CN106192450A - A kind of manufacturing process of wet-type PU synthetic leather - Google Patents

A kind of manufacturing process of wet-type PU synthetic leather Download PDF

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Publication number
CN106192450A
CN106192450A CN201610771842.6A CN201610771842A CN106192450A CN 106192450 A CN106192450 A CN 106192450A CN 201610771842 A CN201610771842 A CN 201610771842A CN 106192450 A CN106192450 A CN 106192450A
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China
Prior art keywords
base fabric
wet
matching
type
impregnation
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Pending
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CN201610771842.6A
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Chinese (zh)
Inventor
黄志新
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Fujian Boyi Mstar Technology Ltd
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Fujian Boyi Mstar Technology Ltd
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Priority to CN201610771842.6A priority Critical patent/CN106192450A/en
Publication of CN106192450A publication Critical patent/CN106192450A/en
Pending legal-status Critical Current

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    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06NWALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
    • D06N3/00Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof
    • D06N3/12Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof with macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds, e.g. gelatine proteins
    • D06N3/14Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof with macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds, e.g. gelatine proteins with polyurethanes
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06BTREATING TEXTILE MATERIALS USING LIQUIDS, GASES OR VAPOURS
    • D06B21/00Successive treatments of textile materials by liquids, gases or vapours
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06NWALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
    • D06N3/00Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof
    • D06N3/0002Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof characterised by the substrate
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06NWALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
    • D06N3/00Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof
    • D06N3/0056Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof characterised by the compounding ingredients of the macro-molecular coating
    • D06N3/0059Organic ingredients with special effects, e.g. oil- or water-repellent, antimicrobial, flame-resistant, magnetic, bactericidal, odour-influencing agents; perfumes
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06NWALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
    • D06N3/00Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof
    • D06N3/0056Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof characterised by the compounding ingredients of the macro-molecular coating
    • D06N3/0063Inorganic compounding ingredients, e.g. metals, carbon fibres, Na2CO3, metal layers; Post-treatment with inorganic compounds
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06NWALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
    • D06N2209/00Properties of the materials
    • D06N2209/10Properties of the materials having mechanical properties
    • D06N2209/103Resistant to mechanical forces, e.g. shock, impact, puncture, flexion, shear, compression, tear
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06NWALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
    • D06N2211/00Specially adapted uses
    • D06N2211/12Decorative or sun protection articles
    • D06N2211/28Artificial leather

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  • Engineering & Computer Science (AREA)
  • Textile Engineering (AREA)
  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Dispersion Chemistry (AREA)
  • Inorganic Chemistry (AREA)
  • Materials Engineering (AREA)
  • Synthetic Leather, Interior Materials Or Flexible Sheet Materials (AREA)

Abstract

The invention discloses the manufacturing process of a kind of wet-type PU synthetic leather, belong to artificial leather synthesis field.Clean process, solidify, wash and drying and processing with dry, impregnation process, pre-consolidated, dry process, coating including dispensing, base fabric.The present invention compared with prior art, has the beneficial effect that the lines that the present invention makes is tight, and feel is soft, white and without stain, anti-fouling;Having good mechanical strength, stretch breaking strength, tearing strength, peel strength and bursting strength value are big, and anti-wear performance is good, stable in properties.The manufacturing process safety and environmental protection of the present invention, low cost, it is possible to meet the demand of PU synthetic leather growing on market.

Description

A kind of manufacturing process of wet-type PU synthetic leather
Technical field
The invention belongs to artificial leather synthesis field, be specifically related to the manufacturing process of a kind of wet-type PU synthetic leather.
Background technology
Polyurethane (PU) is a kind of using various fabricbases as base material, and coating polyurethane resin on base material, to make it give various The real leather intimating synthetic leather of decorative pattern, pattern, function and feel, its overwhelming majority performance has been able to be fully achieved or exceed corium, But in waterproof and breathable performance, still there is a certain distance.
The mid-1960s foreign market occurs in that the dermatine of a kind of novel similar natural leather, polyurethane non-woven fabrics Base wet type synthetic leather, it is to use the production method of wet type to obtain.The performance of this synthetic leather, structure are with conventional dry type (also Claiming dry method) Synthetic Leather compares, and breathability, hygroscopicity, weatherability and presentation quality have substantially change.Wet-type polyurethane Artificial leather begins to appear in world market the end of the seventies, the beginning of the eighties, China in the eighties middle and late stage start produce.Due to sky So the development of leather is limited by numerous conditions, and wet-type PU artificial leather has again excellent imitation leather performance, from the nineties by Gradually instead of the poor PVC artificial leather of the internal performances such as air-moisture-permeable, folding be cold-resistant and dry type PU artificial leather, become domestic city The product that field is badly in need of.
Summary of the invention
Present invention aims to prior art not enough, it is provided that the manufacturing process of a kind of wet-type PU synthetic leather.
For achieving the above object, the present invention adopts the following technical scheme that
The manufacturing process of a kind of wet-type PU synthetic leather, specifically includes following steps:
(1) dispensing: preparation wet type base fabric impregnation fluid,matching and wet type base fabric fluid,matching;
(2) base fabric is cleaned with dry: with cleaning machine by the greasy dirt Impurity removal of scrim surfaces, removes base fabric with heat wheel subsequently unnecessary Moisture, and the base fabric that plates so that base fabric moisture content controls at below 25wt%;
(3) impregnation processes: base fabric wet type base fabric impregnation fluid,matching step (2) obtained carries out impregnation process, and coating weight is 160 ~ 380 grams m, wet type base fabric impregnation fluid,matching viscosity is 200~500cps, and impregnation tension force is 3 ~ 4kgf;
(4) pre-consolidated: the base fabric after impregnation being processed is placed in pre-consolidated groove and carries out pre-consolidated process, and pre-consolidated tension force is 2- 4kgf;And press with extruding wheel extruding, pressure is 3 ~ 4kgf;
(5) dry process: the base fabric heat wheel after step (4) being processed is dry, and controlling base fabric moisture content is 16 ~ 22wt%, heat wheel Temperature is 65 ~ 100 DEG C;
(6) coating processes: wet type base fabric fluid,matching is coated in the base fabric that step (5) obtains, and coating weight is 1000 ~ 1200g/ m2, the viscosity of wet type base fabric fluid,matching is 8500 ~ 9000cps;
(7) solidification: the base fabric after coating is solidified so that wet type base fabric fluid,matching forms solidification in scrim surfaces solidification Film, for wet-type PU base fabric film and closely coupled with base fabric,;And press with extruding wheel extruding, pressure is 3-5kgf;
(8) washing: the connection that step (7) obtains has the base fabric of wet-type PU base fabric film enter rinsing bowl and carries out water elution DMF, water Washing temperature is 40 ~ 50 DEG C;
(9) dry: dry after washing, prepare wet-type PU synthetic leather.
Described wet type base fabric impregnation fluid,matching is counted by weight and is included following components:
DMF:300~500 parts;
Anion surfactant: 1 ~ 3 part;
Polyurethanes: 90 ~ 120 parts;
Titanium dioxide: 2 ~ 4 parts.
Described wet type base fabric fluid,matching is counted by weight and is included following components:
Polyurethane resin: 90 ~ 120 parts;
DMF:95 ~ 100 part;
Anion surfactant: 1 ~ 2 part;
Abscess regulator: 0.5 ~ 1 part;
Wood fiber powder: 10 ~ 30 parts;
Nanoscale attapulgite: 6 ~ 8 parts;
CaCO3: 15 ~ 20 parts;
Titanium dioxide: 1 ~ 1.5 part.
Described anion surfactant is alpha-olefin sodium sulfonate, polyoxyethylenated alcohol sodium sulfate and dodecyl sodium sulfonate Any one in sodium.
The beneficial effects of the present invention is:
(1) the PU synthetic leather lines that the present invention makes is tight, and feel is soft, white and without stain, anti-fouling;
(2) the PU synthetic leather that the present invention makes has good mechanical strength, stretch breaking strength, tearing strength, peel strength and top Broken intensity level is big, and anti-wear performance is good, stable in properties;
(3) the manufacturing process safety and environmental protection of the present invention, low cost, it is possible to meet the need of PU synthetic leather growing on market Ask.
Detailed description of the invention
Below in conjunction with specific embodiment, the present invention will be further described, but the present invention is not limited only to these embodiments.
Embodiment 1
The manufacturing process of a kind of wet-type PU synthetic leather, specifically includes following steps:
(1) dispensing: preparation wet type base fabric impregnation fluid,matching and wet type base fabric fluid,matching;
(2) base fabric is cleaned with dry: with cleaning machine by the greasy dirt Impurity removal of scrim surfaces, removes base fabric with heat wheel subsequently unnecessary Moisture, and the base fabric that plates so that base fabric moisture content controls at below 25wt%;
(3) impregnation processes: base fabric wet type base fabric impregnation fluid,matching step (2) obtained carries out impregnation process, and coating weight is 380 grams m, wet type base fabric impregnation fluid,matching viscosity is 200cps, and impregnation tension force is 3kgf;
(4) pre-consolidated: the base fabric after impregnation being processed is placed in pre-consolidated groove and carries out pre-consolidated process, and pre-consolidated tension force is 2kgf;And press with extruding wheel extruding, pressure is 3kgf;
(5) dry process: the base fabric heat wheel after step (4) being processed is dry, and controlling base fabric moisture content is 16wt%, heat wheel temperature Degree is 65 DEG C;
(6) coating processes: wet type base fabric fluid,matching is coated in the base fabric that step (5) obtains, and coating weight is 1000g/m2, wet type The viscosity of base fabric fluid,matching is 8500cps;
(7) solidification: the base fabric after coating is solidified so that wet type base fabric fluid,matching forms solidification in scrim surfaces solidification Film, for wet-type PU base fabric film and closely coupled with base fabric,;And press with extruding wheel extruding, pressure is 3kgf;
(8) washing: the connection that step (7) obtains has the base fabric of wet-type PU base fabric film enter rinsing bowl and carries out water elution DMF, water Washing temperature is 40 DEG C;
(9) dry: dry after washing, prepare wet-type PU synthetic leather.
Described wet type base fabric impregnation fluid,matching is counted by weight and is included following components:
DMF:300 part;
Alpha-olefin sodium sulfonate: 1 part;
Polyurethanes: 90 parts;
Titanium dioxide: 2 parts.
Described wet type base fabric fluid,matching is counted by weight and is included following components:
Polyurethane resin: 90 parts;
DMF:95 part;
Alpha-olefin sodium sulfonate: 1 part;
Abscess regulator: 0.5 part;
Wood fiber powder: 10 parts;
Nanoscale attapulgite: 6 parts;
CaCO3: 15 parts;
Titanium dioxide: 1 part.
Embodiment 2
The manufacturing process of a kind of wet-type PU synthetic leather, specifically includes following steps:
(1) dispensing: preparation wet type base fabric impregnation fluid,matching and wet type base fabric fluid,matching;
(2) base fabric is cleaned with dry: with cleaning machine by the greasy dirt Impurity removal of scrim surfaces, removes base fabric with heat wheel subsequently unnecessary Moisture, and the base fabric that plates so that base fabric moisture content controls at below 25wt%;
(3) impregnation processes: base fabric wet type base fabric impregnation fluid,matching step (2) obtained carries out impregnation process, and coating weight is 160 grams m, wet type base fabric impregnation fluid,matching viscosity is 500cps, and impregnation tension force is 4kgf;
(4) pre-consolidated: the base fabric after impregnation being processed is placed in pre-consolidated groove and carries out pre-consolidated process, and pre-consolidated tension force is 4kgf;And press with extruding wheel extruding, pressure is 4kgf;
(5) dry process: the base fabric heat wheel after step (4) being processed is dry, and controlling base fabric moisture content is 22wt%, heat wheel temperature Degree is 100 DEG C;
(6) coating processes: wet type base fabric fluid,matching is coated in the base fabric that step (5) obtains, and coating weight is 1200g/m2, wet type The viscosity of base fabric fluid,matching is 9000cps;
(7) solidification: the base fabric after coating is solidified so that wet type base fabric fluid,matching forms solidification in scrim surfaces solidification Film, for wet-type PU base fabric film and closely coupled with base fabric,;And press with extruding wheel extruding, pressure is 5kgf;
(8) washing: the connection that step (7) obtains has the base fabric of wet-type PU base fabric film enter rinsing bowl and carries out water elution DMF, water Washing temperature is 50 DEG C;
(9) dry: dry after washing, prepare wet-type PU synthetic leather.
Described wet type base fabric impregnation fluid,matching is counted by weight and is included following components:
DMF:500 part;
Polyoxyethylenated alcohol sodium sulfate: 3 parts;
Polyurethanes: 120 parts;
Titanium dioxide: 4 parts.
Described wet type base fabric fluid,matching is counted by weight and is included following components:
Polyurethane resin: 120 parts;
DMF:100 part;
Polyoxyethylenated alcohol sodium sulfate: 2 parts;
Abscess regulator: 1 part;
Wood fiber powder: 30 parts;
Nanoscale attapulgite: 8 parts;
CaCO3: 20 parts;
Titanium dioxide: 1.5 parts.
Embodiment 3
The manufacturing process of a kind of wet-type PU synthetic leather, specifically includes following steps:
(1) dispensing: preparation wet type base fabric impregnation fluid,matching and wet type base fabric fluid,matching;
(2) base fabric is cleaned with dry: with cleaning machine by the greasy dirt Impurity removal of scrim surfaces, removes base fabric with heat wheel subsequently unnecessary Moisture, and the base fabric that plates so that base fabric moisture content controls at below 25wt%;
(3) impregnation processes: base fabric wet type base fabric impregnation fluid,matching step (2) obtained carries out impregnation process, and coating weight is 220 grams m, wet type base fabric impregnation fluid,matching viscosity is 350cps, and impregnation tension force is 3.5kgf;
(4) pre-consolidated: the base fabric after impregnation being processed is placed in pre-consolidated groove and carries out pre-consolidated process, and pre-consolidated tension force is 3kgf;And press with extruding wheel extruding, pressure is 3.5kgf;
(5) dry process: the base fabric heat wheel after step (4) being processed is dry, and controlling base fabric moisture content is 19wt%, heat wheel temperature Degree is 85 DEG C;
(6) coating processes: wet type base fabric fluid,matching is coated in the base fabric that step (5) obtains, and coating weight is 1100g/m2, wet type The viscosity of base fabric fluid,matching is 8800cps;
(7) solidification: the base fabric after coating is solidified so that wet type base fabric fluid,matching forms solidification in scrim surfaces solidification Film, for wet-type PU base fabric film and closely coupled with base fabric,;And press with extruding wheel extruding, pressure is 4kgf;
(8) washing: the connection that step (7) obtains has the base fabric of wet-type PU base fabric film enter rinsing bowl and carries out water elution DMF, water Washing temperature is 45 DEG C;
(9) dry: dry after washing, prepare wet-type PU synthetic leather.
Described wet type base fabric impregnation fluid,matching is counted by weight and is included following components:
DMF:400 part;
Dodecyl sodium sulfate: 2 parts;
Polyurethanes: 110 parts;
Titanium dioxide: 3 parts.
Described wet type base fabric fluid,matching is counted by weight and is included following components:
Polyurethane resin: 105 parts;
DMF:97 part;
Dodecyl sodium sulfate: 1.5 parts;
Abscess regulator: 0.8 part;
Wood fiber powder: 20 parts;
Nanoscale attapulgite: 7 parts;
CaCO3: 18 parts;
Titanium dioxide: 1.2 parts.
Performance test
The mechanical performance of table 1 PU of the present invention synthetic leather
The foregoing is only presently preferred embodiments of the present invention, all equalizations done according to scope of the present invention patent change and repair Decorations, all should belong to the covering scope of the present invention.

Claims (4)

1. the manufacturing process of a wet-type PU synthetic leather, it is characterised in that: specifically include following steps:
(1) dispensing: preparation wet type base fabric impregnation fluid,matching and wet type base fabric fluid,matching;
(2) base fabric is cleaned with dry: with cleaning machine by the greasy dirt Impurity removal of scrim surfaces, removes base fabric with heat wheel subsequently unnecessary Moisture, and the base fabric that plates so that base fabric moisture content controls at below 25wt%;
(3) impregnation processes: base fabric wet type base fabric impregnation fluid,matching step (2) obtained carries out impregnation process, and coating weight is 160 ~ 380 grams m, wet type base fabric impregnation fluid,matching viscosity is 200~500cps, and impregnation tension force is 3 ~ 4kgf;
(4) pre-consolidated: the base fabric after impregnation being processed is placed in pre-consolidated groove and carries out pre-consolidated process, and pre-consolidated tension force is 2- 4kgf;And press with extruding wheel extruding, pressure is 3 ~ 4kgf;
(5) dry process: the base fabric heat wheel after step (4) being processed is dry, and controlling base fabric moisture content is 16 ~ 22wt%, heat wheel Temperature is 65 ~ 100 DEG C;
(6) coating processes: wet type base fabric fluid,matching is coated in the base fabric that step (5) obtains, and coating weight is 1000 ~ 1200g/m2, The viscosity of wet type base fabric fluid,matching is 8500 ~ 9000cps;
(7) solidification: the base fabric after coating is solidified so that wet type base fabric fluid,matching forms solidification in scrim surfaces solidification Film, for wet-type PU base fabric film and closely coupled with base fabric;And press with extruding wheel extruding, pressure is 3-5kgf;
(8) washing: the connection that step (7) obtains has the base fabric of wet-type PU base fabric film enter rinsing bowl and carries out water elution DMF, water Washing temperature is 40 ~ 50 DEG C;
(9) dry: dry after washing, prepare wet-type PU synthetic leather.
The manufacturing process of a kind of wet-type PU synthetic leather the most according to claim 1, it is characterised in that: the impregnation of wet type base fabric is joined Conjunction liquid is counted by weight and is included following components:
DMF:300~500 parts;
Anion surfactant: 1 ~ 3 part;
Polyurethanes: 90 ~ 120 parts;
Titanium dioxide: 2 ~ 4 parts.
The manufacturing process of a kind of wet-type PU synthetic leather the most according to claim 1, it is characterised in that: wet type base fabric fluid,matching Count by weight and include following components:
Polyurethane resin: 90 ~ 120 parts;
DMF:95 ~ 100 part;
Anion surfactant: 1 ~ 2 part;
Abscess regulator: 0.5 ~ 1 part;
Wood fiber powder: 10 ~ 30 parts;
Nanoscale attapulgite: 6 ~ 8 parts;
CaCO3: 15 ~ 20 parts;
Titanium dioxide: 1 ~ 1.5 part.
4. according to the manufacturing process of the wet-type PU synthetic leather described in Claims 2 or 3, it is characterised in that: described anion table Face activating agent is any one in alpha-olefin sodium sulfonate, polyoxyethylenated alcohol sodium sulfate and dodecyl sodium sulfate.
CN201610771842.6A 2016-08-31 2016-08-31 A kind of manufacturing process of wet-type PU synthetic leather Pending CN106192450A (en)

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Application Number Priority Date Filing Date Title
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Application Number Priority Date Filing Date Title
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CN106192450A true CN106192450A (en) 2016-12-07

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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108823998A (en) * 2018-08-10 2018-11-16 福建兰峰制革有限公司 The production method of flannelette synthetic leather
CN109594346A (en) * 2019-02-20 2019-04-09 安徽宝博合成革有限公司 The ultra-thin anti-pressing of one kind becomes artificial leather and its synthetic method

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CN102517919A (en) * 2011-12-11 2012-06-27 林炳忠 Leather production method
CN102965964A (en) * 2012-11-25 2013-03-13 安徽安利合成革股份有限公司 Manufacturing method of artificial super-soft abrasion-proof polyurethane shoe lining leather
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CN102304858A (en) * 2011-07-28 2012-01-04 山东同大海岛新材料股份有限公司 Preparation method of superfine fiber high-imitation grain synthetic leather
CN102517919A (en) * 2011-12-11 2012-06-27 林炳忠 Leather production method
CN102965964A (en) * 2012-11-25 2013-03-13 安徽安利合成革股份有限公司 Manufacturing method of artificial super-soft abrasion-proof polyurethane shoe lining leather
CN104744660A (en) * 2013-12-31 2015-07-01 财团法人纺织产业综合研究所 Water-based polyurethane resin, manufacturing method of water-based polyurethane resin and application of water-based polyurethane resin to synthetic leather
CN105178052A (en) * 2015-08-07 2015-12-23 无锡双象超纤材料股份有限公司 Preparation process of microfiber soft sofa leather

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Title
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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108823998A (en) * 2018-08-10 2018-11-16 福建兰峰制革有限公司 The production method of flannelette synthetic leather
CN109594346A (en) * 2019-02-20 2019-04-09 安徽宝博合成革有限公司 The ultra-thin anti-pressing of one kind becomes artificial leather and its synthetic method

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Application publication date: 20161207