CN106193484A - A kind of wet sensitive colour changing wall paper and preparation technology thereof - Google Patents
A kind of wet sensitive colour changing wall paper and preparation technology thereof Download PDFInfo
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- CN106193484A CN106193484A CN201610693451.7A CN201610693451A CN106193484A CN 106193484 A CN106193484 A CN 106193484A CN 201610693451 A CN201610693451 A CN 201610693451A CN 106193484 A CN106193484 A CN 106193484A
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- E—FIXED CONSTRUCTIONS
- E04—BUILDING
- E04F—FINISHING WORK ON BUILDINGS, e.g. STAIRS, FLOORS
- E04F13/00—Coverings or linings, e.g. for walls or ceilings
- E04F13/002—Coverings or linings, e.g. for walls or ceilings made of webs, e.g. of fabrics, or wallpaper, used as coverings or linings
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K13/00—Use of mixtures of ingredients not covered by one single of the preceding main groups, each of these compounds being essential
- C08K13/02—Organic and inorganic ingredients
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/16—Nitrogen-containing compounds
- C08K5/17—Amines; Quaternary ammonium compounds
- C08K5/18—Amines; Quaternary ammonium compounds with aromatically bound amino groups
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/36—Sulfur-, selenium-, or tellurium-containing compounds
- C08K5/41—Compounds containing sulfur bound to oxygen
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D131/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an acyloxy radical of a saturated carboxylic acid, of carbonic acid, or of a haloformic acid; Coating compositions based on derivatives of such polymers
- C09D131/02—Homopolymers or copolymers of esters of monocarboxylic acids
- C09D131/04—Homopolymers or copolymers of vinyl acetate
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H19/00—Coated paper; Coating material
- D21H19/36—Coatings with pigments
- D21H19/38—Coatings with pigments characterised by the pigments
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H19/00—Coated paper; Coating material
- D21H19/36—Coatings with pigments
- D21H19/44—Coatings with pigments characterised by the other ingredients, e.g. the binder or dispersing agent
- D21H19/46—Non-macromolecular organic compounds
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H19/00—Coated paper; Coating material
- D21H19/36—Coatings with pigments
- D21H19/44—Coatings with pigments characterised by the other ingredients, e.g. the binder or dispersing agent
- D21H19/56—Macromolecular organic compounds or oligomers thereof obtained by reactions only involving carbon-to-carbon unsaturated bonds
- D21H19/60—Polyalkenylalcohols; Polyalkenylethers; Polyalkenylesters
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H21/00—Non-fibrous material added to the pulp, characterised by its function, form or properties; Paper-impregnating or coating material, characterised by its function, form or properties
- D21H21/14—Non-fibrous material added to the pulp, characterised by its function, form or properties; Paper-impregnating or coating material, characterised by its function, form or properties characterised by function or properties in or on the paper
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H27/00—Special paper not otherwise provided for, e.g. made by multi-step processes
- D21H27/18—Paper- or board-based structures for surface covering
- D21H27/20—Flexible structures being applied by the user, e.g. wallpaper
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Health & Medical Sciences (AREA)
- Engineering & Computer Science (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Architecture (AREA)
- Structural Engineering (AREA)
- Civil Engineering (AREA)
- Life Sciences & Earth Sciences (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Paper (AREA)
- Non-Silver Salt Photosensitive Materials And Non-Silver Salt Photography (AREA)
Abstract
The invention discloses a kind of wet sensitive colour changing wall paper and preparation technology thereof, this colour changing wall paper includes base paper, and it being coated in the photochromic layer on its surface, both thickness are than for 1:0.08, and described photochromic layer includes the component of following weight portion: cobaltous chloride 5～8 parts, hexamethylenetetramine 16～22 parts, triphenylamine 2～3 parts, sodium lauryl sulphate 1～2 parts, N, N dimethylformamide 12～22 parts, vinyl acetate-ethylene copolymer emulsion 34～45 parts.The colour changing wall paper of the present invention has obvious color to change along with air humidity change, and, i.e. occur color to change in humidity 30%RH, the susceptiveness with humidity change is higher.By the coating uniformity of visualization colour changing wall paper, the present invention has the most preferably color homogeneity.The colour changing wall paper of the present invention remains to the normally variable color along with air humidity change after using 2 years, illustrate that it can be with life-time service.
Description
Technical field
The present invention relates to a kind of wallpaper, be specifically related to a kind of wet sensitive colour changing wall paper and preparation technology thereof, belong to wallpaper technology
Field.
Background technology
Wallpaper is a kind of application house decorative material the most widely, it is adaptable to the indoor dress in house, office and hotel
Repair.Wallpaper has material environmental protection, sound-insulation and heat-insulation, lovely luster, the multiple advantage such as good visual effect and short construction period, domestic
Outer increasing consumer selects wallpaper, and this has been the trend trend of current wall surfacing.
Along with the raising of living standards of the people, people the most not only rest on aesthetic to wallpaper, also start to pursue
The most functional.Wet sensitive colour changing has become as a kind of new trend at present, if wallpaper can meet wet variable color, can carry in time
Awake people use the humidity condition of environment, and meanwhile, the color change of wallpaper also can increase its aesthetic property and sight.
Summary of the invention
It is an object of the invention to as overcoming above-mentioned the deficiencies in the prior art, it is provided that a kind of have substantially along with air humidity changes
The wet sensitive colour changing wall paper of color change.
Present invention also offers its preparation technology.
For achieving the above object, the present invention uses following technical proposals:
A kind of wet sensitive colour changing wall paper, including base paper, and is coated in the photochromic layer on its surface, and both thickness ratio is for 1:0.08, institute
State photochromic layer and include the component of following weight portion: cobaltous chloride 5～8 parts, hexamethylenetetramine 16～22 parts, triphenylamine 2～3 parts,
Sodium lauryl sulphate 1～2 parts, DMF 12～22 parts, vinyl copolymer emulsion 34～45
Part.
Preferably, described base paper is non-woven fabrics, pure paper or PVC plastic base paper.
Preferably, described photochromic layer also includes toner, and it is 0.2～0.3:1 with the mass ratio of cobaltous chloride, described hyperchromic
Agent is any one in phthalocyanine blue, azo orange, azophosphine or azophloxine.
Preferably, described photochromic layer includes the component of following weight portion: cobaltous chloride 6～7 parts, hexamethylenetetramine 17～21
Part, triphenylamine 2～3 parts, sodium lauryl sulphate 1～2 parts, DMF 13～21 parts, vinyl
Copolymer emulsion 35～44 parts.
It is further preferred that described photochromic layer includes the component of following weight portion: cobaltous chloride 6 parts, hexamethylenetetramine 20
Part, triphenylamine 2 parts, sodium lauryl sulphate 1 part, DMF 18 parts, vinyl copolymer emulsion 40
Part.
The preparation technology of above-mentioned a kind of wet sensitive colour changing wall paper, is at base paper surface-coated photochromic layer, be placed on 60 DEG C
Vacuum drying oven solidifies 2 hours, to obtain final product.
Preferably, the compound method of photochromic layer is, weighs each component of formula ratio, stirs 1～2 hour after mixing, filters
After and get final product.
Beneficial effects of the present invention:
The colour changing wall paper of the present invention has obvious color to change along with air humidity change, and, i.e. there is color in humidity 30%RH
Change, the susceptiveness with humidity change is higher.By the coating uniformity of visualization colour changing wall paper, the present invention has the most relatively
Good color homogeneity.The colour changing wall paper of the present invention remains to normally variable color, explanation along with air humidity change after using 2 years
It can be with life-time service.
Detailed description of the invention
Below in conjunction with embodiment, the present invention will be further elaborated, it should explanation, the description below merely to
Explain the present invention, its content is not defined.
The vinyl copolymer emulsion of the present invention, purchased from Guangzhou Qi Sheng Chemical Co., Ltd.；Phthalocyanine blue, azo
Orange, azophosphine or azophloxine, purchased from Dongguan City Tai Sheng pigment company limited.
Embodiment 1:
A kind of wet sensitive colour changing wall paper, including non-woven fabrics, and is coated in the photochromic layer on its surface, both thickness ratio for 1:0.08,
Photochromic layer includes following components: cobaltous chloride 5kg, hexamethylenetetramine 16kg, triphenylamine 2kg, sodium lauryl sulphate 1kg, N,
Dinethylformamide 12kg, vinyl copolymer emulsion 34kg, phthalocyanine blue 1kg.
The preparation technology of above-mentioned a kind of wet sensitive colour changing wall paper, is at base paper surface-coated photochromic layer, be placed on 60 DEG C
Vacuum drying oven solidifies 2 hours, to obtain final product.Wherein, the compound method of photochromic layer is, weighs each component of formula ratio, stirs 1 after mixing
Hour, after filtration and get final product.
Embodiment 2:
A kind of wet sensitive colour changing wall paper, including pure paper, and is coated in the photochromic layer on its surface, and both thickness ratio for 1:0.08, becomes
Chromatograph includes following components: cobaltous chloride 8kg, hexamethylenetetramine 22kg, triphenylamine 3kg, sodium lauryl sulphate 2kg, N, N-
Dimethylformamide 22kg, vinyl copolymer emulsion 45kg, azo orange 2.4kg.
The preparation technology of above-mentioned a kind of wet sensitive colour changing wall paper, is at base paper surface-coated photochromic layer, be placed on 60 DEG C
Vacuum drying oven solidifies 2 hours, to obtain final product.Wherein, the compound method of photochromic layer is, weighs each component of formula ratio, stirs 2 after mixing
Hour, after filtration and get final product.
Embodiment 3:
A kind of wet sensitive colour changing wall paper, including PVC plastic base paper, and is coated in the photochromic layer on its surface, and both thickness ratios are 1:
0.08, photochromic layer includes following components: cobaltous chloride 6kg, hexamethylenetetramine 17kg, triphenylamine 2kg, sodium lauryl sulphate
1kg, DMF 13kg, vinyl copolymer emulsion 35kg, azophosphine 1.2kg.
The preparation technology of above-mentioned a kind of wet sensitive colour changing wall paper, is at base paper surface-coated photochromic layer, be placed on 60 DEG C
Vacuum drying oven solidifies 2 hours, to obtain final product.Wherein, the compound method of photochromic layer is, weighs each component of formula ratio, stirs 1 after mixing
Hour, after filtration and get final product.
Embodiment 4:
A kind of wet sensitive colour changing wall paper, including non-woven fabrics, and is coated in the photochromic layer on its surface, both thickness ratio for 1:0.08,
Photochromic layer includes following components: cobaltous chloride 7kg, hexamethylenetetramine 21kg, triphenylamine 3kg, sodium lauryl sulphate 2kg, N,
Dinethylformamide 21kg, vinyl copolymer emulsion 44kg, azophloxine 2.1kg.
The preparation technology of above-mentioned a kind of wet sensitive colour changing wall paper, is at base paper surface-coated photochromic layer, be placed on 60 DEG C
Vacuum drying oven solidifies 2 hours, to obtain final product.Wherein, the compound method of photochromic layer is, weighs each component of formula ratio, stirs 2 after mixing
Hour, after filtration and get final product.
Embodiment 5:
A kind of wet sensitive colour changing wall paper, including non-woven fabrics, and is coated in the photochromic layer on its surface, both thickness ratio for 1:0.08,
Photochromic layer includes following components: cobaltous chloride 6kg, hexamethylenetetramine 20kg, triphenylamine 2kg, sodium lauryl sulphate 1kg, N,
Dinethylformamide 18kg, vinyl copolymer emulsion 40kg, phthalocyanine blue 1.8kg.
The preparation technology of above-mentioned a kind of wet sensitive colour changing wall paper, is at base paper surface-coated photochromic layer, be placed on 60 DEG C
Vacuum drying oven solidifies 2 hours, to obtain final product.Wherein, the compound method of photochromic layer is, weighs each component of formula ratio, stirs 2 after mixing
Hour, after filtration and get final product.
Comparative example 1:
A kind of wet sensitive colour changing wall paper, including non-woven fabrics, and is coated in the photochromic layer on its surface, both thickness ratio for 1:0.07,
Photochromic layer includes following components: cobaltous chloride 6kg, hexamethylenetetramine 20kg, triphenylamine 2kg, sodium lauryl sulphate 1kg, N,
Dinethylformamide 18kg, vinyl copolymer emulsion 40kg, phthalocyanine blue 1.8kg.
The preparation technology of above-mentioned a kind of wet sensitive colour changing wall paper, is at base paper surface-coated photochromic layer, be placed on 60 DEG C
Vacuum drying oven solidifies 2 hours, to obtain final product.Wherein, the compound method of photochromic layer is, weighs each component of formula ratio, stirs 2 after mixing
Hour, after filtration and get final product.
Comparative example 2:
A kind of wet sensitive colour changing wall paper, including non-woven fabrics, and is coated in the photochromic layer on its surface, both thickness ratio for 1:0.09,
Photochromic layer includes following components: cobaltous chloride 6kg, hexamethylenetetramine 20kg, triphenylamine 2kg, sodium lauryl sulphate 1kg, N,
Dinethylformamide 18kg, vinyl copolymer emulsion 40kg, phthalocyanine blue 1.8kg.
The preparation technology of above-mentioned a kind of wet sensitive colour changing wall paper, is at base paper surface-coated photochromic layer, be placed on 60 DEG C
Vacuum drying oven solidifies 2 hours, to obtain final product.Wherein, the compound method of photochromic layer is, weighs each component of formula ratio, stirs 2 after mixing
Hour, after filtration and get final product.
Comparative example 3:
A kind of wet sensitive colour changing wall paper, including non-woven fabrics, and is coated in the photochromic layer on its surface, both thickness ratio for 1:0.08,
Photochromic layer includes following components: cobaltous chloride 6kg, hexamethylenetetramine 20kg, carbamide 2kg, sodium lauryl sulphate 1kg, N, N-
Dimethylformamide 18kg, vinyl copolymer emulsion 40kg, phthalocyanine blue 1.8kg.
The preparation technology of above-mentioned a kind of wet sensitive colour changing wall paper, is at base paper surface-coated photochromic layer, be placed on 60 DEG C
Vacuum drying oven solidifies 2 hours, to obtain final product.Wherein, the compound method of photochromic layer is, weighs each component of formula ratio, stirs 2 after mixing
Hour, after filtration and get final product.
Comparative example 4:
A kind of wet sensitive colour changing wall paper, including non-woven fabrics, and is coated in the photochromic layer on its surface, both thickness ratio for 1:0.08,
Photochromic layer includes following components: cobaltous chloride 6kg, hexamethylenetetramine 20kg, triphenylamine 2kg, vinyl copolymerization is newborn
Liquid 40kg, phthalocyanine blue 1.8kg.
The preparation technology of above-mentioned a kind of wet sensitive colour changing wall paper, is at base paper surface-coated photochromic layer, be placed on 60 DEG C
Vacuum drying oven solidifies 2 hours, to obtain final product.Wherein, the compound method of photochromic layer is, weighs each component of formula ratio, stirs 2 after mixing
Hour, after filtration and get final product.
Test example
Embodiment 1～5 and under the conditions of the colour changing wall paper of comparative example 1～4 is placed in 25 DEG C, carries out humidity research, and it becomes with humidity
Pornographic condition such as table 1.
Table 1. colour changing wall paper changes with the color that humidity is different
| Humidity (%RH) | 20 | 30 | 50 | 70 | 90 |
| Embodiment 1 | Ash is blue | Sapphire blue | Sky blue | Blackish green | Pea green |
| Embodiment 2 | Coffee | Khaki | Pink | Dark red | Orange red |
| Embodiment 3 | Emerald green | Light green | Blackish green | Lemon yellow | Middle Huang |
| Embodiment 4 | Dark purple | Violet | Purplish red | Deep rhodo | Rhodo |
| Embodiment 5 | Ash is blue | Sapphire blue | Sky blue | Blackish green | Pea green |
| Comparative example 1 | Ash is blue | Ash is blue | Sapphire blue | Sky blue | Sky blue |
| Comparative example 2 | Ash is blue | Ash is blue | Sapphire blue | Sky blue | Sky blue |
| Comparative example 3 | Ash is blue | Ash is blue | Ash is blue | Sapphire blue | Sapphire blue |
| Comparative example 4 | Ash is blue | Ash is blue | Ash is blue | Sapphire blue | Sapphire blue |
As shown in Table 1, the colour changing wall paper of embodiment 1～5 all has obvious color to change along with air humidity change, and, wet
Degree 30%RH i.e. occurs color to change.The start humidity of the colour changing wall paper color change of comparative example 1～4 is substantially higher, and needs higher
Humidity side can start color change.It is obvious that the susceptiveness that the colour changing wall paper of embodiment 1～5 changes with humidity is higher.
Embodiment 1～5 and the colour changing wall paper of comparative example 1～4, all uses the coating of photochromic layer entirety to obtain, in 50%RH bar
By the coating uniformity of visualization colour changing wall paper under part, the color homogeneity of embodiment 1～5 is substantially preferable, the results are shown in Table
2。
The coating uniformity of table 2. colour changing wall paper
| Coating uniformity | |
| Embodiment 1 | Sky blue, color homogeneity is good, no significant difference |
| Embodiment 2 | Pink, color homogeneity is good, no significant difference |
| Embodiment 3 | Blackish green, color homogeneity is good, no significant difference |
| Embodiment 4 | Purplish red, color homogeneity is good, no significant difference |
| Embodiment 5 | Sky blue, color homogeneity is good, no significant difference |
| Comparative example 1 | Sapphire blue, color homogeneity is poor, has obvious color lump sense |
| Comparative example 2 | Sapphire blue, color homogeneity is poor, has obvious color lump sense |
| Comparative example 3 | Ash is blue, and color homogeneity is poor, has obvious color lump sense |
| Comparative example 4 | Ash is blue, and color homogeneity is poor, has obvious color lump sense |
Applicant has carried out long-term investigation to the colour changing wall paper of embodiment 1～5, remains to normally along with air humidity changes after 2 years
And variable color, illustrate that it can be with life-time service.The colour changing wall paper of comparative example 1～2 remains to after 1 year normally along with air humidity changes
And variable color, but cannot normally variable color after 2 years.The colour changing wall paper of comparative example 3～4 can not be along with air humidity change after 1 year
Variable color.
Although the above-mentioned detailed description of the invention to the present invention is described, but not limit to scope
System, on the basis of technical scheme, those skilled in the art need not to pay that creative work can make is each
Plant amendment or deformation still within protection scope of the present invention.
Claims (7)
1. a wet sensitive colour changing wall paper, including base paper, and is coated in the photochromic layer on its surface, it is characterised in that both thickness
Than being 1:0.08, described photochromic layer includes the component of following weight portion: cobaltous chloride 5～8 parts, hexamethylenetetramine 16～22 parts,
Triphenylamine 2～3 parts, sodium lauryl sulphate 1～2 parts, DMF 12～22 parts, vinyl is common
Poly-emulsion 34～45 parts.
A kind of wet sensitive colour changing wall paper the most according to claim 1, it is characterised in that described base paper be non-woven fabrics, pure paper or
PVC plastic base paper.
A kind of wet sensitive colour changing wall paper the most according to claim 1, it is characterised in that described photochromic layer also includes toner,
It is 0.2～0.3:1 with the mass ratio of cobaltous chloride, and described toner is appointing in phthalocyanine blue, azo orange, azophosphine or azophloxine
A kind of.
A kind of wet sensitive colour changing wall paper the most according to claim 1, it is characterised in that described photochromic layer includes following weight portion
Component: cobaltous chloride 6～7 parts, hexamethylenetetramine 17～21 parts, triphenylamine 2～3 parts, sodium lauryl sulphate 1～2 parts, N,
Dinethylformamide 13～21 parts, vinyl copolymer emulsion 35～44 parts.
A kind of wet sensitive colour changing wall paper the most according to claim 1, it is characterised in that described photochromic layer includes following weight portion
Component: cobaltous chloride 6 parts, hexamethylenetetramine 20 parts, triphenylamine 2 parts, sodium lauryl sulphate 1 part, N, N-dimethyl formyl
Amine 18 parts, vinyl copolymer emulsion 40 parts.
6. the preparation technology of the wet sensitive colour changing wall paper according to any one of a Claims 1 to 5, it is characterised in that be at base
Paper surface-coated photochromic layer, the 60 DEG C of vacuum drying ovens of being placed on solidify 2 hours, to obtain final product.
Preparation technology the most according to claim 6, it is characterised in that the compound method of photochromic layer is to weigh formula ratio
Each component, stirs 1～2 hour after mixing, after filtration and get final product.
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Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107386009A (en) * | 2017-07-28 | 2017-11-24 | 广东玉兰集团股份有限公司 | A kind of wet sensitive colour changing wall paper and preparation method thereof |
| CN107629612A (en) * | 2017-09-30 | 2018-01-26 | 华南理工大学 | A kind of green ecological wet sensitive colour changing functional form dry powder paint and preparation method thereof |
Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1048555A (en) * | 1990-08-28 | 1991-01-16 | 北京纺织科学研究所 | Moistrure sensitive allochromic coating |
| CN1109536A (en) * | 1994-03-26 | 1995-10-04 | 姚益群 | Wet sensitive colour changing wall paper and its making method |
| CN103061477A (en) * | 2012-12-28 | 2013-04-24 | 山西金博雅装饰材料有限公司 | Wallpaper capable of changing color with temperatures |
| CN104790621A (en) * | 2015-05-06 | 2015-07-22 | 苏州翔天装饰设计有限公司 | Multiple-functional color changing wallpaper |
| KR20150141234A (en) * | 2014-06-09 | 2015-12-18 | (주)엘지하우시스 | Environmentally friendly wallpaper having discoloration function |
-
2016
- 2016-08-22 CN CN201610693451.7A patent/CN106193484A/en active Pending
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1048555A (en) * | 1990-08-28 | 1991-01-16 | 北京纺织科学研究所 | Moistrure sensitive allochromic coating |
| CN1109536A (en) * | 1994-03-26 | 1995-10-04 | 姚益群 | Wet sensitive colour changing wall paper and its making method |
| CN103061477A (en) * | 2012-12-28 | 2013-04-24 | 山西金博雅装饰材料有限公司 | Wallpaper capable of changing color with temperatures |
| KR20150141234A (en) * | 2014-06-09 | 2015-12-18 | (주)엘지하우시스 | Environmentally friendly wallpaper having discoloration function |
| CN104790621A (en) * | 2015-05-06 | 2015-07-22 | 苏州翔天装饰设计有限公司 | Multiple-functional color changing wallpaper |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107386009A (en) * | 2017-07-28 | 2017-11-24 | 广东玉兰集团股份有限公司 | A kind of wet sensitive colour changing wall paper and preparation method thereof |
| CN107629612A (en) * | 2017-09-30 | 2018-01-26 | 华南理工大学 | A kind of green ecological wet sensitive colour changing functional form dry powder paint and preparation method thereof |
| CN107629612B (en) * | 2017-09-30 | 2020-09-22 | 华南理工大学 | Green ecological humidity-sensitive color-changing functional dry powder coating and preparation method thereof |
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Address after: 314500 Tongxiang Economic Development Zone, Zhejiang City, West Ring Road, No. 106, No. Applicant after: Polytron Technologies Inc Address before: Jiaxing City, Zhejiang province 314500 Tongxiang Wutong Street Huancheng West Road No. 106 building 4 floor 1 Applicant before: Tongxiang Jialifeng Industry Co., Ltd. |
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