CN106188899A - A kind of TPX mould release membrance - Google Patents
A kind of TPX mould release membrance Download PDFInfo
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- CN106188899A CN106188899A CN201610590984.2A CN201610590984A CN106188899A CN 106188899 A CN106188899 A CN 106188899A CN 201610590984 A CN201610590984 A CN 201610590984A CN 106188899 A CN106188899 A CN 106188899A
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- tpx
- mould release
- release membrance
- thin layer
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
- C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L23/18—Homopolymers or copolymers of hydrocarbons having four or more carbon atoms
- C08L23/20—Homopolymers or copolymers of hydrocarbons having four or more carbon atoms having four to nine carbon atoms
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J5/00—Manufacture of articles or shaped materials containing macromolecular substances
- C08J5/18—Manufacture of films or sheets
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2323/00—Characterised by the use of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Derivatives of such polymers
- C08J2323/02—Characterised by the use of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Derivatives of such polymers not modified by chemical after treatment
- C08J2323/18—Homopolymers or copolymers of hydrocarbons having four or more carbon atoms
- C08J2323/20—Homopolymers or copolymers of hydrocarbons having four or more carbon atoms having four to nine carbon atoms
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2469/00—Characterised by the use of polycarbonates; Derivatives of polycarbonates
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/08—Stabilised against heat, light or radiation or oxydation
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2203/00—Applications
- C08L2203/16—Applications used for films
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/14—Polymer mixtures characterised by other features containing polymeric additives characterised by shape
- C08L2205/16—Fibres; Fibrils
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- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Manufacturing & Machinery (AREA)
- Materials Engineering (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Abstract
The present invention provides a kind of TPX mould release membrance, including thin layer, described thin layer includes following weight proportion raw material: TPX, PC, 2 ethyl methacrylate, polyurethane, polyimides, polyetheretherketonefiber fiber, carbon fiber, organo montmorillonite, ethylene glycol, silane coupler, antioxidant, light stabilizer, defoamer and thickening agent;Described TPX mould release membrance surfacing is bright and clean, has good peel strength and hot strength;Secondly, described TPX mould release membrance possesses good heat stability and percent thermal shrinkage, it is possible to light aging resisting also can repeatedly Reusability;Additionally, a kind of TPX mould release membrance environment-protecting asepsis that the present invention provides, synthetic method is simple, easy and simple to handle, mild condition, it is adaptable to industrialized production.
Description
Technical field
The present invention relates to a kind of mould release membrance, be specifically related to a kind of TPX mould release membrance.
Background technology
Mould release membrance, also known as stripping film, isolating membrane, separation film, adhesive block film, fractal film, thin film, plastic sheeting, masking hole film, silicon
Oil film, silicone oil paper, antiadhesion barrier, skidding film, that paper of sky, release paper, silliconfilm, release film, release.Logical
In order to increase the off-type force of plastic sheeting in the case of Chang, plastic sheeting can be done plasma treatment, or be coated with fluorine process, or be coated with silicon
(silicone) mould release is on the top layer of film material, such as PET, PE, OPP etc.;Allow it for various different organic pressures
Sense glue (such as hot melt adhesive, acrylic glue and the pressure sensitive adhesive of rubber series) can show the lightest and stable off-type force.
Owing to mould release membrance has isolation, fills, protects, the advantage such as is easily peeled off, therefore it is widely used in various electricity
In the fields such as son, communication, machinery.
TPX mould release membrance is of wide application, and main uses includes: medical treatment, cosmetics containers, physical and chemical experiment utensil, microwave
With feeder, electrical/electronic part, industrial part, thin film, information equipment part, resin modification agent, electric insulation material etc., in addition
The application such as the light internal memory of advanced person, optical communication equipment, water treatment facilities, air separation membrane are the most under development.
But existing TPX mould release membrance heat sealability is poor, and percent thermal shrinkage is low, being not easy to reclaim, mechanical performance can not expire
The demand of foot industry.
Summary of the invention
For solving the problem of above-mentioned existence, it is an object of the invention to provide a kind of TPX mould release membrance, described TPX mould release membrance
Surfacing is bright and clean, has good peel strength and hot strength;Secondly, described TPX mould release membrance possesses good heat surely
Qualitative and percent thermal shrinkage, it is possible to light aging resisting also can repeatedly Reusability;Additionally, described TPX mould release membrance environment-protecting asepsis, synthesis side
Method is simple, easy and simple to handle, mild condition, it is adaptable to industrialized production.
For reaching above-mentioned purpose, the technical solution used in the present invention is:
A kind of TPX mould release membrance, including thin layer, described thin layer includes following weight proportion raw material:
TPX:100~110 parts, PC:10~15 parts, ethyl 2-methacrylate: 5~10 parts, polyurethane: 3~5 parts, polyamides is sub-
Amine: 2~3 parts, polyetheretherketonefiber fiber: 2~4 parts, carbon fiber: 1~2 part, organo montmorillonite: 1~3 part, ethylene glycol: 15~25
Part, silane coupler: 1~2 part, antioxidant: 0.1~1 part, light stabilizer: 0.1~1 part, defoamer: 0.1~0.5 part, thickening
Agent: 0.1~0.5 part.
Preferably, described thin layer includes following weight proportion raw material:
TPX:102~108 parts, PC:11~14 parts, ethyl 2-methacrylate: 5.5~9.5 parts, polyurethane: 3.4~4.6 parts,
Polyimides: 2.1~2.9 parts, polyetheretherketonefiber fiber: 2.6~3.7 parts, carbon fiber: 1.1~1.92 parts, organo montmorillonite: 1.4
~2.5 parts, ethylene glycol: 17~23 parts, silane coupler: 1.2~1.8 parts, antioxidant: 0.15~0.95 part, light stabilizer:
0.2~0.9 part, defoamer: 0.14~0.46 part, thickening agent: 0.15~0.45 part.
Preferably, described thin layer includes following weight proportion raw material:
TPX:104 part, PC:13 part, ethyl 2-methacrylate: 8.5 parts, polyurethane: 4.2 parts, polyimides: 2.5 parts, polyethers
Ether ketone fiber: 3.25 parts, carbon fiber: 1.58 parts, organo montmorillonite: 2 parts, ethylene glycol: 21 parts, silane coupler: 1.5 parts, anti-
Oxygen agent: 0.5 part, light stabilizer: 0.48 part, defoamer: 0.24 part, thickening agent: 0.3 part.
Further, described organo montmorillonite is hexadecyltrimethylammonium chloride.
Further, described silane coupler be VTES, γ aminopropyltriethoxy silane, β-
One in (3,4-expoxycyclohexyl) ethyl trimethoxy silane.
Separately, the one during described antioxidant is antioxidant 1076, antioxidant 164.
Separately having, described light stabilizer is light stabilizer 770.
Again, described defoamer is polyethers or silicone defoamer.
Further, described thickening agent is ethylhydroxyethylcellulose.
The beneficial effects of the present invention is:
(1) described TPX mould release membrance, improves the affinity between release layer and thin layer so that it is possess good peel strength,
It is capable of large area to peel off, meanwhile, improves again the hot strength that release layer is overall.
(2) described TPX mould release membrance, surfacing is bright and clean, possesses good heat stability and percent thermal shrinkage, also has meanwhile
There is heat radiation energy storage effect, being used for isolating, in filling process, if the apparatus overheat that institute isolates, fills, could be by waste heat
Absorption deposit gets up, and has reached quick heat radiating effect, and function is the most diversified.
(3) described TPX mould release membrance, possesses good light aging resisting property, it is possible to be reused multiple times, and cost performance is more
Height, be a kind of combination property more equalize, superior mould release membrance.
(4) described TPX mould release membrance, environment-protecting asepsis, synthetic method is simple, easy and simple to handle, mild condition, it is adaptable to industrialization
Produce.
Detailed description of the invention
Technical scheme in the embodiment of the present invention will be carried out clear, complete description below, it is clear that described enforcement
Example is only a part of embodiment of the present invention rather than whole embodiments.Based on the embodiment in the present invention, this area is common
The every other embodiment that technical staff is obtained on the premise of not making creative work, broadly falls into present invention protection
Scope.
Embodiment one
A kind of TPX mould release membrance, including thin layer, described thin layer includes following weight proportion raw material:
TPX:104 part, PC:13 part, ethyl 2-methacrylate: 8.5 parts, polyurethane: 4.2 parts, polyimides: 2.5 parts, polyethers
Ether ketone fiber: 3.25 parts, carbon fiber: 1.58 parts, organo montmorillonite: 2 parts, ethylene glycol: 21 parts, silane coupler: 1.5 parts, anti-
Oxygen agent: 0.5 part, light stabilizer: 0.48 part, defoamer: 0.24 part, thickening agent: 0.3 part.
Embodiment two
A kind of TPX mould release membrance, including thin layer, described thin layer includes following weight proportion raw material:
TPX:106 part, PC:14 part, ethyl 2-methacrylate: 9.5 parts, polyurethane: 5 parts, polyimides: 2.7 parts, polyethers ether
Ketone fiber: 3 parts, carbon fiber: 2 parts, organo montmorillonite: 2.5 parts, ethylene glycol: 19 parts, silane coupler: 1 part, antioxidant: 0.15
Part, light stabilizer: 1 part, defoamer: 0.14 part, thickening agent: 0.25 part.
Embodiment three
A kind of TPX mould release membrance, including thin layer, described thin layer includes following weight proportion raw material:
TPX:100 part, PC:12 part, ethyl 2-methacrylate: 5.5 parts, polyurethane: 3.4 parts, polyimides: 3 parts, polyethers ether
Ketone fiber: 3.7 parts, carbon fiber: 1.1 parts, organo montmorillonite: 1 part, ethylene glycol: 23 parts, silane coupler: 1.4 parts, antioxidant:
1 part, light stabilizer: 0.1 part, defoamer: 0.46 part, thickening agent: 0.45 part.
Embodiment four
A kind of TPX mould release membrance, including thin layer, described thin layer includes following weight proportion raw material:
TPX:102 part, PC:10 part, ethyl 2-methacrylate: 10 parts, polyurethane: 4.6 parts, polyimides: 2.1 parts, polyethers
Ether ketone fiber: 4 parts, carbon fiber: 1.45 parts, organo montmorillonite: 3 parts, ethylene glycol: 17 parts, silane coupler: 1.2 parts, antioxygen
Agent: 0.7 part, light stabilizer: 0.2 part, defoamer: 0.5 part, thickening agent: 0.1 part.
Embodiment five
A kind of TPX mould release membrance, including thin layer, described thin layer includes following weight proportion raw material:
TPX:108 part, PC:15 part, ethyl 2-methacrylate: 5 parts, polyurethane: 3 parts, polyimides: 2.9 parts, polyether-ether-ketone
Fiber: 2 parts, carbon fiber: 1 part, organo montmorillonite: 2.2 parts, ethylene glycol: 25 parts, silane coupler: 2 parts, antioxidant: 0.95
Part, light stabilizer: 0.9 part, defoamer: 0.3 part, thickening agent: 0.15 part.
Embodiment six
A kind of TPX mould release membrance, including thin layer, described thin layer includes following weight proportion raw material:
TPX:110 part, PC:11 part, ethyl 2-methacrylate: 7 parts, polyurethane: 3.8 parts, polyimides: 2 parts, polyether-ether-ketone
Fiber: 2.6 parts, carbon fiber: 1.92 parts, organo montmorillonite: 1.4 parts, ethylene glycol: 15 parts, silane coupler: 1.8 parts, antioxygen
Agent: 0.1 part, light stabilizer: 0.4 part, defoamer: 0.1 part, thickening agent: 0.5 part.
A kind of TPX mould release membrance that the present invention provides, described TPX mould release membrance, improve the parent between release layer and thin layer
And power so that it is possess good peel strength, it is possible to realize large area and peel off, meanwhile, improve again release layer entirety
Hot strength.Secondly, described TPX mould release membrance, surfacing is bright and clean, possesses good heat stability and percent thermal shrinkage, meanwhile, also
There is heat radiation energy storage effect, being used for isolating, in filling process, if the apparatus overheat that institute isolates, fills, could be by many waste heat
Amount absorbs deposit and gets up, and has reached quick heat radiating effect, and function is the most diversified.Furthermore, a kind of TPX provided by the present invention from
Type film, possesses good light aging resisting property, it is possible to be reused multiple times, and cost performance is higher, be a kind of combination property more
Equilibrium, superior mould release membrance.Further, described TPX mould release membrance, environment-protecting asepsis, synthetic method is simple, easy and simple to handle, mild condition,
It is applicable to industrialized production.
It should be noted that above example is only in order to illustrate technical scheme and unrestricted.Although with reference to relatively
The present invention has been described in detail by good embodiment, it will be understood by those within the art that, can be to the technology of invention
Scheme is modified or equivalent, and without deviating from the scope of technical solution of the present invention, it all should contain the power in the present invention
In profit claimed range.
Claims (9)
1. a TPX mould release membrance, it is characterised in that include that thin layer, described thin layer include following weight proportion raw material:
TPX:100~110 parts, PC:10~15 parts, ethyl 2-methacrylate: 5~10 parts, polyurethane: 3~5 parts, polyamides is sub-
Amine: 2~3 parts, polyetheretherketonefiber fiber: 2~4 parts, carbon fiber: 1~2 part, organo montmorillonite: 1~3 part, ethylene glycol: 15~25
Part, silane coupler: 1~2 part, antioxidant: 0.1~1 part, light stabilizer: 0.1~1 part, defoamer: 0.1~0.5 part, thickening
Agent: 0.1~0.5 part.
A kind of TPX mould release membrance the most according to claim 1, it is characterised in that described thin layer includes following weight proportion
Raw material:
TPX:102~108 parts, PC:11~14 parts, ethyl 2-methacrylate: 5.5~9.5 parts, polyurethane: 3.4~4.6 parts,
Polyimides: 2.1~2.9 parts, polyetheretherketonefiber fiber: 2.6~3.7 parts, carbon fiber: 1.1~1.92 parts, organo montmorillonite: 1.4
~2.5 parts, ethylene glycol: 17~23 parts, silane coupler: 1.2~1.8 parts, antioxidant: 0.15~0.95 part, light stabilizer:
0.2~0.9 part, defoamer: 0.14~0.46 part, thickening agent: 0.15~0.45 part.
A kind of TPX mould release membrance the most according to claim 1, it is characterised in that described thin layer includes following weight proportion
Raw material:
TPX:104 part, PC:13 part, ethyl 2-methacrylate: 8.5 parts, polyurethane: 4.2 parts, polyimides: 2.5 parts, polyethers
Ether ketone fiber: 3.25 parts, carbon fiber: 1.58 parts, organo montmorillonite: 2 parts, ethylene glycol: 21 parts, silane coupler: 1.5 parts, anti-
Oxygen agent: 0.5 part, light stabilizer: 0.48 part, defoamer: 0.24 part, thickening agent: 0.3 part.
4. according to a kind of TPX mould release membrance described in claim 1 or 2 or 3, it is characterised in that described organo montmorillonite is 16
Alkyl trimethyl ammonium chloride.
5. according to a kind of TPX mould release membrance described in claim 1 or 2 or 3, it is characterised in that described silane coupler is ethylene
In ethyl triethoxy silicane alkane, γ aminopropyltriethoxy silane, β-(3,4-expoxycyclohexyl) ethyl trimethoxy silane
One.
6. according to a kind of TPX mould release membrance described in claim 1 or 2 or 3, it is characterised in that described antioxidant is antioxidant
1076, the one in antioxidant 164.
7. according to a kind of TPX mould release membrance described in claim 1 or 2 or 3, it is characterised in that described light stabilizer is that light is stable
Agent 770.
8. according to a kind of TPX mould release membrance described in claim 1 or 2 or 3, it is characterised in that described defoamer be polyethers or
Silicone defoamer.
9. according to a kind of TPX mould release membrance described in claim 1 or 2 or 3, it is characterised in that described thickening agent is ethyl hydroxyl second
Base cellulose.
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CN201610590984.2A CN106188899A (en) | 2016-07-26 | 2016-07-26 | A kind of TPX mould release membrance |
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CN201610590984.2A CN106188899A (en) | 2016-07-26 | 2016-07-26 | A kind of TPX mould release membrance |
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Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN108797200A (en) * | 2018-07-02 | 2018-11-13 | 温州新意特种纸业有限公司 | A kind of high temperature leather release paper |
CN109466124A (en) * | 2017-12-27 | 2019-03-15 | 宁波长阳科技股份有限公司 | A kind of release film |
Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
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CN103464013A (en) * | 2013-07-25 | 2013-12-25 | 烟台绿水赋膜材料有限公司 | High-performance hybrid separation membrane and preparation method thereof |
CN104945875A (en) * | 2015-05-29 | 2015-09-30 | 吉翔宝(太仓)离型材料科技发展有限公司 | Polycarbonate release film |
CN104962043A (en) * | 2015-05-29 | 2015-10-07 | 吉翔宝(太仓)离型材料科技发展有限公司 | PET photodiffusion release film |
-
2016
- 2016-07-26 CN CN201610590984.2A patent/CN106188899A/en active Pending
Patent Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN103464013A (en) * | 2013-07-25 | 2013-12-25 | 烟台绿水赋膜材料有限公司 | High-performance hybrid separation membrane and preparation method thereof |
CN104945875A (en) * | 2015-05-29 | 2015-09-30 | 吉翔宝(太仓)离型材料科技发展有限公司 | Polycarbonate release film |
CN104962043A (en) * | 2015-05-29 | 2015-10-07 | 吉翔宝(太仓)离型材料科技发展有限公司 | PET photodiffusion release film |
Cited By (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN109466124A (en) * | 2017-12-27 | 2019-03-15 | 宁波长阳科技股份有限公司 | A kind of release film |
CN109466124B (en) * | 2017-12-27 | 2021-08-06 | 宁波长阳科技股份有限公司 | Release film |
CN108797200A (en) * | 2018-07-02 | 2018-11-13 | 温州新意特种纸业有限公司 | A kind of high temperature leather release paper |
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