CN106189236A - A kind of novel environment friendly runway - Google Patents
A kind of novel environment friendly runway Download PDFInfo
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- CN106189236A CN106189236A CN201610638822.1A CN201610638822A CN106189236A CN 106189236 A CN106189236 A CN 106189236A CN 201610638822 A CN201610638822 A CN 201610638822A CN 106189236 A CN106189236 A CN 106189236A
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L81/00—Compositions of macromolecular compounds obtained by reactions forming in the main chain of the macromolecule a linkage containing sulfur with or without nitrogen, oxygen or carbon only; Compositions of polysulfones; Compositions of derivatives of such polymers
- C08L81/06—Polysulfones; Polyethersulfones
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G75/00—Macromolecular compounds obtained by reactions forming a linkage containing sulfur with or without nitrogen, oxygen, or carbon in the main chain of the macromolecule
- C08G75/20—Polysulfones
- C08G75/23—Polyethersulfones
-
- E—FIXED CONSTRUCTIONS
- E01—CONSTRUCTION OF ROADS, RAILWAYS, OR BRIDGES
- E01C—CONSTRUCTION OF, OR SURFACES FOR, ROADS, SPORTS GROUNDS, OR THE LIKE; MACHINES OR AUXILIARY TOOLS FOR CONSTRUCTION OR REPAIR
- E01C13/00—Pavings or foundations specially adapted for playgrounds or sports grounds; Drainage, irrigation or heating of sports grounds
- E01C13/02—Foundations, e.g. with drainage or heating arrangements
-
- E—FIXED CONSTRUCTIONS
- E01—CONSTRUCTION OF ROADS, RAILWAYS, OR BRIDGES
- E01C—CONSTRUCTION OF, OR SURFACES FOR, ROADS, SPORTS GROUNDS, OR THE LIKE; MACHINES OR AUXILIARY TOOLS FOR CONSTRUCTION OR REPAIR
- E01C13/00—Pavings or foundations specially adapted for playgrounds or sports grounds; Drainage, irrigation or heating of sports grounds
- E01C13/04—Pavings made of prefabricated single units
- E01C13/045—Pavings made of prefabricated single units the prefabricated single units consisting of or including bitumen, rubber or plastics
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
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- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
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- Civil Engineering (AREA)
- Structural Engineering (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Abstract
The present invention relates to a kind of novel environment friendly runway.It contains the polymer of 75～85 weight portions, the filler of 1～3 weight portions, the accelerator of 1～2 weight portions, the age resistor of 0.5～0.8 weight portion, the oils and fats of 2～5 weight portions, the polyether polyol of 3～6 weight portions, the antioxidant of 0.05～0.1 weight portion, the UV absorbent of 0.05～0.1 weight portion.When described material forms runway, good mechanical property, surface drying time and hardening time are short, and wearability is good, and weatherability, water proofing property are good, are difficult to aging.
Description
Technical field
The present invention relates to high molecular polymer field, specifically, the present invention relates to environment friendly plastic rubber track material and system thereof
Preparation Method.
Background technology
Plastic cement race track also known as round-the-clock athletics tracks, by base polyurethane prepolymer for use as, admixtured polyether, scrap tire rubber,
EPDM rubber grain or PU granule, pigment, auxiliary agent, filler composition.Plastic cement race track has that flatness is good, comprcssive strength is high, hardness bullet
Property suitably, the characteristic of stable physical property, beneficially athlete's speed and the performance of technology, be effectively improved sports achievement, fall
Low traumatic injury rate.Plastic cement race track is made up of materials such as polyurethane rubbers, has certain elasticity and color, has certain resisting
UV resistance and ageing-resistant power are the optimal all-weather outdoor athletic ground terrace materials generally acknowledged in the world.Plasticized polyurethane glue material
Work progress in the most water funk, rubber cement before primary solidification, encounter drop of water will produce a big bubble, therefore construct
Personnel's operation under the high temperature conditions towel to be prepared wipes the sweat.Necessarily grasp weather condition and to carry out and prevent bust battle array during paving glue surface
The emergency measure of rain.In paving morning to be avoided glue time air and the when that surface humidity being bigger, though fine just
On often working day, laying it is generally advisable to formal after at 9 in the morning, plastic cement race track is laid.The reality paving thickness of glue surface refers to from the bottom of glue
To the center of top layer micelle, typically control in terms of two.First pass through formwork erection and carry out the preliminary examination of gauge, high to basic unit local
The place gone out carries out repairing cuts or hammering carries out ramming low.If exceeding few, can use and adding fixture on flat floating rule and scrape slurry from mould and protect
Card thickness, the main playing area of plastic cement race track, arena, the 11st Asian Games north suburb is for ensureing thickness, and error control is principal-employment, therefore averagely thick
Degree is at more than 14MM.Locally there is shelling of bubbling after preventing glue surface making, strictly to control for basic unit's degree of compaction, prevent Colophonium
Basal layer self embedded squeezing is unreal, and shell delamination, causes cohesive force poor, and gasifying in surface, glue surface is pulled off.Basic unit's degree of compaction is inadequate
Place, can use drill bit to punch, and the method for encapsulating (rubber tack) is reinforced.For ensureing flatness, the gradient, mould bar is fixed
After, it is simulated correction, the place that basic unit is the highest by level indicator, is first flattened, the lowest place, fill and lead up with glue.Quilt
The basic part of contaminated by diesel oil and corrosion is firmly dug up, and fills and leads up with glue.
Between nearly more than ten years, plastic cement race track is developed rapidly in China, scope by original sports departments, expand to big,
In, primary school, become the sports ground that large, medium and small of China is well received.Plastic cement race track adhesive is along with plastic cement race track
Fast-developing and be widely studied and produce, there is number of types of plastic cement race track polyurethane material
Material, but due to different material choice, formula design and synthesis technique so that the performance between these materials exists bigger
Difference, also has use greatly constructor and user can be caused risk, causes environmental pollution.Owing to plastic cement race track is
Use one-component polyurethane adhesive to be combined into gum elastic granule, need to have airing function so that it is at high temperature
The steam that base produces can not quickly distribute, and steam pressure cannot be assembled, and produces bubbling phenomenon.It is thus desirable to a kind of ring
Protecting nontoxic, volatile organic content is low, and adhesion strength is high, and peel strength is high, good mechanical property, surface drying time and hardening time
Short, wearability is good, and weatherability, water proofing property are good, is difficult to aging track material.
Summary of the invention
Present invention aim at providing a kind of environmental protection track material.
Present invention aim at providing the preparation method of a kind of environmental protection track material.
Another object of the present invention is to provide a kind of Formulas I polymer.
Another object of the present invention is to provide the preparation method of a kind of Formulas I polymer.
For solving above-mentioned technical problem, present invention employs following technical proposals:
A kind of environmental protection track material, it contains the polymer of 75～85 weight portions, the filler of 1～3 weight portions, 1～2 weight
The accelerator of part, the age resistor of 0.5～0.8 weight portion, the oils and fats of 2～5 weight portions, the polyether polyol of 3～6 weight portions,
The antioxidant of 0.05～0.1 weight portion, the UV absorbent of 0.05～0.1 weight portion.
Preferably, the polymer of 85 weight portions, the filler of 3 weight portions, the accelerator of 2 weight portions, preventing of 0.5 weight portion is old
Agent, the oils and fats of 2 weight portions, the polyether polyol of 3 weight portions, the antioxidant of 0.05 weight portion, the ultraviolet of 0.1 weight portion is inhaled
Receive agent.
Preferably, the polymer of 75 weight portions, the filler of 1 weight portion, the accelerator of 1 weight portion, preventing of 0.5 weight portion is old
Agent, the oils and fats of 5 weight portions, the polyether polyol of 6 weight portions, the antioxidant of 0.1 weight portion, the ultraviolet of 0.08 weight portion is inhaled
Receive agent.
It is highly preferred that the polymer of 80 weight portions, the filler of 2 weight portions, the accelerator of 1 weight portion, preventing of 0.5 weight portion
Old agent, the oils and fats of 2 weight portions, the polyether polyol of 6 weight portions, the antioxidant of 0.1 weight portion, the ultraviolet of 0.1 weight portion
Absorbent.
The Formulas I polymer that described polymer is as follows, wherein MwIt is 2.88 × 105, MnIt is 0.75 × 105, molecular weight
Profile exponent is 3.84:
Preferably, described filler one in Pulvis Talci, magnesium carbonate, silica flour, potter's clay, calcium carbonate or Kaolin or
Multiple；Described accelerator is selected from N cyclohexyl 2 benzothiazole sulfenamide；Described age resistor is selected from 4.4 '-bis-(2.2-diformazans
Base benzyl) diphenylamines, one or more in antioxidant 264 or antioxidant D；Described oils and fats is selected from amido silicon oil；Described polyethers
One or more in DL-1000, DL-2000, DL-4000 or MN-3050 of polyhydric alcohol；Described antioxidant is selected from antioxygen
Agent 1010, irgasfos 168, antioxidant 164, antioxidant DNP, anti-oxidant DLTP, antioxidant TNP, antioxidant TPP, antioxidant MB
In one or more；Described UV absorbent is selected from oxybenzoic acid phenyl ester, 2,4-DihydroxyBenzophenone, 2-hydroxyl
Base-4-methoxy benzophenone, Octabenzone, 2-(2 '-hydroxyl-3 ', 5 '-two tertiary phenyl)-5-chlorine
Change benzotriazole, single benzoic acid resorcinol, three (1,2,2,6,6-pempidine base) phosphite ester, 4-benzoyloxy-
One in 2,2,6,6-tetramethyl piperidines, 2,4,6-tri-(2 ' n-butoxyphenyl)-1,3,5-triazines, HMPA
Or it is multiple.
It is highly preferred that described filler is selected from Pulvis Talci；Described accelerator is selected from N-cyclohexyl-2-[4-morpholinodithio time sulphonyl
Amine；Described age resistor is selected from 4.4 '-bis-(2.2-dimethyl benzyl) diphenylamines；Described oils and fats is selected from amido silicon oil；Described polyethers
Polyhydric alcohol is selected from DL-1000；Described antioxidant is selected from antioxidant 1010；Described UV absorbent is selected from oxybenzoic acid
Phenyl ester.
It is highly preferred that described filler is selected from calcium carbonate；Described accelerator is selected from N-cyclohexyl-2-[4-morpholinodithio time sulphonyl
Amine；Described age resistor is selected from antioxidant 264；Described oils and fats is selected from amido silicon oil；Described polyether polyol is selected from DL-2000；Institute
State antioxidant selected from irgasfos 168；Described UV absorbent is selected from 2,4-DihydroxyBenzophenone.
Most preferably, described filler is selected from silica flour；Described accelerator is selected from N-cyclohexyl-2-[4-morpholinodithio time sulphonyl
Amine；Described age resistor is selected from antioxidant D；Described oils and fats is selected from amido silicon oil；Described polyether polyol is selected from MN-3050；Described
Antioxidant is selected from antioxidant TNP；Described UV absorbent is selected from single benzoic acid resorcinol.
Preferably, described track material is prepared by following method:
(1) by the polymer of 75～85 weight portions, the accelerator of 1～2 weight portions, the oils and fats of 2～5 weight portions, 3～6 weights
The polyether polyol of amount part, the antioxidant of 0.05～0.1 weight portion, the UV absorbent of 0.05～0.1 weight portion is abundant
Mixing, stirs, is warming up to 90-100 DEG C；
(2) add filler and the age resistor of 0.5～0.8 weight portion of 1～3 weight portions, stir；
(3) with colloid mill, above-mentioned material is ground to particle diameter 400 mesh；
(4) being continuously heating to 100-110 DEG C, vacuum is dehydrated 4 hours at below 0.06MPa.
The preparation method of described track material, it comprises the steps:
(1) by the polymer of 75～85 weight portions, the accelerator of 1～2 weight portions, the oils and fats of 2～5 weight portions, 3～6 weights
The polyether polyol of amount part, the antioxidant of 0.05～0.1 weight portion, the UV absorbent of 0.05～0.1 weight portion is abundant
Mixing, stirs, is warming up to 90-100 DEG C；
(2) add filler and the age resistor of 0.5～0.8 weight portion of 1～3 weight portions, stir；
(3) with colloid mill, above-mentioned material is ground to particle diameter 400 mesh；
(4) being continuously heating to 100-110 DEG C, vacuum is dehydrated 4 hours at below 0.06MPa.
Polymer of the present invention, as shown in Formulas I polymer: wherein MwIt is 2.88 × 105, MnIt is 0.75 × 105, point
Son amount profile exponent is 3.84:
Described Formulas I polymer, it is prepared by following method:
(1) by 2-(N, N-dimethylamino ester group) the fluoro-8-of-3,6-two (1 '-naphthyl)-naphthalene 15.0mmol, 4,4 '-dichloro
Benzene sulfone, 1-(2,5-dihydroxybenzoyl) pyrene, be placed in reaction vessel mixing；
(2) oil bath is heated to 150 DEG C, point water 4 hours, is continuously heating to 190 DEG C, and reaction is overnight；
(3) reactant liquor of step (2) is poured slowly in deionized water, obtains white bars shaped polymer, change water, constant temperature 80
DEG C, decocting in water three times, each 6 hours, dry, then 100 DEG C vacuum drying 24 hours after obtain Formulas I polymer.
The preparation method of described Formulas I polymer, it comprises the steps:
(1) by 2-(N, N-dimethylamino ester group) the fluoro-8-of-3,6-two (1 '-naphthyl)-naphthalene 15.0mmol, 4,4 '-dichloro
Benzene sulfone, 1-(2,5-dihydroxybenzoyl) pyrene, be placed in reaction vessel mixing；
(2) oil bath is heated to 150 DEG C, point water 4 hours, is continuously heating to 190 DEG C, and reaction is overnight；
(3) reactant liquor of step (2) is poured slowly in deionized water, obtains white bars shaped polymer, change water, constant temperature 80
DEG C, decocting in water three times, each 6 hours, dry, then 100 DEG C vacuum drying 24 hours after obtain Formulas I polymer.
Described Formulas I polymer can be used for engineering aspect.
Accompanying drawing explanation
Fig. 1 is the sectional view of runway of the present invention；
1-bottom；2-basic unit；3-surface layer；4-water leg；5-osculum；6-drain pipe.
Embodiment
Below by embodiment, the invention will be further described.It should be understood that method described in the embodiment of the present invention
It is only used for the present invention rather than limitation of the present invention being described, to the present invention side of preparation under the concept thereof of the present invention
The simple modifications of method broadly falls into the scope of protection of present invention.The all raw materials used in embodiment if no special instructions are purchased from
Shanghai Yaoming Kangde New Medicine Development Co., Ltd, solvent is purchased from Sigma Biochemical and Organic
Compounds for Research and Diagnostic Clinical Reagents company.
Embodiment 1: the preparation of Formulas I polymer
Under nitrogen atmosphere, by 2-(N, N-dimethylamino ester group)-3, the fluoro-8-of 6-bis-(1 '-naphthyl)-naphthalene
15.0mmol, 4,4 '-dichloro-benzenes sulfone 8.0mmol, 1-(2,5-dihydroxybenzoyl) pyrene 25mmol, Anhydrous potassium carbonate
30mmol, N,N-dimethylacetamide 60ml, toluene 30ml is placed in reaction vessel mixing, and oil bath is heated to 150 DEG C, point water 4
Hour, steaming toluene, be continuously heating to 190 DEG C, reaction is overnight.Reactant liquor is poured slowly in 500ml deionized water, obtains white
Color strip-shaped polymer, changes water, constant temperature 80 DEG C, decocting in water three times, each 6 hours, dries, then after 100 DEG C of vacuum drying 24 hours
Obtain white fibrous Formulas I polymer, productivity 91.8%.Wherein MwIt is 2.88 × 105, MnIt is 0.75 × 105, molecular weight distribution
Index is 3.84.
1HNMR(300MHz,DMSO),δ:8.90(q,H,CH)；8.37(q,H,CH)；8.14(d,2H,2CH)；7.96(q,
2H,2CH)；7.85(m,H,CH)；7.84(m,4H,4CH)；7.81(d,2H,2CH)；7.77(s,1H,CH)；7.74(s,1H,
CH)；7.70(s,1H,CH)；7.66(d,2H,2CH)；7.56(s,2H,2CH)；7.54(s,H,CH)；7.51(d,2H,2CH)；
7.49(d,H,CH)；7.45(d,2H,2CH)；7.43(d,H,CH)；7.28(d,2H,2CH)；7.00(d,2H,2CH)；6.90
(q,H,CH)；6.57(d,2H)；6.24(d,H,CH)；6.09(t,2H)；5.80(m,2H)；5.16(s,2H,CH2)；3.66(d,
4H,2CH2)；3.27(s,6H,2CH3)；2.63(d,4H,2CH2).
Embodiment 2: the toxicity test of Formulas I polymer:
The PPAR δ activity of the polymer represented by Formulas I of invention is confirmed by transfection detection.It addition, for PPAR hypotype
The selectivity of PPAR α and PPAR γ is also carried out inspection.Test cell toxicity is detected, by animal experiment study body by MTT
Activity.
This detection uses CV-1 cell.Described cell is seeded to containing being added with 10%FBS, DBS (non-specific
Property Ox blood serum, through defat) and 1% penicillin/streptomycin DMEM 96 orifice plates in, and at 37 DEG C, 5%CO2Incubator in
Cultivate.Test and carry out according to the step of inoculation, transfection, sample administration and confirmation.Specifically, CV-1 cell is seeded to 96 holes
Plate (5000 cells/well), transfected after 24 hours.By total length PPAR plasmid DNA, can confirm that because having uciferase activity
PPAR activity reporter dna, provide the beta galactosidase DNA about transfection efficiency information and transfection reagent for transfecting.Will
Sample is dissolved in dimethyl sulfoxide (DMSO), it is administered in cell with variable concentrations by medium.Incubator is cultivated
After cell 24 hours, by using lysis buffer to make cell crack.Photometer and microplate reader is used to measure uciferase activity
And betagalactosidase activity.Use the value of the luciferase of the value correction acquisition of beta galactosidase.These values are utilized to draw
Figure, and calculate EC50。
The polymer of the present invention has high selectivity for PPAR δ as can be seen here.
Perform the cytotoxicity that MTT detection is the polymer in order to test the present invention.MTT is dissolved in the yellow substance of water,
But can become, by the dehydrogenase in mitochondrion, the crystal that purple is insoluble when it is introduced in living cells.MTT is being dissolved
Cytotoxicity can be confirmed by measuring OD550 after in dimethyl sulfoxide.Experiment is carried out as follows.
CV-1 cell is inoculated in 96 orifice plates (5000 cells/well).At 37 DEG C, 5%CO2Incubator in cultivate institute
State cell 24 hours, and it is used the sample of variable concentrations.Then, again described cell is cultivated 24 hours, add wherein
Enter MTT reagent.After cultivating 15 minutes, the purple crystals of generation is dissolved in dimethyl sulfoxide.Microplate reader is used to measure optical density, with
Confirm cytotoxicity.
As a result, Formulas I the polymer represented is identified PPAR is not had to cytotoxicity, even if being EC in its concentration50
Value 100 times～1000 times time the most such.
Embodiment 3: the preparation of track material
(1) by the Formulas I polymer of 85 kilograms, the N cyclohexyl 2 benzothiazole sulfenamide of 2 kilograms, the amino of 2 kilograms
Silicone oil, the DL-1000 of 3 kilograms, the antioxidant 1010 of 0.05 kilogram, the oxybenzoic acid phenyl ester of 0.1 kilogram is sufficiently mixed, and stirs
Mix uniformly, be warming up to about 90 DEG C；
(2) adding the Pulvis Talci of 3 kilograms and 4.4 '-bis-(2.2-dimethyl benzyl) diphenylamines of 0.5 kilogram, stirring is all
Even；
(3) with colloid mill, above-mentioned material is ground to particle diameter 400 mesh；
(4) being continuously heating to about 100 DEG C, vacuum is dehydrated 4 hours at below 0.06MPa.
Embodiment 4: the preparation of track material
(1) by the Formulas I polymer of 75 kilograms, the N cyclohexyl 2 benzothiazole sulfenamide of 1 kilogram, the amino of 5 kilograms
Silicone oil, the DL-2000 of 6 kilograms, the irgasfos 168 of 0.1 kilogram, the 2,4-DihydroxyBenzophenone of 0.08 kilogram is sufficiently mixed,
Stir, be warming up to 95 DEG C；
(2) add the calcium carbonate of 1 kilogram and the antioxidant 264 of 0.5 kilogram, stir；
(3) with colloid mill, above-mentioned material is ground to particle diameter 400 mesh；
(4) being continuously heating to about 110 DEG C, vacuum is dehydrated 4 hours at below 0.06MPa.
Embodiment 5: the preparation of track material
(1) by the Formulas I polymer of 80 kilograms, the N cyclohexyl 2 benzothiazole sulfenamide of 1 kilogram, the amino of 2 kilograms
Silicone oil, the MN-3050 of 6 kilograms, the antioxidant TNP of 0.1 kilogram, single benzoic acid resorcinol of 0.1 kilogram is sufficiently mixed, and stirs
Mix uniformly, be warming up to 90 DEG C；
(2) add the silica flour of 2 kilograms and the antioxidant D of 0.5 kilogram, stir；
(3) with colloid mill, above-mentioned material is ground to particle diameter 400 mesh；
(4) being continuously heating to 100 DEG C, vacuum is dehydrated 4 hours at below 0.06MPa.
Performance test embodiment:
Material embodiment 3-5 prepared detects according to the method described in GB/T14833-2011, material
VOC volatility directly uses fan news method to test, and testing result is as follows:
Can be experienced intuitively by fan news method, the material that the present invention prepares is not pungent, substantially tasteless, therefore originally
Invention has lower VOC emission, shows more excellent environmental-protecting performance.
As can be seen from the above table, the material for runway of the present invention complies fully with national standard requirement.
Embodiment prepared by runway:
A kind of environmental protection runway, it includes bottom 1, basic unit 2 and surface layer 3, bottom 1 is provided with water leg 4, water leg 4
Bottom is provided with multiple osculum 5, and osculum 5 is provided with drain pipe 6, and drain pipe 6 extends to inside soil.Described surface layer 3
Being made up of above-mentioned environmental protection track material, environmental protection track material is pressed into diamond block, is spliced, and there is 5mm at every piece of diamond block edge
Draining seam.Bottom 1 is soil horizon, is provided with basic unit 2, and basic unit 2 is xoncrete structure, and basic unit 2 is provided with surface layer 3,
Skid resistant course can be set between basic unit 2 and surface layer 3.
In use, first bottom 1 is constructed, reserved water leg 4 and osculum 5, in osculum, load draining simultaneously
Pipe.Water leg 4 internal medicine fills cobblestone, by steel wire square on water leg 4, and keep level with the top of bottom 1, then
Lay basic unit 2 and surface layer 3.
Claims (9)
1. a novel environment friendly track material, it is characterised in that: it contains the polymer of 75～85 weight portions, 1～3 weight portions
Filler, the accelerator of 1～2 weight portions, the age resistor of 0.5～0.8 weight portion, the oils and fats of 2～5 weight portions, 3～6 weight portions
Polyether polyol, the antioxidant of 0.05～0.1 weight portion, the UV absorbent of 0.05～0.1 weight portion.
Novel environment friendly track material the most according to claim 1, it is characterised in that: the formula that described polymer is as follows
I polymer, wherein MwIt is 2.88 × 105, MnIt is 0.75 × 105, molecular weight distributing index is 3.84:
Novel environment friendly track material the most according to claim 1, it is characterised in that: described filler is selected from Pulvis Talci, carbonic acid
One or more in magnesium, silica flour, potter's clay, calcium carbonate or Kaolin；Described accelerator is selected from N-cyclohexyl-2-[4-morpholinodithio
Sulfenamide；Described age resistor is selected from 4.4 '-bis-(2.2-dimethyl benzyl) diphenylamines, antioxidant 264 or antioxidant D
Plant or multiple；Described oils and fats is selected from amido silicon oil；Described polyether polyol is selected from DL-1000, DL-2000, DL-4000 or MN-
One or more in 3050；Described antioxidant selected from antioxidant 1010, irgasfos 168, antioxidant 164, antioxidant DNP,
One or more in anti-oxidant DLTP, antioxidant TNP, antioxidant TPP, antioxidant MB；Described UV absorbent is selected from neighbour
Hydroxy benzoic acid phenyl ester, 2,4-DihydroxyBenzophenone, ESCALOL 567,2-hydroxyl-4-n-octyloxy two
Benzophenone, 2-(2 '-hydroxyl-3 ', 5 '-two tertiary phenyl)-5-chlorination benzotriazole, single benzoic acid resorcinol, three (1,2,2,
6,6-pempidine bases) phosphite ester, 4-benzoyloxy-2,2,6,6-tetramethyl piperidines, 2,4,6-tri-(2 ' n-butoxy benzene
Base)-1,3,5-triazines, one or more in HMPA.
4. a novel environment friendly runway, it is characterised in that: including bottom (1), basic unit (2) and surface layer (3), bottom (1) is upper to be arranged
There are water leg (4), the bottom of water leg (4) to be provided with multiple osculum (5), osculum (5) is provided with drain pipe (6), row
Water pipe (6) extends to inside soil.
Novel environment friendly runway the most according to claim 4, it is characterised in that: described surface layer (3) is arbitrary by claim 1-3
Described environmental protection track material is made, and environmental protection track material is pressed into diamond block, is spliced, and there is 5mm at every piece of diamond block edge
Draining seam, described diamond block use prefabricated once molding formed technique make.
6. the preparation method of the arbitrary described novel environment friendly track material of claim 1-3, it is characterised in that comprise the steps:
(1) by the polymer of 75～85 weight portions, the accelerator of 1～2 weight portions, the oils and fats of 2～5 weight portions, 3～6 weight portions
Polyether polyol, the antioxidant of 0.05～0.1 weight portion, the UV absorbent of 0.05～0.1 weight portion is sufficiently mixed,
Stir, be warming up to 90-100 DEG C；
(2) add filler and the age resistor of 0.5～0.8 weight portion of 1～3 weight portions, stir；
(3) with colloid mill, above-mentioned material is ground to particle diameter 400 mesh；
(4) being continuously heating to 100-110 DEG C, vacuum is dehydrated 4 hours at below 0.06MPa.
7. a polymer, it is characterised in that as shown in following Formulas I polymer: wherein MwIt is 2.88 × 105, MnIt is 0.75 × 105,
Molecular weight distributing index is 3.84:
8. the preparation method of the Formulas I polymer described in claim 7, it is characterised in that comprise the steps:
(1) by 2-(N, N-dimethylamino ester group) the fluoro-8-of-3,6-two (1 '-naphthyl)-naphthalene 15.0mmol, 4,4 '-dichloro-benzenes
Sulfone, 1-(2,5-dihydroxybenzoyl) pyrene, be placed in reaction vessel mixing；
(2) oil bath is heated to 150 DEG C, point water 4 hours, is continuously heating to 190 DEG C, and reaction is overnight；
(3) reactant liquor of step (2) is poured slowly in deionized water, obtains white bars shaped polymer, change water, constant temperature 80 DEG C,
Decocting in water three times, each 6 hours, dry, then 100 DEG C vacuum drying 24 hours after obtain Formulas I polymer.
9. the purposes in terms of engineering of the Formulas I polymer described in claim 7.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610638822.1A CN106189236B (en) | 2016-08-08 | 2016-08-08 | A kind of environmental protection runway |
Applications Claiming Priority (1)
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Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107353463A (en) * | 2017-08-24 | 2017-11-17 | 苏州诺乐智能科技有限公司 | A kind of balance car pedal |
| CN108330773A (en) * | 2017-12-08 | 2018-07-27 | 王建中 | A kind of plastic cement race track |
| CN109721482A (en) * | 2017-10-31 | 2019-05-07 | 三星显示有限公司 | Light absorber and organic electroluminescence device including the light absorber |
| US11800791B2 (en) | 2017-10-31 | 2023-10-24 | Samsung Display Co., Ltd. | Light absorber and organic electroluminescence device including the same |
Citations (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB459333A (en) * | 1935-02-04 | 1937-01-06 | Chem Ind Basel | Manufacture of vat-dyestuffs and intermediate products therefor |
| CN1470583A (en) * | 2003-06-25 | 2004-01-28 | 广东药学院 | Environmental-protection type polyurethane paving material for sports ground |
| CN101245184A (en) * | 2007-02-15 | 2008-08-20 | 天津市景鸿体育设施技术有限公司 | Nano-environment protection type polyurethane paving material for athletic ground and manufacture method thereof |
| CN101701067A (en) * | 2009-11-18 | 2010-05-05 | 吉林大学 | Tetramethyl-diphenol type polyarylether ketone (polyarylether sulphone) containing bromine at phenmethyl position and preparation method thereof |
| CN102250542A (en) * | 2011-04-25 | 2011-11-23 | 广州市合工大实力新材料研究院有限公司 | Polyurethane anti-slip finish material as well as preparation method and application thereof |
| CN103666233A (en) * | 2013-11-27 | 2014-03-26 | 金华市一纯体育器材有限公司 | Ventilated polyurethane plastic race-track surface layer cementing material |
| CN105001625A (en) * | 2015-07-03 | 2015-10-28 | 蔡晓明 | Environment-friendly type one-component water-cured lines-self-forming plastic track material and preparation method thereof |
| CN205205612U (en) * | 2015-12-02 | 2016-05-04 | 福建路港（集团）有限公司 | Synthetic track |
-
2016
- 2016-08-08 CN CN201610638822.1A patent/CN106189236B/en active Active
Patent Citations (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB459333A (en) * | 1935-02-04 | 1937-01-06 | Chem Ind Basel | Manufacture of vat-dyestuffs and intermediate products therefor |
| CN1470583A (en) * | 2003-06-25 | 2004-01-28 | 广东药学院 | Environmental-protection type polyurethane paving material for sports ground |
| CN101245184A (en) * | 2007-02-15 | 2008-08-20 | 天津市景鸿体育设施技术有限公司 | Nano-environment protection type polyurethane paving material for athletic ground and manufacture method thereof |
| CN101701067A (en) * | 2009-11-18 | 2010-05-05 | 吉林大学 | Tetramethyl-diphenol type polyarylether ketone (polyarylether sulphone) containing bromine at phenmethyl position and preparation method thereof |
| CN102250542A (en) * | 2011-04-25 | 2011-11-23 | 广州市合工大实力新材料研究院有限公司 | Polyurethane anti-slip finish material as well as preparation method and application thereof |
| CN103666233A (en) * | 2013-11-27 | 2014-03-26 | 金华市一纯体育器材有限公司 | Ventilated polyurethane plastic race-track surface layer cementing material |
| CN105001625A (en) * | 2015-07-03 | 2015-10-28 | 蔡晓明 | Environment-friendly type one-component water-cured lines-self-forming plastic track material and preparation method thereof |
| CN205205612U (en) * | 2015-12-02 | 2016-05-04 | 福建路港（集团）有限公司 | Synthetic track |
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107353463A (en) * | 2017-08-24 | 2017-11-17 | 苏州诺乐智能科技有限公司 | A kind of balance car pedal |
| CN109721482A (en) * | 2017-10-31 | 2019-05-07 | 三星显示有限公司 | Light absorber and organic electroluminescence device including the light absorber |
| CN109721482B (en) * | 2017-10-31 | 2023-07-18 | 三星显示有限公司 | Light absorber and organic electroluminescent device including the same |
| US11800791B2 (en) | 2017-10-31 | 2023-10-24 | Samsung Display Co., Ltd. | Light absorber and organic electroluminescence device including the same |
| CN108330773A (en) * | 2017-12-08 | 2018-07-27 | 王建中 | A kind of plastic cement race track |
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| CN106189236B (en) | 2019-03-08 |
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