and agitator speed is adjusted to 114rpm～234rpm, and temperature is 74 DEG C～144 DEG C, and esterification is anti-
Answer 14～24 hours；
2nd step: take α-trichloromethyl benzyl alcohol propionic ester, formic acid-α, alpha-alpha-dimethyl phenethyl ester is pulverized, and powder diameter is
204～634 mesh；Add α-(4-hydroxy phenyl) methyl propionate mix homogeneously, be laid in pallet, tiling thickness be 14mm～
44mm, to use dosage be 1.4kGy～9.4kGy, energy is the alpha ray irradiation 44 of 5.4MeV～14MeV～124 minutes, and
The β x ray irradiation x 64 of Isodose～154 minutes；
3rd step: the mixed-powder processed through the 2nd step is dissolved in two (to methyl-benzyl) stannum dichloride, adds reactor, agitator
Rotating speed is 74rpm～174rpm, and temperature is 84 DEG C～134 DEG C, starts vacuum pump and makes the vacuum of reactor reach-0.34MPa
～-0.74MPa, keep this state response 14～44 hours；Pressure release is also passed through nitrogen, make reacting kettle inner pressure be 0.24MPa～
0.64MPa, insulation stands 14～24 hours；Agitator speed is promoted to 104rpm～244rpm, and simultaneous reactions still pressure release is extremely
0MPa；It is sequentially added into Dimethyl allyl p-methylbenzyl ammonium Chloride, after zephiran is completely dissolved, adds
Cross-linking agent stirring mixing so that the hydrophile-lipophile balance value of reactor solution is 3.4～6.4, and insulation stands 14～24 hours；
4th step: when agitator speed is 124rpm～254rpm, is sequentially added into docosyl benzyl chloride, chlorine
Change cetyl benzyl dimethyl ammonium, stearyl dimethyl benzyl ammonium chloride, docosyl methyl isophthalic acid-myristyl chlorination
Ammonium, promotes reactor pressure so that it is reaching 0.74MPa～1.54MPa, temperature is 124 DEG C～264 DEG C, polyreaction 14～34
Hour；After having reacted, reacting kettle inner pressure is down to 0MPa, is cooled to 24 DEG C～34 DEG C, discharging, enter molding press and can be prepared by
Catalyst adsorption particle body (2-8).
5. the method for work of a multi-deck cabinet type air cleaning instrument, it is characterised in that the method includes following step:
1st step: control system (5) starts air exhauster (2-1) and purified in clothes closet (2) through air inlet (1) input by contaminated air, and
By gas flowmeter, gas flow is controlled at 18m3/ h～48m3Between/h；Contaminated air takes the lead in flowing through spiral just chimney filter (2-
2) internal, it is positioned at the spiral first filter screen that just chimney filter (2-2) is internal and contaminated air is carried out prefiltration process；
2nd step: the contaminated air after first filtration by air intake shower nozzle (2-4) enter dedusting fall haze plate (2-3) and bottom every
In the cavity formed between plate (2-7), now control system (5) startup anion generator (2-5) is launched in cavity in a large number
Anion stream, the suspended pollution granule of positively charged in anion stream absorption contaminated air, make particulate matter constantly build up change weight, cause
It departs from the molten state of gas and is deposited to dedusting fall haze plate (2-3) surface；
3rd step: the air containing amounts of residual contamination continues up and flows through catalyst adsorption particle body (2-8), catalyst adsorption particle body (2-8)
Continue the gaseous contaminant in contaminated air is carried out further degradation treatment；Control system (5) starts swing air-out dress afterwards
Put (2-12) operating, clean gas is discharged by air outlet (3) and purifies clothes closet (2)；
4th step: during system worked well, suspended pollution pellet degradation energy force transducer (2-6) degraded to suspended pollution granule
Ability is monitored in real time, when the degradation capability of suspended pollution granule is less than 38%～58%, and suspended pollution pellet degradation energy
Automatically controlled signal is fed back to control system (5) by force transducer (2-6), and control system (5) controls anion generator (2-5) and strengthens
The emission measure of anion stream；When suspended pollution pellet degradation energy force transducer (2-6) monitors the degraded energy of suspended pollution granule
When power recovers normal value, automatically controlled signal is fed back to control system (5) by suspended pollution pellet degradation energy force transducer (2-6), control
System processed (5) controls anion generator (2-5) anion stream and recovers normal transmission amount；
5th step: the degradation capability of gaseous contaminant is monitored by gaseous contaminant degradation capability sensor (2-9) in real time, when
When the degradation capability of gaseous contaminant is less than 36%～56%, gaseous contaminant degradation capability sensor (2-9) is by automatically controlled signal
Feeding back to control system (5), control system (5) cutting system power supply makes whole device quit work, and sends audio signal,
Prompting staff opens maintenance dodge gate (4) and changes catalyst adsorption particle body (2-8)；When gaseous contaminant degradation capability senses
Device (2-9) monitors the degradation capability of gaseous contaminant when returning to normal value, gaseous contaminant degradation capability sensor (2-9)
Automatically controlled signal feeds back to control system (5), and control system (5) is connected system power supply and whole device is resumed work.
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| CN107029506A (en) * | 2017-05-21 | 2017-08-11 | 成都蒲江珂贤科技有限公司 | A kind of device for filtering Air haze |
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