CN106189603A - A kind of nanometer fireproof antibacterial environment protection coating and preparation method thereof - Google Patents

A kind of nanometer fireproof antibacterial environment protection coating and preparation method thereof Download PDF

Info

Publication number
CN106189603A
CN106189603A CN201610719737.8A CN201610719737A CN106189603A CN 106189603 A CN106189603 A CN 106189603A CN 201610719737 A CN201610719737 A CN 201610719737A CN 106189603 A CN106189603 A CN 106189603A
Authority
CN
China
Prior art keywords
parts
environment protection
protection coating
ethanol extraction
antibacterial environment
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Withdrawn
Application number
CN201610719737.8A
Other languages
Chinese (zh)
Inventor
代长华
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Individual
Original Assignee
Individual
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Individual filed Critical Individual
Priority to CN201610719737.8A priority Critical patent/CN106189603A/en
Publication of CN106189603A publication Critical patent/CN106189603A/en
Withdrawn legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D133/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Coating compositions based on derivatives of such polymers
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
    • C09D5/14—Paints containing biocides, e.g. fungicides, insecticides or pesticides
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
    • C09D5/18—Fireproof paints including high temperature resistant paints
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K2201/00—Specific properties of additives
    • C08K2201/011—Nanostructured additives
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2201/00—Properties
    • C08L2201/02—Flame or fire retardant/resistant
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00—Polymer mixtures characterised by other features
    • C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend

Landscapes

  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Wood Science & Technology (AREA)
  • Organic Chemistry (AREA)
  • Plant Pathology (AREA)
  • Paints Or Removers (AREA)

Abstract

The invention provides a kind of nanometer fireproof antibacterial environment protection coating and preparation method thereof.Preparation method is as follows: (1), by precipitated calcium carbonate, Pulvis Talci, Gypsum Fibrosum powder, titanium dioxide, ethylene glycol, softening water, high speed dispersion is uniform, and rate of dispersion is 1,000 1500 revs/min, and jitter time is 30 60 minutes；(2) above-mentioned slurry is ground to fineness 34 45 microns by grinder；(3) add alcohol ester 12, acrylic emulsion, Dodecyl trimethyl ammonium chloride, Octylphenol polyoxyethylene ether, side primary leaf ethanol extraction, Herba Lysimachiae ethanol extraction, hydroxypropyl methyl cellulose, stir 40 60 minutes；(4) APP, tripolycyanamide, tetramethylolmethane, ODOPB, nano graphene oxide, ultrasonic shear 60 100 minutes are added.This coating uses environment-friendly type formula, has good fire resistance and antibacterial and mouldproof performance.

Description

A kind of nanometer fireproof antibacterial environment protection coating and preparation method thereof
Technical field
The present invention relates to building coating field, be specifically related to a kind of nanometer fireproof antibacterial environment protection coating and preparation method thereof.
Background technology
Take the way at its surface-coated fireproof coating to carry out flameproof protection, not only can keep original organic synthesis material The premium properties of material, and economic and practical.Fireproof coating application on organic synthesis material also holds out broad prospects.Additionally, Common iron is heated to about 540 DEG C and i.e. loses structural strength.Xoncrete structure is the most easily opened under thermal-flame effect Split disintegrate.Therefore, iron structure and xoncrete structure are carried out flameproof protection, make them can extend when fire occurs and become The time that shape is destroyed, gain time for fire extinguishing, reduce fire damage, by the attention that people are the biggest.Aqueous fire-proof coating is main With polymer emulsion as base material.On the one hand polymer to have stronger cementation, the various components in coating can be bonded in Together, fireproof coating can form firm coating after drying, and the performance of coating is had important impact；On the other hand, coating is met During fire, as macromolecular material, when decomposing carbonization, its carbide intensity unlike little molecule is much higher.City at present The common water borne coating sold at mould proof aspect mainly to add the purpose reaching antibacterial in the way of antimildew and antibacterial agent, but this kind of Antimildew and antibacterial agent has certain toxicity, and next does not reaches the effect of long-term antibacterial.
Summary of the invention
Solve the technical problem that: it is an object of the invention to provide a kind of nanometer fireproof antibacterial environment protection coating, be a kind of ring Guarantor's type coating, has good fire protecting performance, and the fire resistance period of coating is long；This coating also has permanent biocidal property simultaneously.
Technical scheme: a kind of nanometer fireproof antibacterial environment protection coating, is prepared from by weight by following component: lightweight carbonic acid Calcium 7-10 part, Pulvis Talci 3-5 part, Gypsum Fibrosum powder 3-5 part, titanium dioxide 15-25 part, ethylene glycol 1.5-2.5 part, softening water 80-120 Part, alcohol ester 12 2-3 part, acrylic emulsion 20-30 part, Dodecyl trimethyl ammonium chloride 0.5-1.5 part, octyl phenol polyoxy Vinyl Ether 0.1-0.6 part, side primary leaf ethanol extraction 0.5-1.5 part, Herba Lysimachiae ethanol extraction 0.5-1.5 part, hydroxypropyl first Base cellulose 5-7 part, APP 5-10 part, tripolycyanamide 3-6 part, tetramethylolmethane 2-4 part, ODOPB(10-(2,5-dihydroxy Phenyl)-9,10-dihydro-9-oxy miscellaneous-10-phosphinylidyne miscellaneous phenanthrene-10 oxide) 3-5 part, nano graphene oxide 5-10 part.
It is further preferred that described a kind of nanometer fireproof antibacterial environment protection coating, following component prepare by weight and Become: precipitated calcium carbonate 8-9 part, Pulvis Talci 4-5 part, Gypsum Fibrosum powder 4-5 part, titanium dioxide 18-22 part, ethylene glycol 1.8-2.2 part, softening Water 90-110 part, alcohol ester 12 2.2-2.8 part, acrylic emulsion 22-28 part, Dodecyl trimethyl ammonium chloride 0.8-1.2 part, Octylphenol polyoxyethylene ether 0.2-0.5 part, side primary leaf ethanol extraction 0.8-1.2 part, Herba Lysimachiae ethanol extraction 0.8-1.2 Part, hydroxypropyl methyl cellulose 6-7 part, APP 5-8 part, tripolycyanamide 3-5 part, tetramethylolmethane 2-3 part, ODOPB 3-4 Part, nano graphene oxide 6-9 part.
The preparation method of above-mentioned nanometer fireproof antibacterial environment protection coating, comprises the following steps:
(1) by precipitated calcium carbonate, Pulvis Talci, Gypsum Fibrosum powder, titanium dioxide, ethylene glycol, softening water, high speed dispersion is uniform, rate of dispersion For 1000-1500 rev/min, jitter time is 30-60 minute；
(2) above-mentioned slurry is ground to fineness 34-45 micron by grinder；
(3) alcohol ester 12, acrylic emulsion, Dodecyl trimethyl ammonium chloride, Octylphenol polyoxyethylene ether, side primary are added Leaf ethanol extraction, Herba Lysimachiae ethanol extraction, hydroxypropyl methyl cellulose, stir 40-60 minute；
(4) APP, tripolycyanamide, tetramethylolmethane, ODOPB, nano graphene oxide, ultrasonic shear 60-100 are added Minute.
Further, the preparation method of described a kind of nanometer fireproof antibacterial environment protection coating, dispersion in described step (1) Speed is 1200-1400 rev/min, and jitter time is 40-55 minute.
Further, the preparation method of described a kind of nanometer fireproof antibacterial environment protection coating, fineness in described step (2) 34-40 micron.
Further, the preparation method of described a kind of nanometer fireproof antibacterial environment protection coating, stirring in described step (3) Time is 45-55 minute.
Further, the preparation method of described a kind of nanometer fireproof antibacterial environment protection coating, ultrasonic in described step (4) Ripple shear time is 70-90 minute.
Beneficial effect: the nanometer fireproof antibacterial environment protection coating of the present invention uses environment-friendly type formula, and this coating has very well Fire protecting performance and antibacterial and mouldproof performance, when coating layer thickness is 7mm, fire resistance period up to 3.7 hours, this nanometer fireproof simultaneously Antibacterial environment protection coating also has good biocidal property and mildew resistance, and it is 5.2% to colibacillary survival rate, depositing of melanomyces Motility rate is 6.0%, and through 90 days, colibacillary survival rate was 7.5%, and the survival rate of melanomyces is 7.9%.
Detailed description of the invention
Embodiment 1
A kind of nanometer fireproof antibacterial environment protection coating, is prepared from weight portion by pressing composition: precipitated calcium carbonate 10 parts, Pulvis Talci 5 parts, Gypsum Fibrosum powder 3 parts, titanium dioxide 25 parts, ethylene glycol 2.5 parts, soften 120 parts of water, alcohol ester 12 parts, acrylic emulsion 20 parts, Dodecyl trimethyl ammonium chloride 1.5 parts, Octylphenol polyoxyethylene ether 0.6 part, side primary leaf ethanol extraction 1.5 parts, money Grass ethanol extraction 0.5 part, hydroxypropyl methyl cellulose 7 parts, APP 5 parts, tripolycyanamide 3 parts, tetramethylolmethane 2 parts, ODOPB 3 parts, nano graphene oxide 10 parts.
The preparation method of above-mentioned nanometer fireproof antibacterial environment protection coating is: (1) is by precipitated calcium carbonate, Pulvis Talci, Gypsum Fibrosum powder, titanium White lead, ethylene glycol, softening water, high speed dispersion is uniform, and rate of dispersion is 1000 revs/min, and jitter time is 60 minutes；(2) by upper State slurry and be ground to fineness 34 microns by grinder；(3) alcohol ester 12, acrylic emulsion, trimethyl chlorine are added Change ammonium, Octylphenol polyoxyethylene ether, side primary leaf ethanol extraction, Herba Lysimachiae ethanol extraction, hydroxypropyl methyl cellulose, stir Mix 60 minutes；(4) APP, tripolycyanamide, tetramethylolmethane, ODOPB, nano graphene oxide, ultrasonic shear are added 100 minutes.
Embodiment 2
A kind of nanometer fireproof antibacterial environment protection coating, is prepared from weight portion by pressing composition: precipitated calcium carbonate 7 parts, Pulvis Talci 3 Part, Gypsum Fibrosum powder 5 parts, titanium dioxide 15 parts, ethylene glycol 1.5 parts, soften 80 parts of water, alcohol ester 12 parts, acrylic emulsion 30 parts, ten Dialkyl group trimethyl ammonium chloride 0.5 part, Octylphenol polyoxyethylene ether 0.1 part, side primary leaf ethanol extraction 0.5 part, Herba Lysimachiae Ethanol extraction 1.5 parts, hydroxypropyl methyl cellulose 7 parts, APP 5 parts, tripolycyanamide 6 parts, tetramethylolmethane 4 parts, ODOPB 5 parts, nano graphene oxide 5 parts.
The preparation method of above-mentioned nanometer fireproof antibacterial environment protection coating is: (1) is by precipitated calcium carbonate, Pulvis Talci, Gypsum Fibrosum powder, titanium White lead, ethylene glycol, softening water, high speed dispersion is uniform, and rate of dispersion is 1500 revs/min, and jitter time is 30 minutes；(2) by upper State slurry and be ground to fineness 45 microns by grinder；(3) alcohol ester 12, acrylic emulsion, trimethyl chlorine are added Change ammonium, Octylphenol polyoxyethylene ether, side primary leaf ethanol extraction, Herba Lysimachiae ethanol extraction, hydroxypropyl methyl cellulose, stir Mix 40 minutes；(4) APP, tripolycyanamide, tetramethylolmethane, ODOPB, nano graphene oxide, ultrasonic shear 60 are added Minute.
Embodiment 3
A kind of nanometer fireproof antibacterial environment protection coating, is prepared from weight portion by following component: precipitated calcium carbonate 9 parts, Pulvis Talci 5 Part, Gypsum Fibrosum powder 4 parts, titanium dioxide 22 parts, ethylene glycol 1.8 parts, soften 90 parts of water, alcohol ester 12 parts, acrylic emulsion 22 parts, Dodecyl trimethyl ammonium chloride 0.8 part, Octylphenol polyoxyethylene ether 0.5 part, side primary leaf ethanol extraction 1.2 parts, money Grass ethanol extraction 0.8 part, hydroxypropyl methyl cellulose 6 parts, APP 5 parts, tripolycyanamide 3 parts, tetramethylolmethane 2 parts, ODOPB 3 parts, nano graphene oxide 6 parts.
The preparation method of above-mentioned nanometer fireproof antibacterial environment protection coating is: (1) is by precipitated calcium carbonate, Pulvis Talci, Gypsum Fibrosum powder, titanium White lead, ethylene glycol, softening water, high speed dispersion is uniform, and rate of dispersion is 1400 revs/min, and jitter time is 40 minutes；(2) by upper State slurry and be ground to fineness 40 microns by grinder；(3) alcohol ester 12, acrylic emulsion, trimethyl chlorine are added Change ammonium, Octylphenol polyoxyethylene ether, side primary leaf ethanol extraction, Herba Lysimachiae ethanol extraction, hydroxypropyl methyl cellulose, stir Mix 45 minutes；(4) APP, tripolycyanamide, tetramethylolmethane, ODOPB, nano graphene oxide, ultrasonic shear 70 are added Minute.
Embodiment 4
A kind of nanometer fireproof antibacterial environment protection coating, is prepared from weight portion by following component: precipitated calcium carbonate 8 parts, Pulvis Talci 4 Part, Gypsum Fibrosum powder 5 parts, titanium dioxide 18 parts, ethylene glycol 2.2 parts, soften 110 parts of water, alcohol ester 12 parts, acrylic emulsion 28 parts, Dodecyl trimethyl ammonium chloride 1.2 parts, Octylphenol polyoxyethylene ether 0.2 part, side primary leaf ethanol extraction 0.8 part, money Grass ethanol extraction 1.2 parts, hydroxypropyl methyl cellulose 7 parts, APP 8 parts, tripolycyanamide 5 parts, tetramethylolmethane 3 parts, ODOPB 4 parts, nano graphene oxide 9 parts.
The preparation method of above-mentioned nanometer fireproof antibacterial environment protection coating is: (1) is by precipitated calcium carbonate, Pulvis Talci, Gypsum Fibrosum powder, titanium White lead, ethylene glycol, softening water, high speed dispersion is uniform, and rate of dispersion is 1200 revs/min, and jitter time is 55 minutes；(2) by upper State slurry and be ground to fineness 34 microns by grinder；(3) alcohol ester 12, acrylic emulsion, trimethyl chlorine are added Change ammonium, Octylphenol polyoxyethylene ether, side primary leaf ethanol extraction, Herba Lysimachiae ethanol extraction, hydroxypropyl methyl cellulose, stir Mix 55 minutes；(4) APP, tripolycyanamide, tetramethylolmethane, ODOPB, nano graphene oxide, ultrasonic shear 90 are added Minute.
Embodiment 5
A kind of nanometer fireproof antibacterial environment protection coating, is prepared from weight portion by following component: precipitated calcium carbonate 8 parts, Pulvis Talci 4 Part, Gypsum Fibrosum powder 4 parts, titanium dioxide 20 parts, ethylene glycol 2 parts, soften 105 parts of water, alcohol ester 12 parts, acrylic emulsion 25 parts, ten Dialkyl group trimethyl ammonium chloride 1 part, Octylphenol polyoxyethylene ether 0.3 part, side primary leaf ethanol extraction 1 part, Herba Lysimachiae ethanol Extract 1 part, hydroxypropyl methyl cellulose 6 parts, APP 5 parts, tripolycyanamide 3 parts, tetramethylolmethane 2 parts, ODOPB 3 parts, Nano graphene oxide 8 parts.
The preparation method of above-mentioned nanometer fireproof antibacterial environment protection coating is: (1) is by precipitated calcium carbonate, Pulvis Talci, Gypsum Fibrosum powder, titanium White lead, ethylene glycol, softening water, high speed dispersion is uniform, and rate of dispersion is 1400 revs/min, and jitter time is 55 minutes；(2) by upper State slurry and be ground to fineness 34 microns by grinder；(3) alcohol ester 12, acrylic emulsion, trimethyl chlorine are added Change ammonium, Octylphenol polyoxyethylene ether, side primary leaf ethanol extraction, Herba Lysimachiae ethanol extraction, hydroxypropyl methyl cellulose, stir Mix 50 minutes；(4) APP, tripolycyanamide, tetramethylolmethane, ODOPB, nano graphene oxide, ultrasonic shear 80 are added Minute.
Comparative example 1
A kind of nanometer fireproof antibacterial environment protection coating, is prepared from weight portion by pressing composition: precipitated calcium carbonate 10 parts, Pulvis Talci 5 parts, Gypsum Fibrosum powder 3 parts, titanium dioxide 25 parts, ethylene glycol 2.5 parts, soften 120 parts of water, alcohol ester 12 parts, acrylic emulsion 20 parts, Dodecyl trimethyl ammonium chloride 1.5 parts, Octylphenol polyoxyethylene ether 0.6 part, hydroxypropyl methyl cellulose 7 parts, polyphosphoric acid Ammonium 5 parts, tripolycyanamide 3 parts, tetramethylolmethane 2 parts, ODOPB 3 parts, nano graphene oxide 10 parts.
The preparation method of above-mentioned nanometer fireproof antibacterial environment protection coating is: (1) is by precipitated calcium carbonate, Pulvis Talci, Gypsum Fibrosum powder, titanium White lead, ethylene glycol, softening water, high speed dispersion is uniform, and rate of dispersion is 1000 revs/min, and jitter time is 60 minutes；(2) by upper State slurry and be ground to fineness 34 microns by grinder；(3) alcohol ester 12, acrylic emulsion, trimethyl chlorine are added Change ammonium, Octylphenol polyoxyethylene ether, hydroxypropyl methyl cellulose, stir 60 minutes；(4) add APP, tripolycyanamide, Tetramethylolmethane, ODOPB, nano graphene oxide, ultrasonic shear 100 minutes.
Comparative example 2
A kind of nanometer fireproof antibacterial environment protection coating, is prepared from weight portion by pressing composition: precipitated calcium carbonate 7 parts, Pulvis Talci 3 Part, Gypsum Fibrosum powder 5 parts, titanium dioxide 15 parts, ethylene glycol 1.5 parts, soften 80 parts of water, alcohol ester 12 parts, acrylic emulsion 30 parts, ten Dialkyl group trimethyl ammonium chloride 0.5 part, Octylphenol polyoxyethylene ether 0.1 part, side primary leaf ethanol extraction 0.5 part, Herba Lysimachiae Ethanol extraction 1.5 parts, hydroxypropyl methyl cellulose 7 parts, APP 5 parts, tripolycyanamide 6 parts, tetramethylolmethane 4 parts.
The preparation method of above-mentioned nanometer fireproof antibacterial environment protection coating is: (1) is by precipitated calcium carbonate, Pulvis Talci, Gypsum Fibrosum powder, titanium White lead, ethylene glycol, softening water, high speed dispersion is uniform, and rate of dispersion is 1500 revs/min, and jitter time is 30 minutes；(2) by upper State slurry and be ground to fineness 45 microns by grinder；(3) alcohol ester 12, acrylic emulsion, trimethyl chlorine are added Change ammonium, Octylphenol polyoxyethylene ether, side primary leaf ethanol extraction, Herba Lysimachiae ethanol extraction, hydroxypropyl methyl cellulose, stir Mix 40 minutes；(4) APP, tripolycyanamide, tetramethylolmethane, ultrasonic shear 60 minutes are added.
The property indices of material of the present invention see table, it may be seen that this nanometer fireproof antibacterial environment protection coating has Well fire resistance, when coating layer thickness is 7mm, fire resistance period was up to 3.7 hours；This nanometer fireproof antibacterial environment protection coating simultaneously Also having good biocidal property and mildew resistance, it is 5.2% to colibacillary survival rate, and the survival rate of melanomyces is 6.0%, warp Spending 90 days, colibacillary survival rate is 7.5%, and the survival rate of melanomyces is 7.9%.
The property indices of table 1 nanometer fireproof antibacterial environment protection coating

Claims (7)

1. a nanometer fireproof antibacterial environment protection coating, it is characterised in that be prepared from by weight by following component: lightweight carbonic acid Calcium 7-10 part, Pulvis Talci 3-5 part, Gypsum Fibrosum powder 3-5 part, titanium dioxide 15-25 part, ethylene glycol 1.5-2.5 part, softening water 80-120 Part, alcohol ester 12 2-3 part, acrylic emulsion 20-30 part, Dodecyl trimethyl ammonium chloride 0.5-1.5 part, octyl phenol polyoxy Vinyl Ether 0.1-0.6 part, side primary leaf ethanol extraction 0.5-1.5 part, Herba Lysimachiae ethanol extraction 0.5-1.5 part, hydroxypropyl first Base cellulose 5-7 part, APP 5-10 part, tripolycyanamide 3-6 part, tetramethylolmethane 2-4 part, ODOPB 3-5 part, nano oxidized Graphene 5-10 part.
A kind of nanometer fireproof antibacterial environment protection coating the most according to claim 1, it is characterised in that by following component by weight Part is prepared from: precipitated calcium carbonate 8-9 part, Pulvis Talci 4-5 part, Gypsum Fibrosum powder 4-5 part, titanium dioxide 18-22 part, ethylene glycol 1.8- 2.2 parts, softening water 90-110 part, alcohol ester 12 2.2-2.8 part, acrylic emulsion 22-28 part, Dodecyl trimethyl ammonium chloride 0.8-1.2 part, Octylphenol polyoxyethylene ether 0.2-0.5 part, side primary leaf ethanol extraction 0.8-1.2 part, Herba Lysimachiae ethanol carry Take thing 0.8-1.2 part, hydroxypropyl methyl cellulose 6-7 part, APP 5-8 part, tripolycyanamide 3-5 part, tetramethylolmethane 2-3 Part, ODOPB 3-4 part, nano graphene oxide 6-9 part.
3. the preparation method of a nanometer fireproof antibacterial environment protection coating, it is characterised in that comprise the following steps:
(1) by precipitated calcium carbonate, Pulvis Talci, Gypsum Fibrosum powder, titanium dioxide, ethylene glycol, softening water, high speed dispersion is uniform, rate of dispersion For 1000-1500 rev/min, jitter time is 30-60 minute；
(2) above-mentioned slurry is ground to fineness 34-45 micron by grinder；
(3) alcohol ester 12, acrylic emulsion, Dodecyl trimethyl ammonium chloride, Octylphenol polyoxyethylene ether, the primary leaf in side are added Ethanol extraction, Herba Lysimachiae ethanol extraction, hydroxypropyl methyl cellulose, stir 40-60 minute；
(4) adding APP, tripolycyanamide, tetramethylolmethane, ODOPB, nano graphene oxide, ultrasonic shear 60-100 divides Clock.
A kind of nanometer fireproof antibacterial environment protection coating the most according to claim 3, it is characterised in that: described step (1) is divided Scattered speed is 1200-1400 rev/min, and jitter time is 40-55 minute.
A kind of nanometer fireproof antibacterial environment protection coating the most according to claim 3, it is characterised in that: thin in described step (2) Degree 34-40 micron.
A kind of nanometer fireproof antibacterial environment protection coating the most according to claim 3, it is characterised in that: described step is stirred in (3) The time of mixing is 45-55 minute.
A kind of nanometer fireproof antibacterial environment protection coating the most according to claim 3, described in its feature: described step (4) is ultrasonic Ripple shear time is 70-90 minute.
CN201610719737.8A 2016-08-25 2016-08-25 A kind of nanometer fireproof antibacterial environment protection coating and preparation method thereof Withdrawn CN106189603A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201610719737.8A CN106189603A (en) 2016-08-25 2016-08-25 A kind of nanometer fireproof antibacterial environment protection coating and preparation method thereof

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201610719737.8A CN106189603A (en) 2016-08-25 2016-08-25 A kind of nanometer fireproof antibacterial environment protection coating and preparation method thereof

Publications (1)

Publication Number Publication Date
CN106189603A true CN106189603A (en) 2016-12-07

Family

ID=57523582

Family Applications (1)

Application Number Title Priority Date Filing Date
CN201610719737.8A Withdrawn CN106189603A (en) 2016-08-25 2016-08-25 A kind of nanometer fireproof antibacterial environment protection coating and preparation method thereof

Country Status (1)

Country Link
CN (1) CN106189603A (en)

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107163630A (en) * 2017-06-12 2017-09-15 成都金玉雄辉建筑工程有限公司 A kind of environmental protection coating material and preparation method thereof
CN107473699A (en) * 2017-08-22 2017-12-15 佛山市因诺维生物科技有限公司 A kind of indoor mildew resistant paint
CN108677537A (en) * 2018-04-28 2018-10-19 安徽恒益纺织科技有限公司 A kind of fire retardant, anticorrosive slurry of cotton
WO2022133661A1 (en) * 2020-12-21 2022-06-30 张辉航 Ultraviolet-curable white primer for fireproof layer

Citations (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH10251557A (en) * 1997-03-12 1998-09-22 Dainippon Ink & Chem Inc Coating composition and coated metallic steel plate
CN101386719A (en) * 2008-08-28 2009-03-18 冯守中 Multifunctional coatings and preparation method thereof
CN103059516A (en) * 2013-01-08 2013-04-24 天津市凯华绝缘材料有限公司 Fast-cure epoxy powder composition
CN104774509A (en) * 2015-04-22 2015-07-15 北京碧海舟腐蚀防护工业股份有限公司 Fireproof paint
CN105001743A (en) * 2015-08-26 2015-10-28 湖州大周高分子材料有限公司 Coating special for wall
CN105131792A (en) * 2015-09-30 2015-12-09 高碑店市安普特种防火材料制造有限公司 Intumescent type multifunctional fire retardant coating containing nano-graphite sheets
CN105199462A (en) * 2015-10-28 2015-12-30 漳州三德利油漆涂料有限公司 Plant sterilizing insect-repelling functional type inner wall emulsion paint and preparation method thereof
CN105544306A (en) * 2015-11-26 2016-05-04 张建刚 Making method of graphene oxide-containing antibiosis and mildew prevention wallpaper

Patent Citations (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH10251557A (en) * 1997-03-12 1998-09-22 Dainippon Ink & Chem Inc Coating composition and coated metallic steel plate
CN101386719A (en) * 2008-08-28 2009-03-18 冯守中 Multifunctional coatings and preparation method thereof
CN103059516A (en) * 2013-01-08 2013-04-24 天津市凯华绝缘材料有限公司 Fast-cure epoxy powder composition
CN104774509A (en) * 2015-04-22 2015-07-15 北京碧海舟腐蚀防护工业股份有限公司 Fireproof paint
CN105001743A (en) * 2015-08-26 2015-10-28 湖州大周高分子材料有限公司 Coating special for wall
CN105131792A (en) * 2015-09-30 2015-12-09 高碑店市安普特种防火材料制造有限公司 Intumescent type multifunctional fire retardant coating containing nano-graphite sheets
CN105199462A (en) * 2015-10-28 2015-12-30 漳州三德利油漆涂料有限公司 Plant sterilizing insect-repelling functional type inner wall emulsion paint and preparation method thereof
CN105544306A (en) * 2015-11-26 2016-05-04 张建刚 Making method of graphene oxide-containing antibiosis and mildew prevention wallpaper

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107163630A (en) * 2017-06-12 2017-09-15 成都金玉雄辉建筑工程有限公司 A kind of environmental protection coating material and preparation method thereof
CN107473699A (en) * 2017-08-22 2017-12-15 佛山市因诺维生物科技有限公司 A kind of indoor mildew resistant paint
CN108677537A (en) * 2018-04-28 2018-10-19 安徽恒益纺织科技有限公司 A kind of fire retardant, anticorrosive slurry of cotton
WO2022133661A1 (en) * 2020-12-21 2022-06-30 张辉航 Ultraviolet-curable white primer for fireproof layer

Similar Documents

Publication Publication Date Title
CN106189603A (en) A kind of nanometer fireproof antibacterial environment protection coating and preparation method thereof
CN103289453B (en) Anti-bacteria deodorizing inorganic functional coating and preparation method thereof
CN101914329B (en) Nano multifunctional outer wall heat preservation coating
CN103965780B (en) A kind of woodenware lacquer tree fat coating and preparation method thereof
CN103088634B (en) Spirocyclic phosphate expansive type low-smoke coating flame retardance cellulose textile and preparation method thereof
CN105694550A (en) Single-component waterborne inorganic terrace paint formula and manufacturing technology
CN111154364A (en) Interior wall water paint and preparation method thereof
CN105541187B (en) One kind has true mineral varnish of the gorgeous color of light and preparation method thereof
CN109251608A (en) A kind of environmental protection oyster shell whiting biology coating and preparation method thereof
CN107936767A (en) A kind of bi-component water dispersible epoxy primer coating and preparation method thereof
CN101824277A (en) Latex paint and aqueous wood ware paint for eliminating formaldehyde and preparation method thereof
CN109294347A (en) A kind of Gao Baose water paint and production method
TW200740697A (en) Yttrium oxide composition, method of preparing the same, and method of forming yttrium oxide layer using the same
CN104858969A (en) Environmental protection wood flame retardation antiseptic
CN105482587A (en) Environment-friendly water-based nano-structure wood paint and preparation method thereof
CN102617069A (en) Method for preparing inorganic-organic anti-weathering composite material for protecting stone relics
CN101343447A (en) Composite exterior wall paint of inorganic polysiloxane and emulsion, and preparation thereof
CN108456466A (en) A kind of high performance nano paint and preparation method thereof
CN104927616A (en) Ultrathin steel-structure fireproof water paint and preparation method thereof
CN107556803A (en) A kind of mould proof powder of lacquer putty for use on
CN101633812A (en) Flexible texture coating and preparation method thereof
CN103627280B (en) A kind of mono-component aqueous outdoor top-coat varnish
CN108707405A (en) A method of addition modified nano oxide compound prepares wood artwork antibacterial and mouldproof abrasion resistant fire blocking coating
CN104788069A (en) Ceramic mosquito-repellent incense disc containing Chinese herbal medicines
CN104910738A (en) Art texture water paint and preparation method thereof

Legal Events

Date Code Title Description
C06 Publication
PB01 Publication
C10 Entry into substantive examination
SE01 Entry into force of request for substantive examination
WW01 Invention patent application withdrawn after publication

Application publication date: 20161207

WW01 Invention patent application withdrawn after publication