CN106191888A - The preparation of a kind of Non-water washing Degreasing Rust and using method thereof - Google Patents

The preparation of a kind of Non-water washing Degreasing Rust and using method thereof Download PDF

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Publication number
CN106191888A
CN106191888A CN201610714450.6A CN201610714450A CN106191888A CN 106191888 A CN106191888 A CN 106191888A CN 201610714450 A CN201610714450 A CN 201610714450A CN 106191888 A CN106191888 A CN 106191888A
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CN
China
Prior art keywords
rust
water washing
degreasing rust
preparation
demulsifier
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Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201610714450.6A
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Chinese (zh)
Inventor
刘梅霞
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HEFEI LYUJIE ENVIRONMENTAL PROTECTION TECHNOLOGY Co Ltd
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HEFEI LYUJIE ENVIRONMENTAL PROTECTION TECHNOLOGY Co Ltd
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Priority to CN201610714450.6A priority Critical patent/CN106191888A/en
Publication of CN106191888A publication Critical patent/CN106191888A/en
Pending legal-status Critical Current

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    • CCHEMISTRY; METALLURGY
    • C23COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23GCLEANING OR DE-GREASING OF METALLIC MATERIAL BY CHEMICAL METHODS OTHER THAN ELECTROLYSIS
    • C23G1/00Cleaning or pickling metallic material with solutions or molten salts
    • C23G1/24Cleaning or pickling metallic material with solutions or molten salts with neutral solutions
    • C23G1/26Cleaning or pickling metallic material with solutions or molten salts with neutral solutions using inhibitors
    • CCHEMISTRY; METALLURGY
    • C23COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23CCOATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C22/00Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals
    • C23C22/05Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using aqueous solutions
    • C23C22/68Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using aqueous solutions using aqueous solutions with pH between 6 and 8

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  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Mechanical Engineering (AREA)
  • Metallurgy (AREA)
  • Organic Chemistry (AREA)
  • Cleaning And De-Greasing Of Metallic Materials By Chemical Methods (AREA)
  • Detergent Compositions (AREA)
  • Application Of Or Painting With Fluid Materials (AREA)

Abstract

The invention discloses preparation and the using method thereof of a kind of Non-water washing Degreasing Rust, belong to technical field of rust prevention, during preparation, the nonionic surfactant containing alkylol, ethanolamine, sodium citrate, demulsifier, hexamethylenamine and deionized water are uniformly mixed according to a ratio, i.e. can get Non-water washing Degreasing Rust.This Degreasing Rust can be used in the spray occasion especially sensitive to foam, can spray, can impregnate;Form one layer of the most transparent limpid dry film in metal surface, can direct spraying, be not required to washing, and do not affect coating adhesion;This Degreasing Rust is compatible with silane film, can support the use with silane, and naked film corrosion resistance is strong, indoor antirust up to 10 to 30 days;This Degreasing Rust environmental protection, the most phosphorous, alkali, nitrite, waste water processes simple, low cost.

Description

The preparation of a kind of Non-water washing Degreasing Rust and using method thereof
Technical field
The present invention relates to a kind of Degreasing Rust, be specifically related to preparation and the user thereof of a kind of Non-water washing Degreasing Rust Method, belongs to technical field of rust prevention.
Background technology
Producing and in the course of processing, the surface of workpiece is inevitably contaminated, and in coating process, need by Spraying workpiece keep cleaning while can not have corrosion, so needing to use corresponding abluent to be carried out, with ensure or Improve the quality of product.The purpose cleaned generally removes oils and fats, organic residue and pigment dirt and cover layer and oxidation material; It addition, the metalwork produced needs to carry out antirust work.Existing degreasing agent typically can play degreasing effect but need washing, and That can play Non-water washing rust-proof effect does not reaches degreasing effect, be difficult to play defat, rust-proof effect two-in-one while need not Washing, has had a strong impact on production application.
Summary of the invention
The problem existed for above-mentioned prior art, the present invention provides the preparation of a kind of Non-water washing Degreasing Rust and makes By method, prepared Degreasing Rust plays rust-proof effect while effective defat, and last procedure need not water Wash, reduce production technology, energy-conserving and environment-protective, easy to use.
To achieve these goals, the preparation method of a kind of Non-water washing Degreasing Rust that the present invention uses, specifically prepare Method is as follows: by the nonionic surfactant containing alkylol, ethanolamine, sodium citrate, demulsifier, hexamethylenamine and go Ionized water is uniformly mixed according to a ratio, and i.e. can get Non-water washing Degreasing Rust;Content meter by weight percentage, described proportioning is: Nonionic surfactant 1-30% containing alkylol, ethanolamine 1-30%, sodium citrate 0.1-10%, demulsifier 0.1-8%, Hexamethylenamine 0.1-10%, remaining is deionized water.
As improvement, content meter by weight percentage, including following components, containing the non-ionic surfactant of alkylol Agent, 5-20%;Ethanolamine, 5-15%;Sodium citrate, 0.1-5%;Demulsifier, 5-8%;Hexamethylenamine, 5-10%;Remaining is deionization Water.
As improvement, content meter by weight percentage, including following components: containing the non-ionic surfactant of alkylol Agent, 15%;Ethanolamine, 10%;Sodium citrate, 5%;Demulsifier, 5.5%;Hexamethylenamine, 5%;Remaining is deionized water.
As improvement, the described nonionic surfactant containing alkylol is alkylolamides.
As improvement, described demulsifier is in polyoxyethylene polyoxypropylene octadecanol ether, polyoxyethylene polyoxypropylene polyethers One or its mixing.
It addition, present invention also offers the using method of a kind of any of the above-described item described Non-water washing Degreasing Rust, this takes off Fat antirust agent can be coated on the surface of pending material by the either type in soaking, spray, smearing, after having coated, right Pending material carries out drying or naturally drying.
As improvement, described naturally dry under room temperature air-dry.
As improvement, the temperature of described drying is 60 DEG C.
Compared with prior art, the Degreasing Rust of Non-water washing prepared by the employing present invention, have the effect that
1) this Degreasing Rust can be used in the spray occasion especially sensitive to foam, can spray, can impregnate.
2) this product metal surface formed one layer of the most transparent limpid dry film, can direct spraying, be not required to washing, and Do not affect coating adhesion.
3) this Degreasing Rust and silane film are compatible, can support the use with silane, and naked film corrosion resistance is strong, indoor antirust up to 10 to 30 days.
4) this Degreasing Rust environmental protection, the most phosphorous, alkali, nitrite, waste water processes simple, low cost.
Detailed description of the invention
For making the object, technical solutions and advantages of the present invention of greater clarity, below by embodiment, the present invention is entered Row further describes.However, it should be understood that specific embodiment described herein is only in order to explain the present invention, and need not In limiting the scope of the present invention.Unless otherwise defined, all of technical term used herein and scientific terminology with belong to this The implication that the those skilled in the art of invention are generally understood that is identical, the art used the most in the description of the invention Language is intended merely to describe the purpose of specific embodiment, it is not intended that in limiting the present invention.
Embodiment one
The preparation method of a kind of Non-water washing Degreasing Rust, content meter by weight percentage, including following components: containing alkylol Nonionic surfactant, 1%;Ethanolamine, 1%;Sodium citrate, 0.1%;Demulsifier, 0.1%;Hexamethylenamine, 0.1%;Go Ionized water, surplus;
Concrete preparation method is as follows: by the nonionic surfactant containing alkylol, ethanolamine, sodium citrate, demulsifier, Hexamethylenamine and deionized water are uniformly mixed according to a ratio, and i.e. can get Non-water washing Degreasing Rust.
This Degreasing Rust can be coated on the surface of pending material by the either type in soaking, spray, smearing, and is coated with After having covered, pending material is dried or naturally dries;
Wherein, naturally drying for air-drying under room temperature, using the temperature dried is 60 DEG C.
Embodiment two
The preparation method of a kind of Non-water washing Degreasing Rust, content meter by weight percentage, including following components: containing alkylol Nonionic surfactant, 30%;Ethanolamine, 30%;Sodium citrate, 10%;Demulsifier, 8%;Hexamethylenamine, 10%;Go from Sub-water, surplus;
Concrete preparation method is as follows: by the nonionic surfactant containing alkylol, ethanolamine, sodium citrate, demulsifier, Hexamethylenamine and deionized water are uniformly mixed according to a ratio, and i.e. can get Non-water washing Degreasing Rust.
This Degreasing Rust can be coated on the surface of pending material by the either type in soaking, spray, smearing, and is coated with After having covered, pending material is dried or naturally dries;
Wherein, naturally drying for air-drying under room temperature, the temperature of drying is 60 DEG C.
Embodiment three
The preparation method of a kind of Non-water washing Degreasing Rust, content meter by weight percentage, including following components: containing alkylol Nonionic surfactant, 5%;Ethanolamine, 5%;Sodium citrate, 0.1%;Demulsifier, 5%;Hexamethylenamine, 5%;Deionization Water, surplus;
Concrete preparation method is as follows: by the nonionic surfactant containing alkylol, ethanolamine, sodium citrate, demulsifier, Hexamethylenamine and deionized water are uniformly mixed according to a ratio, and i.e. can get Non-water washing Degreasing Rust.
This Degreasing Rust can be coated on the surface of pending material by the either type in soaking, spray, smearing, and is coated with After having covered, pending material is dried or naturally dries;
Wherein, naturally drying for air-drying under room temperature, the temperature of drying is 60 DEG C.
Embodiment four
The preparation method of a kind of Non-water washing Degreasing Rust, content meter by weight percentage, including following components: containing alkylol Nonionic surfactant, 15%;Ethanolamine, 10%;Sodium citrate, 5%;Demulsifier, 5.5%;Hexamethylenamine, 5%;Go from Sub-water, surplus;
Concrete preparation method is as follows: by the nonionic surfactant containing alkylol, ethanolamine, sodium citrate, demulsifier, Hexamethylenamine and deionized water are uniformly mixed according to a ratio, and i.e. can get Non-water washing Degreasing Rust.
This Degreasing Rust can be coated on the surface of pending material by the either type in soaking, spray, smearing, and is coated with After having covered, pending material is dried or naturally dries;
Wherein, naturally drying for air-drying under room temperature, the temperature of drying is 60 DEG C.
Embodiment five
The preparation method of a kind of Non-water washing Degreasing Rust, content meter by weight percentage, including following components: containing alkylol Nonionic surfactant, 20%;Ethanolamine, 15%;Sodium citrate, 5%;Demulsifier, 8%;Hexamethylenamine, 10%;Go from Sub-water, surplus;
Concrete preparation method is as follows: by the nonionic surfactant containing alkylol, ethanolamine, sodium citrate, demulsifier, Hexamethylenamine and deionized water are uniformly mixed according to a ratio, and i.e. can get Non-water washing Degreasing Rust.
This Degreasing Rust can be coated on the surface of pending material by the either type in soaking, spray, smearing, and is coated with After having covered, pending material is dried or naturally dries;
Wherein, the temperature of drying is 60 DEG C.
Embodiment six
The preparation method of a kind of Non-water washing Degreasing Rust, content meter by weight percentage, including following components: containing alkylol Nonionic surfactant, 10%;Ethanolamine, 20%;Sodium citrate, 5%;Demulsifier, 5%;Hexamethylenamine, 2%;Deionization Water, surplus;
Concrete preparation method is as follows: by the nonionic surfactant containing alkylol, ethanolamine, sodium citrate, demulsifier, Hexamethylenamine and deionized water are uniformly mixed according to a ratio, and i.e. can get Non-water washing Degreasing Rust.
This Degreasing Rust can be coated on the surface of pending material by the either type in soaking, spray, smearing, and is coated with After having covered, pending material is dried or naturally dries;
Wherein, naturally drying for air-drying under room temperature, the temperature of drying is 60 DEG C.
The foregoing is only presently preferred embodiments of the present invention, not in order to limit the present invention, all essences in the present invention Any amendment, equivalent or the improvement etc. made within god and principle, should be included within the scope of the present invention.

Claims (8)

1. the preparation method of a Non-water washing Degreasing Rust, it is characterised in that concrete preparation method is as follows: will be containing alkylol Nonionic surfactant, ethanolamine, sodium citrate, demulsifier, hexamethylenamine and deionized water be uniformly mixed according to a ratio, I.e. can get Non-water washing Degreasing Rust;Content meter by weight percentage, described proportioning is: the nonionic table containing alkylol Face activating agent 1-30%, ethanolamine 1-30%, sodium citrate 0.1-10%, demulsifier 0.1-8%, hexamethylenamine 0.1-10%, remaining is Deionized water.
The preparation method of a kind of Non-water washing Degreasing Rust the most as claimed in claim 1, it is characterised in that by weight percentage Content meter, including following components, containing the nonionic surfactant of alkylol, 5-20%;Ethanolamine, 5-15%;Citric acid Sodium, 0.1-5%;Demulsifier, 5-8%;Hexamethylenamine, 5-10%;Remaining is deionized water.
The preparation method of a kind of Non-water washing Degreasing Rust the most as claimed in claim 2, it is characterised in that by weight percentage Content meter, including following components: containing the nonionic surfactant of alkylol, 15%;Ethanolamine 10%;Sodium citrate, 5%; Demulsifier, 5.5%;Hexamethylenamine, 5%;Remaining is deionized water.
4. the preparation method of a kind of Non-water washing Degreasing Rust as described in any one of claim 1-3, it is characterised in that described Nonionic surfactant containing alkylol is alkylolamides.
5. the preparation method of a kind of Non-water washing Degreasing Rust as described in any one of claim 1-3, it is characterised in that described Demulsifier is the one in polyoxyethylene polyoxypropylene octadecanol ether, polyoxyethylene polyoxypropylene polyethers or its mixing.
6. the using method of Non-water washing Degreasing Rust described in an any one of claim 1-5, it is characterised in that this defat is prevented Rust agent can be coated on the surface of pending material by the either type in soaking, spray, smearing, and after having coated, treats place Reason material carries out drying or naturally drying.
The using method of a kind of Non-water washing Degreasing Rust the most as claimed in claim 6, it is characterised in that described naturally dry for Air-dry under room temperature.
The using method of a kind of Non-water washing Degreasing Rust the most as claimed in claim 6, it is characterised in that the temperature of described drying It it is 60 DEG C.
CN201610714450.6A 2016-08-25 2016-08-25 The preparation of a kind of Non-water washing Degreasing Rust and using method thereof Pending CN106191888A (en)

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108546944A (en) * 2018-05-14 2018-09-18 安徽惠明机械制造有限公司 A kind of environment-friendly type iron castings surface conditioning agent and its processing method

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EP0344847A2 (en) * 1988-06-03 1989-12-06 The Procter & Gamble Company Improved liquid cleaners
WO2006010375A1 (en) * 2004-07-27 2006-02-02 Rhodia Chimie Formulation for degreasing metal comprising a demulsifyiing agent, use of the agent, and process for degreasing metal.
CN104629945A (en) * 2014-07-15 2015-05-20 韩刚 Zero-emission metal and nonmetal surface cleaning agent with effects of oil removal, rust removal, scale removal, phosphorization, passivation, oxidation resistance and corrosion prevention
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Publication number Priority date Publication date Assignee Title
EP0344847A2 (en) * 1988-06-03 1989-12-06 The Procter & Gamble Company Improved liquid cleaners
WO2006010375A1 (en) * 2004-07-27 2006-02-02 Rhodia Chimie Formulation for degreasing metal comprising a demulsifyiing agent, use of the agent, and process for degreasing metal.
CN104629945A (en) * 2014-07-15 2015-05-20 韩刚 Zero-emission metal and nonmetal surface cleaning agent with effects of oil removal, rust removal, scale removal, phosphorization, passivation, oxidation resistance and corrosion prevention
CN105063586A (en) * 2015-08-19 2015-11-18 合肥市田源精铸有限公司 Water-based metal antirusting agent
CN105297038A (en) * 2015-11-18 2016-02-03 南京科润工业介质股份有限公司 Non-phosphorous water-based degreasing agent used in non-phosphorous coating pretreatment
CN105696008A (en) * 2016-02-18 2016-06-22 东莞市伟思化学科技有限公司 Ultrasonic water-based cleaning fluid for hardware products and preparation method thereof

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108546944A (en) * 2018-05-14 2018-09-18 安徽惠明机械制造有限公司 A kind of environment-friendly type iron castings surface conditioning agent and its processing method

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